EP1035408A1 - Apparatus for measuring characteristics of optical angle - Google Patents
Apparatus for measuring characteristics of optical angle Download PDFInfo
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- EP1035408A1 EP1035408A1 EP98954767A EP98954767A EP1035408A1 EP 1035408 A1 EP1035408 A1 EP 1035408A1 EP 98954767 A EP98954767 A EP 98954767A EP 98954767 A EP98954767 A EP 98954767A EP 1035408 A1 EP1035408 A1 EP 1035408A1
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- Prior art keywords
- sample
- light
- mirror
- measuring apparatus
- light source
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/47—Scattering, i.e. diffuse reflection
- G01N21/4738—Diffuse reflection, e.g. also for testing fluids, fibrous materials
- G01N21/474—Details of optical heads therefor, e.g. using optical fibres
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
- G01N15/02—Investigating particle size or size distribution
Definitions
- the present invention relates to an optical angle characteristic measuring apparatus capable of measuring, as a function of the angle, the intensity of light emitted from a sample.
- Apparatus for measuring the angle dependency of emitted light is called an optical angle characteristic measuring apparatus. More precisely, apparatus for measuring the angle dependency of scattered light is called a light scattering intensity measuring apparatus.
- the light scattering intensity measuring apparatus is arranged such that light is irradiated in one direction to a sample, that a detector for detecting the scattered light is disposed on a goniometer rotatable around the sample, and that the scattered light is detected at a variety of angles with the goniometer rotated.
- Fig. 4 is a schematic view of a light scattering intensity measuring apparatus according to the present invention.
- the light scattering intensity measuring apparatus comprises a glass-made sample cell 1 for housing a sample to be measured, and a laser device 5 for projecting a laser beam to the sample cell 1 through mirrors 2a, 2b, condensing lenses 3a, 3b, an aperture 3c, a glass window 8 and a pinhole 4.
- the light scattering intensity measuring apparatus further comprises: an ellipsoidal mirror 6 for condensing the scattered light from the sample on an image-forming lens 12; an aperture 11 through which reflected light from the ellipsoidal mirror 6 passes; the image-forming lens 12; and a CCD camera 13.
- the image-forming lens 12 is arranged to form, on the camera face of the CCD camera 13, the image formed on the mirror face of the ellipsoidal mirror 6.
- An absorbing plate 7 is disposed for absorbing the laser beam which has been transmitted straight through the sample cell 1.
- the absorbing plate 7 prevents the transmitted laser beam from reflecting and scattering after striking against the glass window 8 and the like.
- the pinhole 4, the aperture 3c and the aperture 11 are disposed for cutting excessive stray light around the laser beam, contributing to the formation of a clean laser beam profile.
- the laser device 5 is disposed at a position above the sample cell 1 for reasons of drawing a figure in plan elevation.
- the position of the laser device 5 is not limited to the position shown in Fig. 4.
- the laser device 5 can be disposed at a level identical with that at which the sample cell 1 is disposed (In this case, it is a matter of course that the mirror positions are accordingly changed).
- Fig. 5 is a perspective view of a general arrangement of a light scattering intensity measuring apparatus in which the laser device 5 is disposed at a level identical with that at which the sample cell 1 is disposed. Except for the following points (a) and (b), the arrangement in Fig. 5 is the same as the arrangement in Fig. 4.
- the point (a) makes it possible to know the polarization components of the light irradiated to the sample cell 1 and the light scattered from the sample. By evaluating the polarization components, the anisotropy and integrity of the sample can be evaluated.
- the point (b) is a trivial matter.
- Fig. 6 is a view illustrating the function of the ellipsoidal mirror 6.
- the ellipsoidal mirror 6 is obtained by cutting the surface of an ellipsoid of revolution in a round slice of which inner face serves as a mirror face. Because of the nature of the ellipsoid of revolution, light from one focal point 61 strikes against the ellipsoidal mirror 6 and converges on the other focal point 62.
- the ellipsoidal mirror 6 is not always required to be a round circular shape, but may be a partial portion of a round circular piece as shown in Fig. 6(B). It is enough that the mirror is present in the scattering angle range to be measured.
- the light scattering intensity measuring apparatus is provided at the one focal point with the sample cell 1 and at the other focal point with the image-forming lens 12. Accordingly, that portion of the scattered light from the sample cell 1 which has struck against the ellipsoidal mirror 6, is reflected thereby and condensed on the image-forming lens 12, and is then incident upon a CCD camera 13.
- Fig. 7 shows a view illustrating a specific structure of the light scattering intensity measuring apparatus in Fig. 4.
- a laser device for projecting a laser beam to the sample cell 1 a mirror and a condensing lens.
- the sample cell 1 is set in a thermostatic liquid immersion bath 43 filled with a liquid presenting the refractive index close to the cell. Scattered light from the sample cell 1 is transmitted through a glass window 8, strikes against the ellipsoidal mirror 6 and is then reflected thereby. Disposed immediately below the sample cell 1 is a plane mirror 10 by which the light reflected by the ellipsoidal mirror 6, is changed in direction. By changing the reflected light in direction, this plane mirror 10 produces an effect of reducing the height of the entire apparatus.
- the light changed in direction by the plane mirror 10 is incident upon the CCD camera 13 through the aperture 11 and the image-forming lens 12.
- the CCD camera 13 uses a light receiving element very high in positional resolution (for example 512 x 512 pixels). This makes it possible to obtain data with high resolution, i.e., the scattering angle of 1° or less as measuring angle resolution.
- Fig. 8 shows the scattered light intensity pattern generated on the camera face of the CCD camera 13.
- This scattered light pattern is a pattern formed on the mirror face of the ellipsoidal mirror 6 in the form of a circular arc shown in Fig. 6(B), and covers the scattering angle ⁇ range from 5° to 175°.
- Fig. 9 shows this pattern in the form of a graph in which the axis of abscissa presents the scattering angle ⁇ .
- the present invention should not be limited to the embodiment above-mentioned. That is, other mirror than an ellipsoidal mirror may be used for condensing the scattered light from the sample on the image-forming lens 12.
- a mirror 6b obtained by cutting a portion of a cone in a round slice as shown in Fig. 10(A), or a mirror 6c obtained by cutting a portion of a spherical surface in a round slice as shown in Fig. 10(B).
- each of the mirrors 6b, 6c When each of the mirrors 6b, 6c is used, it does not occur that light coming from one focal point and striking against the ellipsoidal mirror 6, is condensed on the other focal point in a stigmatic manner as done with the ellipsoidal mirror 6.
- the width W of each of the mirrors 6b, 6c by reducing the width W of each of the mirrors 6b, 6c, light coming from one focal point and striking against each of the mirrors 6b, 6c, can substantially be condensed upon one point. Accordingly, even the use of each of the mirrors 6b, 6c makes it possible to obtain scattered light data with precision equivalent to that in the case of the use of the ellipsoidal mirror 6.
- Fig. 11 is a block diagram of a general arrangement of an optical angle characteristic measuring apparatus.
- This optical angle characteristic measuring apparatus has an optical system 21 comprising an ellipsoidal mirror of revolution 24, an image-forming lens 25, a camera 26 and motors 27 for operating a variety of movable members.
- the optical angle characteristic measuring apparatus further comprises: an illumination light source 32 for generating monochromatic light to be irradiated to a liquid crystal display element 23 as an example of the sample; an optical fiber 35 for guiding light of the illumination light source 32 to the optical system 21 (a mirror system can be used instead of the optical fiber 35); a camera control unit 31 for taking image data from the camera 26 and controlling the parameters such as light exposure time and the like; a liquid crystal drive unit 33 for generating a signal for driving the liquid crystal display element 23; a motor controller 34; a computer 14 for controlling the apparatus in its entirety; a display device 15; and a keyboard 16.
- examples of the simple include, in addition to a liquid crystal display element, a light emitting diode, an optical fiber light emitting end, a film, a color filter and the like.
- the illumination light source 32 is a combination of a white-color illumination light source 32a with a monochromator 32b.
- the selection of the wavelength of the monochromator 32b is controlled by the computer 14 and the like.
- the monochromator 32b there may be used a laser illumination light source, an illumination light source for generating multi-color light instead of monochromatic light, or an illumination light source for generating white-color light such as a halogen lamp, a Xe lamp, a metal halide lamp or the like. More specifically, the type of illumination light source to be used is dependent on the measuring conditions of the sample 23. When the sample is of the self-light-emitting type, the illumination light source 32 may not be used.
- this linear polarized, light may be used as converted, into a circular polarized light with the use of a 1 ⁇ 4-wavelength plate such that the polarization characteristics exert no effect on the measurement.
- the camera 26 there may be used optional means which can store a formed image.
- optional means which can store a formed image.
- means for converting an image into an electric signal such as a CCD camera, or means for chemically recording an image on a film such as an optical camera.
- a CCD camera it is assumed that a CCD camera is used.
- the motors 27 and the motor controller 34 are disposed for controlling the posture of the sample 23 and for rotating, moving and operating a variety of optical elements such as the shaft for irradiating light to the sample 23, a polarizer, an analyzer, a phase-contrast plate and the like.
- Fig. 12 is a detailed arrangement view illustrating a first specific example of the optical system 21.
- the liquid crystal display element 23 is of the self light-emitting type.
- An illumination light source is not used for the liquid crystal display element 23 and is therefore not shown in Fig. 12.
- the optical system 21 comprises: a stage 28 on and by which the sample 23 is placed and held in an optional posture; an ellipsoidal mirror of revolution 24 for condensing, on the second focal point, the light emitted from the sample 23 disposed in the vicinity of the first focal point; an aperture 29 through which the light reflected by the ellipsoidal mirror of revolution 24 passes; an image-forming lens 25 disposed at the second focal point of the ellipsoidal mirror of revolution 24 for forming the image formed on the surface of the ellipsoidal mirror of revolution 24; and a camera 26 for recording the image formed by the image-forming lens 25.
- An optical filter may be disposed in front of the camera 26.
- the optical filter examples include a wavelength cutting filter for eliminating the wavelength unnecessary for measurement, a Y-view sensitivity filter for approximating the camera sensitivity to the sensitivity of the human eyes, a light attenuating filter for attenuating the light from the sample, and the like. Further, there may be selected and disposed a tristimulus-value filter for measuring chromaticity and brightness.
- the ellipsoidal mirror of revolution 24 having a first focal distance f1 of 55 mm and a second focal distance f2 of 600 mm.
- a space of 8 mm is assured as the distance between the sample 23 and the lower end surface of the ellipsoidal mirror of revolution 24. It is therefore not required to use special attention for placing the sample 23.
- Fig. 13 is a detailed arrangement view illustrating a second specific example of the optical system 21.
- an illumination light source 32 for irradiating light to a liquid crystal display element 23 is used to measure the reflectivity.
- This illumination light source 32 comprises a light source 32h, a lens 32c movable on the optical axis, an iris diaphragm 32d disposed at the light emitting side of the lens 32c, and a reflection mirror 32e for projecting the light from the light source 32h, on the first focal point of the ellipsoidal mirror of revolution 24.
- the reflection mirror 32e can be changed in position and angle such that light from the light source 32h is projected on the ellipsoidal mirror of revolution 24 in the ⁇ range from 0° to several tens of degree.
- the lens 32c serves as an adjusting member for condensing the spot of the illumination light source on the sample 23 or on the point of infinity.
- the spot diameter is minimized when the lens 32c is positioned such that the virtual image of the light source is formed at the position of the second focal point of the ellipsoidal mirror.
- the opening angle of the illumination light is adjusted by the iris diaphragm 32d.
- a light attenuating filter 32f is disposed at the position of regular reflection (In Fig. 13, the light attenuating filter 32f is hidden behind the shadow of the reflection mirror 32e because the angle ⁇ at which the illumination light is incident upon the sample, is 0° ).
- the light attenuating filter 32f serves as a filter (ND filter) for attenuating the light regularly reflected from the sample 23. Such light attenuation reduces the regular reflection component and assures a dynamic range for measurement of a diffusion component.
- Fig. 14 is a detailed arrangement view illustrating a third specific example of the optical system 21.
- the illumination light source 32 for transmittably illuminating the liquid crystal display element 23 from below.
- an ellipsoidal mirror 24a is disposed below the stage 28. Together with the light condensing ellipsoidal mirror 24, this ellipsoidal mirror 24a is cut out from a single ellipsoidal mirror. Therefore, the ellipsoidal mirrors 24, 24a have the same focal distances f1, f2. This does not involve the likelihood that the focal points are positionally shifted from each other.
- the illumination light source 32 used in Fig. 13 is used as rotated by an angle of 180° in the opposite direction. By this arrangement, both transmissivity and reflexibility can be measured with one illumination light source 32. This achieves a compact and economical optical angle characteristic measuring apparatus.
- the light attenuating filter 32f is used to assure a dynamic range for measuring a diffusion component.
- Fig. 15 is a detailed arrangement view illustrating a fourth specific example of the optical system 21.
- This fourth example is arranged to measure the polarization characteristics of the liquid crystal display element 23.
- the reflectivity polarization characteristics can be measured when the illumination light source 32 is located in the position of solid lines, and the transmissivity polarization characteristics can be measured when the illumination light source 32 is located in the position of broken lines.
- the illumination light source 32 has a polarizer 32g, and a phase-contrast plate 30a and an analyzer 30b are disposed between the ellipsoidal mirror 24 and the image-forming lens 25.
- Each of the polarizer 32g, the phase-contrast plate 30a and the analyzer 30b is arranged such that its polarization face is rotatable. By setting each of these rotation angles to a predetermined angle, there can be obtained, as a function of visual field angles, physical values such as the ellipticity (tan ⁇ ,) of polarization of the sample, the phase contrast (cos ⁇ ), the rotation direction of the polarization face.
- the polarizer 32g, the phase-contrast plate 30a and the analyzer 30b are so arranged as to be automatically retreated from the optical axis when no polarization characteristics are measured.
Abstract
An apparatus for measuring the intensity of scattered light from a
sample in terms of a function of a scattering angle, comprising an
ellipsoidal mirror (24) for reflecting scattered light from a sample
(23) and concentrating the same, an imaging lens (25) disposed at a
concentration point of the reflected light from the ellipsoidal mirror
(24) and forming an image of the image formed on the surface of the
ellipsoidal mirror (24), and a camera (26) for recording the image
formed by the imaging lens (25), whereby the detection of scattered light
in a range of a wide angle in a very short period of time.
Description
- The present invention relates to an optical angle characteristic measuring apparatus capable of measuring, as a function of the angle, the intensity of light emitted from a sample.
- By irradiating light to a sample and measuring the emitted light for its angle dependency and changes with the passage of time, there can be obtained information of the particles as to sizes, shapes, molecular weights, thermal agitation and the like.
- Apparatus for measuring the angle dependency of emitted light is called an optical angle characteristic measuring apparatus. More precisely, apparatus for measuring the angle dependency of scattered light is called a light scattering intensity measuring apparatus. The light scattering intensity measuring apparatus is arranged such that light is irradiated in one direction to a sample, that a detector for detecting the scattered light is disposed on a goniometer rotatable around the sample, and that the scattered light is detected at a variety of angles with the goniometer rotated.
- However, when it is intended to measure such scattered light in a wide range of angle with the light scattering intensity measuring apparatus, it takes several tens of minutes or more for measurement. This is disadvantageous in time efficiency. Further, measurement cannot disadvantageously be conducted on a sample which undergoes, within the measuring period of time, changes with the passage of time such as association, cohesion or the like.
- For shortening the measuring period of time, it is required to reduce the number of measuring angle points. This sacrifices the data precision.
- Further, to prevent the observation point from deviating when the goniometer is rotated, it is required to design apparatus with very high precision. This disadvantageously requires much labor.
- In this connection, there is developed apparatus for detecting the scattered light with a plurality of detector fixed in an annular manner around the sample. In this apparatus, however, the number of measuring angles is limited to a certain value.
- It is an object of the present invention to provide an optical angle characteristic measuring apparatus for measuring, as a function of the light emitting angle, the intensity of light emitted from a sample, which apparatus is capable of detecting, in a very short period of time, the emitted light in a wide range of angle up to 360°.
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- (1) According to the present invention, an optical angle characteristic measuring apparatus comprises: a reflection mirror for reflecting and condensing the emitted light from a sample; image-forming means disposed at the condensing point of the light reflected from said reflection mirror for forming, on a record face, the image formed on the surface of the reflection mirror; and record means for recording the image formed by the image-forming means. According to the arrangement above-mentioned, the image-forming means can form, on a record face, the image formed on the mirror face of the reflection mirror. Accordingly, the record means can record the intensity pattern of the emitted light.Thus, the apparatus according to the present invention is different in provision of the image-forming means and the record means from the inventions disclosed in Japanese Patent Laid-Open Publications No. H2-223845 and S64-29737 in each of which a reflection mirror is utilized merely as a kind of an integrating sphere.According to the optical angle characteristic measuring apparatus of the present invention, the angle dependency data of emitted light can simultaneously be measured in a very wide angle range without the optical system component elements moved. This remarkably improves the measurement in time efficiency. Accordingly, the apparatus of the present invention can measure a sample, undergoing a change with the passage of time, which has conventionally been measured with difficulty. For example, dynamic scattering characteristics can also be measured.Further, the apparatus of the present invention has no movable members as optical system component elements. This not only improves the measurement in stability and reliability, but also lengthens the lifetime of the apparatus. The number of the optical system component elements is reduced. This is advantageous in view of cost and production efficiency.
- (2) The optical angle characteristic measuring
apparatus of the present invention is preferably arranged
such that the reflection mirror is an ellipsoidal mirror
formed from a portion of the surface of an ellipsoid of
revolution, the sample being disposed in the vicinity of
a first focal point of the ellipsoidal mirror, and the
image-forming means being disposed in the vicinity of a second
focal point of the ellipsoidal mirror.
According to the arrangement above-mentioned, the
image formed on the mirror face of the ellipsoidal mirror
can be formed on the record face in a stigmatic manner.The following description will discuss the operation
of this optical angle characteristic measuring apparatus
with reference to Fig. 1 illustrating a specific arrangement
of the present
invention.A sample 23 is disposed in the vicinity of a first focal point of anellipsoidal mirror 24. Light emitted from thesample 23 is reflected and condensed by theellipsoidal mirror 24 and then incident upon acamera 26 serving as record means through an image-forminglens 25 disposed at a second focal point of the ellipsoidal mirror 24.The image formed on the recording face of thecamera 26 represents the image formed on the mirror face of theellipsoidal mirror 24, and corresponds to the emitting angle at which light is emitted from the sample. It is a remarkable feature that because of the nature of an ellipsoidal mirror, this image is an image formed in a stigmatic manner.Fig. 2 is a view of coordinates illustrating the light emitting angle. As shown in Fig. 2, aplane sample 23 is assumed and the original point is located in a position which serves as the point to be measured on thesample 23. As shown in Fig. 2, there is formed a system of orthogonal coordinates x,y,z in which an angle is formed between the light direction and the y-axis and an angle is formed between the light image projected on the x-z plane and the x-axis. These angles and are called visual field angles. A position on the mirror face of theellipsoidal mirror 24 can be identified by these visual field angles and .Fig. 3 is a projection view of the angles , reflected on the mirror face of theellipsoidal mirror 24. The real image of this projection view is formed on the recording face of thecamera 26 by the operation of the image-forming lens 25.It is therefore possible to measure the optical characteristics of the sample, according to the visual field angles, such as polarization characteristics, scattering angle characteristics, reflectivity data, transmissivity data, luminance data, chromaticity data and the like. Further, the range of the visual field angles is stigmatic and extends widely from 0° to 90° for and from-20° (340° ) to 200° for as shown in Fig. 3.It can be considered that the curvature of theellipsoidal mirror 24 deviates from the ideal one. In this case, the projection view in Fig. 3 becomes different from the calculated distribution. It is therefore required to correct the distribution with the use of a standard sample (for example, a transmission-type grating) of which visual field angles are known. - (3) The reflection mirror may be a spherical mirror formed from a portion of a spherical surface or a conical mirror formed from a portion of a conical surface. In such a case, too, the projection view is different from the calculated distribution. It is therefore required to correct the distribution with the use of a standard sample (for example, a transmission-type grating) of which visual field angles are known. The best advantage of the arrangement above-mentioned is that such spherical or conical mirror can more readily be produced as compared with the ellipsoidal mirror.
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- Fig. 1 is a view illustrating the operation of an optical angle characteristic measuring apparatus according to the present invention;
- Fig. 2 is a view of coordinates illustrating visual field angles;
- Fig. 3 is a projection view reflected on the mirror face of an ellipsoidal mirror;
- Fig. 4 is a schematic view of a light scattering intensity measuring apparatus;
- Fig. 5 is a perspective view of a light scattering intensity measuring apparatus;
- Each of Fig. 6(A) and Fig. 6(B) is a view of an ellipsoidal mirror obtained by cutting an ellipsoid of revolution in a round slice of which inner face serves as a mirror face;
- Fig. 7 is a view illustrating a specific structure of a light scattering intensity measuring apparatus;
- Fig. 8 is a view illustrating the scattered light intensity pattern generated on the camera face of a CCD camera;
- Fig. 9 is a graph illustrating the scattered light intensity pattern as a function of scattering angle ;
- Fig. 10(A) shows a
mirror 6b obtained by cutting a portion of a cone in a round slice, and Fig. 10(B) shows amirror 6c obtained by cutting a portion of a spherical surface in a round slice; - Fig. 11 is a block diagram of a general arrangement of an optical angle characteristic measuring apparatus;
- Fig. 12 is a detailed arrangement view illustrating a first specific example of the optical system for measuring the angle characteristics of a sample of the self light-emitting type;
- Fig. 13 is a detailed arrangement view illustrating a second specific example of the optical system for measuring the angle characteristics of a sample of the reflection type;
- Fig. 14 is a detailed arrangement view illustrating a third specific example of the optical system for measuring the angle characteristics of a sample of the transmission type; and
- Fig. 15 is a detailed arrangement view illustrating a fourth specific example of the optical system for measuring the polarization angle characteristics of a sample of the reflection or transmission type.
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- The following description will discuss in detail preferred embodiments of the present invention with reference to the attached drawings.
- Fig. 4 is a schematic view of a light scattering intensity measuring apparatus according to the present invention.
- The light scattering intensity measuring apparatus comprises a glass-made sample cell 1 for housing a sample to be measured, and a
laser device 5 for projecting a laser beam to the sample cell 1 throughmirrors lenses aperture 3c, aglass window 8 and apinhole 4. The light scattering intensity measuring apparatus further comprises: anellipsoidal mirror 6 for condensing the scattered light from the sample on an image-forminglens 12; anaperture 11 through which reflected light from theellipsoidal mirror 6 passes; the image-forminglens 12; and aCCD camera 13. The image-forminglens 12 is arranged to form, on the camera face of theCCD camera 13, the image formed on the mirror face of theellipsoidal mirror 6. Anabsorbing plate 7 is disposed for absorbing the laser beam which has been transmitted straight through the sample cell 1. The absorbingplate 7 prevents the transmitted laser beam from reflecting and scattering after striking against theglass window 8 and the like. Thepinhole 4, theaperture 3c and theaperture 11 are disposed for cutting excessive stray light around the laser beam, contributing to the formation of a clean laser beam profile. - In Fig. 4, the
laser device 5 is disposed at a position above the sample cell 1 for reasons of drawing a figure in plan elevation. However, as far as light can be incident upon the sample cell 1, the position of thelaser device 5 is not limited to the position shown in Fig. 4. For example, thelaser device 5 can be disposed at a level identical with that at which the sample cell 1 is disposed (In this case, it is a matter of course that the mirror positions are accordingly changed). - Fig. 5 is a perspective view of a general arrangement of a light scattering intensity measuring apparatus in which the
laser device 5 is disposed at a level identical with that at which the sample cell 1 is disposed. Except for the following points (a) and (b), the arrangement in Fig. 5 is the same as the arrangement in Fig. 4. - (a) A
polarizer 41 and ananalyzer 42 are added. - (b) The light incident direction with respect to the sample cell 1 is different by an angle of 90° .
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- The point (a) makes it possible to know the polarization components of the light irradiated to the sample cell 1 and the light scattered from the sample. By evaluating the polarization components, the anisotropy and integrity of the sample can be evaluated. The point (b) is a trivial matter.
- Fig. 6 is a view illustrating the function of the
ellipsoidal mirror 6. Theellipsoidal mirror 6 is obtained by cutting the surface of an ellipsoid of revolution in a round slice of which inner face serves as a mirror face. Because of the nature of the ellipsoid of revolution, light from onefocal point 61 strikes against theellipsoidal mirror 6 and converges on the otherfocal point 62. Theellipsoidal mirror 6 is not always required to be a round circular shape, but may be a partial portion of a round circular piece as shown in Fig. 6(B). It is enough that the mirror is present in the scattering angle range to be measured. - Utilizing the nature of the ellipsoid of revolution, the light scattering intensity measuring apparatus is provided at the one focal point with the sample cell 1 and at the other focal point with the image-forming
lens 12. Accordingly, that portion of the scattered light from the sample cell 1 which has struck against theellipsoidal mirror 6, is reflected thereby and condensed on the image-forminglens 12, and is then incident upon aCCD camera 13. - Fig. 7 shows a view illustrating a specific structure of the light scattering intensity measuring apparatus in Fig. 4. In Fig. 7, there are omitted a laser device for projecting a laser beam to the sample cell 1, a mirror and a condensing lens.
- The sample cell 1 is set in a thermostatic
liquid immersion bath 43 filled with a liquid presenting the refractive index close to the cell. Scattered light from the sample cell 1 is transmitted through aglass window 8, strikes against theellipsoidal mirror 6 and is then reflected thereby. Disposed immediately below the sample cell 1 is aplane mirror 10 by which the light reflected by theellipsoidal mirror 6, is changed in direction. By changing the reflected light in direction, thisplane mirror 10 produces an effect of reducing the height of the entire apparatus. - The light changed in direction by the
plane mirror 10 is incident upon theCCD camera 13 through theaperture 11 and the image-forminglens 12. TheCCD camera 13 uses a light receiving element very high in positional resolution (for example 512 x 512 pixels). This makes it possible to obtain data with high resolution, i.e., the scattering angle of 1° or less as measuring angle resolution. - Fig. 8 shows the scattered light intensity pattern generated on the camera face of the
CCD camera 13. This scattered light pattern is a pattern formed on the mirror face of theellipsoidal mirror 6 in the form of a circular arc shown in Fig. 6(B), and covers the scattering angle range from 5° to 175°. Fig. 9 shows this pattern in the form of a graph in which the axis of abscissa presents the scattering angle . - Thus, without the optical system component elements moved, scattering light intensity data can simultaneously be obtained at optional angles in a wide angle range.
- The present invention should not be limited to the embodiment above-mentioned. That is, other mirror than an ellipsoidal mirror may be used for condensing the scattered light from the sample on the image-forming
lens 12. For example, there may be used, as such a mirror, amirror 6b obtained by cutting a portion of a cone in a round slice as shown in Fig. 10(A), or amirror 6c obtained by cutting a portion of a spherical surface in a round slice as shown in Fig. 10(B). When each of themirrors ellipsoidal mirror 6, is condensed on the other focal point in a stigmatic manner as done with theellipsoidal mirror 6. However, by reducing the width W of each of themirrors mirrors mirrors ellipsoidal mirror 6. - Fig. 11 is a block diagram of a general arrangement of an optical angle characteristic measuring apparatus.
- This optical angle characteristic measuring apparatus has an
optical system 21 comprising an ellipsoidal mirror ofrevolution 24, an image-forminglens 25, acamera 26 andmotors 27 for operating a variety of movable members. - The optical angle characteristic measuring apparatus further comprises: an
illumination light source 32 for generating monochromatic light to be irradiated to a liquidcrystal display element 23 as an example of the sample; anoptical fiber 35 for guiding light of theillumination light source 32 to the optical system 21 (a mirror system can be used instead of the optical fiber 35); acamera control unit 31 for taking image data from thecamera 26 and controlling the parameters such as light exposure time and the like; a liquidcrystal drive unit 33 for generating a signal for driving the liquidcrystal display element 23; amotor controller 34; acomputer 14 for controlling the apparatus in its entirety; adisplay device 15; and akeyboard 16. It is noted that examples of the simple include, in addition to a liquid crystal display element, a light emitting diode, an optical fiber light emitting end, a film, a color filter and the like. - It is assumed that the
illumination light source 32 is a combination of a white-colorillumination light source 32a with amonochromator 32b. The selection of the wavelength of themonochromator 32b is controlled by thecomputer 14 and the like. Instead of themonochromator 32b, there may be used a laser illumination light source, an illumination light source for generating multi-color light instead of monochromatic light, or an illumination light source for generating white-color light such as a halogen lamp, a Xe lamp, a metal halide lamp or the like. More specifically, the type of illumination light source to be used is dependent on the measuring conditions of thesample 23. When the sample is of the self-light-emitting type, theillumination light source 32 may not be used. When a laser illumination light source is used and the emitted light is a linear polarized light, this linear polarized, light may be used as converted, into a circular polarized light with the use of a ¼-wavelength plate such that the polarization characteristics exert no effect on the measurement. - As the
camera 26, there may be used optional means which can store a formed image. For example, there may be used means for converting an image into an electric signal such as a CCD camera, or means for chemically recording an image on a film such as an optical camera. In Fig. 11, it is assumed that a CCD camera is used. - The
motors 27 and themotor controller 34 are disposed for controlling the posture of thesample 23 and for rotating, moving and operating a variety of optical elements such as the shaft for irradiating light to thesample 23, a polarizer, an analyzer, a phase-contrast plate and the like. - Fig. 12 is a detailed arrangement view illustrating a first specific example of the
optical system 21. In this first example, it is assumed that the liquidcrystal display element 23 is of the self light-emitting type. An illumination light source is not used for the liquidcrystal display element 23 and is therefore not shown in Fig. 12. - The
optical system 21 comprises: astage 28 on and by which thesample 23 is placed and held in an optional posture; an ellipsoidal mirror ofrevolution 24 for condensing, on the second focal point, the light emitted from thesample 23 disposed in the vicinity of the first focal point; anaperture 29 through which the light reflected by the ellipsoidal mirror ofrevolution 24 passes; an image-forminglens 25 disposed at the second focal point of the ellipsoidal mirror ofrevolution 24 for forming the image formed on the surface of the ellipsoidal mirror ofrevolution 24; and acamera 26 for recording the image formed by the image-forminglens 25. An optical filter may be disposed in front of thecamera 26. Examples of the optical filter include a wavelength cutting filter for eliminating the wavelength unnecessary for measurement, a Y-view sensitivity filter for approximating the camera sensitivity to the sensitivity of the human eyes, a light attenuating filter for attenuating the light from the sample, and the like. Further, there may be selected and disposed a tristimulus-value filter for measuring chromaticity and brightness. - There is used the ellipsoidal mirror of
revolution 24 having a first focal distance f1 of 55 mm and a second focal distance f2 of 600 mm. A space of 8 mm is assured as the distance between thesample 23 and the lower end surface of the ellipsoidal mirror ofrevolution 24. It is therefore not required to use special attention for placing thesample 23. - Fig. 13 is a detailed arrangement view illustrating a second specific example of the
optical system 21. In the second example, anillumination light source 32 for irradiating light to a liquidcrystal display element 23 is used to measure the reflectivity. - This illumination
light source 32 comprises alight source 32h, alens 32c movable on the optical axis, aniris diaphragm 32d disposed at the light emitting side of thelens 32c, and areflection mirror 32e for projecting the light from thelight source 32h, on the first focal point of the ellipsoidal mirror ofrevolution 24. In Fig. 13, thereflection mirror 32e is positioned such that light from thelight source 32h is projected on that point of the ellipsoidal mirror ofrevolution 24 which is located immediately above (=0) its first focal point. However, thereflection mirror 32e can be changed in position and angle such that light from thelight source 32h is projected on the ellipsoidal mirror ofrevolution 24 in the range from 0° to several tens of degree. - The
lens 32c serves as an adjusting member for condensing the spot of the illumination light source on thesample 23 or on the point of infinity. The spot diameter is minimized when thelens 32c is positioned such that the virtual image of the light source is formed at the position of the second focal point of the ellipsoidal mirror. The opening angle of the illumination light is adjusted by theiris diaphragm 32d. - A
light attenuating filter 32f is disposed at the position of regular reflection (In Fig. 13, thelight attenuating filter 32f is hidden behind the shadow of thereflection mirror 32e because the angle at which the illumination light is incident upon the sample, is 0° ). Thelight attenuating filter 32f serves as a filter (ND filter) for attenuating the light regularly reflected from thesample 23. Such light attenuation reduces the regular reflection component and assures a dynamic range for measurement of a diffusion component. - Fig. 14 is a detailed arrangement view illustrating a third specific example of the
optical system 21. In this third example, there is disposed theillumination light source 32 for transmittably illuminating the liquidcrystal display element 23 from below. - For transmittably illuminating the liquid
crystal display element 23 from below, anellipsoidal mirror 24a is disposed below thestage 28. Together with the light condensingellipsoidal mirror 24, thisellipsoidal mirror 24a is cut out from a single ellipsoidal mirror. Therefore, the ellipsoidal mirrors 24, 24a have the same focal distances f1, f2. This does not involve the likelihood that the focal points are positionally shifted from each other. In this third example, theillumination light source 32 used in Fig. 13 is used as rotated by an angle of 180° in the opposite direction. By this arrangement, both transmissivity and reflexibility can be measured with oneillumination light source 32. This achieves a compact and economical optical angle characteristic measuring apparatus. - In transmissivity measurement, too, when a direct transmitted light is strong, the
light attenuating filter 32f is used to assure a dynamic range for measuring a diffusion component. - Fig. 15 is a detailed arrangement view illustrating a fourth specific example of the
optical system 21. This fourth example is arranged to measure the polarization characteristics of the liquidcrystal display element 23. The reflectivity polarization characteristics can be measured when theillumination light source 32 is located in the position of solid lines, and the transmissivity polarization characteristics can be measured when theillumination light source 32 is located in the position of broken lines. - The
illumination light source 32 has apolarizer 32g, and a phase-contrast plate 30a and ananalyzer 30b are disposed between theellipsoidal mirror 24 and the image-forminglens 25. Each of thepolarizer 32g, the phase-contrast plate 30a and theanalyzer 30b is arranged such that its polarization face is rotatable. By setting each of these rotation angles to a predetermined angle, there can be obtained, as a function of visual field angles, physical values such as the ellipticity (tan ,) of polarization of the sample, the phase contrast (cos Δ), the rotation direction of the polarization face. - The
polarizer 32g, the phase-contrast plate 30a and theanalyzer 30b are so arranged as to be automatically retreated from the optical axis when no polarization characteristics are measured.
Claims (9)
- An optical angle characteristic measuring apparatus capable of measuring the angle distribution of the intensity of light emitted from a sample, comprising:a reflection mirror for reflecting and condensing the emitted light from a sample;image-forming means disposed at the condensing point of the light reflected from said reflection mirror for forming, on a record face, the image formed on the surface of said reflection mirror; andrecord meant for recording said image formed by said image-forming means.
- An optical angle characteristic measuring apparatus according to Claim 1, further comprising an illumination light source for illuminating light to the sample.
- An optical angle characteristic measuring apparatus according to Claim 2, wherein said illumination light source is a monochromator capable of changing the wavelength of light to be illuminated to the sample.
- An optical angle characteristic measuring apparatus according to Claim 2, wherein said illumination light source is a reflection illumination light source.
- An optical angle characteristic measuring apparatus according to Claim 2, wherein said illumination light source is a transmission illumination light source.
- An optical angle characteristic measuring apparatus according to Claim 2, further comprising a polarizer capable of changing the polarization face of light illuminated from said illumination light source, and an analyzer for detecting the polarization of emitted light from the sample.
- An optical angle characteristic measuring apparatus according to Claim 1, whereinsaid reflection mirror is an ellipsoidal mirror formed from a portion of the surface of an ellipsoid of revolution,the sample being disposed in the vicinity of a first focal point of said ellipsoidal mirror, and said image-forming means being disposed in the vicinity of a second focal point of said ellipsoidal mirror.
- An optical angle characteristic measuring apparatus according to Claim 7, further comprising an illumination light source (32) for illuminating light to said sample through the use of reflection by said ellipsoidal mirror.
- An optical angle characteristic measuring apparatus according to Claim 1, wherein said reflection mirror is a spherical minor formed from a portion of a spherical surface, or a conical mirror formed from a portion of a conical surface.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31875997 | 1997-11-19 | ||
JP31875997A JP3234183B2 (en) | 1997-11-19 | 1997-11-19 | Light scattering intensity measuring device |
JP31875897 | 1997-11-19 | ||
JP31875897A JP3231268B2 (en) | 1997-11-19 | 1997-11-19 | Optical viewing angle measuring device |
PCT/JP1998/005232 WO1999026054A1 (en) | 1997-11-19 | 1998-11-19 | Apparatus for measuring characteristics of optical angle |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1035408A1 true EP1035408A1 (en) | 2000-09-13 |
Family
ID=26569499
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98954767A Withdrawn EP1035408A1 (en) | 1997-11-19 | 1998-11-19 | Apparatus for measuring characteristics of optical angle |
Country Status (8)
Country | Link |
---|---|
US (1) | US6636308B1 (en) |
EP (1) | EP1035408A1 (en) |
KR (1) | KR20010032235A (en) |
CN (1) | CN1170139C (en) |
AU (1) | AU753282B2 (en) |
CA (1) | CA2310625A1 (en) |
TW (1) | TW388788B (en) |
WO (1) | WO1999026054A1 (en) |
Cited By (1)
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WO2000058713A2 (en) * | 1999-03-31 | 2000-10-05 | Semiconductor 300 Gmbh & Co. Kg | Device for rapidly measuring angle-dependent diffraction effects on finely structured surfaces |
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US7649628B2 (en) * | 2004-10-08 | 2010-01-19 | Koninklijke Philips Electronics N.V. | Optical inspection of test surfaces |
JP2007005347A (en) | 2005-06-21 | 2007-01-11 | Tokyo Electron Ltd | Heat-treating apparatus |
JP5721070B2 (en) * | 2011-03-08 | 2015-05-20 | 国立研究開発法人産業技術総合研究所 | Optical property measuring device |
CN102243175A (en) * | 2011-06-21 | 2011-11-16 | 北京航空航天大学 | Surface plasma resonance light detection device based on ellipsoidal reflector light collection structure |
TW201326778A (en) * | 2011-12-30 | 2013-07-01 | Metal Ind Res & Dev Ct | Optical measurement aid with elliptical curved surface structure and optical measurement system |
CN103091847B (en) * | 2013-01-15 | 2015-03-04 | 北京工业大学 | Method of focusing high-power direct semiconductor lasers with non-spherical mirror |
US9619878B2 (en) | 2013-04-16 | 2017-04-11 | Kla-Tencor Corporation | Inspecting high-resolution photolithography masks |
US9759668B2 (en) * | 2013-08-09 | 2017-09-12 | University Of Calcutta | Systems and methods for liquid quality assessment |
US9921144B2 (en) * | 2016-06-29 | 2018-03-20 | Honeywell International Inc. | Particulate matter detector |
JP6961406B2 (en) * | 2017-07-05 | 2021-11-05 | 大塚電子株式会社 | Optical measuring device and optical measuring method |
KR20200068541A (en) * | 2018-03-12 | 2020-06-15 | 오르보테크 엘티디. | Optical system for automated optical inspection |
CN108956093B (en) * | 2018-06-22 | 2020-06-30 | 维沃移动通信有限公司 | Detection method of infrared scattering device and mobile terminal |
CN109073549A (en) * | 2018-06-28 | 2018-12-21 | 深圳市汇顶科技股份有限公司 | Scatter angle measuring device and scattering angle measuring method |
CN109612690A (en) * | 2018-11-02 | 2019-04-12 | 中国科学院上海光学精密机械研究所 | Sensitive chip different incidence angles responsiveness measuring device and measuring method |
TWI683087B (en) * | 2018-11-09 | 2020-01-21 | 志聖工業股份有限公司 | Measurement apparatus for exposure angle |
CN111198093B (en) * | 2018-11-16 | 2021-11-26 | 志圣工业股份有限公司 | Exposure light angle measuring equipment |
CN109540035B (en) * | 2019-01-14 | 2020-03-06 | 吉林大学 | Illumination-adjustable automobile panoramic vision detection system based on elliptical reflection ring |
CN110553955B (en) * | 2019-08-30 | 2020-11-24 | 华中科技大学 | Particle size distribution measuring method and system based on light scattering field |
CN110715930A (en) * | 2019-10-21 | 2020-01-21 | 中国科学院光电技术研究所 | Precise optical surface weak defect microscopic illumination method and device |
CN114609058B (en) * | 2022-05-11 | 2022-08-30 | 中国海洋大学 | Multispectral shipborne navigation measuring device for sea water body scattering |
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- 1998-11-19 CN CNB988112604A patent/CN1170139C/en not_active Expired - Fee Related
- 1998-11-19 AU AU11749/99A patent/AU753282B2/en not_active Ceased
- 1998-11-19 CA CA002310625A patent/CA2310625A1/en not_active Abandoned
- 1998-11-19 KR KR1020007005436A patent/KR20010032235A/en not_active Application Discontinuation
- 1998-11-19 WO PCT/JP1998/005232 patent/WO1999026054A1/en not_active Application Discontinuation
- 1998-11-19 EP EP98954767A patent/EP1035408A1/en not_active Withdrawn
- 1998-11-19 US US09/554,687 patent/US6636308B1/en not_active Expired - Fee Related
- 1998-11-19 TW TW087119164A patent/TW388788B/en active
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2000058713A2 (en) * | 1999-03-31 | 2000-10-05 | Semiconductor 300 Gmbh & Co. Kg | Device for rapidly measuring angle-dependent diffraction effects on finely structured surfaces |
WO2000058713A3 (en) * | 1999-03-31 | 2001-02-01 | Semiconductor 300 Gmbh & Co Kg | Device for rapidly measuring angle-dependent diffraction effects on finely structured surfaces |
US6724475B2 (en) | 1999-03-31 | 2004-04-20 | Infineon Technologies Ag | Apparatus for rapidly measuring angle-dependent diffraction effects on finely patterned surfaces |
Also Published As
Publication number | Publication date |
---|---|
AU1174999A (en) | 1999-06-07 |
CN1170139C (en) | 2004-10-06 |
WO1999026054A1 (en) | 1999-05-27 |
US6636308B1 (en) | 2003-10-21 |
KR20010032235A (en) | 2001-04-16 |
TW388788B (en) | 2000-05-01 |
CN1279763A (en) | 2001-01-10 |
CA2310625A1 (en) | 1999-05-27 |
AU753282B2 (en) | 2002-10-17 |
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