EP1498680A1 - Accumulateur en mousse de mélamine-formaldéhyde pour le maintien de froid et de chaud - Google Patents

Accumulateur en mousse de mélamine-formaldéhyde pour le maintien de froid et de chaud Download PDF

Info

Publication number
EP1498680A1
EP1498680A1 EP04014437A EP04014437A EP1498680A1 EP 1498680 A1 EP1498680 A1 EP 1498680A1 EP 04014437 A EP04014437 A EP 04014437A EP 04014437 A EP04014437 A EP 04014437A EP 1498680 A1 EP1498680 A1 EP 1498680A1
Authority
EP
European Patent Office
Prior art keywords
melamine
storage unit
thermal storage
condensation product
formaldehyde condensation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04014437A
Other languages
German (de)
English (en)
Other versions
EP1498680B1 (fr
Inventor
Bernhard Vath
Christof Dr. Möck
Hans Wörthwein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Febra Kunststoffe GmbH and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Febra Kunststoffe GmbH and Co filed Critical BASF SE
Publication of EP1498680A1 publication Critical patent/EP1498680A1/fr
Application granted granted Critical
Publication of EP1498680B1 publication Critical patent/EP1498680B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/40Impregnation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0004Use of compounding ingredients, the chemical constitution of which is unknown, broadly defined, or irrelevant
    • C08J9/0009Phase change materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/06Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063Materials absorbing or liberating heat during crystallisation; Heat storage materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • F28D20/023Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/05Open cells, i.e. more than 50% of the pores are open
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08J2361/26Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08J2361/28Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2303/00Details of devices using other cold materials; Details of devices using cold-storage bodies
    • F25D2303/08Devices using cold storage material, i.e. ice or other freezable liquid
    • F25D2303/085Compositions of cold storage materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Definitions

  • the invention relates to a thermal storage unit comprising an open-cell foam based on a melamine / formaldehyde condensation product containing its cell pores completely or partially filled with a flowable heat transfer medium, as well as its Production.
  • Open-cell foams based on a melamine / formaldehyde condensation product are used for various heat and sound insulation applications in buildings and vehicles, as well as insulating and shock-absorbing packaging material known.
  • the open-cell structure allows recording and storage suitable cleaning, grinding and polishing agents when used as a cleaning abrasive and polishing sponge (WO 01/94436).
  • US 5,457,136 describes crosslinked gelatin foams for thermal insulation, in particular of pipes.
  • B a melamine / formaldehyde condensation product foamed and dried.
  • Conventional cooling batteries often have too rigid outer skin and allow insufficient contact with the surface of the material to be cooled or the The outer skin is so thin that the cooling battery is easily deformed and the sheathed Cooling gel can easily leak if the outer skin is damaged.
  • Object of the present invention was to remedy the aforementioned disadvantages and to provide a thermal storage unit, in particular a cooling battery, the is dimensionally stable, allows for uniform cooling and with a flowable Heat transfer medium is largely leak-proof filled.
  • the thermal storage unit can be used for cooling or keeping warm.
  • the Heat transfer medium is selected according to the application and temperature range. He should, at least in sub-ranges of temperatures during application or filling, usually be fluid at room temperature.
  • As cooling battery is the thermal storage unit preferably with a cooling gel or a phase change material (PCM) used as a heat transfer medium.
  • PCM phase change material
  • the open-cell foam of the thermal storage unit is preferably with a provided with respect to the heat transfer resistant casing.
  • the sheath consists of a film of polyolefin, such as polyethylene or polypropylene.
  • the thermal storage unit asdeffenakku, in particular for cooling during transport and intermediate storage of temperature-sensitive goods, z.
  • a cooling gel or a phase change material (PCM) completely or partially filled, open-cell Foam based on a melamine / formaldehyde condensation product with a Sheath made of a film of polyolefin suitable as a cold pack.
  • the cooling battery can in various transport containers, z. B made of foamed or unfoamed Plastic materials are used.
  • Preferred transport containers consist of Poly-styrene or polypropylene particle foams.
  • thermal storage unit For the preparation of the thermal storage unit can be an open-cell foam based on a melamine / formaldehyde condensation product with one opposite provided the heat transfer resistant sheathing and before the complete Fill the closure with a flowable heat transfer medium.
  • open-cell foams are preferably elastic foams based a melamine / formaldehyde condensation product having a specific gravity from 5 to 100 g / l, in particular from 8 to 20 g / l, as z.
  • B according to EP-A 071 672 or EP-A 037 470 can be produced used. This is a highly concentrated, propellant-containing Solution or dispersion of a melamine-formaldehyde precondensate with Hot air, water vapor or foamed by microwave irradiation and cured.
  • the molar ratio of melamine / formaldehyde is generally in the range of 1: 1 and 1: 5.
  • the molar ratio in the range from 1: 1.3 to 1: 1.8 and a sulphite group-free precondensate used, such. B described in WO 01/94436.
  • the foams then tempered and pressed.
  • the foams can for tailored shape and thickness and on one or both sides with cover layers be laminated.
  • a Topcoat usually not necessary.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Secondary Cells (AREA)
  • Battery Mounting, Suspending (AREA)
  • Cell Separators (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
EP04014437A 2003-07-16 2004-06-19 Utilisation de mousse de mélamine-formaldéhyde pour accumulateur de froid Expired - Lifetime EP1498680B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10332463A DE10332463A1 (de) 2003-07-16 2003-07-16 Kühl- und Warmhalteakku aus Melamin/Formaldehyd-Schaumstoff
DE10332463 2003-07-16

Publications (2)

Publication Number Publication Date
EP1498680A1 true EP1498680A1 (fr) 2005-01-19
EP1498680B1 EP1498680B1 (fr) 2008-01-16

Family

ID=33461972

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04014437A Expired - Lifetime EP1498680B1 (fr) 2003-07-16 2004-06-19 Utilisation de mousse de mélamine-formaldéhyde pour accumulateur de froid

Country Status (4)

Country Link
EP (1) EP1498680B1 (fr)
AT (1) ATE384236T1 (fr)
DE (2) DE10332463A1 (fr)
ES (1) ES2300678T3 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008095931A2 (fr) * 2007-02-08 2008-08-14 Basf Se Pièce moulée en mousse imprégnée d'un liquide, à base d'aminoplaste, et ses utilisations
WO2011000686A2 (fr) 2009-07-03 2011-01-06 Basf Se Composition de mousse
DE102011108755A1 (de) 2010-08-02 2012-02-02 Basf Se Multifunktionelle Wandelemente
DE102014009936A1 (de) 2014-07-04 2016-01-07 Stefan Henze Vakuum-Isolationselement und zwei Verfahren zur Herstellung
EP2488807A4 (fr) * 2009-10-13 2017-01-04 Sonoco Development, Inc. Dispositif de conditionnement commandé thermiquement et procédé de fabrication
CN111261974A (zh) * 2020-01-21 2020-06-09 广东工业大学 一种电池热管理系统用相变材料模块及其制备方法与应用
GB2626197A (en) * 2023-01-16 2024-07-17 Stuart Biggin Ian Shape stable phase change materials
EP4417644A1 (fr) 2023-02-17 2024-08-21 Basf Se Absorbeurs de son pour salle blanche

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102016003393A1 (de) 2016-03-18 2017-09-21 Siegmar Berndt Kühl- und Isolationsmaterial

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0037470A1 (fr) * 1980-03-27 1981-10-14 BASF Aktiengesellschaft Procédé pour la préparation de mousses élastiques à base d'un produit de condensation du formaldéhyde avec la mélamine
EP0071672A1 (fr) 1981-08-07 1983-02-16 Cadbury Schweppes Transport Services Limited Système d'alimentation de combustible pour un moteur à combustion interne
DE8408966U1 (de) * 1984-06-20 Meinass, Ulrich W., 2120 Lüneburg Kälte- und Wärmeträgerkissen
EP0623662A1 (fr) * 1992-02-28 1994-11-09 Mitsubishi Paper Mills, Ltd. Microcapsule pour matériau accumulateur de chaleur
DE9419804U1 (de) 1994-12-10 1995-02-02 Basf Ag, 67063 Ludwigshafen Schallabsorptionselement
US5457136A (en) 1994-08-10 1995-10-10 Armstrong World Industries, Inc. Thermal foam insulation
US6200681B1 (en) * 1997-11-11 2001-03-13 Basf Aktiengesellschaft Application of microcapsules as latent heat accumulators
WO2001094436A2 (fr) 2000-06-07 2001-12-13 Basf Aktiengesellschaft Procedes pour produire des mousses a partir de condensats de melamine/formaldehyde
DE10243240A1 (de) * 2002-09-17 2004-03-25 Basf Ag Vorwiegend aus Kohlenstoff zusammengesetzte Schaumstoffe hoher innerer Oberfläche und Verfahren zu deren Herstellung

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8408966U1 (de) * 1984-06-20 Meinass, Ulrich W., 2120 Lüneburg Kälte- und Wärmeträgerkissen
EP0037470A1 (fr) * 1980-03-27 1981-10-14 BASF Aktiengesellschaft Procédé pour la préparation de mousses élastiques à base d'un produit de condensation du formaldéhyde avec la mélamine
EP0071672A1 (fr) 1981-08-07 1983-02-16 Cadbury Schweppes Transport Services Limited Système d'alimentation de combustible pour un moteur à combustion interne
EP0623662A1 (fr) * 1992-02-28 1994-11-09 Mitsubishi Paper Mills, Ltd. Microcapsule pour matériau accumulateur de chaleur
US5457136A (en) 1994-08-10 1995-10-10 Armstrong World Industries, Inc. Thermal foam insulation
DE9419804U1 (de) 1994-12-10 1995-02-02 Basf Ag, 67063 Ludwigshafen Schallabsorptionselement
US6200681B1 (en) * 1997-11-11 2001-03-13 Basf Aktiengesellschaft Application of microcapsules as latent heat accumulators
WO2001094436A2 (fr) 2000-06-07 2001-12-13 Basf Aktiengesellschaft Procedes pour produire des mousses a partir de condensats de melamine/formaldehyde
DE10243240A1 (de) * 2002-09-17 2004-03-25 Basf Ag Vorwiegend aus Kohlenstoff zusammengesetzte Schaumstoffe hoher innerer Oberfläche und Verfahren zu deren Herstellung

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008095931A2 (fr) * 2007-02-08 2008-08-14 Basf Se Pièce moulée en mousse imprégnée d'un liquide, à base d'aminoplaste, et ses utilisations
WO2008095931A3 (fr) * 2007-02-08 2008-10-02 Basf Se Pièce moulée en mousse imprégnée d'un liquide, à base d'aminoplaste, et ses utilisations
US20100089551A1 (en) * 2007-02-08 2010-04-15 Quadbeck-Seeger Hans-Juergen Aminoplastic-based, liquid-impregnated foamed plastic part and uses thereof
WO2011000686A2 (fr) 2009-07-03 2011-01-06 Basf Se Composition de mousse
US9249269B2 (en) 2009-07-03 2016-02-02 Basf Se Foam composition
EP2488807A4 (fr) * 2009-10-13 2017-01-04 Sonoco Development, Inc. Dispositif de conditionnement commandé thermiquement et procédé de fabrication
DE102011108755A1 (de) 2010-08-02 2012-02-02 Basf Se Multifunktionelle Wandelemente
DE102014009936A1 (de) 2014-07-04 2016-01-07 Stefan Henze Vakuum-Isolationselement und zwei Verfahren zur Herstellung
CN111261974A (zh) * 2020-01-21 2020-06-09 广东工业大学 一种电池热管理系统用相变材料模块及其制备方法与应用
GB2626197A (en) * 2023-01-16 2024-07-17 Stuart Biggin Ian Shape stable phase change materials
WO2024153920A1 (fr) 2023-01-16 2024-07-25 Ian Stuart Biggin Matières à changement de phase
EP4417644A1 (fr) 2023-02-17 2024-08-21 Basf Se Absorbeurs de son pour salle blanche

Also Published As

Publication number Publication date
DE10332463A1 (de) 2005-02-10
ES2300678T3 (es) 2008-06-16
EP1498680B1 (fr) 2008-01-16
ATE384236T1 (de) 2008-02-15
DE502004005944D1 (de) 2008-03-06

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