CA2381345C

CA2381345C - Use of lubricants containing polyhydroxy compounds

Info

Publication number: CA2381345C
Application number: CA002381345A
Authority: CA
Inventors: Stefan Kupper; Michael Schneider
Original assignee: Henkel Ecolab GmbH and Co KG
Current assignee: Ecolab GmbH and Co oHG
Priority date: 1999-09-07
Filing date: 2000-08-29
Publication date: 2010-02-02
Anticipated expiration: 2020-08-29
Also published as: AU7280700A; PL353088A1; WO2001018159A3; GT200000150A; BR0013847A; EP1240281A2; CA2381345A1; JP2003509536A; AR026158A1; DE19942535A1; WO2001018159A2

Abstract

The invention relates to the use of a selected polyhydroxy compound in lubricant formulations and to the use of chain lubricants containing at least 20% by weight of at least one selected polyhydroxy compound for reducing the friction between conveyor belts and the articles transported thereon. The invention also relates to a lubricant containing other additives besides the polyhydroxy compounds.

Description

USE OF LUBRICANTS CONTAINING POLYHYDROXY COMPOUNDS
This invention relates to the use of at least one selected polyhydroxy compound as a lubricating component in lubricant formulations and to the use of chain lubricants containing at least 20% by weight of at least one selected polyhydroxy compound for reducing the friction between conveyors and the articles transported thereon. The invention also relates to a lubricant containing other additives besides the polyhydroxy compounds.
I n the food industryand especially in beverage factories, the containers to be filled in the bottling plants are conveyed by conveyors differing in design and constituent materials, for example by platform conveyors or chain-like arrangements which are generally referred to hereinafter as chain conveyors.
The conveyors establish the connection between the various optional treatment stages of the bottling process such as, for example, the unpacker, bottle washer, filler, closer, labeller, packer, etc. The containers may assume various forms, more particularly glass and plastic bottles, cans, glasses, casks, beverage containers (kegs), paper and paperboard containers. To guarantee uninterrupted operation, the conveyor chains have to be suitably lubricated to avoid excessive friction with the containers. Dilute aqueous solutions containing suitable friction-reducing ingredients are normally used for lubrication. The chain conveyors are contacted with the aqueous solutions by dipping or spraying, for example, the corresponding lubrication systems being known as dip lubrication or automatic belt lubrication or central chain lubrication systems.
The chain lubricants hitherto used as lubricants are mostly based on fatty acids in the form of their water-soluble alkali metal or alkanolamine salts or on fatty amines, preferably in the form of their organic or inorganic salts.
Whereas both classes of substances can be used without difficulty in dip lubrication, they are attended by a number of disadvantages in the central chain lubrication systems typically in use today. Thus, DE-A-23 13 330 describes soap-based lubricants containing aqueous mixtures of C16_18 fatty acid salts and surface-active substances. Soap-based lubricants such as these have the following disadvantages:

2 1. They react with the hardness ions in water, i.e. the alkaline earth metal ions, and other ingredients of water to form poorly soluble metal soaps, so-called primary alkaline earth metal soaps.
2. A reaction takes place between the soap-based lubricants and carbon dioxide dissolved in water or in the product to be bottled.

3. The in-use solution thus prepared is always germ-promoting.

4. Where hard water is used, ion exchangers have to be employed to soften the water which means an additional source of germs (and is therefore hardly encountered in practice) or, alternatively, products of high complexing agent content have to be used which is ecologically unsafe.

5. Increased foaming occurs which can cause problems in particular at the bottle inspector (automatic bottle control) and results in greater wetting of the transport containers.

6. Most of these products contain solvents.

7. The cleaning effect of the products is poor so that separate cleaning is necessary.

8. Corresponding soap-based lubricant preparations show pH-dependent performance.

9. In addition, soap-based lubricant preparations are dependent on the water temperature.

10. Soap-based lubricants show poor stability in storage, particularly at low temperatures.

11. The EDTA (ethylenediamine tetraacetate) present in many products is known to have poor biodegradability.

12. Soap-based lubricant preparations are not suitable for all plastic transport containers because, in many cases, they give rise to stress cracking in the transport container.
Besides soap-based lubricants, lubricants based on fatty amines are mainly used. Thus, DE-A-36 31 953 describes a process for lubricating chain-type bottle conveyors in bottling factories, more particularly in breweries, and for cleaning the conveyors with a liquid cleaning composition, characterized in that the chain-type bottle conveyors are lubricated with belt lubricants based on neutralized primary fatty amines which preferably contain 12 to 18 carbon atoms and which have an unsaturated component of more than 10%.
EP-A-0 372 628 discloses fatty amine derivatives corresponding to the following formulae:
R' R' I I
N-A-NH2 -A-NHZ and i -A'-CO2H

in which R' is a saturated or unsaturated, branched or linear alkyl group containing 8 to 22 carbon atoms, R 2 is hydrogen, an alkyl or hydroxyalkyl group containing 1 to 4 carbon atoms or -A-NH2, A is a linear or branched alkylene group containing 1 to 8 carbon atoms and A' is a linear or branched alkylene group containing 2 to 4 carbon atoms, as lubricants.
In addition, lubricants based on N-alkylated fatty amine derivatives which contain at least one secondary and/or tertiary amine are known from DE-A-39 05 548.
DE-A-42 06 506 relates to soapless lubricants based on amphoteric compounds, primary, secondary and/or tertiary amines and/or salts of such amines corresponding to general formulae (I), (Ila), (IIb), (Illa), (IIIb), (IIIc), (IVa) and (lVb):

R' I
R-[NH-(CH2)n]m- N - R3- COOM (I) I

_ ------------___- -- -- - _ _ - _ , _-R4 -NH-R5 (Ila) R4 -N+H2 R5 X- (Ilb) R4-NH-(CH2)3NH2 (Illa) R4-NH-(CH2)3N+H3 X. (Illb) R4-N+H2 (CH2)3-N+H3 2X- (Illc) R4-NR'R8 (IVa) and/or R4-N+HR'R8 X- (lVb) in which R is a saturated or mono- or polyunsaturated, linear or branched alkyl group containing 6 to 22 carbon atoms which may optionally be substituted by -OH, -NH21 -NH-, -CO-, -(CH2CH2O)1- or -(CH2CH2CH2O); , R' is hydrogen, an alkyl group containing 1 to 4 carbon atoms, a hydroxyalkyl group containing 1 to 4 carbon atoms or a group -R3COOM, R2 is hydrogen, an alkyl group containing 1 to 4 carbon atoms or a hydroxyalkyl group containing 1 to 4 carbon atoms, but only where M
represents a negative charge, R3 is a saturated or mono- or polyunsaturated, linear or branched alkyl group containing 1 to 12 carbon atoms which may optionally be substituted by -OH, -NHz, -NH-, -CO-, -(CH2CH2O)1- or -(CH2CH2CH2O)1-, R4 is a substituted or unsubstituted, linear or branched, saturated or mono-or polyunsaturated alkyl group containing 6 to 22 carbon atoms which may contain at least one amine, imine, hydroxy, halogen and/or carboxy group as substituent, a substituted or unsubstituted phenyl group which may contain at least one amine, imine, hydroxy, halogen, carboxy and/or a linear or branched, saturated or mono- or polyunsaturated alkyl group containing 6 to 22 carbon atoms as substituent, R5 is hydrogen or - independently of R4 - has the same meaning as R4, X- is an anion from the group consisting of amidosulfonate, nitrate, halide, ~ __--sulfate, hydrogen carbonate, carbonate, phosphate or R6-COO- where R6 is hydrogen, a substituted or unsubstituted, linearor branched alkyl group containing 1 to 20 carbon atoms or alkenyl group containing 2 to 20 carbon atoms, which may contain at least one hydroxy, amine or imine 5 group as substituent, or a substituted or unsubstituted phenyl group which may contain an alkyl group with 1 to 20 carbon atoms as substituent, and R' and R$ independently of one another represent a substituted or unsub-stituted, linear or branched alkyl group containing 1 to 20 carbon atoms or alkenyl group containing 2 to 20 carbon atoms which may contain at least one hydroxy, amine or imine group as substituent, or a substituted or unsubstituted phenyl group which may contain an alkyl group with 1 to 20 carbon atoms as substituent, M is hydrogen, alkali metal, ammonium, an alkyl group containing 1 to 4 carbon atoms, a benzyl group or a negative charge, n is an integer of 1 to 12, m is an integer of 0 to 5 and I is a number of 0 to 5, containing alkyl dimethylamine oxides and/oralkyl oligoglycosides as nonionic surfactants.
EP-B-629 234 discloses a lubricant combination consisting of a) one or more compounds corresponding to the following formula:
R' -N-(CH2)n-COOM

I

in which =
R' is a saturated or mono- or polyunsaturated, linear or branched alkyl group containing 6 to 22 carbon atoms which may optionally be substituted by -OH, -NH2 ,-NH-, -CO-, halogen or a carboxyl group, R2 is a carboxyl group containing 2 to 7 carbon atoms, , _._ .. _... _. . I
. . _~ -.-M is hydrogen, alkali metal, ammonium, an alkyl group containing 1 to 4 carbon atoms or a benzyl group and n is an integer of 1 to 6, b) at least one organic carboxylic acid selected from monobasic or polybasic, saturated or mono- or polyunsaturated carboxylic acids containing 2 to 22 carbon atoms, c) optionally water and additives and/or auxiliaries.
WO 94/03562 describes a lubricant concentrate based on fatty amines and optionally typical diluents or auxiliaries and additives, characterized in that it contains at least one polyamine derivative of a fatty amine and/or a salt of such an amine, the percentage content of the polyamine derivatives of fatty amines in the formulation as a whole being from 1 to 100% by weight.
In one preferred embodiment of WO 94/03562, this lubricant concentrate contains at least one polyamine derivative of a fatty amine corresponding to the following general formula:

R-A-(CH2)k NH-[(CHZ),-NH]y-(CH2)m NHZ - (H+X')n in which R is a substituted or unsubstituted, linear or branched, saturated or mono-or polyunsaturated alkyl group containing 6 to 22 carbon atoms, the substituents being selected from amino, imino, hydroxy, halogen and carboxy, or a substituted or unsubstituted phenyl group, the substituents being selected from amino, imino, hydroxy, halogen, carboxy and a linear or branched, saturated or mono- or polyunsaturated alkyl group containing 6 to 22 carbon atoms, A represents either -NH- or -0-, X- is an anion of an inorganic or organic acid, k, I and m independently of one another are integers of 1 to 6, y is 0, 1, 2 or 3 where A = -NH- or 1, 2, 3 or 4 where A= -O- and n is an integer of 0 to 6.
Lubricants based on polytetrafluoroethylene are used in some bottling plants. They are present in the form of dispersions and are not applied to the chains in the usual way through nozzles, but instead by brushes. These lubricants have the advantage that they significantly reduce the friction between the conveyor belts and the containers transported thereon. In addition, the polytetrafluoroethylene adheres very strongly to the chains. A
disadvantage encountered in practice was that the overall hygienic state in regard to germ population and soiling of the chain conveyors was adversely affected to such an extent that the performance profile of the lubricant gradually deteriorated as a result of the increase in soiling.
Another disadvantage encountered was that the dispersions of poly-tetrafluoroethylene were not stable in storage and gradually separated. The result of this is that, over a prolonged period, varying amounts of active substance are applied to the chain conveyors.
When an attempt was made to clean the chain conveyors, it was found that the layer of lubricant was very difficult to remove from the chains.
In addition, investigation of the compatibility of polytetrafluoroethylene dispersions with plastics showed that they produce stress cracks in PET
botties.
The lubricants normally used have the disadvantage that they form a firmly adhering film on the chain conveyors which is not easy to remove simply by rinsing with water.
Residues and abrasion dust can collect in this film, leading to hygiene and operational problems.
The problem addressed by the present invention was to provide lubricants based on polyhydroxy compounds which would be hydrophilic on the basis of their molecular structure and which, at the same time, would improve lubricating performance by comparison with the amines typically used as lubricants.
The present invention relates to the use of at least one polyhydroxy compound in which, at each point of the molecular structure, there is at least one free, etherified and/or esterified hydroxy group among 10 or less covalently bonded atoms which is covalently bonded through less than 5 atoms to a second free, etherified and/or esterified hydroxy group in lubricant formulations for reducing the friction between conveyor belts and the articles transported thereon. The invention also relates to the use of chain lubricants which, based on the formulation as a whole, contain at least 20% by weight of at least one polyhydroxy compound in which, at each point of the molecular structure, there is at least one free, etherified and/or esterified hydroxy group among 10 or less covalently bonded atoms which is covalently bonded through less than 5 atoms to a second free, etherified and/or esterified hydroxy group for the transport of containers on conveyor belts. The percentage content of polyhydroxy compounds, based on the formulation as a whole, is preferably greater than 25% by weight, more preferably greater than 40% by weight and most preferably greater than 80% by weight. The use of the polyhydroxy compounds characterized in accordance with the invention leads to highly polar, highly hydrophilic lubricants. Such lubricants may therefore be used in practice without the formation of film difficult to remove from the chains. On the contrary, the film formed by the formulations to be used in accordance with the invention can easily be removed simply by rinsing with water. This has the advantage that, where corresponding formulations according to the invention are used, little if any soil collects on the chain conveyors or other surfaces coming into contact with the chain lubricant.
In one preferred embodiment of the use according to the invention, the polyhydroxy compounds comprise organic compounds containing more than 2 hydroxy groups from the groups of alcohols, including sugar alcohols and carbohydrates, phenols and natural and synthetic polymers. In a particularly preferred embodiment, the polyhydroxy compound is at least one component selected from alkanediols or alkanetriols, most preferably glycerol, or their polymers and their esters and ethers.
In another preferred embodiment of the present invention, the formulations to be used in accordance with the invention additionally contain at least one component selected from fluorine and silicone compounds, the fluorine compound in one particularly preferred embodiment being selected from the groups of a) perfluorinated or partly fluorinated monomeric organic compounds, b) pure and mixed dimers and oligomers based on at least one perfluorinated or partly fluorinated organic monomer, c) pure and mixed polymers based on at least one perfluorinated or partly fluorinated organic monomer.
According to the invention, the definition of the boundary between oligomers and polymers is based on the generally known characterization of polymers which are made up of so many identical or similar low molecular weight units (monomers) that the physical properties of these substances, particularly their viscoelasticity, do not change significantly when the number of units is increased or reduced by one unit. This is generally the case when the average molecular weight of the "polymers" is 10,000 g/mole or more.
The term oligomers is used for the low molecular weight dimers, trimers and other lower members of the polymer-homolog series.
In one preferred embodiment, the fluorine compounds a) comprise at least perfluorinated and partly fluorinated surfactants, alkanes, ethers and amines, the formulations used in accordance with the invention in one particularly preferred embodiment containing ammonium perfluoroalkyl sulfonates, lithium perfluoroalkyl sulfonates, potassium perfluoroalkyl sulfonates, amine perfluoroalkyl sulfonates, sodium perfluoroalkyl sulfonates, potassium fluoroalkyl carboxylates, quaternary fluorinated alkyl ammonium iodides, ammonium perfluoroalkyl carboxylates, fluorinated alkyl polyoxyethylene ethanols, fluorinated alkyl alkoxylates, fluorinated alkyl esters in concentrations of 0.001 to 10%. The fluorinated components of group c) are preferably perfluorinated and/or partly fluorinated alkoxy polymers which, in one particularly preferred embodiment, are obtainable from the copolymerization of tetrafluoroethylene and perfluoroalkoxyvinyl ethers.

In another preferred embodiment, the formulations to be used in accordance with the invention contain at least perfluorinated and/or partly fluorinated polyethers from group c).
The silicone compounds present in a preferred embodiment of the formulations to be used in accordance with the invention are preferably selected from polysiloxanes and more preferably from the groups 5 of linear, branched, cyclic and crosslinked polysiloxanes.
In another preferred embodiment, the formulations to be used in accordance with the invention are present in the form of one-component liquids, solutions, gels, emulsions, pastes, dispersions.
In one preferred embodiment, the formulations to be used in 10 accordance with the invention additionally contain at least one antimicrobial component selected from the groups of alcohols, aldehydes, antimicrobial acids, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenyl alkanes, urea derivatives, oxygen and nitrogen acetals and formals, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibrorno-2,4-dicyanobutane, iodo-2-propynyl butyl carbamate, iodine, iodophors, peroxides, the formulations to be used in accordance with the invention in one particularly preferred embodiment containing one or more compounds selected from ethanol, n-propanol, i-propanol, butane-1,3-diol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, citric acid, 2-benzyl-4-chlorophenol, 2,2'-methylene-bis-(6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N-(4-chlorophenyl)-N-(3,4-dichlorophenyl)-urea, N,N'-(1,10-decanediyldi-l-pyridinyl-4-ylidene)-bis-(1-octaneamine)-dihydrochloride, N,N'-bis-(4-chlorophenyl)-3,12-diimino-2,4,1 1,13-tetraazatetradecane diimidoamide, quaternary ammonium compounds oralkyl amines, guanidines, amphoteric surfactants as antimicrobial components.
In another preferred embodiment, the formulations to be used in accordance with the invention contain other components selected from the groups of surfactants and solubilizing agents, at least one alkyl polyglycoside being present as surfactant in a particularly preferred embodiment. Other preferred constituents are fatty alkylamines and/or alkoxylates thereof, more particularly cocofatty amine ethoxylates, and/or imidazoline compounds and/or amphoteric surfactants and/or nonionic surfactants and/or ether carboxylic acids and/or ether amine compounds. In another preferred embodiment, paraffin compounds are added to the formulations to be used in accordance with the invention.
In practice, the formulations to be used in accordance with the invention are applied to the chain conveyors. In the most favorable case, the transport of the containers on the conveyors is not accompanied by foaming.
By comparison with conventional lubricants which are diluted with water by a factor of more than 100 in automatic conveyor installations, the formulations to be used in accordance with the invention reduce frictional resistance between the conveyor and the containers transported thereon by more than 20% by for the same quantities by weight of active lubricating components applied to the conveyor installation over a certain period of time. This is demonstrated by the following Examples.

Example I
A comparison formulation 1 which contains 5% by weight of coconut propylenediamine and which is adjusted to pH 7 with acetic acid is applied to the chain conveyors in a concentration in water of 0.2% through a nozzle block comprising five nozzles each capable of spraying 5 liters per hour. 50 ml of the comparison formulation or ca. 2.5 g of the coconut propylenedi-amine are thus applied to the conveyor chains over a period of 1 hour. This test is carried out for 10 hours. According to the invention, the coefficient of friction between the bottles and the stainless steel conveyor chains is defined as the ratio of the tractive weight applied, for example, to a spring balance when an attempt is made to hold a bottle still while the conveyor is moving to the weight of that bottle.
Where the Comparison Example described above is used, the coefficient of friction p is 0.10. When spraying is stopped, the friction coefficient increases rapidly and the botties fall over after only a few minutes.

In the Comparison Example, a total of 25 ml of lubricating coconut pro-pylenediamine raw materials is applied to the conveyor chains over the total test duration of 10 hours. In a second test, 25 ml of a formulation to be used in accordance with the invention consisting of pure glycerol is distributed over the chain conveyors with a cloth. The coefficient of friction between the bottles and the chain conveyor is then measured over a period of 10 hours under exactly the same conditions as in Comparison Example 1. The coefficient of friction p is about 0.05 over the entire test duration of 10 hours.
This Example shows that the friction coefficient between the bottles and the conveyor system can be reduced by more than 20% and, in the present case, even by more than 40%.
Another preferred embodiment of the present invention is the use of the formulations to be used in accordance with the invention forthe conveying of plastic containers, the plastic containers in one particularly preferred embodiment containing at least one polymer selected from the groups of polyethylene terephthalates (PET), polyethylene naphthenates (PEN), polycarbonates (PC), PVC. In one most particularly preferred embodiment, the containers are PET bottles.

Example 2 In a laboratory test, the stress cracking of a Comparison Example based on 5% by weight coconut propylene diamine and 5% by weight dimethyl lauryl amine adjusted to pH 7 with acetic acid is measured by comparison with the stress cracking of pure glycerol.
According to the test specification, PET bottles are filled with water and conditioned with carbon dioxide in such a way that a pressure of about 7 bar is present inside the bottles. The base cups of the bottles are then dipped in the formulation of the Comparison Example and the Example to be used in accordance with the invention and are placed in a Petri dish for 24 hours.
Thereafter the bottles are opened, emptied and their base cups are rinsed with water. Visual inspection of the base cups of the bottles shows that, in the test with the Comparison Example, many stress cracks of average depth

13 (classification C) are present whereas the test with the Example to be used in accordance with the invention produces only a few stress cracks of minimal depth (classification A). The stress cracks are classified in accordance with the reference images appearing in Chapter IV-22 of the book entitled "CODE
OF PRACTICE - Guidelines for an Industrial Code of Practice for Refillable PET Bottles", Edition 1, 1993-1994.
Example 2 shows that the formulations to be used in accordance with the invention have advantages overtypical commercial amine-based products used as lubricants in the conveying of plastic bottles.
In another preferred embodiment, the formulations to be used in accordance with the invention are used for conveying paperboard packs.
In another preferred use, the conveying surfaces of the conveyor belts are made of plastic - in one particularly preferred embodiment of polyacetal and polyethylene.
In another preferred embodiment, the conveying surfaces of the conveyor belt are made of metal - in one particularly preferred embodiment stainless steel.
In another preferred embodiment, additional antimicrobial agents, more particularly organic peracids, chlorine dioxide or ozone, are additionally incorporated in the formulations to be used in accordance with the invention through separate feed systems either before or after application of the formulations.
In another preferred embodiment, the formulations to be used in accordance with the invention are applied to the conveyor belts without dilution with water using an aid selected from paint brushes, sponges, rollers, cloths, brushes, wipers, rubber, spray nozzles. In another preferred embodiment, the formulations to be used in accordance with the invention are diluted with water in automatic conveyor systems and the resulting solution is applied to the conveyors through metering systems, the dilution factor being between 10,000 and 100. In another preferred embodiment, the formulations to be used in accordance with the invention are selected and applied in such

14 a way that there is no further proliferation of microorganisms on surfaces in contact with the formulations or solution. In one most particularly preferred embodiment, the number of microorganisms is reduced.
The formulations to be used in accordance with the invention are preferably used for the conveying of containers in the food industry.
In a preferred embodiment of the use according to the invention, the bottom of the plastic bottles is rinsed with water before the plastic botties leave the bottling plant.
By virtue of the hydrophilic properties of the formulations to be used in accordance with the invention, a large part of the lubricant residues adhering to the bottoms of the plastic bottles can be removed simply by rinsing with water. As a result, the plastic bottles finding their way onto the market have hardly any residues of chemicals. This aspect is important because, in many cases, it is some time before the chemical attack on the polymeric beverage bottle material leads to a visible attack or even to destruction of the beverage bottles. If, therefore, lubricant residues adhere to the bottoms of the plastic bottles, the polymeric material is not adversely affected through the long-term contact.
For example, the chain lubricants hitherto normally used adhere fairly strongly to PET bottles in view of their surfactant or hydrophobic character and cannot be adequately removed even by rinsing with water.
The chemical attack is intensified if there is an increase in pressure inside the bottles, for example caused by summer temperatures during storage or in transit, so that the bottle material is placed under high stress.
Depending on turnover cycles, the beverage bottles can remain on sale for up to several months before they are returned to the bottling plant.
The advantage of the formulations to be used in accordance with the invention is that they are easy to rinse off and can be removed by a final rinse with water.
Another advantage of the polyhydroxy compounds is that they are readily biodegradable compared with most of the compounds typically used as lubricants.

The present invention also relates to chain lubricants which, based on the formulation as a whole, contain at least 20% by weight, preferably more than 40% by weight and more preferably more than 80% by weight of at least one polyhydroxy compound in which, at each point of the molecular structure, 5 there is at least one free, etherified and/or esterified hydroxy group among or less covalently bonded atoms which is covalently bonded through less than 5 atoms to a second free, etherified and/or esterified hydroxy group.

15

Claims

1. The use of a lubricant composition comprising at least one organic compound selected from alkane triols, and polymers and esters thereof, and a silicone compound selected from the group of linear, branched, cyclic and cross linked polysiloxanes, for reducing the friction between automatic conveyor belts and the articles transported thereon.

2. The use claimed in claim 1, characterized in that the percentage content of the at least one organic compound, based on the composition as a whole, is at least 20% by weight.

3. The use claimed in claim 1 or 2, characterized in that the percentage content of the at least one organic compound, based on the composition as a whole, is greater than 25% by weight.

4. The use claimed in claim 1 or 2, characterized in that the percentage content of the at least one organic compound, based on the composition as a whole, is greater than 40% by weight.

5. The use claimed in claim 1 or 2, characterized in that the percentage content of the at least one organic compound, based on the composition as a whole, is greater than 80% by weight.

6. The use claimed in any one of claims 1 to 5, characterized in that at least one glycerol is present as the at least one organic compound in the composition.

7. The use claimed in any one of claims 1 to 6, characterized in that at least one fluorine compound is additionally present in the composition.

8. The use claimed in claim 7, characterized in that the fluorine compound is selected from the group of a) perfluorinated or partly fluorinated monomeric organic compounds, b) pure and mixed dimers and oligomers based on at least one perfluorinated or partly fluorinated organic monomer, and c) pure and mixed polymers based on at least one perfluorinated or partly fluorinated organic monomer.

9. The use claimed in any one of claims 1 to 8, characterized in that the compositions are present in the form of a liquid, solution, gel, emulsion, paste or dispersion.

10. The use claimed in any one of claims 1 to 9, characterized in that the compositions additionally contain at least one antimicrobial agent selected from the group of alcohols, aldehydes, antimicrobial acids, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenyl alkanes, urea derivatives, oxygen and nitrogen acetals and formals, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynyl butyl carbamate, iodine, iodophors, and peroxides.

11. The use claimed in claim 10, characterized in that the compositions contain one or more compounds selected from ethanol, n-propanol, i-propanol, phenoxyethanol, undecylenic acid, citric acid, 2-benzyl-4-chlorophenol, 2,2'-methylene-bis-(6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N-(4-chlorophenyl)-N-(3,4-dichlorophenyl)-urea, N,N'-(1,10-decanediyldi-l-pyridinyl-4-ylidene)-bis-(1-octaneamine)-dihydro-chloride, N,N'-bis-(4-chlorophenyl)-3,12-diimino-2,4,11,13-tetraazatetradecane diimidoamide, quaternary ammonium compounds or alkyl amines, guanidines, and amphoteric surfactants as antimicrobial agents.

12. The use claimed in any one of claims 1 to 11, characterized in that the compositions contain at least one additional component selected from the group of surfactants and solubilizing agents.

13. The use claimed in any one of claims 1 to 12 for the conveying of plastic containers.

14. The use claimed in claim 13, characterized in that the plastic containers contain at least one polymer selected from the group of polyethylene terephthalates (PET), polyethylene naphthenates (PEN), polycarbonates (PC), and PVC.

15. The use claimed in claim 14, characterized in that the plastic containers are PET bottles.

16. The use claimed in any one of claims 1 to 12 for the conveying of paperboard packs.

17. The use claimed in any one of claims 1 to 16, characterized in that the conveying surfaces of the conveyor belt installation are made of plastic.

18. The use claimed in any one of claims 1 to 16, characterized in that the conveying surfaces of the conveyor belt installation are made of metal.

19. The use claimed in any one of claims 1 to 18, characterized in that at least one antimicrobial agent is separately added during application of the composition.

20. The use claimed in claim 19, characterized in that an organic peracid, chlorine dioxide or ozone is used as the antimicrobial agent.

21. The use claimed in any one of claims 1 to 20, characterized in that the application of the compositions to the conveyor belts occurs without preliminary dilution with water, through use of an aid selected from paint brushes, sponges, rollers, cloths, wipers, rubber and spray units.

22. The use claimed in any one of claims 1 to 20, characterized in that the compositions are diluted with water in automatic conveyor belt installations and the application of the resulting solution to the conveyor belts occurs through metering systems.

23. The use claimed in claim 22, characterized in that the dilution factor is between 10,000 and 100.

24. The use claimed in any one of claims 1 to 23 for the conveying of containers in the food industry.

25. The use claimed in any one of claims 1 to 24, characterized in that rinsing of the bottoms of plastic bottles with water occurs before the plastic bottles leave the bottling factory.