EP2954081B1 - Aluminium casting alloy - Google Patents

Aluminium casting alloy Download PDF

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Publication number
EP2954081B1
EP2954081B1 EP14706468.7A EP14706468A EP2954081B1 EP 2954081 B1 EP2954081 B1 EP 2954081B1 EP 14706468 A EP14706468 A EP 14706468A EP 2954081 B1 EP2954081 B1 EP 2954081B1
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EP
European Patent Office
Prior art keywords
aluminium casting
casting alloy
content
contained
alloy according
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Not-in-force
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EP14706468.7A
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German (de)
French (fr)
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EP2954081A1 (en
Inventor
Klaus Greven
Manikandan Loganathan
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KSM Castings Group GmbH
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KSM Castings Group GmbH
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D18/00Pressure casting; Vacuum casting
    • B22D18/04Low pressure casting, i.e. making use of pressures up to a few bars to fill the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D18/00Pressure casting; Vacuum casting
    • B22D18/06Vacuum casting, i.e. making use of vacuum to fill the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/002Castings of light metals
    • B22D21/007Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04Modified aluminium-silicon alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

Definitions

  • the invention relates to an aluminum casting alloy.
  • the present invention seeks to optimize such Si-poor AI casting alloy in terms of their mechanical properties such that saved when using them for the production of cast components, especially in the chassis of motor vehicles, material and with this material savings accompanying and known in the art advantages in the automotive sector can be achieved.
  • Such an Al casting alloy is stronger, tougher and more ductile than the prior art.
  • the alloys according to the invention may contain production-related impurities, e.g. Pb, Ni, etc., as well known to those skilled in the art.
  • Si is contained with a content of more than 3.1 to less than 3.7 wt .-%. It may be advantageous for certain applications if Si is included at a level of greater than 3.3 to less than 3.7 weight percent. For some other applications, it may be advantageous to include Si at a level of greater than 3.0 to less than 3.3 percent by weight.
  • Mg is contained at a content of 0.5 to 0.6 wt .-%. It may be advantageous if Mg is contained at a content of 0.5 to less than 0.6 wt .-%, preferably from 0.5 to 0.55 wt .-%.
  • Cr is contained at a content of 0.10 to less than 0.20 wt .-%.
  • Cr is contained at a level of 0.12 to 0.17 wt .-%.
  • Fe is contained at a content of 0.01 to 0.15 wt .-%.
  • Mn with a content of 0.01 to 0.05 wt .-%
  • Ti is contained at a content of 0.05 to 0.15 wt .-%.
  • Cu is contained at a content of 0.001 to 0.005 wt .-%.
  • Sr is contained with a content of 0.015 to 0.025 wt .-%.
  • Zr is contained at a content of 0.001 to 0.005 wt .-%.
  • Zn is contained at a content of 0.001 to 0.005 wt .-%.
  • impurities For many applications it may be advantageous to contain impurities with a content of ⁇ 0.05% by weight. For various applications, it may also be advantageous if impurities with a content of ⁇ 0.005 wt .-% are included.
  • the aluminum casting alloy according to the invention is a low-pressure Al casting alloy.
  • the invention also relates to a method for producing a cast component made of an Al casting alloy according to one of claims 1 to 14, in which the low-pressure casting method is used.
  • the Al casting alloy is a counter pressure (CPC) -AI cast alloy.
  • the invention also relates to a method for producing a cast component from an Al casting alloy according to one of claims 1 to 14, in which the low-pressure counter-pressure casting method is used.
  • a manufacturing method for cast components especially as Fahniverksmaschine, preferably as Radder parts, preferably as Dämpferstelzen, wheel or pivot bearing, of motor vehicles from the casting alloy according to the invention can advantageously squeeze casting, gravity die casting or die casting, in particular the Thixo-, Rheo - or low-pressure sand casting, find application.
  • the cast components are subjected to a two-stage heat treatment, namely solution heat treatment and subsequent heat aging. It may be advantageous if the cast component is quenched in water between the two heat treatment stages.
  • the cast component after the casting process between 530 ° C and 550 ° C for 6 to 10h, preferably between 540 ° C and 550 ° C for 7 to 9 h, especially for 8 to 9h, most preferably between more than 540 ° C and 550 ° C for 7 to 9 h, in particular for 8 to 9h, solution-annealed.
  • the cast component after the casting process between 180 ° C and 210 ° C for 1 to 8h, especially for 1 to 6.5 h, preferably between 180 ° C. and 190 ° C. for 1 to 6.5 hours, in particular for 4 to 6.5 hours, more preferably between 180 ° C. and less than 190 ° C. for 4 to 6.5 hours, in particular for 5 to 6.5 hours, is started.
  • the invention further provides for the use of an Al casting alloy according to one of the claims or a heat-treated cast component according to one of claims for motor vehicle parts, preferably for wheel-guiding components of motor vehicles, very particularly preferably for damper stilts, wheel carriers or pivot bearings of motor vehicles.
  • the cast components have an improved strength-elongation ratio with improved structural properties.
  • the casting process enables one of a large defect, known as voids, free casting, on the other hand, the microstructure is positively influenced in such a way that the number of internal notches, which reduce the elongation at break, is minimized.
  • the aluminum casting alloy according to the invention has proven particularly suitable for components subject to heavy loads, such as shock absorber stilts, wheel carriers or pivot bearings.
  • the counter-pressure die casting method (CPC method) is used.
  • Cast components according to the invention which are produced from an Al casting alloy according to one of the claims and / or by a process according to one of the claims, are characterized by a heat treatment by a yield strength R P 0.2 of 300 to 325 MPa, preferably of 305 to 310 MPa, and / or an elongation at break A5 of 4 to 10%, preferably of 7 to 9%, and / or a tensile strength R m of 350-375 MPa, preferably 350-360 MPa.
  • a so-called "French tensile bar” according to DIN 50125 is separated out of a swivel bearing produced by a counter-pressure die casting process (CPC process), the swivel bearing undergoing a heat treatment in advance (solution annealing 540 ° C for 8 h, quenching in water, hot aging 180 ° C for 6,5 h).
  • CPC process counter-pressure die casting process
  • the casting of comparative samples (AlSi3Mg0.5 and AlSi3Mg0.5Cr0.3) and the subsequent heat treatment takes place under the same conditions.
  • the alloys to be compared differ only in the chromium content.
  • the sample rod is removed at the same point of the pivot bearing.
  • chassis part preferably the damper stilts or the wheel carrier
  • CPC counter-pressure chill casting

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Body Structure For Vehicles (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Cookers (AREA)
  • Vehicle Body Suspensions (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Heat Treatment Of Articles (AREA)
  • Forging (AREA)

Description

Die Erfindung bezieht sich auf eine Aluminium-Gusslegierung.The invention relates to an aluminum casting alloy.

Aus der DE 10 2008 055 928 A1 ist eine Al-Gusslegierung bekannt, welche nachfolgend angeführte Legierungsbestandteile

  • Si: 2,5 bis 3,3, vorzugsweise 2,7 bis 3,1 Gew.-%
  • Mg: 0,2 bis 0,7, vorzugsweise 0,3 bis 0,6 Gew.-%
  • Fe: < 0,18, vorzugsweise 0,05 bis 0,16 Gew.-%
  • Mn: < 0,5, vorzugsweise 0,05 bis 0,4 Gew.-%
  • Ti: < 0,1, vorzugsweise 0,01 bis 0,08 Gew.-%
  • Sr: < 0,03, vorzugsweise 0,01 bis 0,03 Gew.-%
  • Cr: 0,3 bis 1,3, vorzugsweise 0,4 bis 1,0,
    besonders bevorzugt 0,5 bis 0,8 Gew.-%
  • Sonstige: < 0,1 Gew.-%
  • enthält, und jeweils zu 100 Gew.-% mit Al ergänzt ist.
From the DE 10 2008 055 928 A1 For example, an Al-casting alloy is known, which alloy components listed below
  • Si: 2.5 to 3.3, preferably 2.7 to 3.1 wt.%
  • Mg: 0.2 to 0.7, preferably 0.3 to 0.6 wt%
  • Fe: <0.18, preferably 0.05 to 0.16 wt%
  • Mn: <0.5, preferably 0.05 to 0.4 wt%
  • Ti: <0.1, preferably 0.01 to 0.08 wt%
  • Sr: <0.03, preferably 0.01 to 0.03 wt%
  • Cr: 0.3 to 1.3, preferably 0.4 to 1.0,
    more preferably 0.5 to 0.8% by weight
  • Other: <0.1% by weight
  • contains, and in each case to 100 wt .-% is supplemented with Al.

Ausgehend von diesem Stand der Technik liegt der Erfindung die Aufgabe zugrunde, eine solche Si-arme AI-Gusslegierung hinsichtlich ihrer mechanischen Eigenschaften derart zu optimieren, dass bei ihrer Verwendung zur Herstellung von Gussbauteilen insbesondere im Fahrwerksbereich von Kraftfahrzeugen, Material eingespart und die mit dieser Materialeinsparung einhergehenden und dem Fachmann bekannten Vorteile im Kraftfahrzeugbereich erreicht werden können.Based on this prior art, the present invention seeks to optimize such Si-poor AI casting alloy in terms of their mechanical properties such that saved when using them for the production of cast components, especially in the chassis of motor vehicles, material and with this material savings accompanying and known in the art advantages in the automotive sector can be achieved.

Dies wird gemäß der Erfindung durch eine Al-Gusslegierung erzielt, die nachfolgend angeführte Legierungsbestandteile

  • Si: 3,0 bis 3,8 Gew.-%
  • Mg: 0,3 bis 0,6
  • Cr: 0,05 bis <0,25 Gew.-%
  • Fe: < 0,18 Gew.-%
  • Mn: < 0,06 Gew.-%
  • Ti: < 0,16 Gew.-%
  • Cu: < 0,006 Gew.-%
  • Sr: 0,010 bis 0,030
  • Zr <0,006 Gew.-%
  • Zn <0,006 Gew.-%
  • Verunreinigungen: < 0,1 Gew.-%,
  • enthält und jeweils zu 100 Gew.-% mit Al ergänzt ist.
This is achieved according to the invention by an Al casting alloy, the alloying components listed below
  • Si: 3.0 to 3.8% by weight
  • Mg: 0.3 to 0.6
  • Cr: 0.05 to <0.25 wt%
  • Fe: <0.18 wt%
  • Mn: <0.06 wt%
  • Ti: <0.16 wt%
  • Cu: <0.006 wt%
  • Sr: 0.010 to 0.030
  • Zr <0.006 wt%
  • Zn <0.006 wt%
  • Impurities: <0.1% by weight,
  • contains and in each case to 100 wt .-% is supplemented with Al.

Eine solche Al-Gusslegierung ist gegenüber dem Stand der Technik stärker, zäher und duktiler.Such an Al casting alloy is stronger, tougher and more ductile than the prior art.

Die erfindungsgemäße Auswahl an Legierungsbestandteilen in der genannten Größenordnung führt zu einer weiteren signifikanten Verbesserung der mechanischen Eigenschaften, die bereits im Gusszustand, insbesondere jedoch bei einem Gussbauteil nach einer 2-stufigen Wärmebehandlung, nämlich einem Lösungsglühen und einem anschließenden Auslagern zu verzeichnen ist, wobei zwischen diesen beiden Wärmebehandlungsstufen vorzugsweise ein Abschrecken des Gussbauteils in Wasser vorgesehen ist. Für Fahniverksanwendungen, vorzugsweise für radführende Bauteile, ganz bevorzugt für Dämpferstelzen, Radträger und insbesondere Schwenklager, ergeben sich so insgesamt erhöhte mechanische Kennwerte.The inventive selection of alloy constituents in the stated order of magnitude leads to a further significant improvement of the mechanical properties, which is already in the cast state, but especially in a cast component after a 2-stage heat treatment, namely a solution annealing and a subsequent aging, between them both heat treatment stages is preferably provided a quenching of the cast component in water. For flagship applications, preferably for wheel-guiding components, very preferably for damper stilts, wheel carriers and in particular pivot bearings, this results in an overall increased mechanical characteristic values.

Vollkommen unerwartet hat sich insbesondere in Bezug auf den mechanischen Kennwert der Bruchdehnung A5 gezeigt, dass der für Chrom gemäß DE 10 2008 055 928 A1 als kritisch angegebene untere Grenzwert von 0,3 Gew.-% erfindungsgemäß weiter unterschritten werden kann.Quite unexpectedly, it has been found, in particular with regard to the mechanical characteristic of the elongation at break A5, that for chromium according to DE 10 2008 055 928 A1 as critically specified lower limit of 0.3 wt .-% according to the invention can be further exceeded.

Die erfindungsgemäßen Legierungen können herstellungsbedingte Verunreinigungen, z.B. Pb, Ni, etc., enthalten, wie sie dem Fachmann allgemein bekannt sind.The alloys according to the invention may contain production-related impurities, e.g. Pb, Ni, etc., as well known to those skilled in the art.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Si mit einem Gehalt von mehr als 3,1 bis weniger als 3,7 Gew.-% enthalten ist. Es kann für bestimmte Anwendungsfälle vorteilhaft sein, wenn Si mit einem Gehalt von mehr als 3,3 bis weniger als 3,7 Gew.-% enthalten ist. Für einige andere Anwendungsfälle kann vorteilhaft sein, wenn Si mit einem Gehalt von mehr als 3,0 bis weniger als 3,3 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Si is contained with a content of more than 3.1 to less than 3.7 wt .-%. It may be advantageous for certain applications if Si is included at a level of greater than 3.3 to less than 3.7 weight percent. For some other applications, it may be advantageous to include Si at a level of greater than 3.0 to less than 3.3 percent by weight.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Mg mit einem Gehalt von 0,5 bis 0,6 Gew.-% enthalten ist. Es kann vorteilhaft sein, wenn Mg mit einem Gehalt von 0,5 bis weniger als 0,6 Gew.-%, vorzugsweise von 0,5 bis 0,55 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Mg is contained at a content of 0.5 to 0.6 wt .-%. It may be advantageous if Mg is contained at a content of 0.5 to less than 0.6 wt .-%, preferably from 0.5 to 0.55 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Cr mit einem Gehalt von 0,10 bis weniger als 0,20 Gew.-% enthalten ist. Für einige Einsatzfälle kann es vorteilhaft sein, wenn Cr mit einem Gehalt von 0,12 bis 0,17 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Cr is contained at a content of 0.10 to less than 0.20 wt .-%. For some applications, it may be advantageous if Cr is contained at a level of 0.12 to 0.17 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Fe mit einem Gehalt von 0,01 bis 0,15 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Fe is contained at a content of 0.01 to 0.15 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Mn mit einem Gehalt von 0,01 bis 0,05 Gew.-%For an optimization of the mechanical characteristics, it may be advantageous if Mn with a content of 0.01 to 0.05 wt .-%

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Ti mit einem Gehalt von 0,05 bis 0,15 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Ti is contained at a content of 0.05 to 0.15 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Cu mit einem Gehalt von 0,001 bis 0,005 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Cu is contained at a content of 0.001 to 0.005 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Sr mit einem Gehalt von 0,015 bis 0,025 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Sr is contained with a content of 0.015 to 0.025 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Zr mit einem Gehalt von 0,001 bis 0,005 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Zr is contained at a content of 0.001 to 0.005 wt .-%.

Für eine Optimierung der mechanischen Kennwerte kann es vorteilhaft sein, wenn Zn mit einem Gehalt von 0,001 bis 0,005 Gew.-% enthalten ist.For an optimization of the mechanical characteristics, it may be advantageous if Zn is contained at a content of 0.001 to 0.005 wt .-%.

Für zahlreiche Anwendungen kann es von Vorteil sein, wenn Verunreinigungen mit einem Gehalt von <0,05 Gew.-% enthalten sind. Für diverse Anwendungen kann es auch von Vorteil sein, wenn Verunreinigungen mit einem Gehalt von <0,005 Gew.-% enthalten sind.For many applications it may be advantageous to contain impurities with a content of <0.05% by weight. For various applications, it may also be advantageous if impurities with a content of <0.005 wt .-% are included.

Für gewisse Gussbauteile hat es sich als vorteilhaft herausgestellt, wenn die erfindungsgemäße Al-Gusslegierung eine Niederdruck-AI-Gusslegierung ist.For certain cast components, it has proven to be advantageous if the aluminum casting alloy according to the invention is a low-pressure Al casting alloy.

Entsprechend betrifft die Erfindung auch ein Verfahren zur Herstellung eines Gussbauteils aus einer Al-Gusslegierung nach einem der Ansprüche 1 bis 14, bei welchem das Niederdruck-Gießverfahren Anwendung findet.Accordingly, the invention also relates to a method for producing a cast component made of an Al casting alloy according to one of claims 1 to 14, in which the low-pressure casting method is used.

Für bestimmte Gussbauteile hat es sich als vorteilhaft herausgestellt, wenn die AI-Gusslegierung eine Gegendruck (CPC)-AI-Gusslegierung ist.For certain cast components, it has been found to be advantageous if the Al casting alloy is a counter pressure (CPC) -AI cast alloy.

Entsprechend betrifft die Erfindung auch ein Verfahren zur Herstellung eines Gussbauteils aus einer Al-Gusslegierung nach einem der Ansprüche 1 bis 14, bei welchem das Niederdruck-Gegendruck-Gießverfahren Anwendung findet.Accordingly, the invention also relates to a method for producing a cast component from an Al casting alloy according to one of claims 1 to 14, in which the low-pressure counter-pressure casting method is used.

Als Fertigungsverfahren für Gussbauteile, insbesondere als Fahniverksteile, vorzugsweise als radführende Teile, ganz bevorzugt als Dämpferstelzen, Radträger oder Schwenklager, von Kraftfahrzeugen aus der erfindungsgemäßen Gusslegierung sind grundsätzlich verschiedene Dauerformgießverfahren geeignet. Aufgrund der sehr guten mechanischen Eigenschaften bei hochbeanspruchten radführenden Teilen von Kraftfahrzeugen eignen sich aber besonders der Niederdruck-Kokillenguss sowie das Gegendruck-Gießverfahren (CPC-Verfahren), das auch als Gegendruck-Kokillengießverfahren bezeichnet wird, als Fertigungsverfahren.As a manufacturing method for cast components, in particular as Fahniverksteile, preferably as Radder parts, most preferably as Dämpfer stilts, wheel or pivot bearings of motor vehicles from the cast alloy according to the invention are fundamentally different Dauerformgießverfahren suitable. Due to the very good mechanical properties of highly stressed wheel-guiding parts of motor vehicles but are particularly low-pressure chill casting and the counter-pressure casting process (CPC process), which is also referred to as a counter-pressure Kokillengießverfahren, as a manufacturing process.

Als Fertigungsverfahren für Gussbauteile, insbesondere als Fahniverksteile, vorzugsweise als radführende Teile, ganz bevorzugt als Dämpferstelzen, Radträger oder Schwenklager, von Kraftfahrzeugen aus der erfindungsgemäßen Gusslegierung kann vorteilhaft das Squeeze-Casting, der Schwerkraft-Kokillenguss oder der Druckguss, insbesondere der Thixo-, Rheo- oder Niederdruck-Sandguss, Anwendung finden.As a manufacturing method for cast components, especially as Fahniverksteile, preferably as Radder parts, preferably as Dämpferstelzen, wheel or pivot bearing, of motor vehicles from the casting alloy according to the invention can advantageously squeeze casting, gravity die casting or die casting, in particular the Thixo-, Rheo - or low-pressure sand casting, find application.

Um die oben genannten Vorteile zu erzielen oder noch weiter zu entwickeln, ist es vorteilhaft, wenn die gegossenen Bauteile einer zweistufigen Wärmebehandlung, nämlich einem Lösungsglühen und einem anschließenden Warmauslagern, unterzogen werden. Es kann vorteilhaft sein, wenn das Gussbauteil zwischen den beiden Wärmebehandlungsstufen in Wasser abgeschreckt wird.In order to achieve or further develop the above-mentioned advantages, it is advantageous if the cast components are subjected to a two-stage heat treatment, namely solution heat treatment and subsequent heat aging. It may be advantageous if the cast component is quenched in water between the two heat treatment stages.

Es kann zweckmäßig sein, wenn das Gussbauteil nach dem Gießprozess zwischen 530°C und 550°C für 6 bis 10h, vorzugsweise zwischen 540°C und 550°C für 7 bis 9 h, insbesondere für 8 bis 9h, ganz besonders bevorzugt zwischen mehr als 540°C und 550°C für 7 bis 9 h, insbesondere für 8 bis 9h, lösungsgeglüht wird.It may be expedient if the cast component after the casting process between 530 ° C and 550 ° C for 6 to 10h, preferably between 540 ° C and 550 ° C for 7 to 9 h, especially for 8 to 9h, most preferably between more than 540 ° C and 550 ° C for 7 to 9 h, in particular for 8 to 9h, solution-annealed.

Es kann zweckmäßig sein, wenn das Gussbauteil nach dem Gießprozess zwischen 180°C und 210°C für 1 bis 8h, insbesondere für 1 bis 6,5h, vorzugsweise zwischen 180°C und 190°C für 1 bis 6,5h, insbesondere für 4 bis 6,5h, besonders bevorzugt zwischen 180°C und weniger als 190°C für 4 bis 6,5h, insbesondere für 5 bis 6,5h, angelassen wird.It may be expedient if the cast component after the casting process between 180 ° C and 210 ° C for 1 to 8h, especially for 1 to 6.5 h, preferably between 180 ° C. and 190 ° C. for 1 to 6.5 hours, in particular for 4 to 6.5 hours, more preferably between 180 ° C. and less than 190 ° C. for 4 to 6.5 hours, in particular for 5 to 6.5 hours, is started.

Die Erfindung sieht ferner die Verwendung einer Al-Gusslegierung nach einem der Ansprüche oder eines insbesondere wärmebehandelten Gussbauteils nach einem der Ansprüche für Fahniverksteile von Kraftfahrzeugen, vorzugsweise für radführende Bauteile von Kraftfahrzeugen, ganz besonders bevorzugt für Dämpferstelzen, Radträger oder Schwenklager von Kraftfahrzeugen vor.The invention further provides for the use of an Al casting alloy according to one of the claims or a heat-treated cast component according to one of claims for motor vehicle parts, preferably for wheel-guiding components of motor vehicles, very particularly preferably for damper stilts, wheel carriers or pivot bearings of motor vehicles.

Erfindungsgemäß weisen die Gussbauteile ein verbessertes Festigkeits-Dehnungsverhältnis bei verbesserten Gefügeeigenschaften auf. Das Gießverfahren ermöglicht zum einen ein von großen Fehlern, bekannt als Lunker, freies Gussstück, zum anderen wird die Mikrostruktur in einer solchen Weise positiv beeinflusst, dass die Anzahl innerer Kerben, die die Bruchdehnung verringern, möglichst gering gehalten wird.According to the invention, the cast components have an improved strength-elongation ratio with improved structural properties. On the one hand, the casting process enables one of a large defect, known as voids, free casting, on the other hand, the microstructure is positively influenced in such a way that the number of internal notches, which reduce the elongation at break, is minimized.

Wie bereits erwähnt hat sich die erfindungsgemäße Al-Gusslegierung insbesondere für stärker beanspruchte Komponenten, wie Dämpferstelzen, Radträger oder Schwenklager, als besonders geeignet herausgestellt. Als ganz bevorzugtes Verfahren zur Herstellung solcher stärker beanspruchter Komponenten wird das Gegendruck-Kokillengießverfahren (CPC-Verfahren) verwendet.As already mentioned, the aluminum casting alloy according to the invention has proven particularly suitable for components subject to heavy loads, such as shock absorber stilts, wheel carriers or pivot bearings. As a very preferred method for producing such more stressed components, the counter-pressure die casting method (CPC method) is used.

Erfindungsgemäße Gussbauteile, die aus einer Al-Gusslegierung nach einem der Ansprüche und/oder nach einem Verfahren gemäß einem der Ansprüche hergestellt sind, zeichnen sich nach einer Wärmebehandlung durch eine eine Dehngrenze RP0,2 von 300 bis 325 MPa, vorzugsweise von 305 bis 310 MPa, und/oder eine Bruchdehnung A5 von 4 bis 10 %, vorzugsweise von 7 bis 9 %, und/oder eine Zugfestigkeit Rm von 350-375 MPa, vorzugsweise von 350 -360 MPa, aus.Cast components according to the invention, which are produced from an Al casting alloy according to one of the claims and / or by a process according to one of the claims, are characterized by a heat treatment by a yield strength R P 0.2 of 300 to 325 MPa, preferably of 305 to 310 MPa, and / or an elongation at break A5 of 4 to 10%, preferably of 7 to 9%, and / or a tensile strength R m of 350-375 MPa, preferably 350-360 MPa.

Beispielexample

Zur Ermittlung der mechanischen Eigenschaften der Legierung AlSi3Mg0.5Cr0.15 wird ein so genannter "Französischer Zugstab" nach DIN 50125 aus einem mittels eines Gegendruck-Kokillengießverfahrens (CPC-Verfahren) hergestellten Schwenklager herausgetrennt, wobei das Schwenklager vorab eine Wärmebehandlung (Lösungsglühen 540°C für 8h, Abschrecken in Wasser, Warmauslagern 180°C für 6,5h) erhalten hat. Das Gießen von Vergleichsproben (AlSi3Mg0.5 und AlSi3Mg0.5Cr0.3) und die anschließende Wärmebehandlung erfolgt unter gleichen Bedingungen. Die zu vergleichenden Legierungen unterscheiden sich lediglich im Chrom-Gehalt. Der Probenstab wird an gleicher Stelle des Schwenklagers entnommen. Ermittelt werden die mechanischen Eigenschaften Zugfestigkeit Rm, Streckgrenze RP0,2 und Bruchdehnung A5 nach DIN10002. Rm [MPa] Rp 0,2 [MPa] A5 [%] AlSi3Mg0.5 327 263 9,3 AlSi3Mg0.5Cr0.15 356 305 8,2 AlSi3Mg0.5Cr0.3 358 308 6,9 To determine the mechanical properties of the AlSi3Mg0.5Cr0.15 alloy, a so-called "French tensile bar" according to DIN 50125 is separated out of a swivel bearing produced by a counter-pressure die casting process (CPC process), the swivel bearing undergoing a heat treatment in advance (solution annealing 540 ° C for 8 h, quenching in water, hot aging 180 ° C for 6,5 h). The casting of comparative samples (AlSi3Mg0.5 and AlSi3Mg0.5Cr0.3) and the subsequent heat treatment takes place under the same conditions. The alloys to be compared differ only in the chromium content. The sample rod is removed at the same point of the pivot bearing. The mechanical properties tensile strength R m , yield strength R P 0.2 and elongation at break A5 according to DIN10002 are determined. R m [MPa] R p 0.2 [MPa] A5 [%] AlSi3Mg0.5 327 263 9.3 AlSi3Mg0.5Cr0.15 356 305 8.2 AlSi3Mg0.5Cr0.3 358 308 6.9

Vor dem Hintergrund der DE 10 2008 055 928 A1 und dem im Hinblick auf die mechanischen Kennwerte als kritisch angegebenen unteren Grenzwert für Chrom von 0,3 Gew.-% war das Erreichen der oben genannten mechanischen Kennwerte für AlSi3Mg0.5Cr0.15 nicht zu erwarten.Against the background of DE 10 2008 055 928 A1 and with regard to the mechanical values specified as critical lower limit value for chromium of 0.3 wt .-%, the achievement of the above mechanical characteristics for AlSi3Mg0.5Cr0.15 was not expected.

Es kann weiterhin vorteilhaft sein, wenn das Fahrwerksteil, vorzugsweise die Dämpferstelze oder der Radträger, durch Niederdruck-Sandguss oder vorzugsweise durch Gegendruck-Kokillenguss (CPC) hergestellt ist. Als besonders vorteilhaft hat sich die Verwendung der in der DE 10 2010 026 480 A1 offenbarten Gießvorrichtung bzw. des dort offenbarten Verfahrens herausgestellt. Der Offenbarungsgehalt der DE 10 2010 026 480 A1 bzw. deren Inhalt wird durch ausdrücklichen Verweis als zum Gegenstand der vorliegenden Anmeldung gehörig in die vorliegende Anmeldung aufgenommen bzw. integriert.It can also be advantageous if the chassis part, preferably the damper stilts or the wheel carrier, by low-pressure sand casting or preferably by counter-pressure chill casting (CPC) is made. Particularly advantageous is the use of in the DE 10 2010 026 480 A1 revealed casting device or the method disclosed therein exposed. The revelation content of the DE 10 2010 026 480 A1 or the content of which is incorporated or integrated into the present application by express reference as part of the present application.

Claims (25)

  1. An aluminium casting alloy which contains the following alloy components
    Si: 3.0 to 3.8 wt%
    Mg: 0.3 to 0.6 wt%
    Cr: 0.05 to <0.25 wt%
    Fe: < 0.18 wt%
    Mn: < 0.06 wt%
    Ti: < 0.16 wt%
    Cu: < 0.006 wt%
    Sr: 0.010 to 0.030
    Zr <0.006 wt%
    Zn <0.006 wt%
    impurities: < 0.1 wt%
    and is respectively supplemented with aluminium up to 100 wt%.
  2. The aluminium casting alloy according to Claim 1, characterised in that Si is contained at a content of more than 3.1 to less than 3.7 wt%.
  3. The aluminium casting alloy according to Claim 1 or 2, characterised in that Mg is contained at a content of 0.5 to 0.6 wt%.
  4. The aluminium casting alloy according to any one of claims 1 to 3, characterised in that Cr is contained at a content of 0.10 to less than 0.20 wt%.
  5. The aluminium casting alloy according to any one of claims 1 to 4, characterised in that Cr is contained at with a content of 0.12 to 0.17 wt%.
  6. The aluminium casting alloy according to any one of claims 1 to 5, characterised in that Fe is contained at a content of 0.01 to 0.15 wt%.
  7. The aluminium casting alloy according to any one of claims 1 to 6, characterised in that Mn is contained at a content of 0.01 to 0.05 wt%.
  8. The aluminium casting alloy according to any one of claims 1 to 7, characterised in that Ti is contained at a content of 0.05 to 0.15 wt%.
  9. The aluminium casting alloy according to any one of claims 1 to 8, characterised in that Cu is contained at a content of 0.001 to 0.005 wt%.
  10. The aluminium casting alloy according to any one of claims 1 to 9, characterised in that Sr is contained at a content of 0.015 to 0.025 wt%.
  11. The aluminium casting alloy according to any one of claims 1 to 10, characterised in that Zr is contained at a content of 0.001 to 0.005 wt%.
  12. The aluminium casting alloy according to any one of claims 1 to 11, characterised in that Zn is contained at a content of 0.001 to 0.005 wt%.
  13. The aluminium casting alloy according to any one of claims 1 to 12, characterised in that impurities are contained at a content of <0.05 wt%.
  14. The aluminium casting alloy according to any one of claims 1 to 13, characterised in that impurities are contained at a content of <0.005 wt%.
  15. Aluminium casting alloys according to any one of claims 1 to 14, characterised in that the aluminium casting alloy is a low-pressure aluminium casting alloy.
  16. Aluminium casting alloys according to any one of claims 1 to 14, characterised in that the aluminium casting alloy is a counter-pressure (CPC) aluminium casting alloy.
  17. A method of manufacturing a cast component from an aluminium casting alloy according to any one of Claims 1 to 14, in which the low-presssure casting method is used.
  18. The method of manufacturing a cast component from an aluminium casting alloy according to any one of Claims 1 to 14, in which the counter-pressure (CPC) casting method is used.
  19. The method of manufacturing a cast component from an aluminium casting alloy according to any one of Claims 1 to 14, in which squeeze casting, gravity die casting or pressure casting, in particular thixo, rheo or low-pressure sand casting, is used.
  20. The method, in particular according to any one of Claims 17 to 19, for manufacturing a cast component from an aluminium casting alloy according to any one of Claims 1 to 16, in which the cast component is subjected to a two-step heat treatment, namely solution annealing and subsequent artificial ageing, after the casting process.
  21. The method according to Claim 20, characterised in that the cast component is quenched in water between the two heat-treatment steps.
  22. The method according to any one of claims 17 to 21, in which, after the casting process, the cast component is solution-annealed between 530°C and 550°C for 6 to 10 h, preferably between 540°C and 550°C for 7 to 9 h, in particular for 8 to 9 h, very particularly preferably between more than 540°C and 550°C for 7 to 9 h, in particular for 8 to 9 h.
  23. The method according to any one of claims 17 to 22, in which, after the casting process, the cast component is tempered between 180°C and 210°C for 1 to 8 h, in particular 1 to 6.5 h, preferably between 180°C and 190°C for 1 to 6.5 h, in particular for 4 to 6.5 h, particularly preferably between 180°C and less than 190°C for 4 to 6.5 h, in particular for 5 to 6.5 h.
  24. Use of an aluminium cast alloy according to any one of the preceding claims or of a cast component made thereof, in particular a heat-treated cast component, for motor vehicle chassis parts, preferably for motor vehicle wheel-guiding components, very particularly preferably for shock-absorber legs, wheel mounts and in particular for pivot bearings of motor vehicles.
  25. A cast component manufactured from an aluminium casting alloy according to any one of the preceding claims or according to a method according to any one of the preceding claims, wherein, after a heat treatment, the cast component has a yield point Rp 0.2 of 300 to 325 MPa, preferably of 305 to 310 MPa, and/or an elongation at break A5 of 4 to 10%, preferably of 7 to 9%, and/or a tensile strength Rm of 350-375 MPa, preferably of 350-360 MPa.
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