EP1585635B1 - Glazing comprising a luminous element - Google Patents

Glazing comprising a luminous element Download PDF

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Publication number
EP1585635B1
EP1585635B1 EP04700702.6A EP04700702A EP1585635B1 EP 1585635 B1 EP1585635 B1 EP 1585635B1 EP 04700702 A EP04700702 A EP 04700702A EP 1585635 B1 EP1585635 B1 EP 1585635B1
Authority
EP
European Patent Office
Prior art keywords
glazing
leds
glazing unit
conductive layer
unit according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP04700702.6A
Other languages
German (de)
French (fr)
Other versions
EP1585635A2 (en
Inventor
Hugues GLAVERBEL - Centre R & D LEFEVRE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Glass Europe SA
Original Assignee
AGC Glass Europe SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by AGC Glass Europe SA filed Critical AGC Glass Europe SA
Priority to EP04700702.6A priority Critical patent/EP1585635B1/en
Publication of EP1585635A2 publication Critical patent/EP1585635A2/en
Application granted granted Critical
Publication of EP1585635B1 publication Critical patent/EP1585635B1/en
Anticipated expiration legal-status Critical
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10174Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10376Laminated safety glass or glazing containing metal wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10541Functional features of the laminated safety glass or glazing comprising a light source or a light guide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60QARRANGEMENT OF SIGNALLING OR LIGHTING DEVICES, THE MOUNTING OR SUPPORTING THEREOF OR CIRCUITS THEREFOR, FOR VEHICLES IN GENERAL
    • B60Q3/00Arrangement of lighting devices for vehicle interiors; Lighting devices specially adapted for vehicle interiors
    • B60Q3/20Arrangement of lighting devices for vehicle interiors; Lighting devices specially adapted for vehicle interiors for lighting specific fittings of passenger or driving compartments; mounted on specific fittings of passenger or driving compartments
    • B60Q3/208Sun roofs; Windows
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/12Supports; Mounting means
    • H01Q1/1271Supports; Mounting means for mounting on windscreens
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B45/00Circuit arrangements for operating light-emitting diodes [LED]
    • H05B45/40Details of LED load circuits
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2329/00Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
    • B32B2329/06PVB, i.e. polyinylbutyral
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2369/00Polycarbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/003Interior finishings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • C03C2217/23Mixtures
    • C03C2217/231In2O3/SnO2
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21YINDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
    • F21Y2109/00Light sources with light-generating elements disposed on transparent or translucent supports or substrates
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0306Inorganic insulating substrates, e.g. ceramic, glass
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0104Properties and characteristics in general
    • H05K2201/0108Transparent
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/10Details of components or other objects attached to or integrated in a printed circuit board
    • H05K2201/10007Types of components
    • H05K2201/10106Light emitting diode [LED]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension

Definitions

  • the present invention relates to glazings, in particular laminated glass, in which electronic components have been inserted.
  • the glazing surface is increasingly important in vehicles and buildings. In addition, this surface is particularly highlighted relative to the outside of the vehicle or building, with respect to its occupants, which allows to provide completely new functions for these windows.
  • automotive glazing means windshields, rear windows, side windows but also opening or non-opening roofs, mirrors, or headlight protection glass.
  • the invention consists in inserting electronic components, as well as their connection circuit, inside a laminated glass in order to confer to it new functionalities such as sensors, lights, indicator light, ....
  • optoelectronic components such as in particular light-emitting diodes (LEDs), photo resistors, photodiodes and vision sensors, for example of the CCD (Charge coupled device) and CMOS (Complementary Metal Oxide Semi) type conductor) are particularly useful because directly related to the optical aspect of the glazing.
  • CCD Charge coupled device
  • CMOS Complementary Metal Oxide Semi
  • other electronic components can also be inserted to make complete electronic circuits. Depending on the type of components and the electrical conductors used, these circuits may or may not be visible.
  • the invention relates to all types of electronic circuits inserted in laminated glasses, in particular the circuits for shaping and amplifying the signals coming from the electromagnetic antennas integrated in these same panes, as well as the control circuits of the lights and sensors above detailed.
  • a laminated glazing usually comprises two sheets of clear or colored glass between which are inserted one or more PVB (polyvinyl butyral) type thermoplastic sheets.
  • PVB sheets available on the market usually have a thickness of 0.38 mm or a thickness of a multiple of 0.38 mm. The higher the desired resistance of the laminate, the greater the total thickness of the PVB-type sheet (s).
  • the subject of the present invention is a laminated glazing unit comprising at least two glass sheets and one or more thermoplastic interleaves, of PVB type, in which electronic components as well as their connection circuit are inserted between the two sheets of glass, the circuit of connection being made of at least one conductive layer.
  • the electronic components may be optoelectronic components, such as light-emitting diodes (LEDs).
  • LEDs light-emitting diodes
  • the electronic components inserted in the glazing according to the invention have a thickness of less than or equal to 3 mm and in particular a thickness of between 0.1 and 1.2 mm.
  • the electrical connections between the components and the electricity source are made by means of conductive layers which may be transparent or not, and are deposited either on the inner surface of one or both glass sheets. either on the PVB film sandwiched between the two sheets of glass.
  • Typical conductive layers are for example doped oxide-based layers whose thickness is generally between 0.02 and 1 ⁇ , preferably between 0.02 and 0.5 ⁇ , more preferably between 0.2 and 0.4 ⁇ and whose surface area can vary between 5 and 80 ⁇ / square, preferably between 10 and 80 ⁇ / square, more preferably between 12 and 20 ⁇ / square.
  • Such layers include, for example, indium or aluminum doped zinc oxide, fluorine doped tin oxide, or tin doped indium oxide (generally known as abbreviation ITO).
  • conductive layers are silver-based layers. These conductive layers may be composed of one, two or even three layers of silver (or any other conductive material), separated by layers of dielectric. For layers comprising a total thickness of conductive material between 10 and 30 nm, the surface resistance can reach very low values of between 2 and 3 ⁇ / square.
  • any other layer even more weakly conductive could be suitable for making the electrical connections between the electronic components.
  • the voltage to be applied will however have to be increased if the resistance of the layer is greater.
  • the conductive layer deposited on the glass is advantageously divided into two distinct zones, constituting two conductive tracks, each of the two zones being connected to an electrode.
  • the electronic components can then be arranged in parallel, one of their terminal being in connection with the first zone and the other terminal of each component being in connection with the second zone of the conductive layer.
  • the conductive layer can also be divided into many areas, each zone connecting an electronic component to the next, the components can thus connected in series. Mixed, serial and parallel arrangements may also be provided.
  • conductive tracks supplying the LEDs by depositing a conductive layer with anti-solar and / or thermally insulating properties over the majority of the glazing and then eliminating or modifying the conductive layer. on thin strips, for example by laser.
  • a conductive layer with anti-solar and / or thermally insulating properties over the majority of the glazing and then eliminating or modifying the conductive layer. on thin strips, for example by laser.
  • one or the other of the known techniques can be used, for example vacuum cathode sputtering or pyrolytic vapor deposition.
  • the thin strips without a layer have a width of between 0.01 and 3 mm, preferably between 0.05 and 1.5 mm, and even more preferably between 0.1 and 0.8 mm. In this way, almost invisible electrical connections can be obtained even if the conductive layer has a slight coloration.
  • LEDs generally consist of a semiconductor chip, electrical connection elements and an envelope whose functions are multiple (protection of oxidation and moisture, heat dissipation, mechanical support).
  • This envelope may have dimensions small enough to be inserted in a laminated glazing. Given the low light output provided by the current LEDs, it would be necessary to have a large number to obtain a satisfactory automotive interior lighting, and make a large number of electrical connections, which would make the manufacturing process expensive.
  • several chips are arranged in a common envelope whose dimensions are such that its width and / or length are at least 10 times greater than its thickness, preferably 20 times greater, and more preferably 40 times larger.
  • This envelope is preferably made of a transparent material or aesthetically compatible with the glazing used. It is also preferably made of a sufficiently flexible material to allow it to match the curvatures of the glazing. It may advantageously comprise a diffusing surface that smooths the light emitted by the various chips.
  • the envelope comprises from 5 to 100 chips, preferably from 10 to 50 chips, and more preferably from 15 to 40 chips.
  • This envelope makes it possible to produce illumination providing from 10 to 500 lumens, preferably from 20 to 250 lumens and more preferably from 30 to 100 lumens, in an economical manner, that is to say without having to proceed with the gluing of a large number of LEDs and without having to make a large number of electrical connections.
  • the envelope has a length and / or a width of between 5 and 100 mm, preferably between 10 and 75 mm and more preferably between 20 and 50 mm.
  • the thickness of the envelope is preferably less than or equal to 3 mm, preferably less than 2 mm, less than 1.2 mm, less than 1 mm and even more preferably between 0.1 and 0.7 mm.
  • Such an envelope makes it possible to make only 2 electrical contacts glass / envelope if the brightness provided by the set of chips reaches about 50 lumens.
  • the glazing comprises a capacitive type switch, actuating the power supply of the light element.
  • This switch consists of a zone of the conductive layer, isolated from the rest of the conductive layer, and functioning as the probe of a capacitive circuit.
  • the glazing is a laminated glazing which comprises two sheets of glass contiguous with one or more thermoplastic interleaves (generally polyvinyl butyral type (PVB)), the LEDs and their connecting circuit being inserted between the two sheets of glass.
  • thermoplastic interleaves generally polyvinyl butyral type (PVB)
  • the layers may be deposited either on the inner surface of one or the other glass sheet, or on the PVB film interposed between the two glass sheets.
  • LEDs and in particular their envelope or "package” will have to withstand the temperature and pressure conditions of the autoclaving step necessary for the manufacture of laminates (of the order of 10 to 15 bar and 80 to 150 ° C for 1 to 4 hours).
  • the envelope When it is inserted into a laminate, the envelope need not necessarily meet the moisture and oxidation protection requirements that are generally required for conventional LED envelopes and for use on a single lens.
  • the skilled person can provide any type of arrangement of the electrical connections to connect the LEDs or chips inside the envelope, either in series, in parallel or provide a mixed arrangement that has the advantage of providing a homogeneous brightness.
  • the whole is autoclaved during a 120 min cycle which comprises at least 35 min at high temperature and pressure (125 ° C and 8 bar).
  • the LEDs are arranged in parallel.
  • This embodiment has the advantage of providing a totally invisible connection circuit even by using two sheets of clear glass.
  • the Fig. 1 represents a laminated glazing made as follows.
  • a conductive layer 6 (conductivity of about 2 ⁇ / square) was deposited on a sheet 2 of clear soda-lime glass 2.1 mm thick, intended to be the outer glass sheet of the glazing.
  • the conductive layer 6 is laser removed on thin strips 4 about 0.15 mm wide, so as to delimit conductive tracks 6a, 6b.
  • LEDs 8 whose outer dimensions do not exceed 0.6 mm in thickness are glued on either side of a thin strip 4 with a conductive adhesive.
  • Typical conductive adhesives are, for example, silver adhesives.
  • the glass sheet 2 is then rolled, facing inwards, with a second sheet of clear soda-lime glass in the traditional manner, by interposing a double thermoplastic sheet 12 of 0.72 mm total thickness.
  • the glue must be chosen for its resistance to the high temperatures and pressure required to produce the laminated glazing. It must also be chosen according to its viscosity so as to prevent it from spreading in the insulating strip 4 during laminating of the laminate.
  • the luminous flux emitted by the LED is indicated by the arrow. It is oriented towards the inner glass sheet 10 of the glazing.
  • the Fig. 2 represents a laminated glazing, similar to that of Example 1, except that the outer glass sheet is a colored glass sheet 14. This type of laminated glass is particularly suitable for making a car roof. Her The light transmission (TL) can thus be reduced to 14% and its energy transmission (TE) to 11%.
  • the Fig. 3 represents a laminated glazing unit comprising an outer glass sheet 2 made of clear soda-lime glass.
  • An opaque decorative layer 16 is deposited on a portion of the inner surface of the glass sheet 2.
  • the conductive layer 6 is, in this case, deposited on the inner glass sheet 10, on its face turned towards the inside of the laminated glazing .
  • Conductive tracks 6a, 6b are made, as in the previous examples, by the elimination of the layer on thin strips 4.
  • LEDs 18, of the "reverse" type, that is to say intended to be glued by their light emitting side, are glued on both sides of the strips 4, on the inner glass sheet 10 of the glazing.
  • This embodiment makes it possible to make the light device invisible on the outside of the glazing since the LEDs 18 are located behind the opaque layer 16 of the glazing.
  • the Fig. 4 represents the same embodiment as at the Fig. 2 .
  • the LEDs 8 are represented with a semiconductor chip 20 each encapsulated in an envelope 22. Separate conductive tracks 6a, ... 6d are necessary to connect each LED 8.
  • the Fig. 7 represents an overall view of a windshield 34 comprising a light element constituted, in the case illustrated schematically, of twelve LEDs 8.
  • the Fig. 7 also shows a conductive zone 40 delimited by insulating strips 4. This functions as a capacitive key and enables the lighting element to be switched on and off.
  • the glazing shown in Fig. 5 comprises as in Example 1: an outer glass sheet 2 coated with a conductive layer 6, a thermoplastic interlayer 12, and an inner glass sheet 10.
  • the luminous element is made by the use of a particularly LED adapted for this purpose and which comprises a plurality of semiconductor chips 20 in a single envelope 24.
  • This embodiment requires to achieve fewer conductive tracks, see only 2 conductive tracks 6a, 6b if the light intensity provided by the chips semiconductors 20 encapsulated in a single envelope 24 is sufficient for the desired application.
  • This embodiment also makes it possible to produce strips 4, between the conducting tracks 6a, 6b, which are wider and avoids the risk of creep of the adhesive in the insulating strips.
  • the glazing shown in Fig. 6 comprises as in Examples 1 and 4: an outer glass sheet 2 coated with a conductive layer 6, a thermoplastic interlayer 12, and an inner glass sheet 10.
  • the light element is produced by the use of a flexible film 26, for example PET, on which are glued a set of LEDs 8 constituted by their envelope 22 each encapsulating one or possibly more semiconductor chips 20.
  • An electrical connection 28 is provided on the film 26, between each envelope 22 and between the last envelope and the conductive layer (not shown).
  • this embodiment makes it possible to make few conductive tracks 6a, 6b and to make relatively wide strips 4, which avoids the creep of the adhesive in the strip 4.
  • the glazing is made by adhesive bonding. once a set of LEDs 8 pre-arranged on the film 26.
  • LEDs have the advantage of consuming very little energy and dissipating virtually no heat. Thanks to their small size, when the device is off, the LEDs are practically not visible. It is therefore conceivable to have the electronic components, not only around the glazing but also on the central part or on a large part of the glass surface without hindering visibility if the connection circuit is achieved through conductive layers.
  • LEDs are usually monochromatic and are available in all shades.
  • the luminous intensity of an LED generally varies between 10 and 180 mCd. By inserting a large number of LEDs, a luminous intensity equivalent to that of incandescent lighting can be obtained, while requiring a much lower consumption.
  • the invention is not limited to this type of embodiment or to this type of function, all other standard electronic components of the market, for example those designed for electronic cards can be inserted, according to the invention between two sheets of paper. glass, provided that their miniaturization is sufficient.
  • SMD Surface Mount Device

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  • Arrangements Of Lighting Devices For Vehicle Interiors, Mounting And Supporting Thereof, Circuits Therefore (AREA)
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Description

La présente invention concerne des vitrages, en particulier en verre feuilleté, dans lesquels des composants électroniques ont été insérés.The present invention relates to glazings, in particular laminated glass, in which electronic components have been inserted.

La surface de vitrage est de plus en plus importante dans les véhicules et les bâtiments. De plus, cette surface est particulièrement mise en évidence par rapport à l'extérieur du véhicule ou du bâtiment, au regard de ses occupants, ce qui permet de prévoir des fonctions totalement nouvelles pour ces vitrages. Par vitrage automobile, on entend les pare-brise, lunettes arrières, vitres latérales mais aussi les toits ouvrants ou non ouvrants, les rétroviseurs, ou verre de protection des phares.The glazing surface is increasingly important in vehicles and buildings. In addition, this surface is particularly highlighted relative to the outside of the vehicle or building, with respect to its occupants, which allows to provide completely new functions for these windows. By automotive glazing means windshields, rear windows, side windows but also opening or non-opening roofs, mirrors, or headlight protection glass.

L'invention consiste à insérer des composants électroniques, ainsi que leur circuit de connexion, à l'intérieur d'un verre feuilleté afin de conférer à celui-ci des fonctionnalités nouvelles telles que capteurs, éclairages, voyant de signalisation, ....The invention consists in inserting electronic components, as well as their connection circuit, inside a laminated glass in order to confer to it new functionalities such as sensors, lights, indicator light, ....

Parmi les composants électroniques intéressants à insérer, les composants optoélectroniques tels que notamment les diodes électroluminescentes (LED), les photo résistances, les photodiodes et les capteurs de vision, par exemple du type CCD (Charge coupled device) et CMOS (Complementary Metal Oxide Semi conductor) sont particulièrement utiles car directement en rapport avec l'aspect optique du vitrage. Cependant, d'autres composants électroniques peuvent aussi être insérés afin de réaliser des circuits électroniques complets. Suivant le type de composants et les conducteurs électriques utilisés, ces circuits peuvent être visibles ou non.Among the interesting electronic components to be inserted, optoelectronic components such as in particular light-emitting diodes (LEDs), photo resistors, photodiodes and vision sensors, for example of the CCD (Charge coupled device) and CMOS (Complementary Metal Oxide Semi) type conductor) are particularly useful because directly related to the optical aspect of the glazing. However, other electronic components can also be inserted to make complete electronic circuits. Depending on the type of components and the electrical conductors used, these circuits may or may not be visible.

L'insertion de diodes électroluminescentes (LED) dans les vitrages automobiles permet, notamment, les fonctionnalités de signalisation suivantes :

  • affichage de témoins lumineux de signalisation destinés au chauffeur du véhicule ou aux passagers (exemple : témoin d'alarme de température du moteur dans le pare-brise, témoin de mise en fonctionnement du système de dégivrage électrique des vitres).
  • affichage de témoins lumineux de signalisation destinés aux personnes à l'extérieur du véhicule (exemple : témoin de mise en fonctionnement de l'alarme du véhicule dans les vitres latérales).
  • affichage lumineux sur les vitrages des véhicules (exemple : affichage lumineux clignotant sur les véhicules de secours, affichage de sécurité avec faible consommation électrique signalant la présence d'un véhicule en danger)
The insertion of light-emitting diodes (LEDs) in automotive glazing allows, in particular, the following signaling functionalities:
  • display of indicator lights for the driver of the vehicle or the passengers (example: engine temperature warning lamp in the windshield, start-up indicator of the electric window defrosting system).
  • display of warning lights for persons outside the vehicle (example: warning lamp for activating the vehicle alarm in the side windows).
  • illuminated display on the windows of vehicles (example: flashing light on emergency vehicles, safety display with low power consumption indicating the presence of a vehicle in danger)

L'insertion de diodes électroluminescentes (LED) dans les vitrages automobiles permet, notamment, les fonctionnalités d'éclairage suivantes :

  • éclairage d'ambiance de l'intérieur du véhicule de façon particulièrement esthétique (exemple : intégration de l'éclairage d'ambiance dans le toit en verre d'un véhicule).
  • feux lumineux et phare dans la surface du vitrage (exemple : intégration dans la lunette arrière du véhicule du 3ème feu « stop »).
The insertion of light-emitting diodes (LEDs) in automotive glazing allows, in particular, the following lighting features:
  • ambient lighting of the vehicle interior in a particularly aesthetic manner (example: integration of the ambient lighting in the glass roof of a vehicle).
  • lights and headlight in the glazing surface (example: integration into the rear window of the vehicle of the 3 rd "stop" light).

L'insertion de diodes électroluminescentes infrarouge (LED) dans les vitrages automobiles permet également des fonctionnalités de communication et d'éclairage, notamment :

  • émetteur infrarouge pour communication (exemple : télécommande de porte de garage, émetteur pour télépéage) ;
  • éclairage de type infrarouge de la route (exemple : source lumineuse dans le pare-brise pour capteur d'aide à la conduite de nuit) ;
  • détecteur de pluie ou de brouillard (exemple : capteur de pluie et/ou de brouillard inséré dans le vitrage du véhicule et destiné au contrôle automatique des essuies glaces et des phares anti-brouillard).
The insertion of infrared light emitting diodes (LEDs) in automotive glazing also allows for communication and lighting features, including:
  • infrared transmitter for communication (example: garage door remote control, electronic toll transmitter);
  • infrared-type lighting of the road (example: light source in the windshield for night-time driving sensor);
  • rain or fog detector (example: rain and / or fog sensor inserted in the vehicle glazing and intended for the automatic control of windscreen wipers and fog lamps).

De plus, l'insertion de photo-diodes et de photo-résistances dans les vitrages automobiles permet, notamment, les fonctionnalités de détection suivantes :

  • mesure de la luminosité ambiante (exemple : capteur de lumière pour allumage automatique des phares ou pour ajustement de la luminosité de l'éclairage interne du véhicule) ;
  • détecteur pour communication infrarouge (exemple : récepteur pour télépéage routier) ;
  • capteurs de température.
In addition, the insertion of photo-diodes and photoresistors in the automotive glazings allows, in particular, the following detection functionalities:
  • measuring the ambient light (example: light sensor for automatic lighting of the headlights or for adjusting the brightness of the internal lighting of the vehicle);
  • detector for infrared communication (example: receiver for electronic road toll);
  • temperature sensors.

L'insertion de capteur de vision de type CCD ou CMOS actifs dans le visible ou l'infrarouge dans les vitrages automobiles permettent les fonctionnalités de détection et d'aide à la conduite, notamment :

  • aide à la conduite (exemple : caméra CCD ou CMOS intégrée dans la vitre arrière du véhicule),
  • aide à la conduite de nuit (exemple : caméra infrarouge dans le pare brise avec éclairage infrarouge associé).
The insertion of CCD or CMOS-type vision sensors in the visible or the infrared in automotive glazing allows detection and driver assistance features, including:
  • driving assistance (example: CCD or CMOS camera integrated into the rear window of the vehicle),
  • night driving assistance (example: infrared camera in the windscreen with associated infrared lighting).

De façon générale, l'invention concerne tous types de circuits électroniques insérés dans les verres feuilletés, notamment les circuits de mise en forme et d'amplification des signaux issus des antennes électromagnétiques intégrées dans ces mêmes vitrages ainsi que les circuits de contrôle des éclairages et des capteurs ci-dessus détaillés.In general, the invention relates to all types of electronic circuits inserted in laminated glasses, in particular the circuits for shaping and amplifying the signals coming from the electromagnetic antennas integrated in these same panes, as well as the control circuits of the lights and sensors above detailed.

Un vitrage feuilleté comporte habituellement deux feuilles de verre clair ou coloré entre lesquelles sont insérées une ou plusieurs feuilles thermoplastiques de type PVB (polyvinylbutyral). Les feuilles de PVB disponibles sur le marché ont habituellement une épaisseur de 0.38 mm ou une épaisseur d'un multiple de 0.38 mm. Plus la résistance souhaitée du feuilleté est élevée, plus l'épaisseur totale de la (ou des) feuille(s) de type PVB doit être importante.A laminated glazing usually comprises two sheets of clear or colored glass between which are inserted one or more PVB (polyvinyl butyral) type thermoplastic sheets. PVB sheets available on the market usually have a thickness of 0.38 mm or a thickness of a multiple of 0.38 mm. The higher the desired resistance of the laminate, the greater the total thickness of the PVB-type sheet (s).

Il a été découvert qu'il est possible d'insérer tout type de composants électroniques entre deux feuilles de verre, malgré leur épaisseur non négligeable. Il existe par exemple des LED dont l'épaisseur est de 0.6 ou 0.8 mm. Dans ce cas, l'utilisation de 2 ou 3 feuilles de PVB permet l'insertion de ce type de composant électronique entre deux feuilles de verre. Il a été découvert que le traitement thermique sous pression élevée, nécessaire pour réaliser un vitrage feuilleté, n'entrave pas le bon fonctionnement des composants électroniques, ni de leurs connexions électriques.It has been discovered that it is possible to insert any type of electronic components between two sheets of glass, despite their significant thickness. There are for example LEDs whose thickness is 0.6 or 0.8 mm. In this case, the use of 2 or 3 sheets of PVB allows the insertion of this type of electronic component between two sheets of glass. It has been discovered that the high pressure heat treatment required to produce laminated glazing does not interfere with the proper functioning of the electronic components or their electrical connections.

La présente invention a pour objet un vitrage feuilleté comportant au moins deux feuilles de verre et un ou plusieurs intercalaires thermoplastiques, de type PVB, dans lequel des composants électroniques ainsi que leur circuit de connexion sont insérés entre les deux feuilles de verre, le circuit de connexion étant réalisé au moins d'une couche conductrice.The subject of the present invention is a laminated glazing unit comprising at least two glass sheets and one or more thermoplastic interleaves, of PVB type, in which electronic components as well as their connection circuit are inserted between the two sheets of glass, the circuit of connection being made of at least one conductive layer.

Suivant les applications recherchées, on utilisera au choix, des feuilles de verre clair, coloré, maté, sablé, sérigraphié ou tout autre type de feuille de verre approprié.Depending on the desired applications, it will be possible to use sheets of clear, colored, matt, sandblasted, screen-printed glass or any other type of suitable glass sheet.

En particulier, les composants électroniques peuvent être des composants optoélectroniques, tels que des diodes électroluminescentes (LED).In particular, the electronic components may be optoelectronic components, such as light-emitting diodes (LEDs).

De manière avantageuse, les composants électroniques insérés dans le vitrage selon l'invention ont une épaisseur inférieure ou égale à 3 mm et en particulier une épaisseur comprise entre 0.1 et 1.2 mm.Advantageously, the electronic components inserted in the glazing according to the invention have a thickness of less than or equal to 3 mm and in particular a thickness of between 0.1 and 1.2 mm.

Selon un mode préféré de réalisation, les connexions électriques entre les composants et la source d'électricité sont réalisées au moyen de couches conductrices qui peuvent être transparentes ou non, et sont déposées soit sur la surface intérieure d'une ou des deux feuilles de verre, soit sur le film de PVB intercalé entre les deux feuilles de verre.According to a preferred embodiment, the electrical connections between the components and the electricity source are made by means of conductive layers which may be transparent or not, and are deposited either on the inner surface of one or both glass sheets. either on the PVB film sandwiched between the two sheets of glass.

Les couches conductrices typiques sont par exemple des couches à base d'oxyde dopé dont l'épaisseur est généralement comprise entre 0.02 et 1 µ, de préférence entre 0.02 et 0.5 µ, de manière encore préférée entre 0.2 et 0.4 µ et dont la résistance de surface peut varier entre 5 et 80 Ω/carré, de manière préférée entre 10 et 80 Ω/carré, de manière encore préférée entre 12 et 20 Ω/carré. De telles couches comprennent par exemple de l'oxyde de zinc dopé à Indium ou à l'Aluminium, de l'oxyde d'étain dopé au fluor ou de l'oxyde d'indium dopé à l'étain (généralement connu sous l'abréviation ITO).Typical conductive layers are for example doped oxide-based layers whose thickness is generally between 0.02 and 1 μ, preferably between 0.02 and 0.5 μ , more preferably between 0.2 and 0.4 μ and whose surface area can vary between 5 and 80 Ω / square, preferably between 10 and 80 Ω / square, more preferably between 12 and 20 Ω / square. Such layers include, for example, indium or aluminum doped zinc oxide, fluorine doped tin oxide, or tin doped indium oxide (generally known as abbreviation ITO).

D'autres couches conductrices typiques sont des couches à base d'argent. Ces couches conductrices peuvent être composées d'une, deux, voire trois couches d'argent (ou tout autre matériau conducteur), séparées par des couches de diélectrique. Pour des couches comprenant une épaisseur totale de matériau conducteur comprise entre 10 et 30 nm, la résistance de surface peut atteindre des valeurs très faibles comprises entre 2 et 3 Ω/carré.Other typical conductive layers are silver-based layers. These conductive layers may be composed of one, two or even three layers of silver (or any other conductive material), separated by layers of dielectric. For layers comprising a total thickness of conductive material between 10 and 30 nm, the surface resistance can reach very low values of between 2 and 3 Ω / square.

Cependant, toute autre couche même plus faiblement conductrice pourrait convenir pour réaliser les connexions électriques entre les composants électroniques. La tension à appliquer devra cependant être augmentée si la résistance de la couche est plus importante.However, any other layer even more weakly conductive could be suitable for making the electrical connections between the electronic components. The voltage to be applied will however have to be increased if the resistance of the layer is greater.

Selon ce mode de réalisation, la couche conductrice déposée sur le verre est avantageusement divisée en deux zones distinctes, constituant deux pistes conductrices, chacune des deux zones étant reliée à une électrode. Les composants électroniques peuvent alors être disposés en parallèles, l'une de leur borne étant en connexion avec la première zone et l'autre borne de chaque composant étant en connexion avec la deuxième zone de la couche conductrice.According to this embodiment, the conductive layer deposited on the glass is advantageously divided into two distinct zones, constituting two conductive tracks, each of the two zones being connected to an electrode. The electronic components can then be arranged in parallel, one of their terminal being in connection with the first zone and the other terminal of each component being in connection with the second zone of the conductive layer.

La couche conductrice peut également être divisée en de nombreuses zones, chaque zone reliant un composant électronique au suivant, les composants peuvent ainsi connectés en série. Des dispositions mixtes, série et parallèle, peuvent aussi être prévues.The conductive layer can also be divided into many areas, each zone connecting an electronic component to the next, the components can thus connected in series. Mixed, serial and parallel arrangements may also be provided.

Il est ainsi possible de réaliser des pistes conductrices alimentant les LED en déposant une couche conductrice à propriétés anti-solaire et/ou thermiquement isolante sur la majeure partie du vitrage et en éliminant ou modifiant ensuite la couche conductrice sur de fines bandes, par exemple par laser. Pour déposer la couche conductrice, l'une ou l'autre des techniques connues peut être utilisées, par exemple la pulvérisation cathodique sous vide ou le dépôt pyrolytique en phase vapeur.It is thus possible to make conductive tracks supplying the LEDs by depositing a conductive layer with anti-solar and / or thermally insulating properties over the majority of the glazing and then eliminating or modifying the conductive layer. on thin strips, for example by laser. To deposit the conductive layer, one or the other of the known techniques can be used, for example vacuum cathode sputtering or pyrolytic vapor deposition.

Il est également envisageable de réaliser, en une seule étape, le dépôt de la couche conductrice et des pistes conductrices par l'utilisation de masques appropriés, éventuellement réalisé par sérigraphie.It is also conceivable to achieve, in a single step, the deposition of the conductive layer and conductive tracks by the use of appropriate masks, possibly made by screen printing.

Les fines bandes sans couche ont une largeur comprise entre 0.01 et 3 mm, de préférence comprise entre 0.05 et 1.5 mm, et de manière encore préférée entre 0.1 et 0.8 mm. De cette manière, on peut obtenir des connexions électriques quasiment invisibles même si la couche conductrice présente une légère coloration.The thin strips without a layer have a width of between 0.01 and 3 mm, preferably between 0.05 and 1.5 mm, and even more preferably between 0.1 and 0.8 mm. In this way, almost invisible electrical connections can be obtained even if the conductive layer has a slight coloration.

Les LED sont généralement constituées d'une puce semi-conductrice, d'éléments de connexion électrique et d'une enveloppe dont les fonctions sont multiples (protection de l'oxydation et de l'humidité, dissipation de la chaleur, support mécanique).LEDs generally consist of a semiconductor chip, electrical connection elements and an envelope whose functions are multiple (protection of oxidation and moisture, heat dissipation, mechanical support).

Cette enveloppe peut présenter des dimensions suffisamment petites pour être insérée dans un vitrage feuilleté. Au vu du faible flux lumineux fourni par les LED actuelles, il serait nécessaire d'en disposer un grand nombre pour obtenir un éclairage intérieur automobile satisfaisant, et de réaliser un grand nombre de connexions électriques, ce qui rendrait le procédé de fabrication onéreux.This envelope may have dimensions small enough to be inserted in a laminated glazing. Given the low light output provided by the current LEDs, it would be necessary to have a large number to obtain a satisfactory automotive interior lighting, and make a large number of electrical connections, which would make the manufacturing process expensive.

Il est possible de disposer de LED dont le flux lumineux est plus important mais, dans ce cas, l'intensité lumineuse de chaque LED est très important, ce qui génère alors des problèmes de surchauffe et/ou d'éblouissement.It is possible to have LEDs whose luminous flux is greater but, in this case, the light intensity of each LED is very important, which then generates problems of overheating and / or glare.

Selon un mode de réalisation avantageux de l'invention, plusieurs puces sont disposées dans une enveloppe commune dont les dimensions sont telles que sa largeur et/ou sa longueur sont au moins 10 fois plus grandes que son épaisseur, de préférence 20 fois plus grande et de manière encore préférée 40 fois plus grande.According to an advantageous embodiment of the invention, several chips are arranged in a common envelope whose dimensions are such that its width and / or length are at least 10 times greater than its thickness, preferably 20 times greater, and more preferably 40 times larger.

Cette enveloppe est de préférence réalisée dans une matière transparente ou esthétiquement compatible avec le vitrage utilisé. Il est également de préférence réalisé dans une matière suffisamment souple pour lui permettre d'épouser les courbures du vitrage. Il peut avantageusement comprendre une surface diffusante qui permet de lisser la lumière émise par les différentes puces.This envelope is preferably made of a transparent material or aesthetically compatible with the glazing used. It is also preferably made of a sufficiently flexible material to allow it to match the curvatures of the glazing. It may advantageously comprise a diffusing surface that smooths the light emitted by the various chips.

En particulier, l'enveloppe comporte de 5 à 100 puces, de manière préférée de 10 à 50 puces, et de manière encore préférée de 15 à 40 puces.In particular, the envelope comprises from 5 to 100 chips, preferably from 10 to 50 chips, and more preferably from 15 to 40 chips.

Cette enveloppe permet de réaliser un éclairage fournissant de 10 à 500 lumens, de manière préférée de 20 à 250 lumens et de manière encore préférée de 30 à 100 lumens de manière économique, c'est-à-dire sans devoir procéder au collage d'un grand nombre de LED et sans devoir réaliser un grand nombre de connexions électriques.This envelope makes it possible to produce illumination providing from 10 to 500 lumens, preferably from 20 to 250 lumens and more preferably from 30 to 100 lumens, in an economical manner, that is to say without having to proceed with the gluing of a large number of LEDs and without having to make a large number of electrical connections.

De manière préférée, l'enveloppe présente une longueur et/ou une largueur comprise entre 5 et 100 mm, de préférence entre 10 et 75 mm et de manière encore préférée entre 20 et 50 mm.Preferably, the envelope has a length and / or a width of between 5 and 100 mm, preferably between 10 and 75 mm and more preferably between 20 and 50 mm.

L'épaisseur de l'enveloppe est de préférence inférieure ou égale à 3 mm, de manière préférée inférieure à 2 mm, inférieure à 1.2 mm, inférieure à 1 mm et de manière encore plus préférée comprise entre 0.1 et 0.7 mm.The thickness of the envelope is preferably less than or equal to 3 mm, preferably less than 2 mm, less than 1.2 mm, less than 1 mm and even more preferably between 0.1 and 0.7 mm.

Une telle enveloppe permet de ne réaliser que 2 contacts électriques verre/ enveloppe si la luminosité fournie par l'ensemble des puces atteint environ 50 lumens.Such an envelope makes it possible to make only 2 electrical contacts glass / envelope if the brightness provided by the set of chips reaches about 50 lumens.

Selon un mode particulier de réalisation de l'invention, le vitrage comporte un interrupteur de type capacitif, actionnant l'alimentation de l'élément lumineux. Cet interrupteur est constitué d'une zone de la couche conductrice, isolée du reste de la couche conductrice, et fonctionnant comme la sonde d'un circuit capacitif.According to a particular embodiment of the invention, the glazing comprises a capacitive type switch, actuating the power supply of the light element. This switch consists of a zone of the conductive layer, isolated from the rest of the conductive layer, and functioning as the probe of a capacitive circuit.

Ceci permet de réaliser un interrupteur quasiment invisible, qui fonctionne par simple contact du doigt sur la zone isolée et qui peut être disposé à proximité de l'élément lumineux sans rompre l'esthétique du vitrage.This allows for an almost invisible switch, which works by simply touching the finger on the insulated area and can be arranged near the light element without breaking the aesthetics of the glazing.

Selon un mode préféré de réalisation de l'invention, le vitrage est un vitrage feuilleté qui comporte deux feuilles de verre accolées à l'aide d'un ou de plusieurs intercalaires thermoplastiques (généralement de type polyvinylbutyral (PVB)), les LED et leur circuit de connexion étant insérées entre les deux feuilles de verre.According to a preferred embodiment of the invention, the glazing is a laminated glazing which comprises two sheets of glass contiguous with one or more thermoplastic interleaves (generally polyvinyl butyral type (PVB)), the LEDs and their connecting circuit being inserted between the two sheets of glass.

Dans ce mode de réalisation, les couches peuvent être déposées soit sur la surface intérieure d'une ou de l'autre feuille de verre, soit sur le film de PVB intercalé entre les deux feuilles de verre.In this embodiment, the layers may be deposited either on the inner surface of one or the other glass sheet, or on the PVB film interposed between the two glass sheets.

Les LED et en particulier leur enveloppe ou « package » devront résister aux conditions de température et de pression de l'étape d'autoclavage nécessaire pour la fabrication de feuilletés (de l'ordre de 10 à 15 bars et 80 à 150°C pendant 1 à 4 heures).LEDs and in particular their envelope or "package" will have to withstand the temperature and pressure conditions of the autoclaving step necessary for the manufacture of laminates (of the order of 10 to 15 bar and 80 to 150 ° C for 1 to 4 hours).

Lors qu'il est inséré dans un feuilleté, l'enveloppe ne doit pas nécessairement répondre aux exigences de protection contre l'humidité et l'oxydation qui sont généralement exigées pour les enveloppes des LED classiques et pour une utilisation sur un verre simple.When it is inserted into a laminate, the envelope need not necessarily meet the moisture and oxidation protection requirements that are generally required for conventional LED envelopes and for use on a single lens.

L'homme du métier pourra prévoir tout type de disposition des connexions électriques pour connecter les LED ou les puces à l'intérieur de l'enveloppe, au choix, en série, en parallèle ou prévoir une disposition mixte qui a l'avantage de fournir une luminosité homogène.The skilled person can provide any type of arrangement of the electrical connections to connect the LEDs or chips inside the envelope, either in series, in parallel or provide a mixed arrangement that has the advantage of providing a homogeneous brightness.

La présente invention est illustrée par les exemples de réalisation spécifique ci-dessous, ces exemples n'étant pas limitatifs, et référence étant faite aux fig. dans lesquelles,

  • les fig. 1 à 4 représentent, en coupe, un vitrage feuilleté comportant un élément lumineux réalisé avec une ou plusieurs LED traditionnelles ;
  • les fig. 5 et 6 représentent un vitrage feuilleté comportant un élément lumineux réalisé avec des LED particulières;
  • La fig. 7 représente une vue d'ensemble d'un pare-brise comportant, dans sa partie supérieure, un élément lumineux ainsi qu'une zone pour l'allumage et l'extinction de l'élément lumineux.
The present invention is illustrated by the specific embodiments below, these examples not being limiting, and reference being made to FIGS. in which,
  • the Fig. 1 to 4 represent, in section, a laminated glazing comprising a light element made with one or more traditional LEDs;
  • the Fig. 5 and 6 represent a laminated glazing unit comprising a luminous element made with particular LEDs;
  • The Fig. 7 represents an overview of a windshield comprising, in its upper part, a light element and a zone for switching on and off the light element.

La présente invention est illustrée par les exemples de réalisation spécifique ci-dessous, ces exemples n'étant pas limitatifs, et référence étant faite aux fig. dans lesquelles,The present invention is illustrated by the specific embodiments below, these examples not being limiting, and reference being made to FIGS. in which,

Exemple 1 :Example 1

Les éléments suivants ont été empilés :

  • une feuille de verre vert de 3.6 mm d'épaisseur comportant une couche conductrice à base d'oxyde d'étain dopé au fluor, de 300 nm d'épaisseur et d'environ 15 Ω/□, la couche conductrice ayant été éliminée sur une fine bande de manière à délimiter deux zones conductrices distinctes;
  • 2 feuilles de PVB clair totalisant une épaisseur de 0.76 mm;
  • un nombre suffisant de LED pour obtenir l'effet lumineux recherché, collées sur ladite zone sans couche conductrice, les extrémités anode de chaque diode étant en contact avec une des deux zones de la couche conductrice et les côtés cathode de chaque diode étant en contact avec l'autre zone de la couche conductrice ; chacune des deux zones étant elles-mêmes connectées à une électrode ;
  • 1 feuille de PVB clair d'une épaisseur de 0.38 mm,
  • une feuille de verre clair de 2.1 mm d'épaisseur.
The following items have been stacked:
  • a 3.6 mm thick green glass sheet having a fluorine doped tin oxide conductive layer of 300 nm thickness and about 15 Ω / □, the conductive layer having been removed on a thin strip so as to delimit two distinct conductive zones;
  • 2 sheets of clear PVB totaling a thickness of 0.76 mm;
  • a sufficient number of LEDs to obtain the desired light effect, glued to said zone without a conductive layer, the anode ends of each diode being in contact with one of the two zones of the conductive layer and the cathode sides of each diode being in contact with the other area of the conductive layer; each of the two zones being themselves connected to an electrode;
  • 1 sheet of clear PVB with a thickness of 0.38 mm,
  • a clear glass sheet 2.1 mm thick.

L'ensemble est passé à l'autoclave pendant un cycle de 120 min qui comporte au minimum 35 min à température et pression élevées (125°C et 8 bars).The whole is autoclaved during a 120 min cycle which comprises at least 35 min at high temperature and pressure (125 ° C and 8 bar).

Dans ce mode de réalisation, les LED sont disposées en parallèle. Ce mode de réalisation a l'avantage de fournir un circuit de connexion totalement invisible même en utilisant deux feuilles de verre clair.In this embodiment, the LEDs are arranged in parallel. This embodiment has the advantage of providing a totally invisible connection circuit even by using two sheets of clear glass.

Exemple 2 :Example 2

La fig. 1 représente un vitrage feuilleté réalisé comme suit. Une couche conductrice 6 (conductivité d'environ 2 Ω/carré) a été déposée sur une feuille 2 de verre sodo-calcique clair de 2.1 mm d'épaisseur, destinée à être la feuille de verre extérieure du vitrage. La couche conductrice 6 est éliminée au laser sur de fines bandes 4 d'environ 0.15 mm de large, de manière à délimiter des pistes conductrices 6a, 6b. Des LED 8 dont les dimensions extérieures ne dépassent pas 0.6 mm d'épaisseur sont collées de part et d'autre d'une fine bande 4 avec une colle conductrice. Des colles conductrices typiques sont par exemple des colles à l'argent.The Fig. 1 represents a laminated glazing made as follows. A conductive layer 6 (conductivity of about 2 Ω / square) was deposited on a sheet 2 of clear soda-lime glass 2.1 mm thick, intended to be the outer glass sheet of the glazing. The conductive layer 6 is laser removed on thin strips 4 about 0.15 mm wide, so as to delimit conductive tracks 6a, 6b. LEDs 8 whose outer dimensions do not exceed 0.6 mm in thickness are glued on either side of a thin strip 4 with a conductive adhesive. Typical conductive adhesives are, for example, silver adhesives.

La feuille de verre 2 est alors laminée, face revêtue vers l'intérieur, avec une deuxième feuille 10 de verre sodo-calcique clair de manière traditionnelle, en intercalant une feuille thermoplastique double 12 de 0.72 mm d'épaisseur totale.The glass sheet 2 is then rolled, facing inwards, with a second sheet of clear soda-lime glass in the traditional manner, by interposing a double thermoplastic sheet 12 of 0.72 mm total thickness.

Pour l'exemple illustré, la colle doit être choisie pour sa résistance aux hautes températures et pression nécessaire pour réaliser le vitrage feuilleté. Elle doit aussi être choisie en fonction de sa viscosité de manière à éviter qu'elle ne se répande dans la bande isolante 4 lors du laminage du feuilleté.For the illustrated example, the glue must be chosen for its resistance to the high temperatures and pressure required to produce the laminated glazing. It must also be chosen according to its viscosity so as to prevent it from spreading in the insulating strip 4 during laminating of the laminate.

Le flux lumineux émis par la LED est indiqué par la flèche. Il est orienté vers la feuille de verre intérieure 10 du vitrage.The luminous flux emitted by the LED is indicated by the arrow. It is oriented towards the inner glass sheet 10 of the glazing.

Exemple 3:Example 3

La fig. 2 représente un vitrage feuilleté, similaire à celui de l'exemple 1, mis à part que la feuille de verre extérieure est une feuille de verre coloré 14. Ce type de verre feuilleté est particulièrement bien approprié pour réaliser un toit automobile. Sa transmission lumineuse (TL) peut ainsi être abaissée à 14% et sa transmission énergétique (TE) à 11%.The Fig. 2 represents a laminated glazing, similar to that of Example 1, except that the outer glass sheet is a colored glass sheet 14. This type of laminated glass is particularly suitable for making a car roof. Her The light transmission (TL) can thus be reduced to 14% and its energy transmission (TE) to 11%.

Exemple 4 :Example 4

La Fig. 3 représente un vitrage feuilleté comportant une feuille de verre extérieure 2 constituée de verre clair sodo-calcique. Une couche de décoration opaque 16 est déposée sur une partie de la surface intérieure de la feuille de verre 2. La couche conductrice 6 est, dans ce cas, déposée sur la feuille de verre intérieure 10, sur sa face tournée vers intérieur du vitrage feuilleté. Des pistes conductrices 6a, 6b sont réalisées, comme aux exemples précédents, par l'élimination de la couche sur de fines bandes 4. Des LED 18, de type « reverse », c'est-à-dire prévues pour être collées par leur côté émettant la lumière, sont collées de part et d'autre des bandes 4, sur la feuille de verre intérieure 10 du vitrage.The Fig. 3 represents a laminated glazing unit comprising an outer glass sheet 2 made of clear soda-lime glass. An opaque decorative layer 16 is deposited on a portion of the inner surface of the glass sheet 2. The conductive layer 6 is, in this case, deposited on the inner glass sheet 10, on its face turned towards the inside of the laminated glazing . Conductive tracks 6a, 6b are made, as in the previous examples, by the elimination of the layer on thin strips 4. LEDs 18, of the "reverse" type, that is to say intended to be glued by their light emitting side, are glued on both sides of the strips 4, on the inner glass sheet 10 of the glazing.

Ce mode de réalisation permet de rendre le dispositif lumineux invisible du côté extérieur du vitrage puisque les LED 18 sont situées derrière la couche opaque 16 du vitrage.This embodiment makes it possible to make the light device invisible on the outside of the glazing since the LEDs 18 are located behind the opaque layer 16 of the glazing.

La fig. 4 représente le même mode de réalisation qu'à la fig. 2. Les LED 8 sont représentées avec une puce semi-conductrice 20 chacune encapsulée dans une enveloppe 22. Des pistes conductrices distinctes 6a, ...6d sont nécessaires pour relier chaque LED 8.The Fig. 4 represents the same embodiment as at the Fig. 2 . The LEDs 8 are represented with a semiconductor chip 20 each encapsulated in an envelope 22. Separate conductive tracks 6a, ... 6d are necessary to connect each LED 8.

La fig. 7 représente une vue d'ensemble d'un pare-brise 34 comportant un élément lumineux constitué, dans le cas illustré schématiquement, de douze LED 8. Des pistes conductrices 6 a, 6 b, ... 6 e, délimitées par des bandes 4 où la couche 6 a été éliminée, relient chacune des LED 8 en série. Dans le cas illustré, 3 séries de 4 LED 8 sont connectées en parallèle.The Fig. 7 represents an overall view of a windshield 34 comprising a light element constituted, in the case illustrated schematically, of twelve LEDs 8. Conductive tracks 6a, 6b, ... 6e, delimited by strips 4 where the layer 6 has been removed, connect each of the LEDs 8 in series. In the illustrated case, 3 sets of 4 LEDs 8 are connected in parallel.

La fig. 7 montre également une zone conductrice 40 délimitée par des bandes isolantes 4. Celle- ci fonctionne comme une touche capacitive et permet l'allumage et l'extinction de l'élément lumineux.The Fig. 7 also shows a conductive zone 40 delimited by insulating strips 4. This functions as a capacitive key and enables the lighting element to be switched on and off.

Exemple 5 :Example 5

Le vitrage représenté à la fig. 5 comporte comme à l'exemple 1 : une feuille de verre extérieure 2 revêtu d'une couche conductrice 6, un intercalaire thermoplastique 12, et une feuille de verre intérieure 10. L'élément lumineux est réalisé par l'utilisation d'une LED particulièrement adaptée pour cet usage et qui comporte une pluralité de puces semi-conductrices 20 dans une seule enveloppe 24. Ce mode de réalisation nécessite de réaliser moins de pistes conductrices, voir uniquement 2 pistes conductrices 6a, 6b si l'intensité lumineuse fournie par les puces semi-conductrices 20 encapsulées dans une seule enveloppe 24 est suffisante pour l'application recherchée. Ce mode de réalisation permet également de réaliser des bandes 4, entre les pistes conductrices 6a, 6b, plus larges et évite les risques de fluage de la colle dans les bandes isolantes.The glazing shown in Fig. 5 comprises as in Example 1: an outer glass sheet 2 coated with a conductive layer 6, a thermoplastic interlayer 12, and an inner glass sheet 10. The luminous element is made by the use of a particularly LED adapted for this purpose and which comprises a plurality of semiconductor chips 20 in a single envelope 24. This embodiment requires to achieve fewer conductive tracks, see only 2 conductive tracks 6a, 6b if the light intensity provided by the chips semiconductors 20 encapsulated in a single envelope 24 is sufficient for the desired application. This embodiment also makes it possible to produce strips 4, between the conducting tracks 6a, 6b, which are wider and avoids the risk of creep of the adhesive in the insulating strips.

Exemple 6 : Example 6

Le vitrage représenté à la fig. 6 comporte comme aux exemples 1 et 4 : une feuille de verre extérieure 2 revêtu d'une couche conductrice 6, un intercalaire thermoplastique 12, et une feuille de verre intérieure 10. L'élément lumineux est réalisé par l'utilisation d'un film souple 26, par exemple en PET, sur lequel sont collées un ensemble de LED 8 constituées de leur enveloppe 22 encapsulant chacune une ou éventuellement plusieurs puces semi-conductrices 20. Une connexion électrique 28 est prévue sur le film 26, entre chaque enveloppe 22 et entre la dernière enveloppe et la couche conductrice (non représenté). Comme à l'exemple précédent, ce mode de réalisation permet de réaliser peu de pistes conductrices 6a, 6b et de réaliser des bandes 4 relativement larges, ce qui évite le fluage de la colle dans la bande 4. Le vitrage est réalisé en collant en une seule fois un ensemble de LED 8 pré-disposées sur le film 26.The glazing shown in Fig. 6 comprises as in Examples 1 and 4: an outer glass sheet 2 coated with a conductive layer 6, a thermoplastic interlayer 12, and an inner glass sheet 10. The light element is produced by the use of a flexible film 26, for example PET, on which are glued a set of LEDs 8 constituted by their envelope 22 each encapsulating one or possibly more semiconductor chips 20. An electrical connection 28 is provided on the film 26, between each envelope 22 and between the last envelope and the conductive layer (not shown). As in the previous example, this embodiment makes it possible to make few conductive tracks 6a, 6b and to make relatively wide strips 4, which avoids the creep of the adhesive in the strip 4. The glazing is made by adhesive bonding. once a set of LEDs 8 pre-arranged on the film 26.

Selon l'invention, il est donc possible d'obtenir un vitrage tout à fait homogène qui comporte en son sein un dessin lumineux. Les LED ont l'avantage de ne consommer que très peu d'énergie et de ne dissiper pratiquement aucune chaleur. Grâce à leur petite taille, lorsque le dispositif est éteint, les LED ne sont pratiquement pas visibles. Il est donc envisageable de disposer des composants électroniques, non seulement au pourtour du vitrage mais également sur la partie centrale ou sur une grande partie de la surface vitrée sans pour autant entraver la visibilité si le circuit de connexion est réalisé grâce des couches conductrices.According to the invention, it is therefore possible to obtain a completely homogeneous glazing which comprises within it a luminous pattern. LEDs have the advantage of consuming very little energy and dissipating virtually no heat. Thanks to their small size, when the device is off, the LEDs are practically not visible. It is therefore conceivable to have the electronic components, not only around the glazing but also on the central part or on a large part of the glass surface without hindering visibility if the connection circuit is achieved through conductive layers.

Les LED sont généralement monochromatiques et sont disponibles dans toutes les teintes. L'intensité lumineuse d'une LED varie généralement entre 10 et 180 mCd. En insérant un grand nombre de LED, une intensité lumineuse équivalente à celle d'un éclairage incandescent peut être obtenue, tout en ne nécessitant qu'une consommation bien plus faible.LEDs are usually monochromatic and are available in all shades. The luminous intensity of an LED generally varies between 10 and 180 mCd. By inserting a large number of LEDs, a luminous intensity equivalent to that of incandescent lighting can be obtained, while requiring a much lower consumption.

Bien entendu, l'invention ne se limite pas à ce type de réalisation ni à ce type de fonction, tous autres composants électroniques standards du marché, par exemple ceux conçus pour les cartes électroniques peuvent être insérés, selon l'invention entre deux feuilles de verre, pour autant que leur miniaturisation soit suffisante.Of course, the invention is not limited to this type of embodiment or to this type of function, all other standard electronic components of the market, for example those designed for electronic cards can be inserted, according to the invention between two sheets of paper. glass, provided that their miniaturization is sufficient.

Les composants pour montage en surface de type SMD (Surface Mount Device) sont particulièrement bien adaptés. Ces composants peuvent être insérés dans le vitrage dans leur packaging habituel prévu pour le montage en surface des cartes électroniques ou dans un packaging spécialement adapté à l'insertion dans le vitrage ou même sans packaging, le vitrage constituant lui-même dans ce cas le packaging.Surface Mount Device (SMD) surface mount components are particularly well suited. These components can be inserted into the glazing in their usual packaging provided for the surface mounting of the electronic cards or in a packaging specially adapted for insertion in the glazing or even without packaging, the glazing itself constituting in this case the packaging .

Claims (8)

  1. Laminated glazing unit comprising two glass sheets (2, 10, 14) and one or more thermoplastic interlayers (12), LEDs (8, 18) being inserted between the two glass sheets, a connecting circuit being formed by means of a conductive layer (6) deposited on the interior surface of one of the two glass sheets, said layer (6) being divided into at least two separate zones, each of the two zones being connected to an electrode, characterized in that zones (6a, 6b... 6e) have been insulated from the rest of the layer by thin insulating strips (4), the insulating strips (4) having a width comprised between 0.01 and 3 mm, preferably between 0.05 and 1.5 mm and even more preferably between 0.1 and 0.8 mm.
  2. Glazing unit according to Claim 1, characterized in that the conductive layer (6) has a thickness comprised between 0.02 and 0.5 µ and preferably comprised between 0.2 and 0.4 µ.
  3. Glazing unit according to either one of Claims 1 and 2, characterized in that the layer (6) has a resistance comprised between 2 and 80 Ω/square, preferably between 10 and 80 and even more preferably between 12 and 20 Ω/square.
  4. Glazing unit according to any one of the preceding claims, characterized in that the electronic components (8, 18) have a thickness smaller than or equal to 3 mm and in particular a thickness comprised between 0.1 and 1.2 mm.
  5. Glazing unit according to any one of the preceding claims, characterized in that the LEDs comprise a plurality of semiconductor chips (2) in an envelope (24).
  6. Glazing unit according to the preceding claim, characterized in that the envelope (24) has dimensions such that its length and/or a width are at least 10 times larger than its thickness, preferably 20 times larger and even more preferably 40 times larger.
  7. Glazing unit according to either one of Claims 5 and 6, characterized in that the envelope (24) has a length and/or a width comprised between 5 and 100 mm, preferably between 15 and 75 mm and even more preferably between 25 and 50 mm.
  8. Glazing unit according to any one of the preceding claims, characterized in that a switch (40) actuating the power supply of the electronic component (8, 18) is made up of a zone of the conductive layer (6) that is insulated from the rest of the conductive layer by thin strips (4).
EP04700702.6A 2003-01-10 2004-01-08 Glazing comprising a luminous element Revoked EP1585635B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP04700702.6A EP1585635B1 (en) 2003-01-10 2004-01-08 Glazing comprising a luminous element

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
BE2003/0023A BE1015302A3 (en) 2003-01-10 2003-01-10 Glass with electronic components.
BE200300023 2003-01-10
EP03104456.3A EP1437215B8 (en) 2003-01-10 2003-11-28 Glazing comprising a luminous element
EP03104456 2003-11-28
EP04700702.6A EP1585635B1 (en) 2003-01-10 2004-01-08 Glazing comprising a luminous element
PCT/EP2004/050007 WO2004062908A2 (en) 2003-01-10 2004-01-08 Glazing comprising electronic elements

Publications (2)

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EP1585635A2 EP1585635A2 (en) 2005-10-19
EP1585635B1 true EP1585635B1 (en) 2015-02-25

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EP04700702.6A Revoked EP1585635B1 (en) 2003-01-10 2004-01-08 Glazing comprising a luminous element

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US (1) US7745838B2 (en)
EP (2) EP1437215B8 (en)
BE (1) BE1015302A3 (en)
ES (2) ES2581952T3 (en)
WO (1) WO2004062908A2 (en)

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EP1437215A1 (en) 2004-07-14
US7745838B2 (en) 2010-06-29
WO2004062908A3 (en) 2004-09-10
BE1015302A3 (en) 2005-01-11
EP1437215B1 (en) 2016-04-13
WO2004062908A2 (en) 2004-07-29
US20060275599A1 (en) 2006-12-07
EP1437215B8 (en) 2016-06-15
EP1585635A2 (en) 2005-10-19
ES2537102T3 (en) 2015-06-02
ES2581952T3 (en) 2016-09-08

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