EP1121203B1 - Low capacity pump with enhanced compatibility - Google Patents
Low capacity pump with enhanced compatibility Download PDFInfo
- Publication number
- EP1121203B1 EP1121203B1 EP99947587A EP99947587A EP1121203B1 EP 1121203 B1 EP1121203 B1 EP 1121203B1 EP 99947587 A EP99947587 A EP 99947587A EP 99947587 A EP99947587 A EP 99947587A EP 1121203 B1 EP1121203 B1 EP 1121203B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pump
- tube
- spray tube
- spring
- shoulder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920003023 plastic Polymers 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 239000007921 spray Substances 0.000 claims abstract 7
- 239000012263 liquid product Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 230000000284 resting effect Effects 0.000 claims 2
- 239000000047 product Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/0005—Components or details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1042—Components or details
- B05B11/1073—Springs
- B05B11/1074—Springs located outside pump chambers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1001—Piston pumps
- B05B11/1023—Piston pumps having an outlet valve opened by deformation or displacement of the piston relative to its actuating stem
Definitions
- the face of the shoulder located on the side of the outer end of the nozzle tube is beveled.
- said shoulder is formed all around the tube.
Landscapes
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Reciprocating Pumps (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Closures For Containers (AREA)
- Lubrication Of Internal Combustion Engines (AREA)
Abstract
Description
La présente invention concerne une pompe et plus particulièrement une pompe de faible capacité pour la distribution de produits liquides tels que des parfums et des produits cosmétiques ou pharmaceutiques.The present invention relates to a pump and more particularly to a low capacity pump for dispensing liquid products such as perfumes and cosmetic or pharmaceutical products.
Les pompes traditionnelles comprennent généralement un corps en matière plastique délimitant une chambre de dosage pourvue à une première extrémité d'un clapet d'admission en produit liquide alimenté à partir d'un réservoir et à une seconde extrémité d'un clapet d'échappement porté par la partie interne d'un tube gicleur mobile axialement en coopérant avec un ressort hélicoïdal.The conventional pumps generally comprise a plastic body delimiting a metering chamber provided at one end with a liquid product inlet valve fed from a reservoir and at a second end of an exhaust valve worn. by the inner part of an axially movable nozzle tube cooperating with a helical spring.
Le document
Cependant, dans de telles pompes le clapet d'admission comporte une bille, réalisée avec des matériaux métalliques, qui est logée à l'intérieur du corps de pompe dans la chambre de dosage tout comme les moyens de rappel constitués généralement d'un ressort lui aussi métalliqueHowever, in such pumps the intake valve comprises a ball, made of metal materials, which is housed inside the pump body in the metering chamber as the return means generally consist of a spring him also metallic
Par conséquent, le produit qui séjourne même pendant une courte période dans la chambre de dosage est mis en contact avec des éléments métalliques, ce qui présente des risques de modification des propriétés et notamment de la qualité du produit.Consequently, the product that stays for a short time in the metering chamber is brought into contact with metal elements, which presents risks of modifying the properties and in particular the quality of the product.
Par ailleurs, le corps de pompe est réalisé avec une matière plastique opaque pour masquer les éléments métalliques internes. Or le réservoir est le plus souvent constitué d'un flacon en verre ou en matière plastique transparente qui laisse apparaître le corps de la pompe, ce qui n'est pas satisfaisant sur le plan esthétique.In addition, the pump body is made of an opaque plastic material to mask the internal metal elements. Or the tank is usually made of a glass bottle or transparent plastic material which reveals the body of the pump, which is not satisfactory in terms of aesthetics.
Par ailleurs, il existe aussi des pompes dans lesquelles les moyens de rappel sont constitués d'un ressort hélicoïdal disposé à l'extérieur de la chambre de dosage.Furthermore, there are also pumps in which the return means consist of a coil spring disposed outside the metering chamber.
Toutefois, dans ce mode de réalisation, le ressort de rappel est maintenu en légère compression autour de la partie externe du tube gicleur notamment par appui de son extrémité supérieure dans le fond d'une cavité ménagée sur une tête de distribution coiffant l'extrémité dudit tube.However, in this embodiment, the return spring is held in slight compression around the outer portion of the nozzle tube in particular by pressing its upper end into the bottom of a cavity formed on a dispensing head capping the end of said tube.
Par conséquent, un tel mode de réalisation ne permet pas de séparer la pompe de la tête de distribution en toute sécurité car, dans ce cas, le ressort ne serait plus solidaire d'aucune pièce et serait alors susceptible d'être perdu notamment lors des opérations de stockage ou de transfert automatique.Therefore, such an embodiment does not allow to separate the pump from the dispensing head safely because, in this In this case, the spring would no longer be integral with any part and would then be likely to be lost, in particular during storage or automatic transfer operations.
En outre, les opérations d'assemblage sont complexes car elles impliquent le montage préalable du ressort.In addition, the assembly operations are complex because they involve the prior assembly of the spring.
La présente invention a pour but de résoudre ces problèmes techniques de manière satisfaisante.The present invention aims to solve these technical problems satisfactorily.
Ce but est atteint conformément à l'invention au moyen d'une pompe selon la revendication 1.This object is achieved according to the invention by means of a pump according to
Selon encore une autre caractéristique, le corps de pompe est réalisé en polypropylène.According to yet another characteristic, the pump body is made of polypropylene.
Selon une variante particulière, la face de l'épaulement en contact avec la première extrémité du ressort est plane et perpendiculaire à l'axe du tube gicleur.According to a particular variant, the face of the shoulder in contact with the first end of the spring is flat and perpendicular to the axis of the nozzle tube.
Selon une autre variante, la face de l'épaulement située du côté de l'extrémité externe du tube gicleur est biseautée.According to another variant, the face of the shoulder located on the side of the outer end of the nozzle tube is beveled.
De préférence, ledit épaulement est réalisé sur tout le pourtour du tube.Preferably, said shoulder is formed all around the tube.
La pompe de l'invention permet un transfert du produit sans contact avec un quelconque élément métallique, ce qui préserve les qualités du produit et simplifie les opérations de fabrication et de montage tout en offrant un prix de revient économique.The pump of the invention allows a transfer of the product without contact with any metal element, which preserves the qualities of the product and simplifies the manufacturing and assembly operations while offering an economic cost.
Par ailleurs, tous les constituants de la pompe qui sont disposés à l'intérieur du réservoir sont réalisés avec une matière translucide ou transparente à la lumière, ce qui améliore considérablement l'aspect esthétique d'ensemble dans la mesure où la pompe n'apparaît pratiquement plus au sein du produit liquide.Furthermore, all the constituents of the pump which are arranged inside the tank are made with a translucent or light-transparent material, which considerably improves the overall aesthetic appearance insofar as the pump does not appear. practically more within the liquid product.
L'invention sera mieux comprise à la lecture de la description qui va suivre en référence au dessin sur lequel :
- la figure 1 unique représente une vue en coupe d'un mode de réalisation de la pompe de l'invention.
- Figure 1 is a single sectional view of an embodiment of the pump of the invention.
La pompe représentée sur la figure 1 comprend un corps 1 réalisé avec une matière plastique transparente ou au moins translucide, par exemple du polypropylène.The pump shown in Figure 1 comprises a
Le corps 1 délimite une chambre de dosage 10 pourvue à une première extrémité d'un clapet d'admission 11 en produit liquide alimenté via un tube plongeur 6 lui aussi translucide à partir d'un réservoir ou d'un flacon (non représenté).The
Selon l'invention, le clapet d'admission 11 comporte une bille 5 non métallique, réalisée avec un matériau transparent à la lumière ou au moins translucide tel que du verre ou du propylène.According to the invention, the
La chambre 10 est pourvue à une seconde extrémité, opposée à la première extrémité, d'un clapet d'échappement 12 porté par la partie interne 2a d'un tube gicleur 2 délimitant un conduit d'éjection axial 20.The
Le tube gicleur 2 est mobile axialement en coopérant avec un ressort hélicoïdal 3 assurant le rappel en position de fermeture du clapet 12. Le ressort 3 est monté coaxialement autour de la partie externe du tube 2.The
La partie externe du tube 2 est pourvue d'un épaulement latéral 21 contre lequel une première extrémité 31 du ressort 3 est en appui de calage. Le ressort 3 est maintenu en légère compression même dans la position de fermeture du clapet d'échappement 12.The outer portion of the
L'épaulement 21 est ici réalisé sur tout le pourtour du tube 2 et comporte une face plane 21a de contact avec la spire de l'extrémité 31 du ressort 3. La face 21 a est, en outre ici, perpendiculaire à l'axe X du tube 2 et de la pompe. La face 21 b de l'épaulement située du côté de l'extrémité externe 2b du tube 2 est biseautée et forme éventuellement une butée pour le montage d'une tête de distribution ou d'un bouton-poussoir (non représenté) destiné à coiffer le tube 2.The
De préférence, la tête de distribution comportera alors soit un alésage cylindrique permettant l'emmanchement en butée sur l'extrémité 2b du tube soit une cavité à profil tronconique destinée à recevoir l'épaulement 21 par assemblage cône sur cône.Preferably, the dispensing head will then have either a cylindrical bore allowing the fitting abutting on the
La pompe comporte également une douille interne 4 emmanchée dans le corps 1 pour obturer la chambre 10 autour de la partie interne du tube gicleur 2.The pump also comprises an inner sleeve 4 fitted into the
La douille 4 est pourvue d'une collerette 41 de support sur le bord externe du corps 1 qui se prolonge à l'intérieur de la chambre 10 par une jupe 42. Dans le mode de réalisation représenté, la jupe 42 est fixée par encliquetage dans la paroi latérale interne de la chambre 10.The sleeve 4 is provided with a
L'extrémité interne de la jupe 42 forme une butée haute pour le clapet d'échappement 12 porté par la partie interne du tube 2. Cette butée correspond à la position de fermeture du clapet 12. Le fond 4a de la douille 4 est destiné à recevoir l'appui de la seconde extrémité 32 du ressort 3.The inner end of the
Claims (5)
- A pump of the type comprising a casing (1) made of a plastic material, defining a dosing chamber (10), the first end of which is provided with a ball (5) check valve (11) for the admission of a liquid product from a container, and a second end of which is provided with a delivery check valve (12) supported by the inner part of an axially mobile spray tube (2) by cooperating with a coil spring (3) coaxially mounted about the outer part of said tube (2), provided with a side shoulder (21) against which a first end (31) of said spring (3) is resting and locked,
characterized in that the casing (1) is made of a transparent or at least a translucent plastic material, whereas the ball is made of glass or polypropylene, and
in that it includes, in addition, an inner socket (4) inserted into said casing (1) in oder to close said chamber (10) about the inner part of the spray tube (2) and the bottom (4a) of which is intended for receiving the resting second end (32) of the spring (3) and which extends inside the chamber (10) by a skirt (42) snapped into the inner side wall of said chamber and the lower end of which forms an upper stop for the delivery check valve (12) supported by the inner part of said tube (2). - A pump according to claim 1, characterized in that the pump casing (1) is made of polypropylene.
- A pump according to one of the preceding claims, characterized in that the face (21b) of the shoulder (21) in contact with the first end (31) of the spring (3) is flat and perpendicular to the axis (X) of the spray tube (2).
- A pump according to one of the preceding claims, characterized in that the face (21b) of the shoulder (21) located on the outer end (2b) side of the spray tube (2) is bevelled.
- A pump according to one of the preceding claims, characterized in that said shoulder (21) is provided on the whole perimeter of the tube (2).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9813004 | 1998-10-16 | ||
FR9813004A FR2784717B1 (en) | 1998-10-16 | 1998-10-16 | LOW CAPACITY PUMP WITH IMPROVED COMPATIBILITY |
PCT/FR1999/002514 WO2000023199A1 (en) | 1998-10-16 | 1999-10-15 | Low capacity pump with enhanced compatibility |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1121203A1 EP1121203A1 (en) | 2001-08-08 |
EP1121203B1 true EP1121203B1 (en) | 2008-03-05 |
Family
ID=9531661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99947587A Expired - Lifetime EP1121203B1 (en) | 1998-10-16 | 1999-10-15 | Low capacity pump with enhanced compatibility |
Country Status (13)
Country | Link |
---|---|
US (1) | US6415959B1 (en) |
EP (1) | EP1121203B1 (en) |
JP (1) | JP4307736B2 (en) |
CN (1) | CN1104964C (en) |
AT (1) | ATE387964T1 (en) |
AU (1) | AU6098099A (en) |
BR (1) | BR9914769A (en) |
CA (1) | CA2347140A1 (en) |
DE (1) | DE69938311T2 (en) |
ES (1) | ES2303384T3 (en) |
FR (1) | FR2784717B1 (en) |
HK (1) | HK1040210B (en) |
WO (1) | WO2000023199A1 (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6446840B2 (en) | 2000-05-18 | 2002-09-10 | Ophardt Product Kg | Apparatus for making and dispensing foam |
FR2823184B1 (en) * | 2001-04-04 | 2003-08-15 | Valois Sa | FLUID PRODUCT DISPENSING PUMP |
EP1389491A1 (en) * | 2002-08-13 | 2004-02-18 | Yon Woo Corporation | Airless dispenser pump |
US6685062B1 (en) * | 2002-09-16 | 2004-02-03 | Yon Woo Corporation | Dispenser pump |
BRPI0417961A (en) * | 2003-12-22 | 2007-03-27 | Valois Sas | fluid product dispensing element and dispenser, said element comprising |
DE102005014407B4 (en) * | 2005-03-30 | 2007-10-04 | Schwan-Stabilo Cosmetics Gmbh & Co. Kg | applicator |
FR2907320B1 (en) * | 2006-10-23 | 2009-01-30 | Rexam Dispensing Systems Sas | PERFUME BOTTLE |
FR2908843B1 (en) * | 2006-11-16 | 2009-02-27 | Rexam Dispensing Systems Sas | PUMP FOR DISPENSING A FLUID PRODUCT |
US9475607B2 (en) * | 2008-10-01 | 2016-10-25 | Rehrig Pacific Company | Plastic beer keg |
EP2421762B1 (en) | 2009-04-20 | 2016-02-10 | Rehrig Pacific Company | Plastic beer keg |
US8967407B2 (en) * | 2009-07-27 | 2015-03-03 | Rehrig Pacific Company | Plastic beer keg |
US9434505B2 (en) * | 2010-01-26 | 2016-09-06 | Rehrig Pacific Company | Plastic beer keg |
US20110303702A1 (en) * | 2010-06-11 | 2011-12-15 | Derxin (Shanghai) Cosmetics Co., Ltd. | Liquid spray head assembly |
FR2966129B1 (en) * | 2010-10-18 | 2012-10-19 | Rexam Dispensing Sys | METHOD AND FLUID FOR DISPENSING A FLUID PRODUCT |
CA2997773A1 (en) | 2010-11-09 | 2012-05-09 | Rehrig Pacific Company | Beer keg valve assembly |
EP2450290B1 (en) * | 2010-11-09 | 2014-03-19 | Rehrig Pacific Company | Plastic beer keg |
FR2975086B1 (en) * | 2011-05-13 | 2013-06-28 | Valois Sas | FLUID PRODUCT DISPENSER. |
GB2491104A (en) * | 2011-05-18 | 2012-11-28 | Ya-Tsan Wang | A push-type dispenser nozzle with the spring located outside the fluid path |
CN202321216U (en) * | 2011-12-14 | 2012-07-11 | 东莞怡信磁碟有限公司 | Refillable spraying bottle |
US20140252042A1 (en) * | 2013-03-06 | 2014-09-11 | Georgia-Pacific Consumer Products Lp | Fluid dispenser |
CN103230850B (en) * | 2013-05-03 | 2016-12-28 | 余姚晟祺塑业有限公司 | Plastic polymer particle ball pressure type fog-spray nozzle |
MX357969B (en) | 2014-06-23 | 2018-08-01 | Rehrig Pacific Co | Plastic beer keg. |
CN110104316B (en) * | 2019-04-30 | 2021-02-12 | 无锡圣马科技有限公司 | Quantitative manual pressurizing press pump |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3187960A (en) * | 1964-05-08 | 1965-06-08 | Sterling Drug Inc | Non-metallic pump dispenser |
IT8421596V0 (en) * | 1984-04-19 | 1984-04-19 | Sar Spa | HAND PUMP TO DISPENSE MICRONIZED LIQUIDS UNDER PRESSURE. |
US4991747A (en) * | 1988-10-11 | 1991-02-12 | Risdon Corporation | Sealing pump |
IT1228787B (en) * | 1989-03-31 | 1991-07-03 | Lumson Srl | MANUAL PUMP FOR DISPENSING LIQUIDS OR PASTES FROM BOTTLES. |
US4984702A (en) * | 1990-03-30 | 1991-01-15 | Specialty Packaging Licensing Company, Inc. | Assembly for securing and sealing a dispenser to a flanged container |
US5385302A (en) * | 1990-10-25 | 1995-01-31 | Contico | Low cost trigger sprayer |
US5251792A (en) * | 1992-09-28 | 1993-10-12 | Sheen Chung Shan | Spray bottle with controllable spray volume |
US5388766A (en) * | 1993-09-22 | 1995-02-14 | The Procter & Gamble Company | High pressure atomization systems for high viscosity products |
FR2719242B1 (en) * | 1994-04-27 | 1996-07-12 | Valois Sa | Advanced precompression pump. |
EP0691161B1 (en) * | 1994-07-07 | 1999-09-29 | SAR S.p.A. | A device for dispensing pastes or liquids from bottles or the like |
US5503306A (en) * | 1994-10-19 | 1996-04-02 | Aptar Group, Inc. | Manually actuated pump |
US5505343A (en) * | 1994-10-19 | 1996-04-09 | Knickerbocker; Michael G. | Manually actuated pump |
FR2735188B1 (en) * | 1995-06-08 | 1997-07-11 | Oreal | PUMP DEVICE FOR COLLECTING A LIQUID FROM A CONTAINER AND DISPENSING IT IN A SPRAY FORM |
US6050457A (en) * | 1995-12-06 | 2000-04-18 | The Procter & Gamble Company | High pressure manually-actuated spray pump |
US5697530A (en) * | 1996-01-29 | 1997-12-16 | Monturas, S.A. | Precompression pump sprayer |
DE29622929U1 (en) * | 1996-06-24 | 1997-10-23 | Industrieplanung Theodor Fessel GmbH, 91522 Ansbach | Dispenser |
DE19642976A1 (en) * | 1996-10-18 | 1998-04-23 | Pfeiffer Erich Gmbh & Co Kg | Discharge device for media |
JP3628827B2 (en) * | 1996-12-24 | 2005-03-16 | 株式会社吉野工業所 | Trigger type liquid jet pump |
FR2764005B1 (en) * | 1997-05-29 | 2004-12-10 | Sofab | ARTICULATED PISTON PUMP |
US6032833A (en) * | 1998-07-24 | 2000-03-07 | Olegnowicz; Israel | Non-throttling valve assembly |
-
1998
- 1998-10-16 FR FR9813004A patent/FR2784717B1/en not_active Expired - Fee Related
-
1999
- 1999-10-15 AT AT99947587T patent/ATE387964T1/en not_active IP Right Cessation
- 1999-10-15 US US09/806,480 patent/US6415959B1/en not_active Expired - Lifetime
- 1999-10-15 ES ES99947587T patent/ES2303384T3/en not_active Expired - Lifetime
- 1999-10-15 CN CN99812205A patent/CN1104964C/en not_active Expired - Fee Related
- 1999-10-15 AU AU60980/99A patent/AU6098099A/en not_active Abandoned
- 1999-10-15 DE DE69938311T patent/DE69938311T2/en not_active Expired - Lifetime
- 1999-10-15 BR BR9914769-6A patent/BR9914769A/en not_active IP Right Cessation
- 1999-10-15 EP EP99947587A patent/EP1121203B1/en not_active Expired - Lifetime
- 1999-10-15 WO PCT/FR1999/002514 patent/WO2000023199A1/en active IP Right Grant
- 1999-10-15 CA CA002347140A patent/CA2347140A1/en not_active Abandoned
- 1999-10-15 JP JP2000576967A patent/JP4307736B2/en not_active Expired - Fee Related
-
2002
- 2002-03-14 HK HK02101969.3A patent/HK1040210B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HK1040210A1 (en) | 2002-05-31 |
DE69938311T2 (en) | 2009-03-19 |
ES2303384T3 (en) | 2008-08-01 |
WO2000023199A1 (en) | 2000-04-27 |
EP1121203A1 (en) | 2001-08-08 |
JP2002527236A (en) | 2002-08-27 |
HK1040210B (en) | 2003-08-22 |
AU6098099A (en) | 2000-05-08 |
CN1323246A (en) | 2001-11-21 |
US6415959B1 (en) | 2002-07-09 |
CN1104964C (en) | 2003-04-09 |
FR2784717B1 (en) | 2001-12-07 |
FR2784717A1 (en) | 2000-04-21 |
CA2347140A1 (en) | 2000-04-27 |
DE69938311D1 (en) | 2008-04-17 |
BR9914769A (en) | 2001-11-13 |
ATE387964T1 (en) | 2008-03-15 |
JP4307736B2 (en) | 2009-08-05 |
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