EP1240281A2 - Verwendung von schmiermitteln mit polyhydroxyverbindungen - Google Patents
Verwendung von schmiermitteln mit polyhydroxyverbindungenInfo
- Publication number
- EP1240281A2 EP1240281A2 EP00960539A EP00960539A EP1240281A2 EP 1240281 A2 EP1240281 A2 EP 1240281A2 EP 00960539 A EP00960539 A EP 00960539A EP 00960539 A EP00960539 A EP 00960539A EP 1240281 A2 EP1240281 A2 EP 1240281A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- use according
- compounds
- formulations
- groups
- transport
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 56
- 150000001875 compounds Chemical class 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 58
- 238000009472 formulation Methods 0.000 claims abstract description 57
- -1 polysiloxanes Polymers 0.000 claims description 52
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 19
- 239000004033 plastic Substances 0.000 claims description 18
- 229920003023 plastic Polymers 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 229920001296 polysiloxane Chemical class 0.000 claims description 12
- 230000000845 anti-microbial effect Effects 0.000 claims description 11
- 235000013361 beverage Nutrition 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 9
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 9
- 150000002894 organic compounds Chemical class 0.000 claims description 7
- 150000002989 phenols Chemical class 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000012895 dilution Substances 0.000 claims description 6
- 238000010790 dilution Methods 0.000 claims description 6
- 150000002222 fluorine compounds Chemical class 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 5
- 230000001050 lubricating effect Effects 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 4
- 150000002357 guanidines Chemical class 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical class FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 3
- 239000011111 cardboard Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 235000013305 food Nutrition 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229920005615 natural polymer Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229920001059 synthetic polymer Polymers 0.000 claims description 3
- MITNMQMWBBEWFQ-UHFFFAOYSA-N 1-(4-chlorophenyl)-1-(3,4-dichlorophenyl)urea Chemical compound C=1C=C(Cl)C(Cl)=CC=1N(C(=O)N)C1=CC=C(Cl)C=C1 MITNMQMWBBEWFQ-UHFFFAOYSA-N 0.000 claims description 2
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 claims description 2
- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 claims description 2
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 claims description 2
- TYBHZVUFOINFDV-UHFFFAOYSA-N 2-bromo-6-[(3-bromo-5-chloro-2-hydroxyphenyl)methyl]-4-chlorophenol Chemical compound OC1=C(Br)C=C(Cl)C=C1CC1=CC(Cl)=CC(Br)=C1O TYBHZVUFOINFDV-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 2
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004155 Chlorine dioxide Substances 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 229940111121 antirheumatic drug quinolines Drugs 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 150000003937 benzamidines Chemical class 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 125000006267 biphenyl group Chemical group 0.000 claims description 2
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 2
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 2
- 229960004106 citric acid Drugs 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 2
- SMGTYJPMKXNQFY-UHFFFAOYSA-N octenidine dihydrochloride Chemical compound Cl.Cl.C1=CC(=NCCCCCCCC)C=CN1CCCCCCCCCCN1C=CC(=NCCCCCCCC)C=C1 SMGTYJPMKXNQFY-UHFFFAOYSA-N 0.000 claims description 2
- 150000004967 organic peroxy acids Chemical class 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 claims description 2
- 239000006072 paste Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 229960005323 phenoxyethanol Drugs 0.000 claims description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 150000003222 pyridines Chemical class 0.000 claims description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 2
- 150000003248 quinolines Chemical class 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 229960002703 undecylenic acid Drugs 0.000 claims description 2
- 150000003672 ureas Chemical class 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 4
- 238000009434 installation Methods 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 25
- 150000001412 amines Chemical class 0.000 description 21
- 239000000344 soap Substances 0.000 description 10
- 125000004429 atom Chemical group 0.000 description 9
- 229920006395 saturated elastomer Polymers 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 125000001424 substituent group Chemical group 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 238000005461 lubrication Methods 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical class [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920001774 Perfluoroether Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 150000002466 imines Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- ORTFAQDWJHRMNX-UHFFFAOYSA-M oxidooxomethyl Chemical compound [O-][C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-M 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 239000013638 trimer Substances 0.000 description 2
- ISJIDFLLBOMQFL-UHFFFAOYSA-N 2-[[6-[(diaminomethylideneamino)methylamino]hexylamino]methyl]guanidine Chemical compound NC(=N)NCNCCCCCCNCNC(N)=N ISJIDFLLBOMQFL-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003831 antifriction material Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical compound O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
- C10M107/36—Polysaccharides, e.g. cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/10—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M105/14—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms polyhydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/08—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least 2 hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M131/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
- C10M131/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen, halogen and oxygen
- C10M131/10—Alcohols; Ethers; Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M131/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
- C10M131/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen, halogen and oxygen
- C10M131/12—Acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C10M135/02—Sulfurised compounds
- C10M135/04—Hydrocarbons
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
- C10M135/10—Sulfonic acids or derivatives thereof
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- C10M151/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
- C10M173/025—Lubricating compositions containing more than 10% water not containing mineral or fatty oils for lubricating conveyor belts
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- C10M2201/02—Water
- C10M2201/022—Hydrogen peroxide; Oxygenated water
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- C10M2201/06—Metal compounds
- C10M2201/063—Peroxides
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- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
- C10M2207/0225—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups used as base material
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- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
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- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
- C10M2209/123—Polysaccharides, e.g. cellulose, biopolymers used as base material
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- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/044—Acids; Salts or esters thereof
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- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/06—Perfluorinated compounds
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- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
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- C10M2213/06—Perfluoro polymers
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- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2221/041—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving sulfurisation of macromolecular compounds, e.g. polyolefins
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2221/043—Polyoxyalkylene ethers with a thioether group
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Definitions
- the present invention relates to the use of at least one selected polyhydroxy compound as a lubricating component in lubricant formulations and the use of chain lubricants which contain at least 20% by weight of at least one selected polyhydroxy compound to reduce the friction between transport goods and transport systems.
- the invention further relates to a lubricant which contains other additives in addition to the polyhydroxy compounds.
- the containers to be filled in the filling plants are transported by means of conveyors of various designs and materials, for example by means of plate conveyor belts or chain-like arrangements, which are to be referred to in the following generally as transport chains.
- the transporters establish the connection between the various optional treatment stages of the filling process such as B. unpacker, bottle washer, filler, capper, labeler, packer, etc.
- the containers can be of various shapes, in particular glass and plastic bottles, cans, glasses, barrels, beverage containers (KEG), paper and cardboard containers.
- KEG beverage containers
- the transport chains must be lubricated in a suitable manner so that excessive friction against the containers is avoided.
- Diluted aqueous solutions containing suitable anti-friction agents are usually used for lubrication.
- the transport chains are brought into contact with the aqueous solutions, for example by immersion or spraying, in which case one speaks of splash lubrication systems or automatic belt lubrication systems or central chain lubrication systems.
- the chain lubricants previously used as lubricants are mostly based on fatty acids in the form of their water-soluble alkali or alkanolamine salts or on fatty amines, preferably in the form of their organic or inorganic salts.
- DE-A-23 13 330 describes soap-based lubricants, the aqueous mixtures of C- j -C- j ß fatty acid salts and surface-active
- soap-based lubricants have the following disadvantages:
- Soap-based lubricant preparations continue to be dependent on water temperature. 10. Soap-based lubricants only have a low storage stability, especially at low temperatures.
- the EDTA ethylenediaminetetraacetate contained in many products is known to be poorly biodegradable.
- Such soap-based lubricant preparations are not suitable for all transport goods made of plastic, since in many cases stress corrosion cracking on the transport goods occurs when these agents are used.
- DE-A-36 31 953 describes a method for lubricating chain-shaped bottle conveyor belts in beverage filling companies, in particular in breweries, and for cleaning the belts using a liquid cleaning agent, which is characterized in that the chain-shaped bottle conveyor belts are based on belt lubricants neutralized primary fatty amines, which preferably have 12 to 18 carbon atoms and contain an unsaturated fraction of more than 10%.
- R 1 is a saturated or unsaturated, branched or linear alkyl group with 8 to 22 C atoms;
- R2 is hydrogen, an alkyl or hydroxyalkyl group with 1 to 4 carbon atoms or -A-
- A is a linear or branched alkylene group with 1 to 8 carbon atoms
- a 1 represents a linear or branched alkylene group with 2 to 4 carbon atoms.
- DE-A-39 05 548 discloses lubricants based on N-alkylated fatty amine derivatives which contain at least one secondary and / or tertiary amine.
- R is a saturated or mono- or polyunsaturated, linear or branched alkyl radical having 6 to 22 carbon atoms, which may be replaced by -OH, - NH 2 , -NH-, -CO-, - (CH 2 CH 2 O) r or - (CH 2 CH 2 CH 2 O) r may be substituted,
- R 1 represents hydrogen, an alkyl radical having 1 to 4 carbon atoms, a hydroxyalkyl radical having 1 to 4 carbon atoms or a radical -R ⁇ COOM
- R2 only in the case that M represents a negative charge for hydrogen, an alkyl radical with 1 to 4 C atoms, or a hydroxyalkyl radical with 1 to 4 C atoms,
- R 3 is a saturated or mono- or polyunsaturated, linear or branched alkyl radical having 1 to 12 carbon atoms, which may be replaced by -OH, - NH 2 , -NH-, -CO-, - (CH 2 CH 2 O) or - (CH 2 CH 2 CH 2 O) r may be substituted,
- R 4 represents a substituted or unsubstituted, linear or branched, saturated or mono- or polyunsaturated alkyl radical having 6 to 22 carbon atoms, which may have at least one amine, imine, hydroxyl, halogen and / or carboxy radical as substituent, a substituted or unsubstituted phenyl radical which may have at least one amine, imine, hydroxyl, halogen, carboxy and / or a linear or branched, saturated or mono- or polyunsaturated alkyl radical with 6 to 22 C atoms as substituents,
- R5 for hydrogen or - independently of R 4 - for a radical R 4
- X stands for an anion from the group amidosulfonate, nitrate, halide, sulfate, hydrogen carbonate, carbonate, phosphate or R 6 -COO " ,
- RO for hydrogen, a substituted or unsubstituted, linear or branched alkyl radical having 1 to 20 carbon atoms or alkenyl radical having 2 to 20 carbon atoms, which may have at least one hydroxyl, amine or imine radical as a substituent, or a substituted or unsubstituted Phenyl radical, which may have an alkyl radical with 1 to 20 C atoms as a substituent, and
- R 7 and R 8 each independently of one another represent a substituted or unsubstituted, linear or branched alkyl radical having 1 to 20 C atoms or alkenyl radical having 2 to 20 C atoms, which may have at least one hydroxyl, amine or imine radical as substituents, or a substituted or unsubstituted phenyl radical, which may have an alkyl radical with 1 to 20 C atoms as substituents,
- M for hydrogen, alkali metal, ammonium, an alkyl radical with 1 to 4 carbon atoms, a benzyl radical or a negative charge
- n for an integer in the range from 1 to 12
- m for an integer in the range from 0 to 5 and
- I stands for a number in the range from 0 to 5, containing alkyldimethylamine oxides and / or alkyl oligoglycosides as nonionic
- EP-B-629 234 discloses a lubricant combination consisting of a) one or more compounds of the formula
- R1 is a saturated or mono- or polyunsaturated, linear or branched alkyl radical having 6 to 22 carbon atoms, which can optionally be substituted by -OH, -NH 2 , -NH-, -CO-, halogen or a carboxyl radical,
- R 2 represents a carboxyl radical with 2 to 7 C atoms
- M for hydrogen, alkali metal, ammonium, an alkyl radical with 1 to 4 C-
- Atoms or a benzyl radical and n is an integer in the range from 1 to 6, b) at least one organic carboxylic acid selected from monobasic or polybasic, saturated or mono- or polyunsaturated carboxylic acids having 2 to 22 carbon atoms, c) optionally water and Additives and / or auxiliaries.
- WO 94/03562 describes a lubricant concentrate based on fatty amines and, if appropriate, customary diluents or auxiliaries or additives, characterized in that it contains at least one polyamine derivative of a fatty amine and / or a salt of such an amine, the proportion of said polyamine derivatives of Fatty amines in the total formulation is 1 to 100% by weight.
- this lubricant concentrate contains at least one polyamine derivative of a fatty amine of the general formula
- R is a substituted or unsubstituted, linear or branched, saturated or mono- or polyunsaturated alkyl radical having 6 to 22 carbon atoms, the substituents being selected from amino, imino, hydroxy, halogen and carboxy, or a substituted or unsubstituted phenyl radical, where the Substituents are selected from amino, imino, hydroxyl, halogen, carboxy and a linear or branched, saturated or mono- or polyunsaturated alkyl radical having 6 to 22 carbon atoms;
- A represents either -NH- or -O-
- Lubricants based on polytetrafluoroethylene are used in some filling plants. These are in the form of dispersions and are not applied to the chains via nozzles, as is usually the practice, but with brushes. These agents have the advantage that they bring about a substantial reduction in the friction between the conveyor belts and the goods to be transported. In addition, the polytetrafluoroethylene adheres very strongly to the chains. In practice, it turned out to be disadvantageous that the overall hygienic condition with regard to contamination and contamination of the transport chains deteriorated. This even went so far that the performance profile of the lubricant deteriorated over time due to the increase in contamination.
- the commonly used lubricants have the disadvantage that they form a firmly adhering film on the transport chains, which is not easy to remove by simply rinsing with water.
- the object of the present invention is to provide lubricants based on polyhydroxy compounds which are hydrophilic due to their molecular structure and at the same time improve the lubricating performance compared to the amines usually used as lubricants.
- the present invention relates to the use of at least one polyhydroxy compound, for which at any point in the molecular structure it applies that among 10 or fewer atoms which are linked to one another via covalent bonds, there is at least one hydroxyl group in free, etherified and / or esterified form which has less than 5 atoms is linked by covalent bond with a second hydroxyl group in free, etherified and / or esterified form, in lubricant formulations to reduce the friction between transport goods and transport systems, and in another object of the invention the use of chain lubricants related to the entire formulation, containing at least 20% by weight of at least one polyhydroxy compound, for which it applies at any point in the molecular structure that at least one hydroxyl group in free, under 10 or fewer atoms linked to one another via covalent bonds etherified and / or esterified form, which is connected via less than 5 atoms by covalent bond with a second hydroxyl group in free, etherified and / or esterified form, for the
- the proportion of polyhydroxy compounds, based on the entire formulation is greater than 25% by weight and, in a very particularly preferred embodiment, greater than 40% by weight and in particular greater than 80% by weight.
- lubricants with high polarity and high hydrophilicity are obtained. Accordingly, such lubricants can be used in practice without forming a difficult-to-remove film on the chains.
- the film formed by the agents to be used according to the invention can be easily removed by simply rinsing with water. This has the advantage that when using appropriate formulations according to the invention, little or no dirt accumulates on the transport chains or other surfaces which come into contact with the chain lubricant.
- the polyhydroxy compounds comprise organic compounds with more than 2 hydroxy groups from the groups of the alcohols, which also include sugar alcohols and carbohydrates, phenols, and natural polymers and synthetic polymers, with at least one component being particularly preferably selected as the polyhydroxy compound from alkanediols or alkanetriols, very particularly preferably glycerol, or their polymers and their esters and ethers are contained.
- the formulations to be used according to the invention additionally comprise at least one component selected from the fluorine and silicone compounds, the fluorine compound being particularly preferably selected from the groups of the a) per- or partially fluorinated monomeric organic compounds, b) pure and mixed di- and oligomers based on at least one per- or partially fluorinated organic monomer, c) pure and mixed polymers based on at least one per- or partially fluorinated organic monomer.
- the present invention relates to the generally known characterization of polymers which are composed of so many identical or similar low molecular weight building blocks (monomers) that the physical properties of these substances, in particular the viscoelasticity, contribute to No longer noticeably change the increase or decrease in the number of blocks by one unit. This is generally the case when the average molecular weight of the "polymers" is 10,000 g / mol or more.
- the fluorine compounds a) comprise at least per- and partially fluorinated surfactants, alkanes, ethers and amines, particularly preferably in the formulations used according to the invention ammonium perfluoroalkylsulfonates, lithium perfluoroalkylsulfonates, potassium perfluoroalkylsulfonates, amine perfluoroalkylsulfonates, sodium perfluoroalkylsulfonates, potassium quaternary fluorinated alkylamomonium iodides, ammonium perfluoroalkylcarboxalates, fluorinated alkylpolyoxyethyleneethanols, fluorinated alkylalkoxylates, fluorinated alkyl esters with concentrations of 0.001 to 10% are used.
- the fluorinated components of group c) are preferably per- and / or partially fluorinated alkoxy polymers, which are particularly preferably obtainable from the copolymerization of tetrafluoroethylene and perfluoroalkoxy vinyl ethers.
- the formulations from group c) to be used according to the invention contain at least per- and / or partially fluorinated polyethers.
- the silicone compounds contained in a preferred embodiment of the formulations to be used according to the invention are preferably selected from the group of the polysiloxanes and particularly preferably selected from the groups of the linear, branched, cyclic and crosslinked polysiloxanes.
- formulations to be used according to the invention are in the form of one-component liquids, solutions, gels, emulsions, pastes, dispersions.
- the formulations to be used according to the invention additionally contain at least one antimicrobial component selected from the groups of alcohols, aldehydes, antimicrobial acids, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals , Benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1, 2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butyl-carbamate, iodine, iodophores, peroxides, where in a particularly preferred embodiment, the formulations to be used according to the invention as antimicrobial components, one or more compounds selected from ethanol, n-propanol, i-propano
- the formulations to be used according to the invention contain further components selected from the groups of the surfactants and solubilizers, it being particularly preferred that at least one alkyl polyglycoside is contained as the surfactant.
- Other preferred ingredients are Fatty alkylamines and / or their alkoxylates, in particular coconut fatty amine ethoxylates and / or imidazoline compounds and / or amphoteric surfactants and / or nonionic surfactants and / or ether carboxylic acids and / or ether amine compounds.
- paraffin compounds it is preferred to add paraffin compounds to the formulations to be used according to the invention.
- the formulations to be used according to the invention are applied to the transport chains, and in the best case it can be observed that no foam is produced when the transport goods are transported on the transport systems. It is further preferred that the formulations to be used according to the invention are compared to conventional lubricants which are diluted with water in transport systems by a dilution factor of more than 100 and in the event that equal amounts of lubricating components are applied to the conveyor belt system within a defined period of time are, when using formulations to be used according to the invention, the frictional resistance between transport goods and conveyor belt system is reduced by more than 20%. This can be shown by example experiments.
- a comparative formulation 1 which contains 5% by weight of coconut propylene diamine and is adjusted to pH 7 with acetic acid, is applied in a 0.2% aqueous concentration to the. Via a nozzle assembly with 5 nozzles, each of which has a spray rate of 5 liters per hour Transport chains applied. Over a period of 1 hour, 50 ml of the comparison formulation, or approximately 2.5 g of the coconut propylene diamine, thus reach the transport chains. This test is carried out over a period of 10 hours.
- the coefficient of friction between the beverage bottle and stainless steel transport chains is defined as the ratio of the pulling weight which is exerted, for example, on a spring balance when one tries to hold a beverage bottle while the transport chains are running, to the weight of the bottle.
- a further preferred embodiment of the present invention is the use of the formulations to be used according to the invention for the transport of plastic containers, the plastic containers particularly preferably at least one polymer selected from the groups of polyethylene terephthalate (PET), polyethylene naphthenate (PEN), polycarbonate (PC), PVC contain and are particularly preferred PET beverage bottles.
- PET polyethylene terephthalate
- PEN polyethylene naphthenate
- PC polycarbonate
- PVC contain and are particularly preferred PET beverage bottles.
- the stress corrosion cracking is measured by a comparative example based on 5% by weight coconut propylene diamine and 5% by weight dimethyl laurylamine, which are adjusted to pH 7 with acetic acid, in comparison to the stress corrosion cracking of pure glycerol.
- PET bottles are filled with water and conditioned with carbon dioxide so that there is a pressure of about 7 bar in the interior of the bottles.
- the bottom cups of the bottles are then incorporated into the formulation of the comparative example or the example to be used according to the invention dipped and placed in a petri dish over a period of 24 hours. After the 24 hours, the bottles are opened, emptied and the floor cups rinsed with water.
- a visual evaluation of the floor cups shows that there are many stress cracks with medium depth, rating C, in the test with the comparative example, while it is found in the test with the example to be used according to the invention that only a few stress cracks with low depth, rating A , are available.
- the classification is based on the reference images contained in Chapter IV-22 of the book 'CODE OF PRACTICE - Guidelines for an Industrial Code of Practice for Refillable PET Bottles', Edition 1, 1993-1994.
- Example 2 shows that the formulations to be used according to the invention have advantages over the transportation of plastic bottles compared to the amine-based products commonly used as lubricants on the market.
- formulations to be used according to the invention are used for the transport of cardboard packaging.
- the transport surfaces of the conveyor belt systems are made of plastic, particularly preferably of polyacetal and polyethylene.
- the transport surfaces of the conveyor belt system are made of metal, particularly preferably made of stainless steel. It is further preferred to add additional antimicrobial substances, particularly preferably organic peracids, chlorine dioxide or ozone, to the formulations to be used according to the invention before or after application by separate addition.
- additional antimicrobial substances particularly preferably organic peracids, chlorine dioxide or ozone
- the formulations to be used according to the invention are applied to the conveyor belts without prior dilution with water using an auxiliary agent which can be selected from a brush, sponge, roller, cloth, rag, brush, wiper, rubber, spraying device.
- those to be used according to the invention are used Formulations in automatic conveyor belt systems diluted with water and the application solution applied to the conveyor belts via metering devices, the dilution factor being between 10,000 and 100. It is further preferred that the formulations to be used according to the invention are selected and applied such that no further multiplication of microorganisms takes place on surfaces which are in contact with the formulations or solution, and very particularly preferably the number of microorganisms is reduced.
- formulations to be used according to the invention are preferably used for the transport of containers in the food industry.
- the bottom of the plastic bottles is rinsed off with water before the plastic bottles leave the bottling plant.
- the chemical attack is intensified if, for example due to summer temperatures during transport or storage, the internal pressure in the bottles increases and the bottle material is therefore under high tension.
- the beverage bottles can be on the market for up to several months before they are transported back to the bottling plant.
- the advantage of the formulations to be used according to the invention is that they are easy to rinse off and can be removed by a final rinse with water.
- polyhydroxy compounds Another advantage of the polyhydroxy compounds is that most of them are readily degradable compared to the compounds that are usually used as lubricants.
- the present invention furthermore relates to chain lubricants which, based on the entire formulation, contain at least 20% by weight, preferably more than 40% by weight and particularly preferably more than 80% by weight, of at least one polyhydroxy compound, to which the molecular structure applies at every point that there are at least one hydroxyl group in free, etherified and / or esterified form among 10 or fewer atoms which are linked to one another via covalent bonds and which are linked via fewer than 5 atoms by covalent bond to a second hydroxyl group in free, etherified and / or esterified form is.
- chain lubricants with high polarity and high hydrophilicity are obtained. Accordingly, such lubricants can be used in practice without a difficult-to-remove film on the chains forms. On the contrary, the film formed by the agents to be used according to the invention can be easily removed by simply rinsing with water. This has the advantage that when using appropriate formulations according to the invention, little or no dirt accumulates on the transport chains or other surfaces which come into contact with the chain lubricant.
- the polyhydroxy compounds comprise organic compounds with more than 2 hydroxyl groups from the groups of alcohols, phenols, sugar alcohols, carbohydrates and natural polymers and synthetic polymers, particularly preferably as polyhydroxy compound at least one component selected from alkane diols or alkane triols, very particularly preferably glycerol , or their polymers as well as their esters and ethers are contained.
- the chain lubricants according to the invention additionally contain at least one component selected from the fluorine and silicone compounds, the fluorine compound being particularly preferably selected from the groups of the a) per- or partially fluorinated monomeric organic compounds, b) pure and mixed di - And oligomers based on at least one per- or partially fluorinated organic monomer, c) pure and mixed polymers based on at least one per- or partially fluorinated organic monomer.
- the present invention relates to the generally known characterization of polymers which are composed of so many identical or similar low molecular weight building blocks (monomers) that the physical properties of these substances, in particular the viscoelasticity, contribute to No longer noticeably change the increase or decrease in the number of blocks by one unit. This is in generally the case when the average molecular weight of the "polymers" is 10,000 g / mol or more.
- the fluorine compounds a) comprise at least per- and partially fluorinated surfactants, alkanes, ethers and amines, particularly preferably in the formulations used according to the invention, ammonium perfluoroalkyl sulfonates, lithium perfluoroalkyl sulfonates, potassium perfluoroalkyl sulfonates, amine perfluoroalkyl sulfonates, sodium perfluoroalkyl sulfonate alkylate, ammonium fluorate ammonium fluorate, ammonium fluoramate fluoromate fluoromate fluoromate fluoromate fluoromate fluorate fluorate quaternary fluoromate, fluorinated alkyl polyoxyethylene ethanols, fluorinated alkyl alkoxylates, fluorinated alkyl
- the fluorinated components of group c) are preferably per- and / or partially fluorinated alkoxy polymers, which are particularly preferably obtainable from the copolymerization of tetrafluoroethylene and perfluoroalkoxy vinyl ethers.
- the formulations from group c) to be used according to the invention contain at least per- and / or partially fluorinated polyethers.
- a further preferred embodiment of the present invention comprises a chain lubricant according to the invention which additionally contains at least one silicon compound in the formulation, preferably selected from the groups of linear, branched, cyclic and crosslinked polysiloxanes.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19942535A DE19942535A1 (de) | 1999-09-07 | 1999-09-07 | Verwendung von Schmiermitteln mit Polyhydroxyverbindungen |
| DE19942535 | 1999-09-07 | ||
| PCT/EP2000/008393 WO2001018159A2 (de) | 1999-09-07 | 2000-08-29 | Verwendung von schmiermitteln mit polyhydroxyverbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1240281A2 true EP1240281A2 (de) | 2002-09-18 |
Family
ID=7921009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00960539A Withdrawn EP1240281A2 (de) | 1999-09-07 | 2000-08-29 | Verwendung von schmiermitteln mit polyhydroxyverbindungen |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1240281A2 (es) |
| JP (1) | JP2003509536A (es) |
| AR (1) | AR026158A1 (es) |
| AU (1) | AU7280700A (es) |
| BR (1) | BR0013847A (es) |
| CA (1) | CA2381345C (es) |
| DE (1) | DE19942535A1 (es) |
| GT (1) | GT200000150A (es) |
| PL (1) | PL353088A1 (es) |
| WO (1) | WO2001018159A2 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19846991C2 (de) * | 1998-10-13 | 2003-04-24 | Bactria Industriehygiene Servi | Kettenschmiermittel für Förder- und Transportanlagen |
| DE19942534A1 (de) * | 1999-09-07 | 2001-03-08 | Henkel Ecolab Gmbh & Co Ohg | Fluorhaltige Schmiermittel |
| US7364033B2 (en) | 1999-11-17 | 2008-04-29 | Ecolab Inc. | Container, such as a food or beverage container, lubrication method |
| DE10106954A1 (de) | 2001-02-15 | 2002-09-05 | Ecolab Gmbh & Co Ohg | Schmiermittelkonzentrate auf alkoholischer Basis |
| DE10146264A1 (de) | 2001-09-20 | 2003-04-17 | Ecolab Gmbh & Co Ohg | Verwendung von O/W-Emulsionen zur Kettenschmierung |
| US7745381B2 (en) | 2005-03-15 | 2010-06-29 | Ecolab Inc. | Lubricant for conveying containers |
| US7741257B2 (en) | 2005-03-15 | 2010-06-22 | Ecolab Inc. | Dry lubricant for conveying containers |
| US7727941B2 (en) | 2005-09-22 | 2010-06-01 | Ecolab Inc. | Silicone conveyor lubricant with stoichiometric amount of an acid |
| US7915206B2 (en) | 2005-09-22 | 2011-03-29 | Ecolab | Silicone lubricant with good wetting on PET surfaces |
| JP2007169555A (ja) * | 2005-12-26 | 2007-07-05 | Daishin Kako Kk | ボトルコンベア用潤滑剤 |
| US7741255B2 (en) | 2006-06-23 | 2010-06-22 | Ecolab Inc. | Aqueous compositions useful in filling and conveying of beverage bottles wherein the compositions comprise hardness ions and have improved compatibility with pet |
| MX360111B (es) | 2010-09-24 | 2018-10-23 | Ecolab Usa Inc | Lubricantes de transportador que incluyen emulsiones y metodos para emplear los mismos. |
| MX2015012067A (es) | 2013-03-11 | 2016-01-12 | Ecolab Usa Inc | Lubricación de placas de transferencia usando un aceite o emulsiones aceite en agua. |
| US10336958B2 (en) | 2016-08-30 | 2019-07-02 | Resinate Materials Group, Inc. | Sustainable base oils for lubricants |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3755168A (en) * | 1971-12-03 | 1973-08-28 | Phillips Petroleum Co | Lubricant for extrusion of thermoplastics |
| US4162347A (en) * | 1977-12-14 | 1979-07-24 | The Dow Chemical Company | Method for facilitating transportation of particulate on a conveyor belt in a cold environment |
| DE3123726C2 (de) * | 1981-06-15 | 1985-07-25 | Ludwig Müller GmbH u. Co KG, 7100 Heilbronn | Haftöle |
| FR2520377B1 (fr) * | 1982-01-22 | 1985-09-13 | Ugine Kuhlmann | Application des amines a chaine polyfluoree comme additifs pour lubrifiants |
| JPH04314792A (ja) * | 1991-04-12 | 1992-11-05 | Nippon Oil Co Ltd | 食品機械用グリース状油脂組成物 |
| US5334322A (en) * | 1992-09-30 | 1994-08-02 | Ppg Industries, Inc. | Water dilutable chain belt lubricant for pressurizable thermoplastic containers |
| JPH06136377A (ja) * | 1992-10-22 | 1994-05-17 | Denki Kagaku Kogyo Kk | 殺菌性潤滑剤 |
| JPH06220472A (ja) * | 1993-01-29 | 1994-08-09 | Nippon Paint Co Ltd | 金属缶用表面処理剤 |
| US5352376A (en) * | 1993-02-19 | 1994-10-04 | Ecolab Inc. | Thermoplastic compatible conveyor lubricant |
| US5559087A (en) * | 1994-06-28 | 1996-09-24 | Ecolab Inc. | Thermoplastic compatible lubricant for plastic conveyor systems |
| JPH08151591A (ja) * | 1994-11-29 | 1996-06-11 | Dainippon Ink & Chem Inc | 潤滑剤組成物 |
| NZ329859A (en) * | 1996-05-31 | 1999-04-29 | Ecolab Inc | Alkyl ether amine conveyor lubricant also comprising of an acid, a stabilising hydrotrope and a surfactant |
| JPH1060465A (ja) * | 1996-08-23 | 1998-03-03 | Daicel Chem Ind Ltd | 金属缶用表面処理剤 |
| JPH11209773A (ja) * | 1998-01-29 | 1999-08-03 | Asahi Denka Kogyo Kk | コンベア用潤滑剤 |
| US5925601A (en) * | 1998-10-13 | 1999-07-20 | Ecolab Inc. | Fatty amide ethoxylate phosphate ester conveyor lubricant |
| CA2381733C (en) * | 1999-08-16 | 2009-05-12 | Ecolab Inc. | Conveyor lubricant, passivation of a thermoplastic container to stress cracking, and thermoplastic stress crack inhibitor |
-
1999
- 1999-09-07 DE DE19942535A patent/DE19942535A1/de not_active Ceased
-
2000
- 2000-08-29 BR BR0013847-9A patent/BR0013847A/pt not_active Application Discontinuation
- 2000-08-29 JP JP2001522371A patent/JP2003509536A/ja active Pending
- 2000-08-29 AU AU72807/00A patent/AU7280700A/en not_active Abandoned
- 2000-08-29 WO PCT/EP2000/008393 patent/WO2001018159A2/de active Application Filing
- 2000-08-29 CA CA002381345A patent/CA2381345C/en not_active Expired - Lifetime
- 2000-08-29 EP EP00960539A patent/EP1240281A2/de not_active Withdrawn
- 2000-08-29 PL PL00353088A patent/PL353088A1/xx unknown
- 2000-09-05 GT GT200000150A patent/GT200000150A/es unknown
- 2000-09-06 AR ARP000104650A patent/AR026158A1/es unknown
Non-Patent Citations (3)
| Title |
|---|
| "Uses of Glycerine", 1 January 1963, article THE GLYCERINE PRODUCER'S ASSOCIATION: "Uses of Glycerine", pages: 1 - 28, XP055194503 * |
| SDA: "Glycerine: an overview terms technical data properties performance The Soap and Detergent Association Glycerine", 1 January 1990 (1990-01-01), XP055442437, Retrieved from the Internet <URL:http://www.aciscience.org/docs/glycerine_-_an_overview.pdf> [retrieved on 20180118] * |
| See also references of WO0118159A3 * |
Also Published As
| Publication number | Publication date |
|---|---|
| AU7280700A (en) | 2001-04-10 |
| PL353088A1 (en) | 2003-10-06 |
| WO2001018159A3 (de) | 2001-06-07 |
| CA2381345C (en) | 2010-02-02 |
| GT200000150A (es) | 2002-02-27 |
| BR0013847A (pt) | 2002-05-14 |
| CA2381345A1 (en) | 2001-03-15 |
| JP2003509536A (ja) | 2003-03-11 |
| AR026158A1 (es) | 2003-01-29 |
| DE19942535A1 (de) | 2001-03-15 |
| WO2001018159A2 (de) | 2001-03-15 |
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