EP1196062A1 - Device for packaging and/or applying a product containing fibres comprising at least a magnetised or magnetizable element - Google Patents

Device for packaging and/or applying a product containing fibres comprising at least a magnetised or magnetizable element

Info

Publication number
EP1196062A1
EP1196062A1 EP01947527A EP01947527A EP1196062A1 EP 1196062 A1 EP1196062 A1 EP 1196062A1 EP 01947527 A EP01947527 A EP 01947527A EP 01947527 A EP01947527 A EP 01947527A EP 1196062 A1 EP1196062 A1 EP 1196062A1
Authority
EP
European Patent Office
Prior art keywords
fibers
magnetic
particles
fiber
brush
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01947527A
Other languages
German (de)
French (fr)
Other versions
EP1196062B1 (en
Inventor
Jean-Louis Gueret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0009115A external-priority patent/FR2811525B1/en
Priority claimed from FR0105110A external-priority patent/FR2823491B1/en
Priority claimed from FR0107310A external-priority patent/FR2825247B1/en
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP1196062A1 publication Critical patent/EP1196062A1/en
Application granted granted Critical
Publication of EP1196062B1 publication Critical patent/EP1196062B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0261Roughness structure on the bristle surface
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D33/00Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
    • A45D33/02Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances with dispensing means, e.g. sprinkling means
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/021Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups arranged like in cosmetics brushes, e.g. mascara, nail polish, eye shadow
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/10Details of applicators
    • A45D2200/1009Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1018Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D33/00Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
    • A45D33/34Powder-puffs, e.g. with installed container

Definitions

  • Packaging and / or application device containing fibers comprising at least one magnetized or magnetizable body
  • the present invention relates to the application of a product, in particular a cosmetic or care product, to the skin or the integuments.
  • the invention aims in particular! meet all or part of the aforementioned needs. It does this by means of a device for packaging and / or applying a cosmetic or care product, characterized in that it comprises fibers comprising at least one magnetized or magnetizable body.
  • fiber should be understood within the meaning of the present invention any body generally elongate, for example to form a hair mascara brush, a 'pile coating of flocking, a hair brush, in particular a pile of brush nail polish or brush for applying a powder, or alternatively to form a filler introduced into a product to be applied to the eyelashes, for example to lengthen them.
  • the fibers can be relatively flexible, even elastically deformable, and be made of a synthetic material.
  • the magnetic properties of the fibers according to the invention can be exploited in many ways.
  • At least one of said fibers may have a substantially constant cross section, for example produced by extrusion or coextrusion of one or more thermoplastic and or elastomeric materials.
  • the plastic used may contain a charge of magnetic particles.
  • the fiber can be produced by coextrusion of two synthetic materials, one of them being for example loaded with magnetic particles.
  • the fiber may also be a coated fiber, manufactured by coating one or more magnetic bodies with at least one non-magnetic material or by coating a non-magnetic body, for example a wood fiber, rayon, nylon, cotton, of PE, by magnetic particles, the latter possibly being encapsulated in a resin.
  • the magnetic particles used can be formed at least in part from a material chosen from the following list: soft magnetic materials, hard magnetic materials, ferrites, in particular based on zinc, nickel or manganese, rare earths, barium sulphate, alloys silicon iron, cobalt iron, possibly charged with molybdenum, or a mixture of these, this list not being limiting.
  • the magnetic particles may be particles coated with a resin, for example cyanoacrylate, or be produced by depositing a magnetic substance on a non-magnetic support, for example a glass microbead or a wood fiber.
  • At least one of said fibers may for example comprise between 0.2 and 30% by weight of magnetized or magnetizable particles, depending on the nature of said particles and the magnetic properties sought.
  • At least one of said fibers can be made with a plastic material selected from the following: polyamides, PET, acetates, PE, PP, PVC, polyester block amide, Rilsan ® plasticized elastomers, in particular polyester elastomers, PE elastomers, silicone elastomers, nitrile elastomers, or a mixture of these materials.
  • the plastic material chosen may have swelling and / or softening properties in contact with the cosmetic or care product which is in contact with it, for example the water contained in this cosmetic or care product.
  • the magnetic particles can be present for example at least on the surface of the fibers, or even on the surface of the fibers only, inside the fibers only or even be dispersed within the plastic material in a substantially homogeneous manner.
  • the fibers can have the most diverse cross-sections, for example a shape chosen from the following: of revolution or not, in a circle, in a solid or hollow square, in a disc with groove possibly, in a full or hollow triangle, in a solid star or hollow, in U, in N, in I, in T, in Z, in -, in +, reniforrne, with three branches, full, hollow, or a combination of these forms.
  • the fiber can be twisted.
  • the fibers can be simply magnetizable, that is to say sensitive to the action of a magnetic field, without being magnetized; alternatively they can be magnetized, that is to say generate a permanent magnetic field.
  • the invention can be applied to a large number of packaging and / or application devices.
  • the fibers having magnetic properties may belong to the applicator and / or to the packaging device and / or be contained in the product.
  • the device comprises an applicator having magnetized fibers and a container containing a composition containing particles capable of being attracted by the magnetic field exerted by fibers of the applicator.
  • the device comprises an applicator having magnetizable fibers and a container containing a composition containing magnetized particles, the fibers being capable of being subjected to the magnetic action of said magnetized particles. In both cases, the magnetic interactions between the fibers and the product can contribute to improving the loading of product with the applicator.
  • the invention also applies to packaging devices comprising a wiping member for wiping an applicator.
  • This wiping member may have magnetic properties, in order for example to magnetize an applicator comprising magnetizable fibers, when it is withdrawn and / or improve the quality of the wiping.
  • the applicator may be a mascara brush and at least one of the bristles of the brush may consist of one of said fibers.
  • the bristles of the brush can be secured to a twisted core, which can be magnetized or not.
  • the applicator may consist of a brush and at least one of the bristles of the brush may consist of one of said fibers.
  • the device may include a flock coating of which at least one of the bristles is formed by one of said fibers.
  • This flock coating can at least partially cover a support, deformable or not, porous or not.
  • the flock coating may in particular at least partially cover one of the following elements: the teeth of a comb, the bristles of a brush, a wringer, a foam, a sponge, a perforated or non-perforated film, a nozzle. , rigid or flexible, in particular an elastomer end piece, a woven or a nonwoven.
  • the device may also include a woven fabric, a nonwoven fabric or a felt made with at least one of said fibers.
  • the fibers can be fixed on any type of support, which can be magnetized so as to subject the fibers to a magnetic field and cause them, for example, to take on a particular configuration or to become magnetized.
  • the fibers can be subjected to the magnetic field of a magnet fixed on a support.
  • the device may also contain a composition comprising a filler constituted at least in part of said fibers.
  • At least one of the fibers may have a larger transverse dimension of, for example, between 0.5 and 500 ⁇ m, or even 50 and 500 ⁇ m.
  • the size of the fibers will be chosen according to their use.
  • at least one of said fibers may have a length of, for example, between 0.5 and 50 mm. The length will be chosen according to the use of the fibers.
  • At least one of the fibers comprises, in addition to a synthetic material and the magnetic particles, particles capable of absorbing a liquid or a compound in solution in this liquid or particles capable of dissolving in a liquid.
  • the liquid can for example be water, an oil, an alcohol or any type of solvent, more generally.
  • the fibers may contain particles of one or more materials chosen in the following Kste: hydrogonflating or lipo-inflating polymers, cross-linked super absorbent polyacrylates with high swelling rate in water, polyvinyl alcohol, carboxyvinyl polymers, semi-synthetic derivatives of cellulose , starches, bio-gums, bio-saccharides, sclero-glucans, casein, phytocoUoids such as alginates, gelatin, cotton fibers, gels, xantane, laponite, silicas, in particular colloidal silica, or mixtures thereof.
  • Kste hydrogonflating or lipo-inflating polymers, cross-linked super absorbent polyacrylates with high swelling rate in water, polyvinyl alcohol, carboxyvinyl polymers, semi-synthetic derivatives of cellulose , starches, bio-gums, bio-saccharides, sclero-glucans, casein, phytocoUoids such as alginates, gelatin,
  • the fibers can be fixed or mobile.
  • the invention also relates to a method of manufacturing a packaging and / or application device comprising fibers as defined above, characterized in that it comprises a step of exposing said fibers to a field.
  • magnetic for example to give them a desired orientation magnetization.
  • the invention also relates to a porous magnetic fiber.
  • the invention also relates to a rough magnetic fiber.
  • Other characteristics and advantages of the present invention will appear on reading the detailed description which follows, of nonlimiting examples of implementation, and on examining the appended drawing (which forms an integral part of the description), on which :
  • FIG. 1 is a diagrammatic view, in cross section, of an example of a fiber having magnetic properties
  • FIGS. 2 to 4 are views similar to FIG. 1, showing alternative embodiments
  • FIGS. 5A and 5B are schematic axial sections representing a fiber incorporating, in addition to the magnetic bodies, particles capable of swelling in the presence of a liquid,
  • FIGS. 6A and 6B are schematic axial sections of a fiber comprising, in addition to the magnetic bodies, particles soluble in a liquid,
  • FIG. 7 illustrates the formation of a gel on the surface of the fiber
  • FIG. 8 represents an embodiment in which the particles other than magnetic are present on the surface of the fiber only
  • FIG. 10 illustrates the manufacture of fibers by extrusion
  • FIG. 11 illustrates the magnetization of the fibers after the extrusion
  • FIG. 27 illustrates the orientation of the bristles of a flocking produced with magnetizable fibers under the effect of the lines of the magnetic field generated by a magnet
  • FIGS. 28A and 28B illustrate the deflection of the bristles of a brush under the effect of magnetic interactions
  • FIGS. 29A and 29B illustrate the deflection of the bristles of a brush under the effect of magnetic interactions
  • FIG. 30 represents an applicator comprising an application element housed under a protective cover, in the absence of use,
  • FIG. 31 represents a coated magnetic particle
  • FIG. 32 shows a magnetic particle formed by depositing a magnetic substance on a non-magnetic body.
  • FIG. 1 a fiber which can be used in a packaging and or application device according to the invention.
  • This fiber is produced, in the example described, by extrusion of a thermoplastic material 11 containing a charge of particles 12 having magnetic properties.
  • the magnetic particles 12 can be produced by fragmenting a magnetic substance or by depositing a magnetic substance M on a non-magnetic body C, for example a microbead or a wood fiber as illustrated in FIG. 32.
  • the magnetic particles can also comprise a magnetic core M and an non-magnetic outer layer R, for example a layer of resin, in particular of cyanoacrylate, as illustrated in FIG. 31,
  • the fiber is full and has a circular section, but it could have other sections, as explained below.
  • the fiber can be produced for example by means of an installation shown in FIG. 10, comprising an extruder 20 and a bath 21 of a cooling liquid in which the fibers are immersed at their outlet from the extruder.
  • the invention is not limited to fibers comprising magnetic particles 12 dispersed in a substantially homogeneous manner within the plastic material 11 and the magnetic particles can be deposited only on the surface of the fibers, by an appropriate method, for example d coating, as illustrated in FIG. 2 or confined inside the fiber, as illustrated in FIG. 3.
  • the magnetic particles can also be replaced by a central core 14, as illustrated in FIG. 4.
  • the fibers can also be made by coating non-magnetic fibers with magnetic particles, all of which can be encapsulated in a resin.
  • the mass proportion of magnetic particles in a fiber can be for example between 0.2 and 30%.
  • the fiber may include additional fillers in addition to the bodies having magnetic properties, and in particular a charge of particles capable of absorbing and / or swelling on contact with a liquid, in particular on contact with the cosmetic or care product to be applied.
  • the fiber may in particular comprise water-absorbing and or water-swellable particles.
  • FIG. 5A shows a fiber comprising a charge of particles 30 of a hydrogonflating compound, before bringing the fiber into contact with a liquid, for example water, and in FIG. 5B the same fiber after contact with this liquid.
  • the swelling of the particles 30 makes it possible to produce a relief on the surface of the fiber, such relief being useful in particular to allow the fiber to be loaded with a greater quantity of product or to hang the eyelashes more in the case where the fiber is used as a mascara brush bristle, for example.
  • the particles can also be useful for absorbing one or more substances within the fiber, for example preservatives or cosmetic or dermatological active agents.
  • one or more compounds solubilized in the liquid of the bath can be introduced into the bath 21 used to cool the fibers at their exit from the extruder. These compounds are absorbed by the particles 30 when the fibers are immersed in the bath 21.
  • the fibers leaving the bath 21 are loaded with the compounds which have been pumped by the particles 30 contained in the fibers. These compounds can then be gradually released on contact with a cosmetic or care product, in order to improve their conservation, for example.
  • the fibers can be dehydrated at the exit of the bath 21.
  • the fibers may also contain, in addition to the bodies having magnetic properties, particles 40 soluble in a liquid, for example bath water 21 used to cool the fibers as they exit the extruder.
  • These particles 40 can consist, for example, of a salt or a sugar soluble in the liquid used, or even gelatin when the liquid is water.
  • FIG. 6A shows a fiber containing such particles 40, before dissolution, that is to say for example just at the outlet of the extruder 20 and in FIG. 6B the same fiber after passing through the bath 21. It is noted that the soluble particles 40 which were present on the surface of the fiber were dissolved by the liquid in the bath 21, creating a roughness on the surface . of the fiber, or even making the fiber porous.
  • Such roughness or porosity can be used to increase the loading of the fiber with product, for example.
  • the roughness or porosity obtained will depend on the initial particle size of the particles 40.
  • the particles 40 may also only be partially dissolved when they leave the bath 21, so that they continue to dissolve on contact with the cosmetic product, or of care present on their surface.
  • the particles 40 may consist of one or more substances having a cosmetic or dermatological effect. In this case, the dissolution of the particles 40 in contact with the product can be accompanied by the release of these substances on the treated surface.
  • the fibers may, where appropriate, be exposed to impacts aimed at causing or facilitating the departure of the particles 40 present on the surface.
  • the particles 40 can also be produced in a material which is not soluble in the bath water 21 but which is only gradually soluble in the cosmetic or care product present in contact with fibers.
  • a gel layer 51 can modify, for example, the affinity of the fiber with the cosmetic or care product in contact with it.
  • the gel can also be deposited on the treated surface, for example the eyelashes, to improve their hold, their appearance or the sliding of the applicator in contact with them.
  • the use of particles capable of absorbing a liquid, in particular water, may also have the advantage of delaying the drying of a cosmetic or care composition on the surface of the fiber, when the liquid absorbed by the particles is capable of being gradually released to compensate for the evaporation of a solvent contained in the composition.
  • particles 30, 40 or 50 can also make it possible to create privileged anchoring zones for the product on the surface of the fiber, for example by virtue of the affinity of the particles used with respect to the hydrophilic or lipophilic compounds contained. in the product.
  • the latter can optionally be an oil / water emulsion and the fibers absorb only oil or water and more generally absorb a component of the product selectively.
  • the particles 30, 40 or 50 having properties other than magnetic can, if necessary, be present on the surface only of the fibers, as illustrated in FIG. 8.
  • the initial particle size of the particles 30, 40 or 50 is for example between 0.1 or 300 ⁇ m, or even between 5 and 200 ⁇ m, or even still between 10 and 150 ⁇ m.
  • the proportion of particles 30, 40 or 50 is for example between 0 and 20% by mass, even between 0 and 6% by mass, dry.
  • the fibers can be given very diverse cross sections, other than solid circular, as will now be described with reference to FIGS. 9A to 9R.
  • the fibers can be extradited with a flat cross section, - as illustrated in FIG. 9A, crosswise as represented in FIG. 9B, in the shape of a three-pointed star, as illustrated in FIG. 9 ' C.
  • the fibers can have a hollow section, as shown in Figure 9D or solid with a cap groove, as shown in Figure 9E.
  • the fibers may also have a U-shaped cross section, as illustrated in figure 9F, a cross section in I as illustrated in figure 9H, in T as illustrated in figure 91, in V as illustrated in figure 9J, in Z as illustrated in figure 9K or a combination of the shapes mentioned above, for example the combination shown in FIG. 9G of the shapes corresponding to FIGS. 9B and 9C.
  • FIG. 9G of the shapes corresponding to FIGS. 9B and 9C.
  • FIG. 9L shows a fiber of square and hollow section, in FIG. 9 a fiber of square and solid section, in FIG. 9N a fiber of star and hollow section, in FIG. 9P a fiber of triangular section and hollow, in FIG. 9Q a fiber of section forming grooves at its periphery and in FIG. 9R a fiber having a reniform section.
  • the fibers can be exposed to a magnetic field of magnetization at the exit of the bath 21, by means of a magnetization device 60, as illustrated in FIG. 11, in order for example to be magnetized with a predefined polarity.
  • the magnetization of the fibers can also take place after incorporation of these fibers into a packaging and / or application device, by subjecting this device or a batch of these devices to a magnetization field.
  • the fact of magnetizing the fibers only once they are in place in the packaging device or application can facilitate manufacturing by limiting the risks of fiber agglomeration.
  • the fibers can be used in various appUcateurs and conditioning devices, as will now be described.
  • FIG. 12 shows a packaging and application device 100, comprising a container 101 for containing a product P to be applied such as a mascara and an applicator 102.
  • the container 101 is provided with a wiper member 106 which can, in a variant not shown, be flocked.
  • the applicator 102 comprises a rod 103, provided at one end with a gripping member 104 also constituting a closure cap for the container 101 and at the other end with a brush 105.
  • the latter comprises a core constituted by a wire twisted metal, in the turns of which hairs are retained consisting of fibers having magnetic properties, such as fibers which have just been described.
  • the magnetic poles of the brush can be oriented for example in the axis of the rod 103 or perpendicular to the axis of the rod 103.
  • the twisted core can be made of a non-magnetic material such as non-magnetic stainless steel or alternatively in a material with magnetic properties. The soul can thus interact magnetically with the hairs.
  • the bristles of the brush 105 can be magnetized, so that the magnetization of a poU of the brush exerts an action on the neighboring bristles, the magnetic interactions between the bristles being able for example to give the bristles the desired orientations.
  • FIGS. 28A and 28B have illustrated the effect of lateral deflection of the bristles of the brush in the event of a transverse magnetic field.
  • the magnetization of the hairs can also be used only to exert during the application of the product to the eyelashes a magnetic field having a beneficial action on them or on a part of the face, for example the eyelids.
  • the magnetic field exerted by the bristles of the brush is liable to change over time, in particular when the configuration of the brush is modified, for example when the applicator is withdrawn or during application.
  • the product P can have magnetic properties, for example containing magnetizable or magnetized particles. In the case where the product P has magnetic properties, having brush bristles which also have magnetic properties can make it possible to favor the loading of the brush with product, for example by attraction of the product by the tips of the brush.
  • the product may also contain fibers or palettes with magnetic properties and the applicator interact magnetically with these flakes, to bring them for example in a particular orientation at the time of application, in order for example to promote the sliding of the applicator.
  • a device 110 for packaging and applying a nail varnish comprising a container 111 and an applicator 112 comprising a rod 113 provided at one end with a gripping element 114 also constituting a closure cap of the container and at the other end of a brush 115 comprising a bundle of relatively grouped bristles.
  • the latter are made from fibers having magnetic properties, which can be used to bring the bristles of the brush 115 in a predefined orientation, in order to facilitate the loading of the brush 115 with product or to exert an action on the treated surface.
  • Magnetic interactions between the bristles of the brush according to the polarity of the magnetic field of each poU, can contribute to group the poUs or on the contrary to separate them.
  • FIGS. 29A and 29B a very schematic illustration has been illustrated in FIGS. 29A and 29B of an effect of separation of the bristles due to magnetic interactions between the bristles.
  • the product P may or may not have magnetic properties.
  • FIG. 14 shows a packaging and appUcation device 120 which comprises a container 121 containing a product P, for example a liquid lipstick, and an applicator 122 comprising a rod 123 provided at one end with a cap 124 for closing the container 121, which also serves as a gripping member, and at the other end of an applicator tip 124, covered by a flocking made with fibers having magnetic properties.
  • the device 120 also includes a wringer formed by a block of foam 125. This block of foam may have magnetic properties or not. One can in particular give the foam block 125 a certain magnetization by incorporating within it magnetic particles. The magnetization of the wiper can be used, for example, to magnetize the flocking of the end piece 124 when the applicator 122 is withdrawn.
  • FIG. 15 shows a device for packaging and applying 130 of a product P, in particular a liquid lipstick, comprising a nozzle 131 covered by a flocking 132 made with fibers having magnetic properties.
  • FIG. 16 shows a brush 140 intended for the application of a powder, the bristles of which are produced with fibers having magnetic properties.
  • Such an appUcator can be used for example to apply a blush on the skin.
  • FIG. 18A shows a liquid lipstick applicator 160 comprising an endpiece 161 of flocked elastomer and in FIG. 18B an eyeliner 160 'also comprising an endpiece 161' of flocked elastomer.
  • the flocking particles consist of fibers having magnetic properties.
  • the fibers can also be used to flock a puff 170, as illustrated in FIG. 19 or a make-up sponge 180, shown in Figure 20.
  • the flock coating may also extend over a film 191 fixed to a block of foam 192, as is the case in the applicator 190 shown in FIG. 21.
  • fibers having magnetic properties in a disc 200 or a towel comprising at least one layer 201 of a nonwoven or of a fabric incorporating said fibers, as illustrated in FIG. 22.
  • FIG. 23 shows a comb 210 for applying a product to the eyelashes, comprising flocked teeth 211.
  • the flocking poUs are produced with fibers having magnetic properties.
  • the applicator may include one or more monoblock magnets in addition to the fibers having magnetic properties.
  • FIG. 24 shows an applicator 220 comprising a handle 221 on which a magnet 222 is fixed.
  • the latter is covered by a block of foam 223, itself coated externally by a flocking 224 made of fibers with magnetic properties.
  • the presence of the magnet 222 makes it possible to subject the hairs of the flocking 294 to a magnetic field.
  • the hairs of the flocking which are connected substantially pe ⁇ endicularly to the underlying support can be oriented along the lines of this magnetic field M, as illustrated in FIG. 27.
  • the hairs tend to stand up on the surface of the element. application or to take other orientations according to the position relative to the magnet 222, which allows for example to load with more product the applicator or to make the application softer.
  • the powder particles tend to deposit on the applicator, in particular on the fibers, and the may cause the powder to fly and the sternutatory effect.
  • FIG. 25 shows a device 230 in which the product is contained in a flexible bag 231 surmounted by a pump 232.
  • the applicator comprises a foam 234, coated on its surface with a flocking 235 and secured to a cover 236.
  • a magnet 237, housed in the foam 234 is carried by the cover 236.
  • the hairs of the flocking 235 have magnetic properties and are subjected to the magnetic field of the magnet 237, like the example of embodiment. previous.
  • Partially shown in FIG. 30 is an applicator 280 comprising a flocked tip 282 housed under a cover 281 in the absence of use.
  • the product P can contain magnetic particles 241 and the applicator present, magnetic properties , for example because it consists of a flocked tip whose flocking coating consists of magnetized fibers.
  • the tip 242 is capable of attracting the magnetic particles 241 contained in the product.
  • the mesh size of the sieve 240 it is possible to ensure that these magnetic particles 241 attracted by the end piece 242 do not pass through the sieve 240 but move from the product P to the end piece 242, which makes it possible to improve the loading of the nozzle 242 with product.
  • the product P itself is magnetic, comprising, for example, coated magnetic particles, and can pass through the meshes of the sieve 240.
  • the fibers can be magnetized over only part of their length.
  • the packaging and apphcation devices which have just been described may comprise fibers having magnetic properties mixed with fibers having no magnetic properties, optionally loaded with particles of a liquid absorbent compound and / or suitable to swell on contact with a liquid, or capable of dissolving on contact with a liquid, this liquid being for example water.

Landscapes

  • Brushes (AREA)
  • Cosmetics (AREA)
  • Coating Apparatus (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Closures For Containers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Nonwoven Fabrics (AREA)
  • Packages (AREA)

Abstract

The invention concerns a device for packaging and/or applying a cosmetic and/or care product, containing fibres comprising at least a magnetised or magnetizable element.

Description

Dispositif de conditionnement et/ou d'application contenant des fibres comportant au moins un corps aimanté ou aimantable Packaging and / or application device containing fibers comprising at least one magnetized or magnetizable body
La présente invention concerne l'application d'un produit, notamment un produit cosmétique ou de soins, sur la peau ou les phanères.The present invention relates to the application of a product, in particular a cosmetic or care product, to the skin or the integuments.
Il est de plus en plus fréquent d'incorporer dans les produits cosmétiques un ou plusieurs actifs destinés au soin de la surface traitée. Il peut s'agir, par exemple, d'actifs hydratants ou antirides. Il existe un besoin pour notamment favoriser la pénétration de ces actifs et renforcer ainsi leur efficacité. On a proposé dans la demande de brevet DE 4 325 071 d'utiliser des particules magnétiques pour favoriser la microcirculation. Dans cette demande, les particules magnétiques sont dispersées dans une crème, lotion ou gel, ou déposées sur un bandage.It is more and more frequent to incorporate in cosmetic products one or more active agents intended for the care of the treated surface. They can be, for example, hydrating or anti-wrinkle active ingredients. There is a need in particular to promote the penetration of these active agents and thus reinforce their effectiveness. It has been proposed in patent application DE 4 325 071 to use magnetic particles to promote microcirculation. In this application, the magnetic particles are dispersed in a cream, lotion or gel, or deposited on a bandage.
Par ailleurs il existe, d'une manière générale, un besoin pour faciliter le prélèvement d'un produit contenu dans un récipient, améliorer l'application du produit sur la surface à traiter et créer de nouveaux effets de maquillage, le cas échéant.Furthermore, there is generally a need to facilitate the removal of a product contained in a container, to improve the application of the product to the surface to be treated and to create new makeup effects, if necessary.
L'invention vise notamment! répondre à tout ou partie des besoins précités. Elle y parvient grâce à un dispositif de conditionnement et/ou d'application d'un produit cosmétique ou de soins, caractérisé par le fait qu'il comprend des fibres comportant au moins un corps aimanté ou aimantable. Par «fibre », il faut comprendre au sens de la présente invention tout corps généralement allongé, destiné par exemple à constituer un poil de brosse à mascara, un ' poil de revêtement de flocage, un poil de pinceau, notamment un poil de pinceau de vernis à ongles ou de pinceau pour l'application d'une poudre, ou encore à constituer une charge introduite dans un produit à appliquer sur les cils, par exemple pour les allonger. Les fibres peuvent être relativement souples, voire élastiquement déformables, et être réalisées dans une matière synthétique.The invention aims in particular! meet all or part of the aforementioned needs. It does this by means of a device for packaging and / or applying a cosmetic or care product, characterized in that it comprises fibers comprising at least one magnetized or magnetizable body. By "fiber" should be understood within the meaning of the present invention any body generally elongate, for example to form a hair mascara brush, a 'pile coating of flocking, a hair brush, in particular a pile of brush nail polish or brush for applying a powder, or alternatively to form a filler introduced into a product to be applied to the eyelashes, for example to lengthen them. The fibers can be relatively flexible, even elastically deformable, and be made of a synthetic material.
Les propriétés magnétiques des fibres selon l'invention peuvent être exploitées de multiples façons.The magnetic properties of the fibers according to the invention can be exploited in many ways.
On peut notamment exercer au moment de l'application, grâce aux fibres, un champ magnétique, d'orientation prédéfinie ou variable, favorisant la micro-circulation et la pénétration d'actifs.One can in particular exert at the time of application, thanks to the fibers, a magnetic field, of predefined or variable orientation, promoting micro-circulation and penetration of active agents.
On peut également, en jouant sur les interactions magnétiques entre les fibres et/ou en exploitant la réactivité des fibres à un champ magnétique extérieur, orienter les fibres d'une manière particulière lors du chargement en produit des fibres, lors d'un essorage éventuel ou lors de l'application, afin par exemple d'augmenter la quantité de produit sur l'applicateur ou de faciliter l'application. Selon les corps magnétiques utilisés pour conférer aux fibres leurs propriétés magnétiques, on pourra bénéficier le cas échéant d'une action biocide, apte à favoriser la conservation d'un produit cosmétique ou de soins à leur contact.We can also, by playing on the magnetic interactions between the fibers and / or by exploiting the reactivity of the fibers to an external magnetic field, orient the fibers in a particular way when loading the product with fibers, during a possible spinning or during application, in order for example to increase the amount of product on the applicator or to facilitate application. Depending on the magnetic bodies used to give the fibers their magnetic properties, it may be possible to benefit from a biocidal action, if necessary, capable of promoting the conservation of a cosmetic or care product in contact with them.
Au moins l'une desdites fibres peut présenter une section transversale sensiblement constante, étant par exemple réalisée par extrusion ou coextrusion d'une ou plusieurs matières thermoplastiques et ou élastomères. La matière plastique utilisée peut contenir une charge de particules magnétiques. La fibre peut être réalisée par coextrusion de deux matières synthétiques, l'une d'entre elles étant par exemple chargée avec des particules magnétiques. La fibre peut encore être une fibre enrobée, fabriquée par enrobage d'un ou plusieurs corps magnétiques par au moins un matériau amagnétique ou par enrobage d'un corps amagnétique, par exemple une fibre de bois, de rayonne, de nylon, de coton, de PE, par des particules magnétiques, ces dernières étant éventuellement encapsulées dans une résine.At least one of said fibers may have a substantially constant cross section, for example produced by extrusion or coextrusion of one or more thermoplastic and or elastomeric materials. The plastic used may contain a charge of magnetic particles. The fiber can be produced by coextrusion of two synthetic materials, one of them being for example loaded with magnetic particles. The fiber may also be a coated fiber, manufactured by coating one or more magnetic bodies with at least one non-magnetic material or by coating a non-magnetic body, for example a wood fiber, rayon, nylon, cotton, of PE, by magnetic particles, the latter possibly being encapsulated in a resin.
Les particules magnétiques utilisées peuvent être formées au moins en partie d'un matériau choisi dans la liste suivante : matériaux magnétiques doux, matériaux magnétiques durs, ferrites, notamment à base de zinc, nickel ou de manganèse, terres rares, sulfate de baryum, alliages fer silicium, fer cobalt, éventuellement chargés en molybdène, ou un mélange de ceux-ci, cette liste n'étant pas limitative. Les particules magnétiques peuvent être des particules enrobées d'une résine, par exemple de cyanoacrylate, ou être réalisées par dépôt d'une substance magnétique sur un support amagnétique, par exemple une microbille de verre ou une fibre de bois.The magnetic particles used can be formed at least in part from a material chosen from the following list: soft magnetic materials, hard magnetic materials, ferrites, in particular based on zinc, nickel or manganese, rare earths, barium sulphate, alloys silicon iron, cobalt iron, possibly charged with molybdenum, or a mixture of these, this list not being limiting. The magnetic particles may be particles coated with a resin, for example cyanoacrylate, or be produced by depositing a magnetic substance on a non-magnetic support, for example a glass microbead or a wood fiber.
Au moins l'une desdites fibres peut comporter par exemple entre 0,2 et 30 % en poids de particules aimantées ou aimantables, selon la nature desdites particules et les propriétés magnétiques recherchées.At least one of said fibers may for example comprise between 0.2 and 30% by weight of magnetized or magnetizable particles, depending on the nature of said particles and the magnetic properties sought.
L'une au moins desdites fibres peut être réalisée avec une matière plastique choisie parmi les suivantes : polyamides, PET, acétates, PE, PP, PVC, polyester bloc amide, Rilsan® plastifié, élastomères, notamment élastomères de polyester, élastomères de PE, élastomères de silicone, élastomères de nitrile, ou un mélange de ces matériaux. Eventuellement, la matière plastique choisie peut présenter des propriétés de gonflement et/ou de ramollissement au contact du produit cosmétique ou de soins qui est à son contact, par exemple de l'eau contenue dans ce produit cosmétique ou de soins.At least one of said fibers can be made with a plastic material selected from the following: polyamides, PET, acetates, PE, PP, PVC, polyester block amide, Rilsan ® plasticized elastomers, in particular polyester elastomers, PE elastomers, silicone elastomers, nitrile elastomers, or a mixture of these materials. Optionally, the plastic material chosen may have swelling and / or softening properties in contact with the cosmetic or care product which is in contact with it, for example the water contained in this cosmetic or care product.
Les particules magnétiques peuvent être présentes par exemple au moins à la surface des fibres, voire à la surface des fibres uniquement, à l'intérieur des fibres uniquement ou encore être dispersées au sein de la matière plastique de manière sensiblement homogène.The magnetic particles can be present for example at least on the surface of the fibers, or even on the surface of the fibers only, inside the fibers only or even be dispersed within the plastic material in a substantially homogeneous manner.
Les fibres peuvent présenter des sections transversales les plus diverses, par exemple une forme choisie parmi les suivantes : de révolution ou non, en cercle, en carré plein ou creux, en disque avec rainure éventuellement, en triangle plein ou creux, en étoile pleine ou creuse, en U, en N, en I, en T, en Z, en -, en +, réniforrne, à trois branches, pleine, creuse, ou une combinaison de ces formes. La fibre peut être torsadée.The fibers can have the most diverse cross-sections, for example a shape chosen from the following: of revolution or not, in a circle, in a solid or hollow square, in a disc with groove possibly, in a full or hollow triangle, in a solid star or hollow, in U, in N, in I, in T, in Z, in -, in +, reniforrne, with three branches, full, hollow, or a combination of these forms. The fiber can be twisted.
Les fibres peuvent être simplement aimantables, c'est-à-dire sensibles à l'action d'un champ magnétique, sans être aimantées ; en variante elles peuvent être aimantées, c'est-à-dire générer un champ magnétique permanent.The fibers can be simply magnetizable, that is to say sensitive to the action of a magnetic field, without being magnetized; alternatively they can be magnetized, that is to say generate a permanent magnetic field.
L'invention peut s'appliquer à un grand nombre de dispositifs de conditionnement et/ou d'application. Les fibres présentant des propriétés magnétiques peuvent appartenir à l'applicateur et/ou au dispositif de conditionnement et/ou être contenues dans le produit. Dans une réalisation particulière, le dispositif comporte un applicateur ayant des fibres aimantées et un récipient contenant une composition renfermant des particules aptes à être attirées par le champ magnétique exercé par des fibres de l'applicateur. Dans une autre réalisation particulière, le dispositif comporte un applicateur ayant des fibres aimantables et un récipient contenant une composition renfermant des particules aimantées, les fibres étant susceptibles d'être soumises à l'action magnétique desdites particules aimantées. Dans les deux cas, les interactions magnétiques entre les fibres et le produit peuvent contribuer à améliorer le chargement en produit de l' applicateur.The invention can be applied to a large number of packaging and / or application devices. The fibers having magnetic properties may belong to the applicator and / or to the packaging device and / or be contained in the product. In a particular embodiment, the device comprises an applicator having magnetized fibers and a container containing a composition containing particles capable of being attracted by the magnetic field exerted by fibers of the applicator. In another particular embodiment, the device comprises an applicator having magnetizable fibers and a container containing a composition containing magnetized particles, the fibers being capable of being subjected to the magnetic action of said magnetized particles. In both cases, the magnetic interactions between the fibers and the product can contribute to improving the loading of product with the applicator.
L'invention s'applique également aux dispositifs de conditionnement comportant un organe d'essorage pour essorer un applicateur. Cet organe d'essorage peut présenter des propriétés magnétiques, afin par exemple d'aimanter un applicateur comportant des fibres aimantables, lors du retrait de celui-ci et/ou améliorer la qualité de l'essorage. L'applicateur peut être une brosse à mascara et l'un au moins des poils de la brosse être constitué par l'une desdites fibres. Les poils de la brosse peuvent être solidaires d'une âme torsadée, laquelle peut être aimantée ou non.The invention also applies to packaging devices comprising a wiping member for wiping an applicator. This wiping member may have magnetic properties, in order for example to magnetize an applicator comprising magnetizable fibers, when it is withdrawn and / or improve the quality of the wiping. The applicator may be a mascara brush and at least one of the bristles of the brush may consist of one of said fibers. The bristles of the brush can be secured to a twisted core, which can be magnetized or not.
L'applicateur peut être constitué par un pinceau et l'un au moins des poils du pinceau être constitué par l'une desdites fibres.The applicator may consist of a brush and at least one of the bristles of the brush may consist of one of said fibers.
Le dispositif peut comporter un revêtement de flocage dont l'un au moins des poils est constitué par l'une desdites fibres. Ce revêtement de flocage peut recouvrir au moins partiellement un support, déformable ou non, poreux ou non. Le revêtement de flocage peut notamment recouvrir au moins partiellement l'un des éléments parmi les suivants : les dents d'un peigne, les poils d'une brosse, un essoreur, une mousse, une éponge, un film perforé ou non, un embout, rigide ou souple, notamment un embout en élastomère, un tissé ou un non-tissé.The device may include a flock coating of which at least one of the bristles is formed by one of said fibers. This flock coating can at least partially cover a support, deformable or not, porous or not. The flock coating may in particular at least partially cover one of the following elements: the teeth of a comb, the bristles of a brush, a wringer, a foam, a sponge, a perforated or non-perforated film, a nozzle. , rigid or flexible, in particular an elastomer end piece, a woven or a nonwoven.
Le dispositif peut encore comporter un tissé, un non-tissé ou un feutre réalisé avec au moins l'une desdites fibres. Comme indiqué plus haut, les fibres peuvent être fixées sur tout type de support, lequel peut être aimanté de manière à soumettre les fibres à un champ magnétique et les amener par exemple à prendre une configuration particulière ou à devenir aimantées. Les fibres peuvent être soumises au champ magnétique d'un aimant fixé sur un support. Le dispositif peut encore renfermer une composition comportant une charge constituée au moins en partie desdites fibres.The device may also include a woven fabric, a nonwoven fabric or a felt made with at least one of said fibers. As indicated above, the fibers can be fixed on any type of support, which can be magnetized so as to subject the fibers to a magnetic field and cause them, for example, to take on a particular configuration or to become magnetized. The fibers can be subjected to the magnetic field of a magnet fixed on a support. The device may also contain a composition comprising a filler constituted at least in part of said fibers.
D'une manière générale, l'une au moins des fibres peut présenter une plus grande dimension transversale comprise par exemple entre 0,5 et 500 μm, voire 50 et 500 μm. La dimension des fibres sera choisie en fonction de leur utilisation. D'une manière générale également, l'une au moins desdites fibres peut présenter une longueur comprise par exemple entre 0,5 et 50 mm. La longueur sera choisie en fonction de l'utilisation des fibres.In general, at least one of the fibers may have a larger transverse dimension of, for example, between 0.5 and 500 μm, or even 50 and 500 μm. The size of the fibers will be chosen according to their use. Generally also, at least one of said fibers may have a length of, for example, between 0.5 and 50 mm. The length will be chosen according to the use of the fibers.
Dans une réalisation particulière, au moins l'une des fibres comporte, outre une matière synthétique et les particules magnétiques, des particules capables d'absorber un liquide ou un composé en solution dans ce liquide ou des particules capables de se dissoudre dans un liquide. Le liquide peut être par exemple de l'eau, une huile, un alcool ou tout type de solvant, plus généralement. Les fibres peuvent renfermer des particules d'un ou plusieurs matériaux choisis dans la Kste suivante : polymères hydrogonflants ou lipogonflants, polyacrylates réticulés super absorbants à fort taux de gonflement dans l'eau, alcool polyvinylique, polymères carboxyvinyliques, dérivés semi-synthétiques de la cellulose, amidons, bio- gommes, bio-saccharides, scléro-glucanes, caséine, phytocoUoïdes tels que les alginates, gélatine, fibres de coton, gélanes, xantane, laponite, silices, notamment la silice colloïdale, ou des mélanges de ceux-ci.In a particular embodiment, at least one of the fibers comprises, in addition to a synthetic material and the magnetic particles, particles capable of absorbing a liquid or a compound in solution in this liquid or particles capable of dissolving in a liquid. The liquid can for example be water, an oil, an alcohol or any type of solvent, more generally. The fibers may contain particles of one or more materials chosen in the following Kste: hydrogonflating or lipo-inflating polymers, cross-linked super absorbent polyacrylates with high swelling rate in water, polyvinyl alcohol, carboxyvinyl polymers, semi-synthetic derivatives of cellulose , starches, bio-gums, bio-saccharides, sclero-glucans, casein, phytocoUoids such as alginates, gelatin, cotton fibers, gels, xantane, laponite, silicas, in particular colloidal silica, or mixtures thereof.
Les fibres peuvent être fixes ou mobiles.The fibers can be fixed or mobile.
L'invention a encore pour objet un procédé de fabrication d'un dispositif de conditionnement et/ou d'application comportant des fibres telles que définies plus haut, caractérisé par le fait qu'il comporte une étape d'exposition desdites fibres à un champ magnétique, afin par exemple de leur donner une aimantation d'orientation voulue.The invention also relates to a method of manufacturing a packaging and / or application device comprising fibers as defined above, characterized in that it comprises a step of exposing said fibers to a field. magnetic, for example to give them a desired orientation magnetization.
L'invention a encore pour objet une fibre poreuse magnétique.The invention also relates to a porous magnetic fiber.
L'invention a encore pour objet une fibre magnétique rugueuse. D'autres caractéristiques et avantages de la présente invention apparaîtront à la lecture de la description détaillée qui va suivre, d'exemples non limitatifs de mise en œuvre, et à l'examen du dessin annexé (qui fait partie intégrante de la description), sur lequel :The invention also relates to a rough magnetic fiber. Other characteristics and advantages of the present invention will appear on reading the detailed description which follows, of nonlimiting examples of implementation, and on examining the appended drawing (which forms an integral part of the description), on which :
- la figure 1 est une vue schématique, en section transversale, d'un exemple de fibre présentant des propriétés magnétiques,FIG. 1 is a diagrammatic view, in cross section, of an example of a fiber having magnetic properties,
- les figures 2 à 4 sont des vues analogues à la figure 1, représentant des variantes de réalisation,FIGS. 2 to 4 are views similar to FIG. 1, showing alternative embodiments,
- les figures 5A et 5B sont des coupes axiales schématiques représentant une fibre incorporant, en plus des corps magnétiques, des particules aptes à gonfler en présence d'un liquide,FIGS. 5A and 5B are schematic axial sections representing a fiber incorporating, in addition to the magnetic bodies, particles capable of swelling in the presence of a liquid,
- les figures 6A et 6B sont des coupes axiales schématiques d'une fibre comportant, en plus des corps magnétiques, des particules solubles dans un liquide,FIGS. 6A and 6B are schematic axial sections of a fiber comprising, in addition to the magnetic bodies, particles soluble in a liquid,
- la figure 7 illustre la formation d'un gel à la surface de la fibre,FIG. 7 illustrates the formation of a gel on the surface of the fiber,
- la figure 8 représente une réalisation dans laquelle les particules autres que magnétiques sont présentes à la surface de la fibre uniquement,FIG. 8 represents an embodiment in which the particles other than magnetic are present on the surface of the fiber only,
- les figures 9A à 9R. sont des coupes transversales schématiques illustrant diverses sections possibles pour les fibres, - la figure 10 illustre la fabrication des fibres par extrusion,- Figures 9A to 9R. are schematic cross sections illustrating various possible sections for the fibers, FIG. 10 illustrates the manufacture of fibers by extrusion,
- la figure 11 illustre la magnétisation des fibres après l'extrusion,FIG. 11 illustrates the magnetization of the fibers after the extrusion,
- les figures 12 à 26 représentent divers exemples de dispositifs de conditionnement et/ou d'application. - la figure 27 illustre l'orientation des poils d'un flocage réalisé avec des fibres aimantables sous l'effet des lignes du champ magnétique généré par un aimant,- Figures 12 to 26 show various examples of packaging and / or application devices. FIG. 27 illustrates the orientation of the bristles of a flocking produced with magnetizable fibers under the effect of the lines of the magnetic field generated by a magnet,
- les figures 28A et 28B illustrent la déviation des poils d'une brosse sous l'effet des interactions magnétiques,FIGS. 28A and 28B illustrate the deflection of the bristles of a brush under the effect of magnetic interactions,
- les figures 29A et 29B illustrent la déviation des poils d'un pinceau sous l'effet des interactions magnétiques,FIGS. 29A and 29B illustrate the deflection of the bristles of a brush under the effect of magnetic interactions,
- la figure 30 représente un applicateur comprenant un élément d'application logé sous un capot protecteur, en l'absence d'utilisation,FIG. 30 represents an applicator comprising an application element housed under a protective cover, in the absence of use,
- la figure 31 représente une particule magnétique enrobée, etFIG. 31 represents a coated magnetic particle, and
- la figure 32 représente une particule magnétique formée par dépôt d'une substance magnétique sur un corps amagnétique.- Figure 32 shows a magnetic particle formed by depositing a magnetic substance on a non-magnetic body.
Dans toutes les figures, les proportions relatives des différents éléments n'ont pas toujours été respectées, afin de rendre le dessin plus clair.In all the figures, the relative proportions of the different elements have not always been respected, in order to make the drawing clearer.
On a représenté sur la figure 1, en section transversale, une fibre pouvant être utilisée dans un dispositif de conditionnement et ou d'application conforme à l'invention. Cette fibre est réalisée, dans l'exemple décrit, par extrusion d'une matière thermoplastique 11 renfermant une charge de particules 12 présentant des propriétés magnétiques. Les particules magnétiques 12 peuvent être réalisées par fragmentation d'une substance magnétique ou par dépôt d'une substance magnétique M sur un corps C amagnétique, par exemple une microbille ou une fibre de bois comme illustré sur la figure 32. Les particules magnétiques peuvent encore comporter un noyau magnétique M et une couche extérieure R amagnétique, par exemple une couche de résine, notamment de cyanoacrylate, comme illustré à la figure 31,There is shown in Figure 1, in cross section, a fiber which can be used in a packaging and or application device according to the invention. This fiber is produced, in the example described, by extrusion of a thermoplastic material 11 containing a charge of particles 12 having magnetic properties. The magnetic particles 12 can be produced by fragmenting a magnetic substance or by depositing a magnetic substance M on a non-magnetic body C, for example a microbead or a wood fiber as illustrated in FIG. 32. The magnetic particles can also comprise a magnetic core M and an non-magnetic outer layer R, for example a layer of resin, in particular of cyanoacrylate, as illustrated in FIG. 31,
Dans l'exemple illustré, la fibre est pleine et présente une section circulaire, mais elle pourrait présenter d'autres sections, comme expliqué plus loin. La fibre peut être réalisée par exemple au moyen d'une installation représentée à la figure 10, comportant une extrudeuse 20 et un bain 21 d'un liquide de refroidissement dans lequel sont immergées les fibres à leur sortie de l'extrudeuse. L'invention n'est pas limitée à des fibres comportant des particules magnétiques 12 dispersées de manière sensiblement homogène au sein de la matière plastique 11 et les particules magnétiques peuvent être déposées uniquement à la surface des fibres, par un procédé approprié, par exemple d'enduction, comme illustré à la figure 2 ou confinées à l'intérieur de la fibre, comme illustré à la figure 3. On peut également remplacer les particules magnétiques par un noyau central 14, comme illustré à la figure 4. Les fibres peuvent encore être réalisées par enrobage de fibres amagnétiques par des particules magnétiques, le tout pouvant être encapsulé dans une résine.In the example illustrated, the fiber is full and has a circular section, but it could have other sections, as explained below. The fiber can be produced for example by means of an installation shown in FIG. 10, comprising an extruder 20 and a bath 21 of a cooling liquid in which the fibers are immersed at their outlet from the extruder. The invention is not limited to fibers comprising magnetic particles 12 dispersed in a substantially homogeneous manner within the plastic material 11 and the magnetic particles can be deposited only on the surface of the fibers, by an appropriate method, for example d coating, as illustrated in FIG. 2 or confined inside the fiber, as illustrated in FIG. 3. The magnetic particles can also be replaced by a central core 14, as illustrated in FIG. 4. The fibers can also be made by coating non-magnetic fibers with magnetic particles, all of which can be encapsulated in a resin.
La proportion massique de particules magnétiques dans une fibre peut être comprise par exemple entre 0,2 et 30 %.The mass proportion of magnetic particles in a fiber can be for example between 0.2 and 30%.
On pourra utiliser comme matériaux magnétiques, par exemple l'un de ceux mentionnés précédemment.One can use as magnetic materials, for example one of those mentioned above.
La fibre peut comporter des charges supplémentaires en plus des corps présentant des propriétés magnétiques, et notamment une charge de particules susceptibles d'absorber et/ou de gonfler au contact d'un liquide, notamment au contact du produit cosmétique ou de soins à appliquer. La fibre peut notamment comporter des particules hydroabsorbantes et ou hydrogonflables. Comme composés absorbeurs de liquide, on peut citer, par exemple, les polymères hydrogonflants ou lipogonflants, les polyacrylates réticulés super absorbants à fort taux de gonflement dans l'eau, l'alcool polyvinylique, les polymères carboxyvinyhques, les dérivés semi-synthétiques de la cellulose, les amidons, les bio-gommes, les bio-saccharides, les scléro-glucanes, la caséine, les phytocoUoïdes tels que les alginates, la gélatine, les fibres de coton, les gélanes, le xantane, la laponite, les silices, notamment la silice colloïdale, ou des mélanges de ceux-ci, cette liste n'étant pas limitative. On a représenté sur la figure 5A une fibre comportant une charge de particules 30 d'un composé hydrogonflant, avant mise au contact de la fibre avec un liquide, par exemple de l'eau, et sur la figure 5B la même fibre après contact avec ce liquide.The fiber may include additional fillers in addition to the bodies having magnetic properties, and in particular a charge of particles capable of absorbing and / or swelling on contact with a liquid, in particular on contact with the cosmetic or care product to be applied. The fiber may in particular comprise water-absorbing and or water-swellable particles. As liquid-absorbing compounds, mention may be made, for example, of hydrogonflating or lipo-inflating polymers, cross-linked polyacrylates which are super absorbent with a high swelling rate in water, polyvinyl alcohol, carboxyvinyl polymers, semi-synthetic derivatives of cellulose, starches, bio-gums, bio-saccharides, sclero-glucans, casein, phytocoUoids such as alginates, gelatin, cotton fibers, gelans, xantane, laponite, silicas, in particular colloidal silica, or mixtures thereof, this list not being limiting. FIG. 5A shows a fiber comprising a charge of particles 30 of a hydrogonflating compound, before bringing the fiber into contact with a liquid, for example water, and in FIG. 5B the same fiber after contact with this liquid.
Le gonflement des particules 30 permet de produire un relief à la surface de la fibre, un tel relief étant utile notamment pour permettre à la fibre de se charger avec une quantité supérieure de produit ou d'accrocher davantage les cils dans le cas où la fibre est utilisée comme poil de brosse à mascara, par exemple. Les particules 30 peuvent également être utiles pour absorber au sein de la fibre une ou plusieurs substances, par exemple des conservateurs ou des actifs cosmétiques ou dermatologiques.The swelling of the particles 30 makes it possible to produce a relief on the surface of the fiber, such relief being useful in particular to allow the fiber to be loaded with a greater quantity of product or to hang the eyelashes more in the case where the fiber is used as a mascara brush bristle, for example. The particles can also be useful for absorbing one or more substances within the fiber, for example preservatives or cosmetic or dermatological active agents.
En particulier, on peut introduire dans le bain 21 utilisé pour refroidir les fibres à leur sortie de l'extrudeuse un ou plusieurs composés solubilisés dans le liquide du bain, par exemple des conservateurs, ces composés étant absorbés par les particules 30 lorsque les fibres plongent dans le bain 21. Ainsi, les fibres sortant du bain 21 sont chargées avec les composés qui ont été pompés par les particules 30 contenues dans les fibres. Ces composés peuvent être ensuite progressivement relargués au contact d'un produit cosmétique ou de soins, afin d'en améUorer la conservation, par exemple. Les fibres peuvent être déshydratées à la sortie du bain 21.In particular, one or more compounds solubilized in the liquid of the bath, for example preservatives, can be introduced into the bath 21 used to cool the fibers at their exit from the extruder. These compounds are absorbed by the particles 30 when the fibers are immersed in the bath 21. Thus, the fibers leaving the bath 21 are loaded with the compounds which have been pumped by the particles 30 contained in the fibers. These compounds can then be gradually released on contact with a cosmetic or care product, in order to improve their conservation, for example. The fibers can be dehydrated at the exit of the bath 21.
Les fibres peuvent encore contenir, en plus des corps présentant des propriétés magnétiques, des particules 40 solubles dans un liquide, par exemple l'eau du bain 21 utilisé pour refroidir les fibres à leur sortie de l'extrudeuse. Ces particules 40 peuvent être constituées par exemple par un sel ou un sucre soluble dans le liquide utilisé, voire de la gélatine lorsque le liquide est de l'eau. On a représenté sur la figure 6 A une fibre contenant de telles particules 40, avant dissolution, c'est-à-dire par exemple juste à la sortie de l'extrudeuse 20 et sur la figure 6B la même fibre après passage dans le bain 21. On remarque que les particules solubles 40 qui étaient présentes à la surface de la fibre ont été dissoutes par le liquide du bain 21, créant une rugosité à la surface.de la fibre, voire rendant la fibre poreuse. Une telle rugosité ou porosité peut être utilisée pour augmenter le chargement de la fibre en produit, par exemple. La rugosité ou porosité obtenue dépendra de la granulométrie initiale des particules 40. Les particules 40 peuvent également n'être dissoutes qu'en partie à leur sortie du bain 21, de sorte qu'eUes continuent à se dissoudre au contact du produit cosmétique, ou de soins présent à leur surface. Les particules 40 peuvent être constituées d'une ou plusieurs substances ayant un effet cosmétique ou dermatologique. Dans ce cas, la dissolution des particules 40 au contact du produit peut s'accompagner de la libération de ces substances sur la surface traitée. Les fibres peuvent le cas échéant être exposées à des chocs visant à provoquer ou à faciliter le départ des particules 40 présentes en surface.The fibers may also contain, in addition to the bodies having magnetic properties, particles 40 soluble in a liquid, for example bath water 21 used to cool the fibers as they exit the extruder. These particles 40 can consist, for example, of a salt or a sugar soluble in the liquid used, or even gelatin when the liquid is water. FIG. 6A shows a fiber containing such particles 40, before dissolution, that is to say for example just at the outlet of the extruder 20 and in FIG. 6B the same fiber after passing through the bath 21. It is noted that the soluble particles 40 which were present on the surface of the fiber were dissolved by the liquid in the bath 21, creating a roughness on the surface . of the fiber, or even making the fiber porous. Such roughness or porosity can be used to increase the loading of the fiber with product, for example. The roughness or porosity obtained will depend on the initial particle size of the particles 40. The particles 40 may also only be partially dissolved when they leave the bath 21, so that they continue to dissolve on contact with the cosmetic product, or of care present on their surface. The particles 40 may consist of one or more substances having a cosmetic or dermatological effect. In this case, the dissolution of the particles 40 in contact with the product can be accompanied by the release of these substances on the treated surface. The fibers may, where appropriate, be exposed to impacts aimed at causing or facilitating the departure of the particles 40 present on the surface.
Les particules 40 peuvent encore être réalisées dans un matériau qui n'est pas soluble dans l'eau du bain 21 mais qui est seulement soluble, progressivement, dans le produit cosmétique ou de soins présent au contact des fibres.The particles 40 can also be produced in a material which is not soluble in the bath water 21 but which is only gradually soluble in the cosmetic or care product present in contact with fibers.
On peut également introduire dans la fibre, en plus des corps magnétiques, des particules 50 aptes à se gélifier au contact d'un liquide, de manière à former une couche de gel 51 à la surface de la fibre, comme illustré à la figure 7. Une telle couche de gel 51 peut modifier par exemple l'affinité de la fibre avec le produit cosmétique ou de soins à son contact. Le gel peut encore se déposer sur la surface traitée, par exemple les cils, pour améliorer leur tenue, leur aspect ou le glissement de l'applicateur à leur contactIt is also possible to introduce into the fiber, in addition to the magnetic bodies, particles 50 capable of gelling on contact with a liquid, so as to form a gel layer 51 on the surface of the fiber, as illustrated in FIG. 7 Such a gel layer 51 can modify, for example, the affinity of the fiber with the cosmetic or care product in contact with it. The gel can also be deposited on the treated surface, for example the eyelashes, to improve their hold, their appearance or the sliding of the applicator in contact with them.
L'utihsation de particules capables d'absorber un liquide, notamment de l'eau, peut encore présenter l'avantage de retarder le séchage d'une composition cosmétique ou de soins à la surface de la fibre, lorsque le liquide absorbé par les particules est susceptible d'être relargué progressivement pour compenser l'évaporation d'un solvant contenu dans la composition.The use of particles capable of absorbing a liquid, in particular water, may also have the advantage of delaying the drying of a cosmetic or care composition on the surface of the fiber, when the liquid absorbed by the particles is capable of being gradually released to compensate for the evaporation of a solvent contained in the composition.
L'utilisation des particules 30, 40 ou 50 peut permettre également de créer à la surface de la fibre des zones d'ancrage privilégiées pour le produit, par exemple grâce à affinité des particules utihsées vis-à-vis de composés hydrophiles ou lipophiles contenus dans le produit. Ce dernier peut éventuellement être une émulsion huile/eau et les fibres absorber uniquement l'huile ou l'eau et plus généralement absorber un composant du produit de manière sélective.The use of particles 30, 40 or 50 can also make it possible to create privileged anchoring zones for the product on the surface of the fiber, for example by virtue of the affinity of the particles used with respect to the hydrophilic or lipophilic compounds contained. in the product. The latter can optionally be an oil / water emulsion and the fibers absorb only oil or water and more generally absorb a component of the product selectively.
Les particules 30, 40 ou 50 présentant des propriétés autres que magnétiques peuvent, le cas échéant, être présentes à la surface uniquement des fibres, comme illustré à la figure 8.The particles 30, 40 or 50 having properties other than magnetic can, if necessary, be present on the surface only of the fibers, as illustrated in FIG. 8.
La granulométrie initiale des particules 30, 40 ou 50 est comprise par exemple entre 0,1 ou 300 μm, voire entre 5 et 200 μm, voire encore entre 10 et 150 μm. La proportion des particules 30, 40 ou 50 est par exemple comprise entre 0 et 20 % en masse, voire entre 0 et 6 % en masse, à sec.The initial particle size of the particles 30, 40 or 50 is for example between 0.1 or 300 μm, or even between 5 and 200 μm, or even still between 10 and 150 μm. The proportion of particles 30, 40 or 50 is for example between 0 and 20% by mass, even between 0 and 6% by mass, dry.
On peut donner aux fibres des sections transversales très diverses, autres que circulaire pleine, comme on va maintenant le décrire en référence aux figures 9A à 9R.The fibers can be given very diverse cross sections, other than solid circular, as will now be described with reference to FIGS. 9A to 9R.
Les fibres peuvent être extradées avec une section transversale plate,- comme illustré sur la figure 9A, en croix comme représenté sur la figure 9B, en forme d'étoile à trois branches, comme illustré sur la figure 9'C. Les fibres peuvent présenter une section creuse, comme représenté sur la figure 9D ou pleine avec une rainure capiUaire, comme illustré à la figure 9E. Les fibres peuvent encore présenter une section transversale en U, comme illustré sur la figure 9F, une section transversale en I comme Ulustré sur la figure 9H, en T comme illustré sur la figure 91, en V comme illustré sur la figure 9J, en Z comme iUustré sur la figure 9K ou une combinaison des formes précitées, par exemple la combinaison représentée à la figure 9G des formes correspondant aux figures 9B et 9C. On a représenté sur la figure 9L une fibre de section carrée et creuse, sur la figure 9 une fibre de section carrée et pleine, sur la figure 9N une fibre de section en étoile et creuse, sur la figure 9P une fibre de section triangulaire et creuse, sur la figure 9Q une fibre de section formant des gorges à sa périphérie et sur la figure 9R une fibre ayant une section réniforme. Les fibres peuvent être exposées à un champ magnétique d'aimantation à la sortie du bain 21, au moyen d'un dispositif d'aimantation 60, comme illustré à la figure 11, afin par exemple d'être magnétisées avec une polarité prédéfinie.The fibers can be extradited with a flat cross section, - as illustrated in FIG. 9A, crosswise as represented in FIG. 9B, in the shape of a three-pointed star, as illustrated in FIG. 9 ' C. The fibers can have a hollow section, as shown in Figure 9D or solid with a cap groove, as shown in Figure 9E. The fibers may also have a U-shaped cross section, as illustrated in figure 9F, a cross section in I as illustrated in figure 9H, in T as illustrated in figure 91, in V as illustrated in figure 9J, in Z as illustrated in figure 9K or a combination of the shapes mentioned above, for example the combination shown in FIG. 9G of the shapes corresponding to FIGS. 9B and 9C. FIG. 9L shows a fiber of square and hollow section, in FIG. 9 a fiber of square and solid section, in FIG. 9N a fiber of star and hollow section, in FIG. 9P a fiber of triangular section and hollow, in FIG. 9Q a fiber of section forming grooves at its periphery and in FIG. 9R a fiber having a reniform section. The fibers can be exposed to a magnetic field of magnetization at the exit of the bath 21, by means of a magnetization device 60, as illustrated in FIG. 11, in order for example to be magnetized with a predefined polarity.
La magnétisation des fibres, le cas échéant, peut également avoir lieu après incorporation de ces fibres dans un dispositif de conditionnement et/ou d'application, en soumettant ce dispositif ou un lot de ces dispositifs à un champ de magnétisation. Le fait de ne magnétiser les fibres qu'une fois celles-ci en place dans le dispositif de conditionnement et oU d'application peut permettre de faciliter la fabrication en limitant les risques d'agglomération de fibres.The magnetization of the fibers, if necessary, can also take place after incorporation of these fibers into a packaging and / or application device, by subjecting this device or a batch of these devices to a magnetization field. The fact of magnetizing the fibers only once they are in place in the packaging device or application can facilitate manufacturing by limiting the risks of fiber agglomeration.
Les fibres peuvent être utilisées dans divers appUcateurs et dispositifs de conditionnement, comme cela va maintenant être décrit.The fibers can be used in various appUcateurs and conditioning devices, as will now be described.
On a représenté sur la figure 12 un dispositif de conditionnement et d'application 100, comportant un récipient 101 pour contenir un produit P à appliquer tel qu'un mascara et un applicateur 102. Le récipient 101 est muni d'un organe d'essorage 106 qui peut, dans une variante non représentée, être floqué. L'applicateur 102 comprend une tige 103, munie à une extrémité d'un organe de préhension 104 constituant également un capuchon de fermeture du récipient 101 et à l'autre extrémité d'une brosse 105. Cette dernière comporte une âme constituée par un fil métallique torsadé, dans les spires duquel sont retenus des poils constitués par des fibres présentant des propriétés magnétiques, teUes que des fibres qui viennent d'être décrites. Les pôles magnétiques de la brosse peuvent être orientés par exemple dans l'axe de la tige 103 ou perpendiculairement à l'axe de la tige 103. L'âme torsadée peut être réalisée dans un matériau amagnétique tel qu'un inox amagnétique ou en variante dans un matériau présentant des • propriétés magnétiques. L'âme peut ainsi interagir magnétiquement avec les poils. Les poils de la brosse 105 peuvent être aimantés, de sorte que l'aimantation d'un poU de la brosse exerce une action sur les poils voisins, les interactions magnétiques entre les poils pouvant servir par exemple à donner aux poils des orientations voulues. Selon l'orientation des pôles magnétiques de la brosse, l'effet sur l'orientation des poUs sera différent. A titre d'exemple, on a illustré sur les figures 28A et 28B l'effet de déviation latérale des poils de la brosse en cas de champ magnétique transverse.FIG. 12 shows a packaging and application device 100, comprising a container 101 for containing a product P to be applied such as a mascara and an applicator 102. The container 101 is provided with a wiper member 106 which can, in a variant not shown, be flocked. The applicator 102 comprises a rod 103, provided at one end with a gripping member 104 also constituting a closure cap for the container 101 and at the other end with a brush 105. The latter comprises a core constituted by a wire twisted metal, in the turns of which hairs are retained consisting of fibers having magnetic properties, such as fibers which have just been described. The magnetic poles of the brush can be oriented for example in the axis of the rod 103 or perpendicular to the axis of the rod 103. The twisted core can be made of a non-magnetic material such as non-magnetic stainless steel or alternatively in a material with magnetic properties. The soul can thus interact magnetically with the hairs. The bristles of the brush 105 can be magnetized, so that the magnetization of a poU of the brush exerts an action on the neighboring bristles, the magnetic interactions between the bristles being able for example to give the bristles the desired orientations. Depending on the orientation of the magnetic poles of the brush, the effect on the orientation of the poUs will be different. By way of example, FIGS. 28A and 28B have illustrated the effect of lateral deflection of the bristles of the brush in the event of a transverse magnetic field.
L'aimantation des poils peut également être mise à profit uniquement pour exercer lors de l' appUcation du produit sur les cils un champ magnétique ayant une action bénéfique sur ceux-ci ou sur une partie du visage, par exemple les paupières.The magnetization of the hairs can also be used only to exert during the application of the product to the eyelashes a magnetic field having a beneficial action on them or on a part of the face, for example the eyelids.
Le champ magnétique exercé, par les poils de la brosse est susceptible d'évoluer dans le temps, notamment lorsque la configuration de la brosse est modifiée, par exemple lors du retrait de l'applicateur ou lors de l'application. Le produit P peut présenter des propriétés magnétiques, par exemple contenir des particules aimantables ou aimantées. Dans le cas où le produit P présente des propriétés magnétiques, le fait d'avoir des poils de brosse qui présentent également des propriétés magnétiques peut permettre de favoriser le chargement de la brosse en produit, par exemple par attraction du produit par les poUs de la brosse. Le produit peut encore contenir des fibres ou des paUlettes présentant des propriétés magnétiques et l'applicateur interagir magnétiquement avec ces paillettes, pour les amener par exemple dans une orientation particulière au moment de l'application, afin par exemple de favoriser le glissement de l'applicateur.The magnetic field exerted by the bristles of the brush is liable to change over time, in particular when the configuration of the brush is modified, for example when the applicator is withdrawn or during application. The product P can have magnetic properties, for example containing magnetizable or magnetized particles. In the case where the product P has magnetic properties, having brush bristles which also have magnetic properties can make it possible to favor the loading of the brush with product, for example by attraction of the product by the tips of the brush. The product may also contain fibers or palettes with magnetic properties and the applicator interact magnetically with these flakes, to bring them for example in a particular orientation at the time of application, in order for example to promote the sliding of the applicator.
On a représenté. sur la figure 13 un dispositif 110 pour le conditionnement et l'application d'un vernis à ongles, comportant un récipient 111 et un appticateur 112 comprenant une tige 113 munie à une extrémité d'un élément de préhension 114 constituant également un capuchon de fermeture du récipient et à l'autre extrémité d'un pinceau 115 comprenant un faisceau de poils relativement groupés. Ces derniers sont réalisés à partir de fibres présentant des propriétés magnétiques, lesquelles peuvent être mises à profit pour amener les poils du pinceau 115 dans une orientation prédéfinie, afin de faciUter le chargement du pinceau 115 en produit ou exercer une action sur la surface traitée. Les interactions magnétiques entre les poils du pinceau, selon la polarité du champ magnétique de chaque poU, peuvent contribuer à regrouper les poUs ou au contraire à les écarter. A titre d'exemple, on a illustré de manière très schématique sur les figures 29A et 29B un effet d'écartement des poils dû à des interactions magnétiques entre les poUs. Le produit P peut présenter ou non des propriétés magnétiques.We represented. in FIG. 13, a device 110 for packaging and applying a nail varnish, comprising a container 111 and an applicator 112 comprising a rod 113 provided at one end with a gripping element 114 also constituting a closure cap of the container and at the other end of a brush 115 comprising a bundle of relatively grouped bristles. The latter are made from fibers having magnetic properties, which can be used to bring the bristles of the brush 115 in a predefined orientation, in order to facilitate the loading of the brush 115 with product or to exert an action on the treated surface. Magnetic interactions between the bristles of the brush, according to the polarity of the magnetic field of each poU, can contribute to group the poUs or on the contrary to separate them. By way of example, a very schematic illustration has been illustrated in FIGS. 29A and 29B of an effect of separation of the bristles due to magnetic interactions between the bristles. The product P may or may not have magnetic properties.
On a représenté sur la figure 14 un dispositif de conditionnement et d'appUcation 120 qui comporte un récipient 121 contenant un produit P, par exemple un rouge à lèvres liquide, et un applicateur 122 comportant une tige 123 munie à une extrémité d'un capuchon 124 de fermeture du récipient 121, qui sert également d'organe de préhension, et à l'autre extrémité d'un embout d'application 124, recouvert par un flocage réaUsé avec des fibres présentant des propriétés magnétiques. Le dispositif 120 comporte également un essoreur constitué par un bloc de mousse 125. Ce bloc de mousse peut présenter des propriétés magnétiques ou non. On peut notamment conférer au bloc de mousse 125 une certaine aimantation en incorporant en son sein des particules aimantées. L'aimantation dé l'essoreur peut servir par exemple à magnétiser le flocage de l' embout 124 lors du retrait de l' applicateur 122.FIG. 14 shows a packaging and appUcation device 120 which comprises a container 121 containing a product P, for example a liquid lipstick, and an applicator 122 comprising a rod 123 provided at one end with a cap 124 for closing the container 121, which also serves as a gripping member, and at the other end of an applicator tip 124, covered by a flocking made with fibers having magnetic properties. The device 120 also includes a wringer formed by a block of foam 125. This block of foam may have magnetic properties or not. One can in particular give the foam block 125 a certain magnetization by incorporating within it magnetic particles. The magnetization of the wiper can be used, for example, to magnetize the flocking of the end piece 124 when the applicator 122 is withdrawn.
On a représenté sur la figure 15 un dispositif de conditionnement et d'application 130 d'un produit P, notamment un rouge à lèvres liquide, comportant un embout 131 recouvert par un flocage 132 réaUsé avec des fibres présentant des propriétés magnétiques.FIG. 15 shows a device for packaging and applying 130 of a product P, in particular a liquid lipstick, comprising a nozzle 131 covered by a flocking 132 made with fibers having magnetic properties.
On a représenté sur la figure 16 un pinceau 140 destiné à l'application d'une poudre, dont les poils sont réalisés avec des fibres présentant des propriétés magnétiques.FIG. 16 shows a brush 140 intended for the application of a powder, the bristles of which are produced with fibers having magnetic properties.
Sur la figure 17, on a représenté un applicateur 150 comportant une mousseIn Figure 17, there is shown an applicator 150 having a foam
151 recouverte à sa surface par un flocage 152 constitué de fibres présentant des propriétés magnétiques. Un tel appUcateur peut servir par exemple à appliquer un blush sur la peau.151 covered on its surface by a flocking 152 made up of fibers having magnetic properties. Such an appUcator can be used for example to apply a blush on the skin.
On a représenté sur la figure 18A un applicateur de rouge à lèvres liquide 160 comportant un embout 161 en élastomère floqué et sur la figure 18B un eye-liner 160' comportant également un embout 161' en élastomère floqué. Dans les deux cas, les poiïs du flocage sont constitués par des fibres présentant des propriétés magnétiques.FIG. 18A shows a liquid lipstick applicator 160 comprising an endpiece 161 of flocked elastomer and in FIG. 18B an eyeliner 160 'also comprising an endpiece 161' of flocked elastomer. In both cases, the flocking particles consist of fibers having magnetic properties.
Les fibres peuvent encore être utilisées pour réaliser un flocage d'une houppette 170, comme Ulustré à la figure 19 ou d'une éponge à démaquiller 180, représentée sur la figure 20.The fibers can also be used to flock a puff 170, as illustrated in FIG. 19 or a make-up sponge 180, shown in Figure 20.
Le revêtement de flocage peut encore s'étendre sur un film 191 fixé sur un bloc de mousse 192, comme c'est le cas dans l'applicateur 190 représenté sur la figure 21.The flock coating may also extend over a film 191 fixed to a block of foam 192, as is the case in the applicator 190 shown in FIG. 21.
On peut également utiliser des fibres présentant des propriétés magnétiques dans un disque 200 ou une serviette comportant au moins une couche 201 d'un non-tissé ou d'un tissu incorporant lesdites fibres, comme illustré sur la figure 22.It is also possible to use fibers having magnetic properties in a disc 200 or a towel comprising at least one layer 201 of a nonwoven or of a fabric incorporating said fibers, as illustrated in FIG. 22.
On a représenté sur la figure 23 un peigne 210 pour l'application d'un produit sur les cils, comportant des dents floquées 211. Les poUs du flocage sont réalisés avec des fibres présentant des propriétés magnétiques. L'applicateur peut comporter un ou plusieurs aimants monoblocs en plus des fibres présentant des propriétés magnétiques.FIG. 23 shows a comb 210 for applying a product to the eyelashes, comprising flocked teeth 211. The flocking poUs are produced with fibers having magnetic properties. The applicator may include one or more monoblock magnets in addition to the fibers having magnetic properties.
A titre d'exemple, on a représenté sur la figure 24 un applicateur 220 comportant un manche 221 sur lequel est fixé un aimant 222. Ce dernier est recouvert par un bloc de mousse 223, lui-même revêtu extérieurement par un flocage 224 constitué de fibres présentant des propriétés magnétiques.By way of example, FIG. 24 shows an applicator 220 comprising a handle 221 on which a magnet 222 is fixed. The latter is covered by a block of foam 223, itself coated externally by a flocking 224 made of fibers with magnetic properties.
La présence de l'aimant 222 permet de soumettre les poils du flocage 294 à un champ magnétique.The presence of the magnet 222 makes it possible to subject the hairs of the flocking 294 to a magnetic field.
En particulier, les poils du flocage qui se raccordent sensiblement peφendiculairement au support sous-jacent peuvent s'orienter selon les Ugnes de ce champ magnétique M, comme illustré sur la figure 27. Les poils tendent à se dresser sur la surface de l'élément d'application ou à prendre d'autres orientations selon la position par rapport à l'aimant 222, ce qui permet par exemple de charger avec davantage de produit l'appUcateur ou de rendre l'application plus douce. De plus, lorsque le produit est une poudre amenée au contact de l'appUcateur et que ce dernier présente des propriétés magnétiques, les particules de poudre tendent à se déposer sur l'applicateur, notamment sur les fibres, et l'on réduit ainsi le risque de faire voler la poudre et l'effet sternutatoire.In particular, the hairs of the flocking which are connected substantially peφendicularly to the underlying support can be oriented along the lines of this magnetic field M, as illustrated in FIG. 27. The hairs tend to stand up on the surface of the element. application or to take other orientations according to the position relative to the magnet 222, which allows for example to load with more product the applicator or to make the application softer. In addition, when the product is a powder brought into contact with the applicator and the latter has magnetic properties, the powder particles tend to deposit on the applicator, in particular on the fibers, and the may cause the powder to fly and the sternutatory effect.
On a représenté sur la figure 25 un dispositif 230 dans lequel le produit est contenu dans une poche souple 231 surmontée d'une pompe 232. L'applicateur comporte une mousse 234, revêtue à sa surface d'un flocage 235 et solidaire d'un capot 236. Un aimant 237, logé dans la mousse 234 est porté par le capot 236. Les poils du flocage 235 présentent des propriétés magnétiques et sont soumis au champ magnétique de l'aimant 237, à l'instar de l'exemple de réaUsation précédent. On a représenté partiellement sur la figure 30 un applicateur 280 comportant un embout floqué 282 logé sous un capot 281 en l'absence d'utiUsation. L'utilisation de fibres contenant des hydroabsorbants ou des hydrogonflants permet de maintenir une ambiance humide sous le capot, retardant le dessèchement de l'embout, lequel pourrait être remplacé par d'autres éléments d'application, par exemple une brosse ou un pinceau. Bien entendu, l'invention n'est pas limitée aux exemples de réalisation qui viennent d'être donnés.FIG. 25 shows a device 230 in which the product is contained in a flexible bag 231 surmounted by a pump 232. The applicator comprises a foam 234, coated on its surface with a flocking 235 and secured to a cover 236. A magnet 237, housed in the foam 234 is carried by the cover 236. The hairs of the flocking 235 have magnetic properties and are subjected to the magnetic field of the magnet 237, like the example of embodiment. previous. Partially shown in FIG. 30 is an applicator 280 comprising a flocked tip 282 housed under a cover 281 in the absence of use. The use of fibers containing water-absorbents or water-swellings makes it possible to maintain a humid atmosphere under the hood, delaying the drying of the nozzle, which could be replaced by other application elements, for example a brush or a paint brush. Of course, the invention is not limited to the exemplary embodiments which have just been given.
On peut notamment prévoir, entre l'applicateur et le produit-contenu dans le récipient, un tamis 240 comme illustré sur la figure 26. Dans ce cas, le produit P peut contenir des particules magnétiques 241 et l'applicateur présenter, des propriétés magnétiques, par exemple parce qu'il est constitué d'un embout floqué dont le revêtement de flocage est constitué par des fibres aimantées. L'embout 242 est capable d'attirer les particules magnétiques 241 contenues dans le produit. En choisissant la taille des mailles du tamis 240, on peut faire en sorte que ces particules magnétiques 241 attirées par l'embout 242 ne passent pas au travers du tamis 240 mais déplacent du produit P vers l'embout 242, ce qui permet d'améliorer le chargement de l'embout 242 en produit. En variante, le produit P lui-même est magnétique, comprenant par exemple des particules magnétiques enrobées, et peut passer à travers les mailles du tamis 240.One can in particular provide, between the applicator and the product-contained in the container, a sieve 240 as illustrated in FIG. 26. In this case, the product P can contain magnetic particles 241 and the applicator present, magnetic properties , for example because it consists of a flocked tip whose flocking coating consists of magnetized fibers. The tip 242 is capable of attracting the magnetic particles 241 contained in the product. By choosing the mesh size of the sieve 240, it is possible to ensure that these magnetic particles 241 attracted by the end piece 242 do not pass through the sieve 240 but move from the product P to the end piece 242, which makes it possible to improve the loading of the nozzle 242 with product. As a variant, the product P itself is magnetic, comprising, for example, coated magnetic particles, and can pass through the meshes of the sieve 240.
Les fibres peuvent être aimantées sur une partie de leur longueur seulement. Les dispositifs de conditionnement et d'apphcation qui viennent d'être décrits peuvent comporter des fibres ayant des propriétés magnétiques mélangées à des fibres n'ayant pas de propriétés magnétiques, éventueUement chargées avec des particules d'un composé absorbeur de tiquide et/ou apte à gonfler au contact d'un liquide, ou capable de se dissoudre au contact d'un liquide, ce liquide étant par exemple de l'eau. The fibers can be magnetized over only part of their length. The packaging and apphcation devices which have just been described may comprise fibers having magnetic properties mixed with fibers having no magnetic properties, optionally loaded with particles of a liquid absorbent compound and / or suitable to swell on contact with a liquid, or capable of dissolving on contact with a liquid, this liquid being for example water.

Claims

REVENDICATIONS
1. Dispositif de conditionnement et/ou d'application d'un produit cosmétique et/ou de soins, caractérisé par le fait qu'il comprend des fibres comportant au moins un corps (12) aimanté ou aimantable.1. Device for packaging and / or applying a cosmetic and / or care product, characterized in that it comprises fibers comprising at least one magnetized or magnetizable body (12).
2. Dispositif selon la revendication 1, caractérisé par le fait que les fibres sont réalisées dans une matière synthétique.2. Device according to claim 1, characterized in that the fibers are made of a synthetic material.
3. Dispositif selon la revendication 1 ou 2, caractérisé par le fait qu'au moins l'une desdites fibres présente une section transversale sensiblement constante. 3. Device according to claim 1 or 2, characterized in that at least one of said fibers has a substantially constant cross section.
4. Dispositif selon l'une quelconque des revendications 1 à 3, caractérisé par le fait qu'au moins l'une desdites fibres est réalisée par extrusion ou coextrusion d'une ou plusieurs matières thermoplastiques et/ou élastomères.4. Device according to any one of claims 1 to 3, characterized in that at least one of said fibers is produced by extrusion or coextrusion of one or more thermoplastic and / or elastomeric materials.
5. Dispositif selon l'une quelconque des revendications 1 à 3, caractérisé par le fait que les fibres sont réalisées par enrobage. 5. Device according to any one of claims 1 to 3, characterized in that the fibers are made by coating.
6. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que lesdites particules (12) sont formées au moins en partie d'un matériau choisi dans la liste suivante : matériaux magnétiques doux, matériaux magnétiques durs, ferrites, notamment à base de zinc, nickel ou de manganèse, terres rares, sulfate de baryum, alUages fer silicium, fer cobalt, éventuellement chargés en molybdène, ou un mélange de ces matériaux.6. Device according to any one of the preceding claims, characterized in that the said particles (12) are formed at least in part from a material chosen from the following list: soft magnetic materials, hard magnetic materials, ferrites, in particular at base of zinc, nickel or manganese, rare earths, barium sulphate, alloys iron silicon, cobalt iron, possibly charged in molybdenum, or a mixture of these materials.
7. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait qu'il comporte des particules magnétiques enrobées.7. Device according to any one of the preceding claims, characterized in that it comprises coated magnetic particles.
8. Dispositif selon l'une quelconque des revendications 1 à 5, caractérisé par le fait qu'il comporte des particules magnétiques réaUsées par dépôt d'une substance magnétique sur un support amagnétique.8. Device according to any one of claims 1 to 5, characterized in that it comprises magnetic particles réaUsés by deposition of a magnetic substance on a non-magnetic support.
9. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait qu'au moins l'une desdites fibres comporte entre 0,2 et 30 % en poids de particules aimantées ou aimantables.9. Device according to any one of the preceding claims, characterized in that at least one of said fibers comprises between 0.2 and 30% by weight of magnetized or magnetizable particles.
10. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que l'une au moins desdites fibres est réalisée avec une matière plastique (11) choisie parmi les suivantes : polyamides, PET,- acétates,. PE, PP, PVC, polyester bloc amide, Rilsan® plastifié, élastomères, notamment élastomères de polyester, élastomères de PE, élastomères de sUicone, élastomères de nitrile, ou un mélange de ces matériaux.10. Device according to any one of the preceding claims, characterized in that at least one of said fibers is made of a plastic material (11) selected from the following: polyamides, PET, - acetates. PE, PP, PVC, polyester amide block, plasticized Rilsan ® , elastomers, especially polyester elastomers, PE elastomers, silicone elastomers, nitrile elastomers, or a mixture of these materials.
11. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que, pour l'une au moins desdites fibres, les particules magnétiques (12) sont présentes au moins à la surface de cette fibre.11. Device according to any one of the preceding claims, characterized in that, for at least one of said fibers, the magnetic particles (12) are present at least on the surface of this fiber.
12. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que, pour l'une au moins desdites fibres, les particules magnétiques (12) sont présentes à la surface de la fibre uniquement.12. Device according to any one of the preceding claims, characterized in that, for at least one of said fibers, the magnetic particles (12) are present on the surface of the fiber only.
13. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que, pour l'une au moins desdites fibres, les particules magnétiques sont présentes à l'intérieur de la fibre uniquement.13. Device according to any one of the preceding claims, characterized in that, for at least one of said fibers, the magnetic particles are present inside the fiber only.
14. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que, pour l'une au moins desdites fibres, les particules magnétiques (12) sont dispersées au sein de la matière plastique (11). 14. Device according to any one of the preceding claims, characterized in that, for at least one of said fibers, the magnetic particles (12) are dispersed within the plastic (11).
15. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que la section transversale de l'une au moins desdites fibres présente une forme choisie parmi les suivantes : de révolution ou non, en cercle, en carré plein ou creux, en disque, avec rainure éventuellement, en triangle plein ou creux, en étoile pleine ou creuse, en U, en V, en I, en T, en Z, en -, en +, réniforme, à trois branches, creuse, ou une combinaison de ces formes, la fibre pouvant être torsadée, éventuellement.15. Device according to any one of the preceding claims, characterized in that the cross section of at least one of said fibers has a shape chosen from the following: whether of revolution or not, in a circle, in a full or hollow square, in disc, with groove if necessary, in full or hollow triangle, in full or hollow star, in U, in V, in I, in T, in Z, in -, in +, reniform, with three branches, hollow, or a combination of these forms, the fiber possibly being twisted.
16. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que l'une au moins desdites fibres est aimantée.16. Device according to any one of the preceding claims, characterized in that at least one of said fibers is magnetized.
17. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait qu'il comporte un organe d'essorage (106 ; 125).17. Device according to any one of the preceding claims, characterized in that it comprises a wiper member (106; 125).
18. Dispositif selon la revendication précédente, caractérisé par le fait que l'organe d'essorage (145) présente des propriétés magnétiques.18. Device according to the preceding claim, characterized in that the wiper member (145) has magnetic properties.
19. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que l'une au moins desdites fibres appartient à un appUcateur (102 ; 112; 122 ; 140 ; 160 ; 170 ; 180 ; 190 ; 200 ; 210 ; 220 ; 234 ; 242) apte à être chargé en produit.19. Device according to any one of the preceding claims, characterized in that at least one of said fibers belongs to an appUcateur (102; 112; 122; 140; 160; 170; 180; 190; 200; 210; 220 ; 234; 242) able to be loaded with product.
20. Dispositif selon la revendication 19, caractérisé par le fait qu'il comporte un récipient (101 ; lll ; 121).20. Device according to claim 19, characterized in that it comprises a container (101; III; 121).
21. Dispositif selon la revendication 20, caractérisé par le fait que le récipient contient une composition renfermant des particules aptes à être attirées par les fibres de l'applicateur. 21. Device according to claim 20, characterized in that the container contains a composition containing particles capable of being attracted by the fibers of the applicator.
22. Dispositif selon la revendication 20, caractérisé par le fait que les fibres de l'appUcateur sont aimantables et par le fait que le récipient contient une composition renfermant des particules aimantées, les fibres étant susceptibles d'être soumises à l'action magnétique desdites particules aimantées.22. Device according to claim 20, characterized in that the fibers of the appUcator are magnetizable and in that the container contains a composition containing magnetized particles, the fibers being capable of being subjected to the magnetic action of said magnetic particles.
23. Dispositif selon l'une des revendications 19 à 22, caractérisé par le fait que l'appUcateur est une brosse à mascara et par le fait que l'un au moins des poils de la brosse est constitué par l'une desdites fibres.23. Device according to one of claims 19 to 22, characterized in that the appUcateur is a mascara brush and in that at least one of the bristles of the brush consists of one of said fibers.
24. Dispositif selon la revendication 23, caractérisé par le fait que les poils de la brosse sont solidaires d'une âme torsadée, et par le fait que l'âme est aimantée.24. Device according to claim 23, characterized in that the bristles of the brush are integral with a twisted core, and by the fact that the core is magnetized.
25. Dispositif selon l'une des revendications 19 à 22, caractérisé par le fait que l'applicateur est constitué par un pinceau et par le fait que l'un au moins des poils du pinceau est constitué par l'une desdites fibres.25. Device according to one of claims 19 to 22, characterized in that the applicator is constituted by a brush and by the fact that at least one of the bristles of the brush consists of one of said fibers.
26. Dispositif selon l'une quelconque des revendications 1 à 22, caractérisé par le fait qu'il comporte un revêtement de flocage dont l'un au moins des poils est constitué par l'une desdites fibres. 26. Device according to any one of claims 1 to 22, characterized in that it comprises a flocking coating of which at least one of the bristles is constituted by one of said fibers.
27. Dispositif selon la revendication 26, caractérisé par le fait que le revêtement de flocage recouvre au moins partiellement l'un des éléments suivants : les dents (231) d'un peigne, les poils d'une brosse, un essoreur, une mousse, une éponge, un film perforé ou non, un embout, un tissé, un non-tissé,27. Device according to claim 26, characterized in that the flock coating at least partially covers one of the following elements: the teeth (231) of a comb, the bristles of a brush, a wringer, a foam , a sponge, a perforated film or not, a nozzle, a woven, a non-woven,
28. Dispositif selon l'une quelconque des revendications 1 à 22, caractérisé par le fait qu'il comporte un tissé, un non-tissé ou un feutre réalisé avec au moins l'une desdites fibres.28. Device according to any one of claims 1 to 22, characterized in that it comprises a woven, a nonwoven or a felt made with at least one of said fibers.
29. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que les fibres sont soumises au champ magnétique (222 ; 237) d'un aimant fixé sur un support. 29. Device according to any one of the preceding claims, characterized in that the fibers are subjected to the magnetic field (222; 237) of a magnet fixed on a support.
30. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait qu'il renferme une composition comportant une charge constituée au moins en partie par lesdites fibres. 30. Device according to any one of the preceding claims, characterized in that it contains a composition comprising a filler constituted at least in part by said fibers.
31. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que l'une au moins desdites fibres présente un diamètre compris entre 0,5 et 500 μm.31. Device according to any one of the preceding claims, characterized in that at least one of said fibers has a diameter of between 0.5 and 500 μm.
32. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait que l'une au moins desdites fibres présente une longueur comprise entre 0,5 et 50 mm.32. Device according to any one of the preceding claims, characterized in that at least one of said fibers has a length of between 0.5 and 50 mm.
33. Dispositif selon l'une quelconque des revendications précédentes, caractérisé par le fait qu'au moins l'une des fibres comporte, outre une matière synthétique et les particules magnétiques, des particules capables d'absorber un liquide ou un composé en solution dans ce liquide ou des particules capables de se dissoudre dans un tiquide.33. Device according to any one of the preceding claims, characterized in that at least one of the fibers comprises, in addition to a synthetic material and the magnetic particles, particles capable of absorbing a liquid or a compound in solution in this liquid or particles capable of dissolving in a liquid.
34. Dispositif selon la revendication 33, caractérisé par le fait que la granulométrie initiale desdites particules, avant gonflement ou dissolution, est comprise entre 0,1 et 300 μm, et par le fait qu'une fibre au moins en contient entre 0 et 20 % en masse, par rapport à sa masse totale, à sec.34. Device according to claim 33, characterized in that the initial particle size of said particles, before swelling or dissolution, is between 0.1 and 300 μm, and by the fact that at least one fiber contains between 0 and 20 % by mass, relative to its total mass, dry.
35. Dispositif selon les revendications 33. ou 34, caractérisé par le fait que ledit liquide est de l'eau, une huile, un alcool.35. Device according to claims 33. or 34, characterized in that said liquid is water, an oil, an alcohol.
36. Dispositif selon l'une quelconque des revendications 33 à 35, caractérisé par le fait que l'une au moins desdites fibres renferme des particules d'un ou plusieurs matériaux choisis dans la liste suivante : polymères hydrogonflants ou hpogonflants, polyacrylates réticulés super absorbants à fort taux de gonflement dans l'eau, l'alcool polyvinylique, polymères carboxyvinyliques, dérivés semi-synthétiques de la ceUulose, amidons, bio-gommes, bio-saccharides, scléro-glucanes, caséine, phytocoUoïdes tels que les alginates, gélatine, fibres de coton, gélanes, xantane, laponite, silices, notamment la sitice colloïdale, ou des mélanges de ceux-ci.36. Device according to any one of claims 33 to 35, characterized in that at least one of the said fibers contains particles of one or more materials chosen from the following list: super-absorbent or hydrogonflating polymers, cross-linked polyacrylates with a high swelling rate in water, polyvinyl alcohol, carboxyvinyl polymers, semi-synthetic derivatives of ceUulose, starches, bio-gums, bio-saccharides, sclero-glucans, casein, phytocoUoids such as alginates, gelatin, cotton fibers, gelans, xantane, laponite, silicas, especially the colloidal sitice, or mixtures thereof.
37. Procédé de fabrication d'un dispositif de conditionnement et/ou d'apptication tel que défini dans l'une quelconque des revendications précédentes, caractérisé par le fait qu'A comporte une étape d'exposition des fibres à un champ magnétique, afin notamment de leur donner une aimantation d'orientation voulue. 37. A method of manufacturing a packaging and / or application device as defined in any one of the preceding claims, characterized in that A comprises a step of exposing the fibers to a magnetic field, in order in particular to give them a desired orientation magnetization.
EP01947527A 2000-07-12 2001-06-19 Device for packaging and/or applying a product containing fibres comprising at least a magnetised or magnetizable element Expired - Lifetime EP1196062B1 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
FR0009115 2000-07-12
FR0009115A FR2811525B1 (en) 2000-07-12 2000-07-12 DEVICE FOR APPLYING A PRODUCT, IN PARTICULAR MAKEUP OR CARE, TO KERATINIC FIBERS, IN PARTICULAR EYELASHES OR EYEBROWS
FR0105110 2001-04-13
FR0105110A FR2823491B1 (en) 2001-04-13 2001-04-13 DEVICE, PARTICULARLY FOR COSMETIC USE, COMPRISING A CONTAINER CONTAINING A PRODUCT TO BE APPLIED AND AN ELEMENT FOR GENERATING A MAGNETIC FIELD
FR0107310A FR2825247B1 (en) 2001-06-05 2001-06-05 CONDITIONING AND / OR APPLICATION DEVICE CONTAINING FIBERS COMPRISING AT LEAST ONE MAGNET OR MAGNET BODY
FR0107310 2001-06-05
PCT/FR2001/001911 WO2002003832A1 (en) 2000-07-12 2001-06-19 Device for packaging and/or applying a product containing fibres comprising at least a magnetised or magnetizable element

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EP1196062A1 true EP1196062A1 (en) 2002-04-17
EP1196062B1 EP1196062B1 (en) 2005-10-26

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EP (1) EP1196062B1 (en)
JP (2) JP2004502482A (en)
CN (1) CN100405954C (en)
AU (1) AU2001269191A1 (en)
BR (1) BR0106967B1 (en)
CA (1) CA2382142C (en)
DE (1) DE60114343T2 (en)
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