EP1161368A1 - Verfahren zum herstellen einer wasserlöslichen verpackung - Google Patents

Verfahren zum herstellen einer wasserlöslichen verpackung

Info

Publication number
EP1161368A1
EP1161368A1 EP00907646A EP00907646A EP1161368A1 EP 1161368 A1 EP1161368 A1 EP 1161368A1 EP 00907646 A EP00907646 A EP 00907646A EP 00907646 A EP00907646 A EP 00907646A EP 1161368 A1 EP1161368 A1 EP 1161368A1
Authority
EP
European Patent Office
Prior art keywords
film
cavity
deformable material
resiliently deformable
curved edge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00907646A
Other languages
English (en)
French (fr)
Other versions
EP1161368B1 (de
Inventor
Richard Harbour
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP1161368A1 publication Critical patent/EP1161368A1/de
Application granted granted Critical
Publication of EP1161368B1 publication Critical patent/EP1161368B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B11/00Wrapping, e.g. partially or wholly enclosing, articles or quantities of material, in strips, sheets or blanks, of flexible material
    • B65B11/50Enclosing articles, or quantities of material, by disposing contents between two sheets, e.g. pocketed sheets, and securing their opposed free margins

Definitions

  • the invention relates to a process for producing a thermoformed package of the type comprising the steps of placing a first sheet of formable film over a forming die having a cavity, moulding the film into the cavity thereby forming a recess in the film, placing a composition in the thus formed recess, and sealing a second sheet of film across the recess to close the package.
  • the invention relates to such a process for producing a water- soluble package containing a detergent composition.
  • Detergent compositions for the machine washing of laundry are provided in many forms.
  • Probably the most prevalent form of laundry detergent is washing powder or granules.
  • a problem with the use of these forms of detergent is that the product needs to be dosed into the machine in such a way that the detergent is quickly and thoroughly dissolved in the wash water of the machine without coming into contact with the laundry in a solid form.
  • many dosing devices which overcome this problem have been proposed.
  • 0 343 070 and 0 343 069 teaches the use of a flexible fabric sock which holds the particulate detergent in the machine, the fabric of the sock being permeable to water so as to allow water enter the sock and carry the detergent out of the sock through the fabric walls in the form of an aqueous solution.
  • More recently unit dose forms of detergent have been proposed in the form of compressed tablets of detergent powder.
  • a problem encountered with the provision of detergent tablets is that the tablets need to be strong enough to withstand storage and transport, yet weak enough to disintegrate and dissolve quickly in the washing machine.
  • a further problem is the need to prevent the tablets "posting" in the porthole and between the drums of conventional washing machines.
  • thermoformed package of the above mentioned type the process being characterised in that the or each cavity in the forming die has a curved edge, wherein at least a portion of the curved edge is formed from a material which is less hard and more deformable than the material of the cavity.
  • at least a portion of the curved edge comprises a resiliently deformable material.
  • a predominant portion, and most preferably a whole, of the curved edge is formed of a resiliently deformable material.
  • the curved edge comprises an annular gasket of resiliently deformable material, which gasket is mounted in a circumferential groove around the or each cavity. In such a case, the gasket should be dimensioned such that, when mounted in the groove, an exposed surface of the gasket should be flush with a surface of the cavity.
  • the or each cavity is surrounded by a raised flange, wherein at least a portion, and ideally most or all, of the raised flange comprises resiliently deformable material.
  • the curved edge and flange are preferably integrally formed.
  • a single gasket preferably comprises the curved edge and the flange.
  • a ratio of a width of the flange to a minor diameter of the cavity is between 1:50 and 1:10, preferably about 1:12.
  • the resiliently deformable material is preferably silicone rubber, however other suitable material performing the same function are envisaged.
  • the film is heated by a heating plate.
  • This may be flat but preferably has at least one concave depression which in use overlies the at least one cavity, wherein the heating step involves the step of bringing the film into intimate contact with the or each depression.
  • the use of a heating plate having concave depressions helps to ensure that the film when heated thermoforms uniformly which results in a package having less weak spots.
  • intimate contact between the film and the concave depression is achieved by exerting a vacuum between the depression and the film.
  • the depression may include holes through which the vacuum may be pulled.
  • the heating plate may comprise a porous material.
  • the vacuum should ideally comprise a pressure of up to 1 Bar, and preferably be less that 0.6 Bar.
  • the film is forced into intimate contact with the concave depression by blowing air against it. Typically the pressure of the blown air will be less than 5 Bar, preferably less than 3 Bar.
  • the heating plate preferably has a temperature in the region of 100 to 120 degrees C, and ideally is approximately 110 degrees C.
  • the time the film contacts the heating plate depends to a large extent on the type of film used and the temperature of the heating plate, the time of contact between the film and the plate should be in the region 0.1 to 5 seconds, preferably 0.5 to lseconds, ideally approximately 700 milliseconds.
  • the film is a water- soluble film.
  • the package contains a liquid, gel or other type of fluent composition.
  • the liquid comprises a detergent or any other type of active agent used in the machine washing of laundry or dishes .
  • the package contains a bathing or shower gel composition or any other type of personal care composition.
  • Fig 1 is a sectional view illustration portions of a forming die and heating plate for use with the process of the invention
  • Fig 2 is a detailed sectional view of a concave depression of Fig 1 ;
  • Fig 3 is a detailed sectional view of an edge of a forming cavity according to the invention.
  • thermoforming process where a number of packages according to the invention are produced from a sheet of water soluble material, namely polyvinyl alcohol supplied under reference CC8534 from Chris Craft.
  • recesses are formed in the sheet using a forming die having a plurality of cavities with dimensions corresponding generally to the dimensions of the packages to be produced.
  • a single heating plate is used for moulding the film for all the cavities, and in the same way a single sealing plate is described.
  • a first sheet of polyvinyl alcohol film is drawn over a forming die so that the film is placed over the plurality of forming cavities in the die, the details of which are described in further detail below. In order to maximise package strength, the film is delivered to the forming die in a crease free form and with minimum tension.
  • the film is heated to 110 degrees C, for approximately 700 micro seconds.
  • a heating plate 1 is used to heat the film, which plate is positioned to superpose the forming die 2.
  • the plate includes a plurality concave depressions 3 (only one is shown) which correspond to the cavity 4 on the forming die 2.
  • Each concave depression is generally circular having a diameter of approximately 50mm and a depth of about 5mm.
  • An edge 5 of the depression 3 is radiussed as is the base 6, the radius of the base being about 50mm and the radius of the edge being about 30 mm.
  • a vacuum is pulled through the pre-heating plate to ensure intimate contact between the film and the pre-heating plate 1, this intimate contact ensuring that the film is heated evenly and uniformly (the extent of the vacuum is dependant of the thermoforming conditions and the type of film used, however in the present context a vacuum of less than 0.6 bar was found to be suitable)
  • Non-uniform heating results in a formed package having weak spots.
  • the vacuum it is possible to blow air against the film to force it into intimate contact with the preheating plate. In such cases the air should be blown at a pressure of less than 3 Bar.
  • thermoformed film is thus moulded into the cavities forming a plurality of recesses which, once formed, are retained in their thermoformed orientation by the application of a vacuum through the walls of the cavities. This vacuum is maintained at least until the packages are sealed.
  • the composition in this case a liquid detergent is added to each of the recesses.
  • a second sheet of polyvinyl alcohol film is then superposed on the first sheet covering the filled recesses and heatsealed thereto using a heating plate.
  • the heat sealing plate which is flat, operates at a temperature of about 140 to 160 degrees centigrade, and contacts the films for 1 to 2 seconds and with a force of 8 to 30kg/cm2, preferably 10 to 20kg/cm2.
  • each cavity 4 is generally dome shaped having a curved edge 10 with a radius of curvature.
  • a raised flange 11 surrounds each cavity to ensure that the films are sealed together along the flange to form a continuous seal.
  • the radiussed edge 10 and raised flange 11 are both formed a by a resiliently deformable material gasket 12 of silicone rubber. This results in reduced force being applied at the inner edge of the sealing flange to avoid heat/pressure damage to the film.
  • the packages formed are separated from the web of sheet film using cutting means. At this stage it is possible to release the vacuum on the die, and eject the formed packages from the forming die. In this way the packages are formed, filled and sealed while nesting in the forming die. In addition they may be cut while in the forming die as well .
  • the relative humidity of the atmosphere is controlled to ca . 50%. This is done to maintain the heat sealing characteristics of the film.
  • it may be necessary to reduce the relative humidity ensure that the films have a relatively low degree of plasticisation and as such tend to be stiffer resulting in easier handling.
  • the actual specific RH of the atmosphere needed will vary according to the temperature of the environment and the type of film used, however for temperatures in the region of 20 degrees C, the RH should be in the region of 30 to 50% depending on the thickness and elasticity of the film.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Plastic Fillers For Packaging (AREA)
  • Packages (AREA)
  • Wrappers (AREA)
  • Paper (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Detergent Compositions (AREA)
EP00907646A 1999-03-17 2000-02-29 Verfahren zum herstellen einer wasserlöslichen verpackung Expired - Lifetime EP1161368B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9906179.8A GB9906179D0 (en) 1999-03-17 1999-03-17 A process for producing a water soluble package
GB9906179 1999-03-17
PCT/EP2000/001647 WO2000055044A1 (en) 1999-03-17 2000-02-29 A process for producing a water soluble package

Publications (2)

Publication Number Publication Date
EP1161368A1 true EP1161368A1 (de) 2001-12-12
EP1161368B1 EP1161368B1 (de) 2002-10-30

Family

ID=10849833

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00907646A Expired - Lifetime EP1161368B1 (de) 1999-03-17 2000-02-29 Verfahren zum herstellen einer wasserlöslichen verpackung

Country Status (14)

Country Link
EP (1) EP1161368B1 (de)
CN (1) CN1344210A (de)
AT (1) ATE226905T1 (de)
AU (1) AU2916100A (de)
BR (1) BR0009048A (de)
CA (1) CA2360805A1 (de)
CZ (1) CZ20013334A3 (de)
DE (1) DE60000684T2 (de)
ES (1) ES2184696T3 (de)
GB (1) GB9906179D0 (de)
RO (1) RO118861B1 (de)
TR (1) TR200102518T2 (de)
WO (1) WO2000055044A1 (de)
ZA (1) ZA200105054B (de)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2001256248A1 (en) 2000-04-14 2001-10-30 Unilever Plc Water soluble package and liquid contents thereof
ATE263227T1 (de) 2000-05-15 2004-04-15 Unilever Nv Flüssiges reinigungsmittel
GB2374830A (en) * 2001-04-20 2002-10-30 Reckitt Benckiser Improvements in or relating to compositions/components including a thermoforming step
DE10215601B4 (de) * 2002-04-10 2005-08-04 Henkel Kgaa Wasserlöslicher Behälter sowie Verfahren zu seiner Herstellung und Verwendung desselben
DE10237200A1 (de) 2002-08-14 2004-03-04 Henkel Kgaa Portionierte Wasch- oder Reinigungsmittelzusammensetzung
DE10244802B4 (de) 2002-09-26 2011-12-22 Henkel Ag & Co. Kgaa Pralle Waschmittelformkörper
GB0222964D0 (en) 2002-10-03 2002-11-13 Unilever Plc Polymeric film for water soluble package
DE10305799B4 (de) * 2003-02-12 2012-12-27 Henkel Ag & Co. Kgaa Verfahren zur Herstellung eines blasgeformten Waschmittelkörpers
GB2475538B (en) * 2009-11-23 2011-11-23 Rideau Machinery Inc Improvements to continuous motion rotary thermoforming of soluble pouches
CN102793607B (zh) * 2012-07-23 2014-08-20 枝江奥美医疗用品有限公司 一种自粘弹性绷带的制造方法及自粘弹性绷带
ES2539732B1 (es) 2013-06-28 2016-02-05 Kao Corporation, S.A. Composición detergente líquida
WO2015000970A1 (de) 2013-07-03 2015-01-08 Basf Se Feste polymerzusammensetzung, erhalten durch polymerisation eines säuregruppenhaltigen monomers in gegenwart einer polyetherverbindung
CN105035389B (zh) * 2015-08-18 2017-03-08 瑞安市贝德机械科技有限公司 水溶膜包装机
RU2018136215A (ru) 2016-03-16 2020-04-16 Басф Се Активные для мытья и чистки полимерные пленки, способ их получения и их применение
EP4219126A3 (de) 2016-08-08 2023-08-30 Mespack Cloud, Llc Beutelformende formkonfiguration, verfahren und beutel
PL3541708T3 (pl) 2016-11-15 2022-07-25 Mespack Cloud, Llc Maszyna do cięcia torebek z ukształtowaną krawędzią obwodową, sposób i torebka
BR112019011726A2 (pt) 2016-12-16 2019-10-22 Basf Se película multicamadas, processo para produzir uma película multicamadas, uso de uma película multicamadas, bainha ou revestimento, e, composições de lavagem ou de limpeza e de lavagem de louça.
CN110291119A (zh) 2016-12-16 2019-09-27 巴斯夫欧洲公司 洗涤和清洁多层膜、其生产方法和用途
WO2019238730A1 (en) 2018-06-14 2019-12-19 Basf Se Process for producing water-soluble containers for dosing detergent
WO2020224962A1 (en) 2019-05-03 2020-11-12 Basf Se Water-soluble films with three-dimensional topography
WO2022017974A1 (en) 2020-07-24 2022-01-27 Basf Se Casein based multilayer film with improved barrier properties

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5920527B2 (ja) * 1979-10-17 1984-05-14 株式会社フジパツクシステム 包装装置
MY131091A (en) 1991-04-05 2007-07-31 Rhone Poulenc Agriculture Package for agrochemicals.
DE9303456U1 (de) * 1993-03-09 1993-04-29 Mosheer, Hanspeter, Buerglen, Ch

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0055044A1 *

Also Published As

Publication number Publication date
EP1161368B1 (de) 2002-10-30
TR200102518T2 (tr) 2002-01-21
CZ20013334A3 (cs) 2002-03-13
DE60000684T2 (de) 2003-06-12
ES2184696T3 (es) 2003-04-16
CA2360805A1 (en) 2000-09-21
ATE226905T1 (de) 2002-11-15
CN1344210A (zh) 2002-04-10
ZA200105054B (en) 2002-06-20
WO2000055044A1 (en) 2000-09-21
AU2916100A (en) 2000-10-04
DE60000684D1 (de) 2002-12-05
BR0009048A (pt) 2002-01-15
RO118861B1 (ro) 2003-12-30
GB9906179D0 (en) 1999-05-12

Similar Documents

Publication Publication Date Title
EP1161369B1 (de) Verfahren zum herstellen einer wasserlöslichen verpackung
US6281183B1 (en) Process for producing a water soluble package
EP1161368B1 (de) Verfahren zum herstellen einer wasserlöslichen verpackung
EP1161587B1 (de) Verfahren zur herstellung einer wasserlöslichen verpackung
EP1361172B1 (de) Wasserlösliche Verpackung
EP1539606B1 (de) Verbesserungen in behältern oder diese betreffend
EP1387797B1 (de) Wasserlösliche behälter mit einrichtungen zur freigabe von gas
GB2390840A (en) Water-soluble container with plural compartments

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20010622

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

17Q First examination report despatched

Effective date: 20020311

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20021030

Ref country code: LI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20021030

Ref country code: CH

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20021030

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20021030

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20021030

REF Corresponds to:

Ref document number: 226905

Country of ref document: AT

Date of ref document: 20021115

Kind code of ref document: T

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 60000684

Country of ref document: DE

Date of ref document: 20021205

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030130

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030130

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20030228

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20030228

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20030228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20030331

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2184696

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20030731

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20110228

Year of fee payment: 12

Ref country code: IT

Payment date: 20110224

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20110224

Year of fee payment: 12

BERE Be: lapsed

Owner name: *UNILEVER N.V.

Effective date: 20120228

REG Reference to a national code

Ref country code: NL

Ref legal event code: V1

Effective date: 20120901

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120901

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 17

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20170213

Year of fee payment: 18

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20190219

Year of fee payment: 20

Ref country code: GB

Payment date: 20190218

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20190219

Year of fee payment: 20

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20190801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180301

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 60000684

Country of ref document: DE

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20200228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20200228