EP0984827A1 - Surfactant mixture - Google Patents

Surfactant mixture

Info

Publication number
EP0984827A1
EP0984827A1 EP97920831A EP97920831A EP0984827A1 EP 0984827 A1 EP0984827 A1 EP 0984827A1 EP 97920831 A EP97920831 A EP 97920831A EP 97920831 A EP97920831 A EP 97920831A EP 0984827 A1 EP0984827 A1 EP 0984827A1
Authority
EP
European Patent Office
Prior art keywords
parts
oil
water
composition according
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97920831A
Other languages
German (de)
French (fr)
Other versions
EP0984827B1 (en
Inventor
Pauline William Zard
David James Barclay-Miller
David William Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PALOX OFFSHORE L SA
Original Assignee
BURWOOD CORP Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BURWOOD CORP Ltd filed Critical BURWOOD CORP Ltd
Publication of EP0984827A1 publication Critical patent/EP0984827A1/en
Application granted granted Critical
Publication of EP0984827B1 publication Critical patent/EP0984827B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M133/08Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/28Polyoxyalkylenes of alkylene oxides containing 2 carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/36Polyoxyalkylenes etherified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26Amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles

Definitions

  • This invention relates to a surfactant mixture for use in preparing industrial lubricants e.g. hydraulic or machine tool cutting oils comprising clear homogenous microemulsions.
  • the present invention seeks to overcome the above mentioned problems by providing a surfactant composition which allows the formulation of oil - water mixtures which are microemulsions of water in oil and are true solutions or behave as such.
  • solution herein describes any mixtures which are clear and homogenous.
  • behave as such means that the mixture has substantially the same stability as a solution.
  • the present invention accordingly provides a composition for use in combining oil and water as a stable solution (emulsion, preferably a microemulsion) which composition comprises (a) a fatty acid amine ethoxylate (b) a C 6 -C 15 alcohol ethoxylate and optionally (c) a tall oil fatty acid amine.
  • compositions are combined together in quantities that allow the formation of microemulsions on addition to the appropriate oil and water mixture.
  • composition may comprise additional components. These have been found to include sorbitan esters, mono and di - glycerides of fatty acids, polymeric emulsifiers containing fatty acid side groups, polyimides and substituted polyimides such as poly isobutenylsuccimide. Other surfactant types will be apparent to those versed in the art.
  • Preferred components of the surfactant composition are all readily available commercially.
  • the parts by volume in each case being relative to the total volume of the composition.
  • the composition of the present invention comprises the tall oil fatty acid amine.
  • This component may be used to impart (further) stability to the composition of the present invention.
  • the minimum quantity of the surfactant composition required is dependant upon the water content of the desired microemulsion and the base oil type being used. For example, 80 parts of a naphthenic base oil (Shell, solvent pale 60) was emulsified with 20 parts of water such that a microemulsion was obtained. This was achieved with the addition of 20 parts of the surfactant composition. Using a different base oil, based upon a paraffinic type (Shell, 130 solvent neutral), with the same quantities of water and oil required 30 parts of the surfactant composition to form a microemulsion.
  • a naphthenic base oil Shell, solvent pale 60
  • the surfactant is added to the oil water mixture with gentle mixing until a clear homogenous microemulsion is obtained.
  • microemulsions will have many applications in the industrial lubricants market. It may be necessary for certain applications to incorporate other additives i.e. to give extreme pressure protection for higher temperature applications. These applications and additional additives will be apparent to those skilled in the art.
  • composition suitable for combining 70 parts of a paraffinic type base oil (Shell 130 solvent neutral) with 30 parts of water was prepared by adding the following components in the quantities stated:
  • Example 2 The components were gently mixed to form a homogenous solution.
  • Example 2 The components were gently mixed to form a homogenous solution.
  • Example 1 30 ml of water was added to 70 m of Shell 130 solvent neutral in a clear glass container.
  • the surfactant composition of Example 1 was introduced to the oil and water from a burette. After each addition of surfactant the resulting solution was mixed. This continued until a clear homogenous solution was observed. The resulting solution remains stable for more than one year.
  • Example 1 20 ml of water was added to 80 ml of Shell solvent neutral in a clear glass container.
  • the surfactant solution of Example 1 was introduced into the oil and water as in Example 2. The resulting solution remains stable for more than one year.
  • Example 2 The solution obtained in Example 2 was used to determine its corrosive properties on mild steel. This was done by placing a piece of mild steel in the solution and observing the formation of rust. No corrosion has been observed after 6 months.
  • composition of the present invention is effective in preventing such growth.
  • Any growth of this algae was to be monitored by any colour change of the solution as the algae produce a green growth in macroemulsions. No micro-organism growth was observed after 6 months. It is believed that the compositions of the present invention prevents any micro-organism growth because the water droplets in the solution containing the surfactant composition are smaller than the micro-organisms and so there is insufficient oxygen for the algae to grow.
  • Microemulsions have been prepared in the following base oil types i) paraffinic ii) naphthenic iii) linear alpha olefins iv) ester type base fluids
  • a microemulsion using linear alpha olefin was prepared as in Example 2 using 35 parts of the surfactant composition. This was then tested using the lubricant industry standard IP287 to determine the potential of the solution to promote corrosion. No corrosion has been observed using this or indeed any other prepared solution.
  • Example 8 The solution from Example 8 was doped with a heavily contaminated soluble oil. The resulting solution was then tested using an agar dipslide to monitor bacterial growth within the solution. No culture or bacterial growth was observed after 168 hours at 35°C. It is generally recognised that bacteria will be observed on the culture medium after 72 hours when held at 35°C.
  • a hydraulic oil was prepared using the microemulsion from example 2 with an anti- wear additive based on sulphur. This was added at a rate of 5 % v/v. A further hydraulic oil was prepared using the same base oil and sulphur additive. Both oils were then tested for their anti-wear properties using the Reichert testing apparatus. The microemulsion showed a reduced weight loss compared to the standard oil of 10 % .
  • a gear oil has been prepared using a commercially available oil (Mobil Glygoyle HE460) and the composition of Example 1.
  • the resulting oil has shown improved coolancy with no loss in lubricity using standard anti-wear tests i.e. four ball tests.
  • a grinding oil was prepared using a linear alpha olefin base oil with the composition of Example 1. This was tested against a standard grinding oil and was shown to be of superior cooling ability with no loss in lubricity.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Colloid Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Soft Magnetic Materials (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

A surfactant composition is described. This composition is used for the emulsification of oil and water to form microemulsions. These microemulsions can be used as industrial lubricants e.g. machine tool cutting oils (although many uses are possible) and show distinct advantages over traditional neat oils or macroemulsions.

Description

Surfactant Mixture
This invention relates to a surfactant mixture for use in preparing industrial lubricants e.g. hydraulic or machine tool cutting oils comprising clear homogenous microemulsions.
The use of cutting oil and macroemulsions of these oils in metalworking is well known. Neat oils are used when a good surface finish is required on the metal being worked. However, due to the poor coolant properties of the oils used rapid degeneration of the machine tool (which can reach temperatures in excess of 200°C) takes place.
To improve the life of the machine tool macroemulsions of the oil are made with water. The excellent coolant properties of the water does indeed improve the life of the tool. However, the incorporation of water coupled with the instability of macroemulsions gives rise to several other problems. These are that the lubricity of the oil is decreased with addition of water thereby affecting the surface finish of the metal. Also, as water is present the likelihood of corrosion becomes apparent. Consequently, the macroemulsion requires further addition of specialist additives to overcome the occurrence of corrosion. The presence of water droplets (> 0.1 μm) may also give rise to bacterial growth which not only can affect performance of the lubricant but also is unpleasant for the machine operator due to the oil becoming rancid and thus foul smelling.
The present invention seeks to overcome the above mentioned problems by providing a surfactant composition which allows the formulation of oil - water mixtures which are microemulsions of water in oil and are true solutions or behave as such. The term "solution" herein describes any mixtures which are clear and homogenous. The term "behave as such" means that the mixture has substantially the same stability as a solution. The present invention accordingly provides a composition for use in combining oil and water as a stable solution (emulsion, preferably a microemulsion) which composition comprises (a) a fatty acid amine ethoxylate (b) a C6-C15 alcohol ethoxylate and optionally (c) a tall oil fatty acid amine.
The components of the composition are combined together in quantities that allow the formation of microemulsions on addition to the appropriate oil and water mixture.
The composition may comprise additional components. These have been found to include sorbitan esters, mono and di - glycerides of fatty acids, polymeric emulsifiers containing fatty acid side groups, polyimides and substituted polyimides such as poly isobutenylsuccimide. Other surfactant types will be apparent to those versed in the art.
Preferred components of the surfactant composition are all readily available commercially.
A preferred embodiment of the invention comprises the following components :
i) 1 - 5 parts of a fatty acid amine ethoxylate ii) 0.5 - 4 parts of alcohol ethoxylate and optionally iii) 1.5 - 5 parts of tall oil fatty acid amine
the parts by volume in each case being relative to the total volume of the composition.
In a highly preferred embodiment, the composition of the present invention comprises the tall oil fatty acid amine. This component may be used to impart (further) stability to the composition of the present invention. The minimum quantity of the surfactant composition required is dependant upon the water content of the desired microemulsion and the base oil type being used. For example, 80 parts of a naphthenic base oil (Shell, solvent pale 60) was emulsified with 20 parts of water such that a microemulsion was obtained. This was achieved with the addition of 20 parts of the surfactant composition. Using a different base oil, based upon a paraffinic type (Shell, 130 solvent neutral), with the same quantities of water and oil required 30 parts of the surfactant composition to form a microemulsion.
To determine the minimum quantity of the surfactant composition required the surfactant is added to the oil water mixture with gentle mixing until a clear homogenous microemulsion is obtained.
These microemulsions will have many applications in the industrial lubricants market. It may be necessary for certain applications to incorporate other additives i.e. to give extreme pressure protection for higher temperature applications. These applications and additional additives will be apparent to those skilled in the art.
The invention shall now be described by way of example only.
Example 1
A composition suitable for combining 70 parts of a paraffinic type base oil (Shell 130 solvent neutral) with 30 parts of water was prepared by adding the following components in the quantities stated:
3 parts fatty acid amine ethoxylate 2.75 parts tall oil fatty acid amine 2 parts C6-C15 alcohol ethoxylate
The components were gently mixed to form a homogenous solution. Example 2
30 ml of water was added to 70 m of Shell 130 solvent neutral in a clear glass container. The surfactant composition of Example 1 was introduced to the oil and water from a burette. After each addition of surfactant the resulting solution was mixed. This continued until a clear homogenous solution was observed. The resulting solution remains stable for more than one year.
Example 3
20 ml of water was added to 80 ml of Shell solvent neutral in a clear glass container. The surfactant solution of Example 1 was introduced into the oil and water as in Example 2. The resulting solution remains stable for more than one year.
Example 4
The solution obtained in Example 2 was used to determine its corrosive properties on mild steel. This was done by placing a piece of mild steel in the solution and observing the formation of rust. No corrosion has been observed after 6 months.
Example 5
When using macroemulsions of oil and water problems of micro-organism growth can arise.
To determine whether the composition of the present invention is effective in preventing such growth an algae was introduced to the solution of Example 2. Any growth of this algae was to be monitored by any colour change of the solution as the algae produce a green growth in macroemulsions. No micro-organism growth was observed after 6 months. It is believed that the compositions of the present invention prevents any micro-organism growth because the water droplets in the solution containing the surfactant composition are smaller than the micro-organisms and so there is insufficient oxygen for the algae to grow.
Example 6
A series of tests were conducted on an industrial lathe using solutions in Examples 2 and 3 and the neat base oil (Shell 130 solvent neutral). Initially the tool bits that were to be used were prepared by grinding to the same specification. These were then electron micrographed to confirm that the tool bits were to all intents and purposes identical. The bits were then used to lathe 75 mm external diameter mild steel rod down to 20 mm external diameter over a 600 mm length at a rate of 2.5 mm per cut. The tool bits were then electron micrographed for a second time to determine which bits were wearing faster. The results, which are shown in Table 1 and figures 1-10, show that bits containing just neat oil or neat oil with an extreme pressure additive (Cereclor E45) wear considerably more quickly than those of Examples 2 and 3. The surface finish of the mild steel of all the samples was compared and found to be no different, thereby indicating no loss in the lubricity of the solutions containing water.
An added benefit was also observed during this test. When lathing the steel the observable amount of smoke was reduced using the solutions of Examples 2 and 3. In addition it is believed that the emissions given by the solutions of the present invention will be cleaner due to the higher oxygen content because of the presence of water. As seen in Table 1, the swarf generated by the cutting was collected and an experiment was carried out to determine the oil that had become associated with it. Again, the solutions from Examples 2 and 3 were shown to have an improvement over the neat oil as less oil was associated with these cuttings. Example 7
Microemulsions have been prepared in the following base oil types i) paraffinic ii) naphthenic iii) linear alpha olefins iv) ester type base fluids
Example 8
A microemulsion using linear alpha olefin was prepared as in Example 2 using 35 parts of the surfactant composition. This was then tested using the lubricant industry standard IP287 to determine the potential of the solution to promote corrosion. No corrosion has been observed using this or indeed any other prepared solution.
Example 9
The solution from Example 8 was doped with a heavily contaminated soluble oil. The resulting solution was then tested using an agar dipslide to monitor bacterial growth within the solution. No culture or bacterial growth was observed after 168 hours at 35°C. It is generally recognised that bacteria will be observed on the culture medium after 72 hours when held at 35°C.
Example 10
Solutions from Examples 2, 3 and 8 have been tested for wear prevention using a Reichert testing machine. This involves rotating a roller bearing over a known distance (100 m) within a specific length of time (60 s) with a load of 1.5 Kg. When comparing the solutions with their respective straight oils a reduction in weight loss of 22 % was observed on the solutions from Examples 2 and 3 whilst that of Example 8 showed a reduction in weight loss of 14 %. Example 11
A hydraulic oil was prepared using the microemulsion from example 2 with an anti- wear additive based on sulphur. This was added at a rate of 5 % v/v. A further hydraulic oil was prepared using the same base oil and sulphur additive. Both oils were then tested for their anti-wear properties using the Reichert testing apparatus. The microemulsion showed a reduced weight loss compared to the standard oil of 10 % .
Example 12
A gear oil has been prepared using a commercially available oil (Mobil Glygoyle HE460) and the composition of Example 1. The resulting oil has shown improved coolancy with no loss in lubricity using standard anti-wear tests i.e. four ball tests.
Example 13
A grinding oil was prepared using a linear alpha olefin base oil with the composition of Example 1. This was tested against a standard grinding oil and was shown to be of superior cooling ability with no loss in lubricity.

Claims

1. A composition for preparing a microemulsion of oil and water, the composition comprising
i) a fatty acid amine ethoxylate ii) C6-C15 alcohol ethoxylate; and optionally iii) tall oil fatty acid amine
2. A composition according to claim 1 which comprises the following
i) 1 - 5 parts of a fatty acid amine ethoxylate ii) 0.5 - 4 parts of a C6-C15 alcohol ethoxylate; and optionally iii) 1.5 - 5 parts tall oil fatty acid amine
3. A composition according to claim 1 or claim 2 comprising 3 parts of component (i) and 2 parts of component (ii) and optionally 2.75 parts of component (in).
4. A composition according to claim 1 or claim 2 comprising 3 parts of component (i) and 1 part of component (ii) and optionally 1.5 parts of component (iii).
5. A composition according to claim 1 or claim 2 comprising 2 parts of component (i) and 1 part of component (ii) and optionally 3 parts of component (iii).
6. A process comprising adding to a mixture of oil and water a surfactant composition according to any of claims 1 - 5 such that a clear homogenous microemulsion is formed.
7. A process according to claim 6 wherein a composition according to claim 4 is added to a mixture of 30 parts of water and 70 parts of paraffinic type base oil in an amount of 40 parts by volume relative to the oil water mixture.
8. A process according to claim 6 wherein a composition according to claim 3 is added to a mixture of 20 parts of water and 80 parts of paraffinic type base oil in an amount of 29 parts by volume relative to the oil water mixture.
9. A process according to claim 6 wherein a composition according to claim 5 is added to a mixture of 10 parts of water and 90 parts of paraffinic type base oil in an amount of 14 parts by volume relative to the oil water mixture.
10. A clear homogenous microemulsion produced by the process of any of claims 6 - 9.
11. An emulsion comprising oil, water and a composition according to any one of claims 1 to 5.
12. A microemulsion according to claim 10 or claim 11 for use as an industrial lubricant.
13. Use of a composition to any one of claims 1 to 5 to form a microemulsion.
14. Use of a composition according to any one of claims 1 to 5 to prevent growth of micro-organisms in an oil and water mixture.
EP97920831A 1997-05-02 1997-05-02 Microemulsions Expired - Lifetime EP0984827B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/GB1997/001223 WO1998050139A1 (en) 1997-05-02 1997-05-02 Surfactant mixture

Publications (2)

Publication Number Publication Date
EP0984827A1 true EP0984827A1 (en) 2000-03-15
EP0984827B1 EP0984827B1 (en) 2008-03-05

Family

ID=10806367

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97920831A Expired - Lifetime EP0984827B1 (en) 1997-05-02 1997-05-02 Microemulsions

Country Status (9)

Country Link
US (1) US20020032130A1 (en)
EP (1) EP0984827B1 (en)
JP (1) JP2001523293A (en)
AT (1) ATE387953T1 (en)
AU (1) AU741967B2 (en)
CA (1) CA2288130C (en)
DE (1) DE69738549T2 (en)
GB (1) GB2340418C (en)
WO (1) WO1998050139A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9493709B2 (en) 2011-03-29 2016-11-15 Fuelina Technologies, Llc Hybrid fuel and method of making the same
US10308885B2 (en) 2014-12-03 2019-06-04 Drexel University Direct incorporation of natural gas into hydrocarbon liquid fuels
SE2050672A1 (en) * 2020-06-09 2021-12-10 Biobase Sweden Ab Microemulsions, viscous substances and their uses

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6716801B2 (en) * 1997-05-02 2004-04-06 Pauline Abu-Jawdeh Compositions and method for their preparation
GB2364713B (en) * 1999-03-06 2003-08-27 Pauline Abu-Jawdeh Compositions for preparing water-in-fuel microemulsions
KR20020088732A (en) * 2001-05-21 2002-11-29 남광식 Cutting oil dilution liquid and its dilution method and cutting oil supply method
GB2434372A (en) * 2006-01-20 2007-07-25 Palox Offshore S A L Water-in-oil microemulsions
JP5204414B2 (en) * 2007-02-27 2013-06-05 Jx日鉱日石エネルギー株式会社 Cutting / grinding method using oil containing ultra fine water droplets
GB2463030B (en) * 2008-08-28 2010-08-11 Formatex Method of determining particulate solids contamination in a liquid hydrocarbon
GB0913644D0 (en) 2009-08-05 2009-09-16 Palox Offshore S A L Compositions for preparing emulsions
BR112012006085B1 (en) 2009-10-14 2021-02-09 Palox Limited use of at least one ethoxylate (c6-c15) alcohol having from 2 to 12 o groups and at least one (c8-c24) alkyl starch (c1-c6) alkyl betaine in a liquid hydrocarbon fuel, method to reduce or eliminate formation, in a hydrocarbon liquid fuel, of ice particles, aircraft refueling method, with a hydrocarbon liquid fuel and aircraft fuel
GB201001923D0 (en) 2010-02-05 2010-03-24 Palox Offshore S A L Protection of liquid fuels
DE102016107522A1 (en) 2016-04-22 2017-10-26 Basf Se A fuel additive device, method for adding fuel and use of the same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE554495A (en) * 1956-02-02
GB1075196A (en) * 1965-04-07 1967-07-12 Shell Int Research Improvements in or relating to emulsifiable lubricating oil compositions
DE3607193A1 (en) * 1986-03-05 1987-10-01 Henkel Kgaa LIQUID SURFACTANT BLENDS

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9850139A1 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9493709B2 (en) 2011-03-29 2016-11-15 Fuelina Technologies, Llc Hybrid fuel and method of making the same
US10308885B2 (en) 2014-12-03 2019-06-04 Drexel University Direct incorporation of natural gas into hydrocarbon liquid fuels
SE2050672A1 (en) * 2020-06-09 2021-12-10 Biobase Sweden Ab Microemulsions, viscous substances and their uses
SE544637C2 (en) * 2020-06-09 2022-10-04 Biobase Sweden Ab Microemulsions and their uses

Also Published As

Publication number Publication date
ATE387953T1 (en) 2008-03-15
GB2340418B (en) 2001-11-07
CA2288130C (en) 2006-09-19
JP2001523293A (en) 2001-11-20
DE69738549D1 (en) 2008-04-17
CA2288130A1 (en) 1998-11-12
GB2340418A (en) 2000-02-23
EP0984827B1 (en) 2008-03-05
GB2340418C (en) 2011-07-25
WO1998050139A1 (en) 1998-11-12
AU741967B2 (en) 2001-12-13
GB9923909D0 (en) 1999-12-08
US20020032130A1 (en) 2002-03-14
DE69738549T2 (en) 2009-04-02
AU2706297A (en) 1998-11-27

Similar Documents

Publication Publication Date Title
CN106118834B (en) A kind of aluminum alloy cutting fluid with long service life and preparation method thereof
CN105861135B (en) Green metal cutting fluid and preparation method thereof
CA2288130C (en) Water-in-oil microemulsions and their preparation
US3429909A (en) Secondary aminoalcohol-boric acid reaction product and production thereof
CN106164040B (en) High-performance water dilution type oiliness additive for the application of polymetallic intermetallic composite coating
EP0178177B1 (en) Soluble-oil cutting fluid
DE19983009B4 (en) Metalworking lubricant composition
KR20180096608A (en) Metalworking fluids
EP2110426B1 (en) Metalworking fluid and metalworking method
EP0120665B1 (en) Soluble oil cutting fluid
JPH03229631A (en) Novel biodegradation resisting surfactant and cutting oil compound using same
US3791974A (en) Bacterial spoilage inhibited metal working lubricant compositions
JP2795890B2 (en) Aqueous metalworking oil
JPH05505806A (en) Esters and liquids containing them
JP3912837B2 (en) Water-soluble processing oil
AU628454B2 (en) Synthetic metalworking fluid
JPH08302379A (en) Bacteristat and water-base or emulsion-base metal processing composition containing same
WO1992007053A1 (en) Metal working fluid
CA1161026A (en) Inherently bactericidal metal working fluid
RU2133261C1 (en) Method of preparing emulsol for machining of metals
JPH0445557B2 (en)
CA1059980A (en) Cutting oil compositions having low air misting compositions
GB2305934A (en) Metal working
CA1067480A (en) Lubricant-coolant emulsion additive
JPH0730351B2 (en) Antibacterial water-soluble cutting fluid

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19991021

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL PAYMENT 19991021;LT PAYMENT 19991021;LV PAYMENT 19991021;RO PAYMENT 19991021;SI PAYMENT 19991021

17Q First examination report despatched

Effective date: 20030217

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: PALOX OFFSHORE S.A.L.

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RTI1 Title (correction)

Free format text: MICROEMULSIONS

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Extension state: AL LT LV RO SI

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69738549

Country of ref document: DE

Date of ref document: 20080417

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080305

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080616

REG Reference to a national code

Ref country code: FR

Ref legal event code: RN

LTIE Lt: invalidation of european patent or patent extension

Effective date: 20080305

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080305

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
REG Reference to a national code

Ref country code: FR

Ref legal event code: FC

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080305

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080605

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080805

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080305

EN Fr: translation not filed
ET Fr: translation filed
EN Fr: translation not filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080531

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080531

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080305

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080531

26N No opposition filed

Effective date: 20081208

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080502

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080305

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080502

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080606

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 69738549

Country of ref document: DE

Representative=s name: ABK PATENTANWAELTE, DE

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

Free format text: REGISTERED BETWEEN 20110721 AND 20110727

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 69738549

Country of ref document: DE

Representative=s name: ABK PATENTANWAELTE, DE

Effective date: 20110803

Ref country code: DE

Ref legal event code: R081

Ref document number: 69738549

Country of ref document: DE

Owner name: PALOX LTD., CY

Free format text: FORMER OWNER: PALOX OFFSHORE S.A.L., BEIT-MERY, LB

Effective date: 20110803

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

Owner name: PALOX LIMITED, CY

Effective date: 20110822

REG Reference to a national code

Ref country code: FR

Ref legal event code: EERR

Free format text: CORRECTION DE BOPI 08/52 - 3.2.

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20160512

Year of fee payment: 20

Ref country code: DE

Payment date: 20160506

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20160527

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 69738549

Country of ref document: DE

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20170501

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20170501