EP1575361A1 - Solution aqueuse acaricide - Google Patents
Solution aqueuse acaricideInfo
- Publication number
- EP1575361A1 EP1575361A1 EP03795923A EP03795923A EP1575361A1 EP 1575361 A1 EP1575361 A1 EP 1575361A1 EP 03795923 A EP03795923 A EP 03795923A EP 03795923 A EP03795923 A EP 03795923A EP 1575361 A1 EP1575361 A1 EP 1575361A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solution
- aqueous
- sodium bicarbonate
- mites
- acaricidal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000000895 acaricidal effect Effects 0.000 title claims abstract description 20
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 24
- 239000000243 solution Substances 0.000 claims abstract description 21
- 239000007864 aqueous solution Substances 0.000 claims abstract description 20
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 12
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 12
- 241000282414 Homo sapiens Species 0.000 claims abstract description 10
- 239000004753 textile Substances 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 231100000189 neurotoxic Toxicity 0.000 claims description 2
- 230000002887 neurotoxic effect Effects 0.000 claims description 2
- 241000238876 Acari Species 0.000 description 19
- 239000000642 acaricide Substances 0.000 description 9
- 241000282412 Homo Species 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 240000004460 Tanacetum coccineum Species 0.000 description 2
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 2
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229960000490 permethrin Drugs 0.000 description 2
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 2
- 229940015367 pyrethrum Drugs 0.000 description 2
- 241000239223 Arachnida Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 241000238740 Dermatophagoides pteronyssinus Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012244 neurotoxicant Substances 0.000 description 1
- 231100000421 neurotoxicant Toxicity 0.000 description 1
- 230000001682 neurotoxicant effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/04—Carbon disulfide; Carbon monoxide; Carbon dioxide
Definitions
- the invention relates to an aqueous acaricidal solution. It also relates to the use of such an aqueous solution.
- aqueous acaricide solution an aqueous solution causing the death of the mites.
- the mites can be in the state of eggs, larvae or adults.
- the action of the aqueous solution can be direct. It can also be indirect, for example when the aqueous acaricide solution destroys a substance necessary for the survival of the mite.
- Dust mites are small arachnids, with dimensions close to a tenth of a millimeter, which develop in particular in bedding and carpets of dwellings and likely to cause allergic reactions in humans. Their optimal living conditions require a humidity between 55 and 85% and a temperature between 15 and 35 ° C. Dust mites mainly feed on dander and organic matter which accumulate in thick textiles. The average adult human loses 1.5 g of dead skin per day, which is enough to feed 1.5 million mites.
- acaricide compositions in powder form are difficult to apply homogeneously and to penetrate the heart of the textile.
- the invention aims to provide an aqueous, natural and harmless solution for humans, making it possible to eliminate mites in a simple, effective and economical manner.
- the invention relates to an aqueous acaricidal solution comprising at least 10 g / l of sodium bicarbonate.
- Sodium bicarbonate is known to be harmless to humans. It is even authorized by various organizations (such as the FDA in the United States) in human food. It has been observed that the mites do not absorb the aqueous acaricidal solution according to the invention but that, upon evaporation of the water, the sodium bicarbonate crystallizes in the form of extremely fine grains. These fine grains adhere to the outer surface of the mites. Without wishing to be bound by a theoretical explanation and without excluding other modes of action, the inventor thinks that the grains of bicarbonate deteriorate certain equilibria of membrane exchanges in the cuticle of the mite and the shell of the egg, which would induce their dehydration and ultimately their death.
- the aqueous acaricide solution comprises at least 10 g / l of sodium bicarbonate. It is unnecessary for it to include more than 100 g / l. It is recommended that it contain at least 30 g / 1 of sodium bicarbonate, preferably 40 g / 1. It is advantageous if the aqueous solution does not comprise more than 80 g / l of sodium bicarbonate, preferably 60 g / l. Acaricidal aqueous solutions comprising from 40 to 60 g / l of sodium bicarbonate are particularly suitable.
- the aqueous solution does not comprise any other acaricidal substance.
- the only acaricide active ingredient is sodium bicarbonate.
- the aqueous solution does not contain any neurotoxic substance "such as pyrethrum or permethrin.
- the invention also relates to the use of the aqueous solution according to the invention described above for its acaricidal effects, in particular for the processing elements of the human environment.
- elements of the human environment is meant the interior elements of the buildings in which humans live, such as offices or residences.
- material elements with which man is in contact conducive to the development of mites.
- elements include for example: bedding (mattresses, pillows, textiles for bedding), rugs, carpets, armchairs, textiles for clothing, plush and fleeces.
- the aqueous solution according to the invention which is natural and harmless to humans is particularly suitable for the treatment of carpets, rugs and textiles for bedding and clothing.
- the aqueous solution according to the invention correctly penetrates into the texture to be treated. It can be applied in particular by brushing, spraying or immersion.
- the aqueous solution is applied by spraying. Sprinkling consists to form very fine droplets and to project these onto the element to be treated. Spraying can be assisted by the expansion of a gas, which improves the projection of the droplets. It is then commonly called “spray".
- the quantity of aqueous acaricide solution to be applied, per square meter, can vary depending on the nature of the surface to be treated.
- the aqueous solution is applied to the element to be treated by immersion of the latter in the aqueous solution.
- the immersion time must be sufficient to ensure correct penetration of the aqueous solution into the element to be treated.
- Mites (Dermatophagoides pteronyssinus) were used, originating from a laboratory strain reared on a substrate composed of a 50/50 mixture (mass / mass) of wheat germ and brewer's yeast in flakes calibrated by sieving (fragments of size less than 1 mm).
- the temperature was between 23 and 25 ° C and the relative humidity maintained at 75% by the presence of a saturated solution of ammonium sulfate ([(NH4) 2 SO4]); the strain was kept in the dark.
- Standard cotton plots (150g / m 2 ) were previously infested with around 200 mites of all stages.
- the cotton plots were then treated by spraying with an aqueous solution obtained by mixing 10, 30 or 50 g / 1 of sodium bicarbonate in water.
- a control batch of mites was followed in parallel to know the natural mortality of the mites subjected to spraying with the same volume of water. Each experimental series was repeated three times and averages of the mortality results obtained were taken.
- Example 2 in which the cotton patch is infested with mites before being treated, illustrates the curative miticide effect of the solution according to the invention.
- Example 2 in which the cotton patch is infested with mites before being treated, illustrates the curative miticide effect of the solution according to the invention.
- Example 2 The procedure was as in Example 1 except that the aqueous acaricidal solution was not applied by spraying but that the standard cotton plots (150 g / m 2 ) were immersed in baths of sodium bicarbonate solution.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0216447 | 2002-12-19 | ||
| FR0216447A FR2848779B1 (fr) | 2002-12-19 | 2002-12-19 | Solution aqueuse acaricide |
| PCT/EP2003/014523 WO2004056183A1 (fr) | 2002-12-19 | 2003-12-18 | Solution aqueuse acaricide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1575361A1 true EP1575361A1 (fr) | 2005-09-21 |
Family
ID=32406341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP03795923A Withdrawn EP1575361A1 (fr) | 2002-12-19 | 2003-12-18 | Solution aqueuse acaricide |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20060159777A1 (enExample) |
| EP (1) | EP1575361A1 (enExample) |
| JP (2) | JP4771700B2 (enExample) |
| AU (1) | AU2003298207A1 (enExample) |
| FR (1) | FR2848779B1 (enExample) |
| WO (1) | WO2004056183A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2848780B1 (fr) * | 2002-12-19 | 2005-05-13 | Solvay | Utilisation d'une poudre acaricide |
| FR2859601B1 (fr) * | 2003-09-16 | 2008-05-09 | Solvay | Suspension aqueuse parasiticide |
| FR2883129B1 (fr) * | 2005-03-17 | 2008-02-15 | Solvay | Procede de deparasitage et poudre parasiticide |
| FR2883128B1 (fr) * | 2005-03-17 | 2008-02-15 | Solvay | Suspension aqueuse parasiticide |
| FR2891991B1 (fr) * | 2005-10-17 | 2008-01-18 | Solvay | Procede et composition pediculicide |
| FR2969463A1 (fr) * | 2010-12-23 | 2012-06-29 | Solvay | Ensemble parasiticide |
| CA2958950C (en) | 2014-09-04 | 2022-11-22 | Solvay Sa | Method for the prophylactic treatment of a food product silo |
| EP3745858A1 (en) | 2018-02-02 | 2020-12-09 | Solvay Sa | Method for the prophylactic treatment of a food product |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL65143A (en) * | 1981-03-26 | 1987-10-20 | Robins Co Inc A H | Household pesticidal compositions in powder form |
| US5254386A (en) * | 1991-05-10 | 1993-10-19 | Church & Dwight Co., Inc. | Deodorized carpets and process for producing same |
| JPH0539206A (ja) * | 1991-08-06 | 1993-02-19 | Rikagaku Kenkyusho | 殺虫剤 |
| WO1993022915A1 (en) * | 1992-05-12 | 1993-11-25 | Church & Dwight Company, Inc. | Insecticide compositions |
| AU2884692A (en) * | 1992-11-03 | 1994-05-24 | Sil-Tech International Corporation | Insect control compositions |
| US5518987A (en) * | 1995-10-03 | 1996-05-21 | Church & Dwight Co., Inc. | Pesticide compositions for control of fungal disease in cultivated crops |
| JPH1087408A (ja) * | 1996-09-09 | 1998-04-07 | Aramuya:Kk | 害虫防除剤 |
| FR2891991B1 (fr) * | 2005-10-17 | 2008-01-18 | Solvay | Procede et composition pediculicide |
-
2002
- 2002-12-19 FR FR0216447A patent/FR2848779B1/fr not_active Expired - Fee Related
-
2003
- 2003-12-18 AU AU2003298207A patent/AU2003298207A1/en not_active Abandoned
- 2003-12-18 WO PCT/EP2003/014523 patent/WO2004056183A1/fr not_active Ceased
- 2003-12-18 EP EP03795923A patent/EP1575361A1/fr not_active Withdrawn
- 2003-12-18 JP JP2004561350A patent/JP4771700B2/ja not_active Expired - Fee Related
- 2003-12-18 US US10/539,564 patent/US20060159777A1/en not_active Abandoned
-
2011
- 2011-03-08 JP JP2011050217A patent/JP2011148807A/ja active Pending
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2004056183A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004056183A1 (fr) | 2004-07-08 |
| AU2003298207A1 (en) | 2004-07-14 |
| JP2011148807A (ja) | 2011-08-04 |
| JP4771700B2 (ja) | 2011-09-14 |
| FR2848779A1 (fr) | 2004-06-25 |
| JP2006510698A (ja) | 2006-03-30 |
| FR2848779B1 (fr) | 2005-05-13 |
| US20060159777A1 (en) | 2006-07-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20050719 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
| AX | Request for extension of the european patent |
Extension state: AL LT LV MK |
|
| DAX | Request for extension of the european patent (deleted) | ||
| 17Q | First examination report despatched |
Effective date: 20070911 |
|
| R17C | First examination report despatched (corrected) |
Effective date: 20080729 |
|
| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: SOLVAY SA |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20150701 |