Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
  • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M145/24—Polyethers
  • C10M145/26—Polyoxyalkylenes
  • C10M145/36—Polyoxyalkylenes etherified
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
  • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M145/24—Polyethers
  • C10M145/26—Polyoxyalkylenes
  • C10M145/28—Polyoxyalkylenes of alkylene oxides containing 2 carbon atoms only
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
  • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M145/24—Polyethers
  • C10M145/26—Polyoxyalkylenes
  • C10M145/30—Polyoxyalkylenes of alkylene oxides containing 3 carbon atoms only
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
  • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M145/24—Polyethers
  • C10M145/26—Polyoxyalkylenes
  • C10M145/34—Polyoxyalkylenes of two or more specified different types
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
  • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/08—Hydraulic fluids, e.g. brake-fluids

Definitions

• Hydraulic and industrial functional fluids are required to exhibit a number of performance characteristics and this is usually achieved by blending a base oil (stock) with a multi functional additive package.
• Conventional packages are designed for use in Group I base stocks.
• the number of refiners producing Group II and Group III base stocks has increased recently, and the use of these base stocks has posed a number of challenges to formulators not encountered with Group I base stocks.
• Group II and III base stocks are produced by hydro processing and this reduces the aromatics content of the base stock resulting in differences in base stock solvency. Differences exist between different Group base stocks and between base stocks within the same Group.
• the reduced aromatics content of the base stock means that certain surface active components used in conventional hydraulic and industrial additive packages, such as demulsifiers, that function well when used in Group I base stocks do not always have sufficient solubility in all Group II and all Group III base stocks.
• demulsifiers such as copolymers of ethylene oxide and propylene oxide provide satisfactory demulse performance and are fully soluble in Group I base oils but, at useful concentrations, tend not to be fully soluble in Group II and Group III base oils.
• the present invention provides the use of an additive comprising an oil-soluble polyoxypropylene glycol monoalkyl ether for improving the demulse performance of a hydraulic or industrial functional fluid.
• improved demulse performance is meant the ability of an oil to separate from water.
• the established test to evaluate the ability of hydraulic and industrial oil to separate from water is the ASTM D1401. In this test 40ml of oil is mixed with 40ml of water at 54C and the time taken for the resulting emulsion to reduce to 3ml or less is recorded. If complete separation does not occur then the volume of oil, water and emulsion present is recorded. Most hydraulic and industrial specifications require separation to 37ml of water and 3ml of emulsion in less than 30 minutes.
• the polyoxypropylene glycol monoalkyl ether has a number average molecular weight of 3000 to 6000, preferably from 3500 to 4500 and, more preferably of about 4100.
• the alkyl moiety of this component is n-butyl.
• the ether component typically has a viscosity at 40°C of about 360 to 410cSt. In a preferred embodiment the viscosity of the component is about 400 cSt at 40°C and about 50 cSt at 100°C.
• the component usually has a pour point of -15 to -35°C, preferably about -22°C.
• Useful polyoxypropylene glycol monoalkyl ethers are commercially available or may be made by the application or adaptation of known techniques.
• the ether component is typically employed in an amount of 0.5 % to 4.0 wt %, preferably 1 to 3 wt% and more preferably 2.0 wt% based on the weight of the fully formulated fluid.
• the polyoxypropylene ether described is used in combination with a copolymer of ethylene oxide and propylene oxide.
• a copolymer of ethylene oxide and propylene oxide is capable of providing even better demulse performance without detriment to the cleanliness of the composition (as may be assessed by the clarity and brightness of the finished fluid and by the Afnor wet filtrability test using a 0.8 micron filter).
• this combination is employed the amount of the copolymer of ethylene oxide and propylene oxide required to give effective demulse performance is significantly reduced which allows for formulation of clear and bright finished lubricants when using either Group I, II or III base stocks.
• the copolymer has a mole ratio of units derived from ethylene oxide to units derived from propylene oxide of 2.0:1 to 0.3:1, preferably 0.65:1.
• the copolymer has a number average molecular weight of 2000 to 4500, preferably 3800.
• the weight ratio of the polyoxypropylene glycol monoalkyl ether to copolymer is 60:1 to 10:1, preferably about 20:1.
• Base oils contemplated for use in this invention include natural oils, synthetic oils and mixtures thereof. Suitable oils also include base stocks obtained by isomerization of synthetic wax and slack wax, as well as base stocks produced by hydro cracking (rather than solvent extracting) the aromatic and polar components of crude oil.
• both the natural and synthetic oils will each have a kinematic viscosity ranging from about 1 x 10 -6 m 2 /s to about 40 x 10 -6 m 2 /s (about 1 to about 40 cSt) at 100°C, although typical applications will require each oil to have a viscosity ranging from about 2 x 10 -6 m 2 /s to about 8 x 10 -6 m 2 /s (about 2 to about 8 cSt) at 100°C.
• Natural base oils include animal oils, vegetable oils (e.g., castor oil and lard oil), petroleum oils, mineral oils, and oils derived from coal or shale.
• the preferred natural base oil is mineral oil.
• the mineral oils useful in this invention include all common mineral oil base stocks. This would include oils that are naphthenic or paraffinic in chemical structure. Oils that are refined by conventional methodology using acid, alkali, and clay or other agents such as aluminum chloride, or they may be extracted oils produced, for example, by solvent extraction with solvents such as phenol, sulfur dioxide, furfural, dichlorodiethyl ether, etc. They may be hydro treated or hydro-refined, dewaxed by chilling or catalytic dewaxing processes, or hydro cracked. The mineral oil may be produced from natural crude sources or be composed of isomerized wax materials or residues of other refining processes.
• the mineral oils will have kinematic viscosities of from 2 x 10 -6 m 2 /s to 12 x 10 -6 m 2 /s (2 cSt to 12 cSt) at 100C.
• the preferred mineral oils have kinematic viscosities of from 3 x 10 -6 m 2 /s to 10 x 10 -6 m 2 /s (3 to 10 cSt), and most preferred are those mineral oils with viscosities of 5 x 10 -6 m 2 /s to 9 x 10 -6 m 2 /s (5 to 9 cSt) at 100C.
• Synthetic oils useful in this invention include hydrocarbon oils and halo-substituted hydrocarbon oils such as oligomerized, polymerized, and interpolymerized olefins [e.g., polybutylenes, polypropylenes, propylene, isobutylene copolymers, chlorinated polylactenes, poly(1-hexenes), poly(1-octenes), and mixtures thereof]; alkylbenzenes [e.g., polybutylenes, polypropylenes, propylene, isobutylene copolymers, chlorinated polylactenes, poly(1-hexenes), poly (1-octenes) and mixtures thereof]; alkylbenzenes [e.g., dodecyl-benzenes, tetradecylbenzenes, dinonyl-benzenes and di(2-ethylhexyl)benzene]; polyphenyls [e
• Synthetic oils also include alkylene oxide polymers, interpolymers, copolymers, and derivatives thereof where the terminal hydroxyl groups have been modified by esterification or etherification.
• This class of synthetic oils is exemplified by: polyoxyalkylene polymers prepared by polymerization of ethylene oxide or propylene oxide; the alkyl and aryl ethers of these polyoxyalkylene polymers (e.g., methyl-polyisopropylene glycol ether having an average molecular weight of 1000, diphenyl ether of polypropylene glycol having a molecular weight of 100-1500); and mono- and poly-carboxylic esters thereof (e.g., the acetic acid esters, mixed C 3 -C 8 fatty acid esters, and C 12 oxo acid diester of tetraethylene glycol).
• Another suitable class of synthetic oils comprises the esters of dicarboxylic acids (e.g., phthalic acid, succinic acid, alkyl succinic acids and alkenyl succinic acids, maleic acid, azelaic acid, suberic acid, sebacic acid, fumaric acid, adipic acid, linoleic acid dimer, malonic acid, alkylmalonic acids and alkenyl malonic acids) with a variety of alcohols (e.g., butyl alcohol, hexyl alcohol, dodecyl alcohol, 2-ethylhexyl alcohol, ethylene glycol, diethylene glycol monoethers and propylene glycol).
• dicarboxylic acids e.g., phthalic acid, succinic acid, alkyl succinic acids and alkenyl succinic acids, maleic acid, azelaic acid, suberic acid, sebacic acid, fumaric acid, adipic acid, linoleic acid dim
• esters include dibutyl adipate, di(2-ethylhexyl) sebacate, di-n-hexyl fumarate, dioctyl sebacate, diisooctyl azelate, diisodecyl azelate, dioctyl isophthalate, didecyl phthalate, dieicosyl sebacate, the 2-ethylhexyl diester of linoleic acid dimer, and the complex ester formed by reacting one mole of sebacic acid with two moles of tetraethylene glycol and two moles of 2-ethyl-hexanoic acid.
• a preferred type of oil from this class of synthetic oils are adipates of C 4 to C 12 alcohols.
• Esters useful as synthetic oils also include those made from C 5 to C 12 monocarboxylic acids and polyols and polyol ethers such as neopentyl glycol, trimethylolpropane pentaerythritol, dipentaerythritol and tripentaerythritol.
• Silicon-based oils (such as the polyalkyl-, polyaryl-, polyalkoxy-, or polyaryloxy-siloxane oils and silicate oils) comprise another useful class of synthetic lubricating oils. These oils include tetra-ethyl silicate, tetraisopropyl silicate, tetra-(2-ethylhexyl) silicate, tetra-(4-methyl-2-ethylhexyl) silicate, tetra-(p-tert-butylphenyl) silicate, hexa-(4-methyl-2-pentoxy)-disiloxane, poly(dimethyl)siloxanes and poly (methylphenyl) siloxanes.
• oils include tetra-ethyl silicate, tetraisopropyl silicate, tetra-(2-ethylhexyl) silicate, tetra-(4-methyl-2-ethylhe
• Other synthetic lubricating oils include liquid esters of phosphorus containing acids (e.g., tricresyl phosphate, trioctylphosphate, and diethyl ester of decylphosphonic acid), polymeric tetrahydrofurans and poly-olefins.
• the base oils may be derived from refined, re-refined oils, or mixtures thereof.
• Unrefined oils are obtained directly from a natural source or synthetic source (e.g., coal, shale, or tar sands bitumen) without further purification or treatment.
• Examples of unrefined oils include a shale oil obtained directly from a retorting operation, a petroleum oil obtained directly from distillation, or an ester oil obtained directly from an esterification process, each of which is then used without further treatment.
• Refined oils are similar to the unrefined oils except that refined oils have been treated in one or more purification steps to improve one or more properties.
• Suitable purification techniques include distillation, hydro treating, dewaxing, solvent extraction, acid or base extraction, filtration, and percolation, all of which are known to those skilled in the art.
• Re-refined oils are obtained by treating used oils in processes similar to those used to obtain the refined oils. These re-refined oils are also known as reclaimed or reprocessed oils and are often additionally processed by techniques for removal of spent additives and oils breakdown products.
• White oils, as taught in U.S. 5,736,490 may also be used as the base oil, especially for turbine applications.
• the base oil is a Group I, Group II, Group III or Group IV base oil.
• the use of Group II or Group III base oils is preferred.
• the American Petroleum Institute has categorized these different base stock types as follows: Group I, >0.03 wt% sulfur, and/or ⁇ 90 vol% saturates, viscosity index between 80 and 120; Group II, 0.03 wt% sulfur, and 90 vol% saturates, viscosity index between 80 and 120; Group III, 0.03 wt% sulfur, and 90 vol% saturates, viscosity index >120; Group IV, all polyalphaolefins. Hydro treated base stocks and catalytically dewaxed base stocks, because of their low sulfur and aromatics content, generally fall into the Group II and Group III categories.
• Polyalphaolefins (Group IV base stocks) are synthetic base oils prepared from various alpha olefins and are substantially free of sulfur and aromatics.
• the functional fluids may be prepared by simple blending of the various components with a suitable base oil.
• the additive components used in practice of this invention may be provided as a concentrate for formulation into a functional fluid ready for use.
• the concentrate may comprise, in addition to the fluid components, a solvent or diluent for the fluid components.
• the solvent or diluent should be miscible with and/or capable of dissolving in the base oil to which the concentrate is to be added. Suitable solvents and diluents are well known.
• the solvent or diluent may be the base oil of the functional fluid itself.
• the concentrate may suitably include any of the conventional additives used in hydraulic and industrial applications. The proportions of each component in the concentrate are controlled by the intended degree of dilution, though top treatment of the formulated fluid is possible.
• additives commonly used in fluids for hydraulic and industrial applications may be included in the compositions or concentrates of the present invention. These include antioxidants, dispersants, friction modifiers, detergents, antiwear and/or extreme pressure agents, rust inhibitors and corrosion inhibitors. These additives, when present, are used in amounts conventionally used in such applications. Some additives may be included in the concentrate and some added to the fully formulated fluid as a top-treat.
• hydraulic and industrial applications where the present invention may be employed include hydraulic oils, turbine (R&O) oil, compressor oils, slideway oils, paper machine oils.
• R&O turbine
• compressor oils slideway oils
• paper machine oils examples include hydraulic oils, turbine (R&O) oil, compressor oils, slideway oils, paper machine oils.
• a functional fluid was prepared by blending an additive package comprising the components listed below with a base stock.
• the treat rate of the additive package was 0.85%.
• the demulsifier was a polyoxypropylene glycol monoalkyl ether having a weight average molecular weight of about 4100.
• the formulated fluid was then subjected to the ASTM D1401 demulse test.
• each fluid was assessed using Afnor E48-691 (wet) test.
• Afnor E48-691 wet test.
• a water-treated fluid is filtered under conditions of constant pressure and temperature through a membrane with a determined absolute stopping power.
• the IF ratio therefore consists of comparing the filtration speeds of the fluid in the course of the test.
• the ratio as well as the filtration speed of the various segments for each sample are indicative of the ease of filtration of the fluid.
• An IF value of less than 1 indicates a fault in the test method. The closer the IF value to 1, the better filtrability of the fluid. If during testing the membrane becomes clogged an abort result is recorded.
• the results are shown in the following table which also identifies the kind of base oil used in formulating the fluid.
• Base Oil (Group) BP ISO 32 (I) Petrocanada SPC 35LT (II) Excel ISO 32 (II) Yubase 6 (HI) D1401 Time to 37 ml water 11 13.04 9.40 16.42 Time to 3 ml emulsion 11 13.04 9.40 16.42 Result at 30 minutes 40/39/1 40/40/0 40/40/0 40/39/1 Afnor Dry 1.09 - - 1.18 Afnor Wet 1.34 - - 1.62
• Additive packages A and B were prepared containing the following components.
• a (wt %) B (wt %) Detergents 7.88 7.88 Rust Inhibitor 6 6
• Antioxidants 23.00 23.00 Demulsifier 0.75 0.1 Demulsifier - 2 Process oil 1.02 1.02 Antiwear and/or extreme pressure agent 60.00 60.00
• Rust and oxidation turbine oils were prepared by blending additive package C and D, comprising the components listed below, with a base stock.
• the treat rate was 0.8% wt.
• Additive packages A and B were prepared containing the following components.
• C(wt%) D (wt %)
• Antioxidant 60
• Rust Inhibitor 15 15
• Corrosion Inhibitor 3 3

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Organic Chemistry (AREA)
• Lubricants (AREA)

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• 1999
  • 1999-03-03 EP EP99301603A patent/EP1048711A1/fr not_active Withdrawn
• 2000
  • 2000-02-17 CA CA002299203A patent/CA2299203C/fr not_active Expired - Fee Related
  • 2000-02-23 AU AU19422/00A patent/AU1942200A/en not_active Abandoned
  • 2000-02-29 SG SG200001083A patent/SG89319A1/en unknown
  • 2000-02-29 JP JP2000053382A patent/JP3856365B2/ja not_active Expired - Fee Related
  • 2000-03-02 US US09/516,855 patent/US6255263B1/en not_active Expired - Fee Related
  • 2000-03-03 KR KR1020000010693A patent/KR20000062735A/ko not_active Application Discontinuation
  • 2000-03-03 CN CNB001038524A patent/CN1175092C/zh not_active Expired - Fee Related

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