EP1360118B1 - Closure cap comprising means for securing a moulded joint - Google Patents

Closure cap comprising means for securing a moulded joint Download PDF

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Publication number
EP1360118B1
EP1360118B1 EP02706854A EP02706854A EP1360118B1 EP 1360118 B1 EP1360118 B1 EP 1360118B1 EP 02706854 A EP02706854 A EP 02706854A EP 02706854 A EP02706854 A EP 02706854A EP 1360118 B1 EP1360118 B1 EP 1360118B1
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EP
European Patent Office
Prior art keywords
seal
cap
projection
assembly according
axis
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EP02706854A
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German (de)
French (fr)
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EP1360118A1 (en
Inventor
Philippe Nusbaum
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Bericap SARL
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Bericap SARL
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/02Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
    • B65D41/04Threaded or like caps or cap-like covers secured by rotation
    • B65D41/0435Threaded or like caps or cap-like covers secured by rotation with separate sealing elements
    • B65D41/045Discs

Definitions

  • the invention relates to an assembly comprising a stopper and a joint by pouring into the bottom of the stopper, as well as a method for carrying out of such a plug.
  • the invention relates more particularly to plastic plugs comprising a cylindrical skirt and a transverse end wall, the seal being cast against said transverse end wall.
  • the deposited material is hot, liquid or pasty, and therefore spreads on the inner face of the transverse wall.
  • the seal is then compressed against the transverse wall using a tool. It then occurs a physicochemical bonding the seal cast on the inner face of the transverse wall.
  • the adhesion of the seal to the transverse wall is not optimal. he happens in fact that the seal is detached from the said wall, and can escape of the stopper, in particular during the storage of the cap-seal assembly and transport for mounting on a container neck. The seal between the cap and the container neck on which it is mounted can no longer be assured.
  • US 4,697,716 discloses a plug having a groove on the face its transverse wall and intended to receive a seal cast in this throat.
  • the groove is delimited by two substantially axial walls: on the one hand the skirt of the cap and on the other hand an annular projection.
  • the annular projection may have a surface having a certain inclination with respect to the transverse wall of the plug, so as to allow the attachment of the seal and to avoid its axial displacement towards the opening of the plug.
  • annular projection is placed with respect to the axis of the plug of way that, once the seal is poured into the groove, and when the cap is screwed on a container neck, the seal is located opposite the rim of the neck of the container.
  • the projection serves both to hook the seal and sealing the plug. Because of this, the characteristics dimensioning of the projection must be precise, the plug molding being therefore made more complex.
  • the document GB 1 224 669 discloses a cap according to the preamble of the appended claim 1, having an annular projection on the internal face of its transverse wall, the projection being intended to serve as a means for attaching a seal to the bottom of the cap .
  • This document also describes a method according to the preamble of claim 13. A seal is poured into the bottom of the plug and then stamped, so as to match the shape of the inner face of the transverse wall and the projection. The seal thus has an annular boss at the projection.
  • the seal is intended to come into contact with the rim of a container neck at level of this boss. Therefore, the projection is placed so as to be in view of the rim of a container neck when the plug is associated with said neck.
  • stamping of the seal must also be carried out accurately, the surface state of the gasket at the level of the protrusion must make it possible to guarantee a good sealing. This stamping therefore constitutes an additional operation generating additional costs and longer manufacturing times.
  • document GB 2 111 965 As for the document GB 2 111 965, it describes a stopper, provided with lips sealing means for cooperating with the rim of a container neck. When the cap is placed on the neck, the lips are bent and applied against this rim, so as to seal. In order to ensure a good despite the rigidity of the lips, document GB 2 111 965 provides for cover the lips with a thin film of a softer material allowing to improve the contact between the lips and the rim of the neck.
  • the flexible material covers the lips forming a ring at the bottom of the plug.
  • the ring has a curved surface or a wedding shape perfectly the shape of the projections.
  • GB 2 111 965 is to improve the sealing of caps with sealing lips but without seal. It does not offer an effective solution to the problem of attachment of a seal cast against the transverse wall of a plug.
  • the object of the invention is to solve the problems posed by the prior art by providing a stopper - associated with a cast seal - in which the functions of attachment of the seal and sealing are dissociated.
  • the projection comprises at least one inclined face of an acute angle relative to the axis of the plug so that when the seal is placed in the plug, at least one zone of said seal is included in a zone latch located axially between the transverse wall and a part of the said projection.
  • the projection has, in axial section, the shape of at least one trapezium whose small base is located towards the free end of the said projection, said trapezium being such that one of the two angles adjacent to the small base is acute.
  • One of the two angles adjacent to the small base is between 40 ° and 80 °, especially close to 60 °.
  • the projection has, in axial section, the shape at least one trapezium whose large base is located towards the free end of the said projection.
  • said trapezoid has an axis of symmetry substantially parallel to the axis of the plug.
  • the projection is annular and substantially axis confused with the axis of the cap.
  • the cap may comprise two annular projections substantially concentric, of axis substantially coincident with the axis of the plug, the free ends of the two projections being for example axially offset one compared to each other.
  • the projection may have an axial height less than half to one third of the thickness of the transverse wall of the plug.
  • the invention relates to a set of parts cap and a seal, as previously described, and on the other hand a collar of container or receptacle having a neck, the receptacle being empty or at least partially filled with some content.
  • FIG. 1 shows a plug 1 of axis 2, the plug 1 being for example made of plastic.
  • the plug 1 comprises firstly a transverse end wall 3, substantially discoidal, and a cylindrical skirt 4 protruding substantially perpendicular to the transverse wall 3.
  • the cylindrical skirt 4 comprises, on its outer face 5, notches 6 intended for facilitate the screwing and unscrewing of the cap 1 by a user, and, on his inner face 7, a thread 8 intended to cooperate with the external thread of a container neck not shown.
  • the plug 1 also comprises an annular band 9 of tamper, connected at the free end 10 of the cylindrical skirt 4 by frangible bridges 11 or by a line of weaker resistance.
  • the tamper-evident band 9 has latching projections 12, directed towards the axis 2 of the plug 1, and intended for cooperate with the neck of a container to ensure the maintenance of the band at the neck of said container when, during the first opening of the said container, the bridges 11 are broken.
  • the plug 1 comprises locking elements 13, extending axially from the free end 10 of the cylindrical skirt 4 to and inside the tamper band 9, over a length such that the free end 14 of the said blocking element 13 is located, radially, opposite the band 9.
  • the locking elements 13 are located towards the inside of the cap 1 with respect to the tamper band. 9. Their role is to guarantee the integrity of the tamper-evident band 9 and the bridges 11 during assembly of the cap 1 on the neck of the container for which it is intended.
  • the stopper 1 finally comprises a seal 15, put in place by casting against the transverse wall 3, which will be described in more detail later in the description.
  • the transverse wall 3 of the plug 1 has, on its inner face 16, one or several projections 17 forming hooking means of the seal 15, thus preventing the separation of said seal 15 of the transverse wall 3.
  • the projections 17 are made by molding, with the stopper 1. They present a relatively low axial height, in particular less than half or even third, the thickness of the transverse wall 3 of the plug 1. In addition, the width protrusions 17 in cross section is also reduced.
  • the projections 17 are annular, of axis substantially coincident with the axis 2 of the cap 1.
  • Figure 4 shows a projection 17 according to the first embodiment, in axial section.
  • the projection 17 has, in axial section, the shape of a trapezium, or rather of two trapezes symmetrical with respect to the axis of said protrusion 17.
  • the large base 18 of the trapezium is substantially merged with the wall transverse 3, the small base 19 of the trapezium constituting the free end of the 17.
  • the small base 19 may be of very small length, so that the trapeze is like a triangle.
  • a first face 20 of the trapezium is inclined relative to the transverse wall 3 of a angle ⁇ obtus, for example between 130 ° and 170 °, especially close to 150 °.
  • a second face 21 of the trapezium, opposite the first face 20, is inclined relative to the transverse wall 3 by an acute angle ⁇ , for example between 40 ° and 80 °, in particular close to 60 °.
  • the angle between the transverse wall 3 and the second face 21 of the trapezium is round.
  • the transverse wall 3 of the cap 1 comprises three projections 17 annular, substantially concentric, axis substantially confused with the axis 2 of the plug 1.
  • a first annular projection 17 has a radius substantially equal to half the radius of the transverse wall 3.
  • Two additional projections 17, of close radius, are arranged towards the periphery of the transverse wall 3.
  • the transverse wall 3 of the plug 1 comprises three projections 17 annular, substantially concentric, axis substantially confused with the axis 2 of the plug 1.
  • a first annular projection 17 has a radius substantially equal to half the radius of the transverse wall 3.
  • a protrusion 17 additional is arranged towards the periphery of the transverse wall 3.
  • FIG. 5 a second embodiment of FIG. making projections 17.
  • the projection 17 has, in axial section, the shape of a trapezium, or rather of two trapezes symmetrical with respect to the axis of said protrusion 17.
  • the small base 22 of the trapezium is substantially merged with the wall transverse 3, the large base 23 of the trapezium constituting the free end of the projection 17.
  • the trapezium has an axis of symmetry 24 substantially parallel to the axis of the cap 1.
  • the faces 25, 26 of the trapezium distinct from the bases 22, 23 are inclined by relative to the transverse wall 3 of an acute angle ⁇ , for example between 40 ° and 80 °, especially close to 60 °.
  • the establishment of the seal 15 is by depositing a certain volume of material at bottom of said plug 1. This deposit can be made from an extruder or a hot melt gun.
  • the seal 15 thus extends substantially over the entire inner face 16 of the wall transverse 3 of the plug 1, and has the shape of a disk, thick substantially constant over its entire surface.
  • the seal can then be compressed against the transverse wall by means of a tool, leaving an impression on the seal 15 as illustrated in FIG. 2.
  • the volume of material deposited is sufficient for the thickness of the seal 15 to be greater at the axial height of the projections 17, even after compression.
  • This stamping makes it possible to give the seal 15 a shape perfectly adapted to the shape of the neck of the container to which the plug 1 is intended to be associated, in order to guarantee a very good seal.
  • the stamping makes it possible to penetrate the projections 17 into the material constituting the seal 15.
  • stamping of the seal 15, corresponding to a preferred embodiment of the invention, however, is optional, since it is not essential to the attachment of the seal 15 against the transverse wall 3 of the plug 1 with the help of protrusions 17.
  • the outer face of the seal 15 - that is to say the face of the seal 15 opposite the transverse wall 3 - is substantially flat, the exception possibly of the peripheral extreme zone of the joint 15 (without this has consequences that affect the water resistance).
  • the projections 17 having an axial height less than the thickness of the seal 15, they do not protrude outside the joint 15, but remain embedded and contained in the inside of the seal 15. As a result, the projections 17 do not deform the face exterior of the joint 15, the latter having a good quality surface condition, to ensure a good contact with the rim of the container neck, and therefore a good seal.
  • the method for producing the plug 1 is considerably simplified, and the dimensional requirements of the mold used considerably reduced.
  • the configuration of the projection 17 is such that there is a zone 27 - called zone hooking - included axially between the transverse wall 3 and the said projection 17. Part of the material deposited at the bottom of the cap and flowing against the transverse wall 3 is placed in the attachment zone 27.

Abstract

The invention concerns a closure cap comprising a terminal transverse wall (3) and a cylindrical skirt (4) including, on its inner surface, a thread designed to co-operate with a complementary outer thread of a container neck. The closure is designed to receive a moulded joint (15) extending substantially on the entire inner surface (16) of the transverse wall (3), over a substantially constant thickness. The transverse wall (3) comprises, on its inner surface (16), at least a projection (17) forming catching means for the joint (15), thereby ensuring retention of the joint (15) against the transverse wall (3). The axial height of the projection (17) is less than the thickness of said joint (15).

Description

L'invention concerne un ensemble comprenant un bouchon et un -joint mis en place par coulage au fond du bouchon, ainsi qu'un procédé pour la réalisation d'un tel bouchon.The invention relates to an assembly comprising a stopper and a joint by pouring into the bottom of the stopper, as well as a method for carrying out of such a plug.

L'invention se rapporte plus particulièrement aux bouchons en matière plastique comprenant une jupe cylindrique et une paroi transversale d'extrémité, le joint étant coulé contre la dite paroi transversale d'extrémité.The invention relates more particularly to plastic plugs comprising a cylindrical skirt and a transverse end wall, the seal being cast against said transverse end wall.

On connaít déjà de tels bouchons, dans lesquels la mise en place du joint se fait par dépôt d'un certain volume de matière constitutive du joint sur la paroi transversale, à l'aide d'un distributeur.We already know such plugs, in which the implementation of the seal is done by deposition of a certain volume of constituent material of the gasket on the wall transversal, using a dispenser.

La matière déposée est chaude, liquide ou pâteuse, et de ce fait s'étale sur la face interne de la paroi transversale. Le joint est ensuite comprimé contre la paroi transversale à l'aide d'un outil. Il se produit alors un collage physico-chimique du joint coulé sur la face interne de la paroi transversale.The deposited material is hot, liquid or pasty, and therefore spreads on the inner face of the transverse wall. The seal is then compressed against the transverse wall using a tool. It then occurs a physicochemical bonding the seal cast on the inner face of the transverse wall.

Dans l'art antérieur, le joint coulé est maintenu contre la paroi transversale uniquement par cette force d'adhésion physico-chimique.In the prior art, the cast seal is held against the transverse wall only by this force of physicochemical adhesion.

Cependant, l'adhérence du joint à la paroi transversale n'est pas optimale. Il arrive en effet que le joint se décolle de la dite paroi, et puisse ainsi s'échapper du bouchon, notamment lors du stockage de l'ensemble bouchon - joint et de son transport en vue du montage sur un col de récipient. L'étanchéité entre le bouchon et le col de récipient sur lequel il est monté ne peut alors plus être assurée.However, the adhesion of the seal to the transverse wall is not optimal. he happens in fact that the seal is detached from the said wall, and can escape of the stopper, in particular during the storage of the cap-seal assembly and transport for mounting on a container neck. The seal between the cap and the container neck on which it is mounted can no longer be assured.

Plusieurs solutions ont été envisagées pour résoudre ce problème.Several solutions have been considered to solve this problem.

Le document US 4 697 716 décrit un bouchon présentant une gorge sur la face interne de sa paroi transversale et destiné à recevoir un joint coulé dans cette gorge. La gorge est délimitée par deux parois sensiblement axiales : d'une part la jupe du bouchon et d'autre part une saillie annulaire.US 4,697,716 discloses a plug having a groove on the face its transverse wall and intended to receive a seal cast in this throat. The groove is delimited by two substantially axial walls: on the one hand the skirt of the cap and on the other hand an annular projection.

La saillie annulaire peut posséder une surface présentant une certaine inclinaison par rapport à la paroi transversale du bouchon, de façon à permettre l'accrochage du joint et à éviter son déplacement axial vers l'ouverture du bouchon.The annular projection may have a surface having a certain inclination with respect to the transverse wall of the plug, so as to allow the attachment of the seal and to avoid its axial displacement towards the opening of the plug.

Toutefois, la saillie annulaire est placée par rapport à l'axe du bouchon de manière que, une fois le joint coulé dans la gorge, et lorsque le bouchon est vissé sur un col de récipient, le joint soit situé en regard du rebord du col du récipient.However, the annular projection is placed with respect to the axis of the plug of way that, once the seal is poured into the groove, and when the cap is screwed on a container neck, the seal is located opposite the rim of the neck of the container.

De ce fait, la saillie doit répondre à un certain nombre de critères :

  • d'une part, la saillie doit présenter une hauteur axiale suffisamment importante pour permettre de délimiter une gorge et de contenir le joint dans cette gorge. Lorsque le bouchon est vissé sur le col de récipient, le joint est comprimé de sorte qu'il présente localement une épaisseur inférieure à la hauteur axiale de la saillie, et reste maintenu dans la gorge ;
    d'autre part, la position de la saillie doit être précise. En particulier, la saillie ne doit pas présenter un diamètre trop faible, ceci pouvant nuire à un bon maintien du joint dans la gorge. A l'inverse, la saillie ne doit pas présenter un diamètre trop important, car elle risquerait de ce cas de se trouver en regard du rebord du col du récipient, ce qui nuirait à l'étanchéité. De plus, compte tenu de la hauteur axiale de la saillie, le vissage du bouchon sur le col pourrait endommager la saillie.
As a result, the projection must meet a number of criteria:
  • on the one hand, the projection must have an axial height large enough to delimit a groove and contain the seal in this groove. When the cap is screwed onto the container neck, the seal is compressed so that it has locally a thickness less than the axial height of the projection, and remains in the groove;
    on the other hand, the position of the projection must be precise. In particular, the protrusion must not have a too small diameter, this may be detrimental to a good maintenance of the seal in the groove. Conversely, the protrusion should not have too large a diameter, because it might be in this case to be opposite the rim of the neck of the container, which would affect the seal. In addition, given the axial height of the projection, screwing the cap on the neck could damage the projection.

Ainsi, dans le document US 4 697 716, la saillie sert à la fois à l'accrochage du joint et à l'étanchéité du bouchon. De ce fait, les caractéristiques dimensionnelles de la saillie doivent être précises, le moulage du bouchon étant par conséquent rendu plus complexe. Thus, in document US Pat. No. 4,697,716, the projection serves both to hook the seal and sealing the plug. Because of this, the characteristics dimensioning of the projection must be precise, the plug molding being therefore made more complex.

Le document GB 1 224 669 décrit un bouchon selon le préambule de la revendication 1 annexée, comportant une saillie annulaire sur la face interne de sa paroi transversale, la saillie étant destinée à servir de moyen d'accrochage d'un joint au fond du bouchon. Ce document décrit aussi une méthode selon le préambule de la revendication 13.
Un joint est coulé au fond du bouchon puis matricé, de sorte à épouser la forme de la face interne de la paroi transversale et de la saillie. Le joint présente de ce fait un bossage annulaire au niveau de la saillie.
The document GB 1 224 669 discloses a cap according to the preamble of the appended claim 1, having an annular projection on the internal face of its transverse wall, the projection being intended to serve as a means for attaching a seal to the bottom of the cap . This document also describes a method according to the preamble of claim 13.
A seal is poured into the bottom of the plug and then stamped, so as to match the shape of the inner face of the transverse wall and the projection. The seal thus has an annular boss at the projection.

Le joint est destiné à venir en contact avec le rebord d'un col de récipient au niveau de ce bossage. Par conséquent, la saillie est placée de sorte à être en regard du rebord d'un col de récipient lorsque le bouchon est associé au dit col.The seal is intended to come into contact with the rim of a container neck at level of this boss. Therefore, the projection is placed so as to be in view of the rim of a container neck when the plug is associated with said neck.

De façon similaire au document US 4 697 716, la fabrication du bouchon décrit dans le document GB 1 224 669 est relativement complexe. En effet, les saillies doivent être positionnées et moulées de façon très précises, puisqu'elles jouent un rôle fondamental pour l'étanchéité.In a similar manner to US Pat. No. 4,697,716, the manufacture of the cap described in GB 1 224 669 is relatively complex. Indeed, the projections must be positioned and molded in a very precise way, since they play a fundamental role for sealing.

De plus, le matriçage du joint doit également être effectué de façon précise, l'état de surface du joint au niveau de la saillie devant permettre de garantir une bonne étanchéité. Ce matriçage constitue donc une opération supplémentaire générant un surcoût et des temps de fabrication plus importants.In addition, the stamping of the seal must also be carried out accurately, the surface state of the gasket at the level of the protrusion must make it possible to guarantee a good sealing. This stamping therefore constitutes an additional operation generating additional costs and longer manufacturing times.

Quant au document GB 2 111 965, il décrit un bouchon, muni de lèvres d'étanchéité destinées à coopérer avec le rebord d'un col de récipient. Lorsque le bouchon est placé sur le col, les lèvres sont fléchies et appliquées contre ce rebord, de façon à assurer l'étanchéité. Afin de permettre d'assurer une bonne étanchéité, malgré la rigidité des lèvres, le document GB 2 111 965 prévoit de revêtir les lèvres d'un mince film d'une matière plus souple permettant d'améliorer le contact entre les lèvres et le rebord du col.As for the document GB 2 111 965, it describes a stopper, provided with lips sealing means for cooperating with the rim of a container neck. When the cap is placed on the neck, the lips are bent and applied against this rim, so as to seal. In order to ensure a good despite the rigidity of the lips, document GB 2 111 965 provides for cover the lips with a thin film of a softer material allowing to improve the contact between the lips and the rim of the neck.

La matière souple recouvre les lèvres en formant un anneau au fond du bouchon. L'anneau présente une surface bombée ou une forme épousant parfaitement la forme des saillies. The flexible material covers the lips forming a ring at the bottom of the plug. The ring has a curved surface or a wedding shape perfectly the shape of the projections.

Toutefois, l'objectif du document GB 2 111 965 est d'améliorer l'étanchéité des bouchons munis de lèvres d'étanchéité mais dépourvus de joint. Il ne propose pas de solution efficace au problème d'accrochage d'un joint coulé contre la paroi transversale d'un bouchon.
Le but de l'invention est de résoudre les problèmes posés par l'art antérieur, en fournissant un bouchon - associé à un joint coulé - dans lequel les fonctions d'accrochage du joint et d'étanchéité sont dissociées.
However, the purpose of GB 2 111 965 is to improve the sealing of caps with sealing lips but without seal. It does not offer an effective solution to the problem of attachment of a seal cast against the transverse wall of a plug.
The object of the invention is to solve the problems posed by the prior art by providing a stopper - associated with a cast seal - in which the functions of attachment of the seal and sealing are dissociated.

A cet effet, et selon un premier aspect, l'invention concerne un ensemble comprenant :

  • un bouchon du type comportant une paroi transversale d'extrémité et une jupe cylindrique comprenant, sur sa face interne un filetage destiné à coopérer avec un filetage complémentaire externe d'un col de récipient ;
  • et un joint placé contre la face interne de la paroi transversale du bouchon, le joint ayant été mis en place par coulage et s'étendant sensiblement sur toute la face interne de la dite paroi transversale la paroi transversale du bouchon comprend, sur sa face interne, au moins une saillie formant moyen d'accrochage pour le joint, la dite saillie étant enrobée et recouverte par le joint, le joint présentant la forme générale d'un disque d'épaisseur sensiblement constante, et la hauteur axiale de la saillie étant inférieure à l'épaisseur du dit joint.
For this purpose, and according to a first aspect, the invention relates to an assembly comprising:
  • a plug of the type comprising a transverse end wall and a cylindrical skirt comprising, on its internal face, a thread intended to cooperate with an external complementary thread of a container neck;
  • and a seal placed against the internal face of the transverse wall of the plug, the seal having been put in place by casting and extending substantially over the entire internal face of said transverse wall, the transverse wall of the plug comprises, on its internal face at least one projection forming attachment means for the seal, said protrusion being coated and covered by the seal, the seal having the general shape of a disc of substantially constant thickness, and the axial height of the projection being less than to the thickness of the said seal.

Ceci permet notamment de s'affranchir des contraintes de positionnement précis des saillies d'accrochage, et donc de réaliser un bouchon selon un procédé plus simple et moins contraignant.This makes it possible to overcome the constraints of positioning accurate hooking projections, and thus to achieve a cap according to a simpler and less restrictive process.

Selon une réalisation de l'invention, la saillie comprend au moins une face inclinée d'un angle aigu par rapport à l'axe du bouchon de sorte que, lorsque le joint est placé dans le bouchon, au moins une zone du dit joint est comprise dans une zone d'accrochage située, axialement, entre la paroi transversale et une partie de la dite saillie. According to one embodiment of the invention, the projection comprises at least one inclined face of an acute angle relative to the axis of the plug so that when the seal is placed in the plug, at least one zone of said seal is included in a zone latch located axially between the transverse wall and a part of the said projection.

Selon une première réalisation, la saillie présente, en coupe axiale, la forme d'au moins un trapèze dont la petite base est située vers l'extrémité libre de la dite saillie, le dit trapèze étant tel que l'un des deux angles adjacents à la petite base est aigu. L'un des deux angles adjacents à la petite base est compris entre 40° et 80°, notamment voisin de 60°.According to a first embodiment, the projection has, in axial section, the shape of at least one trapezium whose small base is located towards the free end of the said projection, said trapezium being such that one of the two angles adjacent to the small base is acute. One of the two angles adjacent to the small base is between 40 ° and 80 °, especially close to 60 °.

Selon une deuxième réalisation, la saillie présente, en coupe axiale, la forme d'au moins un trapèze dont la grande base est située vers l'extrémité libre de la dite saillie. Par exemple, le dit trapèze possède un axe de symétrie sensiblement parallèle à l'axe du bouchon.According to a second embodiment, the projection has, in axial section, the shape at least one trapezium whose large base is located towards the free end of the said projection. For example, said trapezoid has an axis of symmetry substantially parallel to the axis of the plug.

Selon une réalisation possible, la saillie est annulaire et d'axe sensiblement confondu avec l'axe du bouchon.According to one possible embodiment, the projection is annular and substantially axis confused with the axis of the cap.

Le bouchon peut comprendre deux saillies annulaires sensiblement concentriques, d'axe sensiblement confondu avec l'axe du bouchon, les extrémités libres des deux saillies étant par exemple décalées axialement l'une par rapport à l'autre.The cap may comprise two annular projections substantially concentric, of axis substantially coincident with the axis of the plug, the free ends of the two projections being for example axially offset one compared to each other.

Selon d'autres caractéristiques, la saillie peut présenter une hauteur axiale inférieure à la moitié ou au tiers de l'épaisseur de la paroi transversale du bouchon.According to other features, the projection may have an axial height less than half to one third of the thickness of the transverse wall of the plug.

Selon un deuxième aspect, l'invention concerne un ensemble d'une part un bouchon et un joint, tel que précédemment décrits, et d'autre part un col de récipient ou un récipient ayant un col, le dit récipient étant vide ou au moins partiellement rempli d'un certain contenu.According to a second aspect, the invention relates to a set of parts cap and a seal, as previously described, and on the other hand a collar of container or receptacle having a neck, the receptacle being empty or at least partially filled with some content.

Enfin, selon un troisième aspect, l'invention concerne un procédé de réalisation d'un ensemble bouchon - joint comprenant les étapes suivantes :

  • on réalise par moulage un bouchon comprenant au moins une saillie ;
  • on dépose au fond du bouchon un certain volume de matière constitutive du joint sous forme liquide ou pâteuse, de sorte que la matière s'étale sur la face interne de la paroi transversale du bouchon, enrobe et recouvre la saillie, le dit volume étant suffisant pour que l'épaisseur du joint soit supérieure à la hauteur axiale de la saillie.
Finally, according to a third aspect, the invention relates to a method for producing a plug-and-seal assembly comprising the following steps:
  • a plug is produced by molding comprising at least one projection;
  • at the bottom of the cap is deposited a certain volume of constituent material of the seal in liquid or pasty form, so that the material spreads on the inner face of the transverse wall of the plug, coats and covers the projection, said volume being sufficient so that the thickness of the seal is greater than the axial height of the projection.

Une fois la matière constitutive du joint déposée au fond du bouchon, on peut comprimer la dite matière contre la paroi transversale du bouchon.Once the constitutive material of the seal deposited at the bottom of the cap, one can compressing said material against the transverse wall of the stopper.

Les autres caractéristiques de l'invention résultent de la description qui suit de modes de réalisation, description effectuée en référence aux figures annexées dans lesquelles :

  • la figure 1 est une vue en coupe axiale d'un bouchon présentant des saillies selon un premier mode de réalisation, le dit bouchon comportant un joint coulé contre sa paroi transversale ;
  • la figure 2 est une vue du détail A de la figure 1 ;
  • la figure 3 est une vue en coupe axiale partielle d'un bouchon présentant des saillies selon une variante d'un premier mode de réalisation ;
  • la figure 4 est une vue du détail B de la figure 3 ;
  • la figure 5 est une vue en coupe axiale partielle d'un bouchon présentant des saillies selon un deuxième mode de réalisation ;
The other features of the invention result from the following description of embodiments, description made with reference to the appended figures in which:
  • Figure 1 is an axial sectional view of a cap having projections according to a first embodiment, said plug having a seal cast against its transverse wall;
  • Figure 2 is a view of detail A of Figure 1;
  • Figure 3 is a partial axial sectional view of a cap having projections according to a variant of a first embodiment;
  • Figure 4 is a detail view B of Figure 3;
  • Figure 5 is a partial axial sectional view of a cap having projections according to a second embodiment;

On se réfère tout d'abord à la figure 1 qui représente un bouchon 1 d'axe 2, le bouchon 1 étant par exemple réalisé en matière plastique.Referring first to Figure 1 which shows a plug 1 of axis 2, the plug 1 being for example made of plastic.

Le bouchon 1 comprend tout d'abord une paroi transversale d'extrémité 3, sensiblement discoïdale, ainsi qu'une jupe cylindrique 4 faisant saillie sensiblement perpendiculairement à la paroi transversale 3.The plug 1 comprises firstly a transverse end wall 3, substantially discoidal, and a cylindrical skirt 4 protruding substantially perpendicular to the transverse wall 3.

La jupe cylindrique 4 comporte, sur sa face extérieure 5, des crans 6 destinés à faciliter le vissage et le dévissage du bouchon 1 par un utilisateur, et, sur sa face intérieure 7, un filetage 8 destiné à coopérer avec le filetage externe d'un col de récipient non représenté.The cylindrical skirt 4 comprises, on its outer face 5, notches 6 intended for facilitate the screwing and unscrewing of the cap 1 by a user, and, on his inner face 7, a thread 8 intended to cooperate with the external thread of a container neck not shown.

Le bouchon 1 comprend également une bande d'inviolabilité 9 annulaire, reliée à l'extrémité libre 10 de la jupe cylindrique 4 par des ponts frangibles 11 ou par une ligne de plus faible résistance. La bande d'inviolabilité 9 comporte des saillies d'accrochage 12, dirigées vers l'axe 2 du bouchon 1, et destinées à coopérer avec le col d'un récipient pour assurer le maintien de la bande d'inviolabilité 9 au col du dit récipient lorsque, lors de la première ouverture du dit récipient, les ponts 11 sont rompus.The plug 1 also comprises an annular band 9 of tamper, connected at the free end 10 of the cylindrical skirt 4 by frangible bridges 11 or by a line of weaker resistance. The tamper-evident band 9 has latching projections 12, directed towards the axis 2 of the plug 1, and intended for cooperate with the neck of a container to ensure the maintenance of the band at the neck of said container when, during the first opening of the said container, the bridges 11 are broken.

Le bouchon 1 comporte des éléments de blocage 13, s'étendant axialement depuis l'extrémité libre 10 de la jupe cylindrique 4 vers et à l'intérieur de la bande d'inviolabilité 9, sur une longueur telle que l'extrémité libre 14 du dit élément de blocage 13 se situe, radialement, en regard de la bande d'inviolabilité 9. Les éléments de blocage 13 sont situés vers l'intérieur du bouchon 1 par rapport à la bande d'inviolabilité 9. Leur rôle est de garantir l'intégrité de la bande d'inviolabilité 9 et des ponts 11 lors du montage du bouchon 1 sur le col du récipient auquel il est destiné.The plug 1 comprises locking elements 13, extending axially from the free end 10 of the cylindrical skirt 4 to and inside the tamper band 9, over a length such that the free end 14 of the said blocking element 13 is located, radially, opposite the band 9. The locking elements 13 are located towards the inside of the cap 1 with respect to the tamper band. 9. Their role is to guarantee the integrity of the tamper-evident band 9 and the bridges 11 during assembly of the cap 1 on the neck of the container for which it is intended.

Le bouchon 1 comporte enfin un joint d'étanchéité 15, mis en place par coulage contre la paroi transversale 3, et qui sera décrit plus en détail dans la suite de la description.The stopper 1 finally comprises a seal 15, put in place by casting against the transverse wall 3, which will be described in more detail later in the description.

La paroi transversale 3 du bouchon 1 comporte, sur sa face interne 16, une ou plusieurs saillies 17 formant moyen d'accrochage du joint 15, empêchant ainsi la désolidarisation du dit joint 15 de la paroi transversale 3. Les saillies 17 sont venues de fabrication, par moulage, avec le bouchon 1. Elles présentent une hauteur axiale relativement faible, notamment inférieure à la moitié, voire au tiers, de l'épaisseur de la paroi transversale 3 du bouchon 1. De plus, la largeur des saillies 17 en coupe transversale est également réduite.The transverse wall 3 of the plug 1 has, on its inner face 16, one or several projections 17 forming hooking means of the seal 15, thus preventing the separation of said seal 15 of the transverse wall 3. The projections 17 are made by molding, with the stopper 1. They present a relatively low axial height, in particular less than half or even third, the thickness of the transverse wall 3 of the plug 1. In addition, the width protrusions 17 in cross section is also reduced.

Les saillies 17 sont annulaires, d'axe sensiblement confondu avec l'axe 2 du bouchon 1. The projections 17 are annular, of axis substantially coincident with the axis 2 of the cap 1.

On décrit à présent, en référence aux figures 1 à 4, un premier mode de réalisation des saillies 17.
La figure 4 représente une saillie 17 conforme au premier mode de réalisation, en coupe axiale.
A first embodiment of the projections 17 is now described with reference to FIGS. 1 to 4.
Figure 4 shows a projection 17 according to the first embodiment, in axial section.

La saillie 17 présente, en coupe axiale, la forme d'un trapèze, ou plutôt de deux trapèzes symétriques par rapport à l'axe de la dite saillie 17.The projection 17 has, in axial section, the shape of a trapezium, or rather of two trapezes symmetrical with respect to the axis of said protrusion 17.

La grande base 18 du trapèze est sensiblement confondue avec la paroi transversale 3, la petite base 19 du trapèze constituant l'extrémité libre de la saillie 17. La petite base 19 peut être de longueur très petite, de sorte que le trapèze s'apparente à un triangle.The large base 18 of the trapezium is substantially merged with the wall transverse 3, the small base 19 of the trapezium constituting the free end of the 17. The small base 19 may be of very small length, so that the trapeze is like a triangle.

Une première face 20 du trapèze, distincte des bases 18, 19, et située en regard de l'axe 2 du bouchon 1, est inclinée par rapport à la paroi transversale 3 d'un angle α obtus, par exemple compris entre 130° et 170°, notamment voisin de 150°. Une deuxième face 21 du trapèze, opposée à la première face 20, est inclinée par rapport à la paroi transversale 3 d'un angle β aigu, par exemple compris entre 40° et 80°, notamment voisin de 60°.A first face 20 of the trapezium, distinct from the bases 18, 19, and located opposite of the axis 2 of the plug 1, is inclined relative to the transverse wall 3 of a angle α obtus, for example between 130 ° and 170 °, especially close to 150 °. A second face 21 of the trapezium, opposite the first face 20, is inclined relative to the transverse wall 3 by an acute angle β, for example between 40 ° and 80 °, in particular close to 60 °.

L'angle entre la paroi transversale 3 et la deuxième face 21 du trapèze est arrondi.The angle between the transverse wall 3 and the second face 21 of the trapezium is round.

Selon une première variante de ce premier mode de réalisation, illustrée sur les figures 1 et 2, la paroi transversale 3 du bouchon 1 comprend trois saillies 17 annulaires, sensiblement concentriques, d'axe sensiblement confondu avec l'axe 2 du bouchon 1. Une première saillie annulaire 17 possède un rayon sensiblement égal à la moitié du rayon de la paroi transversale 3. Deux saillies 17 supplémentaires, de rayons proches, sont disposées vers la périphérie de la paroi transversale 3.According to a first variant of this first embodiment, illustrated on the Figures 1 and 2, the transverse wall 3 of the cap 1 comprises three projections 17 annular, substantially concentric, axis substantially confused with the axis 2 of the plug 1. A first annular projection 17 has a radius substantially equal to half the radius of the transverse wall 3. Two additional projections 17, of close radius, are arranged towards the periphery of the transverse wall 3.

Selon une deuxième variante de ce premier mode de réalisation, illustrée sur la figure 3, la paroi transversale 3 du bouchon 1 comprend trois saillies 17 annulaires, sensiblement concentriques, d'axe sensiblement confondu avec l'axe 2 du bouchon 1. Une première saillie annulaire 17 possède un rayon sensiblement égal à la moitié du rayon de la paroi transversale 3. Une saillie 17 supplémentaire est disposée vers la périphérie de la paroi transversale 3.According to a second variant of this first embodiment, illustrated on the 3, the transverse wall 3 of the plug 1 comprises three projections 17 annular, substantially concentric, axis substantially confused with the axis 2 of the plug 1. A first annular projection 17 has a radius substantially equal to half the radius of the transverse wall 3. A protrusion 17 additional is arranged towards the periphery of the transverse wall 3.

On décrit maintenant, en référence à la figure 5, un deuxième mode de réalisation des saillies 17.With reference to FIG. 5, a second embodiment of FIG. making projections 17.

La saillie 17 présente, en coupe axiale, la forme d'un trapèze, ou plutôt de deux trapèzes symétriques par rapport à l'axe de la dite saillie 17.The projection 17 has, in axial section, the shape of a trapezium, or rather of two trapezes symmetrical with respect to the axis of said protrusion 17.

La petite base 22 du trapèze est sensiblement confondue avec la paroi transversale 3, la grande base 23 du trapèze constituant l'extrémité libre de la saillie 17. Le trapèze possède un axe de symétrie 24 sensiblement parallèle à l'axe du bouchon 1.The small base 22 of the trapezium is substantially merged with the wall transverse 3, the large base 23 of the trapezium constituting the free end of the projection 17. The trapezium has an axis of symmetry 24 substantially parallel to the axis of the cap 1.

Les faces 25, 26 du trapèze distinctes des bases 22, 23 sont inclinées par rapport à la paroi transversale 3 d'un angle γ aigu, par exemple compris entre 40° et 80°, notamment voisin de 60°.The faces 25, 26 of the trapezium distinct from the bases 22, 23 are inclined by relative to the transverse wall 3 of an acute angle γ, for example between 40 ° and 80 °, especially close to 60 °.

La mise en place du joint 15 se fait par dépôt d'un certain volume de matière au fond du dit bouchon 1. Ce dépôt peut être effectué à partir d'une extrudeuse ou d'un pistolet à « hot melt ».The establishment of the seal 15 is by depositing a certain volume of material at bottom of said plug 1. This deposit can be made from an extruder or a hot melt gun.

La matière constitutive du joint 15, chaude et liquide, ou du moins pâteuse, s'étale sur la face interne 16 de la paroi transversale 3, s'écoule jusqu'aux saillies 17, les enrobe et les recouvre.The constituent material of the seal 15, hot and liquid, or at least pasty, spread on the inner face 16 of the transverse wall 3, flows to protrusions 17, coats and covers them.

Le joint 15 s'étend ainsi sensiblement sur toute la face interne 16 de la paroi transversale 3 du bouchon 1, et présente la forme d'un disque, d'épaisseur sensiblement constante sur toute sa surface.The seal 15 thus extends substantially over the entire inner face 16 of the wall transverse 3 of the plug 1, and has the shape of a disk, thick substantially constant over its entire surface.

Le joint peut ensuite être comprimé contre la paroi transversale à l'aide d'un outil, laissant sur le joint 15 une empreinte comme illustré sur la figure 2. Le volume de matière déposé est suffisant pour que l'épaisseur du joint 15 soit supérieure à la hauteur axiale des saillies 17, même après compression.
Ce matriçage permet de donner au joint 15 une forme parfaitement adaptée à la forme du col du récipient auquel le bouchon 1 est destiné à être associé, afin de garantir une très bonne étanchéité. De plus, le matriçage permet de bien faire pénétrer les saillies 17 dans la matière constitutive du joint 15.
The seal can then be compressed against the transverse wall by means of a tool, leaving an impression on the seal 15 as illustrated in FIG. 2. The volume of material deposited is sufficient for the thickness of the seal 15 to be greater at the axial height of the projections 17, even after compression.
This stamping makes it possible to give the seal 15 a shape perfectly adapted to the shape of the neck of the container to which the plug 1 is intended to be associated, in order to guarantee a very good seal. In addition, the stamping makes it possible to penetrate the projections 17 into the material constituting the seal 15.

Le matriçage du joint 15, correspondant à un mode de réalisation préféré de l'invention, est toutefois optionnel, puisqu'il n'est pas indispensable à l'accrochage du joint 15 contre la paroi transversale 3 du bouchon 1 à l'aide des saillies 17.The stamping of the seal 15, corresponding to a preferred embodiment of the invention, however, is optional, since it is not essential to the attachment of the seal 15 against the transverse wall 3 of the plug 1 with the help of protrusions 17.

Avec ou sans matriçage, la face extérieure du joint 15 - c'est-à-dire la face du joint 15 opposée à la paroi transversale 3 - est sensiblement plane, à l'exception éventuellement de la zone extrême périphérique du joint 15 (sans que ceci ait des conséquences nuisant à l'étanchéité).With or without coining, the outer face of the seal 15 - that is to say the face of the seal 15 opposite the transverse wall 3 - is substantially flat, the exception possibly of the peripheral extreme zone of the joint 15 (without this has consequences that affect the water resistance).

Les saillies 17 ayant une hauteur axiale inférieure à l'épaisseur du joint 15, elles ne dépassent pas à l'extérieur du joint 15, mais restent enrobées et contenues à l'intérieur du joint 15. De ce fait, les saillies 17 ne déforment pas la face extérieure du joint 15, celle-ci présentant un état de surface de bonne qualité, permettant de garantir un bon contact avec le rebord du col de récipient, et donc une bonne étanchéité. De plus, les saillies ne dépassant pas à l'extérieur du joint 15, il n'existe aucune contrainte particulière sur leur position au niveau de la face intérieure 16 de la paroi transversale 3 du bouchon 1.The projections 17 having an axial height less than the thickness of the seal 15, they do not protrude outside the joint 15, but remain embedded and contained in the inside of the seal 15. As a result, the projections 17 do not deform the face exterior of the joint 15, the latter having a good quality surface condition, to ensure a good contact with the rim of the container neck, and therefore a good seal. In addition, protrusions not exceeding the outside of 15, there is no particular constraint on their position at the level of the inner face 16 of the transverse wall 3 of the plug 1.

Le procédé de réalisation du bouchon 1 s'en trouve considérablement simplifié, et les exigences dimensionnelles du moule utilisé considérablement réduites.The method for producing the plug 1 is considerably simplified, and the dimensional requirements of the mold used considerably reduced.

La configuration de la saillie 17 est telle qu'il existe une zone 27 - dite zone d'accrochage - comprise axialement entre la paroi transversale 3 et la dite saillie 17. Une partie de la matière déposée au fond du bouchon et s'écoulant contre la paroi transversale 3 vient se placer dans la zone d'accrochage 27. The configuration of the projection 17 is such that there is a zone 27 - called zone hooking - included axially between the transverse wall 3 and the said projection 17. Part of the material deposited at the bottom of the cap and flowing against the transverse wall 3 is placed in the attachment zone 27.

Ainsi, en plus du collage physico-chimique du joint 15 coulé sur la face interne 16 de la paroi transversale 3, il existe, du fait de la présence des saillies 17, un accrochage mécanique du dit joint 15, une fois solidifié, qui l'empêche de se désolidariser de la dite paroi transversale 3.Thus, in addition to the physicochemical bonding of the seal 15 cast on the face 16 of the transverse wall 3, it exists, because of the presence of protrusions 17, a mechanical attachment of said joint 15, once solidified, which prevents it from becoming detached from said transverse wall 3.

Claims (14)

  1. Assembly comprising:
    a cap (1) of the type comprising an end cross wall (3) and a cylindrical skirt (4) comprising a thread (8) on its inside face (7) designed to cooperate with a complementary external thread on the neck of a receptacle;
    and a seal (15) placed in contact with the inside face (16) of the cross wall (3) of the cap (1), the seal (15) having been put into place by moulding and extending approximately over the entire inside face (16) of the said cross wall (3);
       the cross wall (3) of the cap (1) comprising at least one projection (17) on its inside face (16) forming an attachment means for the seal (15), the said projection (17) being coated and covered by the seal (15), characterised in that the seal is generally in the form of a disk with an approximately constant thickness, the axial height of the protection (17) being less than the thickness of the said seal (15).
  2. Assembly according to claim 1, characterised in that the protection (17) comprises at least one face (21, 25, 27) inclined at an acute angle (β,γ) from the axis (2) of the cap (1) such that when the seal (15) is put into place in the cap (1), at least one area of the said seal (15) is included within an attachment area (27) located axially between the cross wall (3) and a part of the said projection (17).
  3. Assembly according to claim 1 or 2, characterised in that the projection (17) has an axial section in the form of at least one trapezium for which the small base (19) is located towards the free end of the said projection (17), the said trapezium being such that one of the two angles (β) adjacent to the small base (19) is acute.
  4. Assembly according to claim 3, characterised in that one of the two angles (β) adjacent to the small base (19) is between 40° and 80°, and particularly close to 60°.
  5. Assembly according to claim 1 or 2, characterised in that projection (17) is in the shape of at least one trapezium in an axial section, for which the large base (23) is towards the free end of the said projection (17).
  6. Assembly according to claim 5, characterised in that the said trapezium has an axis of symmetry (24) approximately parallel to the axis (2) of the cap (1).
  7. Assembly according to any one of claims 1 to 6, characterised in that the projection (17) is annular, the axis of the said projection (17) being approximately coincident with the axis (2) of the cap (1).
  8. Assembly according to any one of claims 1 to 7, characterised in that it comprises two approximately concentric annular projections (17), with an axis approximately coincident with the axis (2) of the cap (1).
  9. Assembly according to claim 8, characterised in that the free ends (19) of the two projections (17) are axially offset from each other.
  10. Assembly according to any one of claims 1 to 9, characterised in that the axial height of the projection (17) is less than half the thickness of the cross wall of the cap.
  11. Assembly according to any one of claims 1 to 10, characterised in that the axial height of the projection (17) is less than a third of the thickness of the cross wall of the cap.
  12. Assembly comprising firstly a cap (1) and a seal (15) according to any one of claims 1 to 11, and secondly a receptacle neck or a receptacle with a neck, the said receptacle being empty or at least partially filled with given contents.
  13. Process for making a cap (1) - seal (15) assembly according to any one of claims 1 to 11, comprising the following steps:
    a cap (1) comprising at least one projection (17) is made by moulding;
    a given volume of material forming the seal (15) is deposited in the bottom of the cap (1), in liquid or paste form, such that the material spends over the inside face (16) of the cross wall (3) of the cap (1), and coats and covers the projection (17), and is characterised in that the said volume is sufficient so that the thickness of the seal is greater than the axial height of the projection (17).
  14. Process for making a cap (1) - seal (15) assembly according to claim 13, characterised in that once the material from which the seal (15) is made has been deposited in the bottom of the cap (1), the said material is compressed in contact with the cross wall (3) of the cap (1).
EP02706854A 2001-02-15 2002-02-13 Closure cap comprising means for securing a moulded joint Expired - Lifetime EP1360118B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0102084A FR2820722B1 (en) 2001-02-15 2001-02-15 PLUG COMPRISING MEANS FOR HANGING A CAST JOINT
FR0102084 2001-02-15
PCT/FR2002/000553 WO2002064440A1 (en) 2001-02-15 2002-02-13 Closure cap comprising means for securing a moulded joint

Publications (2)

Publication Number Publication Date
EP1360118A1 EP1360118A1 (en) 2003-11-12
EP1360118B1 true EP1360118B1 (en) 2005-09-28

Family

ID=8860068

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02706854A Expired - Lifetime EP1360118B1 (en) 2001-02-15 2002-02-13 Closure cap comprising means for securing a moulded joint

Country Status (7)

Country Link
EP (1) EP1360118B1 (en)
AT (1) ATE305418T1 (en)
DE (1) DE60206360T2 (en)
ES (1) ES2250621T3 (en)
FR (1) FR2820722B1 (en)
HU (1) HUP0303032A3 (en)
WO (1) WO2002064440A1 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1224669A (en) * 1967-09-06 1971-03-10 Armstrong Cork Co Container closure having a moulded-in liner
NL8204885A (en) * 1981-12-24 1983-07-18 Anchor Hocking Corp LINELESS VACUUM CLOSURE OF PLASTIC.
US4697716A (en) * 1982-07-06 1987-10-06 Owens-Illinois, Inc. Closures with cast sealing gasket

Also Published As

Publication number Publication date
HUP0303032A3 (en) 2004-04-28
DE60206360T2 (en) 2006-06-22
ATE305418T1 (en) 2005-10-15
DE60206360D1 (en) 2005-11-03
FR2820722B1 (en) 2003-07-25
ES2250621T3 (en) 2006-04-16
FR2820722A1 (en) 2002-08-16
EP1360118A1 (en) 2003-11-12
WO2002064440A1 (en) 2002-08-22
HUP0303032A2 (en) 2003-12-29

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