EP1468761A1 - Cylindre de coulée pour le moulage de feuilles d'aluminium ou d'alliages d'aluminium - Google Patents

Cylindre de coulée pour le moulage de feuilles d'aluminium ou d'alliages d'aluminium Download PDF

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Publication number
EP1468761A1
EP1468761A1 EP04006766A EP04006766A EP1468761A1 EP 1468761 A1 EP1468761 A1 EP 1468761A1 EP 04006766 A EP04006766 A EP 04006766A EP 04006766 A EP04006766 A EP 04006766A EP 1468761 A1 EP1468761 A1 EP 1468761A1
Authority
EP
European Patent Office
Prior art keywords
diffusion barrier
layer
casting
casting roll
roll according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04006766A
Other languages
German (de)
English (en)
Inventor
Hans-Jürgen Dipl.-Ing. Hemschemeier
Dirk Dr. Rode
Hark Dipl.-Ing. Schulze
Dietmar Kolbeck
Hans-Günter Dr. Wobker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KM Europa Metal AG
Original Assignee
KM Europa Metal AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KM Europa Metal AG filed Critical KM Europa Metal AG
Publication of EP1468761A1 publication Critical patent/EP1468761A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637Accessories therefor
    • B22D11/0648Casting surfaces
    • B22D11/0651Casting wheels

Definitions

  • the invention relates to a casting roller for casting strips of aluminum or Aluminum alloys.
  • the invention is based on the object To take measures with which the crack formation on a casting roll at least one copper cladding layer for casting aluminum strips or aluminum alloys can be slowed to the life of the Increase casting roller.
  • Diffusion barrier designed as a single-layer protective layer.
  • the one to create one Diffusion barrier required effort is therefore limited and impaired the economics of manufacturing and providing a casting roll in one only insignificant scope.
  • the Diffusion barrier from a through a high-energy thermal spray process applied metallic, metal-ceramic or ceramic protective layer is formed.
  • the thermal spray process can, for example, be plasma or Be laser spraying.
  • the metallic, metal-ceramic or ceramic layers can be based in particular on nickel, cobalt and oxides and carbides be formed.
  • the diffusion barrier consists of a electroplated chrome layer is formed.
  • Such a diffusion barrier only needs to have a thickness of approx. 5 ⁇ m to 20 ⁇ m. Because one repeated Reworking the casting roller in use would be relatively easy on site feasible chrome plating makes sense. Tampon electroplating is ideal for this, if necessary as part of normal reworking in a foundry can be carried out. Large pools for holding a casting roller are not required here.
  • the applied Chromium layer can be further improved in its properties by nitriding, because it also closes minimal cracks in the chrome layer can.
  • the diffusion barrier instead of a diffusion barrier made of a chrome layer, it is according to the characteristics of claim 5 possible, the diffusion barrier from a galvanic to form an applied layer of nickel or a nickel alloy.
  • a solution / suspension with oxide or phosphate-forming Metals such as chrome, zinc, titanium or zirconium, also in combination with aluminum or silicon oxides can be applied. Then such an order advantageously before starting a casting roll by a suitable one thermal treatment converted into the effective protective layer.
  • a diffusion barrier can also consist of a through Combustion generated carbon layer can be formed.
  • To burn the Carbon layer can, for example, at least one acetylene burner be used.
  • a carbon layer can also be formed from an oil / lubrication film.
  • the embodiment defined in claim 8 sees a diffusion barrier applied organic paint. After this varnish has dried, one should closed protective layer with a thickness of at least 10 ⁇ m should be present. As upper limit should not be exceeded 60 ⁇ m. Here is one ensure uniform wetting of the cladding layer, but this depends on the viscosity and the subsequent drying of the paint depends.
  • a diffusion barrier can also use a PVD / CVD method (Physical or Chemical Vapor Deposition), e.g. on the Base of TiN, CrN or TiAI.
  • PVD / CVD method Physical or Chemical Vapor Deposition
  • a diffusion barrier made of an inorganic Protective layer formed it is preferably in the range of 0.01 mm to 0.2 mm.
  • the thickness of the Diffusion barrier is in the range of 0.05 mm to 0.12 mm. Larger layer thicknesses are disadvantageous, since then under the swelling operating load Casting roller in turn can form cracks that lead to crack propagation in the Lead base material.
  • a diffusion barrier expediently a thickness between an inorganic protective layer 5 ⁇ m and 50 ⁇ m. This is particularly the case when the diffusion barrier is considered Carbon layer is deposited from a combustion process. Essential is also a closed, uniform layer. Can be applied also an oil / grease film. Ideally, cracking into one takes place here carbon-containing layer with a typical thickness of approx. 5 ⁇ m to 40 ⁇ m. However, a uniformly dense, less porous layer is preferred in the Target thickness range from 10 ⁇ m to 30 ⁇ m.
  • the diffusion barrier with a multi-layer protective layer to form similar layer combinations.
  • a multi-layer protective layer e.g. galvanic layers with possibly different properties in the Layers of the protective layer are particularly advantageous.
  • the diffusion barrier consists of a multi-layer protective layer with each other deviating layer combinations is formed. It can be for example metallic / metal-ceramic / ceramic base layers on the one hand and top layers on the other hand from a suspension order from a Act carbon layer, etc., whereby the barrier effect against diffusion of aluminum in the copper cladding layer can be specifically increased. Also PVD protective layers on a metallic base layer represent an advantageous one Protective layer.
  • Figure 1 in Figure 1 is a casting roll for casting strips of aluminum or Called aluminum alloys. The representation is not to scale.
  • This casting roller 1 has a cladding layer 2 made of copper or a copper alloy while the core 3 is made of steel.
  • a casting roll 1 is also conceivable with several, at least two, concentric cladding layers.
  • the peripheral surface 4 of the cladding layer 2 has a blocking effect against the diffusion of aluminum into the copper edge zone Provide diffusion barrier 5.
  • the diffusion barrier 5 is a single-layer protective layer executed.
  • the diffusion barrier 5 can be made by a high-energy thermal Metallic, metal-ceramic or ceramic spray applied Protective layer can be formed.
  • diffusion barrier 5 made of an electroplated chrome layer conceivable.
  • the diffusion barrier 5 can consist of a galvanically applied layer Nickel or a nickel alloy may be formed.
  • the diffusion barrier 5 by thermal Treatment of an applied to the surface 4 of the cladding layer 2 Solution / suspension with oxide or phosphate-forming metals is formed.
  • the diffusion barrier 5 can also be applied by applying an organic lacquer be educated.
  • the diffusion barrier 5 can be made using a PVD / CVD method applied protective layer may be formed.
  • the diffusion barrier 5 consists of an inorganic protective layer this a thickness D between 0.01 mm and 0.2 mm, preferably 0.05 mm to 0.12 mm.
  • a thickness becomes D between 5 ⁇ m and 50 ⁇ m.
  • Figure 2 is a casting roll 1a for casting strips of aluminum or Illustrated aluminum alloys, which also a cladding layer 2 made of copper has on a steel core 3.
  • Two layers 6, 7 are illustrated. These layers 6, 7 can be of the same type Layer combinations can be formed.
  • the layers 6, 7 are made of different ones Layer combinations are formed.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
EP04006766A 2003-04-17 2004-03-20 Cylindre de coulée pour le moulage de feuilles d'aluminium ou d'alliages d'aluminium Withdrawn EP1468761A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2003117666 DE10317666A1 (de) 2003-04-17 2003-04-17 Gießwalze zum Gießen von Bändern aus Aluminium oder Aluminium-legierungen
DE10317666 2003-04-17

Publications (1)

Publication Number Publication Date
EP1468761A1 true EP1468761A1 (fr) 2004-10-20

Family

ID=32892390

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04006766A Withdrawn EP1468761A1 (fr) 2003-04-17 2004-03-20 Cylindre de coulée pour le moulage de feuilles d'aluminium ou d'alliages d'aluminium

Country Status (3)

Country Link
EP (1) EP1468761A1 (fr)
JP (1) JP2004314170A (fr)
DE (1) DE10317666A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007101512A1 (fr) * 2006-03-09 2007-09-13 Sms Demag Ag Rouleau pour l'usinage des metaux, notamment rouleau de coulee continue ainsi que procede de fabrication d'un tel rouleau
CN100372621C (zh) * 2006-04-24 2008-03-05 江苏兴荣高新科技股份有限公司 一种铜铝复合管材的制造方法及该方法制造的铜铝复合管材
CN102418813A (zh) * 2010-09-28 2012-04-18 江苏兴荣高新科技股份有限公司 一种新型铜铝复合管
CN104138926A (zh) * 2014-06-20 2014-11-12 合肥长城制冷科技有限公司 一种制冷机铜铝复合管及其加工工艺
CN105344952A (zh) * 2015-09-30 2016-02-24 中钢集团西安重机有限公司 一种连铸机堆焊辊子及保证辊子堆焊层成份的工艺方法
IT201700036965A1 (it) * 2017-04-04 2018-10-04 Bruno Presezzi S P A Struttura di camicia per rulli di colata continua, particolarmente per la produzione di nastri in alluminio o in lega di alluminio e di nastri in leghe a base di zinco
CN111515617A (zh) * 2020-03-24 2020-08-11 葫芦岛华扬电力复合新材料有限公司 一种中低速磁悬浮列车方形接地块的生产方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100776097B1 (ko) 2006-06-20 2007-11-15 김충열 동복알루미늄선의 제조방법
KR100791702B1 (ko) * 2007-02-13 2008-01-04 엘에스전선 주식회사 동복 알루미늄선의 제조방법

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0320572A2 (fr) * 1987-12-17 1989-06-21 Kawasaki Steel Corporation Cylindre de refroidissement pour la fabrication de bandes métalliques minces trempées
JPH02160145A (ja) * 1988-12-10 1990-06-20 Kawasaki Steel Corp 急冷薄帯製造用の冷却ロール及びその製造方法
WO1996002340A1 (fr) * 1994-07-18 1996-02-01 Siemens Aktiengesellschaft Couche de protection contre l'usure de cylindres de coulage
WO1998016335A1 (fr) * 1996-10-17 1998-04-23 Gränges Ab Coulage de bandes d'aluminium
WO1998052706A1 (fr) * 1997-05-23 1998-11-26 Voest-Alpine Industrieanlagenbau Gmbh Cylindre de coulee pour une installation de coulee continue de bandes minces
US20020153123A1 (en) * 2001-02-20 2002-10-24 Ali Unal Continuous casting of aluminum

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0320572A2 (fr) * 1987-12-17 1989-06-21 Kawasaki Steel Corporation Cylindre de refroidissement pour la fabrication de bandes métalliques minces trempées
JPH02160145A (ja) * 1988-12-10 1990-06-20 Kawasaki Steel Corp 急冷薄帯製造用の冷却ロール及びその製造方法
WO1996002340A1 (fr) * 1994-07-18 1996-02-01 Siemens Aktiengesellschaft Couche de protection contre l'usure de cylindres de coulage
WO1998016335A1 (fr) * 1996-10-17 1998-04-23 Gränges Ab Coulage de bandes d'aluminium
WO1998052706A1 (fr) * 1997-05-23 1998-11-26 Voest-Alpine Industrieanlagenbau Gmbh Cylindre de coulee pour une installation de coulee continue de bandes minces
US20020153123A1 (en) * 2001-02-20 2002-10-24 Ali Unal Continuous casting of aluminum

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 014, no. 416 (M - 1021) 7 September 1990 (1990-09-07) *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007101512A1 (fr) * 2006-03-09 2007-09-13 Sms Demag Ag Rouleau pour l'usinage des metaux, notamment rouleau de coulee continue ainsi que procede de fabrication d'un tel rouleau
CN100372621C (zh) * 2006-04-24 2008-03-05 江苏兴荣高新科技股份有限公司 一种铜铝复合管材的制造方法及该方法制造的铜铝复合管材
CN102418813A (zh) * 2010-09-28 2012-04-18 江苏兴荣高新科技股份有限公司 一种新型铜铝复合管
CN102418813B (zh) * 2010-09-28 2013-08-21 江苏兴荣高新科技股份有限公司 一种新型铜铝复合管
CN104138926A (zh) * 2014-06-20 2014-11-12 合肥长城制冷科技有限公司 一种制冷机铜铝复合管及其加工工艺
CN105344952A (zh) * 2015-09-30 2016-02-24 中钢集团西安重机有限公司 一种连铸机堆焊辊子及保证辊子堆焊层成份的工艺方法
IT201700036965A1 (it) * 2017-04-04 2018-10-04 Bruno Presezzi S P A Struttura di camicia per rulli di colata continua, particolarmente per la produzione di nastri in alluminio o in lega di alluminio e di nastri in leghe a base di zinco
EP3385012A1 (fr) * 2017-04-04 2018-10-10 Bruno Presezzi S.p.A. Enveloppe pour un rouleau utilisé dans le coulage continu, en particulier pour la production de bandes d'aluminium ou d'alliage d'aluminium et de bandes en alliage à base de zinc
CN111515617A (zh) * 2020-03-24 2020-08-11 葫芦岛华扬电力复合新材料有限公司 一种中低速磁悬浮列车方形接地块的生产方法

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JP2004314170A (ja) 2004-11-11
DE10317666A1 (de) 2004-11-04

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