EP1360343A1 - Dispositif de revetement de type ceramique d'un substrat - Google Patents
Dispositif de revetement de type ceramique d'un substratInfo
- Publication number
- EP1360343A1 EP1360343A1 EP02701200A EP02701200A EP1360343A1 EP 1360343 A1 EP1360343 A1 EP 1360343A1 EP 02701200 A EP02701200 A EP 02701200A EP 02701200 A EP02701200 A EP 02701200A EP 1360343 A1 EP1360343 A1 EP 1360343A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substrate
- coating
- layer
- ceramic
- source
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 50
- 238000000576 coating method Methods 0.000 title claims abstract description 28
- 239000011248 coating agent Substances 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000002245 particle Substances 0.000 claims description 11
- 238000009792 diffusion process Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000005684 electric field Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000005524 ceramic coating Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 56
- 239000007789 gas Substances 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 9
- 239000000919 ceramic Substances 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 235000019589 hardness Nutrition 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 239000002318 adhesion promoter Substances 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000005284 excitation Effects 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910003481 amorphous carbon Inorganic materials 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002347 wear-protection layer Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910019923 CrOx Inorganic materials 0.000 description 1
- 229910004205 SiNX Inorganic materials 0.000 description 1
- 229910010037 TiAlN Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- -1 transition metal nitride Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32192—Microwave generated discharge
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3471—Introduction of auxiliary energy into the plasma
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
- C23C14/354—Introduction of auxiliary energy into the plasma
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
- C23C14/354—Introduction of auxiliary energy into the plasma
- C23C14/357—Microwaves, e.g. electron cyclotron resonance enhanced sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/32—Processing objects by plasma generation
- H01J2237/33—Processing objects by plasma generation characterised by the type of processing
- H01J2237/339—Synthesising components
Definitions
- the invention relates to a device for ceramic-like coating of a substrate according to the preamble of claim 1.
- ceramic-like layers with excellent mechanical, electrical, optical and chemical properties can be produced.
- Appropriate methods have long been used for the coating of tools to extend the service life or to increase the life of mechanically stressed components or machine elements, such as. B. shafts, bearing components, pistons, gears or the like, and used for the decorative design of surfaces.
- metallic compounds such as. B. high-melting oxides, nitrides and carbides of aluminum, titanium, zirconium, chromium or silicon are used.
- the titanium-based coating systems such as TiN, TiCN or TiAlN coating systems, are mainly used as wear protection on cutting tools.
- Superhard materials are also known which represent a combination of a nanocrystalline (nc), hard transition metal nitride Me n N with amorphous (a) Si 3 N 4 .
- nc-MeN / a-SI 3 N 4 composite materials for example, the hardness increases sharply with decreasing crystallite size below about 4 to 5 nanometers and approximates that of the diaantes at 2 to 3 nanometers.
- the multi-phase structure of the coating leads, for example, to layers with a hardness> 2500 HV with comparatively low brittleness.
- Corresponding layers are produced in particular by plasma-activated chemical vapor deposition (PACVD) processes at temperatures of approximately 500 to 600 ° C.
- PSVD plasma-activated chemical vapor deposition
- the comparatively high temperature of the substrate and consequently the coating enable diffusion of correspondingly amorphously deposited coating components and thus the formation of nanocrystallites in an amorphous matrix.
- the object of the invention is to propose a device for ceramic-like coating of a substrate, means for applying a material, in particular by means of a plasma, to a surface of the substrate being provided which, compared to the prior art, also include a ceramic-like coating of comparatively temperature-sensitive Allows substrates.
- This object is achieved on the basis of a device of the type mentioned in the introduction by the characterizing features of claim 1.
- a device is characterized in that an energy source that is different from a material source of the material provided for coating is provided for locally defined energy input into the material located in front of and / or on the surface.
- this enables, in particular, a nanostructured ceramic, high-quality layer system to be implemented within a layer, the nanostructured metal crystallites with a crystal size of up to approximately 100 nm, for example consisting of MeO, MeN or MeC, in a further structure which is amorphous, crystalline or metallic and e.g. consists of amorphous silicon compounds or the like.
- the nanostructured layer contains at least one crystalline hard material phase.
- the layer hardness is significantly increased, for example hardnesses of over 4000 HV can be achieved when TiO crystallites are embedded.
- the brittleness of the ceramic layers is reduced, in particular by the nanostructuring.
- the entire layer system can be one or more layers, chemically and partially graded and / or ungraded.
- a run-in layer can be realized by a carbon-containing cover layer.
- corresponding nanocomposites can advantageously be deposited, for example at substrate temperatures T ⁇ 400 ° C., preferably at temperatures T ⁇ 250 ° C., so that comparatively temperature-sensitive substrates can also be coated.
- the supply of kinetic energy for increasing the surface mobility and thus for the diffusion of the deposited material components preferably takes place via an additional plasma excitation, so that compared to the prior art in particular much higher ion densities can be achieved, which is also due to a corresponding change in the color and the brightness of the Plasma is made clear.
- the plasma excitation or higher ion density and thus higher energy density the initially amorphously deposited particles on the substrate receive enough energy for diffusion to be able to form, for example, nanometer-sized TiO crystallites on the substrate.
- Further plasma sources are also conceivable for this purpose, which in particular at lower pressure, e.g. be operated in a fine vacuum.
- the high ion energy or ion density preferably prevents the build-up of microcrystallites which have already formed, and at the same time favors the advantageous nanocrystalline growth.
- This can include various three-dimensional components can be coated accordingly.
- the energy is introduced into the material located on the surface, so that the initially amorphously deposited particles on the substrate again have enough energy available for diffusion, in turn, for example, cubic, hexagonal, metallic or on the substrate to be able to form other nanometer-sized crystallites.
- a microwave unit is advantageously provided for the energy input, so that, for example, the ion density of the material can be increased by additional ionization during sputtering.
- advantageous ionization densities of approximately 10 10 to 10 13 ions per cm 3 can be achieved, so that the material which is initially amorphously deposited on the substrate has sufficient energy available for diffusion.
- microwave radiation for so-called electron cyclotron resonance excitation (ECR) is preferably provided.
- an ion source unit is provided for the energy input, so that in turn advantageous plasma excitation or an increase in the ionization density is realized, thereby permitting the diffusion of the initially amorphously deposited material on the substrate.
- a DC or RF excited hollow cathode unit or the like can also be provided for the energy input according to the invention.
- Common to these units is the locally defined energy input according to the invention, preferably into the material located in front of the surface of the substrate.
- UV unit or the like is advantageously provided. These units are preferably used to introduce additional kinetic energy for the diffusion of the particles initially deposited amorphously on the substrate into the material on the surface of the substrate.
- a cooling device for cooling the substrate is provided. This advantageously ensures that the substrate temperature is reduced as far as possible. In particular, this measure makes it possible to coat more temperature-sensitive substrates.
- the cooling device is preferably implemented by means of a metallic or other highly thermally conductive substrate carrier.
- an advantageous coolant can also flow through the cooling device, so that a further reduction in the substrate temperature can be achieved.
- a voltage source for generating an electrical field is provided between the material source and the substrate. This ensures that, for example, an advantageous potential profile is generated between the material source and the substrate and that charging of the substrate, in particular by means of an RF substrate or bias voltage, is prevented.
- FIG. 1 shows a schematic structure of a device according to the invention
- FIG. 2 shows a schematic 3D representation of a section of a coating produced according to the invention
- 3 shows a schematic representation of a multilayer layer produced according to the invention
- FIG. 4 shows a schematic illustration of a further multilayer layer produced according to the invention
- FIG. 5 shows a schematic representation of a third multilayer layer produced according to the invention.
- FIG. 1 schematically shows a section of a coating chamber 1 during a coating process.
- a layer 3 is applied to a substrate 2 at a chamber pressure of approximately 10 "3 to 10 " 2 mbar.
- a first material 5 is atomized by a sputter source 4.
- a second material 7 is sputtered with the material 5 simultaneously or with a time delay from a sputter source 6.
- the energy input locally defined according to the invention into the two materials 5, 7 takes place by means of the plasma 8 shown schematically in FIG is provided as plasma gas.
- the plasma 8 is generated, for example, with a microwave radiation of the frequency 2.45 GHz with a layer-dependent power of preferably 1 kW.
- the microwave radiation is coupled in, for example, via a rod antenna (not shown in more detail).
- the sputtering source 4 can comprise a metal, a metal oxide target or a mixed target, wherein the metal can be, for example, titanium, chromium, copper, zirconium or the like.
- a gas supply 9 and 10 two different reaction gases can be metered in as required during the coating.
- oxygen can be metered into the coating chamber 1 by the gas supply 9 in order to produce oxidic ceramic layers. If a sputter source 4 with a metal oxide target is used, oxidic ceramic layers can also be produced without an oxygen supply by means of the gas supply 9.
- the sputter source 6 can comprise, for example, a silicon and / or carbon target, so that the sputter source 6 enables the formation of the amorphous matrix, such as silicon nitride or the like, in particular with nitrogen supplied by the gas supply 10.
- the gas supply 10 can also supply other gases, so that other matrices can also be produced if required.
- the reaction of the sputtering components mostly takes place on the substrate.
- additional energy is introduced into the atomized or deposited particles by the plasma 8 by means of the ECR microwave source without the substrate being heated to any significant extent.
- the substrate temperature can be kept comparatively low. Due to the energy introduced by the ECR microwave source, particles of nanometer size, for example titanium oxide particles, are formed in the coating 3 on the substrate by diffusion of the initially amorphously deposited particles. Consequently, the high temperatures of the substrate which lead to the formation of the nanostructured coating according to the prior art are not required, so that temperature-sensitive substrates can also be coated according to the invention.
- the coating is scalable, without, for example, the substrate having to be used as an electrode for compacting the applied coating.
- a special embodiment of the invention comprises a voltage source which, for example, provides an RF bias voltage on the substrate. In this way, primarily only charging of the substrate 2 is prevented, so that in particular the deposition of the materials 5, 7 does not change disadvantageously even over a comparatively longer coating period.
- the nanocrystallites 11 can be TiO, TiN, ZrN, ZrO, TiC, SiC, carbon or corresponding nanocrystallites 11 and various mixtures thereof with grain sizes in the range from 5 to 20 nm.
- the proportion of the surface volume in the total volume is very high and the interfaces between the nanocrystallites 11 and the amorphous matrix 12 are comparatively sharp.
- FIG. 3 schematically shows a layer structure of a coating 3 produced according to the invention, the nanoscale multilayer layer 3 being applied to the substrate 2.
- layer 3 comprises an adhesion promoter 13, which can optionally be applied and, for example, consists of a metallic layer, such as an approximately 300 nm thick titanium adhesive layer.
- a layer according to FIG. 2, for example an amorphous silicon nitride layer 12 with nanoscale titanium oxide and / or carbon particles 11, can be applied as the next layer 14.
- a cover layer 15 can optionally be applied, which preferably consists of amorphous carbon ,
- three-dimensional components such as drills or the like can also be coated with a corresponding nanoscale multilayer layer 3.
- the three-layer structure ensures, in particular by means of the adhesion promoter 13, good adhesion of the superhard ceramic metal oxide layer 14 to the substrate 2.
- the cover layer 15 ensures, for example with a similar hardness, a high coefficient of friction, so that in particular the frictional properties of the nanostructured layer in a run-in phase of mechanically stressed components or machine elements, such as. B-. Shafts, bearing components, pistons, gears or the like, the two friction partners or over the entire life of the two friction partners is improved.
- a layer structure according to FIG. 4 can be provided.
- the adhesion promoter 13 and a layer 14, which for example comprises an amorphous carbon network 12 with nanoscale titanium oxide particles 11, are optionally provided.
- an alternative layer structure can in turn be provided with an optional adhesion promoter 13 and an amorphous carbon layer 16 and a layer 14 with an amorphous silicon nitride layer 12 and nanoscale titanium oxide particles 11.
- nanostructured metal oxide layers 14 can also be applied to diamond-like carbon layers 16, for example in order to improve the running-in behavior of wear protection layers with a lower coefficient of friction.
- nanostructured metal oxide layers 14 with or without inclusions or Upper cover layer 15 can be used as a wear protection layer for the highest load collectives with novel multifunctional properties. For example, due to their non-stick and advantageous rubbing properties, these can be used as dry lubricant layers for machining stainless steel, aluminum or the like.
- self-cleaning properties of titanium oxide layers can be combined with anti-scratch properties.
- Oxidic ceramic layers are generally advantageous because they have a high chemical inertness, are optically transparent and have a lower coefficient of friction than, for example, nitride layers.
- ceramic oxide layers have so far been used only to a limited extent in production, primarily due to the more sensitive, reactive process control than with nitridic layer systems.
- the stoichiometric oxygen content can be set here, for example, by regulating optical emission.
- oxidic ceramics are characterized by good rubbing properties and high chemical resistance with high layer hardness.
- nanocrystalline powder material can generally be supplied to an ion source or synthesized by means of this.
Abstract
L'invention concerne un dispositif de revêtement de type céramique d'un substrat (2), comportant des moyens d'application d'un matériau (5, 7), notamment au moyen d'un plasma (8), sur une surface du substrat (2). L'invention vise à mettre en oeuvre un revêtement céramique (3) de substrats (2) sensibles à la température. A cet effet, le dispositif selon l'invention comporte une source d'énergie différente d'une source de matériau (4, 6) destinée à émettre le matériau de revêtement (5, 7), ladite source d'énergie servant à l'apport d'énergie défini localement dans le matériau (3, 5, 7, 8) situé devant et/ou sur la surface.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10104611A DE10104611A1 (de) | 2001-02-02 | 2001-02-02 | Vorrichtung zur keramikartigen Beschichtung eines Substrates |
DE10104611 | 2001-02-02 | ||
PCT/DE2002/000138 WO2002061165A1 (fr) | 2001-02-02 | 2002-01-18 | Dispositif de revetement de type ceramique d'un substrat |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1360343A1 true EP1360343A1 (fr) | 2003-11-12 |
Family
ID=7672549
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02701200A Ceased EP1360343A1 (fr) | 2001-02-02 | 2002-01-18 | Dispositif de revetement de type ceramique d'un substrat |
Country Status (5)
Country | Link |
---|---|
US (1) | US20040144318A1 (fr) |
EP (1) | EP1360343A1 (fr) |
JP (1) | JP2004518026A (fr) |
DE (1) | DE10104611A1 (fr) |
WO (1) | WO2002061165A1 (fr) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10141696A1 (de) | 2001-08-25 | 2003-03-13 | Bosch Gmbh Robert | Verfahren zur Erzeugung einer nanostruktuierten Funktionsbeschichtung und damit herstellbare Beschichtung |
DE10256063A1 (de) * | 2002-11-30 | 2004-06-17 | Mahle Gmbh | Verfahren zum Beschichten von Kolbenringen für Verbrennungsmotoren |
DE10256257A1 (de) * | 2002-12-03 | 2004-06-24 | Robert Bosch Gmbh | Vorrichtung und Verfahren zum Beschichten eines Substrates und Beschichtung auf einem Substrat |
DE10305109B8 (de) * | 2003-02-07 | 2010-11-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Bauteil mit einer elektrisch hochisolierenden Schicht und Verfahren zu dessen Herstellung |
JP4559425B2 (ja) | 2004-07-22 | 2010-10-06 | 日本電信電話株式会社 | 2安定抵抗値取得装置及びその製造方法 |
EP1643005A3 (fr) * | 2004-09-01 | 2008-03-19 | EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt | Procédé de déposition de nanocouches inorganiques et/ou organiques par decharge de plasma |
DE102004052515B4 (de) | 2004-10-22 | 2019-01-03 | Aesculap Ag | Chirurgische Schere und Verfahren zum Herstellen einer chirurgischen Schere |
FR2886636B1 (fr) * | 2005-06-02 | 2007-08-03 | Inst Francais Du Petrole | Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree |
SE528908C2 (sv) * | 2005-07-15 | 2007-03-13 | Abb Research Ltd | Kontaktelement och kontaktanordning |
EP1937865A4 (fr) * | 2005-10-18 | 2012-12-12 | Southwest Res Inst | Revetements resistants a l'erosion |
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-
2001
- 2001-02-02 DE DE10104611A patent/DE10104611A1/de not_active Ceased
-
2002
- 2002-01-18 JP JP2002561097A patent/JP2004518026A/ja active Pending
- 2002-01-18 EP EP02701200A patent/EP1360343A1/fr not_active Ceased
- 2002-01-18 WO PCT/DE2002/000138 patent/WO2002061165A1/fr active Application Filing
- 2002-01-18 US US10/470,400 patent/US20040144318A1/en not_active Abandoned
Non-Patent Citations (1)
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See references of WO02061165A1 * |
Also Published As
Publication number | Publication date |
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DE10104611A1 (de) | 2002-08-14 |
US20040144318A1 (en) | 2004-07-29 |
WO2002061165A1 (fr) | 2002-08-08 |
JP2004518026A (ja) | 2004-06-17 |
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