EP1406044B1 - Verfahren und Einrichtung zur Abfallverarbeitung - Google Patents

Verfahren und Einrichtung zur Abfallverarbeitung Download PDF

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Publication number
EP1406044B1
EP1406044B1 EP03022047A EP03022047A EP1406044B1 EP 1406044 B1 EP1406044 B1 EP 1406044B1 EP 03022047 A EP03022047 A EP 03022047A EP 03022047 A EP03022047 A EP 03022047A EP 1406044 B1 EP1406044 B1 EP 1406044B1
Authority
EP
European Patent Office
Prior art keywords
waste
incineration chamber
ash
pyrolysis
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03022047A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1406044A1 (de
Inventor
Heinz Albert Steimen
Björn Fossen
Vidar Brenden
Reidar Brattebrekke
Trond Kaasa
Joachim Dr.Ing.Habil. Otschik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Zosen Innova AG
Original Assignee
Norsk Inova AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2002145954 external-priority patent/DE10245954B4/de
Application filed by Norsk Inova AS filed Critical Norsk Inova AS
Publication of EP1406044A1 publication Critical patent/EP1406044A1/de
Application granted granted Critical
Publication of EP1406044B1 publication Critical patent/EP1406044B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F23G5/0276Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/303Burning pyrogases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/304Burning pyrosolids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00Combustion
    • F23G2202/40Combustion in a pulsed combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/12Waste feed arrangements using conveyors
    • F23G2205/121Screw conveyor

Definitions

  • the invention relates to a method for waste disposal, in particular of wet waste, in at least a first combustion chamber, in which the waste is transported from a feed point with a transport screw under heating.
  • a further aspect of the invention relates to a corresponding device for waste processing, with which this method can be carried out.
  • TOC Total Organic Compound
  • the pyrolysis reactor converts the waste into carbonization gas and solid pyrolysis residue. These two substances are fed to a high-temperature reactor for combustion. In principle, therefore, pyrolysis and oxidation, in particular of the pyrolysis gas are separated.
  • the first heater causes a basic heating in the pyrolysis reactor in particular by the waste heat from the flue gas of the high-temperature reactor, wherein an indirect heating is carried out with a circulating heat medium.
  • the state of the art also includes a device for refuse processing, in which a charging device, a degassing channel, in which at least one transport screw is arranged, and a high-temperature reactor follow one another ( DE 43 30 788 A1 ).
  • the degassing is surrounded by a jacket heating, which can be operated with steam or gas.
  • the transport screw transports waste continuously from the charging device to the high-temperature reactor, the waste being heated to a temperature of approximately 600 ° C. and degassed.
  • One with it resulting solid residue and the gas are fed to the high-temperature reactor in which synthesis gas and a melt arise, which are further treated externally.
  • air can be supplied to a middle section of the degasification duct, as a result of which carbonization gas and residual carbon are burned in the degassing duct and thus the waste is heated directly.
  • the screw conveyor may be formed hollow to be charged for heating with steam or gas.
  • the biomass In the gasification chamber, the biomass can burn over a grate under which primary air is injected into an ash bed. Combustion gas or exhaust gas produced during combustion is conducted via a pipe into a gas combustion chamber, into which secondary air is introduced. Pure exhaust gas, which consists essentially only of CO 2 , H 2 O, O 2 and N 2 , should be discharged from the gasification chamber.
  • the screw conveyor is used only for the transport of biomass, but not for drying or pyrolysis.
  • the prior art includes an apparatus and a process for the thermal treatment of solid or liquid waste, where the waste is processed by dry distillation and drying ( WO 00/13811 ).
  • the waste is transported through a heated furnace to the atmosphere in the furnace by means of a screw conveyor in a thermally insulated, heat-proof evaporation chamber.
  • the heated waste is separated by evaporation into solid and liquid components.
  • One of the exits of the vaporization chamber leads to a condenser in which vapors or gases formed in the vaporization chamber are condensed.
  • Other outputs of the evaporation chambers are provided for non-condensable gas as well as solid components.
  • the present invention is therefore based on the object to develop a method for waste disposal, with the waste of various types, especially wet waste is uncomplicated, safely and efficiently burned to ash and flue gas with very low TOC, without a long residence time in the implementation required by the procedure.
  • a long residence time can be set that, for example, legal requirements are met.
  • a first step comprises drying the waste during its transport via at least one end-side section of a transport screw such as, for example US-A-3,027,854 is known.
  • a transport screw such as, for example US-A-3,027,854
  • two high-quality fuels namely pyrolysis gas or carbonization gas and pyrolysis coke
  • the heat required for drying and pyrolysis is formed by combustion of the pyrolysis mainly in the first combustion chamber, so that the process itself keep going can.
  • the end-side section of the transport screw is in direct contact with the atmosphere of the first combustion chamber, which is supplied with air, for example, by a ventilator.
  • the first combustion chamber contains ash, flue gas and residual partially-burned pyrolysis gas or carbonization gas.
  • the second step of the process by injecting pulsating air into an ash bed which collects in the first combustion chamber at the bottom, causes the TOC content of the ash to be further reduced. For this purpose, accumulating ash after a longer residence time discharged from the first combustion chamber, which is a multiple of the residence time of the gases.
  • a baked ash layer or ash bridge which may have formed, broken through, so that the removal of the ash from the first combustion chamber can be carried out unhindered.
  • the pyrolysis gas is combined in a third step with the flue gas formed in the first combustion chamber, which contains oxygen, intensively mixed and post-combusted in a second combustion chamber. It is essential in the third step, a high contact rate between the flue gas or its oxygen and the partially burned pyrolysis gas.
  • Such a high contact rate or intensive mixing of the partially combusted pyrolysis gas and flue gas in the second combustion chamber is achieved according to claim 7 reliably with a turbulator package, which, for example. may include a little self-consuming pack of high temperature resistant wire.
  • the turbulator package can also serve as a separator, which retains fly ash according to claim 2 from the nachverbumbleden pyrolysis gas and flue gas in the second combustion chamber.
  • the turbulator can be provided for this purpose but also a cyclone.
  • the waste is in the furnace inside first on the screw conveyor and then in the free area of the furnace interior of a furnace atmosphere of 850 ° C to 1200 ° C exposed.
  • parallel to the processing wet waste with a first screw with a first variable speed drive waste low moisture with a second screw with a controlled independently from the first variable speed drive second drive can also be processed in direct contact with the furnace atmosphere.
  • the temperature of the hot atmosphere is not only in the first combustion chamber, but also in the second combustion chamber 850 ° C to 1200 ° C. If the temperature goes beyond that, the structure of the device with which the method is exercised would be jeopardized.
  • a definition of wet waste with a water content of up to 75 percent by mass and the dry waste with a water content of up to 15 percent by mass is given in claim 5.
  • the second process step can be realized in a less complicated manner according to claim 6 as the first alternative that the pulsating air is injected into the ash bed in only one radial distance.
  • the injection takes place as a second alternative in two different radial distances: This can be achieved that a lower portion of the ash bed is cooled by air injection and in this the ash screw.
  • the injection which takes place at a greater radial distance from the ash screw, with respect to the breaking up of the baked layer or ash bridge is particularly effective.
  • the air nozzles according to claim 13 are arranged as a first alternative in at least one row at only a radial distance to the ash screw and according to claim 14 in at least two rows at two radial distances.
  • a liquid or gaseous auxiliary fuel burner associated with the device of claim 19 is activated until the atmosphere adjacent to the screw conveyor reaches at least 850 ° C C reached. Subsequently, the supply of waste begins. As soon as sufficient high-quality fuel, in particular pyrolysis gas, has been produced from this, which burns in the first combustion chamber when the air is supplied, and the atmosphere of the first combustion chamber and thus sufficiently heated in the screw conveyor, the supply of additional fuel can be stopped because the combustion process in the first combustion chamber itself can receive.
  • the built-up of several modules waste processing apparatus according to claim 8 is particularly favorable production for the production of devices of different performance.
  • the furnace volume can be easily adapted to the amount of waste to be burned.
  • the residence time of the flue gas in the device can be adjusted.
  • the second module which includes the second combustion chamber, according to claim 9 are composed of a plurality of volume segments, wherein the volume segments are interconnected via preferably horizontal passages for the partially burned pyrolysis gas.
  • An outlet opening of a volume segment forms an access opening with an inlet opening of an adjacent volume segment.
  • An exit port of a volume segment may communicate with its entrance port via a turbulator package. If the turbulator packages are packaged ever closer in such fluidly arranged behind one another volume segments, a particularly good fly ash separation effect is achieved.
  • the volumes of the modules or volume segments can be made easily variable by insertable wall spacers to tune the residence time by volume change.
  • volume adjustment to the throughput of the burning waste also serves to minimize the TOC content.
  • the turbulator package provided in each case in the second module or at least one volume segment of the second module preferably comprises a packing of high temperature resistant wire according to claim 11.
  • the wire may vibrate under the flow of the gas stream passed through the turbulator package, thereby improving the reaction rate of residual combustion of the partially combusted pyrolysis gas with the residual oxygen of the flue gas through intensive contact.
  • the discharge device according to claim 13 is preferably realized as an ash screw.
  • the air nozzles are arranged at least in a row at a radial distance to the ash screw to inject the air pulsating into the ash bed.
  • the end-side portion of the screw conveyor which is provided for transporting the waste into the first combustion chamber with drying and subsequent pyrolysis, as already proposed, taken down in a half-shell coat of refractory material.
  • two transport screws one for each wet moist waste and dry waste disposed at a head of the first combustion chamber.
  • the screw conveyor can be cooled according to claim 17 inside by forced air, so as not to be thermally overloaded.
  • the device comprises a first module 1 and a second module 2, which is composed of volume segments 3 and 4.
  • the first module includes, as explained below, a first combustion chamber 6 and the second module 2, a second combustion chamber 7.
  • the volumes of the modules 1, 2 and the volume segments 3-4 of the second module 2 can by inserting wall spacers 8-10 adapted to the required capacity of the waste incinerator.
  • the first module 1 is with the Volume segment 3 of the second module 2 connected via a passage 12 gas-conducting.
  • Another passage 13 connects the volume segment 3 to the further volume segment 4 of the second module 2.
  • a further passage 14 of the second volume segment may lead to a third volume segment or forms an exit of the device.
  • the optimal volume segment 4 is shown with broken lines. Apart from the exit of the last volume segment, each passage connects an entrance opening of a module eg 2 to an exit opening of an adjacent module eg 1. The entrance openings and the exit openings are not marked in the drawing.
  • the transport screw 15 Facing away from a feed side 17 is the first combustion chamber 6, which is in open communication with the space 18 surrounding the transport screws 15, 16.
  • the screw conveyors are open at the top and includes only on their undersides of a non-illustrated shell-shaped, approximately U-shaped shell of refractory material.
  • the coat is suitably formed from a furnace lining of firebrick.
  • a burner 19 for additional fuel such as diesel fuel or waste oil is arranged in the space 18 so that it can heat the atmosphere in the space 18 and the transported with the screw conveyors 15, 16 waste after ignition of the additional fuel.
  • first combustion chamber 6 further opens an air fan 20, which is housed below the space 18 in a frame.
  • an ash collecting and transporting device 21 is arranged with an ash screw 22 so that they can catch the ash resulting from the combustion of the pyrolysis products, which subsequently discharged with the ash screw becomes.
  • an ash collecting and transporting device 21 is arranged with an ash screw 22 so that they can catch the ash resulting from the combustion of the pyrolysis products, which subsequently discharged with the ash screw becomes.
  • At a radial distance from the transport screw 22 are still in the first combustion chamber 6 four rows of air nozzles 23 - 26, which are acted upon by a line 27 with pulsating air.
  • the rows 23 and 26 are in a closer radial distance to the ash screw 22 than the rows 24 and 25th
  • the output of the first combustion chamber 6 at the passage 12 is located in the upper region of the first combustion chamber 6 for the passage of flue gas and partially combusted pyrolysis gas to the second module. 2
  • a turbulator package 29 is housed, in such a way that it separates the passage 12, in which the flue gas and partially burned pyrolysis gas enters, from the output serving as the passage 13 of this volume segment.
  • An openwork wall 30 also serves this purpose.
  • the turbulator package 29 is formed in the present embodiment from a packing of high-temperature-resistant wire, wherein the packing density is adapted to the respective individual requirements. At low packing density, the flue gas and the largely burned pyrolysis gas is passed to the passage 13 with little resistance.
  • the turbulator package 29 can also exert a separation function for fly ash from the flue gas, which is conveyed at a higher packing density.
  • an optional air blower 31 which is housed below the turbulator package 29 in the volume segment 3 of the second module 2.
  • volume segment 3 volume segment 4 is similar to the volume segment 3 constructed, but does not include an air blower.
  • the volume segment 4 may be formed without a further turbulator package 32, but with the flow path between the passage 13 and the passage 14 with forming wall 33.
  • the method of waste processing that can be performed with the described device is initiated by heating the space 18 by means of the burner 19. Once the space 18 has reached a temperature of at least 850 ° C, the waste to be incinerated is fed to the transport screws 15 and 16, namely the transport screw 15 wet waste and the screw conveyor 16 dry waste. In the course of transport to the first combustion chamber 6, the wet waste is first dried. In the prevailing in the space 18 temperature> 850 ° C, the waste, which is transported with the screw conveyors 15 and 16 further to the first combustion chamber 6, pyrolyzed, resulting in high-quality fuels pyrolysis and pyrolysis.
  • the pyrolysis gas and the pyrolysis coke are burned, wherein the burn-out of these pyrolysis products in the first combustion chamber 6 is largely completed. In it are finally ash, flue gas with partially burned pyrolysis gas available. The TOC content of these products is already low after the described first step.
  • the TOC content of the ash collected from the ash capture and transport means 21 is further reduced by injecting pulsating air into the forming ash bed 34 by means of the rows 23-26 air nozzles.
  • the air flow through the line 27 can be interrupted every second.
  • the pulsating Injected compressed air has the further effect that a caked layer is broken on the ash bed and so can also be carried away with the ash screw 22.
  • To break through serve primarily the rows 23 and 26 air nozzles at a greater distance to the ash screw.
  • the rows of air nozzles 24 and 25 are closer to the ash screw 22 to cool it over the ash bed 34.
  • the second step achieves that high quality ash, i. such is discharged with a very low TOC content from the first combustion chamber 6.
  • the flue gas and partially burned pyrolysis gas flows through the turbulator package, with which a high contact rate between the partially burned pyrolysis gas and the oxygen present in the flue gas is achieved, so that both gases are mixed intensively and the pyrolysis gas is post-combusted.
  • additional air can contribute to the afterburning which is transported by the air blower 31 in the space upstream of the turbulator package 29.
  • the turbulator package 29 in the second module 2 can continue to act as a separator for fly ash, especially in dense packing.
  • the turbulator package 29 can be supplemented with a vibrator and a fly ash discharge device.
  • volume segments due to their flow path between the passages 12 and input and output affect the residence time. It may therefore be useful to have subsequent volume segments such as the volume segment 4 without turbulator package to ensure a sufficient flue gas residence time in the device. In this way, for example, at least two seconds residence time, as prescribed by the (German) Federal Emission Control Law, can be achieved with certainty.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
EP03022047A 2002-10-02 2003-10-01 Verfahren und Einrichtung zur Abfallverarbeitung Expired - Lifetime EP1406044B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2002145954 DE10245954B4 (de) 2002-07-23 2002-10-02 Verfahren und Einrichtung zur Abfallverarbeitung
DE10245954 2002-10-02

Publications (2)

Publication Number Publication Date
EP1406044A1 EP1406044A1 (de) 2004-04-07
EP1406044B1 true EP1406044B1 (de) 2007-07-18

Family

ID=29414339

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03022047A Expired - Lifetime EP1406044B1 (de) 2002-10-02 2003-10-01 Verfahren und Einrichtung zur Abfallverarbeitung

Country Status (4)

Country Link
EP (1) EP1406044B1 (no)
AT (1) ATE367558T1 (no)
DE (1) DE50307688D1 (no)
NO (1) NO324180B1 (no)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2553871C2 (ru) * 2013-09-11 2015-06-20 Антон Дмитриевич Овсянко Устройство для пиролиза углеродосодержащего сырья
CN113845934B (zh) * 2021-09-28 2024-01-23 石家庄卓度橡塑设备有限公司 橡胶软化油加工装置及方法
CN114110611B (zh) * 2021-11-08 2023-03-14 西安交通大学 一种带蓄热及烘干功能的垃圾热解气化处理系统
CN114383136A (zh) * 2021-12-31 2022-04-22 中环国投生态科技股份有限公司 一种垃圾热解气化炉

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3027854A (en) * 1957-11-14 1962-04-03 Fred E Akerlund Apparatus and process for thermal destruction of waste materials
US5255634A (en) * 1991-04-22 1993-10-26 Manufacturing And Technology Conversion International, Inc. Pulsed atmospheric fluidized bed combustor apparatus
EP0692679A3 (de) * 1994-07-13 1997-01-02 Kloeckner Humboldt Deutz Ag Verfahren und anlagentechnische Schaltung zur Trocknung und Verbrennung von Klärschlamm
JP4154029B2 (ja) * 1998-04-07 2008-09-24 株式会社東芝 廃棄物の処理方法および廃棄物処理装置
GB2359874B (en) * 2000-02-29 2003-12-31 Andrew William Webster Gasification auger
KR100482187B1 (ko) * 2001-09-20 2005-04-13 니폰 조키 세야쿠 가부시키가이샤 유기폐기물의 탄화처리방법 및 장치

Also Published As

Publication number Publication date
DE50307688D1 (de) 2007-08-30
NO20034397L (no) 2004-04-05
NO324180B1 (no) 2007-09-03
ATE367558T1 (de) 2007-08-15
NO20034397D0 (no) 2003-10-01
EP1406044A1 (de) 2004-04-07

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