EP1296751A1 - Procede et dispositif pour la conversion catalytique d'une matiere - Google Patents

Procede et dispositif pour la conversion catalytique d'une matiere

Info

Publication number
EP1296751A1
EP1296751A1 EP01940226A EP01940226A EP1296751A1 EP 1296751 A1 EP1296751 A1 EP 1296751A1 EP 01940226 A EP01940226 A EP 01940226A EP 01940226 A EP01940226 A EP 01940226A EP 1296751 A1 EP1296751 A1 EP 1296751A1
Authority
EP
European Patent Office
Prior art keywords
substance
active material
catalytically active
fuel
gas stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01940226A
Other languages
German (de)
English (en)
Inventor
Erich Hums
Horst Spielmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of EP1296751A1 publication Critical patent/EP1296751A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/90—Injecting reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1208—Inorganic compounds elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/01—Adding substances to exhaust gases the substance being catalytic material in liquid form
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Definitions

  • the invention is in the field of catalysts.
  • the invention relates to a method for converting a substance in a gas stream, in particular for the catalytic conversion of nitrogen oxide into one mixed with ammonia
  • the invention also relates to a method for reactivating an at least partially deactivated catalyst module which has been produced by depositing a catalytically active material in or on a catalyst substrate, in particular for reactivating a catalyst module which works on the principle of selective catalytic reduction for the reduction of nitrogen oxide in a flue gas.
  • the invention also relates to a fuel for combustion in a combustion process.
  • the invention relates to an exhaust gas purification system of the first type, in particular for a combustion system of a power plant or for an internal combustion engine of a motor vehicle, in which an exhaust gas stream resulting from the combustion is passed through a catalytic converter module to convert a pollutant contained therein by separating a the catalytic conversion of the pollutant-promoting catalytically active material is produced on or in a catalyst substrate, it being possible in particular to convert nitrogen oxide contained in the exhaust gas stream according to the principle of selective catalytic reduction.
  • the invention also relates to an exhaust gas purification system of the second type, in particular for a combustion system of a power plant or an internal combustion engine of a motor vehicle, in which an exhaust gas stream resulting from the combustion of a fuel for converting a pollutant contained therein is passed through a catalyst module which is separated by separating the catalytic conversion of the pollutant-demanding catalytically active material is produced on or in a catalyst substrate, wherein in particular nitrogen oxide contained in the exhaust gas stream can be converted according to the principle of selective catalytic reduction.
  • the oxidic combustion of fossil fuels creates substances or pollutants in the exhaust gas or flue gas that pollute the environment.
  • nitrogen oxides for example NO or NO 2
  • An exhaust gas or fluid flow of a comparable type also arises when diesel fuel or other fuels are burned in the internal combustion engines of motor vehicles.
  • SCR selective catalytic reduction
  • nitrogen oxides are converted catalytically into harmless nitrogen and water vapor by adding ammonia.
  • the flue gas or exhaust gas is passed through a catalytic converter or through a catalytic converter module at a temperature between 300 and 500 ° C.
  • the catalyst module consists of a ceramic matrix or a ceramic catalyst substrate, on which a catalytically active material is deposited, which effects or promotes the conversion of the nitrogen oxides into nitrogen and water vapor.
  • a catalytically active material are, for example, the oxides of titanium, vanadium and / or tungsten and / or molybdenum.
  • SCR catalysts deactivate in the course of their operation, depending on the smoke gas constituents.
  • the reasons for the deactivation are e.g. chemically justified, i.e. that the catalytically active material forms compounds that cannot participate in the SCR process.
  • the catalytically active material is transported out of the catalytic converter module by the exhaust gas stream flowing through during operation. This occurs in particular if the catalytically active material enters into volatile metal-halogen compounds with halogens contained in the exhaust gas.
  • the invention is therefore based on the object of specifying a method, a device and a substance for this purpose.
  • a catalyst module is not necessarily required when performing this method.
  • the catalytic conversion of the pollutant in the exhaust gas can take place solely through such catalytically active material that is fed to the reaction space in the form of the substance.
  • This catalytically active material can be fed continuously or batchwise.
  • the gas stream is passed through a catalyst substra, in particular arranged in the reaction space, or past one.
  • the substance is preferably added to the gas stream in the flow direction upstream of the catalyst substrate.
  • the substance is highly dispersed or atomized when added to the gas stream.
  • the substance is preferably or is admixed with a fuel, the combustion of which produces the substance contained in the gas stream as exhaust gas.
  • a catalytically active material which promotes the catalytic conversion of the substance is incorporated or deposited to form a catalyst module with particular advantage in or on the catalyst substrate.
  • the catalyst module was thus produced, for example, by separating the catalytically active material in a separate manufacturing process before carrying out the method according to the invention.
  • the catalytically active material which is supplied with the gas stream or is formed from the substance is the same as the catalytically active material which was incorporated or deposited in the manufacture of the catalyst module. This regenerates the catalytic converter module in a particularly efficient manner.
  • the catalytic material added to or formed in the gas stream itself has a catalytic effect, so that an increase in the catalytic efficiency would be possible even if the catalyst module were not regenerated.
  • the catalytically active material added upstream of the catalyst module or the catalytically active material formed from the substance has the property of being deposited on the catalyst module.
  • a catalyst module is likewise formed with particular advantage by incorporating or depositing the catalytically active material of the gas stream in or on the catalyst substrate.
  • the catalyst module then gradually forms by separating or storing the catalytically active material formed from or contained in the substance.
  • the catalyst module is produced in particular in the following steps: a) The gas stream is mixed with a substance which is or contains catalytically active material or from which catalytically active material can be separated. b) The gas stream is then passed through or over a catalyst substrate. c) The catalyst module is formed by depositing or embedding the catalytically active material on or in the catalyst substrate.
  • the process-related object is achieved in relation to the method mentioned at the outset according to the invention in that the catalyst module is wetted with a substance which is or contains catalytically active material or from which catalytically active material can be separated.
  • catalytic material is again applied or introduced into or onto the catalyst substrate of the catalyst module.
  • the catalytically active material of the substance is stored and / or deposited in or on the catalytically active material which is present due to the production.
  • the catalytically active material of the substance is particularly advantageously the same as the catalytically active material that was deposited or deposited during the manufacture of the catalyst module.
  • the substance is fed to the catalyst module during catalyst operation.
  • Such online operation has the particular advantage that the catalyst module does not have to be taken out of operation for the regeneration and therefore there is no need to interrupt the catalytically influenced process.
  • the substance is preferably mixed with a substance which is fed to the catalyst module to promote the conversion of the substance. It is therefore advantageously not necessary to have a separate material flow to the catalyst module, since the substance is admixed with the substance that is supplied to the catalyst module anyway in accordance with the operation.
  • the substance is preferably in the vaporized or gaseous state.
  • the substance is or is mixed with a fuel, the combustion of which produces a substance as exhaust gas, which is fed to the catalyst module to promote the conversion of the substance.
  • the catalytically active material preferably contains atoms of one of the elements vanadium, titanium, tungsten, iron and / or molybdenum, and the catalytically active material is in particular an oxide of one of these metals. Mixtures of the elements mentioned are also possible.
  • the related to a material object is .jpg of the invention characterized by '' a fuel for combustion in a combustion process, which contains a substance or a substance is added, the catalytically active material or is selected from the catalytically active material in the combustion arises.
  • the fuel thus contains, in particular, catalytically active material or catalytically active material is added to it.
  • Such a fuel is particularly suitable for carrying out the method according to the invention, in particular for those configurations in which a fuel is explicitly used.
  • the advantages mentioned in this connection apply analogously to the fuel.
  • the substance content in the fuel preferably has a value between 10 mg / kg of fuel and 200 mg / kg of fuel.
  • the catalytic material content of the fuel has a value between 50 mg / kg fuel and 100 mg / kg fuel.
  • the substance, and in particular the catalytically active material is preferably contained in the fuel in dissolved or dispersed form or is added to it in soluble or dispersing form.
  • the catalytically active material is preferably suitable for promoting the conversion of the pollutant formed during the combustion.
  • the catalytically active material has the property of converting nitrogen oxide according to the principle of selective catalytic reduction, which is contained in the exhaust gas produced during the combustion.
  • the catalytically active material contains at least one of the elements vanadium, titanium, tungsten, iron, molybdenum, or mixtures thereof.
  • the device-related object is achieved in relation to the exhaust gas purification system of the first type mentioned at the outset according to the invention by an injection device with which a substance can be fed into the exhaust gas in the flow direction upstream of the catalyst module, the substance being or containing catalytically active material or from the substance being catalytically active Material is separable.
  • the injection device preferably has a storage container for holding the substance.
  • the device-related object is achieved in relation to the exhaust gas cleaning system of the second type mentioned at the outset according to the invention by means of a feed device by means of which a substance can be added to the fuel, the substance being or containing or containing catalytically active material or being able to be separated from the substance.
  • the exhaust gas cleaning systems of both types are particularly suitable for carrying out the first-mentioned method according to the invention.
  • the advantages mentioned in connection with this apply analogously to these emission control systems.
  • the feed device preferably has a storage container for holding the substance.
  • FIG. 1 shows a first exemplary embodiment of an exhaust gas cleaning system according to the invention
  • FIG. 3 shows a third exemplary embodiment relating to a method according to the invention
  • FIG. 6 shows a sixth exemplary embodiment relating to an apparatus and a method according to the invention
  • FIG. 1 shows a line 1 in which a reaction space 2 is formed.
  • a catalyst device comprising three catalyst modules 3 is arranged in the reaction space 2.
  • a fluid or gas A which is an exhaust gas or flue gas, flows through the catalyst modules 3 in the flow direction 5.
  • the exhaust gas A contains a substance or pollutant, namely nitrogen oxide NO (NO x ).
  • NO x nitrogen oxide NO
  • SCR selective catalytic reduction
  • ammonia NH (NH 3 ) reducing agent is added to the gas A with the pollutant NO by means of a first feed line 7 opening into the line 1.
  • the exhaust gas A originates, for example, from the combustion system of a power plant operated with gas, oil or coal.
  • the catalyst modules 3 contain K as a catalytically active material, vanadium, molybdenum, tungsten and / or titanium, in particular in oxidic form. In the preferred temperature range of 300 ° C to 450 ° C, the catalytically active materials K used for the SCR process work highly selectively, so that undesirable side reactions are largely prevented.
  • the catalyst modules 3 can partially or completely deactivate after prolonged operation.
  • new or fresh catalytically active material KU is fed to the exhaust gas A in the flow direction 5 upstream of the catalyst modules 3 by means of an injection device 8.
  • the injection device 8 can also be used to supply a substance S from which the catalytically active material KU is formed, for example only in the exhaust gas stream A.
  • the added or forming catalytically active material KU is the same or has a similar composition to the catalytically active material K that is already present in the catalyst modules 3 or was originally present.
  • the injection device 8 has a storage container 11 for holding the substance S or the catalytically active material KU.
  • a second feed line 9 opens into the line 1 carrying the exhaust gas A.
  • the second feed line 9 is configured at its mouth in such a way that the substance S or the catalytically active material KU disperses or enters the line 1 is atomized.
  • the second exemplary embodiment of a method according to the invention shown in FIG. 2 differs from the first exemplary embodiment essentially in that the
  • Substance S or the fresh catalytically active material KU is mixed with a fuel B, from which voltage in a combustion chamber 15, the exhaust gas A only arises.
  • the fuel B to which the substance S or the catalytically active material KU is added in dissolved or dispersed form, is conveyed into the combustion chamber 15 by means of a fuel line 17.
  • a pump 19 is provided to deliver the fuel B from a tank 21.
  • the fuel B contains the substance S or the catalytically active material KU with a proportion between 10 mg / kg fuel and 200 mg / kg fuel.
  • the fuel B is burned in the combustion chamber 15, producing nitrogen oxide-containing exhaust gas A.
  • the new catalytically active material KU also forms from the substance S in the combustion chamber 15.
  • the exhaust gas A with the nitrogen oxide NO and the new catalytically active material KU comes out of the combustion chamber 15 through the line 1 to the catalyst modules 3 in the reaction space 2.
  • the first feed line is used, as in the first exemplary embodiment 7 ammonia NH mixed.
  • the catalyst modules 3 are regenerated by the combustion of the fuel B mixed with substance S or catalytically active material KU for a longer period of time.
  • catalytic material KU was added to the fuel B of a refinery power plant as a mixture of vanadium V and iron Fe. 102 mg vanadium and 252 mg Eis.en per kg fuel B were added. During the combustion of fuel B, an exhaust gas flow with a volume flow iN moist of 150,000 m 3 / h was generated. The vanadium content in exhaust gas A or flue gas was 316 ppm. A damp smoke density of 1.31 kg / m 3 was used as a basis. The operating temperature of the catalyst modules 3 was 370 ° C.
  • the vanadium content V205 in the catalyst modules 3 is plotted in percent on the left ordinate.
  • the time t in hours (h) is plotted on the abscissa.
  • the diagram shows that the vanadium content V205 had risen to about 1.3%.
  • the nitrogen oxide-specific catalytic activity K-NOx of the catalyst modules 3 rose from initially approximately 41.5 m / h to approximately 48.5 m / h after 6000 operating hours (right ordinate).
  • FIG. 8 the oxidation rate K-SOx for the oxidation reaction from S0 2 to S0 3 is plotted on the right ordinate. During the 6000-hour observation phase, this increased from initially 200 m / h to approx. 550 m / h.
  • the third exemplary embodiment shown in FIG. 3 differs from the second exemplary embodiment shown in FIG. 2 in that the substance S or the fresh catalytically active material KU is not already mixed into the fuel B in the tank 21, but is only mixed into the fuel B from a separate container 25 after it has been conveyed out of the tank 21.
  • the substance S or the catalytically active material KU is fed from the container 25 to the fuel line 17 by means of a feed line 27, so that the fuel B mixed with the substance S or the fresh catalytically active material KU - as in the exemplary embodiment of Figure 2 - gets into the combustion chamber 15.
  • This variant of supplying fuel to the combustion chamber 15 can also be implemented in the exemplary embodiment in FIG. 2.
  • the container 25 and the feed line 27 form a feed device 28.
  • the exemplary embodiment in FIG. 3 also differs from the exemplary embodiment in FIG. 2 in that no catalyst modules 3 are present.
  • the catalytic conversion of the nitrogen oxides NO produced during the combustion in the exhaust gas stream A is done in this embodiment by the action al ⁇ lein of the fuel admixed B ka ⁇ catalytically active material KU on the nitrogen oxides NO, in particular in the reaction space. 2
  • the fourth exemplary embodiment of a method according to the invention shown in FIG. 4 serves to reactivate an at least partially deactivated catalyst module 3.
  • the reactivation takes place ex-situ in the example shown, i.e. in a state in which the catalyst modules 3 are not used for the catalytic conversion of the substance NO.
  • the deactivated catalyst modules 3 are arranged in this Reakti ⁇ onsraum 2 and are wetted with a substance S, the new or fresh catalytically active material KU is or contains or can be separated from such a catalytically active material KU.
  • an initially inert catalyst substrate 33 is assumed.
  • This catalyst substrate 33 is acted upon by a gas stream or exhaust gas stream A which arises, for example, when a fuel is burned.
  • the gas flow A is either in a manner analogous to FIGS. 2 or 3 (in FIG.
  • a substance S is added which is or contains catalytically active material K or from which catalytically active material K can be formed.
  • a catalyst module 3 is thus produced by introducing the inert catalyst substrate 33 into the line 1 through which the exhaust gas A flows.
  • the exhaust gas purification system 41 shown in FIG. 6 as the sixth exemplary embodiment comprises, like the third exemplary embodiment shown in FIG. 3, a feed device 28. In contrast to FIG. 3, however, in FIG. 3,
  • catalyst modules 3 are present in the reaction chamber 2, which have been produced by depositing or depositing a catalytically active material K in or on a catalyst substrate 31.
  • the catalyst modules 3 are therefore regenerated by means of the new or fresh catalytically active material KU added by the feed device 28, or by means of the substance S, “in situ” or “online”.
  • a downstream of the capacitor modules 3 in the flow direction 5 is a separating device 49, in which catalytic converter 3 which is not required for regeneration of the catalyst modules effective material KU, that is, 'which is still contained in the exhaust gas stream A after the catalyst modules 3, is separated.
  • a return line 51 leads from the separating device 49 - possibly via a concentrating device (not shown) - to the feed device 28. In this way, catalytically active material KU that is fed in but not required can be used again for feeding into the fuel B. As a result, the costs for catalytically active material KU are considerably reduced.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé pour convertir une matière dans un flux gazeux (A). Ce procédé consiste à acheminer ce dernier (A) à une zone de réaction (2) et à soumettre la matière (NO) à l'action d'un matériau catalytique (K, KU). Une substance (S), constituée d'un matériau catalytique (K; KU) ou permettant d'obtenir ce dernier, est acheminée avec le flux gazeux (A) à la zone de réaction (2). De préférence, cette substance (S) est mélangée à un combustible (B) au cours de la combustion duquel la matière (NO) contenue dans le flux gazeux (A) est produite sous forme de gaz de combustion. Selon un procédé de réactivation d'un module catalyseur (3) désactivé, ce dernier est imprégné d'une substance (S) constituée d'un matériau catalytique frais (K; KU) ou contenant ce dernier ou bien à partir de laquelle ce dernier peut être séparé. Les deux procédés peuvent être mis en oeuvre notamment selon le principe de la réduction catalytique sélective pour décomposer de l'oxyde d'azote (NO) dans un gaz de combustion (A). L'invention concerne également un combustible (B) qui contient une substance (S) constituée d'un matériau catalytique (K; KU) ou permettant d'obtenir ce dernier lors de la combustion.
EP01940226A 2000-05-10 2001-05-10 Procede et dispositif pour la conversion catalytique d'une matiere Withdrawn EP1296751A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10022763 2000-05-10
DE10022763A DE10022763A1 (de) 2000-05-10 2000-05-10 Verfahren und Vorrichtung zur katalytischen Umwandlung eines Stoffs
PCT/DE2001/001782 WO2001085311A1 (fr) 2000-05-10 2001-05-10 Procede et dispositif pour la conversion catalytique d'une matiere

Publications (1)

Publication Number Publication Date
EP1296751A1 true EP1296751A1 (fr) 2003-04-02

Family

ID=7641443

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01940226A Withdrawn EP1296751A1 (fr) 2000-05-10 2001-05-10 Procede et dispositif pour la conversion catalytique d'une matiere

Country Status (6)

Country Link
EP (1) EP1296751A1 (fr)
KR (1) KR20030015236A (fr)
CN (1) CN1240467C (fr)
DE (1) DE10022763A1 (fr)
TW (1) TW561144B (fr)
WO (1) WO2001085311A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2623100T3 (es) * 2005-07-08 2017-07-10 Phyre Technologies, Inc. Sistema de reducción catalítica de componente reactivo y métodos para el uso del mismo
US7538059B2 (en) * 2006-01-31 2009-05-26 Rohm And Haas Company Regeneration of mixed metal oxide catalysts
US7707824B2 (en) * 2007-04-10 2010-05-04 Gm Global Technology Operations, Inc. Excess NH3 storage control for SCR catalysts
US8048818B2 (en) * 2008-03-26 2011-11-01 Babcock & Wilcox Power Generation Group, Inc. In-situ regeneration of a catalyst masked by calcium sulfate
DE102008046381B4 (de) * 2008-09-09 2011-12-22 Man Truck & Bus Ag Verfahren zur Verminderung von Stickoxiden im Abgasstrom von Brennkraftmaschinen
FR3043570B1 (fr) * 2015-11-13 2020-08-07 Ifp Energies Now Fluide pour la depollution des moteurs thermiques et modes de preparation desdits fluides par emulsification

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3168368A (en) * 1960-04-27 1965-02-02 Air Prod & Chem Method of treating exhaust gases of internal combustion engines
US5322671A (en) * 1992-02-25 1994-06-21 Blue Planet Technologies Co., L.P. Catalytic vessel
US5308810A (en) * 1992-12-28 1994-05-03 Atlantic Richfield Company Method for treating contaminated catalyst
US5519149A (en) * 1994-10-28 1996-05-21 E. I. Du Pont De Nemours And Company Vapor phase catalytic oxidation of N-butane to maleic anhydride incorporating in situ catalyst calcination/activation
DE19507219C1 (de) * 1995-03-02 1996-05-15 Daimler Benz Ag Verfahren und Vorrichtung zum Nachbeschichten einer deaktivierten Katalysatorbeschichtung bei einem Katalysator
AU2253597A (en) * 1996-01-31 1997-08-22 Clean Diesel Technologies, Inc. Method and apparatus for reducing harmful emissions from a diesel engine by post combustion catalyst injection
DE19800873C2 (de) * 1998-01-13 2000-03-02 Erc Emissions Reduzierungs Con Katalysatorlösung und deren Verwendung sowie Verfahren zur Reduzierung der Emission von Schadstoffen bei Verbrennungen und thermischen Prozessen
GB2333048B (en) * 1998-01-13 2002-03-20 Hugh F Collins A rejuvenating and/or cleaning agent
US6395665B2 (en) * 1998-07-24 2002-05-28 Mitsubishi Heavy Industries, Ltd. Methods for the regeneration of a denitration catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0185311A1 *

Also Published As

Publication number Publication date
KR20030015236A (ko) 2003-02-20
WO2001085311A1 (fr) 2001-11-15
TW561144B (en) 2003-11-11
DE10022763A1 (de) 2001-11-22
CN1429129A (zh) 2003-07-09
CN1240467C (zh) 2006-02-08

Similar Documents

Publication Publication Date Title
EP1395351B1 (fr) Installation d'epuration des gaz d'echappement dotee d'un dispositif d'alimentation en agent de reduction
DE60111040T2 (de) Plasmaunterstützte gasbehandlung
DE69902446T2 (de) Verbesserungen der schadstoffregelung
EP0988104A1 (fr) Procede et dispositif pour eliminer des polluants de type oxyde dans un gaz d'echappement contenant de l'oxygene et moteur fonctionnant de fa on correspondante
EP2568137B1 (fr) Système d'injection chauffé pour systèmes de gaz d'échappement de moteurs diesel
EP2428659A1 (fr) Catalyseur destiné à supprimer les oxydes d'azote contenus dans les gaz d'échappement de moteurs diesel
EP1961933A1 (fr) Filtre à particule de diesel activé de manière catalytique et doté d'une action de blocage à l'ammoniac
WO1999056858A2 (fr) Procede et dispositif pour la reduction catalytique des oxydes d'azote
DE10054877A1 (de) Abgasreinigungsanlage für die selektive katalytische Reduktion von Stickoxiden unter mageren Abgasbedingungen und Verfahren zur Abgasreinigung
DE10308288A1 (de) Verfahren zur Entfernung von Stickoxiden aus dem Abgas eines mager betriebenen Verbrennungsmotors und Abgasreinigungsanlage hierzu
EP2112339A1 (fr) Procédé et dispositif de nettoyage de gaz d'échappement d'un moteur à combustion interne
EP0791390A1 (fr) Procédé et dispositif pour la purification de gaz
DE60019169T2 (de) Verfahren, katalysatorsystem und vorrichtung zur behandlung von schwefelhaltigem gas
EP2118460B1 (fr) Procédé et dispositif de production d'ammoniac pour le traitement des gaz d'échappement de moteurs à combustion interne dans un véhicule automobile
DE102011012799A1 (de) Katalysator zur Entfernung von Stickoxiden aus dem Abgas von Dieselmotoren
EP2408541A1 (fr) Traitement combiné de courants d'effluent gazeux contenant de l'ammoniac et des oxydes d'azote dans des installations industrielles
DE3229314C2 (fr)
EP1296751A1 (fr) Procede et dispositif pour la conversion catalytique d'une matiere
WO2007014650A1 (fr) Procede pour reduire les emissions d'oxyde d'azote et de particules d'un moteur a combustion interne et unite correspondante pour retraiter les gaz d'echappement
DE10242303A1 (de) Abgasreinigungsanlage und Verfahren zur Reinigung von Absagen
EP1702147A1 (fr) Procede permettant de faire fonctionner un filtre a particules dans la voie d'echappement du moteur a combustion interne d'un vehicule a moteur
DE3412870A1 (de) Verfahren und vorrichtung zur entfernung unerwuenschter gasfoermiger bestanteile aus rauchgasen
WO2002092195A1 (fr) Procede de traitement de gaz de fumee contenant de l'ammoniac
WO2003016688A1 (fr) Systeme catalytique, son utilisation et son mode de fonctionnement
DE20122446U1 (de) Vorrichtung zur katalytischen Umwandlung eines Stoffs

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20021021

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

17Q First examination report despatched

Effective date: 20030919

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20050617