EP1257371B1 - Vorrichtung zum einspritzen eines mittels an einen bestimmten ort eines sich bewegenden objektes - Google Patents

Vorrichtung zum einspritzen eines mittels an einen bestimmten ort eines sich bewegenden objektes Download PDF

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Publication number
EP1257371B1
EP1257371B1 EP01907670A EP01907670A EP1257371B1 EP 1257371 B1 EP1257371 B1 EP 1257371B1 EP 01907670 A EP01907670 A EP 01907670A EP 01907670 A EP01907670 A EP 01907670A EP 1257371 B1 EP1257371 B1 EP 1257371B1
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EP
European Patent Office
Prior art keywords
support
cam
injectors
objects
movement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01907670A
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English (en)
French (fr)
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EP1257371A1 (de
Inventor
Patrick Mie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sidel SA
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Sidel SA
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Filing date
Publication date
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Publication of EP1257371A1 publication Critical patent/EP1257371A1/de
Application granted granted Critical
Publication of EP1257371B1 publication Critical patent/EP1257371B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B3/00Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
    • B65B3/04Methods of, or means for, filling the material into the containers or receptacles
    • B65B3/10Methods of, or means for, filling the material into the containers or receptacles by application of pressure to material
    • B65B3/12Methods of, or means for, filling the material into the containers or receptacles by application of pressure to material mechanically, e.g. by pistons or pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/08Cleaning containers, e.g. tanks
    • B08B9/20Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought
    • B08B9/28Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought the apparatus cleaning by splash, spray, or jet application, with or without soaking
    • B08B9/30Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought the apparatus cleaning by splash, spray, or jet application, with or without soaking and having conveyors
    • B08B9/32Rotating conveyors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B43/00Forming, feeding, opening or setting-up containers or receptacles in association with packaging
    • B65B43/42Feeding or positioning bags, boxes, or cartons in the distended, opened, or set-up state; Feeding preformed rigid containers, e.g. tins, capsules, glass tubes, glasses, to the packaging position; Locating containers or receptacles at the filling position; Supporting containers or receptacles during the filling operation
    • B65B43/54Means for supporting containers or receptacles during the filling operation
    • B65B43/60Means for supporting containers or receptacles during the filling operation rotatable

Definitions

  • the invention relates to a device for injecting a product in the direction of a predetermined place of objects moving from continuously on a given trajectory by being spaced apart from each other by a determined step.
  • a device of this type is known; see for example US-A-3,129,713.
  • the invention will be described in the context of a installation for manufacturing and / or filling containers made of thermoplastic. More particularly, the device according to the invention will be described in the context of a machine for manufacturing bottles in polyethylene terephthalate (PET) in which the bottles are obtained by blowing a preform previously made by injection molding.
  • PET polyethylene terephthalate
  • this product may for example be a sterilizing agent.
  • the product is injected by a fixed nozzle in each hollow body when the hollow body considered pass in front of the nozzle.
  • the length of time each hollow body is next to the nozzle is extremely reduced.
  • To inject the quantity product it is then necessary to increase the product flow, at the expense of a good mastery of the jet.
  • the invention therefore aims to propose a new design an injection device that is simple and reliable and that allows to inject a product in hollow bodies in motion, the conditions of injection product to be perfectly controlled.
  • the invention proposes a device for injecting a product towards a predetermined place of objects moving from continuously on a given trajectory by being spaced apart from each other others of a determined step, characterized in that the device comprises a series of injectors that are carried by a mobile support being spaced on the support a step corresponding to that of the objects, in that that the support is driven according to an reciprocating movement such that, during a go phase of the movement, the injectors move each next to the predetermined location of one of the objects, and that the period of the reciprocating motion of the support is equal to the interval of time between the passage of two consecutive objects in front of the same point fixed, multiplied by the number of injectors on the support.
  • the invention will be described below in the context of a device 10 for injecting a sterilizing agent such as hydrogen peroxide (H 2 O 2 ) or peracetic acid (APA) into preforms 12 intended for the manufacture of PET bottles.
  • a sterilizing agent such as hydrogen peroxide (H 2 O 2 ) or peracetic acid (APA)
  • preforms 12 intended for the manufacture of PET bottles.
  • the preforms are hollow bodies made by injection molding. They are generally substantially tubular and have a closed end and an open end.
  • the open end 14, which is intended to form the open neck of the final container, is generally made directly to its final shape in the injection mold and it comprises for example a thread 16 and an outer radial collar 18.
  • preforms are transported to the blow molding machine by a positive transfer system in which the preforms follow, continuously, a defined trajectory being spaced from each other by one step determined.
  • This positive transfer system comprises for example a wheel with notches 20 which is rotated in a continuous manner around its axis A1 substantially vertical.
  • the wheel 20 has, at its periphery, twenty notches 22 in a semicircle, the diameter of the notches 22 being substantially equivalent to that of the preforms.
  • the preforms 12 are introduced on the wheel 20 at a loading point of to be received each in a notch, and so as to be in support by their flange 18 on the wheel 20.
  • a guide 24 in a circular arc axis A1 extends around the wheel 20 to form another support zone for the preforms 12 and for prevent them from escaping from the notches 22.
  • the preforms 12 are on the wheel 20, they follow an arcuate trajectory of circle around the A1 axis, up to a point of unloading at the level from which they leave the wheel 20 to continue to be transferred by other ways.
  • such a wheel notches may for example be arranged between a feeding device in preforms and a thermal conditioning furnace in which the preforms are brought to a temperature allowing their molding by blowing.
  • the device 10 comprises several injectors 26 which are carried by a mobile support 28.
  • the injectors 26 are five in number and they are carried by a plate-shaped support 28 which is rotatable around the axis A1 and which is arranged above the level of the wheel 20.
  • the injectors 26 are arranged on an arc of a circle around the axis A1 whose diameter corresponds to the diameter of the wheel notches, and they are spaced apart from each other along this arc of a distance corresponding to the distance separating two notches 22 consecutive of the wheel 22.
  • the five injectors 26 can inject the produced in five preforms carried by the wheel 20.
  • the support 28 is controlled according to a movement alternating in rotation around the axis A1, the movement control being such that, during at least one phase of this movement, the injectors 26 exactly follow the scrolling movement of the preforms that are carried by the wheel 20.
  • the reciprocating motion of the support 28 is controlled by a two cam system.
  • the device comprises a first cam 30 which presents the shape of a plate whose contour forms a cam path.
  • Drug 30 is intended to be rotated about a central axis A2 which, in the illustrated example, is parallel to the axis A1 but distinct from it.
  • the mobile support 28 has a first cam follower 32 which is for example made in the form of a roller and which is intended to roll on the song of the first cam.
  • the first cam 30 is intended to be rotated by the same shaft 34 as that which drives the notched wheel 20, by intermediate of a pair of gears 36, 38 which are dimensioned by such that the cam 30 rotates twice as fast about its axis A2 the wheel 20 about its axis A1, the directions of rotation being reversed.
  • the cam 30 is symmetrical around its A2 axis in that two points of the edge of the plate that are diametrically opposite to the axis A2 are located at equal distance from the A2 axis.
  • the cam follower 32 is intended to remain permanently in pressing against the cam path formed by the edge of the first cam 30. This could be ensured by an elastic return system, for example a spring interposed between the movable support 28 and a fixed frame member to force the roller 32 to rest on the cam.
  • a second cam 40 which is secured to the first cam 30, which has a profile complementary to the first cam 30, and which is intended to cooperate with a second cam follower 42 connected to the support 28.
  • the second cam 40 is therefore also rotated about the axis A2, the profile of this second cam is also symmetrical with respect to the axis A2.
  • the second cam follower 42 is not rigidly connected to the support 28.
  • the second cam follower 42 is carried at one end of a lever 44 which is rotatably mounted by its other end 46 on the movable support 28.
  • the axis rotation A3 of the lever 44 relative to the support 28 is parallel to the axes A1 and A2.
  • the lever 44 has a protrusion 50 on which is mounted a stop finger 48 which can slide along its axis A4 by compared to the outgrowth 50.
  • This possibility of sliding is limited and the finger is biased towards a rest position by a stack of elastic washers 51 type "Belleville".
  • This finger 48 is intended to bear against an abutment surface 52 of the support 28, this surface being positioned on the support so as to force the second cam follower 42 against the second cam 40.
  • the action of the second cam 40 forces the support 28 into opposite direction of what the first cam 30 does.
  • the two cams 30, 40 and the two cam followers 32, 42 are arranged in such a manner that they force each other in support on the cam paths, such so that the angular position of the movable support 28 is always perfectly defined regardless of the angular position of the two cams.
  • the sliding finger 48 and the spring washers 51 make it possible to catch up with the running games.
  • the dual cam system can also be replaced by a system having a single plate-shaped cam in one face of which would be dug a closed loop furrow.
  • the path would then consist of two parallel opposite edges for guiding a cam follower connected to the support in both directions of the reciprocating motion.
  • cams 30, 40 have an axis of rotation A2 parallel but distinct from the axis A1 of rotation of the support 28.
  • This arrangement makes it possible to use a cam drive system particularly simple.
  • FIGS. 5A to 5F the notch wheel 20 is illustrated and, on this wheel, two series 12a and 12b of preforms engaged in notches 22 of the wheel 20.
  • the wheel 20 is driven by rotation in a continuous manner about its axis A1, in this case in the counterclockwise if one refers to FIGS. 5A to 5F.
  • FIG. 5A corresponds to an angular position of the cams 30, 40 around their axis A2 for which the support is in a position extreme. With respect to the direction of rotation of the wheel 20, and therefore in the sense of the preforms 12 carried by the wheel 20, this position will be qualified as extreme upstream position.
  • This extreme upstream position corresponds to a reversal point of the reciprocating motion of the support 28, so that the speed of the support at this point is zero. In this position, we can see that the first set of preforms 12a is offset upstream with respect to the injectors 26 carried by the support.
  • FIG. 5B The position of the support shown in Figure 5B marks the beginning of a follow-up phase during which, for a certain period, the wheel 20 and the support 28 have substantially the same speed. In this way, while Along this phase of the movement, the injectors move in a to stay just above the preforms to inject a product.
  • This follow-up phase continues to the end of follow-up position which is illustrated in FIG. 5C, in which it can be seen that the injectors 26 are still in line with the preforms 12a, although these have continued their scrolling movement related to the rotation of the wheel 20.
  • FIG. 5D the extreme downstream position of the support 28 is illustrated. Between the positions of FIGS. 5C and 5D, the support has progressively idle for, at the position of Figure 5 D have zero velocity. We see indeed that the preforms 12a of the first series are now offset downstream from the series of injectors 26. This positon therefore corresponds to a second turning point of the movement alternative of support 28.
  • the wheel 20 has made a quarter turn, which is five times the angular spacing between two successive notches.
  • the length of time between passage of the support from its position of Figure 5A to that of Figure 5F, which corresponds to a period of the reciprocating movement of the support 28, is equal to the time required for the passage of five preforms in front of a fixed point of their trajectory on the wheel 20.
  • the cams 30, 40 have at the same time made a half-turn and, because of their profile which has a central symmetry with respect to the axis A2, the operation of the device can then continue analogous to what has been described above, the injectors 26 in front of then follow the preforms 12b of the second series.
  • the device according to the invention there is a time of sufficient projection, without stopping or slowing the preforms, while treating of course all the preforms.
  • the duration of the step of the movement which is the time possible for product projection on objects in motion, represents only about a quarter to a third of the duration total of a complete cycle of movement.
  • this ratio could easily be varied, but which, it allows to have reversal steps that do not impose on the support for sudden changes in speed.
  • This advantage presupposes that the durations of the going and reversing stages of the movement are of the same order of magnitude, ie the ratio between the duration of the step and the shortest duration is less than 10.
  • the amplitude of the reciprocating motion of the support 28 is relatively limited so that injectors 26 can be supplied with product by a fixed tank connected to the injectors by a or multiple flexible pipe. Such a provision is therefore very much easier than if you had to use a rotary distributor.
  • the invention has therefore been described in the particular context of spraying sterilizing product into a preform for manufacturing of containers.
  • a device incorporating the teachings of the invention can be used for the treatment of other objects, such as plugs. It can also be used to treat other places predetermined values of an object, for example, in the case of a preform or a bottle, the threaded outer part of the neck.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Basic Packing Technique (AREA)
  • Loading And Unloading Of Fuel Tanks Or Ships (AREA)
  • Formation And Processing Of Food Products (AREA)
  • Infusion, Injection, And Reservoir Apparatuses (AREA)
  • Confectionery (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
  • On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)

Claims (19)

  1. Vorrichtung zum Einspritzen eines Produktes in Richtung einer vorbestimmten Stelle von Objekten, die sich kontinuierlich auf einer gegebenen Bahn bewegen und um einen vorbestimmten Abstand voneinander entfernt sind,
    dadurch gekennzeichnet, dass die Vorrichtung (10) eine Reihe von Einspritzdüsen (26) umfasst, die von einer beweglichen Stütze (28) getragen werden und auf der Stütze um einen Abstand, der jenem der Objekte entspricht, voneinander entfernt sind, dass die Stütze (28) in einer Wechselbewegung angetrieben wird, so dass sich während einer Hinbewegungsphase die Einspritzdüsen (26) jeweils gegenüber der vorbestimmten Stelle eines der Objekte verschieben, und dass der Zeitraum der Wechselbewegung der Stütze gleich dem Zeitintervall zwischen dem Durchgang zweier aufeinander folgender Objekte vor einem Fixpunkt, multipliziert mit der Anzahl von Einspritzdüsen auf der Stütze, ist.
  2. Vorrichtung nach Anspruch 1, dadurch gekennzeichnet, dass sich während der Hinbewegungsphase die Einspritzdüsen (26) parallel zu den Objekten und mit derselben Geschwindigkeit wie diese verschieben.
  3. Vorrichtung nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass die Wechselbewegung der Stütze (28) zusätzlich zur Hinbewegungsphase eine Rückbewegungsphase, während der die Bewegung in umgekehrte Richtung erfolgt, und zwei Umkehrphasen umfasst.
  4. Vorrichtung nach Anspruch 3, dadurch gekennzeichnet, dass die Dauern der vier Bewegungsphasen von derselben Größenordnung sind.
  5. Vorrichtung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass während der gesamten Wechselbewegung die Bahn der Einspritzdüsen (26) zur Bahn der Objekte parallel bleibt.
  6. Vorrichtung nach Anspruch 5, dadurch gekennzeichnet, dass die Bahn der Einspritzdüsen ein Kreisbogen ist.
  7. Vorrichtung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie ein Übertragungsrad (20) umfasst, das eine kontinuierliche Drehbewegung um seine Achse (A1) ausführt und auf dem die Objekte entlang eines Teils ihrer Bahn aufgeladen sind, und dass die Einspritzdüsen (26) eine Bahn in Kreisbogenform um dieselbe Achse (A1) verfolgen.
  8. Vorrichtung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Wechselbewegung der beweglichen Stütze durch ein System gesteuert wird, das eine bewegliche Nocke (30) und eine mit der Stütze (28) verbundene Nockenverfolgungseinrichtung (32) umfasst.
  9. Vorrichtung nach den Ansprüchen 7 und 8 in Kombination, dadurch gekennzeichnet, dass die Nocke (30) eine Drehnocke ist, die eine kontinuierliche Drehbewegung ausführt.
  10. Vorrichtung nach Anspruch 9, dadurch gekennzeichnet, dass die Nocke eine kontinuierliche Drehbewegung um dieselbe Achse wie die Drehachse der Stütze ausführt.
  11. Vorrichtung nach Anspruch 9, dadurch gekennzeichnet, dass die Nocke (30) eine kontinuierliche Drehbewegung um eine Achse (A2) parallel zur Drehachse (A1) der Stütze (28) ausführt.
  12. Vorrichtung nach einem der Ansprüche 9 bis 11, dadurch gekennzeichnet, dass die Nocke (30) die Form einer Platte aufweist, deren Kontur den Nockenweg bildet.
  13. Vorrichtung nach Anspruch 12, dadurch gekennzeichnet, dass die Nockenverfolgungseinrichtung gegen die Nocke durch elastische Rückstellmittel angelegt wird.
  14. Vorrichtung nach Anspruch 12, dadurch gekennzeichnet, dass die Vorrichtung (10) eine zweite Nocke (40) umfasst, mit der eine zweite Nockenverfolgungseinrichtung (42) zusammenwirkt, die mit der Stütze (28) verbunden ist, und dass die Profile der beiden Nocken (30, 40) komplementär sind, so dass eine positive Steuerung der Stütze (28) in beide Richtungen ihrer Wechselbewegung sichergestellt ist.
  15. Vorrichtung nach Anspruch 14, dadurch gekennzeichnet, dass mindestens eine der beiden Nockenverfolgungseinrichtungen (32, 42) elastische Mittel (48, 50, 51) umfasst, die die geometrischen Ungenauigkeiten der Vorrichtung (10) ausgleichen können.
  16. Vorrichtung nach Anspruch 12, dadurch gekennzeichnet, dass sie eine Platte umfasst, in der eine Spur mit zwei parallelen Rändern ausgebildet ist, in der eine Rolle umläuft, die mit der Stütze verbunden ist und die mit jedem der beiden Ränder der Spur zusammenwirken kann, wobei jeder der beiden Ränder jeweils einen Nockenweg bildet, um eine positive Steuerung der Stütze in beide Richtungen ihrer Bahn sicherzustellen.
  17. Vorrichtung nach einem der Ansprüche 9 bis 16, dadurch gekennzeichnet, dass die Nocke (30) in Drehung durch das Übertragungsrad (20) angetrieben wird, wobei ein Untersetzungsmechanismus (36, 38) zwischengeschaltet ist.
  18. Vorrichtung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Objekte Hohlkörper sind, die eine Öffnung umfassen.
  19. Vorrichtung nach Anspruch 18, dadurch gekennzeichnet, dass die Einspritzdüsen dazu vorgesehen sind, ein Produkt in das Innere der Hohlkörper zu spritzen.
EP01907670A 2000-02-16 2001-01-23 Vorrichtung zum einspritzen eines mittels an einen bestimmten ort eines sich bewegenden objektes Expired - Lifetime EP1257371B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0001872 2000-02-16
FR0001872A FR2804938B1 (fr) 2000-02-16 2000-02-16 Dispositif pour injecter un produit sur un endroit predetermine d'un objet en mouvement
PCT/FR2001/000209 WO2001060536A1 (fr) 2000-02-16 2001-01-23 Dispositif pour injecter un produit sur un endroit predetermine d'un objet en mouvement

Publications (2)

Publication Number Publication Date
EP1257371A1 EP1257371A1 (de) 2002-11-20
EP1257371B1 true EP1257371B1 (de) 2004-09-22

Family

ID=8847028

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EP01907670A Expired - Lifetime EP1257371B1 (de) 2000-02-16 2001-01-23 Vorrichtung zum einspritzen eines mittels an einen bestimmten ort eines sich bewegenden objektes

Country Status (15)

Country Link
US (1) US6681816B2 (de)
EP (1) EP1257371B1 (de)
JP (1) JP3650753B2 (de)
KR (1) KR100506372B1 (de)
CN (1) CN1242855C (de)
AT (1) ATE276837T1 (de)
AU (1) AU776470B2 (de)
BR (1) BR0108345B1 (de)
CA (1) CA2396556C (de)
DE (1) DE60105765T2 (de)
ES (1) ES2228809T3 (de)
FR (1) FR2804938B1 (de)
MX (1) MXPA02007825A (de)
PT (1) PT1257371E (de)
WO (1) WO2001060536A1 (de)

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US7261199B2 (en) * 2004-06-29 2007-08-28 Hartness International, Inc. Neck gripping conveyor and link, and related rotary filler and system
US7055677B2 (en) * 2003-11-13 2006-06-06 Hartness International, Inc. Conveyor with movable grippers, and related conveyor link
US7055676B2 (en) * 2003-11-13 2006-06-06 Hartness International, Inc. Conveyor with movable gripper and related conveyor link
US7299832B2 (en) * 2004-06-29 2007-11-27 Hartness International, Inc. Rotary filling machine and related components, and related method
US7185753B2 (en) * 2004-09-28 2007-03-06 Hartness International, Inc. Shuttle conveyor
US9020913B2 (en) 2007-10-25 2015-04-28 International Business Machines Corporation Real-time interactive authorization for enterprise search
FR2923802B1 (fr) * 2007-11-19 2012-08-31 Sidel Participations Dispositif de transport d'un corps creux, installation pourvue de tels dispositifs et procede de convoyage d'un corps creux solidarise a un tel dispositif.
EP2143545A1 (de) * 2008-07-07 2010-01-13 Nestec S.A. Verfahren und Vorrichtung zum Abfüllen von flüssigen Lebensmitteln
NL2012834B1 (en) 2014-05-16 2016-03-02 Sluis Cigar Machinery Bv System for performing a processing step on cigarette parts of an electronic cigarette.
CN108045654B (zh) * 2017-10-20 2020-06-12 惠州亿纬锂能股份有限公司 用于锂电池注液的注液系统及其锂电池注液设备
CN112009953B (zh) * 2020-08-28 2022-04-01 哈尔滨工业大学(深圳) 一种西林瓶用盘式取药装置和自动配药机器人
DE102021131574A1 (de) * 2021-12-01 2023-06-01 Krones Aktiengesellschaft Lageranordnung zum Lagern eines Behälterbehandlungskarussells gegen ein Grundgestell einer Behälterbehandlungsvorrichtung in einer Getränkeabfüllanlage

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US3129713A (en) * 1963-04-04 1964-04-21 Dostal & Lowey Co Inc Bottle washing machine with improved rinsing means
US4004620A (en) * 1974-10-04 1977-01-25 Sidney Rosen Fluid filling machine
US4159608A (en) * 1978-04-28 1979-07-03 Package Engineering Corporation Bottling machine
US4678015A (en) * 1986-04-03 1987-07-07 Raque Food Systems, Inc. Product apportioning system

Also Published As

Publication number Publication date
AU3558201A (en) 2001-08-27
CN1242855C (zh) 2006-02-22
FR2804938B1 (fr) 2002-04-26
JP2003522691A (ja) 2003-07-29
FR2804938A1 (fr) 2001-08-17
US6681816B2 (en) 2004-01-27
US20030000969A1 (en) 2003-01-02
ATE276837T1 (de) 2004-10-15
CA2396556C (fr) 2006-07-11
EP1257371A1 (de) 2002-11-20
DE60105765D1 (de) 2004-10-28
MXPA02007825A (es) 2003-02-10
BR0108345B1 (pt) 2009-08-11
JP3650753B2 (ja) 2005-05-25
BR0108345A (pt) 2003-03-11
AU776470B2 (en) 2004-09-09
DE60105765T2 (de) 2006-03-09
KR100506372B1 (ko) 2005-08-10
PT1257371E (pt) 2005-01-31
CN1400928A (zh) 2003-03-05
CA2396556A1 (fr) 2001-08-23
WO2001060536A1 (fr) 2001-08-23
KR20020092360A (ko) 2002-12-11
ES2228809T3 (es) 2005-04-16

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