EP1486595B1 - Schnittfestes Garn - Google Patents
Schnittfestes Garn Download PDFInfo
- Publication number
- EP1486595B1 EP1486595B1 EP04291386A EP04291386A EP1486595B1 EP 1486595 B1 EP1486595 B1 EP 1486595B1 EP 04291386 A EP04291386 A EP 04291386A EP 04291386 A EP04291386 A EP 04291386A EP 1486595 B1 EP1486595 B1 EP 1486595B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- thread
- cladding
- filaments
- protective equipment
- equipment according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000011521 glass Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 229920000742 Cotton Polymers 0.000 claims abstract description 6
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 3
- 229920001194 natural rubber Polymers 0.000 claims abstract description 3
- 239000008187 granular material Substances 0.000 claims abstract 2
- 230000001681 protective effect Effects 0.000 claims description 12
- 239000004952 Polyamide Substances 0.000 claims description 10
- 229920002647 polyamide Polymers 0.000 claims description 10
- -1 polyethylene Polymers 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920003235 aromatic polyamide Polymers 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229920000459 Nitrile rubber Polymers 0.000 claims description 2
- 238000003486 chemical etching Methods 0.000 claims description 2
- 238000005530 etching Methods 0.000 claims description 2
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- 238000005253 cladding Methods 0.000 claims 6
- 238000000576 coating method Methods 0.000 abstract description 23
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229920003051 synthetic elastomer Polymers 0.000 abstract 1
- 239000005061 synthetic rubber Substances 0.000 abstract 1
- 238000004804 winding Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 22
- 239000000835 fiber Substances 0.000 description 10
- 238000009940 knitting Methods 0.000 description 5
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 5
- 238000004448 titration Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 210000000707 wrist Anatomy 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 201000011243 gastrointestinal stromal tumor Diseases 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
- D02G3/182—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure
- D02G3/185—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure in the core
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/442—Cut or abrasion resistant yarns or threads
Definitions
- the invention relates to a yarn having cut-resistant properties, cut-prevention equipment, in particular a glove, made from such a yarn and a method for producing such equipment.
- Glass filaments are known to have cut resistance properties. This resistance can be defined in relation to the French and European standard NF EN 388 concerning protective gloves against mechanical risks.
- a monofilament core wire has a stiffness too great to allow comfortable use of the glove made from such a wire.
- the number of glass filaments is not adjusted so that for a given title, the yarn has great flexibility and resistance to repeated bending.
- the aim of the invention is to overcome this disadvantage by proposing a wire having cut resistance properties comprising one or more coated multifilament core wires, the core wire being a multifilament wire whose number of filaments is adjusted to provide a greater flexibility and greater strength.
- the glove made from such a yarn has cut resistance characteristics in accordance with the NF EN 388 standard, in particular with regard to the resistance to slicing cut, and a flexibility adapted to its use as well as great longevity.
- the invention relates to a yarn having cut-resistance properties comprising at least one core yarn coated with at least one coating yarn consisting of continuous fibers or filaments, the core yarn having a titration of 110 decitex and is a multifilament yarn comprising 200 continuous filaments of glass whose diameter is substantially equal to 5 micrometers.
- the core wire is more flexible and more resistant to repeated bending.
- the invention relates to cut protection equipment such as a glove, comprising a knit of at least one thread as described above.
- Such a glove is comfortable and has a long life.
- the yarn 1 according to the invention comprises one or more core yarns 2 coated with one or more encasing threads 3.
- the wire 1 comprises three core wires 2 and a coating wire 3 for simplification purposes.
- the core wire 2 is a multifilament yarn comprising a plurality of continuous filaments of glass 4. These filaments 4 may be twisted or not and the core yarn 2 may have different titrations. It should be noted that at equal titration, a monofilament yarn is stiffer than a multifilament yarn.
- the core wire 2 comprises 200 continuous filaments of glass 4 with a diameter of 5 microns.
- the core wire 2 comprises 200 filaments with a diameter of 5 microns for a titer of 110 dTex.
- It can be chosen to coat a single core wire 2 or more in order to reinforce the resistance to cutting the wire 1. In the case where several core wires 2 are used, they can be twisted together. between them or not.
- the core son 2 are coated with one or more coating son 3, for example by grinding.
- the coating son 3 may also be multifilament.
- the filaments or continuous fibers of the coating son are made of a material from polyamide, polyester, acrylic, cotton, polyethylene, polypropylene or meta and para aramid. It is also conceivable to use filaments of different materials depending on the characteristics that are to be conferred on the wire 1.
- the core yarn 2 is coated with two polyester coating yarns 3 having a titration of 110 decitex each.
- the wire 1, as described above, makes it possible to produce protection equipment against cutting.
- Such equipment is for example a protective glove 5, such as that shown on the figure 2 .
- the glove 5 comprises a knit of at least one yarn 1.
- This yarn can also be knitted with other textile yarns, for example with less expensive yarns in order to lower production costs, while keeping a sufficient proportion of glass to ensure the desired protection.
- These yarns comprise a plurality of filaments or continuous fibers belonging to the family of polyamide, polyester, acrylic, cotton, polyethylene, polypropylene or meta and para-aramid.
- the glove may comprise at least a partial coating on the knit.
- This coating may be a layer of PVC, natural rubber, polyurethane, polychloroprene or nitrile rubber. These materials can be used alone or in a mixture and the coating can comprise several layers.
- the coating may be smooth or rough. When rough, the coating improves the grip of oily, wet or slippery objects.
- the first step consists in coating at least one core wire 2 with at least one coating wire 3, for example by grinding, so as to produce a wire 1.
- the knit is coated at least partially with one or more layers of coating, for example by dipping according to known methods.
- composition 5 the glass is associated with a polyethylene fiber having a high cut resistance. It can be seen that this combination makes it possible to obtain a high index of resistance to cut-off.
- the composition 6 relates to a glove coated with PVC, the glass is therefore contained in the lining of this glove.
- the proportion of glass in the liner is suitable, it is found that the glove retains a good resistance to cutting after PVC coating.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Gloves (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Knitting Of Fabric (AREA)
- Ropes Or Cables (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Claims (10)
- Faden mit schnittfesten Eigenschaften, der zumindest einen Seelenfaden (2) umfasst, der von zumindest einem Mantelfaden (3) umhüllt ist, der aus Fasern oder Endlosfilamenten besteht, dadurch gekennzeichnet, dass der Seelenfaden (2) einen Titer von 110 Dezitex aufweist und ein Multifilament ist, das 200 Endlosfilamente aus Glas (4) mit einem Durchmesser, der im Wesentlichen 5 Mikrometer beträgt, umfasst.
- Faden nach Anspruch 1, dadurch gekennzeichnet, dass der Mantelfaden (3) Fasern oder Endlosfilamente aus einem oder mehreren Materialien umfasst, die zu den Familien Polyamide, Polyester, Acryl, Baumwolle, Polyethylen, Polypropylen oder Meta- und Paraaramid gehören.
- Faden nach Anspruch 2, dadurch gekennzeichnet, dass der Seelenfaden (2) von zwei Polyestermantelfäden (3) umhüllt ist, die jeweils einen Titer von 110 Dezitex aufweisen.
- Ausrüstung zum Schutz vor Schnitten, wie etwa ein Handschuh (5), dadurch gekennzeichnet, dass sie ein Gestrick mit zumindest einem Faden (1) nach einem der Ansprüche 1 bis 3 umfasst.
- Schutzausrüstung nach Anspruch 4, dadurch gekennzeichnet, dass das besagte Gestrick des Weiteren Textilfäden umfasst, die mehrere Fasern oder Endlosfilamente umfassen, die zu den Familien Polyamide, Polyester, Acryl, Baumwolle, Polyethylen, Polypropylen oder Meta- und Paraaramid gehören.
- Schutzausrüstung nach einem der Ansprüche 4 oder 5, dadurch gekennzeichnet, dass sie zumindest teilweise mit einer Schicht aus PVC, Naturkautschuk, Polyurethan, Polychloropren oder Nitrilkautschuk, die jeweils alleine oder als Mischung verwendet werden, überzogen ist.
- Schutzausrüstung nach Anspruch 6, dadurch gekennzeichnet, dass der Überzug des Weiteren zumindest eine zusätzliche Schicht umfasst.
- Schutzausrüstung nach einem der Ansprüche 6 oder 7, dadurch gekennzeichnet, dass die Außenschicht des Überzugs rau ist.
- Verfahren zur Herstellung einer Schutzausrüstung nach einem der Ansprüche 6 bis 8, dadurch gekennzeichnet, dass es folgende Schritte umfasst:- Umhüllen von zumindest einem Seelenfaden (2) mit zumindest einem Mantelfaden (3), so dass ein Faden (1) nach einem der Ansprüche 1 bis 3 entsteht;- Verstricken von zumindest einem Faden (1) zur Form einer Schutzausrüstung;- zumindest teilweises Überziehen des Gestricks mit einer oder mehreren Überzugschichten.
- Verfahren zur Herstellung einer Schutzausrüstung nach Anspruch 9, wenn dieser von Anspruch 8 abhängig ist, dadurch gekennzeichnet, dass es einen zusätzlichen Schritt umfasst, der darin besteht, die Außenschicht des Überzugs durch Pulver- oder Granulatbeschichtung, chemische Ätzung oder 5mechanische Gravur rau zu machen.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0306872A FR2855837B1 (fr) | 2003-06-06 | 2003-06-06 | Fil ayant des proprietes de resistance a la coupure |
| FR0306872 | 2003-06-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1486595A1 EP1486595A1 (de) | 2004-12-15 |
| EP1486595B1 true EP1486595B1 (de) | 2008-03-12 |
Family
ID=33186451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04291386A Revoked EP1486595B1 (de) | 2003-06-06 | 2004-06-03 | Schnittfestes Garn |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7143570B2 (de) |
| EP (1) | EP1486595B1 (de) |
| JP (1) | JP2004360168A (de) |
| KR (1) | KR20040105586A (de) |
| CN (1) | CN1572930A (de) |
| AT (1) | ATE389044T1 (de) |
| CA (1) | CA2470233A1 (de) |
| DE (1) | DE602004012345T2 (de) |
| FR (1) | FR2855837B1 (de) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0717118B1 (pt) * | 2006-10-17 | 2017-02-14 | Dsm Ip Assets Bv | fio resistente a corte, um processo para produzir o fio e produtos contendo o fio |
| US7721518B2 (en) | 2007-01-26 | 2010-05-25 | Pascale Industries, Inc. | Yarns for cut-resistant webbing and other products |
| US8074436B2 (en) * | 2008-01-23 | 2011-12-13 | Ansell Healthcare Products Llc | Cut, oil and flame resistant glove and a method therefor |
| US7934394B2 (en) * | 2009-01-26 | 2011-05-03 | E. I. Du Pont De Nemours And Company | Cut-resistant gloves containing fiberglass and para-aramid |
| US7669442B1 (en) * | 2009-01-26 | 2010-03-02 | E. I. Du Pont De Nemours And Company | Cut-resistant gloves containing fiberglass and para-aramid |
| US7934396B2 (en) * | 2009-01-26 | 2011-05-03 | E. I. Du Pont De Nemours And Company | Cut-resistant gloves containing fiberglass and para-aramid |
| CN102561076B (zh) * | 2010-12-16 | 2015-02-25 | 杜邦公司 | 具有高断裂强力和高断裂伸长率的复合绳及相关增强制品和用途 |
| JP5813963B2 (ja) * | 2011-02-28 | 2015-11-17 | ローム株式会社 | 半導体装置、および、半導体装置の実装構造 |
| PL2707527T3 (pl) * | 2011-05-10 | 2019-01-31 | Dsm Ip Assets B.V. | Przędza, sposób wytwarzania przędzy i wytwory zawierające przędzę |
| CN102828312B (zh) * | 2012-09-12 | 2015-05-20 | 常州科旭纺织有限公司 | 一种耐切割包芯纱线及其应用 |
| CN102851813A (zh) * | 2012-09-24 | 2013-01-02 | 海安县中山合成纤维有限公司 | 一种锦纶和玻璃纤维混纺纱 |
| CN102953184B (zh) * | 2012-09-27 | 2015-01-07 | 杭州翔盛高强纤维材料股份有限公司 | 一种多异复合防切割包覆纱装置及其制备方法 |
| CN104452007A (zh) * | 2013-09-13 | 2015-03-25 | 常州科旭纺织有限公司 | 一种高性能包芯纱线及其应用 |
| CN104814549B (zh) * | 2015-05-19 | 2016-08-17 | 江苏工程职业技术学院 | 超高分子量聚乙烯棉型防切割手套的制备方法 |
| JP5865541B1 (ja) * | 2015-07-16 | 2016-02-17 | 茶久染色株式会社 | 放射線遮蔽織物および放射線遮蔽用品 |
| CN105155066A (zh) * | 2015-09-07 | 2015-12-16 | 南通强生安全防护科技有限公司 | 涤纶包覆纱线及制备方法和用途 |
| US20170175301A1 (en) * | 2015-12-17 | 2017-06-22 | E I Du Pont De Nemours And Company | Hybrid Cord and Use Thereof |
| US20170340038A1 (en) * | 2016-05-25 | 2017-11-30 | Supreme Corporation | Cut, slash and/or abrasion resistant protective fabric and lightweight shaped knit garment made therefrom having improved appearance and cut resistance |
| CN105926104B (zh) * | 2016-06-20 | 2019-07-30 | 常州科旭纺织有限公司 | 手感舒适的高防割纱线及其生产方法和应用 |
| CN106087171A (zh) * | 2016-08-30 | 2016-11-09 | 上海固甲新材料科技有限公司 | 一种新型防割纱线及其防割制品的制备方法 |
| CN110709545B (zh) * | 2017-04-03 | 2022-06-24 | 帝斯曼知识产权资产管理有限公司 | 耐切割的经填充的伸长体 |
| CN107574519B (zh) * | 2017-09-29 | 2024-06-11 | 汇鸿(南通)安全用品有限公司 | 一种防切割包胶纱线 |
| WO2019134090A1 (en) * | 2018-01-04 | 2019-07-11 | Honeywell International Inc. | Cut-resistant composite yarn structure |
| CN108981467B (zh) * | 2018-07-16 | 2020-11-24 | 南通大学 | 一种复合结构的软质防刺材料及其制备方法 |
| EP3674456B1 (de) | 2018-12-18 | 2024-08-14 | Honeywell International Inc. | Schnittfeste garnstruktur |
| CN109797477A (zh) * | 2019-03-11 | 2019-05-24 | 公安部第一研究所 | 一种防割服装面料 |
| CN110512326A (zh) * | 2019-08-20 | 2019-11-29 | 南通嘉得利安全用品有限公司 | 一种包芯纱线及其制造方法及防割制品 |
| CN111286836A (zh) * | 2020-03-11 | 2020-06-16 | 山东星宇手套有限公司 | 一种基于改性聚苯硫醚的阻燃防切割纱线、制备方法及手套 |
| CN111364138A (zh) * | 2020-03-11 | 2020-07-03 | 山东星宇手套有限公司 | 制作高温作业防护用品的复合纱线、制备方法及高温作业防护手套 |
| CN112410977A (zh) * | 2020-11-05 | 2021-02-26 | 江苏锵尼玛新材料股份有限公司 | 一种防割耐磨面料及其制备方法和应用 |
| CN113861528B (zh) * | 2021-09-23 | 2022-11-04 | 汇鸿(南通)安全用品有限公司 | 一种防化防切割无内衬手套的制备方法 |
| CN114672907B (zh) * | 2022-04-21 | 2023-03-28 | 江南大学 | 一种辅助陶瓷纤维织物织造包绕合股装置及方法 |
| CN116463865A (zh) * | 2023-04-03 | 2023-07-21 | 南通强生新材料科技股份有限公司 | 一种抗热抗切割的双浸pvc手套及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3404409A (en) * | 1966-06-03 | 1968-10-08 | Tillotson Corp | Work glove |
| US4272568A (en) * | 1977-10-21 | 1981-06-09 | Societe Anonyme Parinter | Protective glove and its method of manufacture |
| CA2071926A1 (en) * | 1990-01-09 | 1991-07-10 | David S. Cordova | Cut resistant protective glove |
| US5146628A (en) * | 1990-10-26 | 1992-09-15 | Bettcher Industries, Inc. | Slip-resistant protective glove and method for manufacturing slip-resistant glove |
| US5845476A (en) * | 1997-06-04 | 1998-12-08 | Kolmes; Nathaniel H. | Composite yarn with fiberglass core |
| US6532724B2 (en) * | 2000-05-15 | 2003-03-18 | Gilbert Patrick | Cut-resistant yarn and method of manufacture |
| DE10040589C1 (de) * | 2000-08-15 | 2002-06-06 | Twaron Products Gmbh | Schnittschutzkleidung |
-
2003
- 2003-06-06 FR FR0306872A patent/FR2855837B1/fr not_active Expired - Fee Related
-
2004
- 2004-06-03 AT AT04291386T patent/ATE389044T1/de not_active IP Right Cessation
- 2004-06-03 DE DE602004012345T patent/DE602004012345T2/de not_active Revoked
- 2004-06-03 EP EP04291386A patent/EP1486595B1/de not_active Revoked
- 2004-06-03 US US10/860,794 patent/US7143570B2/en not_active Expired - Fee Related
- 2004-06-04 CA CA002470233A patent/CA2470233A1/en not_active Abandoned
- 2004-06-05 KR KR1020040041115A patent/KR20040105586A/ko not_active Withdrawn
- 2004-06-07 CN CNA2004100462365A patent/CN1572930A/zh active Pending
- 2004-06-07 JP JP2004168270A patent/JP2004360168A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2855837A1 (fr) | 2004-12-10 |
| DE602004012345D1 (de) | 2008-04-24 |
| KR20040105586A (ko) | 2004-12-16 |
| DE602004012345T2 (de) | 2009-04-23 |
| US20050022494A1 (en) | 2005-02-03 |
| US7143570B2 (en) | 2006-12-05 |
| JP2004360168A (ja) | 2004-12-24 |
| CN1572930A (zh) | 2005-02-02 |
| FR2855837B1 (fr) | 2006-01-27 |
| CA2470233A1 (en) | 2004-12-06 |
| EP1486595A1 (de) | 2004-12-15 |
| ATE389044T1 (de) | 2008-03-15 |
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