EP1400370B1 - Substrat mit einer Haftkleberschicht - Google Patents
Substrat mit einer Haftkleberschicht Download PDFInfo
- Publication number
- EP1400370B1 EP1400370B1 EP02021042A EP02021042A EP1400370B1 EP 1400370 B1 EP1400370 B1 EP 1400370B1 EP 02021042 A EP02021042 A EP 02021042A EP 02021042 A EP02021042 A EP 02021042A EP 1400370 B1 EP1400370 B1 EP 1400370B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- adhesive layer
- substrate
- coating
- adhesive
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 47
- 239000012790 adhesive layer Substances 0.000 title abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 52
- 230000001070 adhesive effect Effects 0.000 claims abstract description 52
- 239000010410 layer Substances 0.000 claims abstract description 44
- 238000000576 coating method Methods 0.000 claims abstract description 31
- 239000011248 coating agent Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000004821 Contact adhesive Substances 0.000 claims abstract 11
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 6
- 239000001099 ammonium carbonate Substances 0.000 claims description 6
- 239000004005 microsphere Substances 0.000 claims description 5
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 3
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 2
- 238000010410 dusting Methods 0.000 claims 1
- 238000004924 electrostatic deposition Methods 0.000 claims 1
- 239000002861 polymer material Substances 0.000 claims 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 39
- 230000002779 inactivation Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002313 adhesive film Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000002998 adhesive polymer Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D5/00—Sheets united without binding to form pads or blocks
- B42D5/003—Note-pads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42C—BOOKBINDING
- B42C3/00—Making booklets, pads, or form sets from multiple webs
Definitions
- the invention relates to a substrate which is based on at least one Site completely or partially provided with a pressure-sensitive adhesive layer is, as well as a method for temporarily reducing the Adhesive force of a pressure-sensitive adhesive layer.
- So-called sticky notes are widely used in everyday office life. It is a piece of paper from a substrate (usually paper), the on one side usually on a partial surface coated with a so-called repositionable adhesive are.
- the piece of paper can be repeatedly on a smooth counter surface stick on and peel off without a substantial Reduction of the adhesive force occurs.
- a repositionable substrate for use as a sticky note
- an adhesive whose surface inactive in places.
- the surface of the adhesive layer is partially through covered or non-sticky (adhesive) particles, so that only the between These areas exposed areas are available as adhesive areas.
- the term substrate designates any useful document for Applying a pressure-sensitive adhesive.
- it may be the substrate is a paper or polymeric material, preferably are, for example, notes or markers, Adhesive films or the like.
- the substrate is wholly or partly on at least one side provided with a pressure-sensitive adhesive layer.
- This is any self-adhesive coating, which is an adhesion of the Can cause substrates on a mating surface. It may be to act a permanent adhesive, in this case is a once glued substrate not or only with change or destruction of the substrate and / or the pressure-sensitive adhesive layer removable again.
- repositionable Adhesive in particular repositionable microsphere adhesive with microspheres made of self-adhesive polymer, for example from polyacrylate, as for example from DE-A-2836319 are known.
- Repositionable means that such a pressure-sensitive adhesive on a clean, smooth counter surface glued on several times and again can be replaced without appreciable on this counter surface Leave adhesive residue or appreciable adhesive strength losing.
- a coating that reduces the adhesive force is applied on the substrate opposite side of at least part of the pressure-sensitive adhesive layer.
- a bond strength reduction to below is preferred 50 cN / 25 mm, preferably below 35 cN / 25 mm, more preferably below 20 cN / 25 mm, more preferably below 5 cN / 25 mm.
- the term adhesive refers to the FINAT test method # 2 (peel adhesion) measured force required is to make a 25 mm wide strip of paper with the appropriate pressure-sensitive adhesive layer is provided by a standardized Remove counter surface from steel. This so-called Peel adhesion is measured at a peel angle of 90 ° at a withdrawal speed of 300 mm / min.
- the term coating designates in the context of the present Invention on the side facing away from the substrate of the Pressure-sensitive adhesive layer applied and their adhesive force-reducing Layer of a material which, when heated to a temperature the substrate and pressure-sensitive adhesive layer are not irreversible change, is fleeting.
- the material of the coating volatilizes According to the invention preferably at a temperature of 40 ° C or more. In particular, such material is preferred which at a temperature of 40 - 200 ° C, preferably 50 - 150 ° C, more preferably 50 - 100 ° C volatile is.
- the material of the adhesion-reducing coating is according to the invention preferably in powder form and selected from the group consisting of azodicarbonamides, ammonium carbonate and more preferably ammonium bicarbonate.
- the present invention is under a non-irreversible Change the substrate and the pressure-sensitive adhesive layer too understand that after heating the substrate its use is guaranteed for the predetermined purpose and the Pressure-sensitive adhesive layer has sufficient adhesive power to adhesion to effect the substrate on the predetermined mating surface.
- the inactivation amount of the adhesive on the pressure-sensitive adhesive layer Coating is dependent on the substrate and type and Amount of pressure-sensitive adhesive layer on the substrate; also of the type and nature of the inactivation material used. Preferred are amounts of the inactivation material of at least 15 gsm of pressure-sensitive adhesive surface, more preferred at least 25 or 35 gsm.
- a commonly used repositionable pressure sensitive adhesive is a Polyacrylate microsphere pressure-sensitive adhesive, such as in DE-C-28 36 319 and under the mark "Info-Notes” used sticky notes is used.
- the adhesive application weight is about 5 gsm.
- For inactivation of this adhesive layer about 15 g / sqm are crystalline Ammonium hydrogen carbonate required as it is the name "ABC shoot” is available.
- the essence of the invention is the bond strength of an already functionally effective adhesive layer, with the one Substrate is provided by coating with a while heating temporarily reduce volatile material for as long as until by simply heating the coating Adhesive strength of the adhesive layer (at least partially) restored becomes.
- the particular advantage of the present invention is in the Facilitate the processing and packaging of already with a pressure-sensitive adhesive layer provided substrate.
- the substrate can thus easily Assembled in rolls and also unrolled again be without the pressure-sensitive adhesive layer handling problems prepares. Also the subsequent cutting and finishing is due to the inactivated pressure-sensitive adhesive layer considerably relieved. After the completion of the corresponding Processing and finishing steps can be done by heating of the finished product its bond strength restored become.
- the invention further relates to a method for temporary Reduction of the adhesive force of a pressure-sensitive adhesive layer on the pressure-sensitive adhesive layer, a the adhesive force-reducing Coating is applied and the material of this coating volatilizes upon heating to a temperature which does not irreversibly change the pressure-sensitive adhesive layer.
- the application of this coating is when using powdered coating material by simply brushing, Sputtering or electrostatic application possible.
- the invention is described below by way of examples and a Drawing explained.
- the drawing shows a cross section by a substrate according to the invention.
- the substrate 1 is coated on one side with a pressure-sensitive adhesive layer 2, on the on the side facing away from the substrate one the adhesive inactivating coating 3 is applied.
- Adhesive strips coated with "ABC shoot” show one complete inactivation of the pressure-sensitive adhesive layer; that too after 24 hours exposure at room temperature remains. A 20 minute warming to 100 ° C reactivates the Adhesive strength of the pressure-sensitive adhesive layer of the "ABC shoot” coated Samples completely.
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
- Coupling Device And Connection With Printed Circuit (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Laminated Bodies (AREA)
Description
- auf die vom Substrat abgewandte Seite wenigstens eines Teils der Haftkleberschicht ist eine die Klebkraft mindernde Beschichtung aufgebracht,
- das Material dieser Beschichtung ist flüchtig bei Erwärmung auf eine Temperatur, die Substrat und Haftkleberschicht nicht irreversibel verändert.
Probe Nr. | anhaftende Menge "ABC-Trieb" (mg) | g/m2 Klebefläche |
1 | 43,4 | 8,7 |
2 | 58,1 | 11,6 |
3 | 82,4 | 16,5 |
4 | 109,4 | 21,9 |
5 | 90,3 | 18,1 |
6 | 80,9 | 16,2 |
7 | 76,1 | 15,2 |
8 | 70,1 | 14,0 |
9 | 54,0 | 10,8 |
10 | 89,4 | 17,9 |
Mittelwert | 75,4 | 15,1 ± 3,9 |
Versuchsbedingungen | Klebekraft (cN/25 mm) | |
unbeschichtet (Kontrolle) | mit "ABC-Trieb" beschichtet | |
Ausgangswert | 24 | 0 |
nach 24 h bei RT | 25 | 0 |
nach 20 min. bei 100 °C | 27 | 24 |
Claims (13)
- Substrat, das auf wenigstens einer Seite ganz oder teilweise mit einer Haftkleberschicht (2) versehen ist, dadurch gekennzeichnet, daß auf die vom Substrat (1) abgewandte Seite wenigstens eines Teils der Haftkleberschicht (2) eine die Klebkraft mindernde Beschichtung (3) aufgebracht ist und daß das Material dieser Beschichtung (3) flüchtig ist bei Erwärmen auf eine Temperatur, die Substrat (1) und Haftkleberschicht (2) nicht irreversibel verändert.
- Substrat nach Anspruch 1, dadurch gekennzeichnet, daß das Material der die Klebkraft mindernden Beschichtung (3) bei einer Temperatur von 40°C oder mehr flüchtig ist.
- Substrat nach Anspruch 2, dadurch gekennzeichnet, daß das Material der die Klebkraft mindernden Beschichtung (3) bei einer Temperatur von 40 - 200°C, vorzugsweise 50 - 150°C, weiter vorzugsweise 50 - 100°C flüchtig ist.
- Substrat nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß das Material der die Klebkraft mindernden Beschichtung (3) pulverförmig ist.
- Substrat nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß das Material der die Klebkraft mindernden Beschichtung (3) ausgewählt ist aus der Gruppe bestehend aus Azodicarbonamiden, Ammoniumcarbonat und Ammoniumhydrogencarbonat.
- Substrat nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Haftkleberschicht (2) einen Permanentkleber aufweist.
- Substrat nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Haftkleberschicht (2) einen repositionierbaren Kleber aufweist.
- Substrat nach Anspruch 7, dadurch gekennzeichnet, daß der repositionierbare Kleber ein Mikrokugelkleber ist.
- Substrat nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß die Klebkraft der Haftkleberschicht (2) auf der vom Substrat (1) abgewandten Seite unter 50 cN/25mm , vorzugsweise unter 35 cN/25 mm, weiter vorzugsweise unter 20 cN/25 mm, weiter vorzugsweise unter 5 cN/25 mm beträgt.
- Substrat nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß das Basismaterial des Substrats (1) ein Papier- oder Polymerwerkstoff ist.
- Substrat nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, daß es auf einer Rolle aufgerollt ist.
- Verfahren zum temporären Vermindern der Klebkraft einer Haftkleberschicht (2), dadurch gekennzeichnet, daß auf diese Haftkleberschicht (2) eine die Klebkraft mindernde Beschichtung (3) aufgebracht wird und daß das Material dieser Beschichtung (3) flüchtig ist bei Erwärmen auf eine Temperatur, die die Haftkleberschicht (2) nicht irreversibel verändert.
- Verfahren nach Anspruch 12, dadurch gekennzeichnet, daß das Material der die Klebkraft mindernden Beschichtung (3) pulverförmig ist und das Aufbringen dieser Beschichtung (3) erfolgt durch Aufstreichen, Aufstäuben oder elektrostatisches Auftragen.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE50203772T DE50203772D1 (de) | 2002-09-20 | 2002-09-20 | Substrat mit einer Haftkleberschicht |
AT02021042T ATE300432T1 (de) | 2002-09-20 | 2002-09-20 | Substrat mit einer haftkleberschicht |
SI200230186T SI1400370T1 (sl) | 2002-09-20 | 2002-09-20 | Substrat z adhezivnim slojem |
ES02021042T ES2246366T3 (es) | 2002-09-20 | 2002-09-20 | Sustrato con una capa de adhesivo de contacto. |
DK02021042T DK1400370T3 (da) | 2002-09-20 | 2002-09-20 | Substrat med kontaktklæberlag |
PT02021042T PT1400370E (pt) | 2002-09-20 | 2002-09-20 | Substrato com uma camada de cola de contacto |
EP02021042A EP1400370B1 (de) | 2002-09-20 | 2002-09-20 | Substrat mit einer Haftkleberschicht |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02021042A EP1400370B1 (de) | 2002-09-20 | 2002-09-20 | Substrat mit einer Haftkleberschicht |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1400370A1 EP1400370A1 (de) | 2004-03-24 |
EP1400370B1 true EP1400370B1 (de) | 2005-07-27 |
Family
ID=31896894
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02021042A Expired - Lifetime EP1400370B1 (de) | 2002-09-20 | 2002-09-20 | Substrat mit einer Haftkleberschicht |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1400370B1 (de) |
AT (1) | ATE300432T1 (de) |
DE (1) | DE50203772D1 (de) |
DK (1) | DK1400370T3 (de) |
ES (1) | ES2246366T3 (de) |
PT (1) | PT1400370E (de) |
SI (1) | SI1400370T1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102018004759A1 (de) | 2017-06-16 | 2018-12-20 | Euroimmun Medizinische Labordiagnostika Ag | Diagnose einer Neuroautoimmunkrankheit |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4166152B1 (en) | 1977-08-17 | 1999-05-18 | Minnesota Mining & Mfg | Tacky polymeric microspheres |
WO1987005315A1 (en) * | 1986-02-26 | 1987-09-11 | Erich Pagendarm | Article with adhesive coating and process for its production |
US6268032B1 (en) * | 1997-10-03 | 2001-07-31 | 3M Innovative Properties Company | Repositionable note sheets and method of formation thereof |
-
2002
- 2002-09-20 DK DK02021042T patent/DK1400370T3/da active
- 2002-09-20 EP EP02021042A patent/EP1400370B1/de not_active Expired - Lifetime
- 2002-09-20 AT AT02021042T patent/ATE300432T1/de not_active IP Right Cessation
- 2002-09-20 DE DE50203772T patent/DE50203772D1/de not_active Expired - Fee Related
- 2002-09-20 PT PT02021042T patent/PT1400370E/pt unknown
- 2002-09-20 ES ES02021042T patent/ES2246366T3/es not_active Expired - Lifetime
- 2002-09-20 SI SI200230186T patent/SI1400370T1/sl unknown
Also Published As
Publication number | Publication date |
---|---|
ATE300432T1 (de) | 2005-08-15 |
SI1400370T1 (sl) | 2005-12-31 |
EP1400370A1 (de) | 2004-03-24 |
ES2246366T3 (es) | 2006-02-16 |
DK1400370T3 (da) | 2005-11-28 |
PT1400370E (pt) | 2005-11-30 |
DE50203772D1 (de) | 2005-09-01 |
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