EP1363582A1 - Aerosol-spray zur behandlung keratinischer fasern - Google Patents
Aerosol-spray zur behandlung keratinischer fasernInfo
- Publication number
- EP1363582A1 EP1363582A1 EP01962900A EP01962900A EP1363582A1 EP 1363582 A1 EP1363582 A1 EP 1363582A1 EP 01962900 A EP01962900 A EP 01962900A EP 01962900 A EP01962900 A EP 01962900A EP 1363582 A1 EP1363582 A1 EP 1363582A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- preparation according
- wax
- oil
- preparation
- blowing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the invention relates to a preparation for the treatment of keratin fibers, in particular human hair in the form of an aerosol spray, and the use of this preparation for the treatment of keratin fibers, in particular human hair.
- Keratin fibers especially human hair, are undergoing a variety of treatments nowadays.
- the treatments that serve to permanently or temporarily shape the hair play an important role.
- Temporary shapes that are supposed to give a good hold without impairing the healthy appearance of the hair, such as, for example, its shine, can be achieved, for example, by hair sprays, hair waxes, blow dryer waves, etc.
- Hair sprays usually contain synthetic polymers as a shaping component.
- Preparations which contain a dissolved or dispersed polymer can be applied to the hair by means of propellant gases or by a pump mechanism.
- propellant gases or by a pump mechanism.
- a satisfactorily uniform distribution of the polymer on the hair is achieved; application from spray or pump containers is easy and clean.
- Hair waxes usually contain vegetable, animal or mineral waxes as a shaping component and are offered as solid formulations, usually in jars. For use, these products are first rubbed in the hand and then spread over the hair. These hair waxes, based on natural raw materials, ensure a good hold of the hair with a strong shine. Nevertheless, the hair waxes on the market can meet the needs of users simple application and easy distribution on the hair are not yet completely satisfactory. Rubbing on the hand requires either the use of gloves or a subsequent intensive cleaning of the hands to remove the greasy product residues. Furthermore, a very even distribution of the product on the hair is difficult to achieve and requires a lot of time.
- gloss sprays are also on the market. These can give human hair in particular a special shine due to their content of vegetable, mineral and / or synthetic oils. Since the conventional synthetic and natural film formers are practically insoluble in these oils, these gloss sprays have no styling properties. The possibility of incorporating film formers into gloss sprays using solvents, such as high amounts of ethanol, does not lead to satisfactory results, since the additional styling properties can only be achieved at the expense of a significantly poorer gloss and feel.
- the waxes used in hair waxes can also be formulated and used as aerosol sprays. This allows the product to be applied to the hair much more easily and evenly than the conventional solid formulations. Furthermore, even when the spray cans were completely emptied, there were no problems with the nozzle components being blocked by the wax components. The problem of "greasy hands" after application of the product is completely eliminated.
- the present invention therefore relates to preparations for the treatment of keratin fibers, in particular human hair, for spraying as an aerosol spray, characterized in that they
- the first mandatory component of the preparations according to the invention is a wax with a melting point in a range from 40 to 90 ° C.
- all waxes can be used, which melt in the temperature range mentioned, which meet the general definition for waxes, as they exist for.
- B. is listed in UUmanns Encyklopadie der Technische Chemie, 4th edition, volume 24, page 3, left column, and which are physiologically compatible.
- the waxes are preferably selected from vegetable, animal and mineral waxes, it being possible to use waxes which have a melting point in the range from 50 ° C. to 85 ° C., in particular from 60 ° C. to 75 ° C.
- Particularly preferred waxes according to the invention are beeswax (Gera Alba), carnauba wax, candelilla wax, montan wax, microcrystalline waxes (microcrystalline paraffins) and cetyl palmitate.
- the teaching according to the invention also includes the combined use of several waxes.
- An addition of small amounts of carnauba wax can be used to increase the melting and dropping point of another wax and to reduce its stickiness.
- a number of wax mixtures, possibly in a mixture with other additives, are also commercially available.
- liquid waxes such as jojoba oil
- jojoba oil in addition to the compounds usually defined as waxes (see above), so-called “liquid waxes”, such as jojoba oil, can also be used, provided that the melting point of this “wax mixture” is not below 40 ° C.
- the preparations according to the invention preferably contain the waxes in amounts of 1.5 to 60% by weight, based on the entire preparation. Amounts of 5 to 40% by weight, in particular 10 to 25% by weight, are particularly preferred.
- the preparations according to the invention contain at least one emulsifier.
- emulsifiers both anionic and ampholytic, zwitterionic, cationic and nonionic surface-active compounds which are suitable for use on the human body are suitable as emulsifiers.
- anionic and nonionic surface-active compounds is preferred according to the invention.
- Anionic surface-active compounds are characterized by a water-solubilizing anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 carbon atoms.
- a water-solubilizing anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 carbon atoms.
- glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups can be contained in the molecule.
- Atoms and x 0 or 1 to 12, mixtures of surface-active hydroxysulfonates, sulfated hydroxyalkyl polyethylene and / or hydroxyalkylene propylene glycol ethers, sulfonates of unsaturated fatty acids, esters of tartaric acid and citric acid with alcohols, the adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols having 8 to 22 carbon atoms, Kokosmonoglyceridsulfate, phosphoric acid mono-, di- and tri-esters of alkoxylated fatty alcohols and mixtures thereof, such as the products sold under the trademark Hostaphat ®, as well as esters of hydroxy-substituted bi- or tricarboxylic acids with polyhydroxylated organic compounds which are selected from the group consisting of etherified (C 6 -C 18 ) alkyl polysaccharides having 1 to 6 monomeric saccharide units and etherified ali
- Preferred anionic surface-active compounds are the salts of ether carboxylic acids and compounds containing phosphate groups, in particular the phosphoric acid mono-, di- and triesters of ethoxylated C10-C18, in particular C12-C14, fatty alcohols with degrees of ethoxylation of 2 to 10, in particular 3 to 5 ,
- Non-ionic surface-active compounds contain z.
- Such connections are, for example
- Preferred nonionic surface-active compounds are the addition products of alkylene oxide, in particular ethylene oxide, with fatty alcohols and fatty acids.
- Zwitterionic surface-active compounds are those substances which have at least one quaternary ammonium group and at least one in the molecule
- Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the cocoalkyl-dimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammoniumglycinate, for example the cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethyl carboxymethylglycinate.
- a preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine.
- a pholytic surface-active compounds are understood to mean those substances which, in addition to a C 8 -C 18 -alkyl or acyl group, have at least one free one in the molecule
- ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N-alkyliminodipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N-alkyltaurine, N-alkylsarcosine, 2-alkylaminopropionic acid and alkylaminoacetic acid each with about 8 to 18 C. Atoms in the alkyl group.
- Preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C I2 . Ig - acyl sarcosine.
- cationic surface-active compounds are, in particular, quaternary ammonium compounds.
- Ammonium halides in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. B. cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride. May continue to the very readily biodegradable quaternary Esterasticen as they are for example sold under the trademark Dehyquart ® series, and quaternized protein hydrolyzates, and silicone compounds are used according to the invention.
- the compounds with alkyl groups used as surfactants can each be uniform substances. However, it is generally preferred to start from natural vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
- both products with a "normal" homolog distribution and those with a narrowed homolog distribution can be used.
- "Normal" homolog distribution is understood to mean mixtures of homologs that are used in the implementation of fatty alcohol and Alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts.
- narrow homolog distributions are obtained if, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts.
- the preparations according to the invention contain the emulsifiers in amounts of 0.1 to 10% by weight, based on the entire preparation. Amounts of 0.5 to 5, in particular 0.7 to 3% by weight are preferred.
- the third mandatory component of the preparations according to the invention is the blowing agent.
- the blowing agent is advantageously selected so that it simultaneously serves as a solvent for the wax components.
- the blowing agent can then serve as a solvent for the wax components if they are at least 1% by weight, based on the blowing agent, soluble in it at 20 ° C.
- Propellants preferred according to the invention are alkanes with 3 to 5 carbon atoms, such as propane, n-butane, isobutane, n-pentane and isopentane; n-butane and propane are particularly preferred.
- the preparations according to the invention contain the alkanes mentioned or mixtures of the alkanes mentioned as the only blowing agent.
- the invention also expressly includes the use of blowing agents of the chlorofluorocarbon type, but in particular the fluorocarbons.
- Dimethyl ether in amounts below 5%, based on the entire preparation, can also be present in the preparations according to the invention as an additional blowing agent.
- the blowing agents are preferably present in the preparations according to the invention in amounts of 40 to 98% by weight, based on the entire preparation. Amounts of 50 to 95% by weight, in particular 60-90% by weight, are particularly preferred.
- the preparations according to the invention can consist solely of the three mandatory components mentioned.
- they contain the wax as the only styling component and are free of polymers, in particular polymers with a styling effect.
- preparations according to the invention can also be incorporated into the preparations according to the invention.
- the hair can be given an improved shine.
- preparations according to this embodiment can achieve the object of imparting additional styling properties to the conventional gloss sprays.
- Both vegetable and mineral or synthetic oils can be used as the oil component.
- a preferred embodiment of the present invention is therefore preparations which further contain at least one oil component selected from vegetable, mineral and synthetic oils. These oil components or oil components are preferably contained in the preparations according to this preferred embodiment in amounts of 0.5 to 50% by weight, in particular 5 to 50% by weight, based on the entire preparation. Amounts of 10 to 40% by weight can be particularly preferred.
- Triglycerides and mixtures of triglycerides are usually used as natural oils.
- Preferred natural oils are kukui nut oil, (sweet) almond oil, walnut oil, peach kernel oil, avocado oil, tea tree oil (tea tree oil), soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango kernel oil, meadow herb oil, safflower oil, apricot kernel oil, macadamia oil, macadamia oil, macadamia oil, macadamia oil, macadamia oil, macadamia oil, macadamia oil Babassu oil, olive oil, Wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil and shea butter.
- (sweet) almond oil, avocado oil, soybean oil, sesame oil, sunflower oil, palm kernel oil, mango kernel oil, macadamia nut oil, apricot kernel oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil and hazelnut oil are particularly preferred.
- Mineral oils, paraffin and isoparaffin oils and synthetic hydrocarbons are used in particular as mineral oils.
- An inventively employable synthetic hydrocarbon is for example the commercial products available as compound l, 3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol ® S).
- Mineral oils preferred according to the invention are paraffin oils.
- Suitable synthetic oils are silicone compounds, in particular dialkyl and alkylarylsiloxanes, such as, for example, dimethylpolysiloxane and methylphenylpolysiloxane, and their hydroxyl-terminated, alkoxylated and quaternized analogs.
- silicones examples include the products sold by Dow Corning under the names DC 190, DC 200 and DC 1401 and the commercial products DC 344 and DC 345 from Dow Corning, Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Corning ® 929 emulsion (containing a hydroxylamino-modified silicone, which is also referred to as amodimethicone), SM-2059 (manufacturer: General Electric) and SLM-55067 (manufacturer: Wacker).
- Preferred silicone compounds according to the invention are linear and cyclic, alkoxylated and non-alkoxylated dialkylsiloxanes, alkylarylsiloxanes and siloxanes with amino groups.
- oils which can be used according to the invention also include dialkyl ethers and dialkyl carbonates.
- Dialkyl ethers which can be used according to the invention are, in particular, di-n-alkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di- n-undecyl ether, di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n- Undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether as well as di-tert-butyl ether, di-isopentyl ether, di-3-ethyldecyl ether, tert-but
- dialkyl carbonates which can be used according to the invention can be obtained by complete transesterification of low molecular weight dialkyl carbonates, for example dimethyl carbonate or diethyl carbonate, with, for example, fatty alcohols having 6 to 22 carbon atoms or their ethylene oxide and / or propylene oxide addition products.
- Further dialkyl carbonates which can be used according to the invention have branched alkyl groups.
- a commercially available product of this type is, for example, di- (2-hexyldecyl) carbonate, which is obtained by transesterification of diethyl carbonate with 2-hexyl-decanoI, a Guerbet alcohol, and is also referred to as “Guerbet carbonate”.
- Another preferred one Dialkyl carbonate with branched alkyl chains is di- (2-ethylhexyl) carbonate.
- liquid oils are used
- the invention also includes the use of mixtures of liquid and solid oil components, provided that these mixtures are liquid at room temperature.
- the quantitative ratio of wax components and oil components is not subject to any fundamental restrictions.
- the proportion of wax components, based on the sum of the wax and oil components is usually in the range from 0.5 to 99.5% by weight, in particular in the range from 10 to 90% by weight. Preparations in which this wax content is in the range from 40 to 75% by weight are distinguished by particularly outstanding properties.
- the proportion of propellant gas in the preparations according to this preferred embodiment is preferably 20 to 98% by weight, in particular 40 to 90% by weight and particularly preferably 50 to 80% by weight, based on the overall preparation.
- the preparations according to the invention generally contain further components which are customary for the corresponding products.
- Such other components are special
- Oil-soluble vitamins preferred according to the invention belong to groups A, D and E.
- Retinol vitamin A ⁇ and 3,4-didehydroretinoI (vitamin A 2 ) belong to the group of substances called vitamin A.
- ⁇ -carotene is the provitamin of
- vitamin A components include, for example, vitamin A-acid and its esters, vitamin A-aldehyde and vitamin A-alcohol as well as its esters such as the palmitate and the acetate.
- Vitamin E tocopherols, especially ⁇ -tocopherol.
- Tocopherol and its derivatives which include in particular the esters such as acetate, nicotinate, phosphate and succinate, are preferably present in the agents according to the invention in amounts of 0.05-1% by weight, based on the total agent.
- soluble UV filters are those UV filters which are soluble in the preparations according to the invention in amounts of at least 0.1% by weight, based on the preparation as a whole.
- Such UV filters can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
- UV filters which can be used according to the invention are 4-amino-benzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methyl sulfate, 3,3,5-trimethyl cyclohexyl salicylate (homosalates ), 2-Hydroxy-4-methoxy-benzophenone (Benzophenone-3; Uvinul ® M 40, Uvasorb ® MET, Neoheliopan ® BB, Eusolex ® 4360), l- (4-tert-butylphenyl) -3- (4- methoxyphenyl) propane-1,3-dione (butyl methoxydibenzoylmethane; Parsol ® 1789, Eusolex ® 9020), ethoxylated 4-aminobenzoic acid ethyl ester (PEG-25 PABA; Uvinul ® P 25), 4-dimethylaminobenzoic acid 2-ethyl
- Suitable pigments are, for example, the pigments with the C.I.names Pigment Red 57: 1, Pigment Red 57: 2.
- the preparations according to the invention are produced and packaged in a conventional manner known to the person skilled in the art. First the wax components and the emulsifiers are melted and mixed. This mixture is then filled in liquid form together with any other constituents in aerosol cans. After fitting the valve, the blowing agent is finally added as the last component.
- Another object of the invention is the use of the preparations mentioned for the treatment of keratin fibers, in particular human hair
- Vaseline-Vaseline oil and wax mixture (INCI name: Ceresin) (PARAFLUID MINERAL ⁇ LGES.) Phosphoric acid tris (C12-14 alcohol + 4 ethylene oxide) ester (CLARIANT) mono-di-tri-C 16-18 fatty alcohol + 4 ethylene oxide ortho-phosphoric acid ester (CLARIANT) lauryl alcohol + 4.5 ethylene oxide-acetic acid sodium salt (approx.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10109460 | 2001-02-27 | ||
DE10109460 | 2001-02-27 | ||
PCT/EP2001/008935 WO2002067872A1 (de) | 2001-02-27 | 2001-08-02 | Aerosol-spray zur behandlung keratinischer fasern |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1363582A1 true EP1363582A1 (de) | 2003-11-26 |
Family
ID=7675688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01962900A Ceased EP1363582A1 (de) | 2001-02-27 | 2001-08-02 | Aerosol-spray zur behandlung keratinischer fasern |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1363582A1 (de) |
DE (1) | DE10138093A1 (de) |
WO (1) | WO2002067872A1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014221367A1 (de) * | 2014-10-21 | 2016-04-21 | Henkel Ag & Co. Kgaa | Stylingmittel mit verbesserter Applizierbarkeit |
DE102014224383A1 (de) * | 2014-11-28 | 2016-06-02 | Henkel Ag & Co. Kgaa | Stylingmittel mit verbesserter Applizierbarkeit und Kühleffekt |
DE102016225873A1 (de) | 2016-12-21 | 2018-06-21 | Henkel Ag & Co. Kgaa | Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3330730A (en) * | 1962-08-03 | 1967-07-11 | Colgate Palmolive Co | Pressurized emulsion quick breaking foam compositions |
GB1298154A (en) * | 1969-04-18 | 1972-11-29 | Plough | Aerosol emollient |
JPS572215A (en) * | 1980-06-05 | 1982-01-07 | Toyo Aerosol Kogyo Kk | Aerosol cosmetic for hair |
FR2677369B1 (fr) * | 1991-06-05 | 1994-09-16 | Promotion Rech Innovation Tec | Mousse aerosol. |
JP3437637B2 (ja) * | 1994-05-12 | 2003-08-18 | 花王株式会社 | 泡状毛髪化粧料 |
DE19641992C2 (de) * | 1996-10-13 | 2001-07-26 | Wella Ag | Blütenwachs enthaltende kosmetische Zubereitungen |
KR100562977B1 (ko) * | 1997-03-21 | 2006-06-22 | 가부시키가이샤 시세이도 | 왁스의 미세분산 조성물 및 모발 화장료, 광택제 |
JP2000239131A (ja) * | 1999-02-18 | 2000-09-05 | Milbon Co Ltd | スプレー式ヘアワックス |
DE20022542U1 (de) * | 2000-10-04 | 2001-12-06 | Wella Ag | Haarwachsprodukt mit Wachsen, nicht-flüchtigen Ölen und flüchtigen, hydrophoben Stoffen |
-
2001
- 2001-08-02 EP EP01962900A patent/EP1363582A1/de not_active Ceased
- 2001-08-02 WO PCT/EP2001/008935 patent/WO2002067872A1/de active Application Filing
- 2001-08-03 DE DE10138093A patent/DE10138093A1/de not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO02067872A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE10138093A1 (de) | 2002-09-05 |
WO2002067872A1 (de) | 2002-09-06 |
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