EP1530608B1 - Bouchon en plastique mousse thermoplastique - Google Patents
Bouchon en plastique mousse thermoplastique Download PDFInfo
- Publication number
- EP1530608B1 EP1530608B1 EP03763498A EP03763498A EP1530608B1 EP 1530608 B1 EP1530608 B1 EP 1530608B1 EP 03763498 A EP03763498 A EP 03763498A EP 03763498 A EP03763498 A EP 03763498A EP 1530608 B1 EP1530608 B1 EP 1530608B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cork
- foamed
- laser beam
- laser
- stopper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001169 thermoplastic Polymers 0.000 title description 2
- 239000004416 thermosoftening plastic Substances 0.000 title description 2
- 229920002994 synthetic fiber Polymers 0.000 title 1
- 239000007799 cork Substances 0.000 claims description 22
- 239000000049 pigment Substances 0.000 claims description 15
- 239000004033 plastic Substances 0.000 claims description 12
- 229920003023 plastic Polymers 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 239000012815 thermoplastic material Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000013532 brandy Nutrition 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 235000014101 wine Nutrition 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 241001124569 Lycaenidae Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 235000014987 copper Nutrition 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 229920006249 styrenic copolymer Polymers 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D39/00—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers
- B65D39/0005—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers made in one piece
- B65D39/0011—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers made in one piece from natural or synthetic cork, e.g. for wine bottles or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/28—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating
- B41M5/282—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using thermochromic compounds or layers containing liquid crystals, microcapsules, bleachable dyes or heat- decomposable compounds, e.g. gas- liberating using thermochromic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
- B44C1/228—Removing surface-material, e.g. by engraving, by etching by laser radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D51/00—Closures not otherwise provided for
- B65D51/24—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes
- B65D51/245—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes provided with decoration, information or contents indicating devices, labels
Definitions
- the invention relates to a method for producing a plug of foamed, thermoplastic material, which is provided with a cork fire.
- foamed polyethylene is almost exclusively suitable for the slug; the production of the cork brandy is similar to that of the original cork brandy in a cork cork by heat, but the discoloration can not be achieved by partial charring of the cork material. but only by the discoloration of inorganic, food grade pigments that change their color when exposed to heat.
- the pigment Iriodin® that is, pearlescent pigments based on mica and titanium oxide or iron (III) oxide, has prevailed, although this material is expressly not mentioned in the abovementioned EP 1 022 226 A. becomes.
- EP 0 754 562 A deals with the labeling of mold plates, films and the like. From polyolefins using lasers and the mica pigments, explicitly that under the name Iriodin®, disclosed as thermally discolourable pigments.
- the laser beam used is not focused on the surface of the prog, but is used defocused, whereby a larger area is hit with lower energy density than the focused beam.
- the focal point lies in a plane, viewed in the direction of the laser beam, in front of the surface of the prog. This lower density makes it possible to use the laser with a lower sweep frequency than is usual in focused operation, whereby, viewed integrated over time, the sum of the energy supply obtained at each location of the total is at least approximately the same as in the conventional one.
- the process according to the invention was used with a polyethylene graft (available from Borealis) mixed with paint, blowing agent and the discolourable pigment (laser patch) (all from Gabriel Chemie) and in one Injection molding machine after stepwise heating to 185 ° C (fluctuation ⁇ 3 ° C) is injected into the mold.
- the injected amount, actually mass, depends on the desired plug volume, in fact on the desired plug length, values of 8.5 g are usual for medium-length plugs.
- the cooling of the wall of the mold is significant, since at a cooling water temperature of about 12 ° C, an "outer skin" of the graft arises, in which the density of the graft is 5 to 10 times as high as in its interior.
- outer skin This formation of a different outer region in terms of its properties from the properties in the core of the graft, hereinafter referred to as "outer skin", is essential both for the sealing properties of the graft and for its visual appearance, but this is already known and is well known in the art from the professional in the field of injection molding of foamed plastics, in particular of foamed polyethylene.
- the cooling time of the prick depends on the type and amount of propellant gas used, it is essential that after ejection from the mold no abrading of the product takes place, as this would affect the dimensions and the quality of the outer skin.
- a graft made in this way is now laser-engraved with a lamp-pumped 30 watt YAG laser with a 254 mm objective focusing the laser beam at a distance of 410 mm from the object.
- the speed is set to 700 to 900 mm / sec. This speed is the superposition of the wobble motion and the forward motion.
- a QS frequency frequency of how often one of the beam per minute or off
- a lamp current 25 to 30 amps were, as the distance between the Surface of the plugs not kept the 410 mm to the focal point, but 420 mm, and kept the sweep frequency at 200 to 500 hertz.
- Line widths in the typeface between 0.1 and 0.5 mm were lasered (wider lines are easily reached) and the resulting cork firing on the one hand was optically flawless and on the other hand without affecting the smooth surface.
- the plug was guided in the focal distance of 410 mm and the sweep frequency was varied between 200 and 600 hertz. Depending on the frequency of sweeping, the resulting cork fire had either a rough to molten surface or was unsuitable for insufficient discoloration of the pigment.
- an endless rod made of polyethylene with a polymer film (in the experiment polyethylene, but polyurethane is also possible, necessary is the food suitability or adapting to the application of the plug) is surrounded by coextrusion, the pigment iriodin only in this film area was contained along the mantle.
- the laser energy was reduced to 15 watts and the sweep frequency to 280 hertz.
- the invention is not limited to the illustrated examples, but may be modified variously. These modifications relate both to the composition of the graft and the manner of its preparation on the one hand and the laser devices used on the other hand. It is essential that, according to the finding that the foamed plastic behaves differently with respect to the laser irradiation, light is visible or invisible, than the same plastic in the unfoamed, potted state and therefore that according to the invention the laser is used defocused, that is the surface to be lasered is located before or, preferably, behind the point at which the laser beam is to be regarded as focused. In order to compensate for the reduction in the specific energy (based on the surface area) and to supply the pigments with sufficient energy for color change, the sweep frequency is correspondingly reduced so that ultimately the same energy is supplied as usual but in a "gentler" form.
- the basic idea of the invention is that in order to avoid damage to the thin plastic pellicles, the energy required for color change of the pigments is applied in a lower density for a longer period of time.
- the energy required for color change of the pigments is applied in a lower density for a longer period of time.
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Closures For Containers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (4)
- Procédé d'application d'une marque sur un bouchon en matière synthétique thermoplastique expansée, dans auquel un rayon laser va modifier la couleur de pigments colorables thermiquement, caractérisé en ce que le point focal du rayon laser utilisé se trouve dans un plan différent de celui de la surface du bouchon.
- Procédé selon la revendication 1, caractérisé en ce que le point focal se trouve dans un plan situe devant la surface du bouchon regardé en direction du rayon laser.
- Procédé selon la revendication 1 ou 2, caractérisé en ce que la fréquence vobulée est plus petite que la fréquence vobulée pour la même matière synthétique, mais non expansée.
- Procédé selon la revendication 3, caractérisé en ce que l'énergie imprimée avec le laser sur une zone donnée de marque, intégrée sur le temps de la laserisation, correspond pour l'essentiel ä l'énergie imprimée sur la même matière synthétique sous forme non expansée.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI200330323T SI1530608T1 (sl) | 2002-07-17 | 2003-07-02 | Zamasek iz penaste termoplasticne umetne snovi |
| AT03763498T ATE321807T1 (de) | 2002-07-17 | 2003-07-02 | Propfen aus geschaeumtem, thermoplastischen kunststoff |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT10792002 | 2002-07-17 | ||
| AT0107902A AT412710B (de) | 2002-07-17 | 2002-07-17 | Pfropfen aus geschäumtem, thermoplastischen kunststoff |
| PCT/AT2003/000185 WO2004007599A1 (fr) | 2002-07-17 | 2003-07-02 | Bouchon en plastique mousse thermoplastique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1530608A1 EP1530608A1 (fr) | 2005-05-18 |
| EP1530608B1 true EP1530608B1 (fr) | 2006-03-29 |
Family
ID=30120910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP03763498A Expired - Lifetime EP1530608B1 (fr) | 2002-07-17 | 2003-07-02 | Bouchon en plastique mousse thermoplastique |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20050253306A1 (fr) |
| EP (1) | EP1530608B1 (fr) |
| AT (1) | AT412710B (fr) |
| AU (1) | AU2003243796B2 (fr) |
| CY (1) | CY1105056T1 (fr) |
| DE (1) | DE50302831D1 (fr) |
| ES (1) | ES2264773T3 (fr) |
| PT (1) | PT1530608E (fr) |
| WO (1) | WO2004007599A1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20042454A1 (it) * | 2004-12-22 | 2005-03-22 | Guizzardi Maria Morena | Metodo per la marchiatura di tappi sintetici dispositivo per realizzare detto metodo e tappo sintetico |
| BE1016664A3 (nl) * | 2005-06-30 | 2007-04-03 | Indurub Nv | Werkwijze en inrichting voor het vervaardigen van kurken uit kunststof. |
| ES2336987B1 (es) | 2007-12-31 | 2011-03-22 | ON-LASER SYSTEMS & APPLICATIONS, S.L. | Procedimiento y dispositivo de marcaje rotativo. |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4143258A1 (de) * | 1991-12-31 | 1993-07-01 | Hoechst Ag | Laserbeschriftbare kunststoff-formmasse, verfahren zu ihrer herstellung und verwendung |
| DE19525960A1 (de) * | 1995-07-17 | 1997-01-23 | Quarzwerke Gmbh | Polyolefin zur Laserbeschriftung, laserbeschriftete Formkörper und Verfahren zu ihrer Herstellung |
| US6075223A (en) * | 1997-09-08 | 2000-06-13 | Thermark, Llc | High contrast surface marking |
| EP0947352A1 (fr) * | 1998-04-03 | 1999-10-06 | Tetra Laval Holdings & Finance Sa | Méthode pour imprimer sur un dispositif de fermeture et méthode pour la fabrication d'un dispositif de fermeture pour l'impression par laser |
| AT406476B (de) * | 1999-01-25 | 2000-05-25 | P1 Handels Gmbh | Pfropfen aus geschäumtem thermoplastischem kunststoff |
| US6780497B1 (en) * | 1999-08-05 | 2004-08-24 | Gore Enterprise Holdings, Inc. | Surface modified expanded polytetrafluoroethylene devices and methods of producing the same |
| AU2001276669B2 (en) * | 2001-01-16 | 2006-04-27 | Ardea Seal S.A.S. | Closure in synthetic material for containers |
-
2002
- 2002-07-17 AT AT0107902A patent/AT412710B/de not_active IP Right Cessation
-
2003
- 2003-07-02 EP EP03763498A patent/EP1530608B1/fr not_active Expired - Lifetime
- 2003-07-02 PT PT03763498T patent/PT1530608E/pt unknown
- 2003-07-02 DE DE50302831T patent/DE50302831D1/de not_active Expired - Fee Related
- 2003-07-02 ES ES03763498T patent/ES2264773T3/es not_active Expired - Lifetime
- 2003-07-02 WO PCT/AT2003/000185 patent/WO2004007599A1/fr not_active Ceased
- 2003-07-02 US US10/521,969 patent/US20050253306A1/en not_active Abandoned
- 2003-07-02 AU AU2003243796A patent/AU2003243796B2/en not_active Ceased
-
2006
- 2006-06-26 CY CY20061100860T patent/CY1105056T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1530608A1 (fr) | 2005-05-18 |
| US20050253306A1 (en) | 2005-11-17 |
| ES2264773T3 (es) | 2007-01-16 |
| AT412710B (de) | 2005-06-27 |
| PT1530608E (pt) | 2006-08-31 |
| WO2004007599A1 (fr) | 2004-01-22 |
| ATA10792002A (de) | 2004-11-15 |
| AU2003243796B2 (en) | 2007-08-16 |
| CY1105056T1 (el) | 2010-03-03 |
| DE50302831D1 (de) | 2006-05-18 |
| AU2003243796A1 (en) | 2004-02-02 |
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