EP1549566B1 - Dispenser for liquid or pasty product - Google Patents
Dispenser for liquid or pasty product Download PDFInfo
- Publication number
- EP1549566B1 EP1549566B1 EP03795043A EP03795043A EP1549566B1 EP 1549566 B1 EP1549566 B1 EP 1549566B1 EP 03795043 A EP03795043 A EP 03795043A EP 03795043 A EP03795043 A EP 03795043A EP 1549566 B1 EP1549566 B1 EP 1549566B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- piston
- dispenser according
- needle
- knurl
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 235000011837 pasties Nutrition 0.000 title claims description 9
- 239000007788 liquid Substances 0.000 title claims description 8
- 238000000034 method Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920002457 flexible plastic Polymers 0.000 claims description 2
- 238000006073 displacement reaction Methods 0.000 abstract description 4
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 43
- 238000007789 sealing Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 230000009471 action Effects 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000005429 filling process Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003556 assay Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D47/00—Closures with filling and discharging, or with discharging, devices
- B65D47/04—Closures with discharging devices other than pumps
- B65D47/20—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
- B65D47/2018—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure
- B65D47/2056—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure lift valve type
- B65D47/2062—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure lift valve type in which the deformation raises or lowers the valve stem
- B65D47/2068—Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge comprising a valve or like element which is opened or closed by deformation of the container or closure lift valve type in which the deformation raises or lowers the valve stem in which the stem is lowered by the pressure of the contents and thereby opening the valve
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/0005—Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container
- B65D83/0011—Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container moved by a screw-shaft
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/0005—Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container
- B65D83/0027—Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container piston co-operating with a screw-thread in the side wall of the container
Definitions
- the invention relates to a liquid or pasty product dispenser in which the product is extracted by controlled displacement of a piston inside a body, the assembly defining a chamber containing such a product.
- Dispensers for thick or pasty liquid products, comprising a generally cylindrical body and a piston capable of moving in the body and forming a movable wall of a chamber containing the product.
- An extraction mechanism in communication with the chamber includes a pump configured to aspirate and dispense a predetermined dose upon each actuation.
- the piston is simply follower, its movement being determined by the amount of product extracted.
- the volume of the chamber decreases by adapting to the amount of product remaining.
- the pump is located between the chamber and an ejection nozzle or the like, so that product can dry and / or deteriorate in the ejection duct and the pump.
- a known device of this kind has a large number of relatively fragile parts, including those that constitute the pump, which makes a high cost of packaging for reliability sometimes poor.
- the document FR 2807631 discloses a liquid or pasty product dispenser according to the preamble of claim 1.
- the invention overcomes these disadvantages.
- An object of the invention is to provide a liquid product dispenser in which the distribution of the product is obtained by direct action on the piston, without the need to integrate a pump.
- the invention relates to a liquid or pasty product dispenser comprising a hollow body and a piston mounted to move internally therein and defining with said body a chamber for the product to be dispensed, an outlet channel. being defined in an end wall of said body, and which has a wheel rotatably mounted relative to said body at one end thereof, in that a rotational locking arrangement is defined between said body and said piston, in that said piston is provided with a hollow skirt threaded internally in that said wheel has an internal cylindrical portion engaged in said hollow skirt and in that said cylindrical portion is threaded externally and screwed into said hollow skirt.
- Another object of the invention is to provide a distributor of the kind defined above, supplemented by means for assaying the amount of product extracted.
- anti-return locking means are defined between the wheel and the body to impose a one-way rotation of the wheel relative to said body. This arrangement allows itself to control the stroke of the piston and therefore to achieve a certain dosage, proportional to the rotation of the wheel.
- the dispenser defined above is characterized in that, said wheel and / or said body being made of relatively deformable plastic material, said anti-return locking means comprise sawtooth ribs. , defined on two generally cylindrical parts facing said body and said wheel and nested in each other.
- the dispenser of liquid or pasty product has the general shape of a rod having an orifice arranged on the face of the end wall thereof.
- the product is distributed through this orifice.
- the latter is preferably in the center of said end wall so that the dose of dispensed product accumulates thereon.
- the product can be removed from the finger, for example for application, if it is a cosmetic product.
- the dispenser may have at its end an applicator whose shape and structure are adapted to the use for which the product is intended.
- the dispenser is characterized in that a needle is mounted to slide sealingly through said piston and in alignment with the internal orifice of said outlet channel, in that it is elastically biased towards said output channel and in that the end of said needle is shaped and dimensioned to engage in said outlet channel and seal it
- This needle thus makes it possible to effectively isolate the chamber when the dispenser is not used, which improves the conservation of the product.
- the outlet channel consists of an axial rectilinear hole through said end wall and the needle has an end shaped and dimensioned to close said hole, substantially to the outer face of the wall of the wall. end of said body. This provides a seal at any end and no dried product residue is likely to form downstream of the needle in the outlet channel since the volume of it, reduced to a minimum, is occupied by the needle itself .
- the needle has a section reduction in said chamber.
- the removal of the needle is obtained automatically under the effect of an increase in pressure in the chamber, that is to say when actuating the wheel.
- the needle may be biased in the closed position by a spring installed in said hollow skirt between a shoulder of the needle and the wheel. In this way, the needle retracts and releases the outlet channel as soon as the pressure in the chamber becomes sufficient to generate on said needle a force greater than that developed by the spring.
- the distributor is intended to be filled by the distribution channel, when the chamber is at its maximum volume, that is to say with the piston remote maximum of the wall end of the body.
- the arrangement of the needle advantageously lends itself to the evacuation of the air during filling of the dispenser.
- an air outlet channel is defined in said needle.
- This evacuation channel comprises an axial section emerging at the rear of the needle, while a plug is engaged from the rear in this axial section.
- the cap is released from the back of the needle during filling to allow the evacuation of air, it is depressed permanently at the end of the filling phase.
- the invention also relates to a method of filling a dispenser according to the preceding description and characterized in that it consists, said chamber being at its maximum volume, to maintain said air evacuation channel in communication with the atmosphere, filling said product chamber by injecting said product under pressure through said outlet channel and recapping the air outlet channel when said chamber is filled with product.
- the liquid or pasty product dispenser 11 as shown comprises a generally cylindrical hollow body 14 having an open end 15 and an opposite end wall 17 provided with an outlet channel 18 consisting of a axial straight hole passing through this wall 17.
- a piston 20 is mounted to move sealingly inside the body.
- any reference to an axial direction or an axis refers to the general axis of symmetry YY 'of the distributor, coinciding with that of the piston and the channel 18.
- the piston and the body define between they a variable volume chamber 21 containing the product 22 to distribute.
- the dispenser further comprises a knob 24 rotatably mounted relative to the body on the open end side thereof.
- the dispenser body has two longitudinally adjacent portions of different diameters.
- this difference in diameter is obtained by a decrease in wall thickness of said body on a portion 25 thereof from the open end.
- the wheel 24 which here has a generally cylindrical shape is mounted in the thinned portion of the dispenser body, so that its outer side wall 26 is generally in the extension of the outer side wall 27 of the rest of the body 14.
- the piston 20 is provided with a hollow skirt 30 threaded internally, (thread 31).
- the wheel has an internal cylindrical portion 32 engaged in the hollow skirt 30 of the piston.
- the inner cylindrical portion of the wheel is threaded externally (thread 33) and is screwed into the hollow skirt.
- the wheel 24 and the body are immobilized in axial translation relative to each other by a set-throat.
- the ring 34 is defined on the inner face of an outer skirt constituting the wheel, while the groove 35 is defined on a cylindrical portion of the body, in the vicinity of the open end 15 thereof.
- a rotational locking arrangement 38 is defined between said body and said piston.
- the rotational locking arrangement comprises at least one and preferably several ribs 40 extending parallel to the longitudinal axis of the device and defined on the internal face of said body 14.
- the piston 20 is made of a relatively flexible plastic material so that the ribs 40 therein imprint to prevent rotation of the piston relative to said body.
- the end of the piston 20 located on the side of the chamber 21 is shaped with a peripheral sealing lip 42 in sealing contact and "scraping" with the inner cylindrical wall of the body.
- the ribs 40 are formed in an inner portion of enlarged diameter of the body, adjacent the smooth wall portion which defines the chamber 21, so that said ribs can not come into contact with the sealing lip defined at the periphery of the face. active piston, at the time of assembly of the piston.
- the skirt 30 of the piston itself comprises a portion 42 of smaller section extending over a distance at least equal to the stroke of the piston, between the lip 42 and a portion 44 of large section cooperating with the ribs 40.
- the dispenser makes it possible to measure at least approximately the quantity of product taken with each use, especially if care is taken to inscribe graduations along two neighboring circular lines worn. respectively by the body and the wheel. Indeed, it is clear that the amount of product expelled depends directly on the angle that is rotated the wheel relative to the body.
- anti-return blocking means 46 are defined between the wheel 24 and the body 14, to impose a rotation in one direction, the wheel relative to said body.
- the wheel and the body are made of relatively deformable plastic materials.
- said anti-return blocking means 46 consist of notching ribs, with opposite 48.49 sawtooth profile, facing each other, respectively defined on two generally cylindrical parts facing each other. body and wheel. As is clearly visible on the figure 2 these ribs are nested inside one another. Each rib has a face extending substantially radially. These radial faces respectively belonging to the outer surface of the body and to the inner surface of the wheel abut in pairs and prevent rotation in one direction.
- the central portion of the active face 50 of the piston 20 is recessed and shaped with an inner lip 52 in sealing contact with the cylindrical side wall of a needle 54 axially mounted in the distributor, in alignment with the orifice internal of the outlet channel 18.
- the needle is biased elastically towards the outlet channel. Its end is shaped and dimensioned to engage in said outlet channel.
- the outlet channel 18 is a straight axial hole of short length passing through the end wall of the body, said needle has an end portion 56 shaped and dimensioned to close said hole substantially to the outer face 57 of the end wall of the body.
- the end portion 56 is cylindrical. This gives a complete closure of the dispenser called "any end" preventing any drying of residual product.
- the needle has a section reduction in the chamber, that is to say a decrease in diameter between the cylindrical portion against which the piston slides and that 56 which closes the outlet channel.
- a section reduction in the chamber that is to say a decrease in diameter between the cylindrical portion against which the piston slides and that 56 which closes the outlet channel.
- an increase in pressure in the chamber 21 results in an axial force on the needle 54 tending to move it away from the end wall of the body.
- a spring 60 is installed in precompression in the hollow skirt of the piston between a shoulder of the needle and the knob 24. The end of the needle opposite to that which controls the outlet channel engages and slides in a central hole 62 bottom 63 of the knob which closes the open end 15 of the body.
- the body 14 and the wheel 24 are advantageously two generally cylindrical elements and arranged in the extension of one another so as to form a generally cylindrical unit.
- the dispenser as described may constitute a standardized functional entity constituting a kind of "motor” capable of receiving a covering whose shape is representative of the product offers.
- this covering may consist of two parts, one essentially covering the body and the other the wheel, these two parts having a configuration not necessarily cylindrical.
- Such a shape allows itself a visual assay (even in the absence of notching ribs between the body and the wheel) by the simple fact that a rotation between two positions where the lateral faces of the body and the wheel come into the extension of each other is in itself an indication of dosage.
- the needle 54 is advantageously suitable for the evacuation of air at the time of filling the chamber.
- the dispenser must be filled by positioning the piston so that the chamber 21 has its maximum volume, as shown in FIG. figure 1 because the injection pressure of the product would be insufficient to push the piston, given its method of coupling by threading the wheel. It must therefore be able to evacuate the air during filling. Therefore, an air outlet channel 65, closable by a plug 66, is defined in the needle to allow filling of the chamber.
- This air outlet channel comprises an axial portion 68 connected to the chamber by radial bores 69 and opening axially at the rear of the needle. The cap 66 is engaged from the rear in this axial section.
- the plug 66 has a solid end portion 70 extended by fins 71 engaged in the axial section.
- the plug can be partially engaged in the axial section and remain in a chosen position thanks to the friction forces developed in particular between the fins 71 and the inner wall of this axial section.
- the cap is half engaged in the axial section so that the air can escape freely between the chamber and the outside.
- the plug is pressed as far as possible in the axial section ( figure 3 ) and the exhaust duct is permanently closed.
- the figure 4 illustrates the filling process.
- the dispenser empty, with the cap half engaged, is positioned "upside down" in one of the cavities of a bezel 76 whose bottom is provided with a tubular filling spout 77 equipped with a seal sealing 78 coming to bear around the orifice of the outlet channel 18.
- the product is injected under pressure by the filling spout and thus enters the chamber through the outlet channel. Filling takes place when the cavity of the bezel in which the empty dispenser is located faces an upper stop 80 immobilizing the dispenser in the bezel, which makes it possible to seal the filling spout around the outlet channel.
- the upper stop may be equipped with a traction fork 81 shaped to come to grip the cap by the solid portion 70 thereof, which comprises a flange.
- This range is linked to a jack not shown so that the needle can be positively retracted at the time of filling. It should be noted that this arrangement is not necessarily necessary if the injection pressure of the product is sufficient to cause the lifting of the needle.
- the chamber being at its maximum volume, the air evacuation channel is maintained in communication with the atmosphere and the product chamber is filled by injecting said product under pressure by the output channel, as shown on the figure 4 .
- the filling process is completed by pushing the cap to the maximum when the distributor 11 is disengaged from the stop 80.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Basic Packing Technique (AREA)
- Jellies, Jams, And Syrups (AREA)
- Coating Apparatus (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Infusion, Injection, And Reservoir Apparatuses (AREA)
- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
- Loading And Unloading Of Fuel Tanks Or Ships (AREA)
Abstract
Description
L'invention concerne un distributeur de produit liquide ou pâteux dans lequel le produit est extrait par déplacement contrôlé d'un piston à l'intérieur d'un corps, l'ensemble définissant une chambre contenant un tel produit.The invention relates to a liquid or pasty product dispenser in which the product is extracted by controlled displacement of a piston inside a body, the assembly defining a chamber containing such a product.
On connaît des distributeurs pour des produits liquides épais ou pâteux, comprenant un corps globalement cylindrique et un piston susceptible de se déplacer dans le corps et formant une paroi mobile d'une chambre renfermant le produit. Un mécanisme d'extraction, en communication avec la chambre, comporte une pompe conçue pour aspirer et distribuer une dose prédéterminée à chaque actionnement. Le piston est simplement suiveur, son déplacement étant déterminé par la quantité de produit extrait. Le volume de la chambre diminue en s'adaptant à la quantité de produit restant. Dans un tel dispositif, la pompe est située entre la chambre et un bec d'éjection ou analogue, de sorte que du produit peut sécher et/ou s'altérer dans le conduit d'éjection et la pompe. En outre, un dispositif connu de ce genre comporte un grand nombre de pièces relativement fragiles, notamment celles qui constituent la pompe, ce qui en fait un conditionnement de prix de revient élevé pour une fiabilité parfois médiocre. Le document
L'invention permet de surmonter ces inconvénients.The invention overcomes these disadvantages.
Un objet de l'invention est de proposer un distributeur de produit liquide dans lequel la distribution du produit s'obtient par action directe sur le piston, sans qu'il soit nécessaire d'y intégrer une pompe.An object of the invention is to provide a liquid product dispenser in which the distribution of the product is obtained by direct action on the piston, without the need to integrate a pump.
Plus particulièrement, l'invention concerne un distributeur de produit liquide ou pâteux comprenant un corps creux et un piston monté à déplacement étanche à l'intérieur de celui-ci et délimitant avec ledit corps une chambre pour le produit à distribuer, un canal de sortie étant défini dans une paroi d'extrémité dudit corps, et qui comporte une molette montée en rotation par rapport audit corps à une extrémité de celui-ci, en ce qu'un agencement de blocage en rotation est défini entre ledit corps et ledit piston, en ce que ledit piston est pourvu d'une jupe creuse filetée intérieurement en ce que ladite molette comporte une partie cylindrique interne engagée dans ladite jupe creuse et en ce que cette partie cylindrique est filetée extérieurement et vissée dans ladite jupe creuse.More particularly, the invention relates to a liquid or pasty product dispenser comprising a hollow body and a piston mounted to move internally therein and defining with said body a chamber for the product to be dispensed, an outlet channel. being defined in an end wall of said body, and which has a wheel rotatably mounted relative to said body at one end thereof, in that a rotational locking arrangement is defined between said body and said piston, in that said piston is provided with a hollow skirt threaded internally in that said wheel has an internal cylindrical portion engaged in said hollow skirt and in that said cylindrical portion is threaded externally and screwed into said hollow skirt.
Un autre objet de l'invention est de proposer un distributeur du genre défini ci-dessus, complété par des moyens de dosage de la quantité de produit extrait.Another object of the invention is to provide a distributor of the kind defined above, supplemented by means for assaying the amount of product extracted.
Selon un mode de réalisation possible, des moyens de blocage anti-retour sont définis entre la molette et le corps pour imposer une rotation en sens unique de la molette par rapport audit corps. Cet agencement permet en soi de contrôler la course du piston et par conséquent, de réaliser un certain dosage, proportionnel à la rotation de la molette.According to a possible embodiment, anti-return locking means are defined between the wheel and the body to impose a one-way rotation of the wheel relative to said body. This arrangement allows itself to control the stroke of the piston and therefore to achieve a certain dosage, proportional to the rotation of the wheel.
Selon un mode de réalisation plus particulièrement avantageux, le distributeur défini ci-dessus est caractérisé en ce que, ladite molette et/ou ledit corps étant réalisés en matériau plastique relativement déformable, lesdits moyens de blocage anti-retour comportent des nervures en dents de scie, définies sur deux parties globalement cylindriques en regard dudit corps et de ladite molette et imbriquées les unes dans les autres.According to a more particularly advantageous embodiment, the dispenser defined above is characterized in that, said wheel and / or said body being made of relatively deformable plastic material, said anti-return locking means comprise sawtooth ribs. , defined on two generally cylindrical parts facing said body and said wheel and nested in each other.
De cette façon, l'utilisateur peut facilement contrôler la progression du piston, cran par cran. En choisissant judicieusement les matières plastiques utilisées pour constituer ledit corps et ladite molette, on peut rendre relativement audible l'actionnement des moyens de blocage anti-retour constituant un système de progression à cliquet. Ceci permet à l'utilisateur de compter le nombre de pas pour contrôler la quantité de produit distribué.In this way, the user can easily control the progress of the piston, notch by notch. By judiciously choosing the plastics used to form said body and said wheel, it can be made relatively audible the actuation of the non-return locking means constituting a ratchet progression system. This allows the user to count the number of steps to control the amount of product dispensed.
Dans un mode de réalisation simple, le distributeur de produit liquide ou pâteux a la forme générale d'un bâtonnet comportant un orifice aménagé sur la face de la paroi d'extrémité de celui-ci. Le produit est distribué par cet orifice. Ce dernier se trouve de préférence au centre de ladite paroi d'extrémité en sorte que la dose de produit distribué s'accumule sur celle-ci. Le produit peut être prélevé du doigt, par exemple pour application, s'il s'agit d'un produit cosmétique. Dans d'autres cas, le distributeur peut posséder à son extrémité un applicateur dont la forme et la structure sont adaptées à l'usage auquel est destiné le produit.In a simple embodiment, the dispenser of liquid or pasty product has the general shape of a rod having an orifice arranged on the face of the end wall thereof. The product is distributed through this orifice. The latter is preferably in the center of said end wall so that the dose of dispensed product accumulates thereon. The product can be removed from the finger, for example for application, if it is a cosmetic product. In other cases, the dispenser may have at its end an applicator whose shape and structure are adapted to the use for which the product is intended.
Selon une autre caractéristique avantageuse, le distributeur est caractérisé en ce qu'un pointeau est monté coulissant de façon étanche au travers dudit piston et dans l'alignement de l'orifice interne dudit canal de sortie, en ce qu'il est sollicité élastiquement vers ledit canal de sortie et en ce que l'extrémité dudit pointeau est conformée et dimensionnée pour s'engager dans ledit canal de sortie et l'obturerAccording to another advantageous characteristic, the dispenser is characterized in that a needle is mounted to slide sealingly through said piston and in alignment with the internal orifice of said outlet channel, in that it is elastically biased towards said output channel and in that the end of said needle is shaped and dimensioned to engage in said outlet channel and seal it
Ce pointeau permet donc d'isoler efficacement la chambre lorsque le distributeur n'est pas utilisé, ce qui améliore la conservation du produit.This needle thus makes it possible to effectively isolate the chamber when the dispenser is not used, which improves the conservation of the product.
Dans un mode de réalisation avantageux, le canal de sortie est constitué par un trou rectiligne axial traversant ladite paroi d'extrémité et le pointeau comporte une extrémité conformée et dimensionnée pour obturer ledit trou, sensiblement jusqu'à la face externe de la paroi d'extrémité dudit corps. On obtient ainsi une étanchéité de toute extrémité et aucun résidu de produit séché n'est susceptible de se former en aval du pointeau dans le canal de sortie puisque le volume de celui-ci, réduit au minimum, est occupé par le pointeau lui-même.In an advantageous embodiment, the outlet channel consists of an axial rectilinear hole through said end wall and the needle has an end shaped and dimensioned to close said hole, substantially to the outer face of the wall of the wall. end of said body. This provides a seal at any end and no dried product residue is likely to form downstream of the needle in the outlet channel since the volume of it, reduced to a minimum, is occupied by the needle itself .
Selon une autre caractéristique avantageuse, le pointeau présente une réduction de section dans ladite chambre. Par ce moyen simple, le retrait du pointeau s'obtient automatiquement sous l'effet d'une augmentation de pression dans la chambre, c'est à dire lorsqu'on actionne la molette. Par exemple, le pointeau peut être sollicité en position de fermeture par un ressort installé dans ladite jupe creuse entre un épaulement du pointeau et la molette. De cette façon, le pointeau se rétracte et libère le canal de sortie dès que la pression dans la chambre devient suffisante pour engendrer sur ledit pointeau, une force supérieure à celle qui est développée par le ressort.According to another advantageous characteristic, the needle has a section reduction in said chamber. By this simple means, the removal of the needle is obtained automatically under the effect of an increase in pressure in the chamber, that is to say when actuating the wheel. For example, the needle may be biased in the closed position by a spring installed in said hollow skirt between a shoulder of the needle and the wheel. In this way, the needle retracts and releases the outlet channel as soon as the pressure in the chamber becomes sufficient to generate on said needle a force greater than that developed by the spring.
Par ailleurs, le couplage entre la molette et le piston étant irréversible, le distributeur est prévu pour être rempli par le canal de distribution, lorsque la chambre est à son volume maximum, c'est à dire avec le piston éloigné au maximum de la paroi d'extrémité du corps. L'agencement du pointeau se prête avantageusement à l'évacuation de l'air pendant le remplissage du distributeur.Moreover, the coupling between the wheel and the piston being irreversible, the distributor is intended to be filled by the distribution channel, when the chamber is at its maximum volume, that is to say with the piston remote maximum of the wall end of the body. The arrangement of the needle advantageously lends itself to the evacuation of the air during filling of the dispenser.
Pour ce faire, un canal d'évacuation d'air, obturable, est défini dans ledit pointeau. Ce canal d'évacuation comporte un tronçon axial débouchant à l'arrière du pointeau, tandis qu'un bouchon est engagé par l'arrière dans ce tronçon axial. Le bouchon est dégagé de l'arrière du pointeau pendant le remplissage pour permettre l'évacuation de l'air, il est enfoncé définitivement à la fin de la phase de remplissage.To do this, an air outlet channel, closable, is defined in said needle. This evacuation channel comprises an axial section emerging at the rear of the needle, while a plug is engaged from the rear in this axial section. The cap is released from the back of the needle during filling to allow the evacuation of air, it is depressed permanently at the end of the filling phase.
L'invention concerne aussi un procédé de remplissage d'un distributeur conforme à la description qui précède et caractérisé en ce qu'il consiste, ladite chambre étant à son volume maximum, à maintenir ledit canal d'évacuation d'air en communication avec l'atmosphère, à remplir ladite chambre de produit en injectant ledit produit sous pression par ledit canal de sortie et à reboucher le canal d'évacuation d'air lorsque ladite chambre est remplie de produit.The invention also relates to a method of filling a dispenser according to the preceding description and characterized in that it consists, said chamber being at its maximum volume, to maintain said air evacuation channel in communication with the atmosphere, filling said product chamber by injecting said product under pressure through said outlet channel and recapping the air outlet channel when said chamber is filled with product.
L'invention sera mieux comprise et d'autres avantages de celle-ci apparaîtront plus clairement à la lumière de la description qui va suivre d'un distributeur de produit liquide ou pâteux conforme à son principe, donnée uniquement à titre d'exemple et faite en référence aux dessins annexés dans lesquels :
- la
figure 1 est une vue en élévation, suivant une coupe I-I de lafigure 2 , d'un distributeur conforme à l'invention ; - la
figure 2 est une coupe II-II de lafigure 1 ; - la
figure 3 est une vue analogue à lafigure 1 montrant le dispositif pendant la distribution d'une dose de produit ; - la
figure 4 illustre le remplissage du dispositif.
- the
figure 1 is an elevation view, following a section II of thefigure 2 , a dispenser according to the invention; - the
figure 2 is a II-II section of thefigure 1 ; - the
figure 3 is a view similar to thefigure 1 showing the device during the dispensing of a dose of product; - the
figure 4 illustrates the filling of the device.
Le distributeur de produit liquide ou pâteux 11, tel que représenté comprend un corps creux 14, globalement cylindrique, comportant une extrémité ouverte 15 et une paroi d'extrémité 17, à l'opposé, munie d'un canal de sortie 18 constitué par un trou rectiligne axial traversant cette paroi 17. Un piston 20 est monté à déplacement étanche à l'intérieur du corps. Dans la suite de la description, toute mention d'une direction axiale ou d'un axe fait référence à l'axe général de symétrie YY' du distributeur, confondu avec celui du piston et du canal 18. Le piston et le corps définissent entre eux une chambre à volume variable 21 contenant le produit 22 à distribuer. Le distributeur comporte en outre une molette 24 montée en rotation par rapport au corps du côté de l'extrémité ouverte 15 de celui-ci. Le corps du distributeur comporte deux parties adjacentes longitudinalement de diamètres différents. Dans l'exemple, cette différence de diamètre est obtenue par une diminution d'épaisseur de paroi dudit corps sur un tronçon 25 de celui-ci partant de l'extrémité ouverte. La molette 24 qui a ici une forme globalement cylindrique est montée dans la partie amincie du corps du distributeur, en sorte que sa paroi latérale extérieure 26 se situe globalement dans le prolongement de la paroi latérale extérieure 27 du reste du corps 14. Le piston 20 est pourvu d'une jupe creuse 30 filetée intérieurement, (filetage 31). La molette comporte une partie cylindrique interne 32 engagée dans la jupe creuse 30 du piston. La partie cylindrique interne de la molette est filetée extérieurement (filetage 33) et est vissée dans la jupe creuse. La molette 24 et le corps sont immobilisés en translation axiale l'un par rapport à l'autre, par un ensemble jonc-gorge. Dans l'exemple, le jonc 34 est défini sur la face interne d'une jupe extérieure constituant la molette, tandis que la gorge 35 est définie sur une partie cylindrique du corps, au voisinage de l'extrémité ouverte 15 de celui-ci. En outre, un agencement de blocage en rotation 38 est défini entre ledit corps et ledit piston. Dans l'exemple représenté, l'agencement de blocage en rotation comporte au moins une et de préférence plusieurs nervures 40 s'étendant parallèlement à l'axe longitudinal du dispositif et définies à la face interne dudit corps 14. Par ailleurs, le piston 20 est réalisé dans un matériau plastique relativement souple en sorte que les nervures 40 y impriment leurs empreintes pour empêcher la rotation du piston par rapport audit corps. Il n'est donc pas nécessaire de prévoir, par moulage, des gorges à la surface de la paroi cylindrique extérieure du piston, compte tenu du matériau mou utilisé pour constituer celui-ci ; le montage du piston s'en trouve facilité. L'extrémité du piston 20 située du côté de la chambre 21 est conformé avec une lèvre périphérique d'étanchéité 42 en contact étanche et « raclant » avec la paroi cylindrique intérieure du corps. Les nervures 40 sont pratiquées dans une portion interne de diamètre élargi du corps, jouxtant la partie à paroi lisse qui définit la chambre 21, en sorte que lesdites nervures ne peuvent entrer en contact avec la lèvre d'étanchéité définie à la périphérie de la face active du piston, au moment du montage du piston. La jupe 30 du piston comporte elle-même une portion 42 de moindre section s'étendant sur une distance au moins égale à la course du piston, entre la lèvre 42 et une portion 44 de forte section coopérant avec les nervures 40.The liquid or
Tel qu'il vient d'être défini jusqu'à présent, le distributeur permet de doser au moins approximativement la quantité de produit prélevé à chaque usage, notamment si on prend soin d'inscrire des graduations le long de deux lignes circulaires voisines portées respectivement par le corps et la molette. En effet, il est clair que la quantité de produit expulsé dépend directement de l'angle dont on fait tourner la molette par rapport au corps.As it has been defined so far, the dispenser makes it possible to measure at least approximately the quantity of product taken with each use, especially if care is taken to inscribe graduations along two neighboring circular lines worn. respectively by the body and the wheel. Indeed, it is clear that the amount of product expelled depends directly on the angle that is rotated the wheel relative to the body.
Néanmoins, pour que le dosage soit plus précis, des moyens de blocage anti-retour 46 sont définis entre la molette 24 et le corps 14, pour imposer une rotation en sens unique, de la molette par rapport audit corps.Nevertheless, for the dosage to be more accurate, anti-return blocking means 46 are defined between the
Dans l'exemple représenté, la molette et le corps sont réalisés en matériaux plastiques relativement déformables. Dans ces conditions, selon un mode de réalisation avantageux, lesdits moyens de blocage anti-retour 46 consistent en des nervures de crantage, à profil de dents de scie 48,49 opposées, face à face, définies respectivement sur deux parties globalement cylindriques en regard du corps et de la molette. Comme cela est bien visible sur la
En outre, la partie centrale de la face active 50 du piston 20 est évidée et conformée avec une lèvre intérieure 52 en contact étanche avec la paroi latérale cylindrique d'un pointeau 54 monté axialement dans le distributeur, dans l'alignement de l'orifice interne du canal de sortie 18. Le pointeau est sollicité élastiquement vers le canal de sortie. Son extrémité est conformée et dimensionnée pour s'engager dans ledit canal de sortie. Dans l'exemple, le canal de sortie 18 se résume à un trou rectiligne axial de faible longueur traversant la paroi d'extrémité du corps, ledit pointeau comporte une portion d'extrémité 56 conformée et dimensionnée pour obturer ledit trou sensiblement jusqu'à la face externe 57 de la paroi d'extrémité du corps. Dans l'exemple, la portion d'extrémité 56 est cylindrique. On obtient ainsi une fermeture complète du distributeur dite « de toute extrémité » empêchant tout séchage de produit résiduel. De plus, le pointeau présente une réduction de section dans la chambre, c'est à dire une diminution de diamètre entre la partie cylindrique contre laquelle coulisse le piston et celle 56 qui ferme le canal de sortie. De cette façon, une augmentation de pression dans la chambre 21 se traduit par une force axiale sur le pointeau 54 tendant à l'éloigner de la paroi d'extrémité du corps. Par ailleurs, un ressort 60 est installé en précompression dans la jupe creuse du piston entre un épaulement du pointeau et la molette 24. L'extrémité du pointeau opposée à celle qui commande le canal de sortie s'engage et coulisse dans un trou central 62 du fond 63 de la molette qui obture l'extrémité ouverte 15 du corps.In addition, the central portion of the active face 50 of the
Le fonctionnement du dispositif tel que décrit jusqu'à présent est des plus simples. Lorsque l'utilisateur désire extraire une certaine quantité de produit, il lui suffit de tourner la molette 24 par rapport au corps 14 dans le seul sens autorisé. Le piston étant immobilisé en rotation dans le corps, et la molette étant liée au piston par filetage, il en résulte un déplacement axial du piston strictement proportionnel à l'angle de rotation de la molette. Si on suppose que la chambre est entièrement remplie de produit, sans inclusion d'air, l'actionnement du piston engendre immédiatement une augmentation de pression dans ladite chambre 21 qui se traduit, compte tenu de la forme du pointeau, par un retrait axial de celui-ci, libérant le conduit de sortie 18. Par conséquent, une dose prédéterminée de produit (
Comme représenté sur le dessin, le corps 14 et la molette 24 sont avantageusement deux éléments globalement cylindriques et agencés dans le prolongement l'un de l'autre de façon à former une unité globalement cylindrique. Le distributeur tel que décrit peut constituer une entité fonctionnelle standardisée, constituant une sorte de « moteur » apte à recevoir un habillage dont la forme est représentative du produit proposé. Par exemple, cet habillage peut être constitué de deux parties, l'une recouvrant essentiellement le corps et l'autre la molette, ces deux parties ayant une configuration non obligatoirement cylindrique. On pourra choisir un habillage présentant des facettes parallèles à l'axe de rotation et définissant, en section, un contour polygonal. Une telle forme permet en soi un dosage visuel (même en l'absence de nervures de crantage entre le corps et la molette) par le simple fait qu'une rotation entre deux positions où les faces latérales du corps et de la molette viennent dans le prolongement l'une de l'autre est en soi une indication de dosage. Dans ce contexte, il est aussi possible de prévoir un encliquetage unidirectionnel inverse entre la molette et son propre habillage pour permettre un retour en arrière et un alignement des faces latérales après utilisation, sans entraîner, bien entendu, un quelconque retrait du piston.As shown in the drawing, the
Revenant sur la structure du distributeur 11 en tant que tel, il est à noter que le pointeau 54 se prête avantageusement à l'évacuation de l'air au moment du remplissage de la chambre. En effet, le distributeur doit être rempli en positionnant le piston de façon que la chambre 21 ait son volume maximum, comme représenté sur la
La
Claims (16)
- A liquid or pasty product dispenser comprising a hollow body (14) and a piston (20) sealingly mounted to move therein and delimiting with said body a chamber (21) for the product to be dispensed, an output channel (18) being defined in an end wall of said body, a knurl (24) being mounted to rotate with respect to said body, at one end thereof, characterized in that a rotation locking arrangement (38) is defined between said body and said piston, in that said piston is provided with an internally threaded hollow skirt (30), in that said knurl includes an internal cylindrical portion (32) engaged in said hollow skirt and in that said cylindrical portion is externally threaded and screwed into said hollow skirt.
- A dispenser according to claim 1, characterized in that it includes means for measuring the quantity of the extracted product.
- A dispenser according to claim 1 or 2, characterized in that said check locking means (46) are defined between the knurl and the body to rotate the knurl in only one direction with respect to said body.
- A dispenser according to claim 3, characterized in that said knurl (24) and/or said body (14) being made in a relatively deformable plastic material, said check locking means (46) include saw-tooth ribs (48, 49) defined on substantially cylindrical portions facing said body and said knurl and imbricated into one another.
- A dispenser according to any one of the preceding claims, characterized in that said knurl (24) and said body (14) are immobilized in translation with respect to each other by a snap ring-groove assembly, said snap ring (34) and said groove (35) being defined on two substantially cylindrical portions facing the body and the knurl.
- A dispenser according to one of the preceding claims, characterized in that said rotation locking arrangement includes at least one rib (40) defined on the inner face of said body and extending parallel to the moving axis of said piston.
- A dispenser according to claim 6, characterized in that said ribs are provided (40) in an inner portion of said body having an enlarged diameter.
- A dispenser according to claim 6 or 7, characterized in that said piston (20) is made of a relatively flexible plastic material, so that the or each rib of said body prints its print therein to ascertain the immobilization, in rotation, of said piston with respect to said body.
- A dispenser according to one of the preceding claims, characterized in that a needle (54) is slidingly sealed through said piston, being aligned with the inner orifice of said output channel, in that it is resiliently pulled towards said output channel and in that the end of said needle (56) is so formed and sized as to engage in and seal said output channel.
- A dispenser according to claim 9, characterized in that said output channel (18) is composed of a rectilinear axial hole going through said end wall and in that said needle (54) includes an end portion so formed and sized as to seal said hole substantially up to the outer face (57) of said end wall of said body.
- A dispenser according to claim 10, characterized in that said needle (54) has a reduced section in said chamber.
- A dispenser according to one of claims 9 to 11, characterized in that a spring (60) is fitted in a previously compressed condition in said hollow skirt, between a shoulder of said needle (54) and said knurl (24).
- A dispenser according to one of claims 9 to 12, characterized in that a sealable air discharge channel (65) is defined in said needle (54) for filling the chamber.
- A device according to claim 13, characterized in that said air discharge channel includes an axial segment (68) opening behind the needle and in that a plug (66) is engaged from the back into such axial segment.
- A dispenser according to one of the preceding claims, characterized in that said body and said knurl (24) are two substantially cylindrical elements arranged one being the extension of the other.
- A method for filling a dispenser according to any one of claims 13 or 124, characterized in that it consists, with the volume of the chamber being at its maximum, in keeping (81) said air discharge channel in communication with the atmosphere, in filling said chamber (21) by injecting pressurized product through said output channel and in capping (66) the air discharge channel when said chamber is full.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0211417A FR2844506B1 (en) | 2002-09-13 | 2002-09-13 | DISPENSER OF LIQUID OR PASTY PRODUCT |
FR0211417 | 2002-09-13 | ||
PCT/FR2003/002699 WO2004024592A1 (en) | 2002-09-13 | 2003-09-12 | Dispenser for liquid or pasty product |
Publications (2)
Publication Number | Publication Date |
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EP1549566A1 EP1549566A1 (en) | 2005-07-06 |
EP1549566B1 true EP1549566B1 (en) | 2008-10-29 |
Family
ID=31897392
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03795043A Revoked EP1549566B1 (en) | 2002-09-13 | 2003-09-12 | Dispenser for liquid or pasty product |
Country Status (13)
Country | Link |
---|---|
US (1) | US7325707B2 (en) |
EP (1) | EP1549566B1 (en) |
JP (1) | JP2005538002A (en) |
CN (1) | CN100411957C (en) |
AT (1) | ATE412590T1 (en) |
AU (1) | AU2003276331A1 (en) |
BR (1) | BR0314432A (en) |
CA (1) | CA2498744A1 (en) |
DE (1) | DE60324445D1 (en) |
ES (1) | ES2315564T3 (en) |
FR (1) | FR2844506B1 (en) |
MX (1) | MXPA05002759A (en) |
WO (1) | WO2004024592A1 (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2646350B1 (en) * | 1989-04-28 | 1991-06-28 | Adir | NOVEL BENZOTHIAZOLINON DERIVATIVES, THEIR PREPARATION PROCESS AND THE PHARMACEUTICAL COMPOSITIONS CONTAINING THE SAME |
FR2857652B1 (en) * | 2003-07-15 | 2008-10-31 | Rexam Dispensing Sys | FLAP TIP FOR DISTRIBUTOR OF LIQUID COSMETIC PRODUCTS |
CN1953914B (en) * | 2004-05-06 | 2010-06-16 | 雷克斯姆分配Smt公司 | Closure device for a non-vented liquid product dispenser |
US8517225B2 (en) * | 2007-11-19 | 2013-08-27 | Elc Management, Llc | Rotary actuated lotion pump |
WO2010081205A2 (en) * | 2009-01-15 | 2010-07-22 | Victor Esteve | Packaging element with a hermetically sealed dosing mechanism for semi-solid products |
GB2472412A (en) * | 2009-08-05 | 2011-02-09 | Twistub Ltd | Dispenser for viscous fluid |
US20110127299A1 (en) * | 2009-12-01 | 2011-06-02 | Daniel Jeffery Calkins | Dispenser for spreadable food |
KR101473539B1 (en) | 2009-12-23 | 2014-12-16 | 콜게이트-파아므올리브캄파니 | Oral care system |
DE102010045935B4 (en) * | 2010-09-21 | 2014-07-17 | Heraeus Kulzer Gmbh | Container, container system, method for applying a pasty mass from this container and method for mixing a plurality of masses from this container |
FR2969935B1 (en) | 2011-01-03 | 2013-12-27 | Cinqpats | PACKAGING, DISTRIBUTION, APPLICATION OF PASTA LIQUID CONSISTENCY CONTENT. |
US8545121B2 (en) | 2011-11-02 | 2013-10-01 | Avon Products, Inc. | Dispensing mechanism assembly |
FR3017277B1 (en) * | 2014-02-07 | 2016-02-12 | Albea Le Treport | SYSTEM FOR DISPENSING A CONDITIONED FLUID PRODUCT IN A BOTTLE |
US8827115B1 (en) * | 2014-04-07 | 2014-09-09 | Victor Katz | Container for storing, measuring and dispensing a liquid |
CN105537063A (en) * | 2016-01-22 | 2016-05-04 | 奉化市威优特电器有限公司 | Photo-curing glue splicer |
WO2017182972A1 (en) * | 2016-04-19 | 2017-10-26 | Flexidose | Dosing dispenser |
EP3565627A4 (en) | 2017-01-04 | 2021-01-13 | Reflex Medical Corporation | Metered dose topical applicator |
CN107082182B (en) * | 2017-06-09 | 2019-01-22 | 中山市意创科技研发有限公司 | A kind of single-chamber dosing container |
KR102344584B1 (en) * | 2017-06-27 | 2021-12-31 | 게르하르트 브뤼거 | dispensing vessel |
USD848611S1 (en) | 2018-01-24 | 2019-05-14 | Reflex Medical Corp. | Metered dose topical applicator |
US11382400B2 (en) | 2018-08-10 | 2022-07-12 | Go Products Co. | Material applicator |
RU2721360C1 (en) * | 2019-05-13 | 2020-05-19 | Владимир Васильевич Чернявец | Device for sealing of defects of shells of spacecrafts |
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US2738905A (en) * | 1950-11-10 | 1956-03-20 | Carl E Olson | Paste or like dispenser |
US2926818A (en) * | 1958-07-14 | 1960-03-01 | John J Spero | Dispenser for dispensing a plurality of materials |
DE1934416A1 (en) * | 1968-07-10 | 1970-01-08 | Albert Simoen | packaging |
FR2670755B1 (en) * | 1990-12-24 | 1995-03-03 | Sopiel | CONTAINER FOR DISPENSING LIQUID OR CREAMY MATERIALS. |
DE9320087U1 (en) * | 1993-12-29 | 1994-02-17 | Maag, Hans-Jürgen, Dipl.-Ing., 56072 Koblenz | Apparatus for the production of aerosols |
US5524795A (en) * | 1994-04-14 | 1996-06-11 | Lee; Gary K. | Dispensing unit for a threaded neck bottle |
CN2217594Y (en) * | 1995-02-15 | 1996-01-17 | 马爱和 | Internal-extruding type paste container |
IT1317276B1 (en) * | 2000-04-18 | 2003-05-27 | Laffon Spa | CONTAINMENT AND DISPENSING DEVICE FOR COSMETIC LIQUID PRODUCTS |
CN2467432Y (en) * | 2000-12-21 | 2001-12-26 | 高航 | Rotational shear squeezing package tube |
-
2002
- 2002-09-13 FR FR0211417A patent/FR2844506B1/en not_active Expired - Fee Related
-
2003
- 2003-09-12 AT AT03795043T patent/ATE412590T1/en not_active IP Right Cessation
- 2003-09-12 MX MXPA05002759A patent/MXPA05002759A/en unknown
- 2003-09-12 CN CNB038217708A patent/CN100411957C/en not_active Expired - Fee Related
- 2003-09-12 AU AU2003276331A patent/AU2003276331A1/en not_active Abandoned
- 2003-09-12 BR BR0314432-1A patent/BR0314432A/en not_active IP Right Cessation
- 2003-09-12 DE DE60324445T patent/DE60324445D1/en not_active Expired - Lifetime
- 2003-09-12 WO PCT/FR2003/002699 patent/WO2004024592A1/en active Application Filing
- 2003-09-12 ES ES03795043T patent/ES2315564T3/en not_active Expired - Lifetime
- 2003-09-12 CA CA002498744A patent/CA2498744A1/en not_active Abandoned
- 2003-09-12 EP EP03795043A patent/EP1549566B1/en not_active Revoked
- 2003-09-12 JP JP2004535603A patent/JP2005538002A/en active Pending
-
2005
- 2005-03-22 US US11/086,086 patent/US7325707B2/en not_active Expired - Fee Related
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AU2003276331A1 (en) | 2004-04-30 |
US7325707B2 (en) | 2008-02-05 |
US20050242127A1 (en) | 2005-11-03 |
FR2844506A1 (en) | 2004-03-19 |
WO2004024592A1 (en) | 2004-03-25 |
EP1549566A1 (en) | 2005-07-06 |
DE60324445D1 (en) | 2008-12-11 |
BR0314432A (en) | 2005-07-19 |
FR2844506B1 (en) | 2004-12-10 |
CN100411957C (en) | 2008-08-20 |
ATE412590T1 (en) | 2008-11-15 |
ES2315564T3 (en) | 2009-04-01 |
MXPA05002759A (en) | 2005-06-03 |
CN1681720A (en) | 2005-10-12 |
CA2498744A1 (en) | 2004-03-25 |
JP2005538002A (en) | 2005-12-15 |
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