EP1236403A2 - Vorrichtung und Verfahren zum Herstellen von Partikeln aus einer Lebensmittel-Masse, insbesondere einer Schokoladenmasse - Google Patents
Vorrichtung und Verfahren zum Herstellen von Partikeln aus einer Lebensmittel-Masse, insbesondere einer Schokoladenmasse Download PDFInfo
- Publication number
- EP1236403A2 EP1236403A2 EP02003359A EP02003359A EP1236403A2 EP 1236403 A2 EP1236403 A2 EP 1236403A2 EP 02003359 A EP02003359 A EP 02003359A EP 02003359 A EP02003359 A EP 02003359A EP 1236403 A2 EP1236403 A2 EP 1236403A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- contact surface
- cooled
- particles
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/04—Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
- A23G1/042—Manufacture or treatment of liquids, creams, pastes, granules, shreds or powders
- A23G1/047—Transformation of liquids, pastes, creams, lumps, powders, granules or shreds into powders, granules or shreds; Manufacture or treatment of powders
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G7/00—Other apparatus or process specially adapted for the chocolate or confectionery industry
- A23G7/02—Cooling or drying apparatus
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/20—Agglomerating; Granulating; Tabletting
Definitions
- the invention relates to an apparatus and a method for producing Particles from a food mass, in particular a chocolate mass, the Art explained in the preambles of claims 1 and 14.
- a device and a method of this type are known from EP 976 333.
- the known device contains a downpipe arranged with a vertical central axis, in the upper area a dropletizer for the flowable chocolate mass is arranged.
- the dropping device contains a cross section of the downpipe essentially covering the nozzle assembly from a large number of individual Droplet nozzles from which mass drops emerge and through in free fall the downpipe fall.
- the nozzle stick is heated to prevent the chocolate mass becomes solid during the droplet and clogs the nozzles.
- As the only one Coolant is a cooled gas, preferably nitrogen.
- the nitrogen should have a temperature of at least - 60 ° C, preferably - 160 ° C when discharging and - 80 ° C when leaving the downpipe.
- the shape of the particles to be produced should vary , this has to be done in a rather cumbersome way by an appropriate changed gas flow of the coolant happen to a certain, to the desired Result to produce leading turbulence of the gas. That turbulence is preferably achieved by a tangential confluence of the gas, whereby a Swirl component to be generated in the pipe flow; so through a constructive completely different solution that requires its own downpipe.
- the invention is therefore based on the object of an apparatus and a method provide with which in a constructively and procedurally simple manner Particles made from a food mass, in particular a chocolate mass can be.
- the object is achieved by a device according to claim 1 and a method according to Claim 14 solved.
- the contact surface is preferably the rotating peripheral surface driven cooling roller, but it would also be conceivable, for example a Shake slide to use, or a movable nozzle over a fixed To move the contact surface.
- Claim 4 describes a structurally particularly simple device, the Mass droplets reach the contact surface under the influence of gravity.
- the invention is particularly suitable for the production of sterile particles as they are microbially sensitive products, such as dairy products, are added, since both the nozzle and the contact surface according to claim 7 together in one can be housed sterile to keep shaping container, according to claims 8 to 10 can be further developed.
- EP 974 275 describes a method for sterilizing food masses, especially chocolate, known, but there is no way described to form particles from this mass without contamination.
- the mass, especially chocolate is solidified into a process brought closed double jacket pressure vessel, and there with the help of the jacket heater heated to about 80 ° C until the mass is flowable. Then there is direct steam initiated by which the mass brought to a sterilization temperature of 125 ° C. becomes.
- the jacket heating remains active, but is more likely to avoid heat loss.
- the sterilization pressure is about 3 bar, absolute.
- the mass is over a predetermined Time kept at the elevated temperature and then a vacuum applied to the undesired by the steam introduced into the mass Evaporate water and cool the chocolate to approx. 60 ° C.
- the flowable Chocolate is then pumped into a storage tank. Further processing is not described. Heating the mass to sterilization temperature below
- using direct steam has the disadvantage, as does the description
- the known method can be seen that the mass is disproportionate a lot of water is introduced, which is particularly undesirable for chocolate is and must be removed again, which complicates the procedure leads.
- the sterilization device arranged between a melting device and the shaping container, so that the mass is already homogeneously flowable and easy to mix into the sterilization device arrives.
- the sterilization device expediently contains a container with a heatable and coolable double jacket, so that the mass by direct Contact with the heated double jacket brought to the sterilization temperature and / or by direct contact with the cooled double jacket from the sterilization temperature can be cooled to the further processing temperature.
- a heatable stacking tank which is sufficient Stock of flowable mass for loading the intermittent sterilization device can provide.
- the invention further relates to a method according to claim 14 and further developments of the method according to claims 15 to 21.
- Fig. 1 shows a schematic representation of the most important components of a device 1 for producing particles from a food mass and in particular a device for producing sterile particles from this food mass.
- the food mass can be any mass at an eating temperature, is solid especially at room temperature and by increasing the temperature can be melted in a flowable manner, in particular masses containing cocoa or Mixtures containing cocoa components, preferably chocolate compounds.
- the device 1 contains one in the direction of increasing processing of the masses Heating device 2, in which the mass is heated so far that it is flowable with chocolate masses, the temperature required for this is between about 40 ° C and about 80 ° C.
- the heater need not necessarily be in the process line integrated - the mass can already be processed by a supplier to be delivered.
- This flowable, heated mass is via a pipe 3 passed into a stacking tank 4, which is insulated and provided with its own heating is. In this stacking tank 4, the mass is in a flowable state, i.e. between 40 ° C and 80 ° C, preferably 60 ° C, with chocolate mass.
- the sterilization device 7 contains a double-walled, pressure-tight and closed Container 8, the double wall with a heating circuit 9 for a heating medium, in particular steam or superheated water, and a cooling circuit 10 for one Cooling medium, especially cold water, is connected.
- a gas line 12 provided with a pump 11, via the sterile and / or inert gas, such as sterile air or nitrogen, in the upper Area of the container 8 can be initiated, and via the pump 11 a vacuum can be generated in the container 8.
- one of the usual mixing mechanisms 14 is arranged, which in is able to continuously circulate the entire mass located in the container 8 and especially against excessive exposure to the heated To protect the container wall.
- the mixer 14 is preferably an agitator with an associated Scraper trained.
- the flowable mass is pump 6 through line 5 and the shut-off device 5a is conveyed into the container 8 in a predetermined amount.
- the mixing device 14 runs and the wall of the container 8 is via the steam circuit 9 heated to a temperature that the mass inside the container 8 to a Sterilization temperature between about 110 ° C and about 140 ° C to kill all viable Can heat germs.
- Via the line 12 and the pump 11 Mass in the container 8 covered with sterile air or nitrogen, so that a pressure of about 2.5 bar.
- the mass in the container 8 has a temperature of about 100 ° C, so that essential condensation can no longer be expected must, additional steam can be added via line 13 to the Increase mortality.
- the container is placed under vacuum becomes.
- the container is cooled down so far that the mass inside the Container assumes a temperature at which it is just still flowable, with chocolate mass this is about 20 ° C to about 40 ° C.
- the mass is on kept at this temperature, again by supplying a heating medium to the Heating circuit 9, optionally mixed with a cooling medium via the cooling circuit 10th
- sterilization can also be done by heating the mass is made using microwave or radio frequency technology, as is known in itself.
- double jacket other known ones can also be used Heat exchangers, such as scraping or shell-and-tube heat exchangers, can be used, with uniform heating must be ensured without that the food is broken down into its components. The heating in tubes with sufficient turbulence by suitable mixers or a high Pump performance gives the best results. Even if the mass is heated by other heat sources, cooling can still be done by the double jacket of the container 8 take place.
- the sterilization container 8 is via a double-walled, heated output line 15, in which a suitable shut-off device 15a and optionally a pump 16 are arranged, connected to a shaping device 17.
- the output line 15 is supplied with a heating medium via a heating circuit 18, so that the Mass in the output line 15 at the desired temperature at which the mass is just flowable, can be held, i.e. for chocolate masses between about 25 ° C to about 30 ° C.
- the shaping device 17 is explained in more detail below with reference to FIG. 2 and also contains a closed container 18 in which a dropping device 19 and a vertically aligned and spaced below, horizontally aligned Cooling roller 20 are arranged.
- the cooling roller 20 is driven by a motor 21 a drive shaft 21a is rotatably driven and has a coolant circuit 22 for cooling brine in connection.
- a shut-off device 23 In the lower area of the container 18 is a shut-off device 23 a coolable drain line 24 connected via a further Shut-off device 25 with an only indicated reservoir 26 for the Chocolate particle is related.
- the shut-off devices 23 and 25 act as a lock to maintain sterile conditions in container 18.
- the molding container 18 contains an upper, cylindrical region 18a and a funnel-shaped one lying below in the direction of the flow of gravity Area 18b.
- the dropping device is in the upper, cylindrical region 18a 19 arranged, which contains at least one nozzle 19a.
- the dropping device is preferred 19 designed as a heatable nozzle and contains a variety of each other at preferably the same distance from nozzles that are on the same horizontal Plane and preferably in parallel to each other and to the drive shaft 21a Rows arranged side by side and aligned with the apex line of the cooling roller 20 are.
- the cooling roller 20 is through the drive shaft 21a of the motor 21 in the direction of the arrow A rotating and can be driven with adjustable speed.
- the drive shaft 21a extends is sterile through the container wall and is over sliding shaft seals and Condensate locks are stored on the container wall, so that aseptic conditions given are.
- the drive contains a frequency converter, which together with the Cooling roller 20 is preassembled on a flange and for fine-tuning the roller rotation on the rate of constipation.
- the drive shaft 21a is arranged so that the peripheral surface 20a is at the apex of the cooling roller 20 at a distance B below the droplet nozzle 19a 19 is arranged.
- the distance B thus determines the smallest free one Fall path, which the those emerging from the nozzles 19a or pressed out under pressure Drops of mass 27a have to cover before they reach the contact surface formed circumferential surface 20a of the cooling roller 20 impinge.
- the cooling roller 20 is a stripping device 28 in the form of a scraper or the like assigned to the solidified drops of mass from the contact surface 20a strips and as solid particles 27b in the funnel-shaped as a storage area Part 18b of the container 18 drops.
- the distance B between the contact surface 20a and the nozzle 19 can be adjusted, preferably via an adjustable flange 29, which the dropletizer 19 holds on the container 18.
- the roller 20 is cooling brine via the coolant circuit 22 shown in FIG. 1 from - 20 ° C via the hollow drive shaft 21a to and on the motor side dissipated again.
- the coolant circuit 22 is still a line 22a the line 24 and via a line 22b the funnel-shaped forming the storage area Part 18b of the shaping container 18 connected.
- the cylindrical Part 18a of the shaping container 18 opens a further coolant line 30, about the coolant at a relatively low temperature, preferably nitrogen, in the molding container 18 can be inserted to accelerate the cooling, to achieve complete cooling of the particles and heating to avoid.
- the coolant line 30 extends in the form of a type of cooling lance with a large number of outlet openings parallel to the drive shaft 21 a and laterally below the cooling roller 20 into the container 18 and over the entire axial Length of the cooling roll 20.
- the first shut-off device 23 can be closed again before the second shut-off device 25 opens is so that the shut-off devices 23 and 25 act as a kind of lock that keep the inside of the molding container 18 aseptic.
- the finished particles can then be kept in stock in a suitable storage container 26.
- Steam lines can be used with all components of the device according to the invention or the like. To sterilize the entire system from time to time can.
- both the coolant and the heating means is always circulated in order to save energy in this way.
- the Shaping device also used for processing non-sterilized masses become.
- the contact surface can be designed as a vibrating slide or the like.
- the storage area in the lower part of the shaping container can be omitted, in particular if continuous removal of the solid particles is guaranteed.
- the temperatures can be processed depending on the properties and sensitivity of the processed Masses can be selected.
- the special coolants and heating agents can also to be replaced by others.
- the slide shown in the drawings other suitable shut-off devices can be used, in particular the shut-off device closing the shaping container can be a metering valve his. Instead of over a drop distance, the mass drops can also fall on one, if necessary also vertically arranged, contact surface are sprayed.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Confectionery (AREA)
- Formation And Processing Of Food Products (AREA)
Abstract
Description
- Fig. 1
- eine schematische Darstellung einer erfindungsgemäßen Vorrichtung zur Durchführung des erfindungsgemäßen Verfahrens, und
- Fig. 2
- eine schematische, vergrößerte Darstellung eines Formgebungsbehälters.
Claims (21)
- Vorrichtung (1) zum Herstellen von Partikeln (27b) aus einer Lebensmittel-Masse, insbesondere einer Schokoladenmasse, mit einer Schmelzeinrichtung (2) zum Erwärmen der Masse bis zur Fließfähigkeit und einer Formgebungseinrichtung (17), die wenigstens eine Düse (19a) zum Vertropfen der fließfähigen Masse sowie eine Kühlung (20) zum Verfestigen der Massetropfen (27a) in Partikelform (27b) enthält, dadurch gekennzeichnet, dass die Kühlung eine relativ zur Düse (19a) bewegbare, gekühlte Kontaktfläche (20a) enthält.
- Vorrichtung nach Anspruch 1, dadurch gekennzeichnet, dass die Kontaktfläche (20a) die Umfangsfläche einer rotierend angetriebenen Kühlwalze (20) ist.
- Vorrichtung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der sich bewegenden Kontaktfläche (20a) eine Abstreifeinrichtung (28) zum Lösen der Partikel (27b) von der Kontaktfläche (20a) zugeordnet ist.
- Vorrichtung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Düse (19a) im Wesentlichen senkrecht und in einem Abstand (B) oberhalb der gekühlten Kontaktfläche (20a) angeordnet ist.
- Vorrichtung nach Anspruch 4, dadurch gekennzeichnet, dass der Abstand (B) zwischen der Düse (19a) und der Kontaktfläche (20a) verstellbar ist.
- Vorrichtung nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Kühlung zusätzlich ein gasförmiges Kühlmittel enthält.
- Vorrichtung nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass zum Herstellen von sterilen Partikeln (27b) ein Formgebungsbehälter (18) vorgesehen ist, in dem die Düse (19a) und die Kontaktfläche (20a) angeordnet sind.
- Vorrichtung nach Anspruch 7, dadurch gekennzeichnet, dass der Formgebungsbehälter (18) einen Lagerbereich (18b) für die Partikel (27b) enthält.
- Vorrichtung nach Anspruch 8, dadurch gekennzeichnet, dass der Lagerbereich (18b) kühlbar ist.
- Vorrichtung nach einem der Ansprüche 7 bis 9, dadurch gekennzeichnet, dass der Formgebungsbehälter (18) eine gekühlte und mit einer Schleuse (23, 25) versehene Ausgabeleitung (24) für die Partikel (27b) aufweist.
- Vorrichtung nach einem der Ansprüche 7 bis 10, dadurch gekennzeichnet, dass zwischen der Schmelzeinrichtung (2) und dem Formgebungsbehälter (18) eine Sterilisierungseinrichtung (7) angeordnet ist.
- Vorrichtung nach Anspruch 11, dadurch gekennzeichnet, dass die Sterilisierungseinrichtung (7) einen Behälter (8) mit einem als Wärmetauscher ausgebildeten Doppelmantel aufweist.
- Vorrichtung nach Anspruch 11 oder 12, dadurch gekennzeichnet, dass zwischen der Schmelzeinrichtung (2) und der Sterilisierungseinrichtung (7) ein beheizbarer Stapeltank (3) zum Zwischenspeichern von fließfähiger Masse angeordnet ist.
- Verfahren zum Herstellen von Partikeln (27b) aus einer Lebensmittel-Masse, insbesondere einer Schokoladenmasse, wobei die Masse bis zur Fließfähigkeit erwärmt, vertropft und in Partikelform abgekühlt wird, dadurch gekennzeichnet, dass die Massetropfen (27a) zum Abkühlen auf eine gekühlte, sich relativ zu den Massetropfen (27a) bewegende Kontaktfläche (20a) aufgebracht werden.
- Verfahren nach Anspruch 14, dadurch gekennzeichnet, dass die Massetropfen (27a) durch freien Fall auf die Kontaktfläche (20a) aufgebracht werden, und dass die Länge der Fallstrecke verändert werden kann.
- Verfahren nach Anspruch 14 oder 15, dadurch gekennzeichnet, dass die Massetropfen (27a) zusätzlich durch ein gasförmiges Kühlmedium gekühlt werden.
- Verfahren nach einem der Ansprüche 14 bis 16, dadurch gekennzeichnet, dass zum Herstellen steriler Partikel (27b) die Masse zunächst sterilisiert und anschließend in einem geschlossenen Raum (18) vertropft und gekühlt wird.
- Verfahren nach Anspruch 17, dadurch gekennzeichnet, dass die Masse durch Aufheizen an einer beheizten Fläche auf Sterilisationstemperatur gebracht wird.
- Verfahren nach Anspruch 18, dadurch gekennzeichnet, dass die Masse beim Sterilisieren mit einem sterilen Gas unter erhöhtem Druck überschichtet wird.
- Verfahren nach Anspruch 18 oder 19, dadurch gekennzeichnet, dass zum Sterilisieren zusätzlich Dampf in die Masse eingebracht wird, sobald die Masse eine vorbestimmte, erhöhte Temperatur, bevorzugt etwa 100°C, erreicht hat.
- Verfahren nach einem der Ansprüche 14 bis 20, gekennzeichnet durch eine mehrstufige Temperaturführung, wobei die Masse zunächst bis zur Fließfähigkeit erwärmt, bei einer Schokoladenmasse auf etwa 40°C bis etwa 80°C, dann zur Sterilisierung gefördert, anschließend auf Sterilisierungstemperatur erhitzt, bevorzugt zwischen etwa 110°C bis etwa 140°C, anschließend bis auf eine noch fließfähige Temperatur gekühlt, bei Schokoladenmasse auf etwa 20°C bis etwa 40°C, und bei dieser Temperatur zum Vertropfen gefördert wird.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10107124A DE10107124A1 (de) | 2001-02-15 | 2001-02-15 | Vorrichtung und Verfahren zum Herstellen von Partikeln aus einer Lebensmittel-Masse, insbesondere einer Schokoladenmasse |
| DE10107124 | 2001-02-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1236403A2 true EP1236403A2 (de) | 2002-09-04 |
| EP1236403A3 EP1236403A3 (de) | 2005-06-15 |
Family
ID=7674192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02003359A Withdrawn EP1236403A3 (de) | 2001-02-15 | 2002-02-13 | Vorrichtung und Verfahren zum Herstellen von Partikeln aus einer Lebensmittel-Masse, insbesondere einer Schokoladenmasse |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20020197387A1 (de) |
| EP (1) | EP1236403A3 (de) |
| JP (1) | JP2002262774A (de) |
| CN (1) | CN1375211A (de) |
| BG (1) | BG106409A (de) |
| CA (1) | CA2371834A1 (de) |
| CZ (1) | CZ2002567A3 (de) |
| DE (1) | DE10107124A1 (de) |
| HK (1) | HK1048921A1 (de) |
| HR (1) | HRP20020132A2 (de) |
| HU (1) | HUP0200568A3 (de) |
| RU (1) | RU2222202C2 (de) |
| SK (1) | SK2322002A3 (de) |
| TR (1) | TR200200437A2 (de) |
| YU (1) | YU10102A (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT503031B1 (de) * | 2006-12-13 | 2007-07-15 | Agrana Beteiligungs Ag | Verfahren zur verringerung der keimzahl in einer schokolademasse |
| JP6013203B2 (ja) * | 2013-01-15 | 2016-10-25 | 株式会社愛産製作所 | 吐出装置 |
| CN104843623A (zh) * | 2015-05-18 | 2015-08-19 | 辽宁惠智科技有限公司 | 流体食品低温恒温控制远程输送装置及其方法 |
| DE102017000439A1 (de) | 2017-01-19 | 2018-07-19 | Hassia Verpackungsmaschinen Gmbh | Füllvorrichtung zum Abfüllen eines flüssigen und/oder pastösen Produktes |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT263515B (de) * | 1965-08-27 | 1968-07-25 | Eurefta Fa | Verfahren und Vorrichtung zur Überführung von Fetten und Fett-Ölmischungen in eine kristalline, feinpulverige Struktur |
| US3605644A (en) * | 1969-02-18 | 1971-09-20 | Thurman S Inc | Chocolate drop making machine |
| GB8802142D0 (en) * | 1988-02-01 | 1988-03-02 | Air Prod & Chem | Method of freezing liquid & pasty products & freezer for carrying out said method |
| GB2249934B (en) * | 1990-11-22 | 1994-08-24 | Coryell Limited | A process for producing a starch jelly confectionery product |
| EP0998854B1 (de) * | 1998-02-11 | 2003-05-07 | Transucrania, S.A. | Verfahren und vorrichtung zur herstellung von granulatprodukten |
| US6000229A (en) * | 1998-04-24 | 1999-12-14 | Dippin' Dots, Inc. | Cryogenic processor for liquid feed preparation of a free-flowing frozen product and method for freezing liquid composition |
| DE19832415A1 (de) * | 1998-07-18 | 2000-01-27 | Franz Zentis Gmbh & Co Kg | Verfahren zur Sterilisation |
| DE19834064A1 (de) * | 1998-07-29 | 2000-02-03 | Zentis Gmbh & Co Franz | Verfahren und Vorrichtung zur Herstellung von Partikeln eines Lebensmittels |
-
2001
- 2001-02-15 DE DE10107124A patent/DE10107124A1/de not_active Ceased
-
2002
- 2002-02-10 CN CN02105846A patent/CN1375211A/zh active Pending
- 2002-02-13 BG BG106409A patent/BG106409A/bg unknown
- 2002-02-13 HR HR20020132A patent/HRP20020132A2/hr not_active Application Discontinuation
- 2002-02-13 EP EP02003359A patent/EP1236403A3/de not_active Withdrawn
- 2002-02-14 CZ CZ2002567A patent/CZ2002567A3/cs unknown
- 2002-02-14 RU RU2002103619/13A patent/RU2222202C2/ru not_active IP Right Cessation
- 2002-02-14 SK SK232-2002A patent/SK2322002A3/sk not_active Application Discontinuation
- 2002-02-14 CA CA002371834A patent/CA2371834A1/en not_active Abandoned
- 2002-02-14 YU YU10102A patent/YU10102A/sh unknown
- 2002-02-14 HU HU0200568A patent/HUP0200568A3/hu unknown
- 2002-02-15 JP JP2002037969A patent/JP2002262774A/ja not_active Withdrawn
- 2002-02-15 US US10/076,988 patent/US20020197387A1/en not_active Abandoned
- 2002-02-15 TR TR2002/00437A patent/TR200200437A2/xx unknown
-
2003
- 2003-02-18 HK HK03101213.6A patent/HK1048921A1/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2222202C2 (ru) | 2004-01-27 |
| US20020197387A1 (en) | 2002-12-26 |
| SK2322002A3 (en) | 2002-09-10 |
| HUP0200568A3 (en) | 2004-12-28 |
| DE10107124A1 (de) | 2002-09-12 |
| CN1375211A (zh) | 2002-10-23 |
| CA2371834A1 (en) | 2002-08-15 |
| CZ2002567A3 (cs) | 2002-10-16 |
| YU10102A (sh) | 2004-09-03 |
| HK1048921A1 (zh) | 2003-04-25 |
| BG106409A (bg) | 2003-08-29 |
| EP1236403A3 (de) | 2005-06-15 |
| HUP0200568A2 (en) | 2002-09-28 |
| JP2002262774A (ja) | 2002-09-17 |
| HU0200568D0 (en) | 2002-04-29 |
| TR200200437A2 (tr) | 2002-09-23 |
| HRP20020132A2 (en) | 2002-12-31 |
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