EP1334167A1 - Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiques - Google Patents
Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiquesInfo
- Publication number
- EP1334167A1 EP1334167A1 EP01993659A EP01993659A EP1334167A1 EP 1334167 A1 EP1334167 A1 EP 1334167A1 EP 01993659 A EP01993659 A EP 01993659A EP 01993659 A EP01993659 A EP 01993659A EP 1334167 A1 EP1334167 A1 EP 1334167A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- compounds
- chosen
- ammonia
- catalyst
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Definitions
- the present invention relates to a process for hydrotreating a mixture of hydrocarbon compounds comprising from four to eight carbon atoms, rich in olefins and in monoaromatic compounds. It relates more particularly to the hydrotreatment of cuts resulting from the distillation of crude oils, steam cracking, catalytic reforming, catalytic cracking, coking or any process producing such cuts and the cuts resulting from the treatment of coal such as gasolines of coal.
- the refiner is confronted with a double constraint, linked on the one hand to the injection of the liquid into a high pressure gas flow (technological constraints of design of the charge pump and design of safety systems to avoid in particular the return of hydrogen in the event of the pump stopping) and on the other hand to its dispersion by means of an appropriate diffuser taking into account the pressures used in the process.
- the present application therefore relates to a process which requires neither pretreatment of the catalyst, nor of introduction of gaseous or liquid nitrogen compounds in the hydrogenation gas. It relates to a simple process which can be easily implemented whatever the hydrotreatment unit, without requiring investments in too expensive material, with an inexpensive catalyst compared to catalysts containing noble metals such as platinum and palladium, which can adapt to fillers whose composition can vary in concentration of olefins and monoaromatic compounds and which allows good desulfurization of the charge.
- olefins is meant here the monoolefinic and diolefinic compounds generally present in the feeds sent for hydrotreatment.
- the present invention therefore relates to a process for hydrotreating a mixture of hydrocarbon compounds from C4 to C8, rich in olefins and in monoaromatic compounds, by hydrogenation in the presence of a solid catalyst characterized in that a precursor is introduced ammonia in the feed of hydrocarbon compounds and that the catalyst comprises at least one transition metal supported on at least one refractory oxide.
- transition metal is understood to mean any transition metal with the exception of the so-called noble metals, in particular platinum and palladium.
- One of the advantages of the process is linked to the introduction of an ammonia precursor into the feed which makes it possible during the reaction to release gaseous ammonia which is present during the selective hydrogenation reaction of the olefins and which can be recovered and recycled with unused hydrogen.
- this process makes it possible to precisely control the quantity of ammonia released during the hydrotreatment reaction.
- it makes it possible to limit the undesired oligomerization reactions while maintaining excellent catalyst activity for the desired reactions of selective hydrogenation of olefins and desulfurization of the feed.
- the Applicant has found that on the one hand, the oligomerization of aromatic compounds results from the presence of acid sites on the catalyst, these sites being of variable acid forces.
- the efficiency of the hydrotreatment reaction depends on the electrodeficiency of the catalytic support which itself is correlated with its acidity.
- At most 1000 ppm by weight of molar nitrogen equivalent of ammonia precursor is injected into the feed.
- 5 to 1000 ppm by weight of nitrogen molar equivalent of nitrogen precursor will be injected, and preferably from 10 to 200 ppm.
- the ammonia precursors are chosen from nitrogen compounds capable of releasing gaseous ammonia under the conditions of the hydrotreatment. These ammonia precursors must decompose before their arrival on the catalyst so as to release the ammonia as close as possible to the catalyst and for this to have a decomposition temperature lower than the reaction temperature in the reactor.
- the decomposition temperature of the ammonia precursors is less than 300 ° C, and preferably less than 180 ° C.
- the ammonia precursor is chosen from linear and branched amines, polyamines, imines, and urea and its derivatives.
- the amines and polyamines are chosen from the group consisting of mono, di and trialkylamines comprising from 1 to 10 carbon atoms per alkyl group, the alkyl groups being linear or cyclic, and the polyalkylamines comprising from 1 to 5 nitrogen atoms , each alkyl group comprising from 1 to 6 carbon atoms in linear or branched form.
- the preferred amines and polyamines are chosen from methylamine, ethylamine, propylamine, butylamine, pentylamine, hexylamine, heptylamine, cyclohexylamine, cycloheptylamine, dimethylamine, diethylamine, dipropylamine, dibutylamine, trimethylamine, triethylamine, tripropylamine, tributylamine, methylenediamine, ethylenediamine, propylenediamine, butylenediamine, dimethylenetriamine, diethylenetriamine, dipropylenetriamine, triethylenetetramine, tripropylenetetramine, tetraethylenepentamine and tetrapropylenepentamine, cyclohexylamine, triethylamine and ethylenediamine being preferred.
- the catalyst necessary for the process according to the invention consists of at least one metal chosen from the group consisting of nickel, cobalt, molybdenum, vanadium and tungsten; nickel alone and the nickel / molybdenum, cobalt / molybdenum and nickel / tungsten combinations are preferred.
- This or these metals are supported on at least one refractory oxide chosen from alumina, silica, silicoalumines, aluminophosphates, zirconia, magnesia and oxides of titanium, rutile and anatase, these oxides being in amorphous form or crystalline.
- the operation is carried out at a temperature between 50 and 400 ° C., under a pressure between 10 6 Pa and 10 7 Pa, preferably between 3 ⁇ 10 6 Pa and 6 ⁇ 10 6 Pa, and a hvv varying from 0.5 to 10h "1 .
- the excess ammonia gas formed can be recycled into the hydrogen-rich recycle gas. This has the advantage of limiting the quantity of ammonia precursor injected into the feed.
- This hydrotreatment process is particularly suitable for the hydrotreatment of petroleum C6 refining cuts, in particular C 6 cuts from reforming and catalytic gasolines from catalytic cracking.
- the present example describes the conditions under which the invention is carried out by presenting the gain brought by the introduction of ammonia precursor in an industrial feed to be hydrotreated, and this for different ammonia precursors and for different concentrations thereof.
- the feed to be hydrotreated is a mixture at 21% by weight of a C6 reforming cut and 79% by weight of a C6 cut of pyrolysis gasoline. It contains :
- the benzene content was measured in application of the UOP 744-86 method referenced in the "Laboratory test methods for petroleum and its products", published by UOP Process Division, (UOP Inc. 20 UOP Plaza- Algonquin Mt Prospect Roads-Des Plains-Illinois 60016).
- the olefin content is determined by measuring the number of bromine in application of standard ASTM D1159, and the sulfur content by method ASTM D2622.
- ammonia precursors were used on a hydrotreatment pilot unit for 100 ml of catalyst, at a temperature of 200 ° C., a pressure of 26.5 ⁇ 10 5 Pa, operating with an H2 / hydrocarbon ratio of 230NI / I, hvv of the charge being 1.6h "1 .
- the present example aims to emphasize the efficiency of the process whatever the relative concentrations of the load of olefins and of monoaromatic compounds.
- cyclohexylamine or CHA is used as the ammonia precursor.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01993659A EP1334167B1 (fr) | 2000-11-07 | 2001-11-06 | Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiques |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00203887A EP1205531A1 (fr) | 2000-11-07 | 2000-11-07 | Procédé d'hydrotraitement d'un mélange de composés hydrocarbones, riche en oléfines et en composés aromatiques |
EP00203887 | 2000-11-07 | ||
PCT/EP2001/012989 WO2002038701A1 (fr) | 2000-11-07 | 2001-11-06 | Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiques |
EP01993659A EP1334167B1 (fr) | 2000-11-07 | 2001-11-06 | Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiques |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1334167A1 true EP1334167A1 (fr) | 2003-08-13 |
EP1334167B1 EP1334167B1 (fr) | 2011-05-18 |
Family
ID=8172230
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00203887A Withdrawn EP1205531A1 (fr) | 2000-11-07 | 2000-11-07 | Procédé d'hydrotraitement d'un mélange de composés hydrocarbones, riche en oléfines et en composés aromatiques |
EP01993659A Expired - Lifetime EP1334167B1 (fr) | 2000-11-07 | 2001-11-06 | Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiques |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00203887A Withdrawn EP1205531A1 (fr) | 2000-11-07 | 2000-11-07 | Procédé d'hydrotraitement d'un mélange de composés hydrocarbones, riche en oléfines et en composés aromatiques |
Country Status (8)
Country | Link |
---|---|
US (1) | US7399402B2 (fr) |
EP (2) | EP1205531A1 (fr) |
JP (1) | JP4900885B2 (fr) |
KR (1) | KR100591577B1 (fr) |
AT (1) | ATE509997T1 (fr) |
AU (1) | AU2002219087A1 (fr) |
ES (1) | ES2363494T3 (fr) |
WO (1) | WO2002038701A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10150556A1 (de) * | 2001-10-15 | 2003-04-17 | Basf Ag | Verfahren zur katalytischen Hydrierung |
FR2918066B1 (fr) | 2007-06-26 | 2010-11-19 | Total France | Liant concentre non gelifiable et pompable pour bitume/polymere |
FR2929616B1 (fr) * | 2008-04-08 | 2011-09-09 | Total France | Procede de reticulation de compositions bitume/polymere presentant des emissions reduites d'hydrogene sulfure |
CN103068772B (zh) * | 2010-06-23 | 2016-04-06 | 道达尔研究技术弗吕公司 | 醇在受抑制的酸性催化剂上的脱水 |
EP3164466A1 (fr) * | 2014-07-01 | 2017-05-10 | Anellotech, Inc. | Procédés pour la conversion de biomasse en btx à faible teneur en soufre, en azote et en oléfines par l'intermédiaire d'un procédé de pyrolyse catalytique rapide |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE639951A (fr) * | 1962-11-16 | |||
US3859204A (en) * | 1974-01-22 | 1975-01-07 | Gulf Research Development Co | Residual oil hydrodesulfurization process by catalyst pretreatment and ammonia addition |
IT1038403B (it) * | 1975-05-23 | 1979-11-20 | Snam Progetti | Procedimento di idrogenazione selettiva in fase gassosa di composti plurinsaturi |
CA1091700A (fr) | 1976-12-28 | 1980-12-16 | John F. Van De Castle | No translation available |
-
2000
- 2000-11-07 EP EP00203887A patent/EP1205531A1/fr not_active Withdrawn
-
2001
- 2001-11-06 AU AU2002219087A patent/AU2002219087A1/en not_active Abandoned
- 2001-11-06 JP JP2002542022A patent/JP4900885B2/ja not_active Expired - Fee Related
- 2001-11-06 WO PCT/EP2001/012989 patent/WO2002038701A1/fr active IP Right Grant
- 2001-11-06 ES ES01993659T patent/ES2363494T3/es not_active Expired - Lifetime
- 2001-11-06 AT AT01993659T patent/ATE509997T1/de not_active IP Right Cessation
- 2001-11-06 EP EP01993659A patent/EP1334167B1/fr not_active Expired - Lifetime
- 2001-11-06 US US10/416,058 patent/US7399402B2/en not_active Expired - Fee Related
- 2001-11-06 KR KR1020037006246A patent/KR100591577B1/ko not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO0238701A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP4900885B2 (ja) | 2012-03-21 |
EP1334167B1 (fr) | 2011-05-18 |
EP1205531A1 (fr) | 2002-05-15 |
WO2002038701A1 (fr) | 2002-05-16 |
US20040045873A1 (en) | 2004-03-11 |
KR20030066654A (ko) | 2003-08-09 |
US7399402B2 (en) | 2008-07-15 |
KR100591577B1 (ko) | 2006-06-20 |
AU2002219087A1 (en) | 2002-05-21 |
JP2004518775A (ja) | 2004-06-24 |
ES2363494T3 (es) | 2011-08-05 |
ATE509997T1 (de) | 2011-06-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2380397C2 (ru) | Способ переработки тяжелого сырья, такого как тяжелые сырые нефти и кубовые остатки | |
JP5991562B2 (ja) | 原油全体を脱アスファルトおよび脱硫するための統合された方法 | |
CA2175437C (fr) | Procede de transformation de petrole brut lourd et de residus de distillation en distillats | |
EP0343045B1 (fr) | Composition catalytique comprenant un sulfure métallique en suspension dans un liquide contenant des asphaltènes et procédé d'hydroviscoreduction d'une charge d'hydrocarbures | |
CA3008093A1 (fr) | Procede integre d'hydrocraquage deux etapes et d'un procede d'hydrotraitement | |
WO2016102302A1 (fr) | Procede et dispositif pour la reduction des composes aromatiques polycycliques lourds dans les unites d'hydrocraquage | |
FR2500469A1 (fr) | Processus de craquage avec solvant donneur d'hydrogene et procede de traitement de petrole brut | |
US20150344790A1 (en) | Pyrolysis Tar Upgrading Process | |
CN107075392B (zh) | 与真空蒸馏和溶剂脱沥青整合以减少重多环芳香族积累的加氢裂解方法 | |
WO1996037577A1 (fr) | Carbureacteur et procede de preparation de ce carbureacteur | |
JP2017509778A (ja) | 水素化処理ユニットのための供給原料の調製方法 | |
EP1334167B1 (fr) | Procede d'hydrotraitement d'un melange de composes hydrocarbones, riche en olefines et en composes aromatiques | |
US11162039B1 (en) | Systems and processes integrating hydroprocessing and an aromatics recovery complex for separating and upgrading hydrocarbons | |
WO2021069330A1 (fr) | Procede de production d'olefines comprenant un desasphaltage, une hydroconversion, un hydrocraquage et un vapocraquage | |
EP2886629A1 (fr) | Procédé d'hydrodesulfuration de coupes d'hydrocarbures | |
WO2020144095A1 (fr) | Procede d' hydrocraquage en deux etapes pour la production de naphta comprenant une etape d'hydrogenation mise en œuvre en aval de la deuxieme etape d'hydrocraquage | |
FR2933711A1 (fr) | Procede de conversion comprenant une viscoreduction de residu, puis un desasphaltage et une hydroconversion | |
FR2933709A1 (fr) | Procede de conversion comprenant une hydroconversion d'une charge, un fractionnement, puis un desasphatage de la fraction residu sous vide | |
EP3237577A1 (fr) | Procede et dispositif de reduction des composes aromatiques polycycliques lourds dans les unites d'hydrocraquage | |
US20240218269A1 (en) | Processes and systems for producing desulfurized alpha olefins | |
FR2933708A1 (fr) | Procede de conversion comprenant une hydroconversion de la charge puis une viscoreduction et un fractionnement | |
EP3237576A1 (fr) | Procede et dispositif de reduction des composes aromatiques polycycliques lourds dans les unites d'hydrocraquage | |
Nurmamatovich | HYDROGENATION PROCESSES IN THE PROCESSING OF OIL AND OIL PRODUCTS IN INDUSTRY | |
CN117821112A (zh) | 一种提高脱硫选择性的渣油加氢处理方法 | |
FR3097229A1 (fr) | Procede de production d’olefines comprenant un hydrotraitement, un desasphaltage, un hydrocraquage et un vapocraquage |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20030428 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO SI |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: TOTAL PETROCHEMICALS RESEARCH FELUY |
|
17Q | First examination report despatched |
Effective date: 20050503 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: T3 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 60144659 Country of ref document: DE Effective date: 20110630 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2363494 Country of ref document: ES Kind code of ref document: T3 Effective date: 20110805 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110919 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110819 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20120221 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 60144659 Country of ref document: DE Effective date: 20120221 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111130 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111130 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111130 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20121130 Year of fee payment: 12 Ref country code: DE Payment date: 20121121 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20121122 Year of fee payment: 12 Ref country code: IT Payment date: 20121126 Year of fee payment: 12 Ref country code: ES Payment date: 20121127 Year of fee payment: 12 Ref country code: GB Payment date: 20121120 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20121120 Year of fee payment: 12 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111106 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110518 |
|
BERE | Be: lapsed |
Owner name: TOTAL PETROCHEMICALS RESEARCH FELUY Effective date: 20131130 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20140601 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20131106 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20140731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140601 Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131106 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140603 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 60144659 Country of ref document: DE Effective date: 20140603 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131106 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131202 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20150407 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20131107 |