EP1028637B1 - Cigarette with reduced gas phase - Google Patents

Cigarette with reduced gas phase Download PDF

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Publication number
EP1028637B1
EP1028637B1 EP97951904A EP97951904A EP1028637B1 EP 1028637 B1 EP1028637 B1 EP 1028637B1 EP 97951904 A EP97951904 A EP 97951904A EP 97951904 A EP97951904 A EP 97951904A EP 1028637 B1 EP1028637 B1 EP 1028637B1
Authority
EP
European Patent Office
Prior art keywords
filter
cigarette
string
paper
mouth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97951904A
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German (de)
French (fr)
Other versions
EP1028637A1 (en
Inventor
Edgar Mentzel
Henning Seidel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reemtsma Cigarettenfabriken GmbH
Original Assignee
Reemtsma Cigarettenfabriken GmbH
HF and PhF Reemtsma GmbH and Co
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Publication date
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Application filed by Reemtsma Cigarettenfabriken GmbH, HF and PhF Reemtsma GmbH and Co filed Critical Reemtsma Cigarettenfabriken GmbH
Priority to SI9730409T priority Critical patent/SI1028637T1/en
Priority to PT97951904T priority patent/PT1028637E/en
Publication of EP1028637A1 publication Critical patent/EP1028637A1/en
Application granted granted Critical
Publication of EP1028637B1 publication Critical patent/EP1028637B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/043Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/163Carbon

Definitions

  • the invention relates to a cigarette according to the preamble of Claim 1.
  • the object of the invention is a cigarette with a gas phase active Develop filters that are very efficient and at the same time is inexpensive to manufacture.
  • the cigarette paper porosity lies in the filter cigarette according to the invention 30 to 60% rel. higher than the cigarette paper porosity one made with a conventional filter comparable cigarette and the degree of filter ventilation is 10 up to 60% rel. lower than the filter ventilation level one with conventional filter manufactured comparable cigarette.
  • the tissue paper has a basis weight of approx. 40 - 60 g / m 2 , an activated carbon content of 15 - 50% and a thickness of 150 200 ⁇ m.
  • a preferred variant has a weight per unit area of 50 g / m 2 and an activated carbon content of 30% by weight with a thickness of 180 ⁇ m.
  • the strand side Filter part of the double filter is a core filter according to DE 42 05 658 C2, in which the core of carbon-containing tissue paper as in the first-mentioned embodiment is formed by a Jacket made of almost impermeable to the main current smoke Material is surrounded.
  • This almost smoke-proof material consists, for example, of highly compressed cellulose acetate fibers.
  • the cigarettes C and D differed in the same way in the reactivity, whereby the tobacco flavor of variant D is stronger was pronounced.
  • the mouth-side filter part in addition to the known acetate monofilter:
  • a coaxial construction of the mouth-side filter part is known to offer the possibility of simultaneously providing the desired retention and the desired open tensile resistance Optimally adjust cigarette independently.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Colloid Chemistry (AREA)
  • Vending Machines For Individual Products (AREA)
  • Glass Compositions (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacture Of Tobacco Products (AREA)

Abstract

The invention relates to a cigarette with a filter containing activated carbon. Said cigarette comprises a tobacco string wrapped in cigarette paper, a double filter having a string-side part consisting of a tissue paper containing carbon, and a peripherally extending filter ventilation zone and located in the mouth-side part made of cellulose acetate. The tissue paper of the string-side filter part is a very bulky paper which contains 20 to 50 % wt microfine powdered active carbon. The ratio of condensate retention capacities of the string-side filter part to the mouth-side filter part ranges from 1 to 2. The air permeability of the cigarette paper is comprised between 40 and 100 Coresta units and the filter ventilation grade is comprised between 5 and 60 %.

Description

Die Erfindung betrifft eine Cigarette gemäß Oberbegriff des Patentanspruchs 1.The invention relates to a cigarette according to the preamble of Claim 1.

Es ist bekannt, daß durch Einbringen oberflächenreicher Materialien in einen Filter wie z. B. Aktivkohle ein Teil der gasförmigen Rauchbestandteile aus dem Rauch retiniert werden kann. Eine derartige selektive Retention führt zu nicht gewünschten geschmacklichen Veränderungen und damit zur Ablehnung solcher Produkte beim Raucher. Versuche, diese negative Begleiterscheinung zu kompensieren, sind sehr aufwendig, siehe auch DE 41 05 500, kompliziert und kostenintensiv.It is known that by introducing surface-rich materials into a filter such as B. activated carbon part of the gaseous Components of smoke from which smoke can be retained. A such selective retention leads to undesirable ones changes in taste and thus to reject such Products for smokers. Try this negative side effect to compensate are very complex, see also DE 41 05 500, complicated and expensive.

Herkömmliche gasphasenaktive Filter sind in der Mehrzahl Kammerfilter, die in drei Segmente unterteilt sind und in der mittleren Kammer ein oberflächenaktives Material wie z. B. Aktivkohle, Meerschaum, Silicagel usw. enthalten. Diese Systeme sind von der Darstellung her sehr teuer und haben einen gravierenden Nachteil, daß die Kammerstabilität im Hinblick auf das Zusammendrücken während des Rauchens unbefriedigend ist. Andere Lösungsmöglichkeiten sind Doppelfilterkonstruktionen, bei denen die Aktivkohle in geringen Mengen in das tabakstockseitige Filterelement eingestreut werden. Diese Konstruktionen haben nur eine begrenzte und für viele Anwendungsmöglichkeiten nicht ausreichende Gasphasenreduzierung. Allen bekannten Konstruktionen gemein ist die negative geschmackliche Veränderung, die der Raucher als Kohlegeschmack artikuliert.Conventional gas phase active filters are in the majority Chamber filters, which are divided into three segments and in the middle chamber a surface active material such. B. Activated carbon, meerschaum, silica gel etc. included. These systems are very expensive from the viewpoint and have a serious Disadvantage that the chamber stability with regard to the Squeezing while smoking is unsatisfactory. Other Possible solutions are double filter designs in which the activated carbon in small quantities in the tobacco rod side Filter element can be sprinkled. These constructions only have a limited and not for many applications sufficient gas phase reduction. All known constructions what is common is the negative change in taste that the Smokers articulated as a coal flavor.

Eine deutliche, aber noch nicht zufriedenstellende Verbesserung zeigte sich bei der Verwendung eines kohlehaltigen Tissuepapieres, das mit mikrofein gemahlener Kohle (Korngröße < 15 µm) versetzt war. A clear but not yet satisfactory improvement showed up when using a carbonaceous tissue paper, that with microfine coal (grain size <15 µm) was offset.

Aufgabe der Erfindung ist es, eine Cigarette mit einem gasphasenaktiven Filter zu entwickeln, der sehr effizient und gleichzeitig kostengünstig herstellbar ist.The object of the invention is a cigarette with a gas phase active Develop filters that are very efficient and at the same time is inexpensive to manufacture.

Zur Lösung dieser Aufgabe dienen die Merkmale des Patentanspruchs 1.The features of the claim serve to solve this problem 1.

Die Erfindung betrifft also eine Filtercigarette mit einem Aktivkohle enthaltenden Filter mit:

  • a) einem durch ein Cigarettenpapier umgebenen Tabakstrang;
  • b) einem Doppelfilter, bei dem der strangseitige Teil aus einem kohlehaltigen Tissuepapier besteht, und mit
  • c) einer in Umfangsrichtung verlaufenden Filter-Ventilationszone im mundseitigen Teil aus Celluloseacetat;
  • d) das Tissuepapier des strangseitigen Filterteils ist ein sehr voluminöses Papier, das 20 bis 50 Gew.-% mikrofein gemahlene Aktivkohle enthält;
  • e) das Verhältnis der Kondensat-Retentionsleistungen von strangseitigem zu mundseitigem Filterteil beträgt zwischen 1 und 2;
  • f) die Luftdurchlässigkeit des Cigarettenpapiers beträgt 40 bis 100 Coresta-Einheiten; und
  • g) der Filterventilationsgrad beträgt 5 bis 60 %.
  • The invention thus relates to a filter cigarette with a filter containing activated carbon with:
  • a) a tobacco rod surrounded by a cigarette paper;
  • b) a double filter, in which the strand-side part consists of a carbon-containing tissue paper, and with
  • c) a circumferential filter ventilation zone in the mouth-side part made of cellulose acetate;
  • d) the tissue paper of the strand-side filter part is a very voluminous paper which contains 20 to 50% by weight of microfine ground activated carbon;
  • e) the ratio of the condensate retention performances of the strand-side to the mouth-side filter part is between 1 and 2;
  • f) the air permeability of the cigarette paper is 40 to 100 Coresta units; and
  • g) the degree of filter ventilation is 5 to 60%.
  • Vorteilhafte Ausgestaltungen der Erfindung sind Gegenstände der Unteransprüche.Advantageous embodiments of the invention are the subject of Dependent claims.

    Bei der erfindungsgemäßen Filtercigarette liegt die Cigarettenpapier-Porosität 30 bis 60 % rel. höher als die Cigarettenpapier-Porosität einer mit konventionellem Filter hergestellten vergleichbaren Cigarette und der Filterventilationsgrad ist 10 bis 60 % rel. niedriger als der Filterventilationsgrad einer mit konventionellem Filter hergestellten vergleichbaren Cigarette.The cigarette paper porosity lies in the filter cigarette according to the invention 30 to 60% rel. higher than the cigarette paper porosity one made with a conventional filter comparable cigarette and the degree of filter ventilation is 10 up to 60% rel. lower than the filter ventilation level one with conventional filter manufactured comparable cigarette.

    Das Tissuepapier hat ein Flächengewicht von ca. 40 - 60 g/m2, einen Aktivkohlegehalt von 15 - 50 % und eine Dicke von 150 200 µm. Eine bevorzugte Variante hat ein Flächengewicht von 50 g/m2 und einen Aktivkohlegehalt von 30 Gew.-% bei einer Dicke von 180 µm.The tissue paper has a basis weight of approx. 40 - 60 g / m 2 , an activated carbon content of 15 - 50% and a thickness of 150 200 µm. A preferred variant has a weight per unit area of 50 g / m 2 and an activated carbon content of 30% by weight with a thickness of 180 μm.

    In einer besonderen Ausführungsform ist der strangseitige Filterteil des Doppelfilters ein Core-Filter gemäß DE 42 05 658 C2, bei dem der Kern aus kohlehaltigem Tissuepapier wie bei der zuerst genannten Ausführungsform gebildet ist, der von einem Mantel aus für den Hauptstromrauch nahezu undurchlässigem Material umgeben ist. Dieses nahezu rauchundurchlässige Material besteht beispielsweise aus stark verdichteten Celluloseacetatfasern.In a special embodiment, the strand side Filter part of the double filter is a core filter according to DE 42 05 658 C2, in which the core of carbon-containing tissue paper as in the first-mentioned embodiment is formed by a Jacket made of almost impermeable to the main current smoke Material is surrounded. This almost smoke-proof material consists, for example, of highly compressed cellulose acetate fibers.

    Überraschenderweise hat sich gezeigt, daß bei Einsatz des gasphasenaktiven Materials nicht allein die Gasphasenretention, sondern die spezifischen Retentionsverhältnisse der einzelnen Filtersegmente in Kombination mit den Ventilationsverhältnissen der Cigarette von entscheidendem Einfluß sind. Als besonders günstig haben sich die in der Tabelle 1 dargestellten Kombinationen B, D und F der Retentions- und Ventilationsverhältnisse herausgestellt. Die Kombinationen A, C und E sind bekannte Cigaretten, die durch die Kombinationen B, D und F erfindungsgemäß angewandelt wurden.Surprisingly, it has been shown that when using the gas phase-active material not only the gas phase retention, but the specific retention ratios of the individual Filter segments in combination with the ventilation conditions the cigarette are of decisive influence. As special those shown in Table 1 have proved favorable Combinations B, D and F of the retention and ventilation ratios exposed. The combinations A, C and E are known Cigarettes according to the invention by combinations B, D and F were changed.

    Die sensorischen Vergleiche wurden von einem Expertenpanel durchgeführt und ergaben folgende Resultate: Die Cigaretten A und B unterschieden sich nur in dem Punkt Reaktivität, wobei die Variante B signifikant weniger reaktiv, d. h. für den Konsumenten übersetzt weniger rauh und weniger scharf war.The sensory comparisons were made by an expert panel carried out and gave the following results: The cigarettes A and B differed only in the point of reactivity, the Variant B significantly less reactive, i. H. for the consumer translated less rough and less sharp.

    Die Cigaretten C und D unterschieden sich in gleicher Weise in der Reaktivität, wobei das Tabakaroma der Variante D stärker ausgeprägt war. The cigarettes C and D differed in the same way in the reactivity, whereby the tobacco flavor of variant D is stronger was pronounced.

    Zum gleichen Ergebnis kamen die Experten auch bei dem Cigarettenvergleich von E und F. Die F-Variante war deutlich geringer reaktiv, hatte aber ein erhöhtes Tabakaroma.The experts came to the same result when comparing cigarettes of E and F. The F variant was significantly lower reactive, but had an increased tobacco aroma.

    Auffällig ist, daß der Retentionsquotient der Einzelfiltersegmente mit abnehmendem Kondensat- und Nikotinwert größer wird. Gleichzeitig ist es notwendig, zur Erzielung der mindestens gleichen Tabakaromaqualität die Cigarettenpapierporosität der jeweiligen Vergleichscigarette zu erhöhen bei gleichzeitiger Reduzierung der Filterventilation. Eine Ursache für die relative Besserstellung der Aromaqualität könnten hier die Partikelgrößenverteilung des Hauptstromrauches sein, die maßgeblich durch unterschiedliche Strömungsgeschwindigkeiten und damit unterschiedlichen Verglimmungstemperaturen des Tabaks beeinflußt werden. Versuche haben gezeigt, wenn man die Versuchs- und Vergleichscigaretten strömungsmäßig aneinander anpaßt, daß der sog. Kohlegeschmack und ein Abfall in der Aromaqualität eintritt.It is striking that the retention quotient of the individual filter segments increases with decreasing condensate and nicotine levels. At the same time, it is necessary to achieve the minimum same tobacco flavor quality the cigarette paper porosity of to increase respective comparison cigarette at the same time Reduction of filter ventilation. A cause of the relative The particle size distribution could improve the aroma quality of the main stream smoke, which is largely due to different flow velocities and therefore different The smoldering temperatures of the tobacco are affected become. Experiments have shown, if you compare the experimental and Comparative flow cigarettes adapts to each other that the so-called coal taste and a decrease in aroma quality occurs.

    Zur Einstellung des gewünschten Retentionsverhältnisses von stangseitigem zu mundseitigem Filterteil können für den mundseitigen Filterteil neben dem bekannten Acetat-Monofilter auch andere bekannte Ausführungsformen eingesetzt werden: Beispielsweise bietet eine koaxiale Konstruktion des mundseitigen Filterteils bekanntermaßen die Möglichkeit, gleichzeitig die gewünschte Retention und den gewünschten offenen Zugwiederstand der Cigarette unabhängig voneinander optimal einzustellen. Full Flavor Lights Ultra low tar A B C D E F Gesamtlänge [mm] 84 84 84 84 84 84 Länge Tabakstrang [mm] 63 63 59 59 59 59 Länge Filter [mm] 21 21 25 25 25 25 Gewicht Tabakstrang [mg] 820 820 690 690 620 620 Zugwiderstand [daPa] 75 75 140 Filter-Typ Monofilter Doppelfilter Monofilter Doppelfilter Monofilter Doppelfilter Filtermaterial Celluloseacetat Celluloseacetat Celluloseacetat Einzeldenier 3,0 y 2,1 y Gesamidenier 35.000 55.000 Hersteller Rhodia Rhodia strangseitiges Element :    Länge [mm] 13 13 13    Zugwiderstand [daPa] 13 65 97    Material Kohlepapier Kohlepapier Kohlepapier mundseitiges Element :    Länge [mm] 8 12 12    Zugwiderstand [daPa] 24 28 33    Material Celluloseacetat Celluloseacetat Celluloseacetat    Einzeldenier 2,5 y 3,04 y 2,54 y    Gesamtdenier 35.000 35.000 35.000 Kondensat [mg/Cig.] 12,2 12,0 7,2 7,0 2,3 2,0 Nicotin [mg/Cig.] 0,80 0,83 0,64 0,66 0,22 0,24 Papierporosität [Coresta] 24 43 60 80 40 80 Filterventilation [%] 20 17 40 35 70 60 Gesamtretention [%] 38 38 50 50 70 70 Einzelretention [%]    (strangseitig) 19 28 45    (mundseitig) 19 22 25 Retentionskoeffizient 1 1,27 1,8    (Strang/Mund) To set the desired retention ratio of the rod-side to the mouth-side filter part, other known embodiments can be used for the mouth-side filter part in addition to the known acetate monofilter: For example, a coaxial construction of the mouth-side filter part is known to offer the possibility of simultaneously providing the desired retention and the desired open tensile resistance Optimally adjust cigarette independently. Full flavor Lights Ultra low tar A B C D e F Total length [mm] 84 84 84 84 84 84 Length of tobacco rod [mm] 63 63 59 59 59 59 Filter length [mm] 21 21 25 25 25 25 Weight of tobacco rod [mg] 820 820 690 690 620 620 Tensile resistance [daPa] 75 75 140 Filter type Monofilter double filter Monofilter double filter Monofilter double filter filter material cellulose acetate cellulose acetate cellulose acetate Einzeldenier 3.0 y 2.1 y Gesamidenier 35,000 55,000 Manufacturer Rhodia Rhodia strand-side element: Length [mm] 13 13 13 Tensile resistance [daPa] 13 65 97 material carbon paper carbon paper carbon paper mouth-side element: Length [mm] 8th 12 12 Tensile resistance [daPa] 24 28 33 material cellulose acetate cellulose acetate cellulose acetate Einzeldenier 2.5 y 3.04 y 2.54 y total denier 35,000 35,000 35,000 Condensate [mg / cig.] 12.2 12.0 7.2 7.0 2.3 2.0 Nicotine [mg / cig.] 0.80 0.83 0.64 0.66 0.22 0.24 Paper porosity [Coresta] 24 43 60 80 40 80 Filter ventilation [%] 20 17 40 35 70 60 Total retention [%] 38 38 50 50 70 70 Individual retention [%] (Line side) 19 28 45 (Mouth side) 19 22 25 retention coefficient 1 1.27 1.8 (Train / mouth)

    Claims (3)

    1. A filter cigarette having a filter containing activated carbon, having:
      a) a tobacco string surrounded by a cigarette paper;
      b) a double filter, in which the string-side part is made from a tissue paper containing carbon, and having
      c) a filter ventilation zone extending in the peripheral direction and located in the mouth-side part made from cellulose acetate;
      d) the tissue paper of the string-side filter part is a very bulky paper which contains 20 to 50 % by weight microfine powdered activated carbon;
      e) the ratio of the condensate retention capacities of the string-side filter part to the mouth-side filter part is between 1 and 2;
      f) the air permeability of the cigarette paper is 40 to 100 Coresta units; and
      g) the filter ventilation grade is 5 to 60 %.
    2. A filter cigarette according to Claim 1,
      characterised in that the tissue paper of the string-side filter part contains 30 % by weight microfine powdered activated carbon.
    3. A filter cigarette according to Claim 1 or 2,
      characterised in that the string-side part of the filter is a core filter having a core made from tissue paper containing carbon in accordance with one of the preceding Claims, which is surrounded by a casing made from material which is virtually impermeable for the main smoke flow.
    EP97951904A 1997-11-13 1997-11-13 Cigarette with reduced gas phase Expired - Lifetime EP1028637B1 (en)

    Priority Applications (2)

    Application Number Priority Date Filing Date Title
    SI9730409T SI1028637T1 (en) 1997-11-13 1997-11-13 Cigarette with reduced gas phase
    PT97951904T PT1028637E (en) 1997-11-13 1997-11-13 CIGARETTES WITH REDUCED GASEOUS PHASE

    Applications Claiming Priority (1)

    Application Number Priority Date Filing Date Title
    PCT/EP1997/006390 WO1999025210A1 (en) 1997-11-13 1997-11-13 Cigarette with reduced gas phase

    Publications (2)

    Publication Number Publication Date
    EP1028637A1 EP1028637A1 (en) 2000-08-23
    EP1028637B1 true EP1028637B1 (en) 2002-07-24

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    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP97951904A Expired - Lifetime EP1028637B1 (en) 1997-11-13 1997-11-13 Cigarette with reduced gas phase

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    EP (1) EP1028637B1 (en)
    JP (1) JP3387055B2 (en)
    KR (1) KR20010032084A (en)
    AT (1) ATE220862T1 (en)
    BG (1) BG63987B1 (en)
    DE (1) DE59707821D1 (en)
    DK (1) DK1028637T3 (en)
    EA (1) EA001556B1 (en)
    EE (1) EE200000264A (en)
    ES (1) ES2179383T3 (en)
    HK (1) HK1035472A1 (en)
    HU (1) HU228293B1 (en)
    SK (1) SK283397B6 (en)
    TR (1) TR200001355T2 (en)
    UA (1) UA49097C2 (en)
    WO (1) WO1999025210A1 (en)

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    WO1999025210A1 (en) * 1997-11-13 1999-05-27 H.F. & Ph.F. Reemtsma Gmbh Cigarette with reduced gas phase
    DE102005005175A1 (en) * 2005-02-01 2006-08-10 Reemtsma Cigarettenfabriken Gmbh Filter cigarette
    GB0619958D0 (en) * 2006-10-09 2006-11-15 Filtrona Int Ltd Tobacco smoke filter
    DE102009016148A1 (en) * 2009-04-03 2010-10-14 Mcairlaid's Vliesstoffe Gmbh & Co. Kg Filter material for cleaning air and gases
    KR20230056843A (en) * 2021-10-20 2023-04-28 주식회사 케이티앤지 Cigarette filter and cigarette comprising thereof

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    US5365951A (en) * 1990-08-24 1994-11-22 Philip Morris Incorporated Concentric smoking filter having cellulose acetate tow periphery and carbon-particle-loaded web filter core
    DE4105500C1 (en) 1991-02-19 1992-06-17 H.F. & Ph.F. Reemtsma Gmbh & Co, 2000 Hamburg, De
    GB9214267D0 (en) * 1992-07-04 1992-08-19 British American Tobacco Co Improvements relating to smoking articles
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    Publication number Publication date
    ES2179383T3 (en) 2003-01-16
    HK1035472A1 (en) 2001-11-30
    HU228293B1 (en) 2013-08-28
    DK1028637T3 (en) 2002-11-11
    WO1999025210A1 (en) 1999-05-27
    BG104522A (en) 2001-01-31
    EP1028637A1 (en) 2000-08-23
    EE200000264A (en) 2001-06-15
    ATE220862T1 (en) 2002-08-15
    JP2001522616A (en) 2001-11-20
    SK283397B6 (en) 2003-07-01
    HUP0100096A2 (en) 2001-05-28
    HUP0100096A3 (en) 2001-06-28
    SK6942000A3 (en) 2000-10-09
    UA49097C2 (en) 2002-09-16
    DE59707821D1 (en) 2002-08-29
    KR20010032084A (en) 2001-04-16
    JP3387055B2 (en) 2003-03-17
    EA200000507A1 (en) 2000-10-30
    BG63987B1 (en) 2003-09-30
    EA001556B1 (en) 2001-04-23
    TR200001355T2 (en) 2000-09-21

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