EP0963262A1 - CREUSET ET MOULE INTEGRES DESTINES A DES MOULAGES DE GAMA-TIAl DE FAIBLE COUT - Google Patents

CREUSET ET MOULE INTEGRES DESTINES A DES MOULAGES DE GAMA-TIAl DE FAIBLE COUT

Info

Publication number
EP0963262A1
EP0963262A1 EP98911363A EP98911363A EP0963262A1 EP 0963262 A1 EP0963262 A1 EP 0963262A1 EP 98911363 A EP98911363 A EP 98911363A EP 98911363 A EP98911363 A EP 98911363A EP 0963262 A1 EP0963262 A1 EP 0963262A1
Authority
EP
European Patent Office
Prior art keywords
pattern
sleeve
crucible
shell
mold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP98911363A
Other languages
German (de)
English (en)
Other versions
EP0963262B1 (fr
Inventor
Jerry C. Lasalle
David G. Jevens
John F. Ryan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
AlliedSignal Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AlliedSignal Inc filed Critical AlliedSignal Inc
Publication of EP0963262A1 publication Critical patent/EP0963262A1/fr
Application granted granted Critical
Publication of EP0963262B1 publication Critical patent/EP0963262B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns

Definitions

  • the present invention relates generally to crucibles for casting. More particularly, the present invention provides a one piece integrated crucible and invested mold for use in the casting of reactive metals, particularly complex shapes thereof.
  • Reactive metals such as titanium or titanium aluminid ⁇ s
  • crucibles comprising of alumina, zircon, or silicates which are typically used in casting metals such as iron, nickel or aluminum.
  • Turbocharger rotors are typically cast using nickel superalloy which can be easily melted and cast using invested mold having a zircon facecoat and an alumina-silicate crucible attached to the top ofthe mold. Molten titanium aluminide will rapidly react with the alumina-silicate crucible making casting impossible.
  • Candidate crucible materials include yttria (Y 2 O 3 ), thoria (ThO 2 ), calcia (CaO) and other exotic rare earth oxides. Thoria is radioactive and suffers from poor thermal shock resistance. For this reason it has not been exploited industrially. However,
  • yttria crucibles are very expensive, $50 to $ 100
  • the alumina-silicate crucibles used for nickel superalloy castings are less than $ 1. Since titanium and titanium aluminide castings compete with nickel castings in a wide variety of applications, the high cost of yttria crucibles effectively prices titanium and titanium aluminide castings out of the market. This is particularly important for cost sensitive applications, for example automotive applications.
  • Calcia is also a potential refractory material for titanium and titanium aluminides due to its thermal stability.
  • US Patent No. 4,710,481 to Degawa et. al. discloses melting titanium and titanium alloys in calcia crucibles.
  • calcia is highly hydrophilic and spontaneously hydrates in ambient levels of atmospheric moisture. The hydration is accompanied by volume changes which cause cracking and spallation.
  • Calcia crucibles can spontaneously crack after only hours of exposure to atmospheric moisture. For this reason calcia is an impractical material for a crucible in commercial, industrial environments.
  • the present invention provides a graphite crucible attached directly to the top of an invested mold in the shape of the complex molded part, a turbocharger rotor for the specif i c embodiments disclosed herein, to form an integrated unit.
  • a method for producing the integrated crucible and mold is characterized by the steps of attaching an investment pattern to a cylindrical graphite crucible and building an investment mold shell around the pattern and a mating portion of the crucible.
  • the mold shell is created by dipping the pattern and crucible mating portion in an inert ceramic facecoa t slurry, allowing the dipcoat layer to partially dry and/or cure, applying a layer of ceramic stucco over the dipcoat and laminating additional layers of dipcoat and stucco to achieve the desired thickness mold shell.
  • the embodiment of the invention described in detail subsequently, provides a one piece crucible/mold system suitable for casting a metal part in vacuum at temperatures exceeding 1400°C .
  • the method of employing the apparatus of the invention for cas t ing of complex components takes advantage of the rapid melting and casting of the ⁇ -TiAl to
  • Carbon is a known contaminant of ⁇ - TiAl. At low levels, i.e. under 2000 ppm (wt%) it is often added to improve creep
  • FIG. 1 is a section elevation view of the integrated graphite crucible and invested mold
  • FIG. 2 is a pictorial view of an exemplary turbocharger rotor manufacturable from ⁇ -TiAl using the present invention.
  • the integral crucible and mold includes a cylindrical graphite sleeve 10 having a bottom 12 adapted to accommodate attachment of a polystyrene invested mold pattern 14 having an attachment runner 15.
  • the attachment runner is sealingly attached to the sleeve with wax 16.
  • the sleeve is sized to accommodate a desired meitstock billet 17.
  • An investment shell 18 is constituted by laminations of a facecoat slurry 20 and ceramic stucco 22 (shown only over a portion of the section for clarity), which extend over and adhere to a bottom mating portion of the graphite sleeve.
  • the hardened shell laminate After firing, which results in vaporization of the pattern, the hardened shell laminate is fixedly attached to the graphite sleeve forming an integral crucible and mold for casting of the desired part. .
  • An aperture 24 in the bottom face of the sleeve provides a flow path for the molten casting metal into the mold shell while the rim 26 retains the meitstock billet in the crucible in a position for induction heating.
  • a method for creating and employing the apparatus of the present invention includes the steps of attaching the polystyrene turbocharger wheel pattern to the cylindrical graphite sleeve by dipping the- top of the polystyrene pattern in hot wax and inserting it into the recess in the bottom of the graphite sleeve.
  • An investment shell is next built around the polystyrene pattern and the lower portion of the sleeve.
  • the investment mold process begins with dipping the pattern made of wax or plastic having the shape of the desired casting in a facecoat slurry made from any ceramic inert to ⁇ -TiAl, for example, yttria or calcia.
  • the crucible/invested mold assembly is then transferred while still hot from the furnace and placed in a casting chamber and evacuated.
  • a cylindrical meitstock billet of the casting metal is inserted in the crucible.
  • the metal is next rapidly melted by inductively heating the graphite crucible. Since graphite is a strong susceptor, the crucible is quickly heated to the melting temperature of the ⁇ -TiAl.
  • the molten metal falls directly into the attached invested mold with the assistance of gravity with a minimum of superheat and hold time.
  • the short hold time and low superheat prevents significant contamination by carbon from the crucible.
  • the short drop distance attained as a result of the one piece design of the crucible/investment mold, allows full fill in thin sections. Greater drop distances, as would be required by two piece
  • the graphite crucible/invested turbocharger mold assembly was then transferred while still hot from the furnace, charged with the casting metal meitstock billet, placed under a quartz bell jar and evacuated.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Golf Clubs (AREA)
  • Mold Materials And Core Materials (AREA)
  • Adornments (AREA)
  • Physical Vapour Deposition (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
EP98911363A 1997-01-27 1998-01-27 Procede pour la production d'un creuset et moule integres destines a des moulages de gamma-tial de faible cout Expired - Lifetime EP0963262B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US3604197P 1997-01-27 1997-01-27
US36041P 1997-01-27
US814398A 1998-01-16 1998-01-16
US8143 1998-01-16
PCT/US1998/001672 WO1998032557A1 (fr) 1997-01-27 1998-01-27 CREUSET ET MOULE INTEGRES DESTINES A DES MOULAGES DE η-TiAl DE FAIBLE COUT

Publications (2)

Publication Number Publication Date
EP0963262A1 true EP0963262A1 (fr) 1999-12-15
EP0963262B1 EP0963262B1 (fr) 2002-05-02

Family

ID=26677855

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98911363A Expired - Lifetime EP0963262B1 (fr) 1997-01-27 1998-01-27 Procede pour la production d'un creuset et moule integres destines a des moulages de gamma-tial de faible cout

Country Status (9)

Country Link
EP (1) EP0963262B1 (fr)
JP (1) JP2001509083A (fr)
CN (1) CN1101284C (fr)
AT (1) ATE216929T1 (fr)
BR (1) BR9807084A (fr)
DE (1) DE69805164T2 (fr)
ES (1) ES2176986T3 (fr)
PT (1) PT963262E (fr)
WO (1) WO1998032557A1 (fr)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6749006B1 (en) 2000-10-16 2004-06-15 Howmet Research Corporation Method of making investment casting molds
US6663347B2 (en) * 2001-06-06 2003-12-16 Borgwarner, Inc. Cast titanium compressor wheel
DE10209346B4 (de) 2002-03-02 2004-02-19 Daimlerchrysler Ag Herstellungsverfahren für ein mehrteiliges Ventil für Verbrennungsmotoren
PT103018A (pt) * 2003-09-12 2005-03-31 Univ Do Minho Processo para obtencao de pecas em g-tiai por fundicao
FR2870148B1 (fr) * 2004-05-12 2006-07-07 Snecma Moteurs Sa Procede de fonderie a cire perdue avec couche de contact
FR2870147B1 (fr) * 2004-05-12 2007-09-14 Snecma Moteurs Sa Procede de fonderie a cire perdue
US7258158B2 (en) 2004-07-28 2007-08-21 Howmet Corporation Increasing stability of silica-bearing material
US8048365B2 (en) * 2007-04-30 2011-11-01 General Electric Company Crucibles for melting titanium alloys
DE102009018801A1 (de) 2009-04-24 2009-11-05 Daimler Ag Turbolader-Anordnung
CN101875106B (zh) * 2009-11-20 2011-12-28 北京科技大学 一种定向凝固高铌钛铝基合金的制备方法
CN101984321B (zh) * 2010-11-23 2012-05-23 北京科技大学 一种钛铝合金定向凝固用坩埚型模的制备方法
US8858697B2 (en) 2011-10-28 2014-10-14 General Electric Company Mold compositions
CN102527936B (zh) * 2012-01-19 2013-04-10 沈阳铸造研究所 一种用于低膨胀合金精密成形的石墨型铸造方法
US9011205B2 (en) 2012-02-15 2015-04-21 General Electric Company Titanium aluminide article with improved surface finish
US8932518B2 (en) 2012-02-29 2015-01-13 General Electric Company Mold and facecoat compositions
US8906292B2 (en) 2012-07-27 2014-12-09 General Electric Company Crucible and facecoat compositions
US8708033B2 (en) 2012-08-29 2014-04-29 General Electric Company Calcium titanate containing mold compositions and methods for casting titanium and titanium aluminide alloys
US8992824B2 (en) 2012-12-04 2015-03-31 General Electric Company Crucible and extrinsic facecoat compositions
US9592548B2 (en) 2013-01-29 2017-03-14 General Electric Company Calcium hexaluminate-containing mold and facecoat compositions and methods for casting titanium and titanium aluminide alloys
US9511417B2 (en) 2013-11-26 2016-12-06 General Electric Company Silicon carbide-containing mold and facecoat compositions and methods for casting titanium and titanium aluminide alloys
US9192983B2 (en) 2013-11-26 2015-11-24 General Electric Company Silicon carbide-containing mold and facecoat compositions and methods for casting titanium and titanium aluminide alloys
US10391547B2 (en) 2014-06-04 2019-08-27 General Electric Company Casting mold of grading with silicon carbide
DE102018109322A1 (de) * 2018-04-19 2019-10-24 Engel Austria Gmbh Aufschmelzeinheit für eine Formgebungsmaschine und Formgebungsmaschine
CN112108641A (zh) * 2019-06-19 2020-12-22 中冶宝钢技术服务有限公司 用于中间包耐材内衬整体浇注的模芯定位方法
CN118513509A (zh) * 2024-07-23 2024-08-20 洛阳双瑞精铸钛业有限公司 一种钛及钛合金表壳铸件及制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01157759A (ja) * 1987-07-25 1989-06-21 Asahi Roentgen Kogyo Kk チタンまたはチタン合金精密鋳造方法およびその装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9832557A1 *

Also Published As

Publication number Publication date
EP0963262B1 (fr) 2002-05-02
ES2176986T3 (es) 2002-12-01
ATE216929T1 (de) 2002-05-15
WO1998032557A1 (fr) 1998-07-30
DE69805164D1 (de) 2002-06-06
CN1101284C (zh) 2003-02-12
CN1244147A (zh) 2000-02-09
JP2001509083A (ja) 2001-07-10
PT963262E (pt) 2002-09-30
BR9807084A (pt) 2000-04-18
DE69805164T2 (de) 2002-10-31

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