EP1294350A1 - Alcohol-free base for aqueous perfume composition, and alcohol-free aqueous perfume composition comprising same - Google Patents

Alcohol-free base for aqueous perfume composition, and alcohol-free aqueous perfume composition comprising same

Info

Publication number
EP1294350A1
EP1294350A1 EP01947602A EP01947602A EP1294350A1 EP 1294350 A1 EP1294350 A1 EP 1294350A1 EP 01947602 A EP01947602 A EP 01947602A EP 01947602 A EP01947602 A EP 01947602A EP 1294350 A1 EP1294350 A1 EP 1294350A1
Authority
EP
European Patent Office
Prior art keywords
base
alcohol
ethoxylated
isoprene glycol
perfume composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01947602A
Other languages
German (de)
French (fr)
Inventor
Martine Dumanois
Nathalie Gueyne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Laboratoire Bf International (sarl)
Original Assignee
Laboratoire Bf International (sarl)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laboratoire Bf International (sarl) filed Critical Laboratoire Bf International (sarl)
Publication of EP1294350A1 publication Critical patent/EP1294350A1/en
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00Formulations or additives for perfume preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin

Definitions

  • the subject of the present invention is a base for a perfumed aqueous cosmetic composition, without alcohol, non-greasy and non-sticky, such as a perfume, an eau de toilette, a perfumed gel or a deodorant water; it also relates to such a composition comprising such a base.
  • aqueous cosmetic compositions without alcohol and whose appearance can range from that of milk to that of a limpid and transparent liquid, generally comprise the following components: a mixture of natural essential oils and / or synthetic insoluble in water, - one or more cationic surfactants, one or more anionic surfactants, a mixture thereof or one or more nonionic surfactants; these surfactants generally present in high doses are intended, depending on their content, to emulsify or dissolve the mixture of essential oils,
  • solubilizing agent which is both lipophilic and hydrophilic, very generally of the polyethylene glycol type
  • An aqueous dispersant generally water
  • one or more preservatives such as ethyl p-hydroxybenzoate (Nipagine R ) and propyl p-hydroxybenzoate (Nipasol R ).
  • the object of the present invention is to eliminate the above-mentioned drawbacks.
  • the Applicant has therefore sought a means of reducing the dose of surfactants which are at the origin in particular of the sticky and irritant nature of known cosmetic compositions. It has now demonstrated that the aim sought could be achieved by using, instead of known solubilizers, a specific solvent, isoprene glycol.
  • the present invention thus relates to a new base for an aqueous cosmetic composition, perfumed, alcohol-free, non-greasy and non-sticky, comprising an aqueous medium, one or more non-ionic surfactants and a solvent, this base being characterized in that said solvent is isoprene glycol.
  • the latter which is both hydrophilic and lipophilic and also called 3-methyl 1, 3-butanediol, makes it possible, thanks to its solvent and solubilizing power, to very substantially reduce the amount of surfactants to be used. works to achieve a stable base and composition.
  • This solvent also has very essential characteristics for obtaining a base suitable for use in cosmetics.
  • the surfactant (s) of the abovementioned base are preferably chosen from ethoxylated fatty acid alcohols such as ethoxylated oleyl alcohol (for example ethoxylated oleyl alcohol containing 10 moles of ethylene oxide, manufactured by the American company AMERCHOL and marketed in France under the brand AMEROXOL R ), ethoxylated hydrogenated castor oil (for example hydrogenated castor oil with 40 moles of ethylene oxide, marketed by the company BASF under the brand CREMOPHOR R ) and their mixtures.
  • ethoxylated fatty acid alcohols such as ethoxylated oleyl alcohol (for example ethoxylated oleyl alcohol containing 10 moles of ethylene oxide, manufactured by the American company AMERCHOL and marketed in France under the brand AMEROXOL R ), ethoxylated hydrogenated castor oil (for example hydrogenated castor oil with 40 moles of ethylene oxide, marketed by the company BASF
  • the base according to the invention will preferably comprise a preservative such as NIPAGIN R for example.
  • the base comprises isoprene glycol in an amount of about 5 to 30% by weight, AMEROXOL R in an amount of about 0.5 to 5.0% by weight, CREM0PHOR R in an amount of about 0.5 to 5.0% by weight, the remainder being essentially purified water.
  • the present invention further relates to a perfumed aqueous cosmetic composition
  • a perfumed aqueous cosmetic composition comprising a base as defined above and one or more aromatic substances such as natural and / or synthetic essential oils.
  • said perfumed composition comprises the following components:
  • the bases and composition according to the invention can for example be prepared by the following process.
  • the preservative (s) (for example NIPAG INE R ) is dissolved in isoprene glycol and to the solution thus obtained, the aqueous medium (purified water) is added to obtain a first phase.
  • the surfactants are warmed up to melt them, the aromatic substances are added to it and homogenized to obtain a second phase. Finally, the first phase is slowly added with stirring to this second phase.
  • Example 1 eau de perfume
  • This water has the following weight composition:

Abstract

The invention concerns an alcohol-free, non-greasy and non-sticky base for an aqueous perfume composition, comprising an aqueous medium, one or several non-ionic surfactants and a solvent, said base being characterised in that said solvent is isoprene glycol. The invention also concerns said cosmetic composition comprising said base and one or several fragrant substances.

Description

Base pour composition cosmétique aqueuse parfumée, sans alcool, et composition cosmétique aqueuse parfumée, sans alcool, comprenant une telle baseBase for an aqueous perfumed cosmetic composition, without alcohol, and aqueous perfumed cosmetic composition, without alcohol, comprising such a base
La présente invention a pour objet une base pour composition cosmétique aqueuse parfumée, sans alcool, non grasse et non collante, telle qu'un parfum, une eau de toilette, un gel parfumé ou une eau déodorante ; elle a également pour objet une telle composition comprenant une telle base.The subject of the present invention is a base for a perfumed aqueous cosmetic composition, without alcohol, non-greasy and non-sticky, such as a perfume, an eau de toilette, a perfumed gel or a deodorant water; it also relates to such a composition comprising such a base.
A ce jour, les compositions cosmétiques aqueuses, sans alcool et dont l'aspect peut aller de celui du lait à celui d'un liquide limpide et transparent, comprennent généralement les composants suivants : un mélange d'huiles essentielles naturelles et/ou synthétiques insolubles dans l'eau, - un ou plusieurs tensio-actifs cationiques, un ou plusieurs tensio-actifs anioniques, un mélange de ceux-ci ou encore un ou plusieurs tensio-actifs non ioniques ; ces tensio-actifs généralement présents à fortes doses sont destinés, suivant leur teneur, à émulsionner ou à dissoudre le mélange d'huiles essentielles,To date, aqueous cosmetic compositions, without alcohol and whose appearance can range from that of milk to that of a limpid and transparent liquid, generally comprise the following components: a mixture of natural essential oils and / or synthetic insoluble in water, - one or more cationic surfactants, one or more anionic surfactants, a mixture thereof or one or more nonionic surfactants; these surfactants generally present in high doses are intended, depending on their content, to emulsify or dissolve the mixture of essential oils,
- un agent solubilisant à la fois lipophile et hydrophile, très généralement du type polyéthylène glycol,a solubilizing agent which is both lipophilic and hydrophilic, very generally of the polyethylene glycol type,
- un dispersant aqueux (généralement de l'eau), et un ou plusieurs conservateurs tels que le p-hydroxybenzoate d' éthyle (NipagineR) et le p-hydroxybenzoate de propyle (NipasolR) .- An aqueous dispersant (generally water), and one or more preservatives such as ethyl p-hydroxybenzoate (Nipagine R ) and propyl p-hydroxybenzoate (Nipasol R ).
Ces compositions connues présentent cependant les inconvénients suivants :These known compositions however have the following drawbacks:
- elles ne sont pas toujours translucides, - elles sont collantes en raison de la nature collante des tensio-actifs et de la quantité relativement élevée de tensio- actifs mis en oeuvre, le parfum exhalé par les huiles essentielles est susceptible d'être dénaturé par le solubilisant, - elles sont quelque peu irritantes en raison du caractère irritant du solubilisant et agressif des tensio-actifs, et les huiles essentielles sont susceptibles d'être dégradées par oxydation par l'air, ce qui affecte la stabilité des compositions et le rendu olfactif de ces dernières . Le but de la présente invention est de supprimer les inconvénients susmentionnés. La demanderesse a de ce fait recherché le moyen de diminuer la dose de tensio-actifs qui sont à l'origine notamment de la nature collante et irritante des compositions cosmétiques connues. Elle a maintenant mis en évidence que le but recherché pouvait être atteint en mettant en oeuvre à la place des solubilisants connus, un solvant spécifique, l'isoprène glycol.- they are not always translucent, - they are sticky due to the sticky nature of the surfactants and the relatively high amount of surfactants used, the perfume exhaled by the essential oils is likely to be denatured by the solubilizer, - they are somewhat irritating due to the irritant nature of the solubilizer and the aggressive surfactants, and essential oils are liable to be degraded by oxidation by air, which affects the stability of the compositions and the olfactory rendering of the latter. The object of the present invention is to eliminate the above-mentioned drawbacks. The Applicant has therefore sought a means of reducing the dose of surfactants which are at the origin in particular of the sticky and irritant nature of known cosmetic compositions. It has now demonstrated that the aim sought could be achieved by using, instead of known solubilizers, a specific solvent, isoprene glycol.
La présente invention a ainsi pour objet une nouvelle base pour composition cosmétique aqueuse parfumée, sans alcool, non grasse et non collante, comprenant un milieu aqueux, un ou plusieurs tensio-actifs non ioniques et un solvant, cette base étant caractérisée en ce que ledit solvant est l'isoprène glycol. Ce dernier, qui est à la fois hydrophile et lipophile et encore dénommé 3-méthyl 1, 3-butanediol, permet en effet, grâce à son pouvoir solvant et solubilisant, de réduire de manière très substantielle la quantité de tensio-actifs à mettre en oeuvre pour parvenir à une base et composition stables. Ce solvant présente en outre des caractéristiques tout à fait essentielles pour l'obtention d'une base convenant à une utilisation en cosmétique. En effet, il permet de réaliser des bases translucides ; de plus, il ne dénature pas la ou les substances aromatiques destinées à être incorporées dans ladite base pour obtenir une composition parfumée et il n'est ni collant, ni irritant, ni sensible à l'oxydation par l'air. On notera que le ou les tensio-actifs de la base susvisée sont de préférence choisis parmi les alcools d'acides gras éthoxylés tels que l'alcool oléylique éthoxylé (par exemple l'alcool oléylique éthoxylé à 10 moles d'oxyde éthylène, fabriqué par la société américaine AMERCHOL et commercialisé en France sous la marque AMEROXOLR) , l'huile de ricin hydrogénée éthoxylée (par exemple l'huile de ricin hydrogénée à 40 moles d'oxyde d' éthylène, commercialisée par la société BASF sous la marque CREMOPHORR) et leurs mélanges.The present invention thus relates to a new base for an aqueous cosmetic composition, perfumed, alcohol-free, non-greasy and non-sticky, comprising an aqueous medium, one or more non-ionic surfactants and a solvent, this base being characterized in that said solvent is isoprene glycol. The latter, which is both hydrophilic and lipophilic and also called 3-methyl 1, 3-butanediol, makes it possible, thanks to its solvent and solubilizing power, to very substantially reduce the amount of surfactants to be used. works to achieve a stable base and composition. This solvent also has very essential characteristics for obtaining a base suitable for use in cosmetics. Indeed, it allows for translucent bases; moreover, it does not denature the aromatic substance or substances intended to be incorporated into said base in order to obtain a perfumed composition and it is neither sticky, nor irritating, nor sensitive to oxidation by air. It will be noted that the surfactant (s) of the abovementioned base are preferably chosen from ethoxylated fatty acid alcohols such as ethoxylated oleyl alcohol (for example ethoxylated oleyl alcohol containing 10 moles of ethylene oxide, manufactured by the American company AMERCHOL and marketed in France under the brand AMEROXOL R ), ethoxylated hydrogenated castor oil (for example hydrogenated castor oil with 40 moles of ethylene oxide, marketed by the company BASF under the brand CREMOPHOR R ) and their mixtures.
On ajoutera que la base selon l'invention comprendra de préférence un conservateur tel que la NIPAGINER par exemple.It will be added that the base according to the invention will preferably comprise a preservative such as NIPAGIN R for example.
Avantageusement, la base comprend de l'isoprène glycol à raison d'environ 5 à 30 % en poids, de l' AMEROXOLR à raison d'environ 0,5 à 5,0 % en poids, du CREM0PHORR à raison d'environ 0,5 à 5,0 % en poids, le reste étant essentiellement de l'eau purifiée.Advantageously, the base comprises isoprene glycol in an amount of about 5 to 30% by weight, AMEROXOL R in an amount of about 0.5 to 5.0% by weight, CREM0PHOR R in an amount of about 0.5 to 5.0% by weight, the remainder being essentially purified water.
La présente invention a par ailleurs pour objet une composition cosmétique aqueuse parfumée comprenant une base telle que définie ci-dessus et une ou plusieurs substances aromatiques telles que des huiles essentielles naturelles et/ou synthétiques.The present invention further relates to a perfumed aqueous cosmetic composition comprising a base as defined above and one or more aromatic substances such as natural and / or synthetic essential oils.
Cette composition comprendra avantageusement environ 1-10 % en poids de telles substances aromatiques. Selon un mode de réalisation préféré, ladite composition parfumée comprend les composants suivants :This composition will advantageously comprise approximately 1-10% by weight of such aromatic substances. According to a preferred embodiment, said perfumed composition comprises the following components:
- huiles essentielles 1, 0-6, 0 g- essential oils 1, 0-6, 0 g
- isoprène glycol 5, 0-20, 0 g- isoprene glycol 5.0-20-20.0g
- CREMOPHORR 0 , 5-3 , 5 g - A EROXOLR 0,5-3,5 g- CREMOPHOR R 0, 5-3, 5 g - A EROXOL R 0.5-3.5 g
- NIPAGINER 0,1-0,2 g- NIPAGINE R 0.1-0.2 g
- eau purifiée q.s.p 100,0 g Les base et composition selon l'invention peuvent par exemple être préparées par le procédé suivant.- purified water qs 100.0 g The bases and composition according to the invention can for example be prepared by the following process.
On solubilise le ou les conservateurs (par exemple NIPAG INER) dans l'isoprène glycol et à la solution ainsi obtenue, on ajoute le milieu aqueux (eau purifiée) pour obtenir une première phase.The preservative (s) (for example NIPAG INE R ) is dissolved in isoprene glycol and to the solution thus obtained, the aqueous medium (purified water) is added to obtain a first phase.
Séparément, on tiédit les tensio-actifs pour les faire fondre, on y ajoute les substances aromatiques et on homogénéise pour obtenir une deuxième phase. Enfin, on ajoute lentement et sous agitation la première phase à cette deuxième phase.Separately, the surfactants are warmed up to melt them, the aromatic substances are added to it and homogenized to obtain a second phase. Finally, the first phase is slowly added with stirring to this second phase.
On donnera ci-après, à titre illustratif et non limitatif, deux exemples de composition cosmétique aqueuse préférée selon l'invention. Exemple 1 : eau de parfumTwo examples of preferred aqueous cosmetic composition according to the invention will be given below, by way of non-limiting illustration. Example 1: eau de parfum
Cette eau a la composition pondérale suivante :This water has the following weight composition:
- huiles essentielles 5,0 g- essential oils 5.0 g
- isoprène glycol 15, 0 g- isoprene glycol 15, 0 g
- CREMOPHORR 2,5 g - AMEROXOLR 2,5 g- CREMOPHOR R 2.5 g - AMEROXOL R 2.5 g
- NIPAGINER 0, 15 g- NIPAGIN R 0.15 g
- eau purifiée q.s.p 100,0 g- purified water q.s.p 100,0 g
Exemple 2 : eau de toiletteExample 2: eau de toilette
- huiles essentielles 1,0 g - isoprène glycol 5,0 g- essential oils 1.0 g - isoprene glycol 5.0 g
- CREMOPHORR 1,0 g- CREMOPHOR R 1.0 g
- AMEROXOLR 0,5 g- AMEROXOL R 0.5 g
- NIPAGINER 0, 15 g- NIPAGIN R 0.15 g
- eau purifiée q.s.p 100,0 g - purified water q.s.p 100,0 g

Claims

REVENDICATIONS
1. Base pour composition cosmétique aqueuse parfumée, sans alcool, non grasse et non collante, comprenant un milieu aqueux, un ou plusieurs tensio-actifs non ioniques et un solvant, cette base étant caractérisée en ce que ledit solvant est l'isoprène glycol.1. Base for perfumed aqueous cosmetic composition, alcohol-free, non-greasy and non-sticky, comprising an aqueous medium, one or more non-ionic surfactants and a solvent, this base being characterized in that said solvent is isoprene glycol.
2. Base selon la revendication 1, caractérisée en ce que le ou les tensio-actifs sont choisis parmi les alcools d'acides gras éthoxylés, l'huile de ricin hydrogénée éthoxylée et leurs mélanges.2. Base according to claim 1, characterized in that the surfactant (s) are chosen from ethoxylated fatty acid alcohols, ethoxylated hydrogenated castor oil and mixtures thereof.
3. Base selon la revendication 2, caractérisée en ce que le ou les tensio-actifs sont choisis parmi l'alcool oléylique éthoxylé à 10 moles d'oxyde d' éthylène, l'huile de ricin hydrogénée éthoxylée à 40 moles d'oxyde d' éthylène et leurs mélanges.3. Base according to claim 2, characterized in that the surfactant (s) are chosen from oleyl alcohol ethoxylated with 10 moles of ethylene oxide, hydrogenated castor oil ethoxylated with 40 moles of oxide d ethylene and mixtures thereof.
4. Base selon la revendication 3, caractérisée en ce qu'elle comprend 5 à 30 % en poids d' isoprène glycol, 0,5 à 5,0 % en poids d'alcool oléylique éthoxylé à 10 moles d'oxyde d' éthylène, 0,5 à 5,0 % en poids d'huile de ricin hydrogénée éthoxylée à 40 moles d'oxyde d' éthylène.4. Base according to claim 3, characterized in that it comprises 5 to 30% by weight of isoprene glycol, 0.5 to 5.0% by weight of oleyl alcohol ethoxylated to 10 moles of ethylene oxide , 0.5 to 5.0% by weight of hydrogenated castor oil ethoxylated with 40 moles of ethylene oxide.
5. Composition cosmétique aqueuse parfumée, non grasse et non collante, caractérisée en ce qu'elle comprend une base selon l'une des revendications ci-dessus et une ou plusieurs substances aromatiques. β. Composition selon la revendication 5, caractérisée en ce que lesdites substances aromatiques sont des huiles essentielles naturelles et/ou synthétiques.5. A non-greasy, non-sticky perfumed aqueous cosmetic composition, characterized in that it comprises a base according to one of the above claims and one or more aromatic substances. β. Composition according to Claim 5, characterized in that the said aromatic substances are natural and / or synthetic essential oils.
7. Composition selon la revendication 5 ou 6, caractérisée en ce qu'elle comprend 1 à 10 % en poids de substances aromatiques.7. Composition according to claim 5 or 6, characterized in that it comprises 1 to 10% by weight of aromatic substances.
8. Composition selon la revendication 5, 6 ou 7, caractérisée en ce qu'elle comprend les composants suivants : - huiles essentielles 1, 0-6, 0 g8. Composition according to claim 5, 6 or 7, characterized in that it comprises the following components: - essential oils 1, 0-6, 0 g
- isoprène glycol 5, 0-20, 0 g- isoprene glycol 5.0-20-20.0g
- CREMOPHORR 0, 5-3, 5 g- CREMOPHOR R 0, 5-3, 5 g
- AMEROXOLR 0,5-3, 5 g - NIPAGINER 0,1-0,2 g- AMEROXOL R 0.5-3.5 g - NIPAGIN R 0.1-0.2 g
- eau purifiée q.s.p 100,0 g- purified water q.s.p 100,0 g
9. Composition selon la revendication 8, caractérisée en ce qu'elle comprend les composants suivants :9. Composition according to claim 8, characterized in that it comprises the following components:
- huiles essentielles 5,0 g - isoprène glycol 15, 0 g- essential oils 5.0 g - isoprene glycol 15.0 g
- CREMOPHORR 2,5 g- CREMOPHOR R 2.5 g
- AMEROXOLR 2,5 g- AMEROXOL R 2.5 g
- NIPAGINER 0, 15 g- NIPAGIN R 0.15 g
- eau purifiée q.s.p 100,0 g 10. Composition selon la revendication 8, caractérisée en ce qu'elle comprend les composants suivants :- purified water q.s.p 100,0 g 10. Composition according to claim 8, characterized in that it comprises the following components:
- huiles essentielles 1,0 g- essential oils 1.0 g
- isoprène glycol 5,0 g- isoprene glycol 5.0 g
- CREMOPHORR 1,0 g - AMEROXOLR 0,5 g- CREMOPHOR R 1.0 g - AMEROXOL R 0.5 g
- NIPAGINER 0, 15 g- NIPAGIN R 0.15 g
- eau purifiée q.s.p 100,0 g - purified water q.s.p 100,0 g
EP01947602A 2000-06-30 2001-06-29 Alcohol-free base for aqueous perfume composition, and alcohol-free aqueous perfume composition comprising same Withdrawn EP1294350A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0008465A FR2810884B1 (en) 2000-06-30 2000-06-30 BASE FOR AQUEOUS SCENTED COMPOSITION, WITHOUT ALCOHOL, AND AQUEOUS COSMETIC COMPOSITION, WITHOUT ALCOHOL, COMPRISING SUCH A BASE
FR0008465 2000-06-30
PCT/FR2001/001994 WO2002000184A1 (en) 2000-06-30 2001-06-29 Alcohol-free base for aqueous perfume composition, and alcohol-free aqueous perfume composition comprising same

Publications (1)

Publication Number Publication Date
EP1294350A1 true EP1294350A1 (en) 2003-03-26

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EP01947602A Withdrawn EP1294350A1 (en) 2000-06-30 2001-06-29 Alcohol-free base for aqueous perfume composition, and alcohol-free aqueous perfume composition comprising same

Country Status (5)

Country Link
US (1) US20030186836A1 (en)
EP (1) EP1294350A1 (en)
AU (1) AU2001269252A1 (en)
FR (1) FR2810884B1 (en)
WO (1) WO2002000184A1 (en)

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CN1964691B (en) 2004-06-08 2010-12-22 陶氏环球技术公司 Ethanol-free aqueous perfume composition
BE1018403A3 (en) * 2007-06-29 2010-10-05 Debetencourt Jean Jacques Alcohol-free perfume mist effect osmosis.
US9125807B2 (en) * 2007-07-09 2015-09-08 Incept Llc Adhesive hydrogels for ophthalmic drug delivery
EP2316408B1 (en) 2010-10-25 2013-07-03 Symrise AG Ethanol-free perfume oil microemulsion
US8513180B2 (en) 2010-10-25 2013-08-20 Symrise Ag Ethanol-free perfume oil microemulsion
GB201122235D0 (en) 2011-12-23 2012-02-01 Givaudan Sa Composition
DE102012010206A1 (en) * 2012-05-15 2013-11-21 Koray Kaynak Non-alcoholic 'colognes' substitute product
WO2014187950A1 (en) * 2013-05-23 2014-11-27 Givaudan Sa Composition
US10980717B2 (en) 2019-02-05 2021-04-20 Elc Management Llc Aqueous perfume compositions
EP3937885A4 (en) 2019-03-15 2022-05-11 ELC Management LLC Long wear skincare compositions
US11129788B1 (en) 2020-03-24 2021-09-28 Elc Management Llc Sprayable film forming compositions for improving the performance of topical preparations

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US5468725A (en) * 1993-07-01 1995-11-21 International Flvos & Fragrances Inc. Alcohol free perfume
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Also Published As

Publication number Publication date
US20030186836A1 (en) 2003-10-02
AU2001269252A1 (en) 2002-01-08
FR2810884A1 (en) 2002-01-04
FR2810884B1 (en) 2002-10-11
WO2002000184A1 (en) 2002-01-03

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