EP1484420B1 - Verwendung eines gewalzten oder stranggepressten Produkts aus Aluminium-Legierung mit hoher Korrosionbeständigkeit - Google Patents
Verwendung eines gewalzten oder stranggepressten Produkts aus Aluminium-Legierung mit hoher Korrosionbeständigkeit Download PDFInfo
- Publication number
- EP1484420B1 EP1484420B1 EP04356087A EP04356087A EP1484420B1 EP 1484420 B1 EP1484420 B1 EP 1484420B1 EP 04356087 A EP04356087 A EP 04356087A EP 04356087 A EP04356087 A EP 04356087A EP 1484420 B1 EP1484420 B1 EP 1484420B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- rolled
- corrosion resistance
- content
- aluminium alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 6
- 230000007797 corrosion Effects 0.000 title description 8
- 238000005260 corrosion Methods 0.000 title description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 23
- 239000000956 alloy Substances 0.000 claims description 23
- 239000010949 copper Substances 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 239000011572 manganese Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- PQLVXDKIJBQVDF-UHFFFAOYSA-N acetic acid;hydrate Chemical compound O.CC(O)=O PQLVXDKIJBQVDF-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000011664 signaling Effects 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
Definitions
- the invention relates to the use of laminated or spun aluminum alloy products of the 4000 series having both good mechanical strength and good resistance to corrosion.
- Aluminum alloys containing silicon as the main alloying element are widely used for the manufacture of molded parts. On the other hand, they are rarely used in the form of rolled or spun products. Uses in the form of rods or profiles are related to the good resistance to wear and temperature of high silicon alloys, and mainly concern the manufacture of mechanical parts such as connecting rods, transmission shafts, bearings and engine and compressor components.
- the alloy of the document JP-A-9-256095 is used for the manufacture of automotive components.
- the document JP-A-2000-303134 discloses an alloy consisting of, in weight percent: 1.5-5% Si, 0.2-1% Mg, 0.05-1% Mn, 0.2-1.2% Fe, 0.1-1, 5% Zn, 0.1-2.0% Cu, 0.01-0.1% Cr, 0.005-0.1% Ti, remains Al with the inevitable impurities.
- the alloy of the document JP-A-2000-303134 is used for the manufacture of engine components or machine parts.
- the invention which is defined in claim 1 relates to the use of a rolled product or spun aluminum alloy composition (% by weight): If: 1.2 - 2.2 Fe ⁇ 1.5 Cu: 0.2 - 0.8 Mn: 0.6 - 1.5 Mg ⁇ 0.20 Zn ⁇ 0.5
- Ti ⁇ 0.10 remains inevitable aluminum and impurities, for the manufacture of parts having both good mechanical strength and good resistance to corrosion, exposed to the atmosphere without protection, that is to say for panels insulation or components for building and signaling.
- the Si content is between 1.4 and 2%, the copper content between 0.3 and 0.5%, the manganese content between 0.9 and 1.2%, the lower iron content. 0.7% and the magnesium content less than 0.15%.
- the products according to the invention are distinguished from 4015 alloy products by a higher copper content and a lower magnesium content.
- a controlled copper content of between 0.2 and 0.8%, and preferably between 0.3 and 0.5%, leads to an improvement in corrosion resistance, be it pitting corrosion or filiform corrosion.
- This corrosion resistance is also favored by a low magnesium content of less than 0.20%, and preferably of 0.15%.
- the decrease in mechanical strength resulting from the reduction of the magnesium content is more than offset by the increase in the copper content, so that the mechanical strength is higher than for similar products in 4015.
- the products according to the invention have, in the naked state, a resistance to corrosion, measured by the puncture depth in the Sea Water Acetic Acid Test (SWAAT) according to the ASTM G85 standard, which is much better than that of the alloy 4015. They can therefore be used in industrial environments, for example to insulation panels for cables or pipes in workshops, signage and the building.
- SWAAT Sea Water Acetic Acid Test
- Sheet samples were prepared whose thickness (in mm) and chemical composition (in% by weight) are shown in Table 1: Table 1 Alloy e (mm) Yes Fe Cu mn mg AT 1.0 1.61 0.30 0.38 1.05 0.15 B 1.45 1.61 0.30 0.38 1.05 0.15 VS 1.0 1.60 0.58 0.15 1.09 0.28 D 1.45 1.55 0.50 0.17 1.06 0.28 E 1.45 1.59 0.59 0.13 1.16 0.33
- the alloys A and B are according to the invention, the alloys C to E are alloys 4015.
- the manufacturing range is conventional, and comprises a casting of plates, a hot rolling, a cold rolling, and a final work hardening. the state H12.
- the breaking strength R m (in MPa) the conventional yield strength at 0.2% R 0.2 (in MPa) and the elongation A 50 (in%) were measured. according to standard NF EN 10002-1 relating to tensile tests on metallic materials. The results are shown in Table 2: Table 2 Sample rm R 0.2 A 50 AT 176 168 3.2 VS 160 155 4.8
- alloy sheet A according to the invention has a better mechanical strength than the sheet of the same thickness of alloy C. which contains less copper but more magnesium.
- the depths of the pits were measured on the sheets using the SWAAT test, taking into account 5 stitches per sample, and averaging, for 3 samples of the same sheet, maximum depths and mean depths (in ⁇ m). The results are shown in Table 3 / Table 3 Alloy Maximum depth Average depth AT 230 196 B 250 189 VS 660 464 D 700 535 E 730 502
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Conductive Materials (AREA)
- Laminated Bodies (AREA)
- Extrusion Of Metal (AREA)
- Metal Rolling (AREA)
Claims (5)
- Verwendung eines für der Atmosphäre ausgesetzte Dämmplatten oder Bauteile für Gebäude und Signalisation bestimmten Walz- oder Strangpresserzeugnisses aus Aluminiumlegierung der Zusammensetzung (Gew.-%):Si : 1,2 - 2,2 Fe < 1,5 Cu : 0,2 - 0,8 Mn : 0,6 - 1,5 Mg < 0,20 Zn < 0,5 Ti < 0,10, Rest Aluminium und unvermeidbare Verunreinigungen.
- Verwendung nach Anspruch 1, dadurch gekennzeichnet, dass der Siliziumgehalt der Legierung zwischen 1,4 und 2 % liegt.
- Verwendung nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass der Kupfergehalt der Legierung zwischen 0,3 und 0,5 % liegt.
- Verwendung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass der Mangangehalt der Legierung zwischen 0,9 und 1,2 % liegt.
- Verwendung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass der Magnesiumgehalt der Legierung unter 0,15 % liegt.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0306783A FR2855833B1 (fr) | 2003-06-05 | 2003-06-05 | Produit lamine ou file en alliage d'aluminium a bonne resistance a la corrosion |
FR0306783 | 2003-06-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1484420A1 EP1484420A1 (de) | 2004-12-08 |
EP1484420B1 true EP1484420B1 (de) | 2010-06-02 |
Family
ID=33155655
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04356088A Expired - Lifetime EP1484421B1 (de) | 2003-06-05 | 2004-06-03 | Verwendung eines gewalzten oder stranggepressten Produkts aus Aluminium-Legierung mit einer guten Korrosionsbeständigkeit |
EP04356087A Expired - Lifetime EP1484420B1 (de) | 2003-06-05 | 2004-06-03 | Verwendung eines gewalzten oder stranggepressten Produkts aus Aluminium-Legierung mit hoher Korrosionbeständigkeit |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04356088A Expired - Lifetime EP1484421B1 (de) | 2003-06-05 | 2004-06-03 | Verwendung eines gewalzten oder stranggepressten Produkts aus Aluminium-Legierung mit einer guten Korrosionsbeständigkeit |
Country Status (4)
Country | Link |
---|---|
EP (2) | EP1484421B1 (de) |
AT (2) | ATE425273T1 (de) |
DE (2) | DE602004027443D1 (de) |
FR (1) | FR2855833B1 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007033827A1 (de) * | 2007-07-18 | 2009-01-22 | Technische Universität Clausthal | Aluminium-Gusslegierung und deren Verwendung |
WO2011042339A1 (en) * | 2009-10-08 | 2011-04-14 | Aleris Aluminum Duffel Bvba | Multilayer tube with an aluminium alloy core tube |
CN106661679A (zh) * | 2014-07-04 | 2017-05-10 | 爱励轧制产品德国有限责任公司 | 用于建筑工业的铝合金 |
CN111575513A (zh) * | 2020-06-12 | 2020-08-25 | 包头常铝北方铝业有限责任公司 | 一种铝合金带材及其制备方法和中空玻璃用铝隔条 |
CN112746199B (zh) * | 2020-12-16 | 2022-05-31 | 银邦金属复合材料股份有限公司 | 百叶窗用铝合金及其制备方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63216939A (ja) * | 1987-03-03 | 1988-09-09 | Kobe Steel Ltd | ろう付用高強度高耐食性アルミニウム合金複合材 |
FR2617188B1 (fr) * | 1987-06-23 | 1989-10-20 | Cegedur | Alliage a base d'al pour boitage et procede d'obtention |
JPH0456095A (ja) * | 1990-06-22 | 1992-02-24 | Arco Ind Kk | 3相交流アーク炉における大電流導体の配設方式 |
JPH0516577A (ja) * | 1991-07-08 | 1993-01-26 | Dainippon Printing Co Ltd | 反復印字可能なカードの利用方法 |
JP2925884B2 (ja) * | 1993-03-19 | 1999-07-28 | 川崎製鉄株式会社 | 加熱硬化性に優れたAl−Mg−Si系合金板材の製造方法 |
JPH08218143A (ja) * | 1995-02-14 | 1996-08-27 | Furukawa Electric Co Ltd:The | 熱交換器コネクタ用アルミニウム合金押出材及びその製造方法 |
JPH09256095A (ja) * | 1996-03-22 | 1997-09-30 | Furukawa Electric Co Ltd:The | 成形性に優れたアルミニウム合金板およびその製造方法 |
JPH09316577A (ja) * | 1996-05-30 | 1997-12-09 | Furukawa Electric Co Ltd:The | 熱交換器の冷媒通路部材用ブレージングシート |
JP4063388B2 (ja) * | 1998-02-20 | 2008-03-19 | 株式会社神戸製鋼所 | 表面性状に優れた成形加工用Al−Mg−Si系アルミニウム合金板及びその製造方法 |
JP3332885B2 (ja) * | 1999-04-20 | 2002-10-07 | 古河電気工業株式会社 | セミソリッド加工用アルミニウム基合金及びその加工部材の製造方法 |
-
2003
- 2003-06-05 FR FR0306783A patent/FR2855833B1/fr not_active Expired - Fee Related
-
2004
- 2004-06-03 EP EP04356088A patent/EP1484421B1/de not_active Expired - Lifetime
- 2004-06-03 EP EP04356087A patent/EP1484420B1/de not_active Expired - Lifetime
- 2004-06-03 DE DE602004027443T patent/DE602004027443D1/de not_active Expired - Lifetime
- 2004-06-03 AT AT04356088T patent/ATE425273T1/de not_active IP Right Cessation
- 2004-06-03 DE DE602004019840T patent/DE602004019840D1/de not_active Expired - Lifetime
- 2004-06-03 AT AT04356087T patent/ATE469990T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FR2855833B1 (fr) | 2007-03-16 |
ATE469990T1 (de) | 2010-06-15 |
EP1484421B1 (de) | 2009-03-11 |
EP1484421A1 (de) | 2004-12-08 |
ATE425273T1 (de) | 2009-03-15 |
EP1484420A1 (de) | 2004-12-08 |
DE602004027443D1 (de) | 2010-07-15 |
DE602004019840D1 (de) | 2009-04-23 |
FR2855833A1 (fr) | 2004-12-10 |
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