EP1281681A1 - Tempered glass and laminated glass employing it - Google Patents

Tempered glass and laminated glass employing it Download PDF

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Publication number
EP1281681A1
EP1281681A1 EP02015638A EP02015638A EP1281681A1 EP 1281681 A1 EP1281681 A1 EP 1281681A1 EP 02015638 A EP02015638 A EP 02015638A EP 02015638 A EP02015638 A EP 02015638A EP 1281681 A1 EP1281681 A1 EP 1281681A1
Authority
EP
European Patent Office
Prior art keywords
glass
thickness
glass sheet
stress layer
compressive stress
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP02015638A
Other languages
German (de)
English (en)
French (fr)
Inventor
Shigeyuki Asahi Glass Fine Techno Co. Ltd Seto
Takaharu Asahi Glass Company Limited Imamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Publication of EP1281681A1 publication Critical patent/EP1281681A1/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00—Tempering or quenching glass products
    • C03B27/04—Tempering or quenching glass products using gas
    • C03B27/044—Tempering or quenching glass products using gas for flat or bent glass sheets being in a horizontal position
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00—Tempering or quenching glass products
    • C03B27/04—Tempering or quenching glass products using gas
    • C03B27/0417—Controlling or regulating for flat or bent glass sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00—Tempering or quenching glass products
    • C03B27/04—Tempering or quenching glass products using gas
    • C03B27/0413—Stresses, e.g. patterns, values or formulae for flat or bent glass sheets
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material

Definitions

  • the present invention relates to a tempered glass and a laminated glass employing it.
  • a tempered glass is commonly used.
  • the tempered glass is produced by tempering a heated glass sheet by air-quenching, and has a compressive stress layer at the surface and a tensile stress layer inside.
  • the tempered glass is provided with strength sufficient to bear a tensile force exerted to the surface of the glass sheet.
  • the tempered glass has not only such a characteristic that it has such high strength, but also a characteristic that it becomes grainy fragments in the event of fracture, whereby it is less likely to injure a human body. Namely, if a crack having a depth reaching the tensile stress layer, enters in the compressive stress layer at the surface, the balance of stresses in both stress layers collapses, and countless cracks spread in all directions, and thus fragments of the glass sheet become grainy, whereby sharp fragments are not likely to be formed.
  • a tempered glass is used for windows of automobiles.
  • the thickness of the glass sheet is reduced for weight reduction of the glass sheet, the following problems may occur.
  • a tempered glass is a product produced by quenching a heated glass sheet to form a temperature difference between the surface and inside, and by this temperature difference, a compressive stress layer is formed at the surface, and a tensile stress layer is formed inside. Therefore, the thinner the thickness of the glass sheet, the less likely the formation of such a temperature difference, and the thinner the thickness of the compressive stress layer formed at the surface of the glass sheet. As a result, even a very small crack is likely to reach the tensile stress layer inside the glass sheet, whereby the glass sheet is likely to fracture.
  • the thickness of the compressive stress layer formed in the area slightly closer to the center of the glass sheet from the end surface needs to be thinner than the thickness of the compressive stress layer formed in the central region of the glass sheet, and as a result, the glass sheet is likely to fracture by a very small crack.
  • the present invention provides a tempered glass having a compressive stress layer formed at the surface and a tensile stress layer formed inside, wherein the glass thickness (t) is from 1.5 to 3.5 mm, and the minimum thickness (a) of the compressive stress layer in the direction of glass thickness is from 0.15 to 0.7 mm.
  • the present invention provides a laminated glass employing such a tempered glass.
  • the portion of a window glass sheet exposed to the external world is in an environment where it has frictions with other objects by many external factors.
  • a window glass sheet for an automobile exposed to the outside of the automobile is in an environment where it is likely to have frictions with many objects including a brush for car washing.
  • a glass sheet for a sliding window among windows of automobiles has a friction at its peripheral portion with a sash by opening or closing the window.
  • a scratch may be formed on the surface of the glass sheet. Though the scratch is a very small flaw, if the flaw grows through the compressive stress layer and reaches the tensile stress layer, the glass sheet will be fractured.
  • the thickness of the glass sheet of the present invention is from 1.5 to 3.5 mm. In the case of a glass sheet having a thickness exceeding 3.5 mm, it is possible to obtain a compressive stress layer having a certain degree of thickness against the thickness of the sheet by a normal thermally tempering method. On the other hand, as the thickness of the sheet is made thin, the thickness of the compressive stress layer tends to be thin.
  • the depth of a flaw formed on the surface of a glass sheet by a friction with other objects in a normal operation environment is less than 0.15 mm. Therefore, for a glass sheet having a thickness of from 1.5 to 3.5 mm, it is effective to make the minimum thickness of the compressive stress layer to be at least 0.15 mm.
  • the relations between the minimum thickness (a) of the compressive stress layer and the glass thickness (t), and between an average thickness (b) of the compressive stress layer and the glass thickness (t) satisfy 0.1 ⁇ a/t ⁇ 0.2 and 0.15 ⁇ b/t ⁇ 0.25, and the reason is as follows.
  • the tempered glass of the present invention has a minimum thickness of the compressive stress layer of from 0.15 to 0.7 mm.
  • the thickness (t) of the glass sheet is from 1.5 to 3.5 mm.
  • a laminated glass for automobile windows particularly a laminated glass for sliding windows of automobiles
  • a laminated glass for sliding windows of automobiles by employing the tempered glass of this embodiment.
  • a laminated glass comprising two glass sheets having a thickness of about 2 mm bonded one another via an interlayer.
  • the glass sheets used in this case are tempered glass having the degree of tempering adjusted to be slightly lower than that of usual tempered glass. Accordingly, their strength is lower than that of an automobile sliding window employing common tempered glass. Though the strength, particularly the strength against collision of the glass sheets themselves, lowers, the laminated glass as a whole has sufficient strength for a window for automobiles.
  • the thickness of the compressive stress layer formed at the surface of the glass sheet becomes thin.
  • the peripheral portion of the glass sheet for a sliding window for automobiles has a friction with glass-runchannel in a sash when it is guided by the sash at the time of opening/closing of the window. Accordingly, the portion having a thin compressive stress layer is placed in an environment where a scratch is likely to be formed. Therefore, in a case where a laminated glass is used for such a sliding window of an automobile, it is beneficial to employ the tempered glass of the present invention excellent in scratch resistance.
  • a process for producing glass G will be described.
  • a glass sheet cut into a desired shape is transported into a heating furnace and heated to a temperature for bending below the softening point of the glass, whereupon it is processed into a desired shape by e.g. press molding.
  • the glass sheet bent is placed on a ring-shaped holder member to support the peripheral portion of the glass sheet, and the glass sheet is cooled by a high pressure air blown from a plurality of blow nozzles facing to the glass sheet.
  • a compressive stress layer is formed at the surface of glass sheet G, and a tensile stress layer is formed inside.
  • the thickness of the compressive stress layer varies depending on the thickness of the glass sheet and the blowing pressure of the air.
  • a method disclosed in JP-A-2001-2434 may be mentioned.
  • a glass sheet is heated in a heating furnace at the temperature for bending, whereupon the glass sheet is transported on a plurality of rollers which move up and down, whereby the glass sheet is bent following a concavely curved transportation surface formed by the plurality of rollers.
  • the glass sheet bent is transported to a cooling zone by a plurality of rollers moving up and down, and cooled as it is transported, by a cooling air blown from blowing nozzles disposed between the plurality of rollers.
  • the supporting position of the glass sheet keeps changing by the transportation by the rollers, whereby there will be no possibility that cooling becomes insufficient at a particular portion of the glass sheet.
  • a laminated glass suitable for a side window glass By laminating a plurality of tempered glasses produced as described above and interlayers made of a resin such as polyvinyl butyral, a laminated glass suitable for a side window glass can be produced.
  • a known method can be used as the method for producing a laminated glass.
  • Figs 2(a) and 2(b) are diagrams illustrating an apparatus for measuring the thickness of a compressive stress layer.
  • a light source 1 such as a green laser
  • the phase difference oscillator 3 has an optical component having a wedge-shaped cross-section (hereinafter referred to as wedge 3a).
  • the prism 5 is placed on a glass plate G via a refraction liquid (a liquid having the same refractive index as that of the glass plate G).
  • the lens 4 has a shape corresponding to a half of a normal round lens shape, and can be optionally slided in a vertical direction in the Fig. (a direction indicated by a bi-directional arrow in Fig. 2(a)) in the same manner as the wedge 3a.
  • the direction of the light coming out from the lens 4 moves vertically, whereby the incident position at the prism 5 can be adjusted.
  • the light entered into the prism 5 passes through the prism 5 and enters into the glass plate G.
  • Scattered light 11 generated at that time comes out from an oblique plane of the prism 5 and picked up as an image by a CCD camera 6.
  • the image signal thereby obtained is transmitted to a control device 7, and the image signal processed by the control device 7 is displayed on a display device 8.
  • An operator (a person who operates) can control the operation of the control device 7 by operating an inputting device 9.
  • the prism 5 on the glass plate G is a triangular prism having a cross-sectional shape of isosceles triangle and is made of silica glass.
  • the CCD camera 6 is set orthogonally to the oblique plane of the prism 5, and the image picked up by the CCD camera 6 is displayed on the display device 8 by the function of the control device 7.
  • the display device 8 is a common display device such as CRT or LCD
  • the inputting device 9 is a common inputting device such as a keyboard or a mouse.
  • Fig. 3 is a plan view schematically showing scattered lights 10 and 11 displayed on the display device 8.
  • the glass sheet G and scattered light 11 passing through the glass sheet G are displayed on the display device 8, and further, a mouse pointer 8a and bar-shaped cursors 8b to 8d to be used for measuring the thickness of the compressive stress layer are also displayed.
  • Scattered light 10 enters into the glass sheet G from the point P in the Fig., and in the glass sheet G, scattered light 11 is observed as a plurality of beaded small ellipsoidal patterns.
  • Scattered light 11 reached the backside (point A) of the glass sheet G is totally reflected toward the front side of the glass sheet G.
  • the trail of reflected scattered light 11 is observed as beaded small ellipsoidal patterns in the same manner as mentioned above, and exits to the outside from the surface (point C) of the glass sheet G.
  • the operator can optionally move the mouse pointer 8a on the screen by operating the inputting device 9 in Fig. 2. Then, by moving the mouse pointer 8a to a desired position and clicking a button (not shown) of the inputting device 9, the bar-shaped cursors 8b, 8c and 8d can be placed at optional positions.
  • the cursor 8b is placed to align to point A and the cursor 8b is placed to align to point C. Further, the cursor 8c is placed to align to point E on the border of the compressive stress layer and the tensile stress layer. Point E can be discovered by an operation shown in Figs 4(a) to 4(c), which is as follows.
  • Figs 4(a) to 4(c) are diagrams schematically illustrating scattered light 11 changed by adjustment of the phase difference oscillator 3.
  • the wedge 3a of the phase difference oscillator 3 vertically (a direction indicated by a bi-directional arrow in Fig. 2(a))
  • the phase of light 10 entering into the glass sheet G is changed.
  • small ellipses in the glass sheet G move forward or backward along the trail of scattered light 11 according to the phase change.
  • Table 1 shows the results of tests on laminated glasses used as front glasses of automobiles, applying various bending methods. From (1) to (3) are ones wherein a glass sheet was cooled as being transported without a ring, and (4) and (5) are ones wherein a glass sheet is cooled as being supported by a ring at its peripheral portion, and the flow rate of cooling air to the peripheral portion is adjusted. In all cases (including car interior side and car exterior side), the relation between the glass thickness (t) and the minimum thickness (a) of the compressive stress layer in the direction of glass thickness satisfied 0.1 ⁇ a/t ⁇ 0.2, and the relation between the glass thickness (t) and the average thickness (b) of the compressive stress layer in the direction of glass thickness satisfied 0.15 ⁇ b/t ⁇ 0.25.
  • the present invention provides a tempered glass having sufficient strength and a laminated glass employing it. Further, by employing the present invention, it is possible to know the optimum thickness of the compressive stress layer when it is desired to reduce the thickness of a rear window glass or a side window glass for automobiles.
  • the present invention can be employed for a window glass not only for automobiles, but also for railroad trains, airplanes, ships or buildings.
  • infrared shielding fine particles made of a metal, oxide, nitride or sulfide of Sn, Ti, Si, Zn, Zr, Fe, Al, Cr, Co, Ce, In, Ni, Ag, Cu, Pt, Mn, Ta, W, V and/or Mo, or made of such a material doped with Sb or F, may, for example, be mentioned.
  • Those fine particles can be used alone or as a composite. Further, a mixed material of such a single material or composite with an organic resin, or a doped material of such a single material or composite doped with an organic resin, may be mentioned.
  • infrared shielding fine particles antimony-doped tin oxide (ATO) fine particles, or tindoped indium oxide (ITO) fine particles may preferably be used. Both of ATO fine particles and ITO fine particles are excellent in the infrared shielding ability. Accordingly, the amount of incorporation in an interlayer may be small.
  • ITO fine particles are superior in the infrared shielding property as compared with ATO fine particles, and it is particularly preferred to use the ITO fine particles as infrared shielding fine particles.
  • the blend ratio of infrared shielding fine particles in the interlayer to be from 0.1 to 0.5 part by mass based on 100 parts by mass of the total amount of the interlayer, a temperature rise in a car by transmission of infrared rays can be prevented, while realizing an infrared ray communication between inside and outside of the car.

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
EP02015638A 2001-07-31 2002-07-16 Tempered glass and laminated glass employing it Ceased EP1281681A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001232359 2001-07-31
JP2001232359A JP2003048734A (ja) 2001-07-31 2001-07-31 強化ガラスおよびこれを用いた合わせガラス

Publications (1)

Publication Number Publication Date
EP1281681A1 true EP1281681A1 (en) 2003-02-05

Family

ID=19064292

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02015638A Ceased EP1281681A1 (en) 2001-07-31 2002-07-16 Tempered glass and laminated glass employing it

Country Status (6)

Country Link
US (1) US20030031835A1 (ja)
EP (1) EP1281681A1 (ja)
JP (1) JP2003048734A (ja)
KR (1) KR20030013279A (ja)
CN (1) CN1400179A (ja)
MX (1) MXPA02007379A (ja)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7883777B2 (en) * 2006-03-23 2011-02-08 Garware Polyester Ltd. Solar energy shielding window film laminates
US9840431B2 (en) * 2016-01-11 2017-12-12 Corning Incorporated Methods and apparatuses for supporting forming bodies of glass forming apparatuses
EP3548277B1 (en) 2016-11-30 2023-10-25 Corning Incorporated Fusion-formable automotive glass compositions, articles, and laminates
WO2020184426A1 (ja) * 2019-03-13 2020-09-17 Ａｇｃ株式会社 ガラス板

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5525138A (en) * 1994-05-26 1996-06-11 Ford Motor Company Determination of tensile membrane stress and compressive layer thickness in tempered glass using a CO2 laser beam
JP3154645B2 (ja) * 1995-01-23 2001-04-09 セントラル硝子株式会社 自動車用合せガラス
DE69614502D1 (de) * 1995-09-29 2001-09-20 Nippon Kayaku Kk Aktinische strahlungshärtbare und wärmestrahlungsabweisende harzzusammensetzung und damit beschichteter film
JP3414205B2 (ja) * 1997-06-27 2003-06-09 日本板硝子株式会社 合わせガラス
US6686032B1 (en) * 1999-09-14 2004-02-03 Asahi Glass Company, Limited Laminated glass
WO2001044132A1 (fr) * 1999-12-17 2001-06-21 Asahi Glass Company, Limited Composition de dispersion de particules ultrafines, composition de couche de liaison intercouche pour verre feuillete, couche de liaison intercouche, et verre feuillete
DE60122077T2 (de) * 2000-09-14 2007-02-15 Asahi Glass Co., Ltd. Verbundglasscheibe
EP1215039B1 (en) * 2000-12-06 2012-06-06 Asahi Glass Company, Limited Laminated glass and glass plate used for producing laminated glass

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
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Also Published As

Publication number Publication date
US20030031835A1 (en) 2003-02-13
MXPA02007379A (es) 2005-08-26
JP2003048734A (ja) 2003-02-21
CN1400179A (zh) 2003-03-05
KR20030013279A (ko) 2003-02-14

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