EP1696063A1 - Non-tissé de nettoyage et procédé de fabrication - Google Patents

Non-tissé de nettoyage et procédé de fabrication Download PDF

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Publication number
EP1696063A1
EP1696063A1 EP05003866A EP05003866A EP1696063A1 EP 1696063 A1 EP1696063 A1 EP 1696063A1 EP 05003866 A EP05003866 A EP 05003866A EP 05003866 A EP05003866 A EP 05003866A EP 1696063 A1 EP1696063 A1 EP 1696063A1
Authority
EP
European Patent Office
Prior art keywords
fibres
sheet
split
layers
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05003866A
Other languages
German (de)
English (en)
Inventor
Dirk Schubert
Michael Hess
Peter Stoffel
Robert Groten
Nick Simpson
Eric Mariani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jacob Holm Management GmbH
Carl Freudenberg KG
Original Assignee
Jacob Holm Management GmbH
Carl Freudenberg KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jacob Holm Management GmbH, Carl Freudenberg KG filed Critical Jacob Holm Management GmbH
Priority to EP05003866A priority Critical patent/EP1696063A1/fr
Priority to EP20050024535 priority patent/EP1696064A1/fr
Priority to PCT/EP2006/000789 priority patent/WO2006089619A1/fr
Priority to US11/361,842 priority patent/US20060205310A1/en
Publication of EP1696063A1 publication Critical patent/EP1696063A1/fr
Priority to US12/169,544 priority patent/US20090176063A1/en
Withdrawn legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • D04H5/03—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling by fluid jet
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/4334—Polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/435—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43838—Ultrafine fibres, e.g. microfibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005—Synthetic yarns or filaments
    • D04H3/007—Addition polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005—Synthetic yarns or filaments
    • D04H3/009—Condensation or reaction polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005—Synthetic yarns or filaments
    • D04H3/009—Condensation or reaction polymers
    • D04H3/011—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/11—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling

Definitions

  • This application relates to spunlaced fabrics and to multilayered sheets and to a process for their production, wherein the sheet is intended for use as a liquid impregnated wipe, preferably for personal care.
  • Non-wovens made from fibres with very fine denier are known.
  • One method for preparing such non-woven products comprises spinning of multicomponent fibres of incompatible polymers, formation of the non-woven in a manner known per se and subsequently splitting the multicomponent fibres into their single components by the action of hydroentanglement.
  • Those non-wovens are disclosed for example in US-A-5,970,583 and US-A-6,465,095.
  • EP-A-864,006 discloses a non-woven made from micro fibres of very fine denier. These are produced from very fine splittable fibres which are made by melt blowing of at least one hydrophilic or hydrophilically treated polymer. Also disclosed is production of laminated products by combination of these non-wovens with other layers. These products are proposed as single use products (disposal).
  • non-wovens made from split fibres and their combinations with other non-wovens or films are disclosed in WO-A-96/41,041 and WO-A-97/21,862,
  • the split fibre non-wovens are characterised by the presence of two different fibre types from incompatible polymers, one thereof being hydrophilic.
  • the non-wovens can be used in different fields, for example in diapers or in protective clothing.
  • Multilayered textile sheet made from microfibres different from split fibres are also known. Some of these combinations are excellent cleansing wipes.
  • EP-A-569,860 discloses a mufti-layered non-woven which is a combination of spunbond layers with a layer of meltblown microfibres inbetween.
  • the spunbond layers are made of thermobonded thermoplastic filaments and contain a nucleating agent.
  • the laminates are characterised by an improved strength and are used as fabrics for working cloth or as components for diapers.
  • EP-A-423,619 discloses cleansing wipes with good cleansing properties and excellent retention for aqueous liquids.
  • the wipes comprise a reinforcement layer, typically a spunbond, which contains synthetic and natural staple fibres. At the surface of these wipes the staple fibre combinations form sections with different area densities.
  • EP-A-357,496 discloses a cleansing wipe made of a non-woven. This consists of a combination of polymer microfibres and wood pulp or cellulosic fibres and is impregnated with a surface active agent. The wipe possesses an absorption capacity of 5-15 g liquid per g substrate.
  • EP-A-80,383 Another cleansing wipe with high liquid absorption capacity is disclosed in EP-A-80,383. This product easily releases stored liquid and is a non-woven comprising thermobonded meltblown fibres. 1-40% of the product surface are openings.
  • DE 199 17 275 B4 discloses a non-woven cleansing wipe made from micro staple-fibres derived from multicomponent split-fibres from at least two different polymers and from absorbent secondary staple fibres made from the viscose spinning process or the lyocell spinning process. Besides a high abrasion resistance and high absorption volume for abrased dirt the cleansing wipe has a good cleansing activity and a good textile feel.
  • DE 199 03 903 A1 discloses a three-layered wipe for cosmetic applications.
  • the wipe consists of a central layer and two cover layers which consist of split fibres with a fibre diameter of less than 10 ⁇ m.
  • the wipe has a high effectiveness and a small volume can be washed and reused and can be used without pilling.
  • cover layers combinations of polyester and polyamide are disclosed.
  • the central layer can also consist of these fibre combinations, optionally with added viscose fibres or can consist of viscose fibres only.
  • the wipes are designed for dry application.
  • Liquid impregnated wipes for personal care must meet a combination of properties which are difficult to obtain.
  • such wipes should retain the liquid as long and as homogeneous as possible during storage without any leakage/sedimentation from lotion into the storage box.
  • the wipe should transfer a sufficient amount of liquid to the skin of the user.
  • the materials from which the wipes are made should be inexpensive and/or the manufacturing process of said wipes should be simple to minimize manufacturing costs.
  • the amount of lotion necessary for an intended use should be as small as possible.
  • losses during storage or retention of lotion during use should be also as small as possible.
  • Personal cleansing wipes are made using a range of nonwoven technologies.
  • synthetic fibres such as polyester or polypropylene are combined with cellulose fibres such as viscose, lyocell, cotton or wood pulp.
  • cellulose fibres such as viscose, lyocell, cotton or wood pulp.
  • the synthetic fibre provides bulk and low cost and the cellulose fibre provides absorbency.
  • the use of cellulose imposes limitations on softness, strength, bulk and cost.
  • this invention relates to a multilayered sheet impregnated with a liquid comprising a first non-woven layer consisting essentially of thermoplastic polymer fibres of titre of 0.5 to 10 dtex and at least one second non-woven split-fibre layer of thermoplastic polymers.
  • this invention relates to a multilayered sheet impregnated with a liquid comprising at least five layers, one of said layers being a first non-woven central layer consisting essentially of thermoplastic polymer fibres of titre of 0.5 to 10 dtex, two of said layers consist essentially of meltblown fibres of thermoplastic polymers which layers are located at both sides of the first central non-woven layer and which meltblown layers are covered by non-woven layers consisting essentially of thermoplastic polymer fibres of titre of 0.5 to 10 dtex.
  • this invention relates to a one-layered sheet impregnated with a liquid which is a spunlaced fabric produced from a fibre web consisting essentially of 20 to 97 % by weight of thermoplastic polymer fibres of titre 0.5 to 10 dtex and of 3 to 80 % by weight of split-fibres of thermoplastic polymers and of 0 to 50 % by weight of meltblown fibres of thermoplastic polymers.
  • spfit-fibres and/or meltblown fibres in the sheets of this invention provides a combination of valuable properties of the sheet. Adding split-fibres and/or meltblown fibres to fibres with conventional fineness either in form of separate layers and/or as fibre mixtures in single layers results in increased softness, lintfreeness, opacity, storage and release capability for lotion.
  • the impregnated sheets of this invention can consist of one layer only or are preferably multilayer sheets.
  • first non-woven layer consisting essentially of thermoplastic polymer fibres of titre of 0.5 to 10 dteX' shall mean that said fibres form a major part of the fibres of this layer, for example said fibres are present in an amount of at least 50 % by weight, preferably 80 -100 % by weight of said layer.
  • microdenier fibres and/or additives typically used in such non-woven layers may be present. Examples thereof are pigments, such as titanium dioxide, optical brighteners, hydrophilic agents, flameproofing agents, antistatic agents, biocidal agents or a combination of two or more thereof.
  • second non-woven split-fibre layer of thermoplastic polymers shall mean that said split-fibres form a considerable amount of the fibres of this layer, for example said fibres are present in an amount of at least 20 % by weight, preferably 70 -100 % by weight of said layer.
  • regular denier fibres for example, regular denier fibres (fibres with titre between 0.5 and 10 dtex) and/or additives typically used in such non-woven layers may be present. Examples thereof are pigments, such as titanium dioxide, optical brighteners, hydrophilic agents, flameproofing agents, antistatic agents, biocidal agents or a combination of two or more thereof.
  • thermoplastic polymer shall mean all thermoplastic and fibre-forming man-made polymers including thermoplastic elastomers.
  • Very preferred sheets comprise three layers including a central non-woven layer of thermoplastic fibres with denier between 0.5 and 10 dtex or of a mixture of at least 80 % by weight of thermoplastic fibres with denier between 0.5 and 10 dtex and of up to 20 % by weight of split-fibres of thermoplastic polymers and at the surfaces two non-woven split-fibre layers of 100 % by weight of split-fibres of thermoplastic polymers or of a mixture of at least 70 % by weight of split-fibres of thermoplastic fibres and of up to 30 % by weight of fibres of thermoplastic polymers with titre between 0.5 and 10 dtex.
  • a very preferred product of this multilayered sheet consists of three layers, wherein a first non-woven layer is a central non-woven layer which is sandwiched between two non-woven split-fibre layers.
  • Another very preferred product of this invention is a three-layered sheet, wherein a first non-woven layer is combined with a layer consisting of meltblown fibres of_thermoplastic polymer and the surface of the meltblown layer opposite to the first_nvn-woven layer is covered with a non-woven split-fibre layer.
  • thermoplastic polymers consist of five layers, wherein two layers consist essentially of meltblown fibres of thermoplastic polymers. These layers are arranged at both surfaces of a central non-woven layer made of fibres of thermoplastic polymers with titre between 0.5 and 10 dtex. The surfaces of the meltblown layers are covered by non-woven split-fibre layers of thermoplastic polymers.
  • thermoplastic polymers consist of four layers, wherein one layer consists essentially of meltblown fibres of thermoplastic polymers. This layer is arranged at one surface of a central non-woven layer made of fibres of thermoplastic polymers with titre between 0.5 and 10 dtex. The other surface of the meltblown layer and of the central non-woven layer are covered by non-woven split-fibre layers of thermoplastic polymers.
  • the first non-woven layer contains continuous filaments and/or staple fibres of thermoplastic polymers. These fibres possess regular titre between 0.5 and 10 dtex, preferably between 1 and 5 dtex. Typical fibre diameters are above 10 ⁇ m.
  • the first non-woven layer may comprise fibres made from thermoplastic elastomers.
  • the first non-woven layer is made from staple fibres.
  • Preferred titres of fibres forming the first non-woven layer are between 1 and 5 dtex
  • the first non-woven layer consists essentially of fibres made from thermoplastic polymers. All fibre-forming thermoplastic polymers can be used, for example polyesters, such as polyethylenterephthalate, polyamides, such as Nylon 6 or Nylon 6.6, or polyolefins, such as polypropylene. Besides homopolymers copolymers can be used, for example propytene-ethytene-copotymers. Polypropylene-Homo- or -Copolymers are preferred as a fibre forming material for the first non-woven layer.
  • the first non-woven layer typically has a base weight of 5 - 50 g/m 2 , preferably of 10 - 30 g/m 2 .
  • split-fibre layer(s) contain continuous split-fibres and/or staple split-fibres of thermoplastic polymers. These split-fibres may be prepared by the conventional split-fibre process and the single fibres after splitting typically possess a fineness below 1.0 dtex and/or fibre diameters below 10 ⁇ m, preferably a fineness below 0.5 dtex
  • split-fibre layers are made from staple fibres or from continuous filaments.
  • the split-fibre layer(s) may comprise fibres made from thermoplastic elastomers.
  • the split-fibre layer(s) consist also essentially of fibres made from thermoplastic polymers.
  • thermoplastic polymers for the split-fibre process all combinations of splittable fibre-forming thermoplastic polymers can be used, for example combinations of polyester / potyamide(s), such as combinations of polyethylenterephthalate / Nylon 6 and/or Nylon 6.6, or combinations of polyolefins / polyamide(s), such as combinations of polypropylene / Nylon 6 and/or Nylon 6.6 or combinations of polyolefins, such as combinations of polyethylene and polypropylene.
  • the single split-fibre non-woven layer typically has a base weight of 5 -100 g/m 2 , preferably of 10 - 30 g/m 2 .
  • the product of this invention may contain additional layers of microdenier fibres made by other processes, such as meltblown fibres of thermoplastic polymers.
  • the product of this invention may not contain split fibre layers but layers of microdenier fibres made by other processes, such as meltblown fibres of thermoplastic polymers.
  • Single layers of meltblown fibres of thermoplastic polymers typically have an area weight of 5 -100 g/m 2 , preferably of 10 - 60 g/m 2 .
  • thermoplastic polymers consisting essentially of combinations of at least two splittable thermoplastic polymers, preferably of combinations of polyester/ polyamide, polyester / polyolefin or combinations of polyolefins, preferably polyethylene / polypropylene, polypropylene / modified polypropylene or polypropylene / modified polyethylene.
  • thermoplastic polymers consisting essentially of combinations of thermoplastic polymer fibres one of said thermoplastic polymers being hydrophilic and/or hydrophilic modified. Suitable fibre combinations are disclosed in WO-A-96/41,041 and WO-A-97/21,862.
  • thermoplastic polymer fibres of titre of 0.5 to 10 dtex are continuous filaments or staple fibres of polyolefin, preferably of polypropylene
  • the split-fibres of thermoplastic polymers are continuous filaments or staple fibres of the combination polyester / polyamide or of the combination polyester / polypropylene or of the combination polyethylene / polypropylene.
  • the fibres used in the layer(s) of the products of this invention may possess circular or non-circular cross sections or combinations thereof.
  • the sheets of this invention are stabilized after combination of the single non-woven layers.
  • This stabilisation treatment is typically a mechanical treatment by the action of needles, of a calendering roll and/or preferably by hydroentanglement.
  • the sheets of this invention are embossed at least on one surface, for example by the action of a pair of calendering rolls with at least one thereof possessing a profiled surface.
  • this hydroentanglement conditions can be selected to produce an embossing action at the surface. This results in a surface pattem and in a partial solidification of selected parts of the sheet caused by melt adhesion of single fibres at the treated locations of the sheet.
  • At least one outer layer is coloured. This can direct the user to utilize a preferred surface with enhanced wiping properties.
  • the sheet of this invention typically has a base weight of 20 -100 g/m 2 , preferably of 30 - 60 g/m 2 .
  • the typical thickness of the sheet of this invention depends on the amount of layers present and of process parameters used in the preparation. Typically the thickness is between 0.05 and 2 mm, preferably between 0.1 and 1 mm.
  • a monolayered staple fibre sheet this is made of nonwoven fabric by a process, which involves forming a web by carding staple synthetic fibre with up to 80 % by weight of splittable fibre. Bonding is preferably achieved by hydroentanglement (spunlacing process) and base weight is preferably in the range 25 to 100 g/m 2 .
  • the preferred process comprises carding a majority of homofil synthetic staple fibres, such as polyester or polypropylene, with a decitex range of 0.5 to 10, with up to 80 % by weight of splittable fibres with a preferred decitex range of 1 to 4, to form a nonwoven web.
  • the web is preferably stabilized by hydroontanglement.
  • the splittable fibre has, for example, a pie like mufti-segment cross section made up of dissimilar polymers such as polyester and polyamide, situated alternately. The action of hydroentanglemerlt splits the fibre into individual microfibres of titre from 0.05 to 1 decitex.
  • the monolayered fabric so obtained is characterized by a very soft feel, good opacity, and high values for thickness, strength and absorbent capacity.
  • the liquid for impregnation of the sheet of this invention can be of different kinds.
  • a lotion comprising oil-in-water emulsion or water-in-oil emulsion is used.
  • the liquid is an aqueous lotion comprising surface active agents.
  • the amount of liquid in the impregnated sheet of this invention typically is between 200 and 2000 % by weight, preferably between 400 and 1500 % by weight, referring to the impregnated sheet.
  • the invention also relates to a process for the production of muhilayered and split-fibre layer containing sheets as defined above comprising the following steps:
  • the impregnated sheets of this invention can be used for personal care applications.
  • the invention also relates to the use of the above-defined sheets as personal cleansing wipes, preferably as baby wipes.
  • Weight (in g/m 2 ) is determined according to EDANA method 40.3-90.
  • Thickness (in mm) is determined according to EDANA method 30.4-89.
  • Tensile strength (in N/5mm) is determined according to EDANA method 20.2-89.
  • Elongation (in %) is determined according to EDANA method 20.2-89.
  • Absorbent capacity (in %) is determined according to EDANA method 10.1-72.
  • the Handle-O-Meter test referred to in the tables is a measure for the stiffness of the product according to INDA method 90.3 (01).
  • a staple fibre web having a basis weight of 47 g/m 2 was produced from 97% polyester and 3% polyester-polyamide splittable fibre and subjected to hydroentanglement at 47 bar. During the hydroentangtement process the splittable fibres were separated into individual components with a titer of 0.1 decitex Table 1. details the fabric test results in comparison with a commercial personal cleansing wipe.
  • a staple fibre web having a basis weight of 49 g/m 2 was produced from 90% polyester and 10% polyester-polyamide splittable fibre and subjected to hydroentanglement at 47 bar. Fabric test results are detailed in table 1.
  • a tri-layered sheet was produced from a spundbonded nonwoven consisting of polypropylene fibres of titre 1.95 dtex. This layer was sandwiched between two sprit-fibre nonwovens consisting of microfibres of polyethyleneterephthalate and of polypropylene. The tri-layered combination was subjected to hydroentanglement at 150 bar. During the hydroentanglement process the splittable fibres were separated into individual components with a titer of 0.12 dtex. Table 1 details the fabric test results in comparison with a commercial personal cleansing wipe.
  • Example 1 Example 2
  • Example 3 Commercial Sheet Weight (g/m 2 ) 47 49 48 61 Thickness (mm) 0.72 0.68 0.74 0.69
  • Tensile (N/5cm) machine direction 147 147 175 110
  • Cross direction 101 93 123 23 Absorption Capacity (%) 1230 1154 1179 893 Handle-O-Meter (g) 17 19 18 22

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
EP05003866A 2005-02-23 2005-02-23 Non-tissé de nettoyage et procédé de fabrication Withdrawn EP1696063A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP05003866A EP1696063A1 (fr) 2005-02-23 2005-02-23 Non-tissé de nettoyage et procédé de fabrication
EP20050024535 EP1696064A1 (fr) 2005-02-23 2005-11-10 Lingettes, procédé de fabrication et utilisation
PCT/EP2006/000789 WO2006089619A1 (fr) 2005-02-23 2006-01-31 Feuilles demaquillantes, procede de fabrication et utilisation
US11/361,842 US20060205310A1 (en) 2005-02-23 2006-02-23 Cleansing sheets, manufacturing process and use thereof
US12/169,544 US20090176063A1 (en) 2005-02-23 2008-07-08 Cleansing Sheets, Manufacturing Process And Use Thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05003866A EP1696063A1 (fr) 2005-02-23 2005-02-23 Non-tissé de nettoyage et procédé de fabrication

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EP1696063A1 true EP1696063A1 (fr) 2006-08-30

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009101144A1 (fr) * 2008-02-13 2009-08-20 Martin, Cecile Raphaela Lingette hydrophile pour la peau
IT201600107600A1 (it) * 2016-10-25 2018-04-25 Effetaglio S N C Di Ferrari Dario E C Panno tecnico e relativo metodo di utilizzo.
WO2019071170A1 (fr) * 2017-10-06 2019-04-11 Berry Global, Inc. Tissu de nettoyage
CN109868557A (zh) * 2019-03-13 2019-06-11 安徽双孚无纺布科技有限公司 一种高回弹高蓬松复合防滑基布及其制备方法

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EP0992338A2 (fr) * 1998-10-09 2000-04-12 Fort James Corporation Bandes à trois couches aiguilletées par voie hydraulique et produits obtenus à partir de celles-ci
US20020102289A1 (en) * 2000-11-30 2002-08-01 Anja Drucks Cosmetic or dermatological impregnated wipes
US6465095B1 (en) * 2000-09-25 2002-10-15 Fiber Innovation Technology, Inc. Splittable multicomponent fibers with partially overlapping segments and methods of making and using the same
EP1314808A2 (fr) * 1995-11-30 2003-05-28 Kimberly-Clark Worldwide, Inc. Multicouche à base de microfibres très fines
US20030118776A1 (en) * 2001-12-20 2003-06-26 Kimberly-Clark Worldwide, Inc. Entangled fabrics
US20040010895A1 (en) * 2002-07-18 2004-01-22 Kimberly-Clark Worldwide, Inc. Method of forming a nonwoven composite fabric and fabric produced thereof

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EP1314808A2 (fr) * 1995-11-30 2003-05-28 Kimberly-Clark Worldwide, Inc. Multicouche à base de microfibres très fines
EP0992338A2 (fr) * 1998-10-09 2000-04-12 Fort James Corporation Bandes à trois couches aiguilletées par voie hydraulique et produits obtenus à partir de celles-ci
US6465095B1 (en) * 2000-09-25 2002-10-15 Fiber Innovation Technology, Inc. Splittable multicomponent fibers with partially overlapping segments and methods of making and using the same
US20020102289A1 (en) * 2000-11-30 2002-08-01 Anja Drucks Cosmetic or dermatological impregnated wipes
US20030118776A1 (en) * 2001-12-20 2003-06-26 Kimberly-Clark Worldwide, Inc. Entangled fabrics
US20040010895A1 (en) * 2002-07-18 2004-01-22 Kimberly-Clark Worldwide, Inc. Method of forming a nonwoven composite fabric and fabric produced thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009101144A1 (fr) * 2008-02-13 2009-08-20 Martin, Cecile Raphaela Lingette hydrophile pour la peau
CN101945637B (zh) * 2008-02-13 2013-07-10 塞西尔·拉斐尔拉·马丁 吸水性护肤巾
IT201600107600A1 (it) * 2016-10-25 2018-04-25 Effetaglio S N C Di Ferrari Dario E C Panno tecnico e relativo metodo di utilizzo.
WO2019071170A1 (fr) * 2017-10-06 2019-04-11 Berry Global, Inc. Tissu de nettoyage
US11105027B2 (en) 2017-10-06 2021-08-31 Berry Global, Inc. Cleaning fabric
US20210348316A1 (en) * 2017-10-06 2021-11-11 Berry Global, Inc. Cleaning Fabric
CN109868557A (zh) * 2019-03-13 2019-06-11 安徽双孚无纺布科技有限公司 一种高回弹高蓬松复合防滑基布及其制备方法

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