EP1169486B1 - Method of producing a hot-rolled strip - Google Patents

Method of producing a hot-rolled strip Download PDF

Info

Publication number
EP1169486B1
EP1169486B1 EP00906372A EP00906372A EP1169486B1 EP 1169486 B1 EP1169486 B1 EP 1169486B1 EP 00906372 A EP00906372 A EP 00906372A EP 00906372 A EP00906372 A EP 00906372A EP 1169486 B1 EP1169486 B1 EP 1169486B1
Authority
EP
European Patent Office
Prior art keywords
cooling
hot strip
cooled
temperature
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP00906372A
Other languages
German (de)
French (fr)
Other versions
EP1169486A1 (en
Inventor
Rudolf Kawalla
Hans Pircher
Thomas Heller
Bernhard Engl
Pino Tes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Stahl AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7900901&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1169486(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by ThyssenKrupp Stahl AG filed Critical ThyssenKrupp Stahl AG
Publication of EP1169486A1 publication Critical patent/EP1169486A1/en
Application granted granted Critical
Publication of EP1169486B1 publication Critical patent/EP1169486B1/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • B21B37/76Cooling control on the run-out table
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54Furnaces for treating strips or wire
    • C21D9/56Continuous furnaces for strip or wire
    • C21D9/573Continuous furnaces for strip or wire with cooling

Definitions

  • the invention relates to a method for generating a Steel hot strip, in which the hot strip after the Finishing rolling a carried out in several stages Cooling is subjected.
  • the structure can be cooled as such and the proportions of the individual structure types influence this structure. So it is possible through cooling, for example, strength, toughness and To influence the hardness of a hot strip.
  • JP 10-195588 A discloses a method for producing a hot strip from a slab, which (in% by weight) 0.02-0.2% C, 0.1-1, 5% Si, 0.5-3.0% Mn and one or more of the elements Cr and Mo each with 0.1-2.0%, the rest iron.
  • the hot strip is hot-rolled according to the known method at a final temperature corresponding at least to the Ar 3 temperature to thicknesses which are typically in the range from 0.8 to 1.4 mm.
  • the hot strips are continuously cooled in a first stage that begins 0.1 to 5 s after hot rolling with a cooling rate in the temperature range of 680 - 720 ° C that is more than 50 ° C.
  • the first stage of cooling is followed by an intermediate cooling phase, during which the belt cools in air for up to 15 seconds.
  • a third cooling phase then follows, in which cooling is carried out at a cooling rate of at least 30 ° C./s in a temperature range from 300 to 600 ° C. Finally the tape is coiled.
  • a comparable method is known from EP-A-0 719 868 known.
  • a Slab with (in% by weight) 0.001 - 0.1% C, ⁇ 1.5% Si, 0.5 - 3.0% Mn, 0.01-0.1% Al, and one or more of the Elements P (0.05 - 0.15%) and Cr (0.5 - 1.5%), the rest Iron, at a hot rolling end temperature of up to 850 ° C continuously rolled into hot strip.
  • Within A first is carried out 0.5 s after the finish hot rolling Cooling down at temperatures between 650 - 750 ° C lie.
  • the cooling rate is at least 30 ° C / s, typically 42 - 70 ° C / s.
  • the first cooling stage is followed by an intermediate cooling phase at which the belt cools in air for 4 to 60 seconds. This is followed by a third cooling at cooling rates of at least 30 ° C / s to between 100 ° C and 500 ° C lying reel temperature.
  • the object of the invention is to provide a method create with which hot strips can be produced which have high formability and increased strength exhibit.
  • the hot strip is cooled also in at least two consecutive through stages.
  • the hot strip is in the the first cooling phase cooled much faster than the State of the art.
  • This compact cooling during the first cooling phase has the consequence that the ⁇ / ⁇ conversion of effective and targeted in the ⁇ -region of hot-rolled strip is suppressed towards lower temperatures.
  • the tape is then accelerated to the cooling brought desired final temperature.
  • the hardness-increasing second phases of the hot strip structure like martensite, bainite and residual austenite, set. (At the end of the second cooling phase accelerated cooling can reach the final temperature of course, depending on the desired processing results required Act reel temperature.)
  • the hot strip Steel optionally contain additional elements.
  • the proportion (in mass%) of Cu, Ni, Mo not more than 0.8%, that of N, Ti, Nb, V, Zn, B not larger than 0.5%, that of P not larger than 0.09%, that of Cr not greater than 1.5% and that of S should not be greater than 0.02%.
  • the method according to the invention is firstly for generating suitable for hot strips, which are based on steels are manufactured with low carbon contents. So is an advantageous variant of the invention Process characterized in that the steel (in Mass%) not more than 0.07% C, not more than 0.2% Si, not more than 0.6% Mn and not more than 0.08% Al contains the hot strip during finish rolling in Austenite area is rolled, the hot strip in the first Cooling phase of accelerated cooling starting from one Temperature above 850 ° C to a temperature of 680 is cooled to 750 ° C, the hot strip in the second Cooling phase accelerated cooling to a temperature of is cooled to less than 600 ° C and finally coiled becomes.
  • the method of manufacture according to the invention is likewise suitable for DP hot strip steels.
  • a corresponding one Design of the method according to the invention characterized in that the steel (in mass%) 0.04 - 0.09% C, not more than 0.2% Si, 0.5 - 2.0% Mn, 0.02 - Contains 0.09% P and not more than 0.9% Cr, and that the Hot strip after finish rolling in the first cooling phase accelerated cooling based on a temperature above 800 ° C to a temperature of 650 to 730 ° C is cooled that the hot strip in the second cooling phase accelerated cooling cooled to less than 500 ° C and that the hot strip is then coiled.
  • a hot strip which on a steel with (in mass%) 0.25 - 1.05% C, not more than 0.25% Si and not more than 0.6% Mn based, after finishing rolling in the first cooling phase accelerated cooling based on a temperature above 800 ° C to a temperature of 530 to 620 ° C cooled, in the second cooling phase accelerated cooling cooled to less than 500 ° C and then coiled.
  • a hot strip produced in this way has also improved hardness and better Forming properties compared to conventionally produced Tapes.
  • the method is characterized in that the steel (in Mass%) 0.04 - 0.09% C, 0.5 - 1.5% Si, 0.5 - 2.0% Mn, 0.4 - 2.5% Al, no more than 0.09% P and no more than 0.9% Cr contains that the hot strip after Finishing rolls accelerated in the first cooling phase Cooling from a temperature above 800 ° C is cooled to a temperature of 650 to 730 ° C that the hot strip accelerated in the second cooling phase Cooling is cooled to less than 500 ° C and that Hot strip is then coiled.
  • Such one Hot strip has DP and TRIP properties.
  • a structural steel with an increased ferrite content and from it The following particularly good formability can be thereby make the steel (in mass%) 0.07 - 0.22% C, 0.1 - 0.45% Si and 0.2 - 1.5% Mn contains that the Hot strip after finish rolling in the first cooling phase accelerated cooling based on a temperature above 800 ° C to a temperature of 650 to 730 ° C is cooled that the hot strip in the second cooling phase accelerated cooling cooled to less than 500 ° C and that the hot strip is then coiled.
  • a hot strip can be made with the same steel composition with improved hardness, on the other hand, that the hot strip after finish rolling in the first Cooling phase of accelerated cooling starting from one Temperature above 800 ° C to a temperature of 580 is cooled to 650 ° C that the hot strip in the second Cooling phase of accelerated cooling to less than 500 ° C is cooled and that the hot strip is then coiled becomes.
  • the hot strip cooled in this way has one reduced ferrite content, higher bainite and martensite contents on.
  • the Invention passes through the hot strip between the first Cooling phase and the second cooling phase accelerated Cooling an intermediate cooling phase during which the hot strip is exposed to air cooling.
  • This intermediate cooling phase should take at least a second.
  • in the cooling in air takes place the austenite transformation in ferrite faster and reaches one larger scope than in the prior art, wherein at the same time a strong grain-refining effect watch is.
  • the procedure according to the invention can produce a hot strip, which compared to a conventional one Process in two laminar cooling stages with intermediate cooling in air-cooled hot strip same composition an increased hardness and a has a finer grain structure.
  • the tape produced by the method according to the invention high strength and, unlike that after known methods produced tapes, a good one Formability on.
  • the first cooling phase therefore begins at the latest two Seconds after the last pass of finish rolling.
  • a further advantageous embodiment of the method, with which a hot strip of particularly good formability can be produced is characterized in that at least one of the rolling passes is carried out during the finish rolling in the austenite region below a temperature of Ar 3 + 80 ° C and that the total pass decrease during of finish rolling is more than 30%.
  • the hot strip used steel expedient if the in particular as a thin slab primary material steel introduced into the respective rolling mill in the liquid phase with Ca or Ca carrier alloys is treated.
  • the hot strip in the second cooling phase with a cooling rate of is cooled at least 30 ° C / s.
  • Line 1 for producing a hot strip W comprises one Relay of several finishing stands, one of which is here only the last frame 2 is shown. In the Finishing rolling the hot strip W is on its The desired final thickness is rolled.
  • a compact cooling device 3 is arranged.
  • This Compact cooling device 3 includes not shown here Nozzles, via the cooling liquid, preferably water, under increased pressure on the top and bottom of the Hot strip W is brought.
  • the volume flow of the Coolant is adjustable so that within the Compact cooling device 3 cooling speeds of 150 ° C / s to 1000 ° C / s can be achieved.
  • the second cooling device 4 works kind of a conventional laminar cooling, in which the Coolant through several in the conveying direction F arranged one behind the other, also not shown here Fan is brought onto the hot strip W in a fan-like manner.
  • the Number of nozzles acted upon and / or Volume flow in the area of the laminar cooling device 4 applied coolant can be regulated in such a way that in the area of the laminar cooling device 4 Cooling speeds of 30 to 150 ° C / s reached become.
  • a reel device 5 In the conveying direction F of the belt behind the laminar cooling device 4 is a reel device 5 arranged, in which the hot strip W to a coil is wrapped.
  • Hot strip W is used exclusively in the finishing mill in the austenite area with a total decrease of more rolled as 30%. If necessary, the hot strip W during the rolling of a thermomechanical treatment subjected.
  • the hot strip W After the hot strip W has left the last stand 2 of the finished rolling mill, it arrives in the compact cooling device 3 within a transfer phase t 2 , which is shorter than two seconds.
  • the hot strip W Upon entering the compact cooling device 3, the hot strip W becomes a first cooling phase t CK continuously exposed to a compact cooling, during which the hot strip W is cooled from an inlet temperature ET CK to an outlet temperature AT CK .
  • the cooling rates achieved are between 250 and 1000 ° C / s.
  • the ⁇ / ⁇ conversion of the hot strip steel is suppressed by the accelerated cooling of the hot strip W in the compact cooling device 3 within a short time t z after the exit from the finished rolling stack.
  • the hot strip W then runs through a free stretch in which it is cooled in air for an intermediate cooling phase t PAUSE .
  • the duration of the intermediate cooling phase t PAUSE is at least one second. During this time there is a partial conversion of the hot strip steel.
  • the hot strip W arrives in the laminar cooling device 4. In this, it is cooled from an inlet temperature ET LK to an outlet temperature AT LK within a second cooling phase t LK .
  • the set cooling rate is between 30 and 150 ° C / s.
  • second phases bainite, martensite or residual austenite
  • the excretion state of the hot strip W is also controlled in this way.
  • Table 1 compares the structure components and the hardness of hot strips produced from steels "Stahl” - “Stahl2", which were produced according to the method according to the invention explained above, with the structure components and the hardness of hot strips of the same composition, which are produced in a conventional manner have been cooled in air in two laminar cooling devices with intervening cooling.
  • Fig. 3 is for the steel in a solid line the course CLK of that structural change, which occurs when a hot strip is first in the manner according to the invention for the time t CK a compact cooling with a cooling rate of 250 ° C / s, then one Intermediate cooling phase t PAUSE and finally a laminar cooling cycle for the time t LK , contrasted with the LLK course of the structural transformation drawn in dashed lines, which occurs in a conventional combination of two laminar cooling systems with intermediate cooling in air.
  • Table 1 confirms the statement in FIG. 3.
  • Table 1 confirms the statement in FIG. 3.
  • Table 1 confirms the statement in FIG. 3.
  • those manufactured according to the invention Sample a structure with a finer grain structure than that generated by the conventional method. This has to Consequence that the hot strips produced according to the invention a good one despite the increased shares of the hard phases Show formability. This fact has been confirmed also for a TRIP steel ((in mass%) C: 0.2%, Al: 1.8 %, Mn: 1.6%).
  • Such steel pointed to conventional Production method an average ferrite grain diameter from 6 - 7 ⁇ m. With the procedure according to the invention this diameter is reduced to less than 3 ⁇ m.

Abstract

The invention relates to a method for producing hot strip which features good forming ability and increased strength. This is achieved in that a hot strip (W) which is produced in particular from continuous casting in the shape of reheated slabs or slabs obtained directly from the casting heat, from thin slabs or cast strip, based on a steel comprising (in mass %) C: 0.001-1.05%; Si: <=1.5%; Mn: 0.05-3.5%; Al: <=2.5%, if necessary further elements such as Cu, Ni, Mo, N, Ti, Nb, V, Zn, B, P, Cr, Ca and/or S, with the remainder being iron as well as the usual accompanying elements, is continuously finish rolled and subsequently continuously cooled, with cooling taking place in at least two subsequent cooling phases (tCK, tLK) of accelerated cooling, to a final temperature; with the first cooling phase (tCK) of accelerated cooling starting at the latest three seconds after the last pass of finish rolling; and with the hot strip (W) during the first cooling phase (tCK) of accelerated cooling being cooled at a cooling rate of at least 150° C./s.

Description

Die Erfindung betrifft ein Verfahren zum Erzeugen eines Stahl-Warmbandes, bei dem das Warmband nach dem Fertigwalzen einer in mehreren Stufen durchgeführten Abkühlung unterworfen wird.The invention relates to a method for generating a Steel hot strip, in which the hot strip after the Finishing rolling a carried out in several stages Cooling is subjected.

Dem Abkühlen eines Warmbandes nach dem in der Regel in mehreren Stichen erfolgenden Fertigwalzen kommt in Bezug auf die Materialeigenschaften des Bandes eine erhebliche Bedeutung zu. Durch die Anwendung einer geeigneten Abkühlung lassen sich unter anderem die Gefügestruktur als solche und die Anteile der einzelnen Gefügearten an dieser Struktur beeinflussen. So ist es möglich, durch das Abkühlen beispielsweise die Festigkeit, Zähigkeit und Härte eines Warmbandes zu beeinflussen.After cooling a hot strip after the in multiple stitches of finishing rolls comes into play a significant on the material properties of the tape Meaning too. By using an appropriate Among other things, the structure can be cooled as such and the proportions of the individual structure types influence this structure. So it is possible through cooling, for example, strength, toughness and To influence the hardness of a hot strip.

In dem Artikel "Hot rolled coils for special applications", A. De Vito et al., BTF - special issue 1986, Seite 137 - 141, sind verschiedene Untersuchungen beschrieben, welche den Einfluß der Abkühlung bei der Warmbandherstellung belegen. Diese Untersuchungen haben gezeigt, daß es beispielsweise bei der Herstellung eines Dualphasen-Warmbandstahls (DP-Warmbandstahls) zweckmäßig ist, die nach dem Fertigwalzen erfolgende Abkühlung in drei Stufen durchzuführen. In der ersten und der letzten dieser drei Stufen durchläuft das Band zwei herkömmlich ausgebildete, beabstandet zueinander angeordnete Laminarkühlstrecken, bei denen Kühlflüssigkeit in Form einer Vielzahl von in Förderrichtung des Bandes hintereinander angeordneten Schleiern auf das Band gesprüht wird. Die dabei erreichte Abkühlrate liegt in der ersten Stufe des Abkühlens bei rund 70 °C/s. Die Abkühlung des Bandes in der dritten Stufe erfolgt langsamer als in der ersten Stufe.In the article "Hot rolled coils for special applications ", A. De Vito et al., BTF - special issue 1986, pages 137-141, are various studies described the influence of cooling in the Document hot strip production. Have these investigations shown that, for example, in the manufacture of a Dual-phase hot strip steel (DP hot strip steel) is useful is the cooling in after the finish rolling perform three stages. In the first and the last of these three stages, the belt passes through two conventionally trained, spaced from each other Laminar cooling sections, where cooling liquid is in the form a variety of in the conveying direction of the belt sequential veils on the ribbon is sprayed. The cooling rate achieved is in the first stage of cooling at around 70 ° C / s. The The belt is cooled in the third stage slower than in the first stage.

In der zwischen den Laminarkühlstrecken durchlaufenen Zwischenstufe findet die Abkühlung bei dem bekannten Verfahren an Luft statt, wobei die in dieser Stufe erreichte Abkühlgeschwindigkeit wiederum weit niedriger liegt als in der letzten Stufe der Abkühlung.In the one between the laminar cooling sections Intermediate cooling takes place in the known Process in air, taking place at this stage cooling rate reached again much lower lies in the final stage of cooling.

Es hat sich gezeigt, daß sich mit dem voranstehend erläuterten bekannten Verfahren ohne die Anwesenheit von Molybdän in deren Zusammensetzung DP-Warmbandstähle herstellen lassen, bei denen ausgeprägte Martensit- und Ferrit-Anteile vorhanden sind. Die betreffenden Warmbänder weisen eine erhöhte Festigkeit und Zähigkeit auf.It has been shown that the above explained known methods without the presence of Molybdenum in its composition DP hot-rolled steels Have them made with pronounced martensite and Ferrite shares are present. The concerned Hot strips have increased strength and toughness on.

Gleichzeitig muß allerdings eine Einbuße der Duktilität in Kauf genommen werden. Darüber hinaus hat sich herausgestellt, daß die mit dem bekannten Verfahren erzielten Verbesserungen nicht ausreichen, um die insbesondere im Hinblick auf die Härte an derart hergestellte Warmbänder gestellten Anforderungen zu erfüllen.At the same time, however, there must be a loss of ductility to be accepted. Beyond that it was found that with the known method The improvements achieved are not sufficient to achieve the especially with regard to the hardness of such manufactured hot strips to requirements fulfill.

Neben dem voranstehend erläuterten Stand der Technik ist aus der JP 10-195588 A ein Verfahren zum Herstellen eines Warmbandes aus einer Bramme bekannt, die (in Gew.-%) 0,02 - 0,2 % C, 0,1 - 1,5 % Si, 0,5 - 3,0 % Mn sowie ein oder mehrere der Elemente Cr und Mo mit jeweils 0,1 - 2,0 %, Rest Eisen, enthält. Das Warmband wird gemäß dem bekannten Verfahren bei einer mindestens der Ar3-Temperatur entsprechenden Endtemperatur auf Dicken warmgewalzt, die typischerweise im Bereich von 0,8 bis 1,4 mm liegen. Nach Verlassen der Warmwalzstaffel werden die Warmbänder in einer 0,1 bis 5 s nach dem Warmwalzen beginnenden ersten Stufe mit einer mehr als 50 °C betragenden Abkühlgeschwindigkeit im Temperaturbereich von 680 - 720 °C kontinuierlich abgekühlt. An die erste Stufe der Abkühlung schließt sich eine Zwischenkühlphase an, innerhalb der das Band an Luft für bis zu 15 Sekunden kühlt. Dann folgt eine dritte Kühlphase, bei der mit Abkühlgeschwindigkeiten von mindestens 30 °C/s in einem Temperaturbereich von 300 bis 600 °C abgekühlt wird. Schließlich wird das Band gehaspelt.In addition to the prior art explained above, JP 10-195588 A discloses a method for producing a hot strip from a slab, which (in% by weight) 0.02-0.2% C, 0.1-1, 5% Si, 0.5-3.0% Mn and one or more of the elements Cr and Mo each with 0.1-2.0%, the rest iron. The hot strip is hot-rolled according to the known method at a final temperature corresponding at least to the Ar 3 temperature to thicknesses which are typically in the range from 0.8 to 1.4 mm. After leaving the hot rolling mill, the hot strips are continuously cooled in a first stage that begins 0.1 to 5 s after hot rolling with a cooling rate in the temperature range of 680 - 720 ° C that is more than 50 ° C. The first stage of cooling is followed by an intermediate cooling phase, during which the belt cools in air for up to 15 seconds. A third cooling phase then follows, in which cooling is carried out at a cooling rate of at least 30 ° C./s in a temperature range from 300 to 600 ° C. Finally the tape is coiled.

Ein vergleichbares Verfahren ist aus der EP-A-0 719 868 bekannt. Gemäß diesem bekannten Verfahren wird eine Bramme mit (in Gew.-%) 0,001 - 0,1 % C, < 1,5 % Si, 0,5 - 3,0 % Mn, 0,01 - 0,1 % Al, sowie ein oder mehrere der Elemente P (0,05 - 0,15 %) und Cr (0,5 - 1,5 %), Rest Eisen, bei einer Warmwalzendtemperatur von bis zu 850 °C kontinuierlich zu Warmband fertiggewalzt. Innerhalb von 0,5 s nach dem Fertigwarmwalzen erfolgt ein erstes Abkühlen bei Temperaturen, die zwischen 650 - 750 °C liegen. Die Abkühlgeschwindigkeit beträgt dabei mindestens 30 °C/s, typischerweise 42 - 70 °C/s. An die erste Abkühlstufe schließt sich eine Zwischenkühlphase an, bei der das Band für 4 bis 60 Sekunden an Luft kühlt. Dann folgt eine dritte Abkühlung bei Abkühlraten von mindestens 30 °C/s auf eine zwischen 100 °C und 500 °C liegende Haspeltemperatur.A comparable method is known from EP-A-0 719 868 known. According to this known method, a Slab with (in% by weight) 0.001 - 0.1% C, <1.5% Si, 0.5 - 3.0% Mn, 0.01-0.1% Al, and one or more of the Elements P (0.05 - 0.15%) and Cr (0.5 - 1.5%), the rest Iron, at a hot rolling end temperature of up to 850 ° C continuously rolled into hot strip. Within A first is carried out 0.5 s after the finish hot rolling Cooling down at temperatures between 650 - 750 ° C lie. The cooling rate is at least 30 ° C / s, typically 42 - 70 ° C / s. To the The first cooling stage is followed by an intermediate cooling phase at which the belt cools in air for 4 to 60 seconds. This is followed by a third cooling at cooling rates of at least 30 ° C / s to between 100 ° C and 500 ° C lying reel temperature.

Die Aufgabe der Erfindung besteht darin, ein Verfahren zu schaffen, mit welchem Warmbänder erzeugt werden können, die ein hohes Umformvermögen und eine erhöhte Festigkeit aufweisen. The object of the invention is to provide a method create with which hot strips can be produced which have high formability and increased strength exhibit.

Diese Aufgabe wird erfindungsgemäß durch ein Verfahren zum Erzeugen eines Warmbandes gelöst, welches insbesondere aus Strangguß in Form von wiedererwärmten oder direkt aus der Gießhitze eingesetzten Brammen, aus Dünnbrammen oder aus gegossenem Band basierend auf einem Stahl hergestellt ist, der (in Masse-%) C 0,001 - 1,05 %, Si ≤ 1,5 %, Mn 0,05 - 3,5 %, Al ≤ 2,5 %, sowie wahlweise eines oder mehrere der Elemente

  • Cu, Ni, Mo mit einem Anteil ≤ 0,8 %,
  • N, Ti, Nb, V, Zn, B mit einem Anteil ≤ 0,5 %,
  • P mit einem Anteil ≤ 0,09 %,
  • Cr mit einem Anteil ≤ 1,5 % und / oder
  • S mit einem Anteil ≤ 0,02 %,
und als Rest Eisen sowie übliche Begleitelemente enthält, wobei der Stahl ebenso wahlweise in der Flüssigphase mit Ca oder Ca-Trägerlegierungen behandelt sein kann, umfassend die folgenden Schritte:
  • Kontinuierliches Fertigwalzen des Warmbandes (W),
  • kontinuierliches Abkühlen des Warmbandes (W) in mindestens zwei aufeinander folgenden Kühlphasen (tCK, tLK) beschleunigter Kühlung auf eine Endtemperatur,
  • wobei die erste Kühlphase (tCK) beschleunigter Kühlung spätestens drei Sekunden nach dem letzten Walzstich des Fertigwalzens beginnt und
  • wobei das Warmband (W) während der ersten Kühlphase (tCK) beschleunigter Kühlung mit einer Abkühlgeschwindigkeit von mindestens 250 °C/s gekühlt wird.
This object is achieved according to the invention by a method for producing a hot strip, which is produced in particular from continuous casting in the form of reheated slabs or slabs used directly from the casting heat, from thin slabs or from cast strip based on a steel which (in mass%) C 0.001 - 1.05%, Si ≤ 1.5%, Mn 0.05 - 3.5%, al ≤ 2.5%, and optionally one or more of the elements
  • Cu, Ni, Mo with a proportion ≤ 0.8%,
  • N, Ti, Nb, V, Zn, B with a proportion ≤ 0.5%,
  • P with a proportion ≤ 0.09%,
  • Cr with a proportion ≤ 1.5% and / or
  • S with a proportion ≤ 0.02%,
and the balance contains iron as well as usual accompanying elements, wherein the steel can also be optionally treated in the liquid phase with Ca or Ca carrier alloys, comprising the following steps:
  • Continuous finishing of the hot strip (W),
  • continuous cooling of the hot strip (W) in at least two successive cooling phases (t CK , t LK ) accelerated cooling to a final temperature,
  • the first cooling phase (t CK ) of accelerated cooling begins no later than three seconds after the last pass of the finish rolling and
  • the hot strip (W) being cooled during the first cooling phase (t CK ) of accelerated cooling at a cooling rate of at least 250 ° C./s.

Gemäß der Erfindung erfolgt das Abkühlen des Warmbandes ebenfalls in mindestens zwei aufeinander folgend durchlaufenen Stufen. Dabei wird das Warmband in der ersten Kühlphase erheblich schneller gekühlt als beim Stand der Technik. Diese kompakte Kühlung während der ersten Kühlphase hat zur Folge, daß die γ/α-Umwandlung des im γ-Gebiet warmgewalzten Bandes wirksam und zielgerichtet zu tieferen Temperaturen hin unterdrückt wird. In der anschließend durchlaufenen zweiten Kühlphase mit beschleunigter Abkühlung wird das Band dann auf die gewünschte Endtemperatur gebracht. In dieser Kühlphase werden die härtesteigernden Zweitphasen des Warmband-Gefüges, wie Martensit, Bainit und Restaustenit, eingestellt. (Bei der am Ende der zweiten Kühlphase beschleunigter Kühlung erreichten Endtemperatur kann es sich selbstverständlich um die in Abhängigkeit von den gewünschten Bearbeitungsergebnissen erforderliche Haspeltemperatur handeln.)According to the invention, the hot strip is cooled also in at least two consecutive through stages. The hot strip is in the the first cooling phase cooled much faster than the State of the art. This compact cooling during the first cooling phase has the consequence that the γ / α conversion of effective and targeted in the γ-region of hot-rolled strip is suppressed towards lower temperatures. In the then run through the second cooling phase The tape is then accelerated to the cooling brought desired final temperature. In this cooling phase the hardness-increasing second phases of the hot strip structure, like martensite, bainite and residual austenite, set. (At the end of the second cooling phase accelerated cooling can reach the final temperature of course, depending on the desired processing results required Act reel temperature.)

Um die γ/α-Umwandlung sicher bis zu tieferen Temperaturen hin zu unterdrücken, soll die Phase kompakter Kühlung erfindungsgemäß bei möglichst hohen Abkühlraten und in möglichst unmittelbarem Anschluß an den letzten Stich des Fertigwalzens durchlaufen werden. Daher beträgt die in dieser Phase zu erreichende Abkühlgeschwindigkeit mindestens 250 °C/s.Around the γ / α conversion safely down to lower temperatures to suppress the phase of compact cooling according to the invention at the highest possible cooling rates and in as close as possible to the last stitch of the Finish rolling. Therefore the in cooling rate to be achieved in this phase at least 250 ° C / s.

In Abhängigkeit von den gewünschten Materialeigenschaften kann der für die Herstellung des Warmbandes verwendete Stahl wahlweise zusätzliche Elemente enthalten. Dabei sollte im Fall ihrer Anwesenheit der Anteil (in Masse-%) von Cu, Ni, Mo nicht größer als 0,8 %, der von N, Ti, Nb, V, Zn, B nicht größer als 0,5 %, der von P nicht größer als 0,09 %, der von Cr nicht größer als 1,5 % und der von S nicht größer als 0,02 % sein.Depending on the desired material properties can be used for the production of the hot strip Steel optionally contain additional elements. there in the event of their presence, the proportion (in mass%) of Cu, Ni, Mo not more than 0.8%, that of N, Ti, Nb, V, Zn, B not larger than 0.5%, that of P not larger than 0.09%, that of Cr not greater than 1.5% and that of S should not be greater than 0.02%.

Versuche haben gezeigt, daß sich unter anderem insbesondere solche Stähle der voranstehend genannten Art für die Durchführung des erfindungsgemäßen Verfahrens eignen, die 0,005 bis 0,4 Masse-% Silizium enthalten.Experiments have shown that, among other things in particular such steels of the aforementioned type for carrying out the method according to the invention are suitable, which contain 0.005 to 0.4 mass% silicon.

Das erfindungsgemäße Verfahren ist zum einen zum Erzeugen von Warmbändern geeignet, welche basierend auf Stählen mit niedrigen Kohlenstoffgehalten hergestellt sind. So ist eine vorteilhafte Variante des erfindungsgemäßen Verfahrens dadurch gekennzeichnet, daß der Stahl (in Masse-%) nicht mehr als 0,07 % C, nicht mehr als 0,2 % Si, nicht mehr als 0,6 % Mn und nicht mehr als 0,08 % Al enthält, das Warmband während des Fertigwalzens im Austenitgebiet gewalzt wird, das Warmband in der ersten Kühlphase beschleunigter Kühlung ausgehend von einer Temperatur oberhalb 850 °C auf eine Temperatur von 680 bis 750 °C gekühlt wird, das Warmband in der zweiten Kühlphase beschleunigter Kühlung auf eine Temperatur von weniger als 600 °C gekühlt wird und schließlich gehaspelt wird.The method according to the invention is firstly for generating suitable for hot strips, which are based on steels are manufactured with low carbon contents. So is an advantageous variant of the invention Process characterized in that the steel (in Mass%) not more than 0.07% C, not more than 0.2% Si, not more than 0.6% Mn and not more than 0.08% Al contains the hot strip during finish rolling in Austenite area is rolled, the hot strip in the first Cooling phase of accelerated cooling starting from one Temperature above 850 ° C to a temperature of 680 is cooled to 750 ° C, the hot strip in the second Cooling phase accelerated cooling to a temperature of is cooled to less than 600 ° C and finally coiled becomes.

Ebenso ist das erfindungsgemäße Verfahren zum Herstellen von DP-Warmbandstählen geeignet. Eine dementsprechende Ausgestaltung des erfindungsgemäßen Verfahrens ist dadurch gekennzeichnet, daß der Stahl (in Masse-%) 0,04 - 0,09 % C, nicht mehr als 0,2 % Si, 0,5 - 2,0 % Mn, 0,02 - 0,09 % P und nicht mehr als 0,9 % Cr enthält, und daß das Warmband nach dem Fertigwalzen in der ersten Kühlphase beschleunigter Kühlung ausgehend von einer Temperatur oberhalb 800 °C auf eine Temperatur von 650 bis 730 °C gekühlt wird, daß das Warmband in der zweiten Kühlphase beschleunigter Kühlung auf weniger als 500 °C gekühlt wird und daß das Warmband anschließend gehaspelt wird.The method of manufacture according to the invention is likewise suitable for DP hot strip steels. A corresponding one Design of the method according to the invention characterized in that the steel (in mass%) 0.04 - 0.09% C, not more than 0.2% Si, 0.5 - 2.0% Mn, 0.02 - Contains 0.09% P and not more than 0.9% Cr, and that the Hot strip after finish rolling in the first cooling phase accelerated cooling based on a temperature above 800 ° C to a temperature of 650 to 730 ° C is cooled that the hot strip in the second cooling phase accelerated cooling cooled to less than 500 ° C and that the hot strip is then coiled.

Auch bei Stählen mit höheren Kohlenstoff-Anteilen lassen sich bei erfindungsgemäßer Vorgehensweise Verbesserungen der Materialeigenschaften erzielen. So wird gemäß einer weiteren Ausgestaltung der Erfindung ein Warmband, welches auf einem Stahl mit (in Masse-%) 0,25 - 1,05 % C, nicht mehr als 0,25 % Si und nicht mehr als 0,6 % Mn basiert, nach dem Fertigwalzen in der ersten Kühlphase beschleunigter Kühlung ausgehend von einer Temperatur oberhalb 800 °C auf eine Temperatur von 530 bis 620 °C gekühlt, in der zweiten Kühlphase beschleunigter Kühlung auf weniger als 500 °C gekühlt und anschließend gehaspelt. Ein derart hergestelltes Warmband weist ebenfalls eine verbesserte Härte und bessere Umformeigenschaften gegenüber herkömmlich erzeugten Bändern auf.Even with steels with a higher carbon content improvements in the procedure according to the invention of the material properties. According to one a further embodiment of the invention, a hot strip, which on a steel with (in mass%) 0.25 - 1.05% C, not more than 0.25% Si and not more than 0.6% Mn based, after finishing rolling in the first cooling phase accelerated cooling based on a temperature above 800 ° C to a temperature of 530 to 620 ° C cooled, in the second cooling phase accelerated cooling cooled to less than 500 ° C and then coiled. A hot strip produced in this way has also improved hardness and better Forming properties compared to conventionally produced Tapes.

Bei einem aluminiumhaltigen TRIP-Warmband, welches (in Masse-%) 0,12 - 0,3 % C, 1,2 - 3,5 % Mn und 1,1 - 2,2 % Al enthält, und in der erfindungsgemäßen Weise nach dem Fertigwalzen in der ersten Kühlphase ausgehend von einer Temperatur, welche zwischen der Ar3-Temperatur und einer Temperatur von Ar3 + 150 °C liegt, auf eine Temperatur gekühlt wird, welche bis zu 50 °C unterhalb der Ar3-Temperatur liegt, in der zweiten Kühlphase auf 350 bis 550 °C gekühlt wird und anschließend gehaspelt wird, können ebenfalls Verbesserungen der Festigkeit bei gleichzeitig hohem Umformvermögen festgestellt werden.In the case of an aluminum-containing TRIP hot strip, which (in mass%) contains 0.12-0.3% C, 1.2-3.5% Mn and 1.1-2.2% Al, and in the manner according to the invention after finish rolling in the first cooling phase, starting from a temperature which is between the Ar 3 temperature and a temperature of Ar 3 + 150 ° C., is cooled to a temperature which is up to 50 ° C. below the Ar 3 temperature , is cooled to 350 to 550 ° C in the second cooling phase and is then coiled, improvements in strength can also be found with high formability.

Eine weitere vorteilhafte Variante des erfindungsgemäßen Verfahrens ist dadurch gekennzeichnet, daß der Stahl (in Masse-%) 0,04 - 0,09 % C, 0,5 - 1,5 % Si, 0,5 - 2,0 % Mn, 0,4 - 2,5 % Al, nicht mehr als 0,09 % P sowie nicht mehr als 0,9 % Cr enthält, daß das Warmband nach dem Fertigwalzen in der ersten Kühlphase beschleunigter Kühlung ausgehend von einer Temperatur oberhalb 800 °C auf eine Temperatur von 650 bis 730 °C gekühlt wird, daß das Warmband in der zweiten Kühlphase beschleunigter Kühlung auf weniger als 500 °C gekühlt wird und daß das Warmband anschließend gehaspelt wird. Ein solches Warmband weist DP- und TRIP-Eigenschaften auf.Another advantageous variant of the invention The method is characterized in that the steel (in Mass%) 0.04 - 0.09% C, 0.5 - 1.5% Si, 0.5 - 2.0% Mn, 0.4 - 2.5% Al, no more than 0.09% P and no more than 0.9% Cr contains that the hot strip after Finishing rolls accelerated in the first cooling phase Cooling from a temperature above 800 ° C is cooled to a temperature of 650 to 730 ° C that the hot strip accelerated in the second cooling phase Cooling is cooled to less than 500 ° C and that Hot strip is then coiled. Such one Hot strip has DP and TRIP properties.

Ein Baustahl mit erhöhtem Ferrit-Anteil und daraus folgender besonders guter Umformbarkeit läßt sich dadurch herstellen, daß der Stahl (in Masse-%) 0,07 - 0,22 % C, 0,1 - 0,45 % Si sowie 0,2 - 1,5 % Mn enthält, daß das Warmband nach dem Fertigwalzen in der ersten Kühlphase beschleunigter Kühlung ausgehend von einer Temperatur oberhalb 800 °C auf eine Temperatur von 650 bis 730 °C gekühlt wird, daß das Warmband in der zweiten Kühlphase beschleunigter Kühlung auf weniger als 500 °C gekühlt wird und daß das Warmband anschließend gehaspelt wird. Bei gleicher Stahlzusammensetzung läßt sich ein Warmband mit verbesserter Härte demgegenüber dadurch erreichen, daß das Warmband nach dem Fertigwalzen in der ersten Kühlphase beschleunigter Kühlung ausgehend von einer Temperatur oberhalb 800 °C auf eine Temperatur von 580 bis 650 °C gekühlt wird, daß das Warmband in der zweiten Kühlphase beschleunigter Kühlung auf weniger als 500 °C gekühlt wird und daß das Warmband anschließend gehaspelt wird. Das derart abgekühlte Warmband weist bei einem verminderten Ferrit-Anteil höhere Bainit- und Martensit-Anteile auf.A structural steel with an increased ferrite content and from it The following particularly good formability can be thereby make the steel (in mass%) 0.07 - 0.22% C, 0.1 - 0.45% Si and 0.2 - 1.5% Mn contains that the Hot strip after finish rolling in the first cooling phase accelerated cooling based on a temperature above 800 ° C to a temperature of 650 to 730 ° C is cooled that the hot strip in the second cooling phase accelerated cooling cooled to less than 500 ° C and that the hot strip is then coiled. A hot strip can be made with the same steel composition with improved hardness, on the other hand, that the hot strip after finish rolling in the first Cooling phase of accelerated cooling starting from one Temperature above 800 ° C to a temperature of 580 is cooled to 650 ° C that the hot strip in the second Cooling phase of accelerated cooling to less than 500 ° C is cooled and that the hot strip is then coiled becomes. The hot strip cooled in this way has one reduced ferrite content, higher bainite and martensite contents on.

Entsprechend einer zweckmäßigen Ausgestaltung der Erfindung durchläuft das Warmband zwischen der ersten Kühlphase und der zweiten Kühlphase beschleunigter Kühlung eine Zwischenkühlphase, während der das Warmband einer Luftkühlung ausgesetzt ist. Diese Zwischenkühlphase sollte mindestens eine Sekunde lang dauern. Im Zuge der sich an die erste Phase compakter, d.h. stark beschleunigter Abkühlung anschließenden Zwischenphase, in der die Abkühlung an Luft erfolgt, setzt die Austenit-Umwandlung in Ferrit schneller ein und erreicht einen größeren Umfang als beim Stand der Technik, wobei gleichzeitig ein starker kornfeinender Effekt zu beobachten ist.According to an appropriate embodiment of the Invention passes through the hot strip between the first Cooling phase and the second cooling phase accelerated Cooling an intermediate cooling phase during which the hot strip is exposed to air cooling. This intermediate cooling phase should take at least a second. In the course of the first phase more compact, i.e. strongly accelerated cooling subsequent intermediate phase, in the cooling in air takes place the austenite transformation in ferrite faster and reaches one larger scope than in the prior art, wherein at the same time a strong grain-refining effect watch is.

Überraschend ist festgestellt worden, daß sich durch das erfindungsgemäße Vorgehen ein Warmband herstellen läßt, welches im Vergleich zu einem nach dem herkömmlichen Verfahren in zwei Laminar-Kühlstufen mit zwischengeschalteter Kühlung an Luft gekühlten Warmband gleicher Zusammensetzung eine gesteigerte Härte und eine feinkörnigere Gefügestruktur besitzt. Gleichzeitig weist das nach dem erfindungsgemäßen Verfahren erzeugte Band eine hohe Festigkeit und, anders als die nach dem bekannten Verfahren erzeugten Bänder, eine gute Umformbarkeit auf.It has surprisingly been found that the procedure according to the invention can produce a hot strip, which compared to a conventional one Process in two laminar cooling stages with intermediate cooling in air-cooled hot strip same composition an increased hardness and a has a finer grain structure. At the same time the tape produced by the method according to the invention high strength and, unlike that after known methods produced tapes, a good one Formability on.

Gemäß einer bevorzugten Ausgestaltung der Erfindung beginnt daher die erste Kühlphase spätestens zwei Sekunden nach dem letzten Walzstich des Fertigwalzens.According to a preferred embodiment of the invention The first cooling phase therefore begins at the latest two Seconds after the last pass of finish rolling.

Eine weitere vorteilhafte Ausgestaltung des Verfahrens, mit welcher sich ein Warmband von besonders guter Umformbarkeit herstellen läßt, ist dadurch gekennzeichnet, daß mindestens einer der Walzstiche während des Fertigwalzens im Austenitgebiet unterhalb einer Temperatur von Ar3 + 80 °C durchgeführt wird und daß die Gesamtstichabnahme während des Fertigwalzens mehr als 30 % beträgt. A further advantageous embodiment of the method, with which a hot strip of particularly good formability can be produced, is characterized in that at least one of the rolling passes is carried out during the finish rolling in the austenite region below a temperature of Ar 3 + 80 ° C and that the total pass decrease during of finish rolling is more than 30%.

Je nach Beschaffenheit und Zusammensetzung des zur Erzeugung des Warmbandes eingesetzten Stahls ist es zweckmäßig, wenn der insbesondere als Dünnbrammen-Vormaterial in die jeweilige Walzstraße eingeführte Stahl in der Flüssigphase mit Ca oder Ca-Trägerlegierungen behandelt wird.Depending on the nature and composition of the It is generation of the hot strip used steel expedient if the in particular as a thin slab primary material steel introduced into the respective rolling mill in the liquid phase with Ca or Ca carrier alloys is treated.

Abhängig vom jeweils gewünschten Arbeitsergebnis, kann es schließlich vorteilhaft sein, wenn das Warmband in der zweiten Kühlphase mit einer Abkühlgeschwindigkeit von mindestens 30 °C/s gekühlt wird.Depending on the desired work result, it can finally be advantageous if the hot strip in the second cooling phase with a cooling rate of is cooled at least 30 ° C / s.

Nachfolgend wird die Erfindung anhand einer ein Ausführungsbeispiel darstellenden Zeichnung näher erläutert. Es zeigen in schematischer Darstellung:

Fig. 1
den eine Kühlstrecke umfassenden Endabschnitt einer Linie zum Herstellen von Warmbändern in seitlicher Ansicht;
Fig. 2
ein Diagramm, in welchem der Temperaturverlauf während des Abkühlens innerhalb der Kühlstrecke dargestellt ist;
Fig. 3
ein Diagramm, in welchem die umgewandelten Anteile eines zur Herstellung eines Warmbandes verwendeten Stahls über der Temperatur bei herkömmlicher und bei erfindungsgemäßer Verfahrensweise dargestellt sind.
The invention is explained in more detail below on the basis of a drawing illustrating an exemplary embodiment. In a schematic representation:
Fig. 1
the end section of a line for producing hot strips comprising a cooling section in a side view;
Fig. 2
a diagram in which the temperature profile during cooling is shown within the cooling section;
Fig. 3
a diagram in which the converted proportions of a steel used for the production of a hot strip against the temperature are shown in the conventional and in the inventive procedure.

Die Linie 1 zum Herstellen eines Warmbandes W umfaßt eine Staffel von mehreren Fertig-Walzgerüsten, von denen hier lediglich das letzte Gerüst 2 dargestellt ist. In der Fertigwalz-Staffel wird das Warmband W auf seine gewünschte Enddicke fertig gewalzt. Line 1 for producing a hot strip W comprises one Relay of several finishing stands, one of which is here only the last frame 2 is shown. In the Finishing rolling the hot strip W is on its The desired final thickness is rolled.

In geringem Abstand hinter dem letzten Fertig-Walzgerüst 2 ist eine Compakt-Kühleinrichtung 3 angeordnet. Diese Compakt-Kühleinrichtung 3 umfaßt hier nicht dargestellte Düsen, über die Kühlflüssigkeit, vorzugsweise Wasser, unter erhöhtem Druck auf die Ober- und Unterseite des Warmbandes W gebracht wird. Der Volumenstrom der Kühlflüssigkeit ist so einstellbar, daß innerhalb der Compakt-Kühleinrichtung 3 Abkühlgeschwindigkeiten von 150 °C/s bis 1000 °C/s erzielbar sind.A short distance behind the last finished roll stand 2, a compact cooling device 3 is arranged. This Compact cooling device 3 includes not shown here Nozzles, via the cooling liquid, preferably water, under increased pressure on the top and bottom of the Hot strip W is brought. The volume flow of the Coolant is adjustable so that within the Compact cooling device 3 cooling speeds of 150 ° C / s to 1000 ° C / s can be achieved.

In Förderrichtung F des Warmbandes W beabstandet zu der Compakt-Kühleinrichtung 3 ist eine zweite Kühleinrichtung 4 angeordnet. Die zweite Kühleinrichtung 4 arbeitet nach Art einer herkömmlichen Laminarkühlung, bei der die Kühlflüssigkeit durch mehrere in Förderrichtung F hintereinander angeordnete, hier ebenfalls nicht gezeigte Düsen fächerartig auf das Warmband W gebracht wird. Die Anzahl der jeweils beaufschlagten Düsen und / oder der Volumenstrom der im Bereich der Laminar-Kühleinrichtung 4 ausgebrachten Kühlflüssigkeit sind derart regelbar, daß im Bereich der Laminar-Kühleinrichtung 4 Abkühlgeschwindigkeiten von 30 bis 150 °C/s erreicht werden.In the conveying direction F of the hot strip W at a distance from the Compact cooling device 3 is a second cooling device 4 arranged. The second cooling device 4 works Kind of a conventional laminar cooling, in which the Coolant through several in the conveying direction F arranged one behind the other, also not shown here Fan is brought onto the hot strip W in a fan-like manner. The Number of nozzles acted upon and / or Volume flow in the area of the laminar cooling device 4 applied coolant can be regulated in such a way that in the area of the laminar cooling device 4 Cooling speeds of 30 to 150 ° C / s reached become.

In Förderrichtung F des Bandes hinter der Laminar-Kühleinrichtung 4 ist eine Haspeleinrichtung 5 angeordnet, in welcher das Warmband W zu einem Coil gewickelt wird.In the conveying direction F of the belt behind the laminar cooling device 4 is a reel device 5 arranged, in which the hot strip W to a coil is wrapped.

Ein beispielsweise aus einem Mehrphasenstahl erzeugtes Warmband W wird in der Fertigwalzstaffel ausschließlich im Austenitgebiet bei einer Gesamtstichabnahme von mehr als 30 % gewalzt. Erforderlichenfalls wird das Warmband W während des Walzens einer thermomechanischen Behandlung unterzogen. For example, one made from a multi-phase steel Hot strip W is used exclusively in the finishing mill in the austenite area with a total decrease of more rolled as 30%. If necessary, the hot strip W during the rolling of a thermomechanical treatment subjected.

Nachdem das Warmband W das letzte Gerüst 2 der Fertig-Walzstaffel verlassen hat, gelangt es innerhalb einer Überführungsphase t2, welche kürzer als zwei Sekunden ist, in die Compakt-Kühleinrichtung 3. Mit Eintritt in die Compakt-Kühleinrichtung 3 wird das Warmband W in einer ersten Kühlphase tCK kontinuierlich einer compakten Abkühlung ausgesetzt, während der das Warmband W von einer Eingangstemperatur ETCK auf eine Austrittstemperatur ATCK abgekühlt wird. Die dabei erreichten Abkühlgeschwindigkeiten liegen zwischen 250 und 1000 °C/s. Durch die in der Compakt-Kühleinrichtung 3 innerhalb kurzer Zeit tz nach dem Austritt aus der Fertig-Walzstaffel erfolgende beschleunigte Abkühlung des Warmbandes W wird die γ/α-Umwandlung des Warmbandstahls unterdrückt.After the hot strip W has left the last stand 2 of the finished rolling mill, it arrives in the compact cooling device 3 within a transfer phase t 2 , which is shorter than two seconds. Upon entering the compact cooling device 3, the hot strip W becomes a first cooling phase t CK continuously exposed to a compact cooling, during which the hot strip W is cooled from an inlet temperature ET CK to an outlet temperature AT CK . The cooling rates achieved are between 250 and 1000 ° C / s. The γ / α conversion of the hot strip steel is suppressed by the accelerated cooling of the hot strip W in the compact cooling device 3 within a short time t z after the exit from the finished rolling stack.

Anschließend durchläuft das Warmband W eine freie Strecke, in welcher es für eine Zwischenkühlphase tPAUSE an Luft gekühlt wird. Die Dauer der Zwischenkühlphase tPAUSE beträgt mindestens eine Sekunde. In dieser Zeit findet eine Teilumwandlung des Warmbandstahls statt.The hot strip W then runs through a free stretch in which it is cooled in air for an intermediate cooling phase t PAUSE . The duration of the intermediate cooling phase t PAUSE is at least one second. During this time there is a partial conversion of the hot strip steel.

Schließlich gelangt das Warmband W in die Laminar-Kühleinrichtung 4. In dieser wird es innerhalb einer zweiten Kühlphase tLK von einer Eingangstemperatur ETLK auf eine Austrittstemperatur ATLK gekühlt. Die dabei eingestellte Abkühlgeschwindigkeit liegt zwischen 30 und 150 °C/s. In Abhängigkeit von der jeweiligen chemischen Zusammensetzung des Stahls und der gewählten Abkühlgeschwindigkeit werden Zweitphasen (Bainit, Martensit oder Restaustenit) gebildet, durch welche die Eigenschaften des Warmbandes W beeinflußt werden. Auch der Ausscheidungszustand des Warmbandes W wird auf diese Weise gesteuert. Finally, the hot strip W arrives in the laminar cooling device 4. In this, it is cooled from an inlet temperature ET LK to an outlet temperature AT LK within a second cooling phase t LK . The set cooling rate is between 30 and 150 ° C / s. Depending on the respective chemical composition of the steel and the cooling rate chosen, second phases (bainite, martensite or residual austenite) are formed, through which the properties of the hot strip W are influenced. The excretion state of the hot strip W is also controlled in this way.

Zuletzt wird das derart abgekühlte Warmband W in der Haspeleinrichtung 5 aufgehaspelt.Finally, the hot strip W cooled in this way is Coiler device 5 coiled.

In Tabelle 1 sind die Gefügeanteile und die Härte von aus Stählen "Stahll" - "Stahl2" hergestellten Warmbändern, die nach dem voranstehend erläuterten Verfahren gemäß der Erfindung erzeugt worden sind, den Gefügeanteilen und der Härte von Warmbändern gleicher Zusammensetzung gegenübergestellt, welche in herkömmlicher Weise in zwei Laminar-Kühleinrichtungen mit dazwischen geschaltetem Kühlen an Luft abgekühlt worden sind.

Figure 00140001
Table 1 compares the structure components and the hardness of hot strips produced from steels "Stahl" - "Stahl2", which were produced according to the method according to the invention explained above, with the structure components and the hardness of hot strips of the same composition, which are produced in a conventional manner have been cooled in air in two laminar cooling devices with intervening cooling.
Figure 00140001

Die Zusammensetzungen der zur Herstellung der Warmbänder verwendeten Stähle "Stahl1" und "Stahl2" sind in Tabelle 2 angegeben. C Mn P S Si Cu Al N Cr Ni Ti Nb Stahl1 0,15 1,38 0,009 0,007 0.42 0,01 0,026 0,0041 0,02 0,02 0,02 0,018 Stahl2 0,13 1,45 0,012 0,004 0,35 0,14 0,037 0,0064 0,04 0,16 0,034 The compositions of the steels "Stahl1" and "Stahl2" used to produce the hot strips are given in Table 2. C Mn P S Si Cu al N Cr Ni Ti Nb steel1 0.15 1.38 0.009 0,007 00:42 0.01 0.026 0.0041 0.02 0.02 0.02 0,018 Steel2 0.13 1.45 0,012 0,004 0.35 0.14 0.037 0.0064 0.04 0.16 0.034

In Fig. 3 ist für den Stahll in durchgezogener Linie der Verlauf CLK derjenigen Gefügeumwandlung, welcher sich einstellt, wenn ein Warmband zunächst in der erfindungsgemäßen Weise für die Zeit tCK eine Compakt-Kühlung mit einer Abkühlgeschwindigkeit von 250 °C/s, anschließend eine Zwischenkühlphase tPAUSE und schließlich für die Zeit tLK eine Laminar-Kühlung durchläuft, dem in gestrichelter Linie gezeichneten Verlauf LLK der Gefügeumwandlung gegenübergestellt, der sich bei einer herkömmlichen Kombination zweier Laminar-Kühlungen mit zwischengeschalteter Kühlung an Luft einstellt.In Fig. 3 is for the steel in a solid line the course CLK of that structural change, which occurs when a hot strip is first in the manner according to the invention for the time t CK a compact cooling with a cooling rate of 250 ° C / s, then one Intermediate cooling phase t PAUSE and finally a laminar cooling cycle for the time t LK , contrasted with the LLK course of the structural transformation drawn in dashed lines, which occurs in a conventional combination of two laminar cooling systems with intermediate cooling in air.

Es ist deutlich zu erkennen, daß durch die vorgeschaltete Compakt-Kühlung der Anteil an harten Phasen, d.h. solchen, die bei geringen Temperaturen umwandeln, zunimmt. So liegt bei erfindungsgemäßer Abfolge von Compakt- / Luft- / Laminarkühlung der umgewandelte Anteil UA des Austenits bei einer Temperatur von 450 °C erst bei ca. 60 %. Die Umwandlung der restlichen Anteile des Austenits setzt dann in größerem Maße bei Temperaturen unterhalb von 400 °C ein und ist erst bei einer Temperatur von 320 °C abgeschlossen. Demgegenüber hat der umgewandelte Anteil UA im Falle der herkömmlichen Laminar- / Luft- / Laminarkühlung bei 400 °C schon annähernd 90 % erreicht. Die Umwandlung des dann noch verbleibenden Austenits ist schon bei 350 °C abgeschlossen.It can be clearly seen that the upstream Compact cooling the proportion of hard phases, i.e. those that convert at low temperatures, increases. Thus, with the sequence of Compact / air / laminar cooling the converted portion UA of austenite at a temperature of 450 ° C only at about 60%. The conversion of the remaining shares of the Austenite then sets to a greater extent at temperatures below 400 ° C and is only at one Temperature of 320 ° C completed. In contrast, the converted portion UA in the case of the conventional Laminar / air / laminar cooling at 400 ° C already almost 90% achieved. The conversion of the then remaining austenite is already at 350 ° C completed.

Tabelle 1 bestätigt die Aussage der Fig. 3. Bei jedem der untersuchten Warmbänder ist bei Anwendung des erfindungsgemäßen Verfahrens gegenüber herkömmlich abgekühlten Bändern eine Verschiebung der Gefügeanteile zugunsten der härteren Martensit-Phasen erreicht worden. Dies führte bei unveränderter Zusammensetzung zu einer deutlichen Steigerung der Härte des jeweiligen Warmbandes.Table 1 confirms the statement in FIG. 3. In each of the examined hot strips is when using the method according to the invention compared to conventional cooled bands a shift in the structural components in favor of the tougher martensite phases. With unchanged composition, this led to a significant increase in the hardness of each Hot strip.

Gleichzeitig weisen die gemäß der Erfindung hergestellten Proben ein Gefüge mit feinkörnigerer Struktur auf als die nach dem herkömmlichen Verfahren erzeugten. Dies hat zur Folge, daß die erfindungsgemäß hergestellten Warmbänder trotz der gestiegenen Anteile der harten Phasen eine gute Umformbarkeit aufweisen. Bestätigt wurde dieser Umstand auch für einen TRIP-Stahl ((in Masse-%) C: 0,2 %, Al: 1,8 %, Mn: 1,6 %). Ein solcher Stahl wies nach herkömmlicher Herstellungsweise einen mittleren Ferritkorn-Durchmesser von 6 - 7 µm auf. Bei erfindungsgemäßer Vorgehensweise ist dieser Durchmesser auf weniger als 3 µm vermindert. At the same time, those manufactured according to the invention Sample a structure with a finer grain structure than that generated by the conventional method. This has to Consequence that the hot strips produced according to the invention a good one despite the increased shares of the hard phases Show formability. This fact has been confirmed also for a TRIP steel ((in mass%) C: 0.2%, Al: 1.8 %, Mn: 1.6%). Such steel pointed to conventional Production method an average ferrite grain diameter from 6 - 7 µm. With the procedure according to the invention this diameter is reduced to less than 3 µm.

BEZUGSZEICHENREFERENCE NUMBERS

FF
Förderrichtung,Conveying direction,
WW
Warmband,Hot strip,
11
Linie zum Herstellen eines Warmbands,Hot strip production line,
22
Fertigwalz-Gerüst,Finish rolling scaffold,
33
Compakt-Kühleinrichtung,Compact cooling device,
44
Laminar-Kühleinrichtung,Laminar cooling device,
55
Haspeleinrichtung,Coiler,
t2 t 2
Überführungsphase zwischen dem Austritt aus dem Fertigwalz-Gerüst 2 und dem Beginn der Compaktkühlung,Transfer phase between leaving the Finishing mill stand 2 and the beginning of Compaktkühlung,
tCK t CK
erste Kühlphase, welche das Warmband W benötigt, um die Länge der Compakt-Kühleinrichtung 3 zurückzulegen,first cooling phase, which the hot strip W needs to the length of the compact cooling device 3 to cover,
ETCK ET CK
Eingangstemperatur des Warmbandes W beim Eintritt in die Compakt-Kühleinrichtung 3,Inlet temperature of hot strip W when entering the compact cooling device 3,
ATCK AT CK
Austrittstemperatur des Warmbandes W beim Austritt aus der Compakt-Kühleinrichtung 3,Hot strip exit temperature W at exit from the compact cooling device 3,
tPAUSE t PAUSE
Zwischenkühlphase, während der das Warmband W an Luft gekühlt wird,Intermediate cooling phase during which the hot strip W is on Air is cooled
tLK t LK
zweite Kühlphase, in der das Warmband W in der Laminar-Kühleinrichtung 4 abgekühlt wird,second cooling phase, in which the hot strip W in the Laminar cooling device 4 is cooled,
ETLK ET LK
Eingangstemperatur des Warmbandes W beim Eintritt in die Laminar-Kühleinrichtung 4,Inlet temperature of hot strip W when entering the laminar cooling device 4,
ATLK AT LK
Austrittstemperatur des Warmbandes W beim Austritt aus der Laminar-Kühleinrichtung 4,Hot strip exit temperature W at exit from the laminar cooling device 4,
CLKCLK
Verlauf der Gefügeumwandlung, der sich einstellt, wenn ein Warmband zunächst eine Compakt-Kühlung und anschließend eine Laminar-Kühlung durchläuft,Course of the structural transformation that occurs if a hot strip is first compact cooling and then goes through laminar cooling,
LLKLLK
Verlauf LLK der Gefügeumwandlung, der sich bei einer Kombination zweier Laminar-Kühlungen einstellt,Course LLK of structural change, which occurs in a Combination of two laminar cooling sets,
UAUA
jeweiliger umgewandelter Anteil des Austenits.respective converted proportion of austenite.

Claims (14)

  1. A method for producing a hot strip (W) which strip is produced in particular from continuous casting in the shape of reheated slabs or slabs obtained directly from the casting heat, from thin slabs or cast strip, based on a steel comprising (in mass %) C 0.001 - 1.05 %; Si ≤ 1.5 %; Mn 0.05 - 3.5 %; Al ≤ 2.5 %;
    as well as optionally one or several of the following constituents
    Cu, Ni, Mo with an amount of ≤ 0.8 %;
    N, Ti, Nb, V, Zn, B with an amount of ≤ 0.5 %;
    P with an amount of ≤ 0.09 %;
    Cr with an amount of ≤ 1.5 %; and / or
    S with an amount of ≤ 0.02 %;
    and
    the remainder being iron as well as the usual accompanying elements,
    with the steel also optionally having been treated in the liquid phase with Ca or Ca carrier alloys,
    involving the following steps:
    continuous finish rolling of the hot strip (W);
    continuous cooling of the hot strip (W) in at least two subsequent cooling phases (tCK, tLK) of accelerated cooling, to a final temperature;
    with the first cooling phase (tCK) of accelerated cooling starting at the latest three seconds after the last pass of finish rolling; and
    with the hot strip (W) during the first cooling phase (tCK) of accelerated cooling being cooled at a cooling rate of at least 250 °C/s.
  2. A method according to claim 1, characterised in that the steel comprises 0.005 to 0.4 mass % of silicon.
  3. A method according to claim 1, characterised in that
    the steel comprises (in mass %) C ≤ 0.07 %; Si ≤ 0.2 %; Mn ≤ 0.6 %; Al ≤ 0.08 %;
    in that the hot strip (W) during finish rolling is rolled in the austenitic area;
    in that the hot strip (W) in the first cooling phase (tCK) of accelerated cooling starting at a temperature above 850 °C is cooled to a temperature of 680 to 750 °C;
    in that the hot strip (W) in the second cooling phase (tLK) of accelerated cooling is cooled to a temperature of less than 600 °C; and
    in that the hot strip (W) is subsequently coiled.
  4. A method according to claim 1, characterised in that the steel (in mass %) comprises C 0.04 - 0.09 %; Si ≤ 0.2 %; Mn 0.5 - 2.0 %; P 0.02 - 0.09 %; Cr ≤ 0.9 %;
    in that the hot strip (W) after finish rolling in the first cooling phase (tCK) of accelerated cooling starting from a temperature above 800 °C, is cooled to a temperature of 650 to 730 °C;
    in that in the second cooling phase (tLK) of accelerated cooling, the hot strip (W) is cooled to less than 500 °C; and
    in that the hot strip (W) is subsequently coiled.
  5. A method according to one of claims 1, characterised in that the steel comprises (in mass %) C 0.25 - 1.05 %; Si ≤ 0.25 %; Mn ≤ 0.6 %;
    in that the hot strip (W) after finish rolling in the first cooling phase (tCK) of accelerated cooling starting from a temperature above 800 °C, is cooled to a temperature of between 530 and 620 °C;
    in that the hot strip (W) in the second cooling phase (tLK) of accelerated cooling is cooled to a temperature of less than 500 °C; and
    in that the hot strip (W) is subsequently coiled.
  6. A method according to claim 1, characterised in that the steel comprises (in mass %) C 0.12 - 0.3 %; Mn 1.2 - 3.5 %; Al 1.1 - 2.2 %;
    in that the hot strip (W) after finish rolling in the first cooling phase (tCK) of accelerated cooling starting from a temperature between the Ar3 temperature and a temperature of Ar3 + 150 °C, is cooled to a temperature which is up to 50 °C below the Ar3 temperature;
    in that the hot strip (W) in the second cooling phase (tLK) of accelerated cooling is cooled to 350 to 550 °C; and
    in that the hot strip (W) is subsequently coiled.
  7. A method according to claim 1, characterised in that the steel comprises (in mass %) C 0,04 - 0,09 %, Si 0,5 - 1,5 %, Mn 0,5 - 2,0 %, Al 0,4 - 2,5 %, P ≤ 0,09 %, Cr ≤ 0,9 %,
    in that the hot strip (W) after finish rolling in the first cooling phase (tCK) of accelerated cooling starting from a temperature above 800 °C, is cooled to a temperature of 650 to 730 °C;
    in that the hot strip (W) in the second cooling phase (tLK) of accelerated cooling is cooled to less than 500 °C; and
    in that the hot strip (W) is subsequently coiled.
  8. A method according to claim 1, characterised in that the steel comprises (in mass %) C 0,07 - 0,22 %, Si 0,1 - 0,45 %, Mn 0,2 - 1,5 %,
    in that the hot strip (W) after finish rolling in the first cooling phase (tCK) of accelerated cooling starting from a temperature above 800 °C, is cooled to a temperature of 650 to 730 °C;
    in that the hot strip (W) in the second cooling phase (tLK) of accelerated cooling is cooled to less than 500 °C; and
    in that the hot strip (W) is subsequently coiled.
  9. A method according to claim 1, characterised in that the steel comprises (in mass %) C 0,07 - 0,22 %, Si 0,1 - 0,45 %, Mn 0,2 - 1,5 %,
    in that the hot strip (W) after finish rolling in the first cooling phase (tCK) of accelerated cooling starting from a temperature above 800 °C, is cooled to a temperature of 580 to 650 °C;
    in that the hot strip (W) in the second cooling phase (tLK) of accelerated cooling is cooled to less than 500 °C; and
    in that the hot strip (W) is subsequently coiled.
  10. A method according to one of the preceding claims, characterised in that between the first cooling phase (tCK) of accelerated cooling and the second cooling phase (tLK) of accelerated cooling the hot strip (W) passes through an intermediate cooling phase (tPAUSE) during which the hot strip (W) is subjected to cooling by exposure to air.
  11. A method according to claim 10, characterised in that the intermediate cooling phase (tPAUSE) lasts for at least one second.
  12. A method according to one of the preceding claims, characterised in that the first cooling phase (tCK) of accelerated cooling starts at the latest two seconds after the last pass of finish rolling.
  13. A method according to one of the preceding claims, characterised in that at least one of the passes during finish rolling is carried out in the austenitic range below a temperature of Ar3 + 80 °C, and in that an overall pass reduction exceeding 30 % is achieved.
  14. A method according to one of the preceding claims, characterised in that in the second cooling phase (tLK) of accelerated cooling the hot strip (W) is cooled at a cooling rate of at least 30 °C/s.
EP00906372A 1999-03-13 2000-02-24 Method of producing a hot-rolled strip Revoked EP1169486B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19911287 1999-03-13
DE19911287A DE19911287C1 (en) 1999-03-13 1999-03-13 Process for producing a hot strip
PCT/EP2000/001517 WO2000055381A1 (en) 1999-03-13 2000-02-24 Method of producing a hot-rolled strip

Publications (2)

Publication Number Publication Date
EP1169486A1 EP1169486A1 (en) 2002-01-09
EP1169486B1 true EP1169486B1 (en) 2003-05-02

Family

ID=7900901

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00906372A Revoked EP1169486B1 (en) 1999-03-13 2000-02-24 Method of producing a hot-rolled strip

Country Status (7)

Country Link
US (1) US6855218B1 (en)
EP (1) EP1169486B1 (en)
JP (1) JP2002539330A (en)
AT (1) ATE239097T1 (en)
DE (2) DE19911287C1 (en)
ES (1) ES2195867T3 (en)
WO (1) WO2000055381A1 (en)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001023625A1 (en) * 1999-09-29 2001-04-05 Nkk Corporation Sheet steel and method for producing sheet steel
DE10161465C1 (en) * 2001-12-13 2003-02-13 Thyssenkrupp Stahl Ag Production of hot strip used in vehicle chassis comprises casting steel into pre-material, hot rolling to form hot strip, cooling in first cooling step, and cooling in second cooling step after pause to coiling temperature
EP1398390B1 (en) * 2002-09-11 2006-01-18 ThyssenKrupp Steel AG Steel with a very fine ferritic and martensitic microstructure having a high tensile strength
JP4470701B2 (en) * 2004-01-29 2010-06-02 Jfeスチール株式会社 High-strength thin steel sheet with excellent workability and surface properties and method for producing the same
DE102004038159B3 (en) * 2004-08-06 2006-05-18 Ab Skf Process for the heat treatment of workpieces made of steel or cast iron
DE102005003551B4 (en) * 2005-01-26 2015-01-22 Volkswagen Ag Method for hot forming and hardening a steel sheet
US10071416B2 (en) * 2005-10-20 2018-09-11 Nucor Corporation High strength thin cast strip product and method for making the same
US9999918B2 (en) 2005-10-20 2018-06-19 Nucor Corporation Thin cast strip product with microalloy additions, and method for making the same
US9149868B2 (en) * 2005-10-20 2015-10-06 Nucor Corporation Thin cast strip product with microalloy additions, and method for making the same
DE102005051052A1 (en) * 2005-10-25 2007-04-26 Sms Demag Ag Process for the production of hot strip with multiphase structure
DE102005052069B4 (en) * 2005-10-28 2015-07-09 Saarstahl Ag Process for the production of semi-finished steel by hot working
US7471442B2 (en) * 2006-06-15 2008-12-30 Qualcomm Mems Technologies, Inc. Method and apparatus for low range bit depth enhancements for MEMS display architectures
US8333923B2 (en) * 2007-02-28 2012-12-18 Caterpillar Inc. High strength gray cast iron
JP5214905B2 (en) * 2007-04-17 2013-06-19 株式会社中山製鋼所 High strength hot rolled steel sheet and method for producing the same
JP5176431B2 (en) * 2007-08-24 2013-04-03 Jfeスチール株式会社 Manufacturing method of high strength hot-rolled steel sheet
US20090301613A1 (en) * 2007-08-30 2009-12-10 Jayoung Koo Low Yield Ratio Dual Phase Steel Linepipe with Superior Strain Aging Resistance
DE102008004371A1 (en) * 2008-01-15 2009-07-16 Robert Bosch Gmbh Component, in particular a motor vehicle component, made of a dual-phase steel
WO2011100798A1 (en) 2010-02-20 2011-08-25 Bluescope Steel Limited Nitriding of niobium steel and product made thereby
JP5423737B2 (en) * 2010-08-10 2014-02-19 Jfeスチール株式会社 High-strength hot-rolled steel sheet excellent in workability and manufacturing method thereof
FI123847B (en) * 2011-06-15 2013-11-15 Rautaruukki Oyj METHOD FOR THE MANUFACTURE OF MEDIUM-CARBON STEEL AND HOT-ROLLED MEDIUM-STEEL
EP2880188B1 (en) * 2012-07-30 2016-07-27 Tata Steel Nederland Technology B.V. Method for producing steel strip of carbon steel
DE102013019698A1 (en) * 2013-05-03 2014-11-06 Sms Siemag Ag Method for producing a metallic strip
CN107438487B (en) 2014-12-19 2021-01-12 纽科尔公司 Hot-rolled light martensitic steel plate and manufacturing method thereof
CN107828951B (en) * 2017-10-16 2019-12-03 首钢京唐钢铁联合有限责任公司 A kind of method and device manufacturing cold rolling high-strength steel
CN112981229A (en) * 2021-01-20 2021-06-18 江阴兴澄特种钢铁有限公司 High-temperature-resistant fine-grain medium-carbon round steel for hollow transmission half shaft and manufacturing method thereof
CN113198843A (en) * 2021-04-25 2021-08-03 湖南华菱湘潭钢铁有限公司 Production method of high-Si spring round steel
CN113231485B (en) * 2021-05-07 2022-01-28 西安钢研功能材料股份有限公司 Preparation method of high-expansion alloy large coil weight strip without welding seam
AT525283B1 (en) * 2021-10-29 2023-02-15 Primetals Technologies Austria GmbH Method for producing a dual-phase steel strip in a combined casting and rolling plant, a dual-phase steel strip produced using the method and a combined casting and rolling facility
CN113999961A (en) * 2021-11-02 2022-02-01 攀钢集团攀枝花钢铁研究院有限公司 Production method for improving strip-shaped structure of central part of strip steel
CN115198171A (en) * 2022-06-08 2022-10-18 南京钢铁股份有限公司 Low-density bearing steel and smelting method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS572840A (en) * 1980-06-06 1982-01-08 Nippon Steel Corp Production of high strength low yield ratio high ductility composite structure steel plate of high artificial aging hardness after working
JPS57137426A (en) * 1981-02-20 1982-08-25 Kawasaki Steel Corp Production of low yield ratio, high tensile hot rolled steel plate by mixed structure
JP3039842B2 (en) * 1994-12-26 2000-05-08 川崎製鉄株式会社 Hot-rolled and cold-rolled steel sheets for automobiles having excellent impact resistance and methods for producing them
JPH09241790A (en) * 1996-03-07 1997-09-16 Nippon Steel Corp Hot rolled high strength steel plate of low yield ratio type, excellent in durability and fatigue characteristic, by continuous hot rolling process and its production
BE1010142A6 (en) * 1996-04-16 1998-01-06 Centre Rech Metallurgique Method for producing a hot rolled strip steel high strength.
JP3253880B2 (en) 1996-12-27 2002-02-04 川崎製鉄株式会社 Hot-rolled high-strength steel sheet excellent in formability and collision resistance, and method for producing the same

Also Published As

Publication number Publication date
DE50001976D1 (en) 2003-06-05
WO2000055381A1 (en) 2000-09-21
ES2195867T3 (en) 2003-12-16
JP2002539330A (en) 2002-11-19
ATE239097T1 (en) 2003-05-15
EP1169486A1 (en) 2002-01-09
DE19911287C1 (en) 2000-08-31
US6855218B1 (en) 2005-02-15

Similar Documents

Publication Publication Date Title
EP1169486B1 (en) Method of producing a hot-rolled strip
EP2690183B1 (en) Hot-rolled steel flat product and method for its production
DE2426920C2 (en) Process for making weldable steel bars and use of the process
EP1918403B1 (en) Process for manufacturing steel flat products from a steel forming martensitic structure
WO2007048497A1 (en) Method for producing hot strip with a multiphase structure
EP1918402B1 (en) Process for manufacturing steel flat products from a steel forming a complex phase structure
WO2007014868A1 (en) Method for producing a grain-oriented electrical steel strip
WO2007014867A1 (en) Method for producing a grain-oriented electrical steel strip
EP2690184B1 (en) Produit plat en acier laminé à froid et son procédé de fabrication
WO2011079341A2 (en) Thermomechanical treatment method
DE2454163A1 (en) METHOD OF CONTROLLING THE TEMPERATURE OF STEEL DURING HOT ROLLING ON A CONTINUOUS HOT ROLLING DEVICE
WO2015117934A1 (en) High-strength flat steel product having a bainitic-martensitic microstructure and method for producing such a flat steel product
DE3440752C2 (en)
EP1319725B1 (en) Hot strip manufacturing process
DE102014005662A1 (en) Material concept for a malleable lightweight steel
EP1398390B1 (en) Steel with a very fine ferritic and martensitic microstructure having a high tensile strength
EP1633894B1 (en) Method and installation for the production of hot-rolled strip having a dual-phase structure
WO2003097884A1 (en) Non-grain oriented electrical steel strip or electrical steel sheet and method for producing the same
EP1453984B1 (en) Method for the production of hot strip or sheet from a micro-alloyed steel
EP1396549B1 (en) Process for manufacturing hot rolled pearlite-free steel strip and hot strip obtained thereby
EP1918404B1 (en) Process for manufacturing steel flat products from aluminium alloyed multi phase steel
EP1038978B1 (en) Process for manufacturing hot strip
DE2526992C3 (en) Process for the production of hot rolled steel sheet
EP1411140B1 (en) Process for manufacturing of cold-rolled steel strips or sheets having excellent formability
WO2023016965A1 (en) Method and device for producing high-strength and very high-strength multiphase steel

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20010907

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

17Q First examination report despatched

Effective date: 20010206

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: THYSSENKRUPP STAHL AG

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030502

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030502

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20030502

REF Corresponds to:

Ref document number: 50001976

Country of ref document: DE

Date of ref document: 20030605

Kind code of ref document: P

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: GERMAN

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030802

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030802

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030804

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2195867

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

Ref document number: 1169486E

Country of ref document: IE

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20040204

Year of fee payment: 5

ET Fr: translation filed
PLBQ Unpublished change to opponent data

Free format text: ORIGINAL CODE: EPIDOS OPPO

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLBQ Unpublished change to opponent data

Free format text: ORIGINAL CODE: EPIDOS OPPO

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040224

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20040226

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040229

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040229

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: USINOR

Effective date: 20040202

26 Opposition filed

Opponent name: CORUS STAAL BV

Effective date: 20040202

Opponent name: USINOR

Effective date: 20040202

NLR1 Nl: opposition has been filed with the epo

Opponent name: USINOR

Opponent name: CORUS STAAL BV

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050224

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050224

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050225

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

EUG Se: european patent has lapsed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20060223

Year of fee payment: 7

Ref country code: AT

Payment date: 20060223

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20060228

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20060301

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20060310

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20060323

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20060413

Year of fee payment: 7

RDAF Communication despatched that patent is revoked

Free format text: ORIGINAL CODE: EPIDOSNREV1

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

27W Patent revoked

Effective date: 20060608

GBPR Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state

Free format text: 20060608

NLR2 Nl: decision of opposition

Effective date: 20060608

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO