EP1176031B1 - Fabrication d'un support pour une plaque lithographique - Google Patents

Fabrication d'un support pour une plaque lithographique Download PDF

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Publication number
EP1176031B1
EP1176031B1 EP20010000213 EP01000213A EP1176031B1 EP 1176031 B1 EP1176031 B1 EP 1176031B1 EP 20010000213 EP20010000213 EP 20010000213 EP 01000213 A EP01000213 A EP 01000213A EP 1176031 B1 EP1176031 B1 EP 1176031B1
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EP
European Patent Office
Prior art keywords
substrate
salt
orthophosphate
metal
aluminium
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EP20010000213
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German (de)
English (en)
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EP1176031A1 (fr
Inventor
Felton Rudolph Mayers
Tu Vinh Chau
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Agfa Gevaert NV
Agfa Gevaert AG
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Agfa Gevaert NV
Agfa Gevaert AG
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N3/00—Preparing for use and conserving printing surfaces
    • B41N3/03—Chemical or electrical pretreatment
    • B41N3/034—Chemical or electrical pretreatment characterised by the electrochemical treatment of the aluminum support, e.g. anodisation, electro-graining; Sealing of the anodised layer; Treatment of the anodic layer with inorganic compounds; Colouring of the anodic layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N3/00—Preparing for use and conserving printing surfaces
    • B41N3/03—Chemical or electrical pretreatment
    • B41N3/038—Treatment with a chromium compound, a silicon compound, a phophorus compound or a compound of a metal of group IVB; Hydrophilic coatings obtained by hydrolysis of organometallic compounds

Definitions

  • This invention relates to a method for the production of a support for use as a substrate for a lithographic printing plate. More specifically, the invention provides a method for the surface treatment of a support material, whereby a substrate having particularly favourable lithographic properties may be obtained.
  • the material used as the support material depends upon the specific purpose for which the printing plate is to be used and may be, for example, a metal, paper or plastics material.
  • the preferred substrate is aluminium, most preferably electrochemically roughened aluminium which includes a surface layer of anodic aluminium oxide.
  • said aluminium may be laminated to another metal, such as copper or zinc, or to a plastics material, for example a polyester material such as poly(ethylene terephthalate).
  • aluminium substrates intended for use as support materials for lithographic printing plates and their precursors have been subjected to surface treatments prior to application of a light sensitive coating material. These treatments serve to improve the lithographic properties of the aluminium, in particular, its hydrophilicity. This is important during printing operations, since the basis of lithography is the ability of the lithographic plate to accept ink in image areas whilst rejecting ink and accepting water in background (non-image) areas, so that the printed image remains free from dirt and other contamination in said background areas.
  • the light-sensitive coating of a lithographic printing plate precursor is imagewise exposed to radiation in order to change the solubility characteristics of the coating in the radiation-struck areas. The soluble areas are subsequently dissolved away by treatment with a developing solution, to expose the aluminium surface which must be capable of rejecting ink and accepting water.
  • a typical surface treatment comprises an initial graining treatment, wherein the aluminium surface is roughened by either mechanical or electrochemical means, and a subsequent anodising treatment, by means of which a layer of aluminium oxide is formed on the surface of the aluminium.
  • Anodising treatments may, for example, be carried out by passing a grained aluminium web through a bath of a suitable anodising acid, such as sulphuric or phosphoric acid, or a mixture thereof, whilst an electric current flows through the anodising bath and the web serves as the anode.
  • post-anodic dip - is usually applied in order to improve specific lithographic printing properties of the substrate, such as clean up of background areas, coating adhesion or corrosion resistance, and will typically involve treating the aluminium with a solution, often an aqueous solution, of the chosen reagent.
  • aqueous solutions containing, for example, various inorganic salts or organic derivatives such as poly(acrylic acid) or various aqueous-soluble copolymers.
  • EP-A-567178 discloses the treatment of grained and anodised aluminium with an aqueous solution of an alkali metal bicarbonate, whilst the use of solutions containing anions including chloride, fluoride, nitrate, carboxylate, sulphate and phosphate for application to anodised aluminium is described in JP-A-10129143.
  • GB Patent No 1128506 deals with a process wherein anodised aluminium is treated with an aqueous solution of titanium, zirconium or hafnium tetrachloride - or the corresponding double fluoride formed with, for example, alkali metal fluorides-and subsequently dipped in an aqueous alkaline solution of potassium tetrapyrophosphate.
  • GB Patent No 1504503 teaches the use of potassium titanium fluoride in combination with a vegetable tannin compound and a soluble lithium compound in the treatment of anodised aluminium surfaces in order to improve corrosion resistance
  • EP-A-178020 discloses a treatment process for otherwise untreated aluminium which provides excellent corrosion resistance and paint adhesion characteristics and involves sequentially contacting the surface with (1) an aqueous acidic solution containing hafnium, zirconium and/or titanium ions, fluoride ions, a tannin compound and a sequestering agent and (2) a solution comprising a polyphenolic compound or acid salt thereof.
  • an object of the present invention to provide a post-anodic dip treatment for grained and anodised aluminium which eliminates the problem of poor ease of deletion during printing platemaking which is associated with the use of fluoride derivatives of titanium, hafnium and zirconium, whilst at the same time retaining the advantageous properties which are associated with the use of these materials.
  • Said treatment of said at least one grained and anodised surface with an aqueous solution comprising at least one salt of a metal from Group IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB or VIII of the Periodic Table is preferably carried out by treating said substrate with an aqueous solution, preferably containing from 0.01% to 10.0% (w/w) (more preferably from 0.05% to 1.5%) of said salt at a preferred temperature of from 10° to 90°C (more preferably from 40° to 80°C) for a preferred dwell time of from 0.1 second to 5 minutes (more preferably from 0.2 second to 30 seconds) at a pH which preferably lies between 1 and 6, most preferably between 3.5 and 5.5.
  • Various coating techniques may be employed for application of the salt, such as dip coating, slot coating, reverse roll coating or electrochemical coating; most preferred, however, is spray coating.
  • Spray coating most preferred, however, is spray coating.
  • Single pass processes are also preferred since they facilitate the avoidance of contamination which could otherwise occur as a consequence of re-circulation of the solution.
  • Suitable salts which may be used for the said treatment include, for example, salts of titanium, zirconium, hafnium, molybdenum, tungsten, vanadium, manganese, nickel, copper, zinc, tin, niobium, tantalum, selenium, silicon, cobalt or iron.
  • Said salts may include the metal either as the cation, for example in halide, sulphate or nitrate salts, or as part of a complexed anion.
  • the hafnium, zirconium or titanium salt comprises a salt wherein the metal is present in a metal-complex anion, such as a chlorotitanate or fluorozirconate anion.
  • a metal-complex anion such as a chlorotitanate or fluorozirconate anion.
  • alkali metal fluorozirconates particularly potassium hexafluorozirconate.
  • Said treatment of at least one treated surface with an aqueous solution comprising at least one orthophosphate salt of an alkali metal is preferably carried out by treating said substrate with an aqueous solution, preferably containing from 0.01% to 10.0% (w/w) (more preferably from 0.05% to 1.5%) of an orthophosphate salt of an alkali metal at a preferred temperature of from 5° to 90°C (more preferably from 40° to 80°C) for a preferred dwell time of from 0.05 second to 5 minutes (more preferably from 0.1 second to 30 seconds) at a pH which preferably lies between 3 and 7, most preferably around 4.5.
  • orthophosphate salt of an alkali metal such as dip coating, slot coating, reverse roll coating or electrochemical coating; most preferred, however, is spray coating.
  • Spray coating most preferred, however, is spray coating.
  • Single pass processes are also preferred since they facilitate the avoidance of contamination which could otherwise occur as a consequence of re-circulation of the solution.
  • orthophosphate salts of alkali metals which may be used for the said treatment are the orthophosphates of sodium or potassium, including the hydrogen and dihydrogen orthophosphates. It has been found that these materials provide superior results, and are therefore preferred.
  • Other phosphorus-containing compounds such as hypophosphonate, hypophosphate, pyrophosphonate, pyrophosphate, phosphonate, polyphosphonate or metaphosphonate derivatives have been reported in the prior art, but generally provide printing plates of lower quality than those obtained by the application of orthophosphate salts.
  • alkali metal fluorophosphates or difluorophosphates, phosphosilicates and phosphoborates all of which facilitate the controlled release of phosphate into the coating bath, and various organic materials, such as the copolymer of acrylic acid and vinyl phosphonic acid, has been investigated.
  • the cheaper orthophosphates are the most preferred materials, giving excellent performance at optimum cost, with sodium dihydrogen orthophosphate and, most particularly, potassium dihydrogen orthophosphate being especially preferred.
  • the orthophosphate salt of an alkali metal may be applied to the substrate simultaneously with the salt of a metal from Group IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB or VIII of the Periodic Table, or it may be applied in a separate treatment, subsequent to the application of the said salt; in either case, plates showing excellent ease of deletion, as well as other desirable properties, are obtained.
  • precipitation problems which are associated with the simultaneous treatment method are not apparent when the treatments are carried out as separate stages, with the orthophosphate salt of an alkali metal being applied subsequent to the treatment with the salt of a metal from Group IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB or VIII of the Periodic Table.
  • the aqueous solution of the salt of a metal from Group IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB or VIII of the Periodic Table or the aqueous solution of at least one orthophosphate salt of an alkali metal - or the combined solution, if this is to be employed.
  • the solution or solutions may include materials such as sequestering agents, tannin, sulphuric acid, fluorides and other additives which are known to improve the lithographic properties of a substrate, including various organic and inorganic polymeric materials.
  • said substrate may be rinsed with water following said treatment with an aqueous solution comprising at least one salt of a metal from Group IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB or VIII of the Periodic Table, and prior to said treatment with an aqueous solution comprising at least one orthophosphate salt of an alkali metal.
  • an aqueous solution comprising at least one salt of a metal from Group IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB or VIII of the Periodic Table
  • Said aluminium substrate may comprises pure aluminium or an aluminium alloy containing small amounts of, for example, manganese, nickel, cobalt, zinc, iron, copper, magnesium, titanium, vanadium, silicon or zirconium.
  • Said substrate is generally provided in the form of a continuous web or roll of material.
  • said substrate is subjected to a degreasing treatment prior to said graining treatment.
  • Said degreasing treatment is most conveniently carried out by means of an aqueous alkaline solution.
  • said treatment involves passing said substrate through a bath containing a 1-20% w/v solution of, for example, sodium or potassium hydroxide at a temperature of 30-80°C for a dwell time of from 5-60 seconds.
  • said substrate is rinsed with water prior to further treatment.
  • Said graining treatment can involve mechanical graining, wherein the surface of the substrate is subjected to mechanical forces which may, for example, be achieved by the use of a slurry of very small metal balls or via brush graining techniques.
  • electrochemical graining may be employed; said technique typically comprises passing a substrate through a solution of a mineral or organic acid, or a mixture thereof, such as a mixture of hydrochloric and acetic acids, whilst applying an electric current to the acid solution.
  • solutions of suitable inorganic salts in mineral acids are also found to provide highly acceptable results; particularly favoured in this respect is a mixed electrolyte comprising hydrochloric acid, hydrated aluminium chloride and hydrated aluminium sulphate.
  • suitable graining conditions could involve the use of a bath of aqueous hydrochloric acid at a concentration of from 1-30 g/l and a temperature of 5-70°C, with a dwell time of from 1-60 seconds at a charge density of 200-800 C/dm 2 and an applied potential of from 1-60 V. The grained substrate is then rinsed with water prior to further processing.
  • said grained substrate should be subjected to a desmutting treatment in order to remove by-products formed during the course of said electrograining treatment, and deposited on the surface of the substrate.
  • a desmutting treatment in order to remove by-products formed during the course of said electrograining treatment, and deposited on the surface of the substrate.
  • the process involves treatment of the grained substrate with an aqueous acid or alkali according to the methods well known in the art.
  • Suitable desmutting conditions could, for example, involve treatment of the grained substrate with aqueous phosphoric acid at a concentration of around 20-400 g/l at a temperature in the region of 20-80°C for a dwell time of the order of 1 second to 5 minutes; alternatively, a higher temperature treatment - using sulphuric acid at 50-300 g/l and 30-80°C for a shorter dwell time of around 8 seconds - may be employed, or an alkaline treatment, with 2-20 g/l aqueous sodium hydroxide at 5-60°C, would suffice.
  • the substrate is rinsed with water following desmutting.
  • Anodising of the grained substrate is carried out by means of any of the standard techniques well known in the art, and typically involves passing the substrate through a bath containing an aqueous mineral acid, such as sulphuric, phosphoric, nitric, hydrofluoric or chromic acid, or an aqueous solution of an organic acid, for example oxalic, tartaric, citric, acetic or oleic acid, or a mixture of these acids, whilst applying an electric current to the anodising bath.
  • an aqueous mineral acid such as sulphuric, phosphoric, nitric, hydrofluoric or chromic acid
  • an organic acid for example oxalic, tartaric, citric, acetic or oleic acid, or a mixture of these acids
  • Suitable anodising conditions would involve the use of a bath of sulphuric acid at a concentration of from 10 to 300 g/l, preferably 100-150 g/l, and a temperature in the range of from 20-60°C, preferably 40-60°C, with a dwell time of from 1 to 120 seconds, preferably 3 to 40 seconds, an applied potential of from 5-60 V, preferably 10-50 V, and a charge density of from 100-500 C/dm 2 , preferably 200-400 C/dm 2 .
  • the grained and anodised substrate is then rinsed with water prior to further processing.
  • the process provided by the present invention may be successfully employed using various forms of process and coating technology. Principally, said process is suitable for use with the different forms of cell alignment associated with flat bed technology and vertical cell technology, both of which are well known to those skilled in the art.
  • the support provided by the method of the present invention may subsequently be coated with a light-sensitive coating to give a lithographic printing plate precursor.
  • a light-sensitive coating to give a lithographic printing plate precursor.
  • Various coatings of the types well known to those skilled in the art may be applied for this purpose, for example, positive-working coatings incorporating quinone diazide derivatives, negative-working coatings incorporating diazo or azide resins or photocrosslinkable resins or silver halide based coatings.
  • the coatings may be applied by any of the standard coating techniques known to the skilled person, such as curtain coating, dip coating, meniscus coating, slot coating, reverse roll coating, and the like.
  • the thus-obtained lithographic printing plate precursor may then be imagewise exposed and the non-image areas can be developed away to provide a lithographic printing plate which is subsequently used on a printing press to produce copies.
  • Lithographic printing plates produced from aluminium supports obtainable by the method of the present invention show excellent performance in terms of ease of deletion, as well as good corrosion resistance, solvent resistance, clean-up and roll-up on press. No background staining is observed and plates exhibit excellent ink-water balance and damping latitude performance, as well as good run length.
  • An aluminium alloy substrate comprising Al ⁇ 99.1%, Si ⁇ 0.2%, Fe ⁇ 0.4%, Cu ⁇ 0.05%, Mn ⁇ 0.05%, Mg ⁇ 0.05%, Zn ⁇ 0.07%, Ti ⁇ 0.05% and V ⁇ 0.05% was conventionally degreased, rinsed and subjected to an electrochemical graining treatment using a liquor comprising hydrochloric acid (9 g/l) and acetic acid (25 g/l) at a temperature of 30°C for a dwell time of 20 seconds at a charge density of 500 C/dm 2 .
  • the grained substrate was subjected to an anodising process by treating with sulphuric acid (145 g/l) at 45°C for a dwell time of 20 seconds at a charge density of 250 C/dm 2 , then rinsed with water.
  • the grained and anodised aluminium substrate was then treated by spray coating for 20 seconds with an aqueous solution of potassium hexafluorozirconate (5 g/l) having pH 4.0 at 60°C, then spray coated with an aqueous solution of potassium dihydrogen orthophosphate (12 g/l) having pH 4.5 at 60°C for 20 seconds. No evidence of precipitation was observed during, or subsequent to, either treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol to produce a light-sensitive coating layer, and the coated substrate was baked at 130°C for 5 minutes.
  • the resulting lithographic printing plate precursor was imagewise exposed to UV light at 100-300 mJ/cm 2 and the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press. Ink/water balance, damping latitude and solvent resistance were also all exceptionally good.
  • Posidel A a commercial deletion fluid supplied by Agfa-Gevaert
  • the plate showed excellent ease of deletion and little evidence of residual staining.
  • An aluminium alloy substrate comprising Al ⁇ 98.0%, Si ⁇ 0.5%, Fe ⁇ 0.7%, Cu ⁇ 0.05%, Mn 1.0-1.5%, Mg ⁇ 0.15%, Zn ⁇ 0.1%, Ti ⁇ 0.05% and V ⁇ 0.05% was degreased, grained, desmutted and anodised as described in Example 1.
  • the grained and anodised aluminium substrate was then treated by spray coating for a dwell time of 3.5 seconds with an aqueous solution of potassium hexafluorozirconate (5 g/l) having pH 4.0 at 80°C, then further spray coated with an aqueous solution of potassium dihydrogen orthophosphate (8 g/l) having pH 4.5 at 70°C for 0.5 second. No evidence of precipitation was observed during, or subsequent to, either treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol and tetrahydrofuran (1:1) which contained dispersed particles of silica having an average diameter of approximately 4 ⁇ m.
  • the coated substrate was baked at 140°C for 30 seconds to 1 minute to produce a light-sensitive coating layer having a mat surface layer which promoted good vacuum drawdown performance during imagewise exposure. This was carried out using UV light at 100-300 mJ/cm 2 , after which the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press. Ink/water balance, damping latitude and solvent resistance were also all exceptionally good.
  • Posidel A a commercial deletion fluid supplied by Agfa-Gevaert
  • the plate showed excellent ease of deletion and little evidence of residual staining.
  • An aluminium alloy substrate as in Example 1 was conventionally degreased, rinsed and subjected to an electrochemical graining treatment using a liquor comprising hydrochloric acid (12 g/l) and sulphuric acid (9 g/l) at a temperature of 40°C for a dwell time of 5 seconds at a charge density of 540-550 C/dm 2 .
  • a liquor comprising hydrochloric acid (12 g/l) and sulphuric acid (9 g/l) at a temperature of 40°C for a dwell time of 5 seconds at a charge density of 540-550 C/dm 2 .
  • sulphuric acid 145 g/l
  • the grained substrate was subjected to an anodising process by treating with sulphuric acid (145 g/l) at 57°C for a dwell time of 6 seconds at a charge density of 250 C/dm 2 , then rinsed with water.
  • the grained and anodised aluminium substrate was slot coated for 5 seconds with an aqueous solution of potassium hexafluorozirconate (5 g/l) having pH 4.0 at 70°C, then further treated by slot coating with an aqueous solution of potassium dihydrogen orthophosphate (4 g/l) having pH 4.5 at 70°C for 1.0 second. No evidence of precipitation was observed during, or subsequent to, either treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol to produce a light-sensitive coating layer, and the coated substrate was baked at 130°C for 5 minutes.
  • the resulting lithographic printing plate precursor was imagewise exposed to UV light at 100-300 mJ/cm 2 and the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press. Ink/water balance, damping latitude and solvent resistance were also all exceptionally good.
  • Posidel A a commercial deletion fluid supplied by Agfa-Gevaert
  • the plate showed excellent ease of deletion and little evidence of residual staining.
  • An aluminium alloy substrate was degreased, grained, desmutted and anodised as described in Example 1.
  • the grained and anodised aluminium substrate was then treated by spray coating for a dwell time of 3.5 seconds with an aqueous solution of sodium hexachlorotitanate (5 g/l) having pH 4.0 at 80°C, then further spray coated with an aqueous solution of sodium dihydrogen orthophosphate (8 g/l) having pH 4.5 at 70°C for 0.5 second. No evidence of precipitation was observed during, or subsequent to, either treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol to produce a light-sensitive coating layer, and the coated substrate was baked at 130°C for 5 minutes.
  • the resulting lithographic printing plate precursor was imagewise exposed to UV light at 100-300 mJ/cm 2 and the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press. Ink/water balance, damping latitude and solvent resistance were also all exceptionally good.
  • Posidel A a commercial deletion fluid supplied by Agfa-Gevaert
  • the plate showed excellent ease of deletion and little evidence of residual staining.
  • An aluminium alloy substrate was degreased, grained, desmutted and anodised as described in Example 1.
  • the grained and anodised aluminium substrate was treated for 20 seconds with an aqueous solution of potassium hexafluorozirconate (5 g/l) and poly(vinyl phosphonic acid) (2 g/l) having pH 4.0 at 60°C. No evidence of precipitation was observed during, or subsequent to, the said treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol to produce a light-sensitive coating layer, and the coated substrate was baked at 130°C for 5 minutes.
  • the resulting lithographic printing plate precursor was imagewise exposed to UV light at 100-300 mJ/cm 2 and the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press. Ink/water balance, damping latitude and solvent resistance were also all exceptionally good. On treatment with Posidel A (a commercial deletion fluid supplied by Agfa-Gevaert) the plate showed moderate ease of deletion and evidence of residual staining was observed.
  • An aluminium alloy substrate was degreased, grained, desmutted and anodised as described in Example 1.
  • the grained and anodised aluminium substrate was spray coated for 20 seconds with an aqueous solution of potassium hexafluorozirconate (5 g/l) having pH 4.0 at 60°C, then treated with an aqueous solution of a poly(vinyl phosphonic acid) (2 g/l) having pH 3.5 by spray coating at 60°C for 20 seconds. No evidence of precipitation was observed during, or subsequent to, either treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol to produce a light-sensitive coating layer, and the coated substrate was baked at 130°C for 5 minutes.
  • the resulting lithographic printing plate precursor was imagewise exposed to UV light at 100-300 mJ/cm 2 and the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press; ink/water balance and damping latitude were also very good.
  • Posidel A a commercial deletion fluid supplied by Agfa-Gevaert
  • the plate showed excellent ease of deletion and little evidence of residual staining.
  • solvent resistance and corrosion resistance the performance was poor.
  • An aluminium alloy substrate was degreased, grained, desmutted and anodised as described in Example 1.
  • the grained and anodised aluminium substrate was treated for 20 seconds with an aqueous solution of potassium hexafluorozirconate (5 g/l) and sodium pyrophosphate (8 g/l) having pH 4.0 at 60°C. No evidence of precipitation was observed during, or subsequent to, the said treatment.
  • the resulting substrate was rinsed with water and coated with a solution of a naphthoquinone diazide photosensitive resin and a cresol novolak support resin in 2-methoxypropanol to produce a light-sensitive coating layer, and the coated substrate was baked at 130°C for 5 minutes.
  • the resulting lithographic printing plate precursor was imagewise exposed to UV light at 100-300 mJ/cm 2 and the non-image areas were developed away with an aqueous alkaline developer solution by immersion for 30 seconds at 20°C.
  • the resulting lithographic printing plate was rinsed with water and dried in a stream of cool air and subsequently produced 250,000 excellent quality copies on a Drent Web Offset press.
  • the plate showed excellent roll-up and clean-up, with no background staining, on press. Ink/water balance, damping latitude and solvent resistance were also all exceptionally good.
  • Posidel A a commercial deletion fluid supplied by Agfa-Gevaert
  • the plate showed excellent ease of deletion and little evidence of residual staining.

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Claims (13)

  1. Procédé pour la fabrication d'un substrat à utiliser dans la production de clichés d'impression lithographique, ledit procédé comprenant les étapes consistant à :
    (a) procurer un substrat en aluminium ;
    (b) grainer au moins une surface dudit substrat ;
    (c) appliquer une couche anodique sur ladite au moins une surface grainée ;
    (d) traiter ladite au moins une surface grainée et anodisée avec une solution aqueuse comprenant au moins un sel d'un métal du groupe IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB ou VIII du tableau périodique ; et
    (e) traiter ladite au moins une surface traitée avec une solution aqueuse comprenant au moins un sel d'orthophosphate d'un métal alcalin.
  2. Procédé tel que défini à la revendication 1, dans lequel ledit sel d'orthophosphate d'un métal alcalin comprend l'orthophosphate trisodique, l'hydrogéno-orthophosphate disodique, le dihydrogéno-orthophosphate de sodium, l'orthophosphate tripotassique, l'hydrogéno-orthophosphate dipotassique ou le dihydrogéno-orthophosphate de potassium.
  3. Procédé tel que défini à la revendication 1 ou 2, dans lequel ledit sel d'un métal du groupe IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB ou VIII du tableau périodique comprend un sel de titane, de zirconium, de hafnium, de molybdène, de tungstène, de vanadium, de manganèse, de nickel, de cuivre, de zinc, d'étain, de niobium, de tantale, de sélénium, de silicium, de cobalt ou de fer.
  4. Procédé tel que défini dans l'une quelconque des revendications 1 à 3, dans lequel ledit sel d'un métal du groupe IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB ou VIII du tableau périodique englobe le métal sous forme cationique.
  5. Procédé tel que défini à la revendication 1, dans lequel ledit sel comprend un sel de sulfate, de phosphate, de nitrate, d'acétate, de fluorure ou de chlorure de titane, de zirconium ou de hafnium.
  6. Procédé tel que défini dans l'une quelconque des revendications 1 à 3, dans lequel ledit sel d'un métal du groupe IB, IIB, IVA, IVB, VB, VIA, VIB, VIIB ou VIII du tableau périodique englobe le métal sous forme d'une partie d'un anion complexé.
  7. Procédé tel que défini à la revendication 6, dans lequel ledit sel comprend un fluorozirconate de métal alcalin.
  8. Procédé tel que défini à la revendication 7, dans lequel ledit fluorozirconate de métal alcalin comprend de l'hexafluorozirconate de potassium.
  9. Procédé tel que défini dans l'une quelconque des revendications précédentes, dans lequel ledit substrat métallique comprend de l'aluminium ou un alliage à base d'aluminium contenant de petites quantités d'au moins un membre du groupe comprenant le manganèse, le nickel, le cobalt, le zinc, le fer, le cuivre, le magnésium, de titane, le vanadium, le silicium ou de zirconium.
  10. Procédé tel que défini dans l'une quelconque des revendications précédentes, dans lequel ledit traitement de grainage' comprend un traitement de grainage mécanique ou électrochimique.
  11. Procédé tel que défini à la revendication 10, dans lequel ledit traitement de grainage électrochimique comprend le fait de faire passer un substrat à travers une solution d'un acide minéral ou organique ou d'un mélange d'acides de ce type, tout en appliquant un courant électrique sur la solution acide.
  12. Procédé tel que défini dans l'une quelconque des revendications précédentes, dans lequel ladite couche anodique est appliquée sur ladite au moins une surface grainée du substrat en faisant passer ledit substrat à travers une solution d'un acide minéral ou organique ou d'un mélange d'acides de ce type, tout en appliquant un courant électrique sur la solution acide.
  13. Précurseur de cliché d'impression lithographique que l'on peut obtenir en appliquant une couche photosensible sur un substrat obtenu conformément au procédé tel que défini dans l'une quelconque des revendications précédentes.
EP20010000213 2000-07-17 2001-06-14 Fabrication d'un support pour une plaque lithographique Expired - Lifetime EP1176031B1 (fr)

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EP20010000213 EP1176031B1 (fr) 2000-07-17 2001-06-14 Fabrication d'un support pour une plaque lithographique

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EP00202518 2000-07-17
EP00202518 2000-07-17
EP20010000213 EP1176031B1 (fr) 2000-07-17 2001-06-14 Fabrication d'un support pour une plaque lithographique

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Cited By (1)

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CN110527994A (zh) * 2019-09-28 2019-12-03 立邦涂料（重庆）化工有限公司 一种基于氟锆酸的无磷化成剂、制备方法及应用方法

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Publication number Priority date Publication date Assignee Title
DE60320549T2 (de) * 2003-08-13 2009-05-14 Agfa Graphics N.V. Verfahren zum Nacheinbrennen von lithographischen Druckplatten
US7225560B2 (en) 2005-02-04 2007-06-05 Printing Research, Inc. Computer to plate curing system
US7685738B2 (en) 2005-02-04 2010-03-30 Printing Research, Inc. Computer to plate color sensor and drying/curing system and method
ATE440733T1 (de) * 2007-03-20 2009-09-15 Agfa Graphics Nv Verfahren zum herstellen eines lithographiedruckplattenträgers
GB2461240A (en) * 2008-06-24 2009-12-30 Bridgnorth Aluminium Ltd Aluminium alloy for lithographic sheet

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US3440050A (en) * 1965-02-05 1969-04-22 Polychrome Corp Lithographic plate
CH526399A (de) * 1968-12-06 1972-08-15 Hasek Josef Verfahren zur Herstellung einer Offsetdruckplatte
JPS61102650A (ja) * 1984-10-25 1986-05-21 Nippon Seihaku Kk 平版印刷支持体層形成用組成物
JPH07119151B2 (ja) * 1987-12-07 1995-12-20 富士写真フイルム株式会社 平版印刷版用支持体
JP2648976B2 (ja) * 1990-03-09 1997-09-03 富士写真フイルム株式会社 感光性平版印刷版
US5254430A (en) * 1991-01-31 1993-10-19 Fuji Photo Film Co., Ltd. Presensitized plate having anodized aluminum substrate, hydrophilic layer containing phosphonic or phosphinic compound and photosensitive layer containing O-quinone diazide compound

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110527994A (zh) * 2019-09-28 2019-12-03 立邦涂料（重庆）化工有限公司 一种基于氟锆酸的无磷化成剂、制备方法及应用方法

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