EP1085126B1 - Bande de transfert pour une bande humide - Google Patents

Bande de transfert pour une bande humide Download PDF

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Publication number
EP1085126B1
EP1085126B1 EP00306094A EP00306094A EP1085126B1 EP 1085126 B1 EP1085126 B1 EP 1085126B1 EP 00306094 A EP00306094 A EP 00306094A EP 00306094 A EP00306094 A EP 00306094A EP 1085126 B1 EP1085126 B1 EP 1085126B1
Authority
EP
European Patent Office
Prior art keywords
wet web
layer
belt
meltable
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00306094A
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German (de)
English (en)
Other versions
EP1085126A1 (fr
Inventor
Shin Kawashima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ichikawa Co Ltd
Original Assignee
Ichikawa Co Ltd
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Filing date
Publication date
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Application filed by Ichikawa Co Ltd filed Critical Ichikawa Co Ltd
Publication of EP1085126A1 publication Critical patent/EP1085126A1/fr
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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • D21F7/086Substantially impermeable for transferring fibrous webs
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/0027Screen-cloths
    • D21F1/0063Perforated sheets
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • D21F7/083Multi-layer felts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S162/00Paper making and fiber liberation
    • Y10S162/901Impermeable belts for extended nip press
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3707Woven fabric including a nonwoven fabric layer other than paper
    • Y10T442/3724Needled
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3707Woven fabric including a nonwoven fabric layer other than paper
    • Y10T442/3724Needled
    • Y10T442/3756Nonwoven fabric layer comprises at least two chemically different fibers

Definitions

  • This invention relates to papermaking, and more particularly to a wet web transfer belt in a papermaking machine, wherein a wet web is transferred in a closed draw.
  • a pickup felt picks up a wet web from a preceding section of the machine, holding the web underneath the bottom surface of the felt and transferring it to a next stage transfer belt.
  • the wet web is then pinched between the pickup felt and a transfer belt at a first nip formed between a pair of press rolls. Water is squeezed out of the wet web at the first nip. The wet web is then released from the pickup felt and transferred to the transfer belt.
  • the transfer belt carries the wet web to a second nip formed between a third press roll and a shoe press, where further water is drained from the web and picked up by a press felt.
  • the wet web remains on the transfer belt until it reaches a vacuum roll, where the web is transferred to a canvas belt for heating and drying.
  • the closed draw papermaking apparatus utilizes a number of transfer points. Therefore, it is important for the wet web to be released easily to avoid maloperation. It is especially important for the wet web to be released easily at the location immediately following the shoe press because, if the transfer belt is smooth, a continuous film of water is likely to be formed between the wet web and the transfer belt. The water film can cause the wet web to adhere so tightly to the transfer belt that it cannot be released, even by the force applied by the vacuum roll.
  • a filler is mixed into a synthetic resin layer formed on the surface of a base layer.
  • the synthetic resin layer is ground after the resin has cured, and the filler forms projections on its surface. These projections impart a roughness to the surface and are very effective in breaking up the water film formed between the web and the transfer belt.
  • a synthetic resin layer 32 is applied to the surface of a base layer 31 by spraying in such a way that numerous air bubbles are formed in the synthetic resin layer.
  • the air bubbles at the surface produce a multitude of concavities. These concavities impart a roughness to the surface of the belt which is effective to break the water film between the transfer belt and a wet web carried thereby.
  • the projections and concavities on the surfaces of the belts of the prior art can be formed only by grinding the surface of the synthetic resin layer after it has been cured.
  • the need for curing and grinding results in a high production cost.
  • the projections are likely to impart markings to the wet web.
  • the prior art belts which are composed of a base layer and a synthetic resin layer, tend to be heavy and difficult to install in a papermaking machine, depending on the structure and surroundings of the machine.
  • DE-U-29706427 discloses a belt for a papermaking machine which has an impermeable surface layer formed by melting fibers of a compressible fiber structure of the belt, so that the surface layer is an integral part of the belt and thus durably connected to the fiber structure.
  • US-A-5549967 discloses a press fabric for a papermaking machine which comprises a base fabric and a plurality of batt layers. At least one of the base fabric and the plurality of batt layers incorporates yarn or fibers of a bi-component material having a core material with a higher melting point surrounded by a covering material with a lower melting point.
  • the base fabric and batt layers are needled or bonded together and subjected to a heat setting operation in which the lower melting point cover material is softened and flows into the crossings of the batt fibers of the batt material or the weave pattern in the base fabric to stabilise the press fabric and provide greater wear resistance and compaction resistance.
  • DE-C-19803493 discloses a papermaking felt which is formed from a fiber material, a base fabric and at least one layer of non-woven material fixed thereto.
  • the fiber material of the at least one layer of non-woven material comprises a proportion of bi-component fibers which are of the side-by-side kind, so that each component forms part of the outer surface of the bi-component fibers.
  • the invention achieves the aforementioned objects in a wet web transfer belt for a papermaking machine which belt comprises a base layer and a batt layer, the batt layer having a side on which a wet web is placed, and at least a surface layer of said side of the batt layer being formed of fiber comprising a welded layer of meltable fiber, characterized in that the welded layer partly retains a fibrous configuration, forming on the surface of the welded layer projections and concavities capable of flattening when a nip pressure is applied to the belt.
  • the fiber forming the surface of the batt layer can consist substantially entirely of a meltable fiber, in which case the desired surface roughness can be obtained with a reliable quality by regulating the heat in welding the meltable fibers.
  • the fiber forming the surface of the batt layer surface can comprise a mixture of a meltable fiber and a non-meltable (universal) fiber. In the latter case, the desired surface roughness can be achieved by regulating the heat in welding, or by regulating the relative proportions of meltable fiber and non-meltable fibers in the surface of the batt layer.
  • meltable fiber is meltable at a temperature in the range from 120°C to 180°C, and the meltable fiber of the welded layer partly retains a fibrous configuration.
  • the welded layer in order to prevent rewetting by keeping water from migrating deep into the belt, has an air permeability of 2 cc/cm 2 /sec. or less.
  • the preferred surface roughness of the welded layer is in the range of Rz5-80 ⁇ m in order that the water film formed between the wet web and the belt can be broken easily and the wet web can be released easily from the belt after it emerges from the nip press.
  • FIG. 9(a) shows the main part of a closed draw papermaking machine.
  • a pickup felt 10 picks up a wet web P from a preceding section of the machine, for example the wire section (not shown), holding the web underneath the bottom surface of the felt and transferring it to a next stage transfer belt 11.
  • the pickup felt therefore functions as a support for the wet web P.
  • the wet web P is pinched between the pickup felt 10 and the transfer belt 11 at a first nip N1 formed between first and second press rolls 12 and 13. Pressure is applied to the wet web at the nip N1, squeezing water out of the wet web. After passing through the first nip N1, the wet web P is released from the pickup felt 10 and transferred to the web transfer belt 11.
  • the pressure applied to the wet web P at nip N2 further drains water from the web.
  • the water squeezed out of the wet web at nip N2 moves to a press felt 17.
  • the wet web When pressure is released from the wet web P after it passes through nip N2, the wet web remains on transfer belt 11 until it reaches vacuum roll 18'. At the vacuum roll, the web is transferred, by a vacuum applied inside the vacuum roll, to a canvas belt 18, which passes around the vacuum roll. While on the canvas belt, the web is heated and dried by a heating cylinder 19.
  • the transfer belt 11 is smooth, a continuous film of water is likely to be formed between the wet web P and the transfer belt.
  • the water film can cause the wet web P to adhere so tightly to the belt 11 that it cannot be released from belt 11, even by the force applied by the vacuum roll 18'.
  • a belt disclosed in Japanese published application 57678/1994 is depicted in FIG. 9(b) as belt 20.
  • a filler 23 is mixed into a synthetic resin layer 22 formed on the surface of a base layer 21.
  • the filler has a hardness greater than that of the synthetic resin.
  • the filler forms projections on the surface of the layer 22. These projections impart a roughness to the surface of layer 22 and are very effective in breaking up the water film formed between the web and the transfer belt.
  • a belt disclosed in Japanese published application 88193/1985 is depicted in FIG. 9(c) as belt 30.
  • a synthetic resin layer 32 is applied to the surface of a base layer 31 by spraying in such a way that numerous air bubbles 33 are formed in the synthetic resin layer.
  • the air bubbles at the surface produce a multitude of concavities. These concavities impart a roughness to the surface of the belt which is effective to break the water film between the transfer belt and a wet web carried thereby.
  • the projections and concavities on the surfaces of the belts of the prior art can be formed only by grinding the surface of the synthetic resin layer after it has been cured.
  • the need for curing and grinding results in a high production cost.
  • the projections are likely to impart markings to the wet web.
  • the prior art belts which are composed of a base layer and a synthetic resin layer, tend to be heavy and difficult to install in a papermaking machine, depending on the structure and surroundings of the machine.
  • FIGs. 1-7 Several embodiments of the invention will now be described with reference to FIGs. 1-7.
  • the transfer belt of the invention comprises a base layer 2 and a batt layer 3.
  • the batt layer 3 is intertwined and integrated into the base layer 2 by needle punching.
  • the base layer 2 consists of a ground fabric having a woven structure made up of a warp yarn 2a and a weft yarn 2b. Monofilament single yarns, monofilament twisted yarns, and multifilament yarns may be used as the warp yarns and as the weft yarns.
  • the woven structure can be a single weave, a double weave or a triple weave selected singly or provided in a piled combination.
  • the base layer preferably has a basic weight of 300-800 g/m 2 .
  • the batt layer 3 is composed of two sides: a side 3a on which a wet web is placed and a roll contact side 3b which is contacted by the press roll of a papermaking machine.
  • the total basic weight of the batt layer 3 is 600-1200 g/m 2 .
  • the basic weight and apparent density of a completed belt according to the invention be regulated to 900-2000 g/m 2 and 0.40-0.99 g/cm 3 , respectively.
  • the surface layer A (the cross-hatched part of side 3a, on which the wet web is placed) is formed either substantially entirely of a meltable fiber, or of a mixture of a meltable fiber and a non-meltable fiber.
  • the middle layer B, as well as the roll-contacting side 3b are composed of a non-meltable fiber.
  • meltable fiber refers to a fiber the whole or a part of which is melted at a temperature in the range from 120°C - 180°C.
  • a copolymerized nylon which includes nylon 11, nylon 12, nylon 6 and nylon 66, etc. may be used.
  • non-meltable fiber refers to a fiber which is not meltable in the temperature range in which the meltable fiber is melted.
  • universal fibers and heat-resistant fibers which are generally used in conventional press felts are “non-meltable fibers.” It is preferable that the heat-resistant fibers have a melting point higher than that of universal fibers by 20°C or more.
  • PPS, PEEK, PEK, all aromatic polyesters and aromatic polyamides, etc. which have melting points of 280°C or higher can be employed either alone or in mixtures.
  • the surface layer A on side 3a is made of a mixture of a meltable and a non-meltable fiber
  • the non-meltable fiber remains as a fiber without melting even if heat is such that the meltable fiber melts completely. Therefore in the case of a mixture of meltable and non-meltable fibers, projections and concavities can be formed easily on the side of the belt on which the wet web is placed.
  • the belt can be made flexible and more durable by the use of a mixture of fibers.
  • the entire side 3a illustrated by cross-hatching, including not only the surface layer A but also the middle layer B of the butt layer 3 on which a wet web is placed, is made of a meltable fiber substantially by itself or of a mixture of meltable and non-meltable fibers.
  • the roll contact side 3b is made of non-meltable fibers only.
  • projections and concavities are formed on the surface when the meltable fiber in the surface layer A is welded by heat, forming a welded layer 4.
  • the entire side 3a, on which the wet web is placed, as well as the roll contacting side 3b, are composed of a meltable fiber or a mixture of a meltable and non-meltable fiber.
  • projections and concavities are formed on the surface when the meltable fiber in the surface layer A of side 3a is welded by heat to form a welded layer 4.
  • a welded layer 4' may be formed on the roll contacting side 3b, so that the air permeability of the roll contacting side can also be regulated.
  • meltable fiber and non-meltable fiber are mixed in different proportions in the surface layer A, the middle layer B of side 3a and the layer on the roll contacting side 3b respectively.
  • These three layers are distinguished from one another in the drawing by cross-hatching in different directions.
  • the surface layer A, on which the wet web is placed may be composed of 100% meltable fibers, whereas in the roll contacting side, meltable and non-meltable fibers can be present in a mixture consisting of 50% meltable fibers and 50% non-meltable fibers.
  • meltable fibers and non-meltable fibers can be present in the ratio of 50% each in the surface layer A and the middle layer B, while in the roll-contacting side 3b, the mixture can consist of 80% meltable fibers and 20% non-meltable fibers.
  • meltable fibers If a greater proportion of meltable fiber is present in a mixture of meltable and non-meltable fibers, the belt becomes harder and more durable when the fibers are welded. On the other hand, with a lesser proportion of meltable fiber in the mixture, the belt can be made more flexible after welding, and therefore more easily installed.
  • the proportion of meltable and non-meltable fibers may be determined by taking these factors into account.
  • projections and concavities in the wet web-contacting surface of the belt are formed when the meltable fibers of the web-contacting layer are welded by heat to form a welded layer.
  • the air permeability of the welded layer is preferably regulated so that it is not greater than 2 cc/cm 2 /sec.
  • the surface roughness of the welded layer should be regulated at Rz5-80 ⁇ m.
  • the air permeability was measured by A method (fragile type testing machine) standardized in “JIS L 1096 (Testing Methods for Fabrics)", and surface roughness was measured by a method shown in "JIS B0601-1982".
  • FIGs. 5(a)-5(c) The effect of the belt according to the invention is illustrated in FIGs. 5(a)-5(c).
  • a wet web P is placed on the surface of the side 3a of the belt 1 having surface projections 5 and surface concavities 6, a water film W is formed between the surface of the belt and the wet web P by water drained from the wet web.
  • a base layer 2 (600 g/m 2 ) was formed by piling a second (upper) ground fabric (200 g/m 2 ) 2'' on a first (lower) ground fabric (400 g/m 2 ) 2'.
  • twisted yarns made by twisting three monofilaments of nylon 6 (0.2 mm in diameter), were woven into a single plain weave as warp yarns and weft yarns.
  • the same yarns were woven into an endless 3/1 broken weave.
  • the roll contact side 3b was formed by needle-punching batt fibers (300 g/m 2 ) piled on the first ground fabric 2' of the base layer 2. Then the base layer was turned over, and the side 3a, on which a wet web is placed, was formed by piling and needle-punching the batt fibers of the middle layer B (300 g/m 2 ) and the surface layer A (300 g/m 2 ) on the second ground fabric 2''. As will be described later, the side 3a, on which a wet web is placed, is composed substantially entirely of meltable fibers or of a mixture of meltable fibers and universal or heat-resistant fibers.
  • the side 3a was placed into contact with a press roll heated to 170° C, and heat was conducted deep into the belt. (As an alternative, the side 3a can be heated by blowing hot air onto it.)
  • the meltable fiber was melted and welded by the heat, and became film-like to form a welded layer.
  • the air permeability of the welded layer was regulated to be 2 cc/cm 2 /sec or less.
  • FIGs. 7 and 8 Examples are compared in FIGs. 7 and 8.
  • the table of FIG. 7 illustrates eight examples in which the meltable fiber was mixed at different ratios in the surface layer A, the middle layer B of the web-contacting side 3a of the batt layer, and in the roll-contacting side 3b respectively. In these eight examples, the density, air permeability and surface roughness were regulated as shown in the table.
  • the table of FIG. 8 illustrates comparative examples.
  • One comparative example, example 9, is a belt in which meltable fiber was not used in the web-contacting side.
  • Comparative examples 10 and 11 are belts in which the air permeability was greater than 2 cc/cm 2 /sec.
  • Comparative example 12 is a conventional belt of a closed-draw papermaking machine.
  • the tables compare the performance of the belt in three aspects: weight (which affects ease of installation); rewetting; and ease of release.
  • weight which affects ease of installation
  • rewetting and ease of release.
  • the symbol ⁇ indicates poor performance, ⁇ indicates fair performance, ⁇ indicates good performance and o ⁇ indicates excellent performance.
  • examples 1 and 2 wherein the surface of the web-contacting side 3a was composed of 100% meltable fibers, are evaluated as ⁇ (fair) in weight, which is worse than examples 3-8 and the comparative examples 9-11, but not as bad as the conventional belt of example 12, which is evaluated as ⁇ (poor).
  • Examples 1-3 are evaluated as o ⁇ (excellent) with respect to rewetting prevention, which is better than examples 4-8. Insofar as rewetting prevention is concerned, the comparative belts of examples 9-11 were evaluated as ⁇ (poor), but the conventional belt performed excellently (o ⁇ ).
  • examples 4-8 and the comparative belts 9-11 exhibited excellent performance (o ⁇ ).
  • examples 1-8 have no poor ( ⁇ ) evaluations insofar as weight, rewetting and releasability are concerned.
  • each of the comparative belts has a poor ( ⁇ ) evaluation in one of the three categories.
  • belts of examples 1-8 are superior to the others as a whole.
  • the wet web transfer belt of the invention in which at least a surface of the side of the batt layer on which a wet web is placed is formed by a meltable fiber, produces an excellent effect in that a rough surface can be formed on the belt with reliable quality by regulating heat applied in welding the meltable fiber or by regulating the proportion of meltable and non-meltable fibers.
  • the belt can be made light in weight, and is superior in that it allows a wet web to be released easily in a closed-draw papermaking machine.
  • the belt can be formed so that it water squeezed out of the wet web can be kept from moving deep into the belt, and in this way rewetting of the web is effectively prevented.

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Claims (6)

  1. Bande de transfert (1) pour feuille de papier humide pour une machine de fabrication de papier dans laquelle une feuille de papier humide (P) est transférée en tirage fermé, laquelle bande (1) comprend une couche de base (2) et une couche de nappage (3), la couche de nappage (3) ayant une face (3a) sur laquelle une feuille de papier humide (P) est placée, et au moins une couche de surface (A) de ladite face (3a) de la couche de nappage (3) étant formée de fibre comprenant une couche soudée (4) de fibre pouvant être fusionnée, caractérisée en ce que la couche soudée (4) conserve partiellement une configuration fibreuse, formant sur la surface de la couche soudée (A) des saillies (5) et des concavités (6) capables de s'aplatir lorsqu'une pression de pincement est appliquée à la bande (1).
  2. Bande de transfert (1) pour feuille de papier humide selon la revendication 1, dans laquelle la fibre formant ladite couche de surface (A) consiste sensiblement entièrement en une fibre qui peut être fusionnée.
  3. Bande de transfert pour feuille de papier humide selon la revendication 1, dans laquelle la fibre formant ladite couche de surface (A) comprend un mélange d'une fibre qui peut être fusionnée et d'une fibre qui ne peut ne pas être fusionnée.
  4. Bande de transfert pour feuille de papier humide selon l'une quelconque des revendications 1 à 3, dans laquelle au moins une partie de ladite fibre pouvant être fusionnée peut être fusionnée à une température comprise dans l'intervalle de 120°C à 180°C.
  5. Bande de transfert pour feuille de papier humide selon l'une quelconque revendication précédente, dans laquelle la couche soudée (4) a une perméabilité à l'air de 2 cc/cm2/s ou moins.
  6. Bande de transfert pour feuille de papier humide selon l'une quelconque revendication précédente, dans laquelle la couche soudée (4) a une rugosité de surface de Rz5-80 µm.
EP00306094A 1999-07-19 2000-07-18 Bande de transfert pour une bande humide Expired - Lifetime EP1085126B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP20546299 1999-07-19
JP20546299A JP3272328B2 (ja) 1999-07-19 1999-07-19 湿紙搬送ベルト

Publications (2)

Publication Number Publication Date
EP1085126A1 EP1085126A1 (fr) 2001-03-21
EP1085126B1 true EP1085126B1 (fr) 2004-03-03

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EP00306094A Expired - Lifetime EP1085126B1 (fr) 1999-07-19 2000-07-18 Bande de transfert pour une bande humide

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US (1) US6306260B1 (fr)
EP (1) EP1085126B1 (fr)
JP (1) JP3272328B2 (fr)
CN (1) CN1120261C (fr)
DE (1) DE60008658T2 (fr)

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JP2006144149A (ja) 2004-11-17 2006-06-08 Ichikawa Co Ltd 抄紙搬送フェルトおよび該抄紙搬送フェルトを備えた抄紙機のプレス装置
JP5062815B2 (ja) * 2006-11-01 2012-10-31 イチカワ株式会社 湿紙搬送用ベルト
JP6041597B2 (ja) * 2012-09-20 2016-12-14 イチカワ株式会社 湿紙搬送ベルト、抄紙システム、抄紙方法および抄紙システムの設計方法
CN103397557A (zh) * 2013-07-31 2013-11-20 海门市工业用呢厂 一种造纸毛毯
JP7426304B2 (ja) 2020-07-10 2024-02-01 日本フエルト株式会社 製紙用フェルト

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DE29706427U1 (de) * 1997-04-10 1997-06-05 Huyck-Austria Ges.M.B.H., Gloggnitz Biegsames Band, insbesondere zum Einsatz in Papiermaschinen
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US6036819A (en) * 1998-06-29 2000-03-14 Albany International Corp. Method for improving the cleanability of coated belts with a needled web on the inside surface

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DE60008658D1 (de) 2004-04-08
CN1281076A (zh) 2001-01-24
DE60008658T2 (de) 2004-07-29
JP3272328B2 (ja) 2002-04-08
EP1085126A1 (fr) 2001-03-21
US6306260B1 (en) 2001-10-23
JP2001040593A (ja) 2001-02-13
CN1120261C (zh) 2003-09-03

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