EP1196258B1 - Dispositif de purification d'acier fondu - Google Patents
Dispositif de purification d'acier fondu Download PDFInfo
- Publication number
- EP1196258B1 EP1196258B1 EP00936718A EP00936718A EP1196258B1 EP 1196258 B1 EP1196258 B1 EP 1196258B1 EP 00936718 A EP00936718 A EP 00936718A EP 00936718 A EP00936718 A EP 00936718A EP 1196258 B1 EP1196258 B1 EP 1196258B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chamber
- pouring
- inert gas
- steel
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000161 steel melt Substances 0.000 title claims abstract description 21
- 238000005266 casting Methods 0.000 claims abstract description 21
- 238000009749 continuous casting Methods 0.000 claims abstract description 5
- 239000011261 inert gas Substances 0.000 claims description 27
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 230000001603 reducing effect Effects 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims 2
- 238000002309 gasification Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 description 23
- 239000010959 steel Substances 0.000 description 23
- 230000008018 melting Effects 0.000 description 13
- 238000002844 melting Methods 0.000 description 13
- 239000002893 slag Substances 0.000 description 9
- 230000000873 masking effect Effects 0.000 description 7
- IWZSHWBGHQBIML-ZGGLMWTQSA-N (3S,8S,10R,13S,14S,17S)-17-isoquinolin-7-yl-N,N,10,13-tetramethyl-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-amine Chemical compound CN(C)[C@H]1CC[C@]2(C)C3CC[C@@]4(C)[C@@H](CC[C@@H]4c4ccc5ccncc5c4)[C@@H]3CC=C2C1 IWZSHWBGHQBIML-ZGGLMWTQSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000001914 calming effect Effects 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 238000003958 fumigation Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
- B22D11/11—Treating the molten metal
- B22D11/111—Treating the molten metal by using protecting powders
Definitions
- the invention relates to a device for cleaning Melting steel, especially in continuous casting plants, with one Intermediate container (tundish) used to load a mold serves with molten steel from a ladle, the Intermediate tank internals to equalize the flow which has molten steel.
- Oxidation of the aluminum forms alumina (Al 2 O 3 ), which accounts for the majority (> 90%) of the impurities in the steel.
- the total alumina content must be low for steel grades with high purity requirements.
- individual large alumina particles macroscopic inclusions from 50 to over 500 ⁇ m in diameter
- the endogenous oxides generated during deoxidation in the steel mill can be minimized through process control and purity treatment, with outlier melting occurring again and again.
- exogenous oxides can only be used in the intermediate container effective separation technology can be used because that Separation of alumina particles in the mold or in the strand is only in depending on the casting process, solidification time and throughput possible to a small extent.
- the oxide content (essentially Al 2 O 3 ) must be reduced overall.
- One way to achieve this is to make the flow in the intermediate container more uniform and thus to calm it down, which enables the alumina particles to rise and be molded into an alumina-receiving top slag.
- An intermediate container is described in WO 95 06534 A, which is formed by transverse walls is divided into a pouring, a middle and a casting chamber.
- the Middle chamber is a narrow one in the middle with a distance to the transverse walls Bottom wall with openings in the middle for the introduction of inert gas to the Cleaning the molten steel to flush impurities upwards.
- the object is solved by the features of claim 1 Compared to the state of the art, twice the number of installations in the area a calming effect between the inflow and outflow point of the molten steel the turbulent flow prevailing in the inflow chamber in the middle and casting chamber. To do this, the first and second transverse wall and the targeted arranged openings of the same and the bottom wall of the middle chamber.
- the middle chamber has a cover plate.
- the cover plate creates the possibility of gassing the melting level of the middle chamber.
- Their bottom wall offers space for the adjustable inert gas supply and the inert gas spray bars. This means that the steel melt is purged in stages with insrfgas possible, whereby all alumina particles> 50 ⁇ m are flushed up and in the Pot slag can be separated. The latter is due to the inert gas in the formation protected by exogenous oxides.
- the pouring chamber is a cylindrical pouring sleeve with a lid, in the middle of an opening for a shadow pipe of the ladle is provided, which Shadow tube opposite the cover sealing play and opposite the Pouring sleeve has a distance.
- the opposite of that Pouring sleeve sealed with a shade tube allows fumigation the melting level of the same via an inert gas supply and thereby dispensing with masking compounds within the Injection sleeve. This means that when changing the ladle with under the shadow tube lowered melting level no slag or masking compound through the free Schaelzstrahl in the Melt can be flushed in.
- the advantage is that the casting chamber at its bottom, preferably in the end region of the intermediate container, a pouring tube for filling the mold, that of a stopper is mastered.
- the pouring tube lies in an area of the Casting chamber where the flow calms down and the steel melt is tempered.
- the insulating top slag prevents the formation of exogenous oxides and absorbs alumina residues.
- An advantageous solution is also that before Filling the intermediate container with molten steel on the bottom a starting aid in the pouring chamber below the pouring sleeve and another starting aid made of sheet metal or in front of the floor opening fireproof material are provided.
- the jump start made of sheet metal delays the flow of liquid steel from the Pouring chamber into the middle chamber while the sheet is still has not melted. If the melting level is above the Bottom opening of the first transverse wall, the floats Jump start made of fireproof material.
- FIG. 1 an intermediate container 1 is shown through a first transverse wall 2 in a pouring chamber 3 and through a second transverse wall 4 into a central chamber 5 and a casting chamber 6 is divided.
- a ladle 7 has a shadow pipe 8, that opens into the pouring chamber 3.
- the middle chamber 5 has a bottom wall 9 in which controllable inert gas feeds 10 are arranged, which Inert gas spray bars 11 with the central chamber 5 in Flow connection.
- the middle chamber 5 a cover plate 12.
- first transverse wall 2 there are one in the area of the floor wall 9 Bottom opening 13 and another in the second transverse wall 4 Bottom opening 14 and further openings 15 are provided.
- the casting chamber 6 has at its bottom in the end region of the Intermediate container 1, a pouring tube 16 for filling the mold on, which is controlled by a plug 17.
- the intermediate container 1 is filled with a molten steel 18, whose mirror is covered by a masking compound 19. This is different for the individual chambers 3, 5, 6.
- the Cover layer of the pouring chamber 3 takes floating large Particle that is the cover layer of the middle chamber 5 thin and takes all those blown up by inert gas Particles on, while the covering of the casting chamber 6 den Seals the melting level against the ingress of air.
- Figure 2 differs from Figure 1 by, among other things a cylindrical pouring sleeve 20 which has a cover 21st has, in the middle of which there is an opening for a shadow pipe 8 is provided, the 21 seal play against the lid and has a distance from the pouring sleeve 20.
- the Melting level within the pouring sleeve 20 does not carry any Masking compound 19, but is through an inert gas inflow 22nd fumigated.
- the melting level inside the middle chamber 5 is also gassed by an inert gas inflow 22 and with a top slag with a reducing effect. Besides, that is Steel melt 18 of the middle chamber 5 by an electrical Heating element 23 heated.
- a starting aid 24 and in front of the bottom opening 13 another jump starter 25 is provided which is made of sheet metal or fireproof material. These starting aids delay the Flow from the pouring chamber 3 into the middle chamber 5 at Filling the intermediate container 1.
- the molten steel 18 is from the ladle 7 on the Shadow tube 8 filled in the intermediate container 1. This serves as a buffer to avoid the casting process when changing pans To be able to continue the interruption. He also offers the Possibility of further cleaning the molten steel 18.
- the intermediate container 1 in the pouring chamber 3 has a pouring sleeve 20 which Shadow tube 8 seals with its cover 21 and the together with the shadow pipe 8 in the molten steel 18th dips.
- the other starting aid 25 consists of sheet metal that melts or made of refractory material that floats in the melt and so the meltdown clears the way into the middle chamber 5.
- the intermediate container 1 When the intermediate container 1 is filled, it develops in and under the pouring sleeve 20 through the from the shadow pipe 8th escaping pouring stream a short shot flow 26 leading to Deposition of large particles of slag and alumina results. This get into the covering compound 19 of the melt level Inflow chamber and are recorded there.
- the melting level is free of Masking compound 19.
- the inert gas inflow 22 Fumigation of the upper part of the pouring sleeve 20 instead, whereby there is no oxide formation at this point.
- Inert gas bubbles usually made of argon or nitrogen, get into the molten steel 18, but this is completely uncritical is.
- the pre-cleaned emerging from the pouring chamber 3 Steel melt 18 passes through the bottom opening 13 in the Middle chamber 5 and further through the other bottom opening 14 as well as the further openings 15 into the casting chamber 6.
- inert gas emerges from the Inert gas spray strips 11 and pearls in the molten steel 18 high. Depending on the inert gas pressure, they are of different sizes Alumina particles in the area above 50 ⁇ m are flushed up and into the Masking compound 19, a reducing top slag, added.
- the inert gas collects under the cover plate 12 and can there are supplemented by an inert gas inflow 22.
- On Electric heating element 23 is used to set the optimum casting temperature in the casting chamber 6.
- the molten steel 18 of the casting chamber 6 has a covering compound 19 made of insulating top slag. Occurs in the casting chamber 6 a calming of the flow and moderation of the Steel melt 18, so that through the pouring tube 16 of the Stopper 17 controls a cleaned, homogeneous steel melt 18 flows into the mold and there to a quality steel stiffens.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Processing Of Solid Wastes (AREA)
- Continuous Casting (AREA)
- Coating With Molten Metal (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Claims (9)
- Dispositif pour la purification de masses fondues d'acier, en particulier dans le cas d'installations de coulée continue, présentant un récipient intermédiaire (1), qui sert au revêtement d'une lingotière d'une masse fondue d'acier (18) à partir d'une poche de coulée (7) et qui est réparti, pour l'uniformisation de l'écoulement de la masse fondue d'acier (18), en une chambre d'introduction de coulée (3), une chambre médiane (5) et une chambre de coulée (6) séparées par deux parois transversales (2, 4) qui présentent des ouvertures inférieures (13, 14), la chambre médiane (5) présentant une paroi de fond (9) avec des ouvertures pour faire passer un gaz dans la masse fondue d'acier (18), caractériséen ce que la paroi de fond (9) est dimensionnée de telle manière qu'elle s'étend sur toute la longueur de la chambre médiane (5) jusque sous les parois transversales (2, 4) et qu'elle est exécutée avec plusieurs barres (11) de pulvérisation de gaz inerte disposées l'une à côté de l'autre,en ce que la paroi transversale (4) séparant la chambre médiane (5) de la chambre de coulée (6) présente des ouvertures latérales (15),en ce que la chambre médiane (5) présente une plaque de recouvrement (12).
- Dispositif selon la revendication 1, caractérisé en ce qu'on a prévu dans la paroi de fond (9) des alimentations de gaz (10) réglables, qui sont reliées par écoulement via des barres (11) de pulvérisation de gaz inerte avec la chambre médiane (5).
- Dispositif selon la revendication 1 ou 2, caractérisé en ce que la masse fondue dans la chambre médiane (5) peut de préférence être chauffée électriquement.
- Dispositif selon l'une ou plusieurs des revendications 1 à 3, caractérisé en ce que la chambre d'introduction de coulée (5) présente un manchon d'introduction de coulée (20) cylindrique avec un couvercle (21) au centre duquel on a prévu une ouverture pour une busette (8) de la poche de coulée (7).
- Dispositif selon la revendication 4, caractérisé en ce que la busette (8) a un jeu étanche par rapport au couvercle (21) et présente une certaine distance par rapport au manchon d'introduction de coulée (20).
- Dispositif selon la revendication 4 ou 5, caractérisé en ce que les espaces entre le niveau de la masse fondue et le couvercle (21) ou la plaque de recouvrement (12) présentent une alimentation en gaz inerte (22).
- Dispositif selon l'une ou plusieurs des revendications 1 à 6, caractérisé en ce que la chambre de coulée (6) présente, au niveau de son fond, de préférence dans la zone d'extrémité du récipient intermédiaire (1), un tube de coulée (16) pour le remplissage de la lingotière, qui est géré par un bouchon (17).
- Dispositif selon l'une ou plusieurs des revendications 4 à 7, caractérisé en ce qu'avant le remplissage du récipient intermédiaire (1) avec une masse fondue d'acier (18), on a prévu sur le fond de la chambre d'introduction de coulée (3), sous le manchon d'introduction de coulée (20), une aide au démarrage (24) et devant l'ouverture du fond une autre aide au démarrage (25) constituée de tôle ou de matériau réfractaire.
- Procédé pour la purification de masses fondues d'acier dans un récipient intermédiaire (1) qui sert au revêtement d'une lingotière avec une masse fondue d'acier (18) à partir d'une poche de coulée (7), en particulier dans le cas d'installations de coulée continue, selon l'une ou plusieurs des revendications 1 à 8 précédentes, caractérisé en ce que, dans la chambre médiane (5), on réalise un rinçage étagé de la masse fondue d'acier avec un gaz inerte à l'aide des alimentations de gaz inerte réglables (10) et des barres de pulvérisation (11) de gaz inerte, qui repousse les particules d'alumine de différentes grosseurs dans la plage > 50 µ vers le haut et qui sont absorbées dans les scories surnageantes (19) réductrices recouvrant le haut de la masse fondue d'acier (18), suite à quoi le gaz inerte se rassemble dans l'espace entre la plaque de recouvrement (12) et les scories surnageantes (19), complété par une alimentation de gaz inerte (22) qui protège les scories (19) d'une formation d'oxydes exogènes.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19922829 | 1999-05-19 | ||
DE19922829A DE19922829A1 (de) | 1999-05-19 | 1999-05-19 | Vorrichtung zur Reinigung von Stahlschmelzen |
PCT/EP2000/004074 WO2000071283A1 (fr) | 1999-05-19 | 2000-05-06 | Dispositif de purification d'acier fondu |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1196258A1 EP1196258A1 (fr) | 2002-04-17 |
EP1196258B1 true EP1196258B1 (fr) | 2003-01-02 |
Family
ID=7908429
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00936718A Expired - Lifetime EP1196258B1 (fr) | 1999-05-19 | 2000-05-06 | Dispositif de purification d'acier fondu |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1196258B1 (fr) |
AT (1) | ATE230317T1 (fr) |
AU (1) | AU5211600A (fr) |
DE (2) | DE19922829A1 (fr) |
WO (1) | WO2000071283A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT413196B (de) * | 2003-12-02 | 2005-12-15 | Voest Alpine Ind Anlagen | Verfahren zur herstellung eines gegossenen metallstranges hoher reinheit |
KR101949698B1 (ko) | 2017-07-14 | 2019-02-19 | 주식회사 포스코 | 용융물 처리 장치 |
CN109954851B (zh) * | 2017-12-14 | 2023-05-16 | 鞍钢股份有限公司 | 一种中间包钢液渣洗净化与升温的装置及使用方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1543798A (en) * | 1976-12-17 | 1979-04-04 | N Proizv Ob Tulatschermet | Horizontal continuous casting of metal |
JPS5827020B2 (ja) * | 1978-08-31 | 1983-06-07 | 川崎製鉄株式会社 | 連続鋳造用タンデイツシユにおける溶鋼の清浄化方法 |
JPS5626662A (en) * | 1979-08-07 | 1981-03-14 | Kobe Steel Ltd | Method for preventing entry of inclusion in continuous casting of steel |
JPS5717357A (en) * | 1980-07-04 | 1982-01-29 | Sumitomo Metal Ind Ltd | Manufacturing lead free-cutting steel |
JPH01107950A (ja) * | 1987-10-21 | 1989-04-25 | Nkk Corp | 水平連続鋳造用タンデイッシュ |
JPH03151144A (ja) * | 1989-11-08 | 1991-06-27 | Sumitomo Metal Ind Ltd | 連続鋳造用タンディッシュ内溶鋼の精錬方法 |
EP0714330A1 (fr) * | 1993-08-28 | 1996-06-05 | Foseco International Limited | Purification de metal fondu |
-
1999
- 1999-05-19 DE DE19922829A patent/DE19922829A1/de not_active Withdrawn
-
2000
- 2000-05-06 AU AU52116/00A patent/AU5211600A/en not_active Abandoned
- 2000-05-06 EP EP00936718A patent/EP1196258B1/fr not_active Expired - Lifetime
- 2000-05-06 DE DE50001022T patent/DE50001022D1/de not_active Expired - Fee Related
- 2000-05-06 WO PCT/EP2000/004074 patent/WO2000071283A1/fr active IP Right Grant
- 2000-05-06 AT AT00936718T patent/ATE230317T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO2000071283A1 (fr) | 2000-11-30 |
DE50001022D1 (de) | 2003-02-06 |
EP1196258A1 (fr) | 2002-04-17 |
AU5211600A (en) | 2000-12-12 |
DE19922829A1 (de) | 2000-11-23 |
ATE230317T1 (de) | 2003-01-15 |
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