EP1718778A1 - Material based on an aluminum alloy, method for the production thereof and its use - Google Patents
Material based on an aluminum alloy, method for the production thereof and its useInfo
- Publication number
- EP1718778A1 EP1718778A1 EP05714972A EP05714972A EP1718778A1 EP 1718778 A1 EP1718778 A1 EP 1718778A1 EP 05714972 A EP05714972 A EP 05714972A EP 05714972 A EP05714972 A EP 05714972A EP 1718778 A1 EP1718778 A1 EP 1718778A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- magnesium
- base alloy
- content
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/0084—Pistons the pistons being constructed from specific materials
Definitions
- the present invention relates to a method for producing a material based on an aluminum alloy according to the preamble of claim 1, a material obtainable with this method and the use of this material.
- pistons have typically been made from cast aluminum-silicon alloys. Because of the good casting properties, pistons based on aluminum-silicon alloys can be manufactured relatively cheaply and easily using the permanent mold casting process.
- These materials are typically with silicon contents between 12 and 18 wt .-%, in individual cases also up to 24 wt .-%, and with admixtures of magnesium between 1 to 1.5 wt .-%, copper between 1 and 3 wt .-% % and often nickel alloyed between 1 to 3 wt .-%.
- z. B. according to US Pat. No. 6,419,769 A1 recommends setting the copper content between 5.6 and 8.0% by weight.
- FR 2 690 957 A1 the strength of such an alloy is further increased by adding the elements titanium, zirconium and vanadium. However, the alloying of these strength-increasing elements increases the density of the material.
- a heat-resistant alloy with a reduced specific weight is described in patent specification DE 747 355 as being particularly advantageous for pistons.
- This material is characterized by a magnesium content between 4 and 12 wt .-% and a silicon content between 0.5 and 5 wt .-%, the silicon content should always be less than half the magnesium content. Furthermore, between 0.2 and 5% by weight of copper and / or nickel are added. Even without the addition of strength-enhancing components, this material should be characterized by improved heat resistance.
- the magnesium is therefore added depending on the silicon content desired in each case according to the above formula. Some of the magnesium (1.73xSi content) reacts directly with silicon to form magnesium silicide, the remaining 1.5 to 6.0% by mass of magnesium dissolve in the aluminum mixed crystal and, after suitable heat treatment together with copper, increase the strength of the material.
- the material can contain the usual impurities in aluminum alloys. In addition, the alloying of further alloying elements could appear sensible for the purpose of further strengthening. It is known e.g.
- the material obtainable by the process according to the invention is distinguished by excellent strength properties which, even at elevated temperatures, prove to be superior to the piston alloys customary today.
- Advantageous further developments result from the subclaims.
- the base alloy can be treated with all known hot forming processes, for example extrusion, hot rolling or forging. Hot forming should be carried out with a degree of deformation greater than 5 times.
- the aluminum or base alloy used should only contain a small proportion of foreign elements, and not more than 1% by mass per foreign element.
- a heat treatment is advantageously carried out after the hot shaping. This can be done in a manner known per se by solution annealing, quenching and hot aging.
- the material according to the invention is suitable for the production of all types of components, in particular pistons for internal combustion engines.
- the resulting raw material is pre-heated to 400 to 500 ° C warms and 10 times formed by extrusion and then hardened. For this purpose, a heat treatment comprising solution annealing at 500 ° C. for 2 hours, quenching in water and 10 hours tempering at 210 ° C. is carried out
- a heat treatment comprising solution annealing at 500 ° C. for 2 hours, quenching in water and 10 hours tempering at 210 ° C. is carried out.
- Beryllium is added to reduce the tendency of the melt to oxidize.
- Magnesium phosphate is used to refine the grain of the primarily solidifying magnesium silicide. Iron was analyzed as an impurity.
- the finished material shows the following properties:
- the material according to the invention is distinguished from the British aluminum standard 2618 by a lower density and an increased modulus of elasticity.
- the static strength properties achieved match the high-strength wrought alloy 2618.
- the fatigue strength determined clearly exceeds the values achieved with the wrought alloy 2618.
- the material according to the invention is superior in both static and dynamic testing. This combination of properties makes it particularly suitable for the manufacture of pistons for internal combustion engines.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Powder Metallurgy (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Extrusion Of Metal (AREA)
- Forging (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004007704A DE102004007704A1 (en) | 2004-02-16 | 2004-02-16 | Production of a material based on an aluminum alloy used for producing motor vehicle engine components comprises forming an aluminum base alloy containing silicon and magnesium, hot deforming and heat treating |
PCT/DE2005/000254 WO2005078147A1 (en) | 2004-02-16 | 2005-02-15 | Material based on an aluminum alloy, method for the production thereof and its use |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1718778A1 true EP1718778A1 (en) | 2006-11-08 |
EP1718778B1 EP1718778B1 (en) | 2017-04-19 |
Family
ID=34801930
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05714972.6A Expired - Fee Related EP1718778B1 (en) | 2004-02-16 | 2005-02-15 | Material based on an aluminum alloy, method for the production thereof and its use |
Country Status (8)
Country | Link |
---|---|
US (1) | US7892482B2 (en) |
EP (1) | EP1718778B1 (en) |
JP (1) | JP4914225B2 (en) |
KR (1) | KR101220577B1 (en) |
CN (1) | CN100503857C (en) |
BR (1) | BRPI0507719B1 (en) |
DE (1) | DE102004007704A1 (en) |
WO (1) | WO2005078147A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007035124A1 (en) | 2007-07-27 | 2009-01-29 | FNE Forschungsinstitut für Nichteisen-Metalle GmbH | Lightweight construction material with dense, pore-free structure, comprises magnesium silicide reinforcing material in aluminum matrix and is obtained by squeeze-casting |
DE102007035115A1 (en) | 2007-07-27 | 2009-01-29 | FNE Forschungsinstitut für Nichteisen-Metalle GmbH | Aluminum-matrix material for building contains concentration gradient of magnesium silicide |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008056511B4 (en) * | 2008-11-08 | 2011-01-20 | Audi Ag | Process for producing thin-walled metal components from an Al-SiMg alloy, in particular components of a motor vehicle |
CN101985706A (en) * | 2010-11-18 | 2011-03-16 | 江苏万里活塞轴瓦有限公司 | Aluminum alloy material for hot precision forging connection rod and preparation method thereof |
KR101423447B1 (en) * | 2010-12-22 | 2014-07-24 | 쇼와 덴코 가부시키가이샤 | Method for producing formed material for brake piston |
CN102335704B (en) * | 2011-09-22 | 2013-08-28 | 哈尔滨哈飞工业有限责任公司 | Method for forging and forming structural parts of wheel chair rack |
CN103394538A (en) * | 2013-08-06 | 2013-11-20 | 浙江瑞金铜铝型材有限公司 | Molding and aging technology of 7A04 superhard aluminum alloy section bar |
US20160201177A1 (en) * | 2013-08-21 | 2016-07-14 | Drexel University | Selective Grain Boundary Engineering |
CN104451286A (en) * | 2014-12-02 | 2015-03-25 | 绥阳县耐环铝业有限公司 | Magnesium-aluminum alloy and processing technique thereof |
CN104741873A (en) * | 2015-01-30 | 2015-07-01 | 深圳市江为五金螺丝有限公司 | Numerical control extrusion process |
CN104668300B (en) * | 2015-01-30 | 2018-04-27 | 深圳市江为五金螺丝有限公司 | Aluminum alloy extrusion processing technology |
EP3334850A4 (en) | 2015-08-13 | 2019-03-13 | Alcoa USA Corp. | Improved 3xx aluminum casting alloys, and methods for making the same |
CN105648290A (en) * | 2016-03-15 | 2016-06-08 | 昆明理工大学 | High-strength aluminum alloy and preparation method thereof |
KR20170124963A (en) * | 2016-05-03 | 2017-11-13 | 손희식 | Corrosion resistant aluminium alloy for casting |
US10851447B2 (en) | 2016-12-02 | 2020-12-01 | Honeywell International Inc. | ECAE materials for high strength aluminum alloys |
US11649535B2 (en) | 2018-10-25 | 2023-05-16 | Honeywell International Inc. | ECAE processing for high strength and high hardness aluminum alloys |
CN109431152A (en) * | 2018-12-07 | 2019-03-08 | 福建祥鑫股份有限公司 | A kind of folding type aluminum alloy nursing bed and its manufacturing method |
CN109988952B (en) * | 2019-05-10 | 2020-05-05 | 贵州正合可来金科技有限责任公司 | Preparation method of aluminum alloy mobile phone shell |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE747355C (en) * | 1937-10-30 | 1944-09-20 | Mahle Kg | Use of an aluminum alloy for pistons in internal combustion engines |
DE1483229C2 (en) | 1965-09-03 | 1980-04-17 | Honsel-Werke Ag, 5778 Meschede | Use of AlMgSi-GuB alloy for cylinder heads |
JPS508693B1 (en) * | 1969-10-09 | 1975-04-07 | ||
JPS508693A (en) | 1973-05-22 | 1975-01-29 | ||
US4917739A (en) * | 1984-08-10 | 1990-04-17 | Allied-Signal Inc. | Rapidly solidified aluminum-transition metal-silicon alloys |
DE3842812A1 (en) | 1988-12-20 | 1990-06-21 | Metallgesellschaft Ag | CAST LIGHT MATERIAL |
US5178686A (en) * | 1988-12-20 | 1993-01-12 | Metallgesellschaft Aktiengesellschaft | Lightweight cast material |
FR2690957B1 (en) | 1992-05-06 | 1994-06-17 | Senaux Pierre | DEVICE FOR FIXING COLLARS SUPPORTING POSTERS OR FLAGS, WITHOUT ELEVATION MEANS OR FIXING MATERIALS. |
US5520754A (en) | 1994-04-25 | 1996-05-28 | Lockheed Missiles & Space Company, Inc. | Spray cast Al-Li alloy composition and method of processing |
ATE228580T1 (en) * | 1997-08-30 | 2002-12-15 | Honsel Gmbh & Co Kg | ALLOY AND METHOD FOR PRODUCING OBJECTS FROM THIS ALLOY |
US6419769B1 (en) | 1998-09-08 | 2002-07-16 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Aluminum-silicon alloy having improved properties at elevated temperatures and process for producing cast articles therefrom |
-
2004
- 2004-02-16 DE DE102004007704A patent/DE102004007704A1/en not_active Ceased
-
2005
- 2005-02-15 CN CNB2005800049055A patent/CN100503857C/en not_active Expired - Fee Related
- 2005-02-15 JP JP2006553426A patent/JP4914225B2/en not_active Expired - Fee Related
- 2005-02-15 KR KR1020067016815A patent/KR101220577B1/en not_active IP Right Cessation
- 2005-02-15 EP EP05714972.6A patent/EP1718778B1/en not_active Expired - Fee Related
- 2005-02-15 US US10/589,215 patent/US7892482B2/en active Active
- 2005-02-15 BR BRPI0507719-2B1A patent/BRPI0507719B1/en not_active IP Right Cessation
- 2005-02-15 WO PCT/DE2005/000254 patent/WO2005078147A1/en active Search and Examination
Non-Patent Citations (1)
Title |
---|
See references of WO2005078147A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007035124A1 (en) | 2007-07-27 | 2009-01-29 | FNE Forschungsinstitut für Nichteisen-Metalle GmbH | Lightweight construction material with dense, pore-free structure, comprises magnesium silicide reinforcing material in aluminum matrix and is obtained by squeeze-casting |
DE102007035115A1 (en) | 2007-07-27 | 2009-01-29 | FNE Forschungsinstitut für Nichteisen-Metalle GmbH | Aluminum-matrix material for building contains concentration gradient of magnesium silicide |
Also Published As
Publication number | Publication date |
---|---|
US20070169861A1 (en) | 2007-07-26 |
EP1718778B1 (en) | 2017-04-19 |
JP2007522348A (en) | 2007-08-09 |
KR101220577B1 (en) | 2013-01-10 |
KR20060127147A (en) | 2006-12-11 |
BRPI0507719A (en) | 2007-07-03 |
BRPI0507719B1 (en) | 2013-11-26 |
CN1918311A (en) | 2007-02-21 |
JP4914225B2 (en) | 2012-04-11 |
CN100503857C (en) | 2009-06-24 |
US7892482B2 (en) | 2011-02-22 |
DE102004007704A1 (en) | 2005-08-25 |
WO2005078147A1 (en) | 2005-08-25 |
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