EP0989227B1 - Verfahren zur Behandlung des Flocks einer geflockten Unterlage und das so erhaltene Produkt - Google Patents

Verfahren zur Behandlung des Flocks einer geflockten Unterlage und das so erhaltene Produkt Download PDF

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Publication number
EP0989227B1
EP0989227B1 EP99402205A EP99402205A EP0989227B1 EP 0989227 B1 EP0989227 B1 EP 0989227B1 EP 99402205 A EP99402205 A EP 99402205A EP 99402205 A EP99402205 A EP 99402205A EP 0989227 B1 EP0989227 B1 EP 0989227B1
Authority
EP
European Patent Office
Prior art keywords
resin
flocks
support
flocked
impregnated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99402205A
Other languages
English (en)
French (fr)
Other versions
EP0989227A3 (de
EP0989227A2 (de
Inventor
Jean-Pierre Lion
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe dEnduction et de Flockage SAS
Original Assignee
Societe dEnduction et de Flockage SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe dEnduction et de Flockage SAS filed Critical Societe dEnduction et de Flockage SAS
Publication of EP0989227A2 publication Critical patent/EP0989227A2/de
Publication of EP0989227A3 publication Critical patent/EP0989227A3/de
Application granted granted Critical
Publication of EP0989227B1 publication Critical patent/EP0989227B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/12—Decorating textiles by transferring a chemical agent or a metallic or non-metallic material in particulate or other form, from a solid temporary carrier to the textile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using flocked webs or pile fabrics upon which a resin is applied; Teasing, raising web before resin application
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001—Special chemical aspects of printing textile materials

Definitions

  • the present invention relates to a process for treating the flocks of a flocked support, the support being any, for example paper, cardboard, plastic, textile or nonwoven.
  • the invention also relates to the product obtained by this process, whether or not it is subsequently printed.
  • flocked supports It is customary to decorate flocked supports, by printing on the flocks multicolored patterns or by marking the flocks by thermal application of a colored or metallized film, the latter method being generally known by the term "hot foil".
  • the flocked supports are thus decorated in many fields, for example packaging and packaging, decoration, clothing, or wall covering.
  • the flocked supports can be decorated by screen printing, but such an impression does not accurately reproduce finely screened quadrichrome patterns, because the screen-printing frames used are limited by the mesh size.
  • the flocked supports can also be decorated by gravure printing, but this type of printing is also limited in terms of the quality and fineness of the graphic representation, and also requires the prior implementation of specific printing tools. such as engraved cylinders, which are very expensive.
  • screen printing as the heliographic printing require to deposit a large amount of ink on the flocks, and this whatever the nature of the support to print.
  • a colored or metallized layer is applied to a temporary support, usually a transparent polyester film, and then is partially transferred to the flocked support flocks using a heating tool, such as a punch, which briefly briefly presses said layer against flocked flocked media, said layer then being transferred onto the flocked portions of the support which have been crushed by the punch.
  • a heating tool such as a punch
  • the marking of a flocked support is more delicate than that of a paper or a cardboard, because of the textile and irregular nature of the flocked support, which requires to respect precisely particular conditions of application, to to know the selection of a hot stamping film adapted to the flocked support, and the absolute respect of the marking conditions on a precise machine and very well adjusted. Even if these conditions are fully respected, the marking of very fine drawings or texts of very small dimensions can not be done in good readability or will be resistant to friction.
  • Document FR-A-2 718 673 describes a composite material that can be used as a dielectric having improved protection characteristics, in particular moisture-proofing characteristics, or as a metal-layer support for forming flexible printed electrical circuits, as well as a method of manufacturing this composite material.
  • the composite material comprises an electrically and / or thermally insulating substrate, on at least one face of which is formed a protective layer composed of flocked heat-resistant fibers (bonded) on the face of the substrate.
  • the flocked fibers are then impregnated with a heat-resistant resin in solution in an organic solvent so as to obtain a layer of resin reinforced by the fibers.
  • a resin loaded with CuO 2 grains is used and the substrate coated with the protective layer of fibers impregnated with the resin thus charged is then subjected to an immersion metallization process in a aqueous CuO 2 reduction bath and dipping in a copper copper bath.
  • the "printing" of the electrical circuits on the composite material thus metallized is carried out by the usual known methods (generally by photogravure). This document does not describe how to solve the problems related to the printing of colored patterns on a flocked print medium, by means of an offset or flexographic printing machine.
  • the object of the present invention is to propose a process for treating the flocks of a flocked support, which makes it possible to maintain a soft and pleasant feel of the flocked support thus treated, which makes it possible to print the latter by conventional offset printing processes.
  • flexographic, ink-jet or thermal marking using a colored film or metallized under the usual conditions of implementation of these methods, without special adjustment or use of special raw materials, while allowing a precise reproduction of multicolored motifs, especially in four-color process, with the quality of a photograph.
  • the method consists of depositing the resin in a humid medium on the flocks, on the one side of the flocked surface of the support, by any method such as wetting, impregnation, coating or coating. spray.
  • the process consists, after impregnation of flocks with the resin in aqueous dispersion, to spin said flocked support thus impregnated between two pressure rollers to evacuate the excess resin and to uniformize the resin deposit.
  • the resin is a synthetic polymer resin chosen from acrylic esters, synthetic latices and polyesters-polyurethanes, so that the flocked support thus impregnated retains a soft, dry and non-sticky feel.
  • the support is selected from the supports of paper, cardboard, plastic, textile or nonwoven.
  • the invention also relates to the product obtained by the process as previously described, characterized in that it comprises a flocked support whose flocks are impregnated with dry resin whose density is between 2 and 12 g / m 2 , preferably between 6 and 7g / m 2 .
  • the resin-impregnated flocks of the aforementioned product are printed with multicolored patterns, for example in four-color process, by an offset, flexographic, ink-jet printing or thermal application process of a colored or metallized film.
  • the flocked carrier is made by a method known per se, using conventional textile fibers and an adhesive polymer resin to bond the flocks to the selected carrier.
  • flocks of small dimensions for example between 0.3 and 2 mm, are used, and the fibers are chosen from natural fibers, rayon fibers based on viscose, or fibers made of cotton, so that the support thus flocked has a soft and pleasant touch.
  • the flocked carrier is then impregnated with another emulsion polymer resin in an aqueous bath, rather than an organic solution, to protect the environment.
  • the aqueous bath containing the resin in dispersion is uniformly deposited on the flock of the flocked support, by any method, for example by wetting, impregnation, coating or spraying.
  • the flocked support passes between two rolls, the applicator roll of which comprises a layer of foam impregnated with said emulsion for depositing it on the flocks of the flocked support.
  • the flocked support thus impregnated passes between two pressing rolls, for example one of steel and the other of rubber, to remove the excess resin and to uniformize the resin deposit. It is a sort of spinning step of the impregnated flocked support.
  • the concentration of the impregnation bath is adjusted so as to deposit a very small amount of resin on the flocked supports, so as to maintain a soft and pleasant feel, but the amount of resin must be sufficient to allow subsequent printing, as explained below.
  • the impregnated flocked support is dried by passing through a heat treatment oven to evaporate the water contained in the treatment bath. Then, the product thus treated is rolled up and conditioned under conditions adequate to the nature of the support. In the case of paper or cardboard substrates, the moisture content of the packaging should be close to the media recovery rate. Finally, the product thus treated is cut into formats adapted to the desired types of printing, or in the form of small rolls of dimensions adapted to the different printing machines.
  • the treatment bath can be applied by coating by passing the flocked carrier between a cylinder and an applicator squeegee.
  • the surface of the flocks is more regular substantially like paper or cardboard, which allows printing in the usual conditions of implementation, without particular adjustment.
  • offset or flexographic or inkjet printing can be implemented because the presence of the resin in the flocks limits the absorption of the ink by the flocks.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Coloring (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Printing Methods (AREA)

Claims (9)

  1. Verfahren zur Behandlung des Flocks eines beflockten Trägers, bestehend aus dem Imprägnieren des Flocks des beflockten Trägers mit Polymerharz und dem Trocknen des so imprägnierten beflockten Trägers,
    dadurch gekennzeichnet, dass die Imprägnierung durchgeführt wird mit einer geringen Menge von Polymerharz in Emulsion in einem wässrigen Bad, wobei die geringe Menge des Harzes geeignet ist, eventuelle Flockfasern im freien Zustand an dem Träger zu fixieren und das Eindringen von Druckfarben in den Flock bei einem eventuellen späteren Bedruckungsschritt zu begrenzen.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der Gehalt des wässrigen Bades an Harz vorteilhafterweise zwischen 2 und 12 % an Gewicht der Trockenmasse, vorzugsweise zwischen 6 und 7 %, liegt.
  3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, dass es darin besteht, den Flock mit der Emulsion mit einer Dichte zwischen 100 g/m2 und 150 g/m2 zu imprägnieren.
  4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass es daraus besteht, das Harz in nassem Milieu auf dem Flock abzusetzen nur auf der Seite der beflockten Trägerfläche, mit einem beliebigen Verfahren wie Benetzen, Imprägnieren, Beschichten oder Besprühen.
  5. Verfahren nach Anspruch 4, dadurch gekennzeichnet, dass es daraus besteht, nach dem Imprägnieren des Flocks mit dem Harz in wässriger Dispersion, den so imprägnierten beflockten Träger zwischen zwei Druckzylindem auszupressen, um überschüssiges Harz zu entfernen und den Harzauftrag zu vergleichmäßigen.
  6. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das Harz ein synthetisches Polymerharz ist, das ausgewählt ist aus Acrylestern, synthetischem Latex und Polyurethanestern, derart, dass der so imprägnierte beflockte Träger einen weichen, trockenen und nicht klebenden Griff hat.
  7. Verfahren nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass der Träger ausgewählt ist aus Trägern aus Papier, Karton, Kunststoff, Textil oder Faservlies.
  8. Durch das Verfahren nach einem der Ansprüche 1 bis 7 erhaltenes Produkt, dadurch gekennzeichnet, dass es einen beflockten Träger umfasst, dessen Flock mit trockenem Harz imprägniert ist, dessen Dichte zwischen 2 und 12 g/m2, vorzugsweise zwischen 6 und 7 g/m2, liegt.
  9. Produkt nach Anspruch 8, dadurch gekennzeichnet, dass der mit Harz imprägnierte Flock des Produktes mit mehrfarbigen Motiven bedruckt sind, z. B. im Vierfarbendruck, durch ein Offset-Druckverfahren, durch ein flexografisches Verfahren, durch Tintenstrahl oder durch thermische Aufbringung eines gefärbten oder metallisierten Films.
EP99402205A 1998-09-22 1999-09-08 Verfahren zur Behandlung des Flocks einer geflockten Unterlage und das so erhaltene Produkt Expired - Lifetime EP0989227B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9811791A FR2783441B1 (fr) 1998-09-22 1998-09-22 Procede de traitement des flocks d'un support flocke et produit obtenu par ce procede
FR9811791 1998-09-22

Publications (3)

Publication Number Publication Date
EP0989227A2 EP0989227A2 (de) 2000-03-29
EP0989227A3 EP0989227A3 (de) 2000-04-05
EP0989227B1 true EP0989227B1 (de) 2006-07-12

Family

ID=9530686

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99402205A Expired - Lifetime EP0989227B1 (de) 1998-09-22 1999-09-08 Verfahren zur Behandlung des Flocks einer geflockten Unterlage und das so erhaltene Produkt

Country Status (5)

Country Link
EP (1) EP0989227B1 (de)
AT (1) ATE332996T1 (de)
DE (1) DE69932298T2 (de)
ES (1) ES2268837T3 (de)
FR (1) FR2783441B1 (de)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7749589B2 (en) 2005-09-20 2010-07-06 High Voltage Graphics, Inc. Flocked elastomeric articles
US7799164B2 (en) 2005-07-28 2010-09-21 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US8007889B2 (en) 2005-04-28 2011-08-30 High Voltage Graphics, Inc. Flocked multi-colored adhesive article with bright lustered flock and methods for making the same
US8206800B2 (en) 2006-11-02 2012-06-26 Louis Brown Abrams Flocked adhesive article having multi-component adhesive film
US8354050B2 (en) 2000-07-24 2013-01-15 High Voltage Graphics, Inc. Co-molded direct flock and flock transfer and methods of making same
US8475905B2 (en) 2007-02-14 2013-07-02 High Voltage Graphics, Inc Sublimation dye printed textile
US9012005B2 (en) 2009-02-16 2015-04-21 High Voltage Graphics, Inc. Flocked stretchable design or transfer including thermoplastic film and method for making the same
US9175436B2 (en) 2010-03-12 2015-11-03 High Voltage Graphics, Inc. Flocked articles having a resistance to splitting and methods for making the same
US9193214B2 (en) 2012-10-12 2015-11-24 High Voltage Graphics, Inc. Flexible heat sealable decorative articles and method for making the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202005018438U1 (de) * 2005-11-23 2006-03-16 Koch, Norbert Flocktransferbahn

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB979006A (en) * 1961-08-31 1965-01-01 United Merchants & Mfg Differential overprinting of rayon flocked cotton fabrics
JPS4833792B1 (de) * 1970-11-12 1973-10-16
US4125657A (en) * 1977-10-26 1978-11-14 Gonzalez Jose B Decorative article and method
IT1179861B (it) * 1984-12-11 1987-09-16 Fil To Vel Di Contu Giovannino Procedimento per la stampa piatta a piu colori o a colori sovrapposti in quadrioromia in sistema serigrafico su supporti figurativi floccati in rilievo
FR2718673B1 (fr) * 1994-04-19 1996-05-24 Kermel Snc Article composite et procédé de fabrication de celui-ci.

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8354050B2 (en) 2000-07-24 2013-01-15 High Voltage Graphics, Inc. Co-molded direct flock and flock transfer and methods of making same
US8007889B2 (en) 2005-04-28 2011-08-30 High Voltage Graphics, Inc. Flocked multi-colored adhesive article with bright lustered flock and methods for making the same
US7799164B2 (en) 2005-07-28 2010-09-21 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
USRE45802E1 (en) 2005-07-28 2015-11-17 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US7749589B2 (en) 2005-09-20 2010-07-06 High Voltage Graphics, Inc. Flocked elastomeric articles
US8168262B2 (en) 2005-09-20 2012-05-01 High Voltage Graphics, Inc. Flocked elastomeric articles
US8206800B2 (en) 2006-11-02 2012-06-26 Louis Brown Abrams Flocked adhesive article having multi-component adhesive film
US8475905B2 (en) 2007-02-14 2013-07-02 High Voltage Graphics, Inc Sublimation dye printed textile
US9012005B2 (en) 2009-02-16 2015-04-21 High Voltage Graphics, Inc. Flocked stretchable design or transfer including thermoplastic film and method for making the same
US9175436B2 (en) 2010-03-12 2015-11-03 High Voltage Graphics, Inc. Flocked articles having a resistance to splitting and methods for making the same
US9193214B2 (en) 2012-10-12 2015-11-24 High Voltage Graphics, Inc. Flexible heat sealable decorative articles and method for making the same

Also Published As

Publication number Publication date
EP0989227A3 (de) 2000-04-05
DE69932298D1 (de) 2006-08-24
FR2783441A1 (fr) 2000-03-24
FR2783441B1 (fr) 2000-10-20
EP0989227A2 (de) 2000-03-29
DE69932298T2 (de) 2007-07-05
ES2268837T3 (es) 2007-03-16
ATE332996T1 (de) 2006-08-15

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