EP1496856A1 - Emulsions de nettoyage moussantes contenant de l'amidon - Google Patents

Emulsions de nettoyage moussantes contenant de l'amidon

Info

Publication number
EP1496856A1
EP1496856A1 EP03717282A EP03717282A EP1496856A1 EP 1496856 A1 EP1496856 A1 EP 1496856A1 EP 03717282 A EP03717282 A EP 03717282A EP 03717282 A EP03717282 A EP 03717282A EP 1496856 A1 EP1496856 A1 EP 1496856A1
Authority
EP
European Patent Office
Prior art keywords
surfactants
cosmetic cleaning
cosmetic
weight
emulsion according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03717282A
Other languages
German (de)
English (en)
Inventor
Stephan Ruppert
Jörg KÜTHER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of EP1496856A1 publication Critical patent/EP1496856A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to cosmetic cleaning emulsion comprising a) one or more surfactants with an HLB value of greater than or equal to 16, b) one or more pregelatinized, crosslinked starch derivatives, c) an oil phase, in addition to any other cosmetic active ingredients, auxiliaries and additives ,
  • Cleaning means the removal of (environmental) dirt and thus increases the psychological and physical well-being.
  • Cleaning the surface of skin and hair is a very complex process that depends on many parameters.
  • substances coming from outside such as hydrocarbons or inorganic pigments from a wide variety of environments, as well as residues of chemicals or undesired microorganisms, are to be removed as completely as possible.
  • the body's excretions such as sweat, sebum, skin and hair flakes can be washed off without deep intervention in the physiological balance.
  • Cosmetic or dermatological cleansing preparations are so-called “rinse off” preparations, which are rinsed off the skin after use. They are usually applied in the form of a foam with water to the parts of the body to be cleaned. All cosmetic or dermatological cleaning products are based on detergent surfactants.
  • Surfactants are amphiphilic substances that can dissolve organic, non-polar substances in water. They are characterized by an ambivalent behavior towards water and lipids: the surfactant molecule contains at least one hydrophilic one and a lipophilic group that allow attachment at the interface between these two classes of substances.
  • surfactants ensure a reduction in the surface tension of the water, wetting of the skin, easier removal and removal of dirt, easy rinsing and - if desired - also for foam regulation. This provides the basis for the removal of dirt from lipid-containing soiling.
  • hydrophilic parts of a surfactant molecule are mostly polar functional groups, for example -COO " , -OSO 3 2 ' , -SO3 " , while the hydrophobic parts generally represent non-polar hydrocarbon residues.
  • Surfactants are generally classified according to the type and charge of the hydrophilic part of the molecule. There are four groups:
  • Anionic surfactants generally have carboxylate, sulfate or sulfonate groups as functional groups. In aqueous solution they form negatively charged organic ions in an acidic or neutral environment. Cationic surfactants are characterized almost exclusively by the presence of a quaternary ammonium group. In aqueous solution, they form positively charged organic ions in an acidic or neutral environment. Amphoteric surfactants contain both anionic and cationic groups and accordingly behave like anionic or cationic surfactants in aqueous solution depending on the pH. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment. In the neutral pH range, however, they are zwitterionic, as the following example should illustrate:
  • Non-ionic surfactants do not form ions in an aqueous medium. It is understandable that detergent surfactants, which are supposed to clean the skin and hair of greasy and water-soluble dirt components, also have a degreasing effect on normal skin lipids. Every time the skin is cleaned, intercomomeocytic lipids and sebum components are also removed to different degrees. This means that the natural water-lipid coat of the skin is more or less disturbed with every washing process. This can lead to a short-term change in the barrier function of the skin, particularly in the case of extreme degreasing, although the respective condition of the treated skin region is of course also of considerable influence on the changes shown. For example, the thickness of the skin, the number of sebum and sweat glands and the sensitivity associated with it can vary considerably.
  • wash-active surfactants are as inactive as possible in order to avoid undesirable side effects. They should develop their cleaning effect with optimal mildness, best skin compatibility and low degreasing.
  • Cosmetic cleaning agents usually contain mixtures of different types of surfactants. The selection is primarily based on skin tolerance and the desired cosmetic performance of the surfactants. In addition, foaming power, formulability and a favorable performance / cost ratio play an important role.
  • Liquid soaps or washing lotions are not only used to clean the hands, but usually also for the whole body, including the face. Accordingly, they are also suitable for use as a shower preparation.
  • the development of these products focuses on the dermatological requirements, since the skin comes into intensive contact with the concentrated surfactant solution. On the Selection of mild surfactants in low concentration is therefore particularly important. Further criteria are good foaming power as well as a pleasant, refreshing fragrance and the simultaneous care of the skin.
  • Washing lotions and shower baths in particular generally have viscosities of around 3,000 to 10,000 mPa-s, which on the one hand allow the product to be spread easily with quick foaming, but on the other hand should be high enough to enable perfect use by hand or washcloth.
  • Liquid soaps or washing lotions are generally characterized by a more or less high water content, but generally do not have a noticeable care effect, since they have only a low oil content.
  • German Offenlegungsschrift 44 24 210 describes cosmetic or dermatological shower preparations with a surfactant content of at most 55% by weight and an oil content of more than 45% by weight, the preparations being essentially water-free. Due to the high oil content, these preparations have a regenerating effect on the general skin condition. At the same time, they have good foam development and high cleaning power.
  • WO 96/17591 describes foaming liquid skin cleaning compositions which contain the following substances: 5 to 30% by weight of a moisturizing active ingredient which has a Vaughan Solubility Parameter (VSP) of 5 to 10, 0.3 to 5% by weight. % of a water-dispersible gel-forming polymer, 5 to 30% by weight of a synthetic surface-active substance, 0 to 15% by weight of a C 8 to C fatty acid soap and water, the preparations having a lipid deposition value (LDV) of at least 5 to 1000 and wherein the synthetic surfactant and the soap have a common CMC equilibrium surface tension value of 15 to 50.
  • VSP Vaughan Solubility Parameter
  • the prior art also knows cleaning products based on emulsions for cleaning and simultaneous care of the skin. These are formulated in such a way that the emulsion is stabilized with emulsifiers and then a surfactant system is adapted.
  • Emulsifiers also have an amphiphilic structure, so their structure is comparable to that of surfactants. Emulsifiers enable or facilitate the uniform distribution of two or more immiscible phases and at the same time prevent their separation. Since emulsions are generally destroyed by the addition of surfactants, the choice of surfactant system is severely restricted and the cleaning preparations obtained are based on expensive and complicated formulations.
  • HLB value a dimensionless number between 0 and 20
  • HLB value a dimensionless number between 0 and 20
  • Numbers below 9 indicate oil-soluble, hydrophobic emulsifiers, numbers above 11 water-soluble, hydrophilic.
  • the HLB value says something about the balance between the size and strength of the hydrophilic and lipophilic groups of an emulsifier. It can be derived from these considerations that the effectiveness of an emulsifier can also be characterized by its HLB value.
  • the following table shows the relationship between the HLB value and the possible area of application:
  • HLB value of an emulsifier can also be composed of increments, the HLB increments for the various hydrophilic and hydrophobic groups from which a molecule is composed can be found in tables. NEN.
  • HLB values can also be determined for detergent surfactants in this way, although the HLB system was originally designed only for emulsifiers. It can be seen that wash-active substances generally have HLB values that are significantly greater than 20.
  • gel formers that structure the water phase.
  • the central problem in the formulation of foaming emulsions is the selection of a gel former which is compatible both with hydrophilic, in particular ionic, surfactants and with oils.
  • Known gel formers generally do not form stable gel networks in the presence of surfactants and do not oil, so that the formulations become unstable.
  • the gel formation of anionic gel formers is usually very strongly disturbed by anionic surfactants, so that extremely high gel former concentrations have to be used.
  • polyacrylates are used as gel formers to form gel networks in cosmetic cleaning preparations.
  • EP 00112547 describes the stabilization of cleaning emulsions by polyacrylates. With regard to their biological compatibility and, in particular, their degradability and their consumer acceptance, it is desirable to replace polyacrylates with other (natural) substances or to reduce their concentration in the formulations.
  • the object is achieved by cosmetic cleaning emulsion comprising a) one or more surfactants with an HLB value of greater than or equal to 16, b) one or more pregelatinized, crosslinked starch derivatives, c) an oil phase, in addition to any other cosmetic active ingredients, auxiliaries and additives.
  • the products according to the invention are distinguished by an exceptionally pleasantly smooth and velvety feeling on the skin during and after use.
  • the cosmetic cleaning emulsion contains surfactants in a concentration of 1 to 20% by weight and very particularly preferably in a concentration of 5 to 15% by weight, based on the total weight of the preparation.
  • the oil phase is present in the cleaning emulsion in a concentration of 5 to 80% by weight, particularly preferably in a concentration of 30 to 75% by weight and very particularly preferably in a concentration of 40 to 50% by weight ,
  • hydroxypropylated phosphate esters are used as the pregelatinized, crosslinked starch derivatives.
  • Starch derivatives such as those described in US Pat. No. 6,248,338 are particularly advantageous, and hydroxypropyl distarch phosphate is particularly advantageous.
  • acylglutamates especially sodium acylglutamate Sarcosinates, for example myristoyl sarcosin, TEA-lauroyl sarcosinate, sodium lauroylsa cosinate and sodium cocoyl sarcosinate,
  • Sulfonic acids and their salts such as acyl isethionates e.g. Sodium / ammonium cocoyl isethionate,
  • Sulfosuccinates for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA sulfosuccinate
  • sulfuric acid esters such as
  • alkyl ether sulfate for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium and sodium C 12 - 13 pareth,
  • Alkyl sulfates for example sodium, ammonium and TEA lauryl sulfate.
  • Advantageous wash-active cationic surfactants for the purposes of the present invention are quaternary surfactants. Quaternary surfactants contain at least one N atom which is covalently linked to 4 alkyl or aryl groups. Benzalkonium chloride, alkyl betaine, alkyl amidopropyl betaine and alkyl amidopropyl hydroxysultain are advantageous.
  • Acyl- / dialkylethylenediamines for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, sodium acylamphohydroxypropylsulfonate, dinathumacylamphodiacetate and sodium acylamphopropionate,
  • Alkanolamides such as Cocamide MEA / DEA / MIPA
  • esters by esterification of carboxylic acids with ethylene oxide, glycene, sorbitan. or other alcohols,
  • Ethers for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside,
  • ⁇ taurates for example sodium lauroyl taurate and sodium methyl cocoyl taurate
  • ⁇ ether carboxylic acids for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate
  • ⁇ phosphoric acid esters and salts such as, for example, DEA-Oleth-10 phosphate and dilaureth-4 phosphate, ⁇ alkyl sulfonates, for example sodium cocosmonoglyceride sulfate, sodium C 12 . 1 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate.
  • N-alkylamino acids for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.
  • non-ionic surfactants are alcohols.
  • acylglutamates such as di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
  • carboxylic acids and derivatives such as cylenat ⁇ for example lauric acid, aluminum stearate, magnesium and Zinisme-,
  • Ester carboxylic acids for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate,
  • nonionic surfactants for the purposes of the present invention are also amine oxides, such as cocoamidopropylamine oxide. According to the invention, it is particularly preferred if anionic surfactants are used as surfactants.
  • alkyl ether sulfates in particular sodium lauryl ether sulfate or myristyl ether sulfate, is very particularly preferred according to the invention.
  • An embodiment of the present invention which is particularly advantageous according to the invention is in particular the combination of the surfactants of sodium lauryl ether sulfate with sodium cocoyl glutamate and / or decylglycoside.
  • polysorbates can advantageously be incorporated into the emulsion as washing-active agents.
  • the preparation according to the invention can also contain, according to the invention, other ingredients, for example alcohols, diols or polyols of low C number, and also their ethers, preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether , Propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and similar products, furthermore alcohols of low C number, for example Ethanol, isopropanol, 1, 2-propanediol and glycerin.
  • other ingredients for example alcohols, diols or polyols of low C number, and also their ethers, preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether , Propylene glycol monomethyl,
  • the oil phase of the cosmetic or dermatological cleaning emulsions in the sense of the present invention is advantageously selected from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated ver - branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or un-
  • ester oils can then advantageously be selected from the group
  • the oil phase can advantageously be selected from the group of branched and unbranched hydrocarbons and waxes, silicone oils, dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols, and also the fatty acid triglycerides, especially the triglycerol esters of saturated and / or unsaturated , branched and / or unbranched alkane carboxylic acids with a chain length of 8 to 24, in particular 12 to 18, carbon atoms.
  • the fatty acid triglycerides can for example be advantageously selected from the group of synthetic, semi-synthetic and natural oils, e.g. As olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like.
  • any mixtures of such oil and wax components can also be used advantageously for the purposes of the present invention. It may also be advantageous to use waxes, for example cetyl palmitate, as the sole lipid component of the oil phase.
  • the oil phase is advantageously selected from the group consisting of 2-ethylhexyl isostearate, octyldodecanol, isotridecyl isononanoate, isoeicosane, 2-ethylhexyl cocoate, C 12 -i 5 -alkyl benzoate, caprylic capric acid trigiyceride, dicaprylyl ether.
  • C 2 are particularly advantageous. 15 alkyl benzoate and 2-ethylhexyl isostate, mixtures of C 12 . 15 alkyl benzoate and isotridecyl isononanoate and mixtures of C ⁇ 2 .i 5 alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate.
  • hydrocarbons paraffin oil, squalane and squalene can be used advantageously for the purposes of the present invention.
  • the oil phase can advantageously also have a content of cyclic or linear silicone oils or consist entirely of such oils, although it is preferred to use an additional content of other oil phase components in addition to the silicone oil or the silicone oils.
  • Cyclomethicone (octamethylcyclotetrasiloxane) is advantageously used as the silicone oil to be used according to the invention.
  • silicone oils are also beneficial in the sense to use the present invention, for example hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).
  • Mixtures of cyclomethicone and isotridecyl isononanoate, of cyclomethicone and 2-ethylhexyl isostearate are also particularly advantageous.
  • the oil phase is also advantageously selected from the group of phospholipids.
  • the phospholipids are phosphoric acid esters of acylated glycerols.
  • phosphoric acid esters of acylated glycerols are particularly important among the phosphatidylcholines.
  • the lecithins which are characterized by the general structure
  • the cosmetic cleaning emulsion contains one or more polyacrylates.
  • Polyacrylates which are advantageous according to the invention are polymers of acrylic acid, in particular those selected from the group of the so-called carbomers or carbopols (Carbopol® is actually a registered trademark of the B.F. Goodrich Company). Polyacrylates are compounds of the general structural formula
  • the group of polyacrylates also includes acrylate-alkyl acrylate copolymers, for example those which are distinguished by the following structure:
  • R ' represents a long-chain alkyl radical and x and y numbers which symbolize the respective stoichiometric proportion of the respective comonomers.
  • advantageous carbopoles are types 907, 910, 934, 940, 941, 951, 954, 980, 981, 1342, 1382, 2984 and 5984 or types ETD (Easy-to-disperse) 2001, 2020, 2050, Aqua -SF1 where these compounds can be present individually or in any combination with one another.
  • ETD Easy-to-disperse
  • alkyl acrylate to acrylate copolymers comparable copolymers of C 10 ⁇ o-alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or esters thereof.
  • the INCI name for such compounds is "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer”.
  • Particularly advantageous are those available under the trade names Pemulen TR1 and Pemulen TR2 from the BF Goodrich Company.
  • copolymers are used as polyacrylates C 10 to C 30 alkyl acrylate.
  • the content of one or more polyacrylates in the cosmetic or dermatological cleaning emulsion is in the range from 0.5 to 2% by weight, very particularly advantageously from 0.7 to 1.5% by weight. -% is selected, in each case based on the total weight of the preparations
  • compositions according to the invention optionally contain the additives customary in cosmetics, for example perfume, dyes, antimicrobial substances, lipid-replenishing agents, complexing and sequestering agents, pearlescent agents, plant extracts, vitamins, active ingredients, substances Serving agents, bactericides, pigments that have a coloring effect, thickening agents, softening, moisturizing and / or moisturizing substances, or other usual components of a cosmetic or dermatological formulation such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.
  • additives customary in cosmetics for example perfume, dyes, antimicrobial substances, lipid-replenishing agents, complexing and sequestering agents, pearlescent agents, plant extracts, vitamins, active ingredients, substances Serving agents, bactericides, pigments that have a coloring effect, thickening agents, softening, moisturizing and / or moisturizing substances, or other usual components of a cosmetic or dermatological formulation such as alcohols, polyols
  • antioxidants are generally preferred. According to the invention, all the antioxidants suitable or customary for cosmetic and / or dermatological applications can be used as favorable antioxidants.
  • the active substances, auxiliaries and additives which can advantageously be used according to the invention are in no way limited to the substances and compounds mentioned by name here.
  • effect substances e.g. coloring and / or active substance spheres, glitter substances etc.
  • effect substances e.g. coloring and / or active substance spheres, glitter substances etc.
  • the cosmetic cleaning emulsion according to the invention is used as a foam bath, shower bath (shower gel), bath tub and / or shampoo.
  • the use of the cosmetic cleaning emulsion for the prophylaxis and / or treatment of inflammatory skin conditions and / or for skin protection in the case of sensitive and dry skin is also according to the invention.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

Emulsion cosmétique de nettoyage qui contient (a) un ou plusieurs tensioactifs ayant une valeur de rapport hydro-lipophile (HLB) égale ou supérieure à 16, (b) un ou plusieurs dérivés d'amidon prégélatinisés et réticulés transversalement, et (c) une phase huile, ainsi qu'éventuellement d'autres ingrédients actifs, additifs et adjuvants cosmétiques.
EP03717282A 2002-04-11 2003-04-08 Emulsions de nettoyage moussantes contenant de l'amidon Withdrawn EP1496856A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10216510 2002-04-11
DE2002116510 DE10216510A1 (de) 2002-04-11 2002-04-11 Schäumende Reinigungsemulsionen mit Stärke
PCT/EP2003/003611 WO2003084500A1 (fr) 2002-04-11 2003-04-08 Emulsions de nettoyage moussantes contenant de l'amidon

Publications (1)

Publication Number Publication Date
EP1496856A1 true EP1496856A1 (fr) 2005-01-19

Family

ID=28458816

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03717282A Withdrawn EP1496856A1 (fr) 2002-04-11 2003-04-08 Emulsions de nettoyage moussantes contenant de l'amidon

Country Status (4)

Country Link
EP (1) EP1496856A1 (fr)
JP (1) JP2005530718A (fr)
DE (1) DE10216510A1 (fr)
WO (1) WO2003084500A1 (fr)

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Publication number Priority date Publication date Assignee Title
DE102015222074A1 (de) 2015-11-10 2017-05-11 Beiersdorf Ag Wirkstoffkombination zur Hautbefeuchtung in Reinigungszubereitungen

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JP4072458B2 (ja) 2003-05-14 2008-04-09 日本エヌエスシー株式会社 化粧料用水性組成物及びそれを含んで成る化粧料
US6903057B1 (en) * 2004-05-19 2005-06-07 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal product liquid cleansers stabilized with starch structuring system
JP4696507B2 (ja) * 2004-09-13 2011-06-08 味の素株式会社 洗浄剤組成物
JP4832746B2 (ja) * 2004-10-13 2011-12-07 アクゾノーベル株式会社 乳化組成物及びそれを用いた化粧料
JP5936222B2 (ja) * 2011-07-11 2016-06-22 株式会社ミルボン 毛髪処理剤
JP6264290B2 (ja) * 2012-09-24 2018-01-24 味の素株式会社 ステロールエステルを含有する液体洗浄料

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GB9917339D0 (en) * 1999-07-24 1999-09-22 Cerestar Holding Bv Starch granulation
DE10032118B9 (de) * 2000-07-01 2006-12-07 Wella Ag Antithixotropes kosmetisches Mittel

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015222074A1 (de) 2015-11-10 2017-05-11 Beiersdorf Ag Wirkstoffkombination zur Hautbefeuchtung in Reinigungszubereitungen

Also Published As

Publication number Publication date
JP2005530718A (ja) 2005-10-13
DE10216510A1 (de) 2003-10-23
WO2003084500A1 (fr) 2003-10-16

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