EP1370424B2 - Document de valeur - Google Patents
Document de valeur Download PDFInfo
- Publication number
- EP1370424B2 EP1370424B2 EP02748334.6A EP02748334A EP1370424B2 EP 1370424 B2 EP1370424 B2 EP 1370424B2 EP 02748334 A EP02748334 A EP 02748334A EP 1370424 B2 EP1370424 B2 EP 1370424B2
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- EP
- European Patent Office
- Prior art keywords
- document
- range
- value
- value according
- luminescent substance
- Prior art date
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- 239000000126 substance Substances 0.000 claims abstract description 51
- 238000005090 crystal field Methods 0.000 claims abstract description 12
- 239000011651 chromium Substances 0.000 claims description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 239000012876 carrier material Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 230000005284 excitation Effects 0.000 claims description 9
- 238000004020 luminiscence type Methods 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- -1 rare earth metal cations Chemical class 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 229910052775 Thulium Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 2
- 238000010998 test method Methods 0.000 claims 3
- 238000012360 testing method Methods 0.000 claims 3
- 239000000463 material Substances 0.000 description 7
- 238000000295 emission spectrum Methods 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 230000003595 spectral effect Effects 0.000 description 5
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 238000000695 excitation spectrum Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910020091 MgCa Inorganic materials 0.000 description 1
- 101100513612 Microdochium nivale MnCO gene Proteins 0.000 description 1
- 101100003996 Mus musculus Atrn gene Proteins 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/387—Special inks absorbing or reflecting ultraviolet light
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/22—Nonparticulate element embedded or inlaid in substrate and visible
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Business, Economics & Management (AREA)
- Accounting & Taxation (AREA)
- Finance (AREA)
- Luminescent Compositions (AREA)
- Braking Elements And Transmission Devices (AREA)
- Valve Device For Special Equipments (AREA)
- Holo Graphy (AREA)
- Credit Cards Or The Like (AREA)
- Printing Methods (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Control Of Motors That Do Not Use Commutators (AREA)
Claims (26)
- Document de valeur avec au moins une caractéristique d'authenticité sous la forme d'une substance luminescente à base de réseaux cristallins dopés, caractérisé en ce que le réseau cristallin est dopé avec au moins un chromophore de configuration électronique (3d)2, dans lequel le chromophore est du titane au degré d'oxydation 2 ou du vanadium au degré d'oxydation 3 ou du chrome au degré d'oxydation 4 ou du manganèse au degré d'oxydation 5 ou du fer au degré d'oxydation 6, et dans lequel, en ce qui concerne le réseau cristallin, il s'agit d'un composé présentant l'une des formules (1), (2), (3), (4), (5), (6), (7), (8), (9), (10), (11), (12), (13), (14), (15), (16) (17) :
[Baa Cab Src Pbd Cde (Pf Vg Ash Sij Sk Crl O4)3 Fm Cln Brp (OH)q] x, (1)
dans laquelle
a + b + c + d + e = 5;
f + g + h + j + k + l = 1;
m + n + p + q = 1 ;
x = 1 ou 2 ; et
a, b, c, d, e de 0 à 5 ;
f, g, h, j, k, l, m, n, p, q de 0 à 1,
[Mga Bab Cac Srd Pbe Cdf] [Pg Vh Asj Sik Sl Crm] O4 [Fn Clp Brq (OH)r] (2)
dans laquelle a + b + c + d + e + f = 2 ;
g + h + j + k + l + m = 1 ;
n + p + q + r = 1 ; et
a, b, c, d, e, f de 0 à 2 ;
g, h, j, k, l, m, n, p, q, r de 0 à 1,
[Mga Bab Cac Srd Pbe Cdf] [Sig Tih Gej] O4 (3)
dans laquelle a + b + c + d + e + f = 2 ;
g + h + j = 1 ;et
a, b, c, d, e, f de 0 à 2 ;
g, h, j de 0 à 1,
[Lia Nab Kc Rbd] [Pe Asf Vg] O4 (4)
dans laquelle a + b + c + d = 3 ;
e + f + g = 1 ;et
a, b, c, d de 0 à 3 et
e, f, g de 0 à 1,
[Ya Lab] [Sic Tid] O5 (5)
dans laquelle a + b = 2;
c + d = 1 ; et
a, b, de 0 à 2 et
c, d de 0 à 1,
[Baa Cab Src Pbd Cde] (Pf Vg Ash Sij Sk Crl O4)2 (6)
dans laquelle a + b + c + d + e = 3 ;
f + g + h + j + k + l = 1
a, b, c, d, e de 0 à 3 et
f, g, h, j, k, l de 0 à 1,
[Baa Cab Src Pbd Cde] (Pf Vg Ash Sij Sk Crl O4)3 Cl (7)
dans laquelle a + b + c + d + e = 5 ;
f + g + h + j + l = 1 ;
a, b, c, d, e de 0 à 5 et
f, g, h, j, k, l de 0 à 1,
[Naa Kb Rbc Csd] [Se Sef Crg Moh]O4 (8)
dans laquelle a + b + c + d = 2 ;
e + f + g + h = 1;
a, b, c, d de 0 à 2 et
e, f, g, h de 0 à 1,
[Mga Cab Src Bad] [Se Sef Crg Moh Wi] O4 (9)
dans laquelle a + b + c + d = 1 ;
e + f + g + h + i = 1 et
a, b, c, d de 0 à 1 et
e, f, g, h, i de 0 à 1,
[Sca Yb Lac Ced Pre Ndf Pmg Smh Euj Gdk Tbl Dym Hon Erp Tmq Ybr Lns] [Al11 Fev Crx]O3 (10)
dans laquelle :
a + b + c + d + e + f + g + h + j + k + l + m + n + p + q + r + s = 1 ;
u + v + x = 1 ;
a, b, c, d, e, f, g, h, j, k, l, m, n, p, q, r, s, u, v, x de 0 à 1,
[Ya Gdb Scc Lad Lne] [Alf Feg Crh] O12 (11)
dans laquelle a + b + c + d + e = 3 ;
f + g + h = 5;
a, b, c, d, e de 0 à 3 et
f, g, h de 0 à 5,
[Mga Cab Src Bad] [Ale Crf Feg Gah] O4 (12)
dans laquelle a + b + c + d = 1 ;
e + f + g + h = 2 ;
a, b, c, d de 0 à 1 et
e, f, g, h de 0 à 2,
[Mga Cab Src Bad] [Ale Crf Feg Gah] O7 (13)
dans laquelle a + b + c + d = 1 ;
e + f + g + h = 4 ;
a, b, c, d de 0 à 1 et
e, f, g, h de 0 à 4,
Y2 [Sia Tib Zrc]O7 ou MgCa2[Sia Tib Zrc]O7 (14)
dans laquelle a + b + c = 2 et
a, b et c de 0 à 2,
[Baa Cab Src] [Sid Tie Zrf]O5 (15)
dans laquelle a + b + c = 3;
d + e + f = 1 ; et
a, b, c de 0 à 3 et
d, e, f de 0 à 1,
[Ya Lab Zrc] [Pd Sie]O4 (16)
dans laquelle a + b + c = 1 ;
d + e = 1 ; et
a, b, c de 0 à 1 et
d, e de 0 à 1,
K[Ti2a Zr2b](PO4)3 (17)
dans laquelle a + b = 1 ; et
a, b de 0 à 1. - Document de valeur selon la revendication 1, dans lequel le réseau cristallin comprend un champ cristallin fort.
- Document de valeur selon la revendication 1 ou 2, dans lequel le document de valeur est constitué de papier ou de matière plastique.
- Document de valeur selon au moins une des revendications 1 à 3, dans lequel la caractéristique d'authenticité est insérée dans le volume du document de valeur ou se trouve sur une couche disposée sur le document de valeur.
- Document de valeur selon au moins une des revendications 1 à 4, dans lequel la substance luminescente se présente sous la forme d'un revêtement au moins partiellement invisible sur le document de valeur.
- Document de valeur selon au moins une des revendications 1 à 5, dans lequel la substance luminescente est mélangée à une encre d'imprimerie.
- Document de valeur selon au moins une des revendications 1 à 6, dans lequel le revêtement se présente sous la forme d'une ou plusieurs bandes.
- Document de valeur selon au moins une des revendications 1 à 7, dans lequel le réseau cristallin est co-dopé, de manière supplémentaire, avec au moins un représentant du groupe des cations métalliques des terres rares.
- Document de valeur selon la revendication 8, dans lequel le cation métallique de terre rare est choisi parmi le néodyme (Nd), l'holmium (Ho), l'erbium (Er), le thulium (Tm) et l'ytterbium (Yb).
- Document de valeur selon au moins une des revendications 1 à 9, dans lequel le réseau cristallin est sélectionné dans la catégorie des apatites, spodiosites, palmiérites, forstérites, brushites, dahllites, ellestadites, francolites, monétites, morinites, whitlockites, wilkéites, voelkérites, pyromorphites, grenats, pérovskites, silicates, titanates, vanadates, phosphates.
- Document de valeur selon au moins une des revendications 1 à 10, dans lequel les chromophores du réseau cristallin sont dans une configuration tétroxyde.
- Document de valeur selon au moins une des revendications 1 à 11, dans lequel la substance luminescente se présente sous la forme de particules de pigments.
- Elément de sécurité qui présente un matériau support et au moins une substance luminescente telle que définie à la revendication 1.
- Elément de sécurité selon la revendication 13, dans lequel le réseau cristallin présente un champ cristallin fort.
- Elément de sécurité selon la revendication 13 ou 14, dans lequel l'élément de sécurité se présente sous la forme d'une bande ou ruban.
- Elément de sécurité selon au moins une des revendications 13 à 15, dans lequel le matériau support est conçu comme un fil de sécurité, une planchette ou une fibre.
- Elément de sécurité selon au moins une des revendications 13 à 16, caractérisé en ce que l'élément de sécurité est conçu comme une étiquette.
- Elément de sécurité selon au moins une des revendications 13 à 17, caractérisé en ce que la substance luminescente est intégrée dans le matériau support ou appliquée sur le matériau support.
- Procédé de fabrication d'un document de valeur selon au moins une des revendications 1 à 12, caractérisé en ce que la substance luminescente est ajoutée à une encre d'imprimerie.
- Procédé de fabrication d'un document de valeur selon au moins une des revendications 1 à 12, caractérisé en ce que la substance luminescente est appliquée à l'aide d'un procédé de revêtement.
- Procédé de fabrication d'un document de valeur selon au moins une des revendications 1 à 12, caractérisé en ce que la substance luminescente est insérée dans le volume du document de valeur.
- Procédé de fabrication d'un document de valeur selon au moins une des revendications 1 à 12, caractérisé en ce que la substance luminescente est introduite dans le document de valeur à l'aide de fibres mélangées préparées de manière appropriée.
- Procédé de fabrication d'un document de valeur selon au moins une des revendications 1 à 12, caractérisé en ce que la substance luminescente est introduite dans le document de valeur à l'aide d'un fil de sécurité préparé de manière approprié.
- Procédé de contrôle d'authenticité d'un document de valeur selon au moins une des revendications 1 à 12 ou d'un élément de sécurité selon au moins une des revendications 13 à 18, caractérisé en ce que les longueurs d'ondes et/ou le nombre et/ou la forme et/ou les intensités des lignes d'émission et/ou des bandes d'excitation des substances luminescentes sont analysés.
- Procédé de contrôle d'authenticité d'un document de valeur selon la revendication 24, caractérisé en ce que les lignes d'émissions et/ou les bandes d'excitation constituent un codage et/ou un codage est constitué par la variation du réseau cristallin.
- Procédé de contrôle d'authenticité d'un document de valeur selon au moins une des revendications 1 à 12 ou d'un élément de sécurité selon au moins une des revendications 13 à 18, caractérisé en ce que les durées de vie de luminescence de la substance luminescente sont analysées.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE10111116A DE10111116A1 (de) | 2001-03-08 | 2001-03-08 | Wertdokument |
DE10111116 | 2001-03-08 | ||
PCT/EP2002/002405 WO2002070279A1 (fr) | 2001-03-08 | 2002-03-05 | Document de valeur |
Publications (3)
Publication Number | Publication Date |
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EP1370424A1 EP1370424A1 (fr) | 2003-12-17 |
EP1370424B1 EP1370424B1 (fr) | 2004-09-01 |
EP1370424B2 true EP1370424B2 (fr) | 2013-07-31 |
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EP02748334.6A Expired - Lifetime EP1370424B2 (fr) | 2001-03-08 | 2002-03-05 | Document de valeur |
Country Status (16)
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---|---|
US (1) | US8663820B2 (fr) |
EP (1) | EP1370424B2 (fr) |
KR (1) | KR100868176B1 (fr) |
CN (1) | CN1282555C (fr) |
AT (1) | ATE275046T1 (fr) |
AU (1) | AU2002308237B2 (fr) |
CA (1) | CA2440078C (fr) |
DE (2) | DE10111116A1 (fr) |
ES (1) | ES2224072T5 (fr) |
HK (1) | HK1062664A1 (fr) |
PL (1) | PL202501B1 (fr) |
PT (1) | PT1370424E (fr) |
RU (1) | RU2286885C2 (fr) |
TR (1) | TR200402236T4 (fr) |
UA (1) | UA74062C2 (fr) |
WO (1) | WO2002070279A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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RU216603U1 (ru) * | 2021-08-06 | 2023-02-14 | Дмитрий Александрович Зуев | Защитная маркировка |
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DE10111116A1 (de) | 2001-03-08 | 2002-09-19 | Giesecke & Devrient Gmbh | Wertdokument |
DE10346685A1 (de) * | 2003-10-08 | 2005-05-04 | Giesecke & Devrient Gmbh | Codiersystem für Wertdokumente |
DE10346687A1 (de) | 2003-10-08 | 2005-05-04 | Giesecke & Devrient Gmbh | Codierungssystem für Wertdokumente |
WO2006024530A1 (fr) * | 2004-09-02 | 2006-03-09 | Giesecke & Devrient Gmbh | Document de valeur ayant des proprietes luminescentes |
DE102004063217A1 (de) * | 2004-12-29 | 2006-07-13 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal für Wertdokumente |
DE102005041054A1 (de) * | 2005-08-30 | 2007-03-01 | Giesecke & Devrient Gmbh | Verfahren und Vorrichtung zur Echtheitsprüfung von Banknoten |
AR053508A1 (es) * | 2006-05-31 | 2007-05-09 | Agustin Jose Luis Perez | Sistema para la grabacion y lectura de datos a prtir de informacion cromatica impresa que modifica patrones emitidos por una fuente de ondas electromagneticas, generando nuevos patrones y dando origen a categorias reconocibles y asignables a un codigo |
US8550358B2 (en) | 2006-05-31 | 2013-10-08 | Agustin Jose Luis Perez | Procedure for data encoding and reading starting from interference of wave patterns generated in a printed chromatic system |
DE102006047851A1 (de) * | 2006-10-10 | 2008-04-17 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in Form von lumineszierenden Substanzen |
DE102006047852A1 (de) * | 2006-10-10 | 2008-04-17 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in Form einer lumineszierenden Substanz |
DE102008050768C5 (de) † | 2008-10-09 | 2017-11-02 | Bundesdruckerei Gmbh | Sicherheitsmerkmal auf Basis Lumineszenz emittierender Stoffe, Wert- und Sicherheitsdokument mit einem solchen Sicherheitsmerkmal, ein Verfahren sowie eine Vorrichtung zur Verifikation eines solchen Sicherheitsmerkmals |
DE102010034256A1 (de) | 2010-08-13 | 2012-02-16 | Giesecke & Devrient Gmbh | Lumineszenzmittel zur Anwendung in der Medizin |
DE102011122243A1 (de) * | 2011-12-23 | 2013-06-27 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal mit mehreren Komponenten |
DE102011122240A1 (de) * | 2011-12-23 | 2013-06-27 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal mit mehreren Komponenten |
DE102011122246A1 (de) | 2011-12-23 | 2013-06-27 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal mit mehreren Komponenten |
RU2526211C2 (ru) * | 2012-10-03 | 2014-08-20 | Федеральное Государственное Унитарное Предприятие "Гознак" (Фгуп "Гознак") | Ценный документ, защищенный от подделки, и способ определения его подлинности |
DE102013007811A1 (de) | 2013-05-07 | 2014-11-13 | Giesecke & Devrient Gmbh | Verfahren zur Markierung eines Merkmalstoffes, Sicherheitsmerkmal, Wertdokument und Verfahren zur Prüfung desselben |
RU2614980C1 (ru) * | 2015-12-21 | 2017-03-31 | Акционерное общество "Гознак" (АО "Гознак") | Защитная маркировка и изделие, содержащее данную маркировку |
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- 2002-03-05 RU RU2003129071/12A patent/RU2286885C2/ru active
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- 2002-03-05 KR KR1020037011826A patent/KR100868176B1/ko active IP Right Grant
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- 2002-03-05 ES ES02748334T patent/ES2224072T5/es not_active Expired - Lifetime
- 2002-03-05 US US10/471,060 patent/US8663820B2/en active Active
- 2002-03-05 EP EP02748334.6A patent/EP1370424B2/fr not_active Expired - Lifetime
- 2002-03-05 PT PT02748334T patent/PT1370424E/pt unknown
- 2002-03-05 DE DE50200931T patent/DE50200931D1/de not_active Expired - Lifetime
- 2002-03-05 CA CA002440078A patent/CA2440078C/fr not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
---|---|
US20040105962A1 (en) | 2004-06-03 |
ES2224072T5 (es) | 2013-11-15 |
DE10111116A1 (de) | 2002-09-19 |
TR200402236T4 (tr) | 2004-10-21 |
KR100868176B1 (ko) | 2008-11-12 |
CA2440078C (fr) | 2007-08-07 |
CN1501864A (zh) | 2004-06-02 |
ES2224072T3 (es) | 2005-03-01 |
WO2002070279A1 (fr) | 2002-09-12 |
EP1370424A1 (fr) | 2003-12-17 |
RU2286885C2 (ru) | 2006-11-10 |
EP1370424B1 (fr) | 2004-09-01 |
CN1282555C (zh) | 2006-11-01 |
HK1062664A1 (en) | 2004-11-19 |
ATE275046T1 (de) | 2004-09-15 |
DE50200931D1 (de) | 2004-10-07 |
PL363008A1 (en) | 2004-11-15 |
UA74062C2 (en) | 2005-10-17 |
US8663820B2 (en) | 2014-03-04 |
RU2003129071A (ru) | 2005-03-27 |
KR20030087016A (ko) | 2003-11-12 |
PT1370424E (pt) | 2005-01-31 |
PL202501B1 (pl) | 2009-06-30 |
CA2440078A1 (fr) | 2002-09-12 |
AU2002308237B2 (en) | 2006-08-17 |
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