EP1516829A1 - Tête de pulvérisation pour aérosol - Google Patents
Tête de pulvérisation pour aérosol Download PDFInfo
- Publication number
- EP1516829A1 EP1516829A1 EP04021267A EP04021267A EP1516829A1 EP 1516829 A1 EP1516829 A1 EP 1516829A1 EP 04021267 A EP04021267 A EP 04021267A EP 04021267 A EP04021267 A EP 04021267A EP 1516829 A1 EP1516829 A1 EP 1516829A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- spray head
- capillary
- head according
- fluid
- fluid outlet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007921 spray Substances 0.000 title claims abstract description 119
- 239000000443 aerosol Substances 0.000 title claims abstract description 39
- 239000012530 fluid Substances 0.000 claims abstract description 73
- 238000005507 spraying Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000005755 formation reaction Methods 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000881 depressing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/16—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means
- B65D83/20—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means operated by manual action, e.g. button-type actuator or actuator caps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
- B65D83/753—Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by details or accessories associated with outlets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/16—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means
Definitions
- the invention relates to a spray head for an aerosol container with the Features of the preamble of claim 1.
- the known spray head from which the invention proceeds (WO 03/051522 A2), has the special feature that the spraying of the fluid takes place nozzle-free.
- the fluid is under high pressure in a capillary with very little Diameter introduced and passed in the capillary to an outlet end and sprayed from there nozzle-free. It is essential that the use of a Capillary for this form of spraying a liquid causes the Fluid also low in solvents and thus in subjective sensation "dry” can be sprayed.
- This novel spraying low-solvent Liquid is now referred to as "LoFlo". Characteristic This is not only because the liquid that is sprayed, low in solvents is sprayed, but that the spraying with relatively little Propellant gas can be made.
- Spray heads for aerosol cans have been in an unmanageable way for decades Abundance of embodiments known, among which only a few examples to mention are (EP 0 409 497 A1, US 5,388,730 A, US 3,848,778 A).
- In classic spray heads is a non-acting as a capillary Tubes for transporting the liquid to be sprayed in the spray head.
- a spray nozzle At the At the end of this tube is a spray nozzle, which is the way the spraying of the liquid causes.
- the pressure build-up for the spraying of the liquid at the nozzle retroactively so in the tube.
- the fluid dynamic relationships here are completely different than at the spray head with a capillary for nozzle-free spraying of the fluid, from which the invention proceeds.
- a spray head for an aerosol container with an untypical is known Fluid outlet valve (US 2,592,808 A).
- the fluid outlet valve is part of Spray head.
- This spray head itself has a down to the fluid container into reaching dip tube, in which a capillary far into the Fluid tank extends into it.
- the capillary itself puts together with a Sliding the fluid outlet valve.
- the spray head is the capillary from Entry end to the outlet end in an arc of about 90 ° running arranged, wherein the sheet course by interlocking outer and Internal guides is guaranteed.
- This construction is in total for aerosol containers not suitable with conventional fluid outlet valves.
- the spray head itself provides the guidance to the capillary, which in itself has an elongated, straight shape, in the necessary Arc for realizing the correct orientation of the exit end of the To force capillary.
- the spray head is an independent component, the in a conventional female fluid outlet valve in a valve lifter terminates, in which the capillary extends, in a conventional male Fluid outlet valve ends in a receptacle into which the capillary extends.
- the capillary is made in one piece as mentioned in claim 12.
- the invention also relates to an aerosol container with a fluid container and a top side attached thereto and closing the fluid container Fluid outlet valve and with a mounted on the fluid container Spray head with the characteristics of one or more of the Sprayer head claims.
- Spray head 1 is intended for placement on an aerosol container and suitable. Such is indicated for example in Fig. 3 with. Otherwise there the state of the art here a wealth of suggestions.
- the aerosol container has a fluid outlet valve 3, which has an axial fluid outlet direction A defines.
- a conventional fluid outlet valve 3 either a conventional female fluid outlet valve 3 with a receptacle for a valve lifter, which is then arranged on the spray head 1 is, or a male fluid outlet valve 3 with a valve lifter, the one Recording is assigned to the spray head. Also for it may on the state of the Reference may be made, in particular WO 03/051522 A2, US Pat 3,848,778 A for a conventional male fluid outlet valve 3 and for example DE 201 16 335 U1 for a conventional female fluid outlet valve.
- Such a spray head is used for spraying a liquid, preferred here a solvent-poor liquid and sets to a capillary 4 to Guiding and nozzle-free spraying of the liquid - the fluid - a.
- the inlet end 5 of the capillary 4 closes when placed on the aerosol container 2
- Spray head 1 axially against the fluid outlet valve 3.
- the fluid outlet valve 3 opens and fluid enters the capillary 4 under high pressure its inlet end 5, then flows at low pressure, the pressure drop when entering is relevant, in the capillary 4, builds in a corresponding Flow course and finally occurs at the outlet end of the 6 Capillary 4 as a spray of finely divided droplets of selectable droplet size and size distribution.
- WO 03/051522 A2 may for the explanation of here pending phenomena are referred to WO 03/051522 A2.
- the arc 7 of the capillary 4 is about 90 °, in the illustrated embodiment exactly 90 °, in the embodiment of Fig. 3 is slightly less than 90 °.
- the spray head 1 provides the means, the capillary 4 in this sheet 7, which is otherwise stretched by itself, just wants to have or take shape.
- the arc shape of the capillary 4 in the spray head 1 can be on different Realize ways. This becomes the individual embodiments explained in more detail.
- the material of the spray head 1 choose plastic material like that from practice for spray heads in the speech standing species has long been known. Furthermore, it is recommended that the Capillary 4 from a feasible in an arc 7 material, in particular Metal, or, preferably and so also predominantly provided, from Produce plastic. It should be taken into account, what the beginning of the Pressure reduction before the capillary 4 has been explained. In the capillary 4 itself There is no excessively high pressure, so that an execution of the Capillary 4 plastic is practically possible without further notice.
- the length of the Capillary 4 is in some connection to the inner diameter the capillary 4 and should be about 10 mm to about 100 mm, preferably about 25 mm to about 50 mm.
- Typical of the course in a usual Spray head is a length of the capillary 4 of about 30 mm to about 40 mm.
- a spray head 1 for a female fluid outlet valve 3 on the aerosol container 2 shown in Fig. 1 on the - indicated - Aerosol container 2 snap-on lower part 8, on the other hand, a limited movable Upper part 9, which is latched onto the lower part 8 of the spray head 1, and the Capillary 4, the top of the inlet end 5 in the lower part 8, and there via a considerable distance, and at the outlet end 6 between the lower part 8 and the upper part 9 of the spray head 1 is held, but in between the bow. 7 exposed.
- the capillary 4 in the embodiment shown in Fig. 1 at the outlet end 6 brought into their holding position and fixed there.
- Both parts of the spray head 1 are made of plastic and are, as already explained, clipped together.
- Fig. 2 shows the same basic construction as in Fig. 1 with the same parts. The difference is only in that the capillary 4 is here in a spray head 1 for a male fluid outlet valve 3 is arranged with upwardly projecting stem valve.
- Fig. 3 shows a slightly different type of embodiment
- the first Spray head 1 can be detected attached to the aerosol container 2.
- a valve carrier 10 with a valve chamber 11 and a valve spring 12 disposed thereon
- the valve body 13 in Fig. 3 presses upwards in a closed position.
- a riser 14 is arranged, for example, via a not shown, there connectable dip tube in the liquid reservoir in the aerosol container 2 can dip.
- a passage 15 which is at slightly downwardly pressed valve body 13th can be associated with the inlet end 5 of the capillary 4.
- the capillary 4 itself is located with its inlet end 5 in a valve lifter 16, which is part of the spray head 1 in this embodiment.
- the embodiment shown here is characterized in that the Spray head 1 a the desired arc shape of the capillary 4 corresponding Outside guide 17 and that the sheet 7 of the capillary 4 at the Outside guide 17 is guided fitting.
- the spray head 1 It can be seen at the top of the spray head 1 left a bracket 18, in which the outlet end 6 of the capillary 4 just enters and is fixed there. Otherwise, will the arc 7 of the capillary 4 defined by the outer guide 17, the of the spray head 1 itself is specified.
- the spray head 1 is here in one piece Plastic designed and firmly connected to the valve stem 16. If the Spray head 1 is pushed all the way down against the aerosol container 2, the fluid outlet valve 3 opens and the spraying of the fluid takes place via the capillary 4.
- the outer guide 17 in the spray head 1 leads and bends the Capillary 4 in its desired arcuate orientation during the Spray head 1 placed on the aerosol container 2 and the valve stem 16 in the receiving socket 19 is inserted at the upper end of the valve carrier 10 becomes.
- the spray head 1 a the desired arc shape of the capillary 4 corresponding Inner guide 20 and the bow 7 of the capillary 4 on the inner guide 20 is guided fitting. This too leads to a controlled arcuate guidance of the capillary 4, which is thus not close to the entrance end 5 or the outlet end 6 uncontrollably kinks, which is the function would ruin.
- the spray head 1 forms an outer guide 17 and an inner guide 20th
- Fig. 4 shows another variant, the also to an outer guide 17 and an inner guide 20 for the capillary 4 leads.
- the spray head 1 is made in two parts and at the upper part 9, the outer guide 17 and at the lower part 8, the inner guide 20 has.
- Fig. 4 shows the composite spray head 1 of a such embodiment with the capillary 4.
- Fig. 4 shows the assembly including a guide rib 23.
- the entire spray head 1 is made in both parts 8, 9 made of plastic.
- FIG. 5 realized the arcuate guided Capillary 4 in a very different way than the previously described embodiments.
- the Spray head 1 is made in two parts and the two parts 25 half-shell-like trained and common to form outer guide 17 and inner guide 20 are interconnected.
- parts 8, 9, but certainly also the parts 25 of the spray head 1, if this is made of plastic is, via a hinge, in particular a film hinge, to each other connect and, in particular, as a piece, so in one piece mold manufacture.
- the capillary 4 here is made in several pieces, namely located in the valve stem 16 Part of the capillary 4 of the arcuately guided in the arc 7 part of the capillary 4 is disconnected. But especially preferred is here also a one-piece Execution of the capillary 4.
- the capillary 4, einstükkig extends or more pieces, up to the lower edge of the valve stem 16, the part of the spray head 1 is. This is an immediate transition from the fluid outlet valve 3 ensured in the capillary 4.
- Fig. 2 shows a variant which is characterized in that the spray head 1, a receptacle 26 for a valve stem 16 of a male Fluid outlet valve 3 and the capillary 4 up to the recording 26 extends.
- a male fluid outlet valve 3 has one upwards protruding, not shown in this drawing valve lifter.
- This is a typical embodiment of an aerosol container 2. With this configuration can the spray head 1 as a whole, if necessary, even attached to the aerosol container 2 be, namely by the recording 26 of the spray head 1 on the upwardly projecting valve stem of the fluid outlet valve 3 of the aerosol container 2 is attached.
- Such a spray head 1 can be quickly from the Remove the fluid outlet valve 3 of the aerosol container 2 and, for example against another spray head 1, maybe a capillary 4 with other Inner diameter, replace. That's in terms of this interchangeability more expedient than an attachment of the spray head 1 itself on the aerosol container 2 directly.
- the spray head 1 in any case in the region of the capillary. 4 made in one piece and the capillary 4 as a curved channel in the spray head 1 is integrally formed.
- the capillary 4 is an integral part of the spray head 1, so does not have to be provided as a separate component be.
- Fig. 6 to 9 show an embodiment, the above-mentioned idea picks up, but modifies.
- the spray head. 1 multi-part, preferably designed in two parts and the capillary 4 by sealingly intermeshing positively locking formations 27, 28 of the parts 8, 9 is integrally formed in the spray head 1.
- the form-locking education 27 am Lower part 8 is a form-fitting rib, the form-locking formation 28 on the upper part 9, as shown in FIG. 8 in section, a positive locking groove.
- FIG. 8 it is a capillary 4 of square cross-section
- FIG. 9 shows a variant, which leads to a total circular cross-section capillary 4. This too is particularly expediently feasible with a spray head 1, which is made of plastic.
- the invention is also an aerosol container 2, a conventional Fluid container 2 with a conventional, the top side attached and the Fluid container 2 occlusive, male or female fluid outlet valve 3 has. On the fluid container 2 sits a spray head 1, according to the previously explained in detail teaching of the invention is designed.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Nozzles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10343672A DE10343672A1 (de) | 2003-09-18 | 2003-09-18 | Sprühkopf für einen Aerosolbehälter |
DE10343672 | 2003-09-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1516829A1 true EP1516829A1 (fr) | 2005-03-23 |
EP1516829B1 EP1516829B1 (fr) | 2009-12-30 |
Family
ID=34177864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04021267A Active EP1516829B1 (fr) | 2003-09-18 | 2004-09-08 | Tête de pulvérisation pour aérosol |
Country Status (5)
Country | Link |
---|---|
US (1) | US9617064B2 (fr) |
EP (1) | EP1516829B1 (fr) |
AT (1) | ATE453587T1 (fr) |
DE (2) | DE10343672A1 (fr) |
ES (1) | ES2336102T3 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1619139A1 (fr) * | 2004-07-22 | 2006-01-25 | Lindal Ventil GmbH | Tête de distribution pour distributeur de produits fluide ou pasteuse |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1901631B1 (fr) * | 2005-06-16 | 2012-03-21 | Colgate-Palmolive Europe SARL | Antitranspirant à base d'eau et distributeur aérosol idoine |
US20080221561A1 (en) * | 2005-07-18 | 2008-09-11 | Jorg Geiger | Spray Device for Dispensing a Cooling Fluid |
ES2877525T3 (es) * | 2016-12-23 | 2021-11-17 | Doc Bibawo Aps | Dosificadores y recipientes de aerosol y cabezales para dichos recipientes |
CN106726102A (zh) * | 2017-01-13 | 2017-05-31 | 镇江市宜尔医疗器械有限公司 | 一种喷射冷疗装置 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2592808A (en) * | 1946-04-22 | 1952-04-15 | Knapp Monarch Co | Valve structure |
GB1163573A (en) * | 1965-09-04 | 1969-09-10 | Swallowfield Aerosols Ltd | Improvements in medicament applicators |
US4354638A (en) * | 1980-04-25 | 1982-10-19 | Bristol-Myers Company | Spiral actuator for aerosol powdered suspension product |
US20020060255A1 (en) * | 2000-11-15 | 2002-05-23 | Jean-Francois Benoist | Dispensing head and assembly including the same |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2592208A (en) * | 1949-08-31 | 1952-04-08 | Edison Inc Thomas A | Bezel lock for electric safety lamps |
US2941728A (en) * | 1958-10-24 | 1960-06-21 | Leo A Paldanius | Windshield washer |
FR1594378A (fr) * | 1968-12-11 | 1970-06-01 | ||
US3848778A (en) * | 1972-08-14 | 1974-11-19 | P Meshberg | Childproof actuator assembly |
US3913842A (en) * | 1973-12-14 | 1975-10-21 | Block Drug Co | Spray head for aerosol can |
FR2271995B1 (fr) * | 1974-05-21 | 1978-06-16 | Aerosol Inventions Dev | |
CA2020223C (fr) | 1989-07-19 | 1996-02-27 | Shinya Kobayashi | Bouchon pour aerosols |
DE9103135U1 (de) * | 1991-03-15 | 1991-06-13 | Umstadt, Waldemar, 6951 Fahrenbach | Sprühdose |
FR2684358B1 (fr) * | 1991-12-02 | 1995-01-20 | Oreal | Dispositif aerosol pour distribuer une composition a viscosite relativement elevee. |
US5480095A (en) * | 1993-09-14 | 1996-01-02 | Minnesota Mining And Manufacturing Company | Actuator and container for dispensing fluids |
US5388730A (en) * | 1993-11-10 | 1995-02-14 | Enviro Pac International L.L.C. | Lockable actuator for a dispensing canister |
US5732855A (en) * | 1995-03-06 | 1998-03-31 | Park Towers International B.V. | Spray head intended for a spray can, and spray can provided with such a spray head |
FR2749568B1 (fr) * | 1996-06-10 | 1998-08-07 | Oreal | Distributeur de produit liquide a polymere filmogene sous forme de fines gouttelettes |
US6265025B1 (en) * | 1999-09-16 | 2001-07-24 | Lockheed Martin Energy Research Corporation | Method for the production of ultrafine particles by electrohydrodynamic micromixing |
GB0011218D0 (en) * | 2000-05-10 | 2000-06-28 | Incro Ltd | Improvements in or relating to a nozzle arrangement |
US6405898B1 (en) * | 2000-11-16 | 2002-06-18 | The Gillette Company | Dispenser for a foaming product |
JP2002233797A (ja) * | 2001-02-06 | 2002-08-20 | Mitani Valve Co Ltd | 内容物放出操作機構 |
DE20116336U1 (de) | 2001-10-05 | 2001-12-06 | Lindal Gmbh Aerosol Tech | Ventilanordnung für einen unter Druck stehenden Fluidbehälter |
GB0130057D0 (en) * | 2001-12-14 | 2002-02-06 | Dunne Stephen T | Liquid atomising system |
-
2003
- 2003-09-18 DE DE10343672A patent/DE10343672A1/de not_active Ceased
-
2004
- 2004-09-08 AT AT04021267T patent/ATE453587T1/de not_active IP Right Cessation
- 2004-09-08 EP EP04021267A patent/EP1516829B1/fr active Active
- 2004-09-08 ES ES04021267T patent/ES2336102T3/es active Active
- 2004-09-08 DE DE502004010575T patent/DE502004010575D1/de active Active
- 2004-09-17 US US10/943,165 patent/US9617064B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2592808A (en) * | 1946-04-22 | 1952-04-15 | Knapp Monarch Co | Valve structure |
GB1163573A (en) * | 1965-09-04 | 1969-09-10 | Swallowfield Aerosols Ltd | Improvements in medicament applicators |
US4354638A (en) * | 1980-04-25 | 1982-10-19 | Bristol-Myers Company | Spiral actuator for aerosol powdered suspension product |
US20020060255A1 (en) * | 2000-11-15 | 2002-05-23 | Jean-Francois Benoist | Dispensing head and assembly including the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1619139A1 (fr) * | 2004-07-22 | 2006-01-25 | Lindal Ventil GmbH | Tête de distribution pour distributeur de produits fluide ou pasteuse |
Also Published As
Publication number | Publication date |
---|---|
US20050103892A1 (en) | 2005-05-19 |
US9617064B2 (en) | 2017-04-11 |
ATE453587T1 (de) | 2010-01-15 |
EP1516829B1 (fr) | 2009-12-30 |
DE502004010575D1 (de) | 2010-02-11 |
ES2336102T3 (es) | 2010-04-08 |
DE10343672A1 (de) | 2005-05-04 |
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