EP1036133B1 - Production d'olefines - Google Patents

Production d'olefines Download PDF

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Publication number
EP1036133B1
EP1036133B1 EP98958122A EP98958122A EP1036133B1 EP 1036133 B1 EP1036133 B1 EP 1036133B1 EP 98958122 A EP98958122 A EP 98958122A EP 98958122 A EP98958122 A EP 98958122A EP 1036133 B1 EP1036133 B1 EP 1036133B1
Authority
EP
European Patent Office
Prior art keywords
feedstock
catalyst
olefins
effluent
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98958122A
Other languages
German (de)
English (en)
Other versions
EP1036133A1 (fr
Inventor
Jean-Pierre Dath
Luc Delorme
Jacques-François Grootjans
Xavier Vanhaeren
Walter Vermeiren
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Atofina Research SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Research SA filed Critical Atofina Research SA
Priority to EP98958122A priority Critical patent/EP1036133B1/fr
Publication of EP1036133A1 publication Critical patent/EP1036133A1/fr
Application granted granted Critical
Publication of EP1036133B1 publication Critical patent/EP1036133B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

Claims (9)

  1. Procédé pour le craquage catalytique d'une charge d'alimentation riche en oléfines qui est sélectif envers les oléfines légères dans l'effluent, le procédé comprenant la mise en contact de la charge d'alimentation d'hydrocarbures contenant une ou plusieurs oléfines, avec un catalyseur de silicate cristallin de type MFI ayant un rapport atomique silicium/aluminium de 300 à 1000 à une température d'entrée de 500 à 600°C, à une pression partielle en oléfines de 0,1 à 2 bars et où on fait passer la charge d'alimentation sur le catalyseur à une LHSV de 10 à 30h-1, pour produire un effluent avec une teneur en oléfines à poids moléculaire inférieur à celui de la charge d'alimentation.
  2. Procédé selon la revendication 1, où le catalyseur a été préparé par cristallisation en utilisant un gabarit organique et n'a pas été soumis à un traitement ultérieur quelconque à la vapeur ou un procédé de désaluminisation.
  3. Procédé selon la revendication 2, où le catalyseur comprend un catalyseur de type ZSM-5.
  4. Procédé selon l'une quelconque des revendications précédentes, où la charge d'alimentation comprend des hydrocarbures de C4 à C10.
  5. Procédé selon l'une quelconque des revendications précédentes, où le procédé est sélectif envers le propylène dans l'effluent de sorte que l'effluent est riche en propylène.
  6. Procédé selon la revendication 5, où le propylène comprend au moins 93% de composés C3 présents dans l'effluent.
  7. Procédé selon la revendication 5 ou la revendication 6, où le craquage catalytique a un rendement en propylène, calculé sur base oléfinique, de 30 à 50% basé sur la teneur en oléfines dans la charge d'alimentation.
  8. Procédé selon l'une quelconque des revendications précédentes, où le procédé de craquage catalytique rompt les oléfines dans la charge d'alimentation pour former des oléfines plus légères de sorte que les teneurs en oléfines en poids de la charge d'alimentation, et de l'effluent sont inférieures à plus ou moins 15% l'une de l'autre.
  9. Procédé selon l'une quelconque des revendications précédentes, où la température d'entrée se situe entre 540 à 580°C.
EP98958122A 1997-12-05 1998-12-07 Production d'olefines Expired - Lifetime EP1036133B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP98958122A EP1036133B1 (fr) 1997-12-05 1998-12-07 Production d'olefines

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP97121376 1997-12-05
EP97121376A EP0921176A1 (fr) 1997-12-05 1997-12-05 Production d'oléfines
PCT/BE1998/000187 WO1999029802A1 (fr) 1997-12-05 1998-12-07 Production d'olefines
EP98958122A EP1036133B1 (fr) 1997-12-05 1998-12-07 Production d'olefines

Publications (2)

Publication Number Publication Date
EP1036133A1 EP1036133A1 (fr) 2000-09-20
EP1036133B1 true EP1036133B1 (fr) 2003-07-02

Family

ID=8227743

Family Applications (2)

Application Number Title Priority Date Filing Date
EP97121376A Withdrawn EP0921176A1 (fr) 1997-12-05 1997-12-05 Production d'oléfines
EP98958122A Expired - Lifetime EP1036133B1 (fr) 1997-12-05 1998-12-07 Production d'olefines

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP97121376A Withdrawn EP0921176A1 (fr) 1997-12-05 1997-12-05 Production d'oléfines

Country Status (11)

Country Link
EP (2) EP0921176A1 (fr)
JP (1) JP4048458B2 (fr)
KR (1) KR20010032810A (fr)
CN (1) CN1170913C (fr)
AT (1) ATE244288T1 (fr)
AU (1) AU1430299A (fr)
DE (1) DE69816114T2 (fr)
ES (1) ES2202911T3 (fr)
TW (1) TW491889B (fr)
WO (1) WO1999029802A1 (fr)
ZA (1) ZA9811082B (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079813B2 (en) 2010-08-03 2015-07-14 Total Research & Technology Feluy Process to make propylene from isobutanol by dehydration and subsequent cracking
WO2022023359A1 (fr) 2020-07-28 2022-02-03 Totalenergies Se Procédé pour produire une réaction de craquage catalytique endothermique dans un réacteur à lit fluidisé
US11643371B2 (en) 2019-11-22 2023-05-09 Totalenergies Onetech Alkyl halides conversion into ethylene and propylene
US11945760B2 (en) 2019-11-22 2024-04-02 Totalenergies Onetech Process for converting one or more methyl halides into ethylene and propylene

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0921180A1 (fr) * 1997-12-05 1999-06-09 Fina Research S.A. Production d'oléfines
EP1061116A1 (fr) * 1999-06-16 2000-12-20 Fina Research S.A. Production d' oléfines
EP1063274A1 (fr) * 1999-06-17 2000-12-27 Fina Research S.A. Production d'oléfines
EP1365004A1 (fr) * 2002-05-23 2003-11-26 ATOFINA Research Production d'olefines
EP1396481A1 (fr) * 2002-08-14 2004-03-10 ATOFINA Research Production d'oléfines
GB0414442D0 (en) * 2004-06-28 2004-07-28 Borealis As Zeolite catalysts
JP4774812B2 (ja) * 2005-06-03 2011-09-14 三菱化学株式会社 プロピレンの製造方法
EP2173689B8 (fr) 2007-07-31 2023-10-18 TotalEnergies OneTech Belgium Procédé d'utilisation de tamis moléculaires modifiés par du phosphore visant à convertir des composés organiques en oléfines
EP2039427A1 (fr) * 2007-09-12 2009-03-25 Total Petrochemicals Research Feluy Craquage d'oléfines sur des tamis moléculaires modifiés au phosphore
EP2175991A1 (fr) * 2007-07-31 2010-04-21 Total Petrochemicals Research Feluy Procédé de craquage d'oléfines mis en oeuvre sur des tamis moléculaires modifiés par du phosphore
EP2082803A1 (fr) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Procédé pour l'obtention de composites catalyseurs comprenant du MeAPO et leur utilisation dans la conversion de substances organiques en oléfines
EP2082801A1 (fr) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Processus pour obtenir des tamis moléculaires modifiés
EP2082802A1 (fr) 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Procédé pour l'obtention d'un composite catalyseur
EP2108637A1 (fr) 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Processus de fabrication d'oléfines à partir d'éthanol
EP2108635A1 (fr) 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Processus de fabrication d'oléfines à partir d'éthanol
EP2143700A1 (fr) 2008-06-25 2010-01-13 Total Petrochemicals Research Feluy Procédé pour la fabrication d'oléfines à partir de composés oxygénés
US8137631B2 (en) 2008-12-11 2012-03-20 Uop Llc Unit, system and process for catalytic cracking
US8246914B2 (en) 2008-12-22 2012-08-21 Uop Llc Fluid catalytic cracking system
US8889076B2 (en) 2008-12-29 2014-11-18 Uop Llc Fluid catalytic cracking system and process
EP2336272A1 (fr) 2009-12-15 2011-06-22 Total Petrochemicals Research Feluy Décongestionnement d'une unité de craquage à vapeur pour améliorer la production de propylène
CN103153921A (zh) 2010-08-03 2013-06-12 道达尔研究技术弗吕公司 由甲醇和异丁醇制造烯烃的方法
EA030477B1 (ru) 2011-08-03 2018-08-31 Тотал Ресерч & Технолоджи Фелай Катализатор на основе модифицированного фосфором цеолита с частичной alpo-структурой
US10300467B2 (en) 2011-08-03 2019-05-28 Total Research & Technology Feluy Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite
WO2018210827A1 (fr) 2017-05-17 2018-11-22 Total Research & Technology Feluy Procédé de valorisation de mto-ocp pour maximiser la sélectivité en propylène
CN111116289B (zh) * 2018-10-30 2022-12-09 中国石油化工股份有限公司 烯烃催化裂解装置扩能的方法
WO2021198166A1 (fr) 2020-03-30 2021-10-07 Total Se Procédé de conversion de gaz en oléfines avec coproduction d'hydrogène conjointement à un procédé d'intégration thermique
EP4126798A1 (fr) * 2020-03-30 2023-02-08 Totalenergies Onetech Procédés de conversion de gaz en oléfines avec coproduction d'hydrogène
WO2021198175A1 (fr) 2020-03-30 2021-10-07 Total Se Procédé de conversion de gaz en oléfines avec coproduction d'hydrogène conjointement avec une section de réaction électrifiée
WO2021198479A1 (fr) 2020-04-03 2021-10-07 Total Se Production d'oléfines légères par oxychloration

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3372474D1 (en) * 1982-11-10 1987-08-20 Montedipe Spa Process for converting olefins having 4 to 12 carbon atoms into propylene
CA1209121A (fr) * 1983-07-12 1986-08-05 Guenter H. Kuehl Preparation de zeolite zsm-12
US5171921A (en) * 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9079813B2 (en) 2010-08-03 2015-07-14 Total Research & Technology Feluy Process to make propylene from isobutanol by dehydration and subsequent cracking
US11643371B2 (en) 2019-11-22 2023-05-09 Totalenergies Onetech Alkyl halides conversion into ethylene and propylene
US11945760B2 (en) 2019-11-22 2024-04-02 Totalenergies Onetech Process for converting one or more methyl halides into ethylene and propylene
WO2022023359A1 (fr) 2020-07-28 2022-02-03 Totalenergies Se Procédé pour produire une réaction de craquage catalytique endothermique dans un réacteur à lit fluidisé

Also Published As

Publication number Publication date
JPH11246869A (ja) 1999-09-14
ATE244288T1 (de) 2003-07-15
EP1036133A1 (fr) 2000-09-20
EP0921176A1 (fr) 1999-06-09
CN1284110A (zh) 2001-02-14
WO1999029802A1 (fr) 1999-06-17
TW491889B (en) 2002-06-21
KR20010032810A (ko) 2001-04-25
ES2202911T3 (es) 2004-04-01
JP4048458B2 (ja) 2008-02-20
ZA9811082B (en) 1999-06-07
AU1430299A (en) 1999-06-28
DE69816114D1 (de) 2003-08-07
CN1170913C (zh) 2004-10-13
DE69816114T2 (de) 2004-07-15

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