EP1126050B1 - Process and apparatus for manufacturing a wire - Google Patents

Process and apparatus for manufacturing a wire Download PDF

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Publication number
EP1126050B1
EP1126050B1 EP01103006A EP01103006A EP1126050B1 EP 1126050 B1 EP1126050 B1 EP 1126050B1 EP 01103006 A EP01103006 A EP 01103006A EP 01103006 A EP01103006 A EP 01103006A EP 1126050 B1 EP1126050 B1 EP 1126050B1
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EP
European Patent Office
Prior art keywords
intermediate product
electrolyte bath
wire
electrolyte
implementing
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EP01103006A
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German (de)
French (fr)
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EP1126050A1 (en
Inventor
Ralph A. Graf
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Graf und Cie AG
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Graf und Cie AG
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F7/00Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01GPRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G15/00Carding machines or accessories; Card clothing; Burr-crushing or removing arrangements associated with carding or other preliminary-treatment machines
    • D01G15/84Card clothing; Manufacture thereof not otherwise provided for
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01GPRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G15/00Carding machines or accessories; Card clothing; Burr-crushing or removing arrangements associated with carding or other preliminary-treatment machines
    • D01G15/84Card clothing; Manufacture thereof not otherwise provided for
    • D01G15/88Card clothing; Manufacture thereof not otherwise provided for formed from metal sheets or strips

Definitions

  • the invention relates to a method for manufacturing a wire, in particular sawtooth wire for sawtooth wire all-steel fittings, where the surface of a wire-shaped Intermediate, such as one already with saw teeth provided wire, in an electrolyte containing Electrolyte bath is smoothed with an electropolishing process and a device suitable for carrying out such methods.
  • sawtooth wire cored wire sets become in the processing of textile fibers into yarns, nonwovens od. Like. Used.
  • the individual sawtooth wires have this the sawtooth wire all-steel sets usually a height of less than 2 mm and in the area of the tooth tips a width of 0.2 mm or less.
  • For the preparation of such fine sawtooth wires is usually a wire-shaped Starting material first one or more drawing operations subjected to, between the individual drawing processes also still different heat treatment procedures performed can be to the already drawn wire its deformability at least partially return.
  • the wire is usually attached to this preparation corresponding punching device provided with saw teeth. there can the saw teeth produced by the punching process before or even hardened after the punching process.
  • electropolishing becomes from the surface of the anodisch switched wire-shaped intermediate, such as the already serrated and / or hardened wire, under the influence of a material-specific selected Electrolytes and an external DC source Material removed.
  • This material is caused by the electrolyte dissolved, the removal without mechanical stress of Workpiece, so the wire-shaped intermediate takes place and to a smoothing or leveling of the workpiece surface leads.
  • the electropolishing process in principle the reversal of the electroplating process Leveling begins in contrast to mechanical removal methods in the micro range and recorded with increasing operating time even larger structures that rounded and on smoothed their surface.
  • the electropolished surface is characterized in the sequence by smoothness and closure in the micro range and one of initial state, Electropolishing and structure of the material dependent Residual ripple in the macro range.
  • a method according to the preamble of patent claim 1 and a device according to the preamble of the claim 10 are known from (US 4,612,084). At the in This method described dives a wire-shaped Intermediate in a received in a tub treatment solution a and partially circulates in the treatment solution submerged roller 2. In execution of the known Procedure must to ensure a sufficiently long Residence time of the intermediate within the treatment solution either a very large bath for the treatment solution be provided or a particularly low conveying speed be set for the intermediate. Furthermore, in US-A-36 76 32 methods for the Treating septa described where the wires are outside a departmentsbeides arranged pulleys circulate.
  • the invention has for its object to provide a method with which these are solved and one suitable for carrying out this method Specify device.
  • the electropolishing process under a particularly efficient continuous process when the intermediate product is conveyed through the electrolyte bath, preferably with a conveying direction of the intermediate product arranged behind the electrolyte bath and on the intermediate product attacking conveyor by the Electrolyte bath is pulled.
  • the inventive Device preferably a conveyor with two mutually parallel roller axes having Conveyor rollers, wherein the wire-shaped intermediate product is trapped between these conveyor rollers and through Rotation of the conveyor rollers is pulled through the electrolyte bath.
  • the residence time of the wire-shaped intermediate in The electrolyte bath may vary depending on the material properties of the intermediate, such as surface finish after leaving the electrolyte bath, set when the conveying speed is dependent on controlled by these material properties.
  • the effectiveness of the invention Electropolishing process also be promoted by that the GleichstrornPark the anodic to that in the Electrolyte bath recorded intermediate coupled DC source depending on the material properties of the Intermediate, such as the surface texture after Leaving the electrolyte bath, is controlled.
  • the electropolishing method according to the invention is customary using sulfuric acid and phosphoric acid (35-45%) carried out, preferably omitting chromic acid becomes.
  • the electrolyte bath can be different Contain additives or brighteners. To ensure a trouble-free further processing of the wire-shaped intermediate product after passing through the electrolyte bath it is important that residues of the electrolyte completely from the wire-shaped intermediate to be removed. This will be the Intermediate product after carrying out the electropolishing process expediently cleaned accordingly, what it preferably passes through another stationary cleaning device.
  • This further stationary cleaning device may have a plurality from in the conveying direction of the intermediate product in a row arranged cleaning stations, such as water baths, so as to allow complete purification of the intermediate to reach and a carryover of electrolyte residues to exclude in other processing stages.
  • the preservation device expediently also goes through so as to be a continuous process receive.
  • the sawtooth wire in carrying out this process continuously from a uncoiler is withdrawn, then first to the Performing a mechanical cleaning designed cleaning device passes through, then the electrolyte bath passes through, wherein it is substantially helical in the electrolyte bath revolves so as to achieve a long residence time, after leaving the electrolyte bath another cleaning device goes through to remove electrolyte residues, then a preserving device passes through to subsequently presented to a take-up reel and wound up on it be, with the necessary conveyor appropriately between the preservation device and the Take-up reel is arranged and has two conveyor rollers, between which the intermediate product is trapped.
  • FIGS Drawing shows a schematic representation of a For carrying out the method of the invention serving inventive Contraption.
  • the device shown in the drawing consists in essentially from a decoiler 10, on which a wire-shaped Intermediate in the form of one already with saw teeth provided with wire, one to carry out designed a mechanical purification of this intermediate Cleaning device 20, an electrolyte bath 30, a for rinsing the electrolyte bath leaving intermediate designed further cleaning device 40, a preserving device 50, a conveyor 60 and a take-up reel 70.
  • the conveyor 60 includes two parallel to each other running roller axes having conveying rollers 62 and 64, between which the intermediate product is trapped. Go berserk the conveyor rollers 62 and 64 in the in the drawing the arrows P indicated directions, the sawtooth wire. 5 in the direction indicated by the arrow P 'from the unwinding axis 10 deducted. After leaving the uncoiler 10 the sawtooth wire 5 is first with a guide roller 12 a substantially horizontally extending track deflected and then introduced into the cleaning device 20. In this Cleaning device 20 is the sawtooth wire with two cleaning rollers 22 and 24 mechanically cleaned, instead of the cleaning rollers and brushes and / or slurry discs can be used. After leaving the cleaning device 20, the sawtooth wire 5 in the course of by the Conveyor 60 caused promotion in the direction of conveyance behind the cleaning device 20 arranged electrolyte bath 30 introduced.
  • the sawtooth wire rotates 5 are substantially helical two parallel to each other extending roller axes exhibiting and within the electrolyte bath 30 arranged pulleys 33 and 34th
  • the sawtooth wire 5 Anodisch to an externally controllable DC power source (not shown), wherein the direct current intensity in the electrolyte bath depending on the surface properties of the Sawtooth wire is controlled to provide optimal treatment of the sawtooth wire to ensure within the electrolyte bath.
  • the working temperature of the bath is in the electropolishing process about 70 ° C to 580 ° C.
  • electrolyte is a chromic acid-free aqueous solution of sulfuric acid and Phosphoric acid (35-45%), the other additives, in particular Brightener may contain.
  • the volume of the bath is 600 l.
  • the control of the electrolyte bath takes place with a density determination, which expediently with a Density spindle monitored density preferably about 1.78 kg / l with an iron content of 3 g / l already taken into account is.
  • the bath can be supplemented with electrolyte or with the help of water be diluted. In a conventional production process 10 to 20 liters of water per week are added to the electrolyte, where once a week a partial replacement of the bath of 30 up to 40 l.
  • the electrolyte bath also have a different type of deflection.
  • the further cleaning device can also be more or Include less than 4 cleaning baths.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Preliminary Treatment Of Fibers (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Paper (AREA)

Description

Die Erfindung betrifft ein Verfahren zum Herstellen eines Drahtes, insbesondere Sägezahndrahtes für Sägezahndraht-Ganzstahlgarnituren, bei dem die Oberfläche eines drahtförmigen Zwischenproduktes, wie etwa eines bereits mit Sägezähnen versehenen Drahtes, in einem einen Elektrolyten enthaltenden Elektrolytbad mit einem Elektropoliervorgang geglättet wird sowie eine zur Ausführung derartiger Verfahren geeignete Vorrichtung.The invention relates to a method for manufacturing a wire, in particular sawtooth wire for sawtooth wire all-steel fittings, where the surface of a wire-shaped Intermediate, such as one already with saw teeth provided wire, in an electrolyte containing Electrolyte bath is smoothed with an electropolishing process and a device suitable for carrying out such methods.

Sägezahndraht-Ganzstahlgarnituren werden beispielsweise bei der Verarbeitung von Textilfasern zu Garnen, Vliesstoffen od. dgl. eingesetzt. Dabei besitzen die einzelnen Sägezahndrähte der Sägezahndraht-Ganzstahlgarnituren üblicherweise eine Höhe von weniger als 2 mm und im Bereich der Zahnspitzen eine Breite von 0,2 mm oder weniger. Zur Herstellung derartig feiner Sägezahndrähte wird üblicherweise ein drahtförmiges Ausgangsmaterial zunächst einem oder mehreren Ziehvorgängen unterzogen, wobei zwischen den einzelnen Ziehvorgängen auch noch unterschiedliche Wärmebehandlungsverfahren durchgeführt werden können, um dem bereits gezogenen Draht seine Verformbarkeit zumindest teilweise wieder zurückzugeben. Im Anschluß an diese Vorbereitung wird-der Draht üblicherweise mit einer entsprechenden Stanzvorrichtung mit Sägezähnen versehen. Dabei können die durch den Stanzvorgang hergestellten Sägezähne vor oder nach dem Stanzvorgang auch noch gehärtet werden. Dabei bleiben auf der Oberfläche der Sägezahndrähte nach dem Stanzvorgang kleine Stanzbrauen zurück. Weiter können sich auf den Oberflächen der Sägezahndrähte auch noch von den vorhergehenden Bearbeitungsschritten verursachte Verunreinigungen befinden, wie etwa Zunder, also Oxidrückstände, oder im Rahmen der thermischen Behandlung entstandene Schmutzrückstände.For example, sawtooth wire cored wire sets become in the processing of textile fibers into yarns, nonwovens od. Like. Used. The individual sawtooth wires have this the sawtooth wire all-steel sets usually a height of less than 2 mm and in the area of the tooth tips a width of 0.2 mm or less. For the preparation of such fine sawtooth wires is usually a wire-shaped Starting material first one or more drawing operations subjected to, between the individual drawing processes also still different heat treatment procedures performed can be to the already drawn wire its deformability at least partially return. In connection The wire is usually attached to this preparation corresponding punching device provided with saw teeth. there can the saw teeth produced by the punching process before or even hardened after the punching process. there remain on the surface of the sawtooth wires after punching small punch brow back. Next can be on the Surfaces of sawtooth wires also from the previous ones Processing steps caused contamination, such as scale, so oxide residues, or in the context of Thermal treatment resulting dirt residue.

Diese Rückstände auf den Sägezahndrähten sind bei einer späteren Benutzung der Sägezahndrähte zur Bearbeitung von Textilfasern, insbesondere beim Einsatz von Hochleistungsmaschinen störend, weil einzelne Fasern an den Garniturzähnen haften bleiben können und die Garnitur deswegen eine erhöhte Neigung zum Füllen mit Fasern und Verunreinigungen, wie z.B. Schalenteilen od. dgl. aufweist. Zur Vermeidung dieser Nachteile werden zur Herstellung von Sägezahndraht-Ganzstahlgarnituren gedachte Sägezahndrähte üblicherweise nach dem Stanz- oder Härtevorgang auch noch gereinigt und poliert. Dazu wird in der Regel eine Elektrolytpolieranlage eingesetzt. Bei dem mit einer derartigen Elektrolytpolieranlage durchgeführten Elektropolierverfahren wird von der Oberfläche des anodisch geschalteten drahtförmigen Zwischenproduktes, wie etwa des bereits mit Sägezähnen versehenen und/oder gehärteten Drahtes, unter Einwirkung eines üblicherweise werkstoffspezifisch ausgewählten Elektrolyten und einer äußeren Gleichstromquelle Werkstoff abgetragen. Dieser Werkstoff wird durch den Elektrolyt aufgelöst, wobei der Abtrag ohne mechanische Belastung des Werkstückes, also des drahtförmigen Zwischenproduktes erfolgt und zu einer Glättung bzw. Einebnung der Werkstückoberfläche führt. Demnach stellt das Elektropolierverfahren im Prinzip die Umkehrung des Galvanisierungsprozesses dar. Die so erreichte Einebnung beginnt im Gegensatz zu mechanischen Abtragungsverfahren im Mikrobereich und erfaßt mit zunehmender Betriebsdauer auch größere Strukturen, die verrundet und an ihrer Oberfläche geglättet werden. Die elektropolierte Oberfläche ist in der Folge charakterisiert durch Glätte und Geschlossenheit im Mikrobereich und einer von Ausgangszustand, Elektropolierdauer und Struktur des Werkstoffes abhängigen Restwelligkeit im Makrobereich.These residues on the sawtooth wires are at a later use of the sawtooth wires for processing textile fibers, especially when using high-performance machines annoying, because individual fibers adhere to the clothing teeth can stay and the set therefore an increased inclination for filling with fibers and contaminants, e.g. trash od. Like. Has. To avoid these disadvantages intended for the production of sawtooth wire all steel sets Sawtooth wires usually after the punching or hardening process also cleaned and polished. This is in the Usually a Elektrolytpolieranlage used. At the with Such an electrolytic polishing performed electropolishing becomes from the surface of the anodisch switched wire-shaped intermediate, such as the already serrated and / or hardened wire, under the influence of a material-specific selected Electrolytes and an external DC source Material removed. This material is caused by the electrolyte dissolved, the removal without mechanical stress of Workpiece, so the wire-shaped intermediate takes place and to a smoothing or leveling of the workpiece surface leads. Accordingly, the electropolishing process in principle the reversal of the electroplating process Leveling begins in contrast to mechanical removal methods in the micro range and recorded with increasing operating time even larger structures that rounded and on smoothed their surface. The electropolished surface is characterized in the sequence by smoothness and closure in the micro range and one of initial state, Electropolishing and structure of the material dependent Residual ripple in the macro range.

Bei der Herstellung von Sägezahndrähten für Sägezahndraht-Ganzstahlgarnituren werden zur Ausführung eines derartigen Elektropolierverfahrens drahtförmige Zwischenprodukte in mehreren Lagen auf einen Träger gewickelt und für eine vorgegebene Zeit in ein einen geeigneten Elektrolyten enthaltendes Elektrolytbad eingetaucht, in dem dann das Elektropolierverfahren durchgeführt wird.In the production of sawtooth wires for sawtooth wire all steel sets be to execute such Electropolishing wire-shaped intermediates in several layers wrapped on a support and for a given Time in a suitable electrolyte containing Immersed in the electrolyte bath, in which then the electropolishing is carried out.

Es hat sich jedoch gezeigt, daß die mit den herkömmlichen Verfahren erhaltenen Sägezahndrähte eine über ihre Länge variierende Oberflächenbeschaffenheit aufweisen, so daß eine zufriedenstellende Glättung nicht in allen Bereichen der Sägezahndrahtoberflächen erreicht wird. However, it has been found that with the conventional Method obtained sawtooth wires one over their length have varying surface finish, so that a satisfactory smoothing not in all areas of the sawtooth wire surfaces is reached.

Ein Verfahren nach dem Oberbegriff des Patentanspruchs 1 sowie eine Vorrichtung nach dem Oberbegriff des Patentanspruchs 10 sind aus der (US 4,612,084) bekannt. Bei dem in dieser Schrift beschriebenen Verfahren taucht ein drahtförmiges Zwischenprodukt in eine in einer Wanne aufgenommene Behandlungslösung ein und umläuft eine teilweise in die Behandlungslösung eingetauchte Walze 2. Bei Ausführung des bekannten Verfahrens muß zur Sicherstellung einer hinreichend langen Verweilzeit des Zwischenproduktes innerhalb der Behandlungslösung entweder eine besonders große Wanne für die Behandlungslösung bereitgestellt werden oder eine besonders geringe Fördergeschwindigkeit für das Zwischenprodukt eingestellt werden. Ferner sind in der US-A-36 76 32 Verfahren zum Behandeln von Orähten beschrieben, bei denen die Drähte außerhalb eines Behandlungsbeides angeordnete Umlenkrollen umlaufen.A method according to the preamble of patent claim 1 and a device according to the preamble of the claim 10 are known from (US 4,612,084). At the in This method described dives a wire-shaped Intermediate in a received in a tub treatment solution a and partially circulates in the treatment solution submerged roller 2. In execution of the known Procedure must to ensure a sufficiently long Residence time of the intermediate within the treatment solution either a very large bath for the treatment solution be provided or a particularly low conveying speed be set for the intermediate. Furthermore, in US-A-36 76 32 methods for the Treating septa described where the wires are outside a Behandlungsbeides arranged pulleys circulate.

Angesichts dieser Probleme im Stand der Technik liegt der Erfindung die Aufgabe zugrunde, ein Verfahren bereitzustellen, mit dem diese gelöst werden sowie eine zur Ausführung dieses Verfahrens geeignete Vorrichtung anzugeben.Given these problems in the prior art the invention has for its object to provide a method with which these are solved and one suitable for carrying out this method Specify device.

Diese Aufgabe wird durch die im kennzeichnenden Teil des Patentanspruch 1 beschriebene Weiterbildung der bekannten Verfahren bzw. durch die im kennzeichnenden Teil des Patentanspruchs 10 beschriebene Weiterbildung der bekannten Vorrichtungen gelöst. This object is achieved by the in the characterizing part of Claim 1 described refinement of the known method or by the in the characterizing part of the claim 10 described development of the known devices solved.

Dabei kann der Elektropoliervorgang im Rahmen eines besonders effizienten kontinuierlichen Verfahrens durchgeführt werden, wenn das Zwischenprodukt durch das Elektrolytbad gefördert, vorzugsweise mit einer in Förderrichtung des Zwischenproduktes hinter dem Elektrolytbad angeordneten und an dem Zwischenprodukt angreifenden Fördereinrichtung durch das Elektrolytbad gezogen wird. Zu diesem Zweck weist die erfindungsgemäße Vorrichtung vorzugsweise eine Fördereinrichtung mit zwei parallel zueinander verlaufende Rollenachsen aufweisenden Förderrollen auf, wobei das drahtförmige Zwischenprodukt zwischen diese Förderrollen eingeklemmt wird und durch Drehung der Förderrollen durch das Elektrolytbad gezogen wird. In this case, the electropolishing process under a particularly efficient continuous process when the intermediate product is conveyed through the electrolyte bath, preferably with a conveying direction of the intermediate product arranged behind the electrolyte bath and on the intermediate product attacking conveyor by the Electrolyte bath is pulled. For this purpose, the inventive Device preferably a conveyor with two mutually parallel roller axes having Conveyor rollers, wherein the wire-shaped intermediate product is trapped between these conveyor rollers and through Rotation of the conveyor rollers is pulled through the electrolyte bath.

Die Verweilzeit des drahtförmigen Zwischenproduktes in dem Elektrolytbad kann in Abhängigkeit von den Materialeigenschaften des Zwischenproduktes, wie etwa der Oberflächenbeschaffenheit nach Verlassen des Elektrolytbades, eingestellt werden, wenn die Fördergeschwindigkeit in Abhängigkeit von diesen Materialeigenschaften gesteuert wird.The residence time of the wire-shaped intermediate in The electrolyte bath may vary depending on the material properties of the intermediate, such as surface finish after leaving the electrolyte bath, set when the conveying speed is dependent on controlled by these material properties.

Darüber hinaus kann die Wirksamkeit des erfindungsgemäßen Elektropolierverfahrens auch noch dadurch gefördert werden, daß die Gleichstrornstärke der anodisch an das in dem Elektrolytbad aufgenommene Zwischenprodukt gekoppelten Gleichstromquelle in Abhängigkeit von den Materialeigenschaften des Zwischenproduktes, wie etwa der Oberflächenbeschaffenheit nach Verlassen des Elektrolytbades, gesteuert wird.In addition, the effectiveness of the invention Electropolishing process also be promoted by that the Gleichstrornstärke the anodic to that in the Electrolyte bath recorded intermediate coupled DC source depending on the material properties of the Intermediate, such as the surface texture after Leaving the electrolyte bath, is controlled.

Verfahrensmäßig hat es sich als besonders sinnvoll erwiesen, wenn das Zwischenprodukt mit der Fördereinrichtung von einer Abwickelhaspel abgezogen und nach Durchlaufen des Elektrolytbades einer Aufwickelhaspel vorgelegt und darauf aufgewickelt wird. Zur Erhöhung der Wirksamkeit des erfindungsgemäßen Elektropolierverfahrens hat es sich ferner als zweckmäßig erwiesen, wenn das Zwischenprodukt vor Durchführung des Elektropoliervorganges zunächst mechanisch gereinigt wird, wozu es vorzugsweise eine stationäre Reinigungsvorrichtung durchläuft. Diese mechanische Vorreinigung kann mit Hilfe von Bürsten und/oder Schlämmscheiben durchgeführt werden und führt zur Beseitigung grober Unebenheiten, wie Kerben, Kratzer und Riefen oder starker Grate, die mit einem Elektropolierverfahren, welches eine Fein- bzw. Feinstbearbeitung darstellt, nur mit großen Schwierigkeiten beseitigt werden können.Procedurally, it has proven to be particularly useful when the intermediate with the conveyor of withdrawn from a decoiler and after passing through the electrolyte bath presented a take-up reel and wound up on it becomes. To increase the effectiveness of the invention Elektropolierverfahrens it has also been useful proven, if the intermediate product before carrying out the Electropolishing process is first mechanically cleaned, what it preferably a stationary cleaning device passes. This mechanical pre-cleaning can be done with the help of Brushes and / or slurry discs are performed and leads for removing gross imperfections, such as scores, scratches and Ridges or strong burrs, which are treated with an electropolishing process, which represents a fine or Feinstbearbeitung, only can be eliminated with great difficulty.

Das erfindungsgemäße Elektropolierverfahren wird üblicherweise unter Verwendung von Schwefelsäure und Phosphorsäure (35-45 %) durchgeführt, wobei möglichst auf Chromsäure verzichtet wird. Weiterhin kann das Elektrolytbad verschiedene Additive bzw. Glanzmittel enthalten. Zur Sicherstellung einer störungsfreien weiteren Bearbeitung des drahtförmigen Zwischenproduktes nach Durchlaufen des Elektrolytbades ist es wichtig, daß Rückstände des Elektrolyten vollständig von dem drahtförmigen Zwischenprodukt entfernt werden. Dazu wird das Zwischenprodukt nach Durchführung des Elektropolierverfahrens zweckmäßigerweise entsprechend gereinigt, wozu es vorzugsweise eine weitere stationäre Reinigungsvorrichtung durchläuft. Diese weitere stationäre Reinigungsvorrichtung kann eine Mehrzahl von in Förderrichtung des Zwischenproduktes hintereinander angeordneten Reinigungsstationen, wie etwa Wasserbäder, aufweisen, um so eine vollständige Reinigung des Zwischenproduktes zu erreichen und eine Verschleppung von Elektrolytrückständen in andere Bearbeitungsstufen auszuschließen.The electropolishing method according to the invention is customary using sulfuric acid and phosphoric acid (35-45%) carried out, preferably omitting chromic acid becomes. Furthermore, the electrolyte bath can be different Contain additives or brighteners. To ensure a trouble-free further processing of the wire-shaped intermediate product after passing through the electrolyte bath it is important that residues of the electrolyte completely from the wire-shaped intermediate to be removed. This will be the Intermediate product after carrying out the electropolishing process expediently cleaned accordingly, what it preferably passes through another stationary cleaning device. This further stationary cleaning device may have a plurality from in the conveying direction of the intermediate product in a row arranged cleaning stations, such as water baths, so as to allow complete purification of the intermediate to reach and a carryover of electrolyte residues to exclude in other processing stages.

Weiterhin kann daran gedacht werden, daß das Zwischenprodukt nach Durchführung des Elektropoliervorganges und vorzugsweise nach Durchlaufen der weiteren Reinigungsvorrichtung mit einer entsprechenden Konservierungseinrichtung mit einem Rostschutzmittel konserviert wird, wozu das Zwischenprodukt die Konservierungseinrichtung zweckmäßigerweise ebenfalls durchläuft, um so ein kontinuierlich arbeitendes Verfahren zu erhalten.Furthermore, it can be thought that the intermediate after performing the electropolishing process and preferably after passing through the further cleaning device with a corresponding preserving device with a Preserved rust inhibitor, including the intermediate product the preservation device expediently also goes through so as to be a continuous process receive.

Wie der vorstehenden Erläuterung der Erfindung zu entnehmen ist, ist es besonders zweckmäßig, wenn der Sägezahndraht bei Durchführung dieses Verfahrens kontinuierlich von einer Abwickelhaspel abgezogen wird, dann zunächst eine zur Durchführung einer mechanischen Reinigung ausgelegte Reinigungseinrichtung durchläuft, anschließend das Elektrolytbad durchläuft, wobei es in dem Elektrolytbad im wesentlichen wendelförmig umläuft, um so eine große Verweilzeit zu erreichen, nach Verlassen des Elektrolytbades eine weitere Reinigungseinrichtung zum Entfernen von Elektrolytresten durchläuft, dann eine Konservierungseinrichtung durchläuft, um anschließend einer Aufwickelhaspel vorgelegt und darauf aufgewickelt zu werden, wobei die dazu erforderliche Fördereinrichtung zweckmäßigerweise zwischen der Konservierungseinrichtung und der Aufwickelhaspel angeordnet ist und zwei Förderrollen aufweist, zwischen denen das Zwischenprodukt eingeklemmt ist.As can be seen from the above explanation of the invention is, it is particularly useful if the sawtooth wire in carrying out this process continuously from a uncoiler is withdrawn, then first to the Performing a mechanical cleaning designed cleaning device passes through, then the electrolyte bath passes through, wherein it is substantially helical in the electrolyte bath revolves so as to achieve a long residence time, after leaving the electrolyte bath another cleaning device goes through to remove electrolyte residues, then a preserving device passes through to subsequently presented to a take-up reel and wound up on it be, with the necessary conveyor appropriately between the preservation device and the Take-up reel is arranged and has two conveyor rollers, between which the intermediate product is trapped.

Nachstehend wird die-Erfindung unter Bezugnahme auf die Zeichnung, auf die hinsichtlich aller erfindungswesentlichen und in der Beschreibung nicht näher herausgestellten Einzelheiten ausdrücklich verwiesen wird, erläutert. Die einzige Figur der Zeichnung zeigt eine schematische Darstellung einer zur Ausführung des erfindungsgemäßen Verfahrens dienenden erfindungsgemäßen Vorrichtung.Hereinafter, the invention will be described with reference to FIGS Drawing, with respect to all essential to the invention and in the description unspecified details expressly referred to explained. The only figure The drawing shows a schematic representation of a For carrying out the method of the invention serving inventive Contraption.

Die in der Zeichnung dargestellte Vorrichtung besteht im wesentlichen aus einer Abwickelhaspel 10, auf der ein drahtförmiges Zwischenprodukt in Form eines bereits mit Sägezähnen versehenen Drahtes aufgewickelt ist, einer zur Durchführung einer mechanischen Reinigung dieses Zwischenproduktes ausgelegten Reinigungseinrichtung 20, einem Elektrolytbad 30, einer zum Spülen des das Elektrolytbad verlassenden Zwischenproduktes ausgelegten weiteren Reinigungseinrichtung 40, einer Konservierungseinrichtung 50, einer Fördereinrichtung 60 und einer Aufwickelhaspel 70.The device shown in the drawing consists in essentially from a decoiler 10, on which a wire-shaped Intermediate in the form of one already with saw teeth provided with wire, one to carry out designed a mechanical purification of this intermediate Cleaning device 20, an electrolyte bath 30, a for rinsing the electrolyte bath leaving intermediate designed further cleaning device 40, a preserving device 50, a conveyor 60 and a take-up reel 70.

Die Fördereinrichtung 60 umfaßt zwei parallel zueinander verlaufende Rollenachsen aufweisende Förderrollen 62 und 64, zwischen denen das Zwischenprodukt eingeklemmt ist. Durch Drehen der Förderrollen 62 und 64 in den in der Zeichnung durch die Pfeile P angedeuteten Richtungen wird der Sägezahndraht 5 in der durch den Pfeil P' angedeuteten Richtung von der Abwickelhasel 10 abgezogen. Nach Verlassen der Abwickelhaspel 10 wird der Sägezahndraht 5 zunächst mit einer Umlenkrolle 12 auf eine im wesentlichen horizontal verlaufende Bahn umgelenkt und dann in die Reinigungseinrichtung 20 eingeleitet. In dieser Reinigungseinrichtung 20 wird der Sägezahndraht mit zwei Reinigungsrollen 22 und 24 mechanisch gereinigt, wobei anstelle der Reinigungsrollen auch Bürsten und/oder Schlämmscheiben eingesetzt werden können. Nach Verlassen der Reinigungseinrichtung 20 wird der Sägezahndraht 5 im Verlauf der durch die Fördereinrichtung 60 bewirkten Förderung in das in Förderrichtung hinter der Reinigungseinrichtung 20 angeordnete Elektrolytbad 30 eingeführt.The conveyor 60 includes two parallel to each other running roller axes having conveying rollers 62 and 64, between which the intermediate product is trapped. Go berserk the conveyor rollers 62 and 64 in the in the drawing the arrows P indicated directions, the sawtooth wire. 5 in the direction indicated by the arrow P 'from the unwinding axis 10 deducted. After leaving the uncoiler 10 the sawtooth wire 5 is first with a guide roller 12 a substantially horizontally extending track deflected and then introduced into the cleaning device 20. In this Cleaning device 20 is the sawtooth wire with two cleaning rollers 22 and 24 mechanically cleaned, instead of the cleaning rollers and brushes and / or slurry discs can be used. After leaving the cleaning device 20, the sawtooth wire 5 in the course of by the Conveyor 60 caused promotion in the direction of conveyance behind the cleaning device 20 arranged electrolyte bath 30 introduced.

Innerhalb des Elektrolytbades 30 umläuft der Sägezahndraht 5 im wesentlichen wendelförmig zwei parallel zueinander verlaufende Rollenachsen aufweisende und innerhalb des Elektrolytbades 30 angeordnete Umlenkrollen 33 und 34.Within the electrolyte bath 30, the sawtooth wire rotates 5 are substantially helical two parallel to each other extending roller axes exhibiting and within the electrolyte bath 30 arranged pulleys 33 and 34th

Im Verlauf der durch die Fördereinrichtung 60 bewirkten Förderbewegung verläßt der Sägezahndraht 5 das Elektrolytbad auf einer horizontalen Bahn und wird in die in Förderrichtung hinter dem Elektrolytbad 30 angeordnete weitere Reinigungseinrichtung 40 eingeführt. Diese weitere Reinigungseinrichtung 40 besteht aus 4 in Förderrichtung hintereinander angeordneten Wasserbädern, in denen der Sägezahndraht zur Entfernung von Elektrolytresten gespült wird, wobei die Kontamination der einzelnen Wasserbäder in Förderrichtung abnimmt, so daß mit der weiteren Reinigungseinrichtung 40 eine besonders wirksame Kaskadenreinigung bewirkt wird.In the course of the effected by the conveyor 60 Conveying movement leaves the sawtooth wire 5, the electrolyte bath on a horizontal track and is in the direction of conveyance behind the electrolyte bath 30 arranged further cleaning device 40 introduced. This further cleaning device 40 consists of 4 arranged one behind the other in the conveying direction Water baths in which the sawtooth wire for removal of Electrolyte residues is rinsed, the contamination of the individual water baths decreases in the conveying direction, so that with the further cleaning device 40 is a particularly effective Cascade cleaning is effected.

Nach Verlassen der weiteren Reinigungseinrichtung 40 gelangt der Sägezahndraht 5 im Verlauf der durch die Fördereinrichtung 60 bewirkten Förderbewegung in die Konservierungseinrichtung 50, wo er mit einem Rostschutzmittel konserviert wird. Im Anschluß an diese Konservierungseinrichtung 50 durchläuft der Sägezahndraht die Fördereinrichtung 60 und wird dann auf der Aufwickelhaspel 70 aufgewickelt. After leaving the further cleaning device 40 passes the sawtooth wire 5 in the course of by the conveyor 60 effected conveying movement in the conservation facility 50, where he preserves with a rust preventive becomes. Following this preservation device 50 passes the sawtooth wire the conveyor 60 and then wound on the take-up reel 70.

Innerhalb des Elektrolytbades 30 ist der Sägezahndraht 5 anodisch an eine von außen steuerbare Gleichstromquelle (nicht dargestellt) gekoppelt, wobei die Gleichstromstärke im Elektrolytbad in Abhängigkeit von den Oberflächeneigenschaften des Sägezahndrahtes gesteuert wird, um so eine optimale Behandlung des Sägezahndrahtes innerhalb des Elektrolytbades zu gewährleisten. Die Arbeitstemperatur des Bades beträgt bei dem Elektropoliervorgang etwa 70 °C bis 580 °C. Als Elektrolyt wird eine chromsäurefreie wäßrige Lösung von Schwefelsäure und Phosphorsäure (35-45 %) angesetzt, die weitere Additive, insbesondere Glanzmittel enthalten kann. Das Volumen des Bades beträgt 600 l. Die Kontrolle des Elektrolytbades erfolgt mit einer Dichtebestimmung, wobei die zweckmäßigerweise mit einer Dichtespindel überwachte Dichte vorzugsweise etwa 1,78 kg/l beträgt, wobei ein Eisengehalt von 3 g/l bereits berücksichtigt ist. Zur Steuerung der Eigenschaften des Elektrolytbades kann das Bad mit Elektrolyt ergänzt oder mit Hilfe von Wasser verdünnt werden. Bei einem herkömmlichen Produktionsvorgang werden dem Elektrolyten 10 bis 20 1 Wasser pro Woche zugegeben, wobei einmal pro Woche ein Teilaustausch des Bades von 30 bis 40 l erfolgt.Within the electrolyte bath 30 is the sawtooth wire 5 Anodisch to an externally controllable DC power source (not shown), wherein the direct current intensity in the electrolyte bath depending on the surface properties of the Sawtooth wire is controlled to provide optimal treatment of the sawtooth wire to ensure within the electrolyte bath. The working temperature of the bath is in the electropolishing process about 70 ° C to 580 ° C. As electrolyte is a chromic acid-free aqueous solution of sulfuric acid and Phosphoric acid (35-45%), the other additives, in particular Brightener may contain. The volume of the bath is 600 l. The control of the electrolyte bath takes place with a density determination, which expediently with a Density spindle monitored density preferably about 1.78 kg / l with an iron content of 3 g / l already taken into account is. For controlling the properties of the electrolyte bath The bath can be supplemented with electrolyte or with the help of water be diluted. In a conventional production process 10 to 20 liters of water per week are added to the electrolyte, where once a week a partial replacement of the bath of 30 up to 40 l.

Die Erfindung ist nicht auf die anhand der Zeichnung erläuterte Ausführungsform beschränkt. Vielmehr kann das Elektrolytbad auch eine andersartige Umlenkeinrichtung aufweisen. Ferner kann die weitere Reinigungseinrichtung auch mehr oder weniger als 4 Reinigungsbäder umfassen.The invention is not explained with reference to the drawing Embodiment limited. Rather, the electrolyte bath also have a different type of deflection. Furthermore, the further cleaning device can also be more or Include less than 4 cleaning baths.

Claims (14)

  1. A method for producing a wire, particularly a sawtooth wire for sawtooth all-steel clothings, in which the surface of a wire-shaped intermediate product, such as a wire already provided with saw teeth, is smoothed in an electrolyte bath containing an electrolyte by means of an electropolishing process, wherein the intermediate product is moved in the electrolyte bath during the electropolishing process, characterised in that the intermediate product circulates in a substantially helical shape around a deflecting device arranged within the electrolyte bath and preferably comprising at least one deflecting roller.
  2. A method according to Claim 1, characterised in that the intermediate product is conveyed through the electrolyte bath, is preferably pulled through the electrolyte bath by a conveying device arranged behind the electrolyte bath in the conveying direction of the intermediate product and acting on the intermediate product.
  3. A method according to one of Claims 1 or 2, characterised in that the conveying speed of the intermediate product and thus the dwell time of the intermediate product is controlled preferably in dependence on the material properties of the intermediate product, such as the surface finish after leaving the electrolyte bath.
  4. A method according to one of the preceding claims, characterised in that the intermediate product is coupled anodically in the electrolyte bath to a direct current source, and the strength of the direct current is controlled, preferably in dependence on the material properties of the intermediate product.
  5. A method according to one of Claims 2 to 4, characterised in that the intermediate product is pulled by the conveying device off a take-off reel and after passing through the electrolyte bath is placed on a take-up reel.
  6. A method according to one of the preceding claims, characterised in that prior to the implementing of the electropolishing process the intermediate product is mechanically cleaned, preferably passes through a stationary cleaning device.
  7. A method according to one of the preceding claims, characterised in that after the implementing of the electropolishing process the intermediate product is cleaned, preferably passes through a further stationary cleaning device.
  8. A process according to Claim 7, characterised in that the further cleaning device has a plurality of cleaning stations, such as water baths, arranged one after the other in the conveying direction of the intermediate product.
  9. A method according to one of the preceding claims, characterised in that after the implementing of the electropolishing process the intermediate product is preserved with an anti-rust agent, preferably passes through a preserving device.
  10. An apparatus for implementing a method according to one of the preceding claims, comprising an electrolyte bath serving for the electrolytic smoothing of a wire-shaped intermediate product and containing an electrolyte, and a conveying device (60) designed for conveying the intermediate product through the electrolyte bath, characterised by a deflecting device arranged in the electrolyte bath (30), around which the intermediate product (5) circulates in a substantially helical shape, and comprising at least one deflecting roller (32, 34).
  11. An apparatus according to Claim 10, characterised in that the conveying device (60) is arranged behind the electrolyte bath (30) in the conveying direction, and pulls the intermediate product (5) through the electrolyte bath (30).
  12. An apparatus according to one of Claims 10 or 11, characterised by a cleaning device (20) for cleaning the intermediate product (5) prior to the implementing of the electrolytic smoothing.
  13. An apparatus according to one of Claims 10 to 12, characterised by a further cleaning device (40) for cleaning the intermediate product (5) after the implementing of the electrolytic smoothing.
  14. An apparatus according to one of Claims 10 to 13, characterised by a device for preserving the electrolytically smoothed intermediate product with an anti-rust agent.
EP01103006A 2000-02-18 2001-02-08 Process and apparatus for manufacturing a wire Expired - Lifetime EP1126050B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10007567 2000-02-18
DE10007567A DE10007567C2 (en) 2000-02-18 2000-02-18 Method and device for producing a wire

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EP1126050A1 EP1126050A1 (en) 2001-08-22
EP1126050B1 true EP1126050B1 (en) 2005-09-07

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US (1) US6544402B2 (en)
EP (1) EP1126050B1 (en)
JP (1) JP2001248000A (en)
AR (1) AR027915A1 (en)
AT (1) ATE304068T1 (en)
AU (1) AU761171B2 (en)
BR (1) BR0100605A (en)
CA (1) CA2332689A1 (en)
DE (2) DE10007567C2 (en)
ES (1) ES2246261T3 (en)
TW (1) TW593793B (en)

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JP2004307917A (en) * 2003-04-04 2004-11-04 Fuji Photo Film Co Ltd Method and apparatus for controlling concentration of electrolytic treatment liquid
WO2005005693A1 (en) * 2003-07-01 2005-01-20 Superpower, Inc. Process control methods of electropolishing for metal substrate preparation in producing ybco coated conductors
EP1850993B1 (en) * 2005-02-24 2010-12-15 Michael Balint Method for the production of a saw band
CN104032366B (en) * 2013-03-07 2017-06-30 苏州新材料研究所有限公司 Electrochemical polish apparatus and method
EP3597802B1 (en) 2014-05-09 2023-12-20 Groz-Beckert KG Card clothing formed from metal strips and its manufacturing process
CN106929904B (en) * 2017-04-01 2019-03-29 苍南德中纺织机械有限公司 Metallic card clothing linear material continuous electroplating system
CN107267966A (en) * 2017-06-29 2017-10-20 芜湖海成科技有限公司 A kind of continuous chrome-plated process of pin cloth

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JPS5145540B1 (en) * 1967-10-03 1976-12-04
US3676322A (en) * 1970-01-06 1972-07-11 Furukawa Electric Co Ltd Apparatus and method for continuous production of electrolytically treated wires
US3740324A (en) * 1971-01-29 1973-06-19 Hughes Aircraft Co Magnetic wire electropolishing process improvement
JPS4879734A (en) * 1972-01-28 1973-10-25
US3816273A (en) * 1972-12-22 1974-06-11 Gen Dynamics Corp Method of chemically forming wire
JPS56112497A (en) * 1980-02-12 1981-09-04 Dainichi Nippon Cables Ltd Method and apparatus for production of electrodeposited wire
DE3332804C2 (en) * 1983-09-12 1986-10-23 Hollingsworth Gmbh, 7265 Neubulach Process for treating the edges of a sawtooth wire for clothing in textile machines
US4935112A (en) * 1988-04-07 1990-06-19 Seneca Wire And Manufacturing Company Continuous steel strand electrolytic processing
US5176803A (en) * 1992-03-04 1993-01-05 General Electric Company Method for making smooth substrate mandrels
JP3922728B2 (en) * 1993-02-01 2007-05-30 住友電気工業株式会社 Metal-coated superconducting wire manufacturing method and electropolishing apparatus

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CA2332689A1 (en) 2001-08-18
US20010015323A1 (en) 2001-08-23
AR027915A1 (en) 2003-04-16
ES2246261T3 (en) 2006-02-16
US6544402B2 (en) 2003-04-08
AU761171B2 (en) 2003-05-29
TW593793B (en) 2004-06-21
BR0100605A (en) 2001-10-09
AU1835001A (en) 2001-08-23
EP1126050A1 (en) 2001-08-22
DE10007567C2 (en) 2003-08-07
ATE304068T1 (en) 2005-09-15
DE50107322D1 (en) 2005-10-13
DE10007567A1 (en) 2001-08-30
JP2001248000A (en) 2001-09-14

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