EP1297027A1 - Activateurs de cocatalyeurs substitues par un groupe siloxy pour polymerisation des olefines - Google Patents

Activateurs de cocatalyeurs substitues par un groupe siloxy pour polymerisation des olefines

Info

Publication number
EP1297027A1
EP1297027A1 EP01948483A EP01948483A EP1297027A1 EP 1297027 A1 EP1297027 A1 EP 1297027A1 EP 01948483 A EP01948483 A EP 01948483A EP 01948483 A EP01948483 A EP 01948483A EP 1297027 A1 EP1297027 A1 EP 1297027A1
Authority
EP
European Patent Office
Prior art keywords
tri
siloxy
isopropyl
perfluorophenyl
dimethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP01948483A
Other languages
German (de)
English (en)
Inventor
George Rodriguez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/602,289 external-priority patent/US6346636B1/en
Priority claimed from US09/599,909 external-priority patent/US6541410B1/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP1297027A1 publication Critical patent/EP1297027A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

L'invention concerne des compositions ioniques comprenant des cations [Ct]+ chargés positivement et des anions [A]- chargés négativement comprenant un élément de noyau central du groupe 13 auquel des ligands fluoroaryle sont liés, au moins l'un de ces ligands étant substitué par un groupe siloxy représenté par les symboles SiOR¿3?, R représentant un substituant hydrocarbyle ou hydrocarbylsilyle en C1-C30. [Ct]?+ ¿ représente tout cation pouvant être utilisé avec des catalyseurs de polymérisation des oléfines, et sélectionné dans le groupe généralement constitué par des cations d'anilinium et d'ammonium, des cations de trityl carbenium, des cations métalliques du groupe 11, des cations de silylium, les cations des sels hydratés des métaux du groupe 1 ou 2, et des dérivés des cations précités d'anilinium, d'ammonium, de trityl carbenium, et de silylium contenant des substituants d'hydrocarbyle, d'hydrocarbylsilyel, ou d'hydrocarbylamine en C¿1?-C20 pour au moins un atome d'hydrogène desdits cations. Les compositions ioniques décrites peuvent être utilisées pour activer des catalyseurs de polymérisation d'oléfines, et peuvent être préparées de façon à être solubles dans des solvants aliphatiques. L'invention concerne également des synthèses et une polymérisation.
EP01948483A 2000-06-23 2001-06-19 Activateurs de cocatalyeurs substitues par un groupe siloxy pour polymerisation des olefines Ceased EP1297027A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US09/602,289 US6346636B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
US599909 2000-06-23
US602289 2000-06-23
US09/599,909 US6541410B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
PCT/US2001/019585 WO2002000738A1 (fr) 2000-06-23 2001-06-19 Activateurs de cocatalyeurs substitues par un groupe siloxy pour polymerisation des olefines

Publications (1)

Publication Number Publication Date
EP1297027A1 true EP1297027A1 (fr) 2003-04-02

Family

ID=27083479

Family Applications (2)

Application Number Title Priority Date Filing Date
EP01946460.1A Expired - Lifetime EP1296991B1 (fr) 2000-06-23 2001-06-18 Activateurs de cocatalyste a substitution siloxy pour la polymerisation de l'olefine
EP01948483A Ceased EP1297027A1 (fr) 2000-06-23 2001-06-19 Activateurs de cocatalyeurs substitues par un groupe siloxy pour polymerisation des olefines

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP01946460.1A Expired - Lifetime EP1296991B1 (fr) 2000-06-23 2001-06-18 Activateurs de cocatalyste a substitution siloxy pour la polymerisation de l'olefine

Country Status (8)

Country Link
EP (2) EP1296991B1 (fr)
JP (2) JP2004501926A (fr)
KR (2) KR20030019447A (fr)
CN (2) CN1227255C (fr)
BR (2) BR0111515A (fr)
CA (2) CA2412606A1 (fr)
MX (2) MXPA02012672A (fr)
WO (2) WO2002000666A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2353307A1 (fr) 2001-07-13 2003-01-13 Carmen Parent Appareil et procede pour le traitement des effluents gazeux
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
CA2405635A1 (fr) 2002-09-27 2004-03-27 C02 Solution Inc. Methode et usine de production de produits carbonates utiles et de recyclage des emissions de dioxyde de carbone produites par des centrales electriques
WO2009057600A1 (fr) 2007-11-01 2009-05-07 Adeka Corporation Composé de type sel, initiateur de polymérisation cationique et composition cationiquement polymérisable
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system
KR102111927B1 (ko) * 2014-02-13 2020-05-18 미쓰이 가가쿠 가부시키가이샤 에틸렌/α-올레핀 공중합체의 제조 방법
JP2022527465A (ja) * 2019-03-28 2022-06-02 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合触媒活性化剤のための弱配位性アニオンとしてのアニオン性ｉｉｉ族錯体

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Publication number Priority date Publication date Assignee Title
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
FR2679564A1 (fr) 1991-07-23 1993-01-29 Inst Nat Sante Rech Med Nouveaux acylmercaptoalcanoldipeptides, leur preparation et les compositions qui les contiennent.
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5635573A (en) 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
US5502017A (en) * 1994-03-10 1996-03-26 Northwestern University Metallocene catalyst containing bulky organic group
EP0698825A1 (fr) 1994-07-29 1996-02-28 AT&T Corp. Résiste sensible à l'énergie et procédé pour fabriquer un objet en utilisant ce résiste
KR100420432B1 (ko) * 1995-03-10 2004-07-23 다우 글로벌 테크놀로지스 인크. 지지된촉매및이를이용한중합방법
CN1202909A (zh) * 1995-11-27 1998-12-23 陶氏化学公司 含有束缚阳离子生成活化剂的负载型催化剂
US5856256A (en) 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5763556A (en) 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
US5895771A (en) 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
WO1999030822A1 (fr) 1997-12-16 1999-06-24 Exxon Research And Engineering Company Catalyseurs d'amine de metal de transition du groupe 11 pour polymerisation olefinique
ATE243700T1 (de) 1998-02-20 2003-07-15 Dow Global Technologies Inc Expandierte anionen enthaltende katalysatoraktivatoren
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Non-Patent Citations (1)

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See references of WO0200738A1 *

Also Published As

Publication number Publication date
KR20030019447A (ko) 2003-03-06
CN1437618A (zh) 2003-08-20
BR0111487A (pt) 2003-03-25
EP1296991B1 (fr) 2013-05-15
JP2004501989A (ja) 2004-01-22
WO2002000738A1 (fr) 2002-01-03
WO2002000666A1 (fr) 2002-01-03
CN1227255C (zh) 2005-11-16
JP2004501926A (ja) 2004-01-22
CN1437607A (zh) 2003-08-20
CA2412606A1 (fr) 2002-01-03
CA2412608A1 (fr) 2002-01-03
KR20030011363A (ko) 2003-02-07
MXPA02012673A (es) 2003-10-14
CN1178960C (zh) 2004-12-08
BR0111515A (pt) 2003-05-06
EP1296991A1 (fr) 2003-04-02
MXPA02012672A (es) 2004-04-21

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