EP0563245B1 - Kaschierte markierte bedruckbare folie und verfahren zu ihrer herstellung - Google Patents
Kaschierte markierte bedruckbare folie und verfahren zu ihrer herstellung Download PDFInfo
- Publication number
- EP0563245B1 EP0563245B1 EP92902797A EP92902797A EP0563245B1 EP 0563245 B1 EP0563245 B1 EP 0563245B1 EP 92902797 A EP92902797 A EP 92902797A EP 92902797 A EP92902797 A EP 92902797A EP 0563245 B1 EP0563245 B1 EP 0563245B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper
- sheet
- coated
- layer
- ribbed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 3
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- -1 polyethylene Polymers 0.000 claims description 4
- 229920002994 synthetic fiber Polymers 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- 238000004049 embossing Methods 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000003550 marker Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
- D21H19/74—Coated paper characterised by the paper substrate the substrate having an uneven surface, e.g. crêped or corrugated paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24628—Nonplanar uniform thickness material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
- Y10T428/273—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] of coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31931—Polyene monomer-containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31993—Of paper
Definitions
- the invention relates to a marked printable sheet comprising at least one pigmented layer, and more particularly a matt layer.
- the invention further relates to the method of manufacturing such a sheet.
- the terms "marked sheet” and "marked paper” mean a sheet or respectively a paper, presenting marks or patterns in relief produced using embossing rollers or watermarks or using markers markers, possibly hot. It is for example a laid paper, the rods being made using a watermark roll; of a grained paper, the grain being produced by means of an embossing roller or a marker pen. It can also be non-smoothed papers called “machine blanks" which have a certain structured surface (rustic effect) originating from the marking of the felt of the paper machine. It can also be for example an embossed plastic film.
- Papers which have a pigmented layer in order to give them very good printability, in particular in four-color printing.
- marked papers which comprise at least one pigmented layer so as to make them printable.
- Such papers are produced by forming a sheet by the wet technique, that is to say using an aqueous dispersion containing cellulose fibers, optionally with other natural, mineral and / or synthetic fibers, and optionally binders. , dyes and other additives commonly used in stationery.
- the aqueous dispersion is placed on a metal grid, wrung out and then dried.
- the sheet thus obtained is then coated by means coaters with compositions containing fillers (for example kaolin). Then the coated sheet is dried. Finally, a marking of the sheet is carried out outside the machine.
- An object of the invention is therefore to provide a marked paper which has good printability (therefore coated), but which at the same time retains the rigidity of an unmarked paper, of the same grammage and which is of homogeneous mat appearance.
- An object of the invention is therefore to provide paper of the paper type for printing and / or writing, matte, but at the same time marked.
- An object of the invention is therefore to provide a paper which combines the advantages of the two kinds of paper and which avoid their faults: a coated paper therefore having better printability with a soft marking which brings originality without harming the homogeneity of the shine and without harming the rigidity.
- Another object of the invention is to provide a grained coated paper which has good rigidity and avoids the user buying a paper of significantly heavier grammage (the choice of grammage of the paper was indeed often linked to rigidity required by the user).
- the Applicant has produced such a coated, marked and matte printable sheet, the surface appearance of which (that is to say the mattness or the gloss) is uniform and is not affected by the marking, by performing all 'first the marking of a support and covering at least one face of this support by at least one pigmented layer.
- the skilled person has so far thought that if he deposited a pigmented layer on a paper which has been previously marked, the layer would plug the hollow parts and therefore the marks would no longer be visible after the sleeping.
- the layer would not be distributed uniformly, the hollows filling more and the bumps being coated more weakly by the composition of the layer.
- the invention therefore relates to a marked coated printable sheet, such as it consists of a marked support comprising recesses covered on at least one of its faces with at least one pigmented layer deposited uniformly in the recesses.
- the Japanese document JP-A-57 056 212 describes a paper used to manufacture synthetic leathers.
- a transparent or translucent resin 4 ′ is deposited on the surface of a transfer paper which has reliefs 2, 3. When the resin is dry, a pattern 5 is printed with a printing ink.
- the paper is laminated on a sheet of synthetic material, with the application of heat and pressure and the transfer paper is removed.
- thermoplastic material It is a transfer paper which includes prints which are transferred onto a thermoplastic material.
- Other transfer papers include reliefs.
- the one described in the Japanese document contains both prints and reliefs.
- Patent BE-A-377,927 describes a marked sheet on which colored substances are deposited, so as to cause an irregular distribution of these substances, in such a way that more colored substances accumulate in the hollows than in protrusions. An inhomogeneous coloring is then obtained, for example reproducing the appearance of wood. The surface structure of the paper is enhanced by depositing the colored layer.
- US-A-1,900,294 describes a process which consists of embossing the paper and then coating it with wax.
- the hollows contain more wax than the projections. It is a sealable paper for food packaging.
- the pigmented layer has a weight of between 5 and 30 g / m2 in dry conditions and more particularly between 10 and 20 g / m2.
- the pigmented layer is mat. More preferably, the support is grained, laid paper.
- the invention further relates to a method of manufacturing a printable coated sheet marked such that successively a flexible support is formed, marks are made on at least one of the faces of this support by making recesses and bumps, deposited on at at least one of the faces of this support at least one pigmented composition and the sheet thus obtained is dried.
- the flexible support is formed by depositing on a metallic fabric an aqueous dispersion of cellulosic fibers, optionally in admixture with other natural fibers, synthetic, mineral and possibly other additives such as binders, pigments, retention agents, flocculating agents, optical brighteners, dyes, etc.
- the support can consist essentially of synthetic fibers.
- the support can also be formed from polyethylene or its mixtures which are biaxially stretched.
- any pigmented layer may be suitable.
- a matt pigmented layer is preferred, the degree of mattness being able to be more or less high.
- the support can be marked during its manufacture on or off the machine by any type of marking device: embossing rollers, watermarks, marker felts, etc.
- marking can optionally be done hot, in particular for synthetic supports.
- the support can be coated with any coating device usually used in stationery.
- any coating device usually used in stationery can be used.
- an air knife coater or a Bill-Blade coater can be used.
- the layer is deposited on one or both sides of the support.
- the printable sheet according to the invention can advantageously be manufactured entirely on a paper machine, therefore without carrying out operations outside the machine which increase the manufacturing costs.
- the sheet obtained according to the invention can be used for numerous applications such as for example in the fields of printing and / or writing, packaging, labels, etc.
- the paper obtained has gloss points and a synthetic feel.
- EXAMPLE B A paper is produced on a machine which is seeded with a grain felt.
- the grained support is coated with the same composition as for Example A.
- the paper thus obtained has retained its grainy appearance but it has neither a point of gloss nor a synthetic feel.
- NB TABER stiffness is measured according to ISO 2493 (1973). The grammage and bulk index are determined according to ISO 534 (1988). The ash rate is determined according to ISO 2144 (1987).
- the dry extract of the composition is 60%.
- a laid paper sold by the Applicant under the brand RIVES COLOR′CLASSIC is used, which is a laid paper obtained by a watermark roll.
- the grammage of this paper is 90 g / m2.
- the paper is gray in color.
- This support is coated with the above pigmented composition, using a HAND COATING rotary bar.
- the weight of the deposited layer is 12 g / m2 dry.
- the sheet thus obtained has a good printability, very close to that of un laid laid coated papers.
- the sheet has a rigidity equivalent to that of coated paper of the same grammage.
- the sheet has a non-synthetic feel.
- a grained paper sold by the applicant under the brand RIVES COLOR ′ DESIGN having a basis weight of 120 g / m2 and gray in color is used.
- This support is coated with the pigmented composition of Example 1.
- the weight of the layer is 18 g / m2 dry.
- Example 1 As in Example 1, it can be seen that the layer has been deposited in a homogeneous manner and it is observed that the paper obtained always has clearly visible grains. In addition, the sheet has good printability and stiffness comparable to that of ungrained coated paper. The paper has no point of gloss due to the grain.
- a paper (made of cellulose fibers) is made on a lightning paper machine without smoothing it. It is coated with an air knife with the composition of Example 1. The dry layer weight is 12 g / m2.
- the sheet thus coated has retained its non-smoothed ("rustic") surface appearance, but its printability has been improved compared to uncoated paper.
Landscapes
- Laminated Bodies (AREA)
- Paper (AREA)
- Measurement Of Radiation (AREA)
- Ultra Sonic Daignosis Equipment (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Credit Cards Or The Like (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (4)
- Bedruckbares Blatt bzw. bedruckbare Folie, das(die) beschichtet und markiert ist, dadurch gekennzeichnet, daß es(sie) besteht aus einem markierten Träger, der Vertiefungen aufweist, der auf mindestens einer seiner Oberflächen mindestens eine pigmentierte Schicht aufweist, die gleichmäßig in den Vertiefungen abgeschieden worden ist.
- Blatt bzw. Folie nach Anspruch 1, dadurch gekennzeichnet, daß das Trockengewicht der Schicht zwischen etwa 5 und etwa 25 g/m² liegt.
- Blatt bzw. Folie nach einem der Ansprüche 1 und 2, dadurch gekennzeichnet, daß die pigmentierte Schicht matt ist.
- Blatt bzw. Folie nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß der Träger ausgewählt wird unter genarbten, gerippten und nicht-geglätteten (nicht-geschlichteten) Papieren, markierten Kunststoffilmen und markierten Filmen aus biaxial verstrecktem Polyethylen.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9016141 | 1990-12-21 | ||
FR9016141A FR2670811B1 (fr) | 1990-12-21 | 1990-12-21 | Feuille imprimable marquee couchee et son procede de fabrication. |
PCT/FR1991/001047 WO1992011413A1 (fr) | 1990-12-21 | 1991-12-20 | Feuille imprimable marquee couchee et son procede de fabrication |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0563245A1 EP0563245A1 (de) | 1993-10-06 |
EP0563245B1 true EP0563245B1 (de) | 1995-10-11 |
Family
ID=9403566
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92902797A Expired - Lifetime EP0563245B1 (de) | 1990-12-21 | 1991-12-20 | Kaschierte markierte bedruckbare folie und verfahren zu ihrer herstellung |
Country Status (15)
Country | Link |
---|---|
US (1) | US5691042A (de) |
EP (1) | EP0563245B1 (de) |
JP (1) | JPH06504494A (de) |
AT (1) | ATE129037T1 (de) |
AU (1) | AU662507B2 (de) |
BR (1) | BR9107178A (de) |
CA (1) | CA2099871C (de) |
DE (1) | DE69113814T2 (de) |
DK (1) | DK0563245T3 (de) |
ES (1) | ES2081091T3 (de) |
FI (1) | FI108360B (de) |
FR (1) | FR2670811B1 (de) |
NO (1) | NO301846B1 (de) |
WO (1) | WO1992011413A1 (de) |
ZA (1) | ZA9110069B (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9411868D0 (en) * | 1994-06-14 | 1994-08-03 | Wiggins Teape Group The Limite | Paper carrying a surface relief pattern |
WO2001021883A1 (de) * | 1999-09-21 | 2001-03-29 | Heinrich August Schoeller Söhne Gmbh & Co. Kg | Verfahren zur herstellung von papier sowie entsprechendes papier |
FR2841574B1 (fr) * | 2002-06-27 | 2005-04-08 | Arjo Wiggins | Procede de fabrication d'une feuille portant un motif en relief recouverte d'une couche lui conferant un effet de profondeur |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE377927A (de) * | ||||
US1900294A (en) * | 1929-11-04 | 1933-03-07 | George N Lovatt | Waxed paper and process of making the same |
JPS5756212A (en) * | 1980-09-18 | 1982-04-03 | Lonseal Corp | Manufacture of print and embossed sheet free from displacement of pattern |
JP2535180B2 (ja) * | 1987-09-18 | 1996-09-18 | 共和レザー株式会社 | 積層体の製造方法 |
US4957578A (en) * | 1989-03-22 | 1990-09-18 | Westvaco Corporation | Process for producing a paperboard product for premium packaging applications |
-
1990
- 1990-12-21 FR FR9016141A patent/FR2670811B1/fr not_active Expired - Fee Related
-
1991
- 1991-12-20 WO PCT/FR1991/001047 patent/WO1992011413A1/fr active IP Right Grant
- 1991-12-20 CA CA002099871A patent/CA2099871C/fr not_active Expired - Lifetime
- 1991-12-20 JP JP4502909A patent/JPH06504494A/ja active Pending
- 1991-12-20 ES ES92902797T patent/ES2081091T3/es not_active Expired - Lifetime
- 1991-12-20 BR BR919107178A patent/BR9107178A/pt not_active IP Right Cessation
- 1991-12-20 AT AT92902797T patent/ATE129037T1/de not_active IP Right Cessation
- 1991-12-20 DE DE69113814T patent/DE69113814T2/de not_active Expired - Lifetime
- 1991-12-20 ZA ZA9110069A patent/ZA9110069B/xx unknown
- 1991-12-20 US US08/078,248 patent/US5691042A/en not_active Expired - Lifetime
- 1991-12-20 EP EP92902797A patent/EP0563245B1/de not_active Expired - Lifetime
- 1991-12-20 AU AU91472/91A patent/AU662507B2/en not_active Expired
- 1991-12-20 DK DK92902797.7T patent/DK0563245T3/da active
-
1993
- 1993-06-18 FI FI932830A patent/FI108360B/fi active
- 1993-06-21 NO NO932278A patent/NO301846B1/no not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE69113814T2 (de) | 1996-04-18 |
CA2099871C (fr) | 1999-11-09 |
BR9107178A (pt) | 1993-11-03 |
AU9147291A (en) | 1992-07-22 |
FI932830A0 (fi) | 1993-06-18 |
FR2670811A1 (fr) | 1992-06-26 |
NO932278L (no) | 1993-08-16 |
DK0563245T3 (da) | 1996-02-26 |
FI108360B (fi) | 2002-01-15 |
JPH06504494A (ja) | 1994-05-26 |
NO301846B1 (no) | 1997-12-15 |
WO1992011413A1 (fr) | 1992-07-09 |
FR2670811B1 (fr) | 1995-05-12 |
AU662507B2 (en) | 1995-09-07 |
EP0563245A1 (de) | 1993-10-06 |
DE69113814D1 (de) | 1995-11-16 |
ATE129037T1 (de) | 1995-10-15 |
FI932830A (fi) | 1993-06-18 |
CA2099871A1 (en) | 1992-06-22 |
US5691042A (en) | 1997-11-25 |
ZA9110069B (en) | 1992-10-28 |
NO932278D0 (no) | 1993-06-21 |
ES2081091T3 (es) | 1996-02-16 |
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