EP1406044B1 - Verfahren und Einrichtung zur Abfallverarbeitung - Google Patents
Verfahren und Einrichtung zur Abfallverarbeitung Download PDFInfo
- Publication number
- EP1406044B1 EP1406044B1 EP03022047A EP03022047A EP1406044B1 EP 1406044 B1 EP1406044 B1 EP 1406044B1 EP 03022047 A EP03022047 A EP 03022047A EP 03022047 A EP03022047 A EP 03022047A EP 1406044 B1 EP1406044 B1 EP 1406044B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- waste
- incineration chamber
- ash
- pyrolysis
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 32
- 230000008569 process Effects 0.000 title claims description 13
- 238000000197 pyrolysis Methods 0.000 claims abstract description 62
- 238000002485 combustion reaction Methods 0.000 claims abstract description 60
- 239000007789 gas Substances 0.000 claims abstract description 50
- 239000003546 flue gas Substances 0.000 claims abstract description 28
- 239000002956 ash Substances 0.000 claims description 53
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 26
- 239000000446 fuel Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000010881 fly ash Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 230000000717 retained effect Effects 0.000 claims 1
- 238000002347 injection Methods 0.000 abstract description 5
- 239000007924 injection Substances 0.000 abstract description 5
- 230000032258 transport Effects 0.000 description 29
- 238000010438 heat treatment Methods 0.000 description 13
- 238000007872 degassing Methods 0.000 description 9
- 238000002309 gasification Methods 0.000 description 7
- 238000012856 packing Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000002028 Biomass Substances 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000571 coke Substances 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0276—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/303—Burning pyrogases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/304—Burning pyrosolids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/40—Combustion in a pulsed combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2205/00—Waste feed arrangements
- F23G2205/12—Waste feed arrangements using conveyors
- F23G2205/121—Screw conveyor
Definitions
- the invention relates to a method for waste disposal, in particular of wet waste, in at least a first combustion chamber, in which the waste is transported from a feed point with a transport screw under heating.
- a further aspect of the invention relates to a corresponding device for waste processing, with which this method can be carried out.
- TOC Total Organic Compound
- the pyrolysis reactor converts the waste into carbonization gas and solid pyrolysis residue. These two substances are fed to a high-temperature reactor for combustion. In principle, therefore, pyrolysis and oxidation, in particular of the pyrolysis gas are separated.
- the first heater causes a basic heating in the pyrolysis reactor in particular by the waste heat from the flue gas of the high-temperature reactor, wherein an indirect heating is carried out with a circulating heat medium.
- the state of the art also includes a device for refuse processing, in which a charging device, a degassing channel, in which at least one transport screw is arranged, and a high-temperature reactor follow one another ( DE 43 30 788 A1 ).
- the degassing is surrounded by a jacket heating, which can be operated with steam or gas.
- the transport screw transports waste continuously from the charging device to the high-temperature reactor, the waste being heated to a temperature of approximately 600 ° C. and degassed.
- One with it resulting solid residue and the gas are fed to the high-temperature reactor in which synthesis gas and a melt arise, which are further treated externally.
- air can be supplied to a middle section of the degasification duct, as a result of which carbonization gas and residual carbon are burned in the degassing duct and thus the waste is heated directly.
- the screw conveyor may be formed hollow to be charged for heating with steam or gas.
- the biomass In the gasification chamber, the biomass can burn over a grate under which primary air is injected into an ash bed. Combustion gas or exhaust gas produced during combustion is conducted via a pipe into a gas combustion chamber, into which secondary air is introduced. Pure exhaust gas, which consists essentially only of CO 2 , H 2 O, O 2 and N 2 , should be discharged from the gasification chamber.
- the screw conveyor is used only for the transport of biomass, but not for drying or pyrolysis.
- the prior art includes an apparatus and a process for the thermal treatment of solid or liquid waste, where the waste is processed by dry distillation and drying ( WO 00/13811 ).
- the waste is transported through a heated furnace to the atmosphere in the furnace by means of a screw conveyor in a thermally insulated, heat-proof evaporation chamber.
- the heated waste is separated by evaporation into solid and liquid components.
- One of the exits of the vaporization chamber leads to a condenser in which vapors or gases formed in the vaporization chamber are condensed.
- Other outputs of the evaporation chambers are provided for non-condensable gas as well as solid components.
- the present invention is therefore based on the object to develop a method for waste disposal, with the waste of various types, especially wet waste is uncomplicated, safely and efficiently burned to ash and flue gas with very low TOC, without a long residence time in the implementation required by the procedure.
- a long residence time can be set that, for example, legal requirements are met.
- a first step comprises drying the waste during its transport via at least one end-side section of a transport screw such as, for example US-A-3,027,854 is known.
- a transport screw such as, for example US-A-3,027,854
- two high-quality fuels namely pyrolysis gas or carbonization gas and pyrolysis coke
- the heat required for drying and pyrolysis is formed by combustion of the pyrolysis mainly in the first combustion chamber, so that the process itself keep going can.
- the end-side section of the transport screw is in direct contact with the atmosphere of the first combustion chamber, which is supplied with air, for example, by a ventilator.
- the first combustion chamber contains ash, flue gas and residual partially-burned pyrolysis gas or carbonization gas.
- the second step of the process by injecting pulsating air into an ash bed which collects in the first combustion chamber at the bottom, causes the TOC content of the ash to be further reduced. For this purpose, accumulating ash after a longer residence time discharged from the first combustion chamber, which is a multiple of the residence time of the gases.
- a baked ash layer or ash bridge which may have formed, broken through, so that the removal of the ash from the first combustion chamber can be carried out unhindered.
- the pyrolysis gas is combined in a third step with the flue gas formed in the first combustion chamber, which contains oxygen, intensively mixed and post-combusted in a second combustion chamber. It is essential in the third step, a high contact rate between the flue gas or its oxygen and the partially burned pyrolysis gas.
- Such a high contact rate or intensive mixing of the partially combusted pyrolysis gas and flue gas in the second combustion chamber is achieved according to claim 7 reliably with a turbulator package, which, for example. may include a little self-consuming pack of high temperature resistant wire.
- the turbulator package can also serve as a separator, which retains fly ash according to claim 2 from the nachverbumbleden pyrolysis gas and flue gas in the second combustion chamber.
- the turbulator can be provided for this purpose but also a cyclone.
- the waste is in the furnace inside first on the screw conveyor and then in the free area of the furnace interior of a furnace atmosphere of 850 ° C to 1200 ° C exposed.
- parallel to the processing wet waste with a first screw with a first variable speed drive waste low moisture with a second screw with a controlled independently from the first variable speed drive second drive can also be processed in direct contact with the furnace atmosphere.
- the temperature of the hot atmosphere is not only in the first combustion chamber, but also in the second combustion chamber 850 ° C to 1200 ° C. If the temperature goes beyond that, the structure of the device with which the method is exercised would be jeopardized.
- a definition of wet waste with a water content of up to 75 percent by mass and the dry waste with a water content of up to 15 percent by mass is given in claim 5.
- the second process step can be realized in a less complicated manner according to claim 6 as the first alternative that the pulsating air is injected into the ash bed in only one radial distance.
- the injection takes place as a second alternative in two different radial distances: This can be achieved that a lower portion of the ash bed is cooled by air injection and in this the ash screw.
- the injection which takes place at a greater radial distance from the ash screw, with respect to the breaking up of the baked layer or ash bridge is particularly effective.
- the air nozzles according to claim 13 are arranged as a first alternative in at least one row at only a radial distance to the ash screw and according to claim 14 in at least two rows at two radial distances.
- a liquid or gaseous auxiliary fuel burner associated with the device of claim 19 is activated until the atmosphere adjacent to the screw conveyor reaches at least 850 ° C C reached. Subsequently, the supply of waste begins. As soon as sufficient high-quality fuel, in particular pyrolysis gas, has been produced from this, which burns in the first combustion chamber when the air is supplied, and the atmosphere of the first combustion chamber and thus sufficiently heated in the screw conveyor, the supply of additional fuel can be stopped because the combustion process in the first combustion chamber itself can receive.
- the built-up of several modules waste processing apparatus according to claim 8 is particularly favorable production for the production of devices of different performance.
- the furnace volume can be easily adapted to the amount of waste to be burned.
- the residence time of the flue gas in the device can be adjusted.
- the second module which includes the second combustion chamber, according to claim 9 are composed of a plurality of volume segments, wherein the volume segments are interconnected via preferably horizontal passages for the partially burned pyrolysis gas.
- An outlet opening of a volume segment forms an access opening with an inlet opening of an adjacent volume segment.
- An exit port of a volume segment may communicate with its entrance port via a turbulator package. If the turbulator packages are packaged ever closer in such fluidly arranged behind one another volume segments, a particularly good fly ash separation effect is achieved.
- the volumes of the modules or volume segments can be made easily variable by insertable wall spacers to tune the residence time by volume change.
- volume adjustment to the throughput of the burning waste also serves to minimize the TOC content.
- the turbulator package provided in each case in the second module or at least one volume segment of the second module preferably comprises a packing of high temperature resistant wire according to claim 11.
- the wire may vibrate under the flow of the gas stream passed through the turbulator package, thereby improving the reaction rate of residual combustion of the partially combusted pyrolysis gas with the residual oxygen of the flue gas through intensive contact.
- the discharge device according to claim 13 is preferably realized as an ash screw.
- the air nozzles are arranged at least in a row at a radial distance to the ash screw to inject the air pulsating into the ash bed.
- the end-side portion of the screw conveyor which is provided for transporting the waste into the first combustion chamber with drying and subsequent pyrolysis, as already proposed, taken down in a half-shell coat of refractory material.
- two transport screws one for each wet moist waste and dry waste disposed at a head of the first combustion chamber.
- the screw conveyor can be cooled according to claim 17 inside by forced air, so as not to be thermally overloaded.
- the device comprises a first module 1 and a second module 2, which is composed of volume segments 3 and 4.
- the first module includes, as explained below, a first combustion chamber 6 and the second module 2, a second combustion chamber 7.
- the volumes of the modules 1, 2 and the volume segments 3-4 of the second module 2 can by inserting wall spacers 8-10 adapted to the required capacity of the waste incinerator.
- the first module 1 is with the Volume segment 3 of the second module 2 connected via a passage 12 gas-conducting.
- Another passage 13 connects the volume segment 3 to the further volume segment 4 of the second module 2.
- a further passage 14 of the second volume segment may lead to a third volume segment or forms an exit of the device.
- the optimal volume segment 4 is shown with broken lines. Apart from the exit of the last volume segment, each passage connects an entrance opening of a module eg 2 to an exit opening of an adjacent module eg 1. The entrance openings and the exit openings are not marked in the drawing.
- the transport screw 15 Facing away from a feed side 17 is the first combustion chamber 6, which is in open communication with the space 18 surrounding the transport screws 15, 16.
- the screw conveyors are open at the top and includes only on their undersides of a non-illustrated shell-shaped, approximately U-shaped shell of refractory material.
- the coat is suitably formed from a furnace lining of firebrick.
- a burner 19 for additional fuel such as diesel fuel or waste oil is arranged in the space 18 so that it can heat the atmosphere in the space 18 and the transported with the screw conveyors 15, 16 waste after ignition of the additional fuel.
- first combustion chamber 6 further opens an air fan 20, which is housed below the space 18 in a frame.
- an ash collecting and transporting device 21 is arranged with an ash screw 22 so that they can catch the ash resulting from the combustion of the pyrolysis products, which subsequently discharged with the ash screw becomes.
- an ash collecting and transporting device 21 is arranged with an ash screw 22 so that they can catch the ash resulting from the combustion of the pyrolysis products, which subsequently discharged with the ash screw becomes.
- At a radial distance from the transport screw 22 are still in the first combustion chamber 6 four rows of air nozzles 23 - 26, which are acted upon by a line 27 with pulsating air.
- the rows 23 and 26 are in a closer radial distance to the ash screw 22 than the rows 24 and 25th
- the output of the first combustion chamber 6 at the passage 12 is located in the upper region of the first combustion chamber 6 for the passage of flue gas and partially combusted pyrolysis gas to the second module. 2
- a turbulator package 29 is housed, in such a way that it separates the passage 12, in which the flue gas and partially burned pyrolysis gas enters, from the output serving as the passage 13 of this volume segment.
- An openwork wall 30 also serves this purpose.
- the turbulator package 29 is formed in the present embodiment from a packing of high-temperature-resistant wire, wherein the packing density is adapted to the respective individual requirements. At low packing density, the flue gas and the largely burned pyrolysis gas is passed to the passage 13 with little resistance.
- the turbulator package 29 can also exert a separation function for fly ash from the flue gas, which is conveyed at a higher packing density.
- an optional air blower 31 which is housed below the turbulator package 29 in the volume segment 3 of the second module 2.
- volume segment 3 volume segment 4 is similar to the volume segment 3 constructed, but does not include an air blower.
- the volume segment 4 may be formed without a further turbulator package 32, but with the flow path between the passage 13 and the passage 14 with forming wall 33.
- the method of waste processing that can be performed with the described device is initiated by heating the space 18 by means of the burner 19. Once the space 18 has reached a temperature of at least 850 ° C, the waste to be incinerated is fed to the transport screws 15 and 16, namely the transport screw 15 wet waste and the screw conveyor 16 dry waste. In the course of transport to the first combustion chamber 6, the wet waste is first dried. In the prevailing in the space 18 temperature> 850 ° C, the waste, which is transported with the screw conveyors 15 and 16 further to the first combustion chamber 6, pyrolyzed, resulting in high-quality fuels pyrolysis and pyrolysis.
- the pyrolysis gas and the pyrolysis coke are burned, wherein the burn-out of these pyrolysis products in the first combustion chamber 6 is largely completed. In it are finally ash, flue gas with partially burned pyrolysis gas available. The TOC content of these products is already low after the described first step.
- the TOC content of the ash collected from the ash capture and transport means 21 is further reduced by injecting pulsating air into the forming ash bed 34 by means of the rows 23-26 air nozzles.
- the air flow through the line 27 can be interrupted every second.
- the pulsating Injected compressed air has the further effect that a caked layer is broken on the ash bed and so can also be carried away with the ash screw 22.
- To break through serve primarily the rows 23 and 26 air nozzles at a greater distance to the ash screw.
- the rows of air nozzles 24 and 25 are closer to the ash screw 22 to cool it over the ash bed 34.
- the second step achieves that high quality ash, i. such is discharged with a very low TOC content from the first combustion chamber 6.
- the flue gas and partially burned pyrolysis gas flows through the turbulator package, with which a high contact rate between the partially burned pyrolysis gas and the oxygen present in the flue gas is achieved, so that both gases are mixed intensively and the pyrolysis gas is post-combusted.
- additional air can contribute to the afterburning which is transported by the air blower 31 in the space upstream of the turbulator package 29.
- the turbulator package 29 in the second module 2 can continue to act as a separator for fly ash, especially in dense packing.
- the turbulator package 29 can be supplemented with a vibrator and a fly ash discharge device.
- volume segments due to their flow path between the passages 12 and input and output affect the residence time. It may therefore be useful to have subsequent volume segments such as the volume segment 4 without turbulator package to ensure a sufficient flue gas residence time in the device. In this way, for example, at least two seconds residence time, as prescribed by the (German) Federal Emission Control Law, can be achieved with certainty.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Processing Of Solid Wastes (AREA)
- Gasification And Melting Of Waste (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2002145954 DE10245954B4 (de) | 2002-07-23 | 2002-10-02 | Verfahren und Einrichtung zur Abfallverarbeitung |
DE10245954 | 2002-10-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1406044A1 EP1406044A1 (de) | 2004-04-07 |
EP1406044B1 true EP1406044B1 (de) | 2007-07-18 |
Family
ID=29414339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03022047A Expired - Lifetime EP1406044B1 (de) | 2002-10-02 | 2003-10-01 | Verfahren und Einrichtung zur Abfallverarbeitung |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1406044B1 (no) |
AT (1) | ATE367558T1 (no) |
DE (1) | DE50307688D1 (no) |
NO (1) | NO324180B1 (no) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2553871C2 (ru) * | 2013-09-11 | 2015-06-20 | Антон Дмитриевич Овсянко | Устройство для пиролиза углеродосодержащего сырья |
CN113845934B (zh) * | 2021-09-28 | 2024-01-23 | 石家庄卓度橡塑设备有限公司 | 橡胶软化油加工装置及方法 |
CN114110611B (zh) * | 2021-11-08 | 2023-03-14 | 西安交通大学 | 一种带蓄热及烘干功能的垃圾热解气化处理系统 |
CN114383136A (zh) * | 2021-12-31 | 2022-04-22 | 中环国投生态科技股份有限公司 | 一种垃圾热解气化炉 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3027854A (en) * | 1957-11-14 | 1962-04-03 | Fred E Akerlund | Apparatus and process for thermal destruction of waste materials |
US5255634A (en) * | 1991-04-22 | 1993-10-26 | Manufacturing And Technology Conversion International, Inc. | Pulsed atmospheric fluidized bed combustor apparatus |
EP0692679A3 (de) * | 1994-07-13 | 1997-01-02 | Kloeckner Humboldt Deutz Ag | Verfahren und anlagentechnische Schaltung zur Trocknung und Verbrennung von Klärschlamm |
JP4154029B2 (ja) * | 1998-04-07 | 2008-09-24 | 株式会社東芝 | 廃棄物の処理方法および廃棄物処理装置 |
GB2359874B (en) * | 2000-02-29 | 2003-12-31 | Andrew William Webster | Gasification auger |
KR100482187B1 (ko) * | 2001-09-20 | 2005-04-13 | 니폰 조키 세야쿠 가부시키가이샤 | 유기폐기물의 탄화처리방법 및 장치 |
-
2003
- 2003-10-01 EP EP03022047A patent/EP1406044B1/de not_active Expired - Lifetime
- 2003-10-01 NO NO20034397A patent/NO324180B1/no not_active IP Right Cessation
- 2003-10-01 DE DE50307688T patent/DE50307688D1/de not_active Expired - Lifetime
- 2003-10-01 AT AT03022047T patent/ATE367558T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE50307688D1 (de) | 2007-08-30 |
NO20034397L (no) | 2004-04-05 |
NO324180B1 (no) | 2007-09-03 |
ATE367558T1 (de) | 2007-08-15 |
NO20034397D0 (no) | 2003-10-01 |
EP1406044A1 (de) | 2004-04-07 |
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