EP0946765A1 - Procede et dispositif de recuperation hydrometallurgique du zinc - Google Patents
Procede et dispositif de recuperation hydrometallurgique du zincInfo
- Publication number
- EP0946765A1 EP0946765A1 EP97933768A EP97933768A EP0946765A1 EP 0946765 A1 EP0946765 A1 EP 0946765A1 EP 97933768 A EP97933768 A EP 97933768A EP 97933768 A EP97933768 A EP 97933768A EP 0946765 A1 EP0946765 A1 EP 0946765A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- residue
- desired product
- solid residue
- mixed
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000011084 recovery Methods 0.000 title claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 10
- 239000011701 zinc Substances 0.000 title claims description 10
- 229910052725 zinc Inorganic materials 0.000 title claims description 10
- 238000000034 method Methods 0.000 claims abstract description 69
- 239000002699 waste material Substances 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims abstract description 15
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 8
- 230000003134 recirculating effect Effects 0.000 claims abstract description 5
- 239000000047 product Substances 0.000 claims description 47
- 239000007787 solid Substances 0.000 claims description 25
- 239000002244 precipitate Substances 0.000 claims description 20
- 238000000926 separation method Methods 0.000 claims description 18
- 238000001556 precipitation Methods 0.000 claims description 17
- 239000010802 sludge Substances 0.000 claims description 15
- 238000002386 leaching Methods 0.000 claims description 14
- 238000005549 size reduction Methods 0.000 claims description 9
- 238000010992 reflux Methods 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 4
- 238000005342 ion exchange Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000000638 solvent extraction Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 230000001419 dependent effect Effects 0.000 claims 1
- 238000010790 dilution Methods 0.000 claims 1
- 239000012895 dilution Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 5
- 235000011941 Tilia x europaea Nutrition 0.000 description 5
- 239000004571 lime Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 3
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 3
- 229940007718 zinc hydroxide Drugs 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 1
- 239000005750 Copper hydroxide Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229960004887 ferric hydroxide Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 108700012359 toxins Proteins 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/007—Wet processes by acid leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/28—Obtaining zinc or zinc oxide from muffle furnace residues
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/30—Obtaining zinc or zinc oxide from metallic residues or scraps
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/34—Obtaining zinc oxide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention relates to a process for recovering zinc or other desired products from waste and process residues, in particular, but not exclusively those blast furnace residues produced from zinc smelting and steel making (oxygen) operations.
- Waste and process blast furnace slags often contain substances which are valuable and/or difficult to dispose of, for example, containing hazardous metals and/or toxins.
- There are many known ways of removing such products from the solid residue such as ion exchange, solvent extraction or precipitation processes.
- the TETRA Europe Ltd High Density Sludge (HDS) Direct Recycle and Thickened Recycle processes are particularly useful in the removal of such products by precipitation.
- the present invention seeks to provide a method and apparatus to recover desirable constituents from a waste product .
- a process for recovering a desired product from a mixed-solid residue comprising the steps of:
- step c) treating the mixed-solid residue with an acid to make the desired product soluble in the leachate; b) leaching the desired product into the leachate from the mixed-solid residue; c) separating the desired product from the leachate by a precipitation process forming a precipitation residue and the desired product; d) recirculating at least part of the precipitation residue to step a) and/or adding at least some of the waste-solid residue directly to step c).
- a process for recovering a desired product from a residue which includes the step of recirculating either a residue formed in one stage of the process to an earlier stage of the process or the solid waste residue to a later stage of the process.
- the invention uses these residues as a reagent in the step to which the residue is recirculated and thus reduces the amount of reagents which have to be added to the overall process thus reducing the cost of running the process.
- the earlier stage of the process is prior to a treatment step where acid is added to lower the pH of the waste being treated.
- the recirculation of the residue has the advantage for example of reducing the amount of acid required. Further, the recirculation step seems to assist the separation of desired products from the waste and generally improve the efficiency of the process, especially in the preferred and illustrated embodiments of the invention.
- a recovery apparatus for recovering a desired product from a mixed-solid residue comprising:
- the present invention thus provides a practical method of recovery from residues for many different metals and compounds and has particular utility when applied to zinc recovery. It is believed that the invention will make it viable to treat different types of waste.
- the residue is prepared to make it more susceptible to size reduction, to physical separation of desired products, and to solubilising of desired products in a leach solution.
- the preparation step comprises using the residue as a reagent in leachate neutralisation or pH adjustment and precipitation to selectively precipitate the desired products.
- the refluxing of residue is continued back along the various stages until finally the residue is refluxed to the first step, e.g. to the size reduction plant. Over this multi-stage reflux recirculates the residue from the separation stages to the treatment stage.
- the prepared and size-reduced residue is treated with combinations of sulphuric, hydrochloric and nitric acids to make the desired products soluble in the leach solution.
- the residue may be entrained in water before passing through the acids leaching process; or residue may be reacted directly with the acids before passing through the water dilution process.
- the separating step c) comprises treating the leachate in a system selected from the group consisting of: a precipitation process; an ion exchange process; a solvent extraction process; and mixtures thereof.
- the treatment step e) consists of treating the leachate in one or more high density sludge (HDS) processes operating in parallel and/or series.
- HDS high density sludge
- residue in the HDS processes is particularly advantageous to use residue in the HDS processes as the neutralising agent.
- the residue is separated from the HDS underflow sludge and refluxed to the prior neutralising stage and ultimately to the size reduction plant for final preparation before physical separation of desired products and leaching of desired products in the leaching solution.
- the act of reflux reduces the amount of neutralising agent required and the power required to size reduce the residue.
- the high calcium oxide content of the residue readily reacts with acid leach solution, and thus provides the additional benefits of acting as a neutralising agent. This leads to the breaking the internal structure of the vitreous residue which has the effect of reducing power consumption of the size reduction process and improve physical separation of desired products.
- Figure 1 schematically illustrates a multi-stage recovery process according to a preferred embodiment of the invention.
- Figure 1 depicts a particularly preferred embodiment for recovering zinc and other materials from blast furnace slag.
- Waste residue is fed in to the process and in the illustrated embodiment the size of the residue particles are reduced in a size reduction step.
- the size reduction step reduces the typically 3mm uniformly-sized vitreous particles to about 50 - 200 micron particles size.
- size reduction step may not be required in other embodiments depending on the initial size of the waste particles and the separation steps which are to be employed.
- the reduced-sized particles then undergo a physical separation step where products such as lead, gold and silver are recovered by density and/or magnetic means.
- products such as lead, gold and silver are recovered by density and/or magnetic means.
- the precise nature of this step will depend upon the constitution of the waste and this step may not be required in some cases.
- the waste then undergoes a series of leaching operation to leach desired products in to the leachate.
- water is used as the major constituent of the leachate. from the different separation operations.
- the leaching operation may be in batch or continuous stirred tank reactors, or by plug flow pipe reactor means. Unwanted solid materials are removed from the leachate by, for example, gravity means with residue dewatered to produce a cake.
- the leachate is then treated (neutralised) in a series of treatment stages to selectively precipitate desired products at each stage.
- the preferred illustrated embodiment shows a four treatment stage process, but the number and nature of the treatment stages will vary depending upon the constitution of the waste and the desirability/necessity of recovering the various constituents from the waste.
- each treatment stage is conducted at a different pH to form different precipitates containing the desired products at each stage.
- the first treatment stage uses calcium carbonate to adjust the pH of the leachate to about pH2 to precipitate calcium sulphate dihydrate (gypsum) . If alternatively a different compound or mixture of compounds was used instead of calcium carbonate then the precipitate may, of course, differ.
- the gypsum is recovered from the precipitate following dewatering and drying in a normal fashion.
- the second treatment stage uses lime to adjust the pH of the leachate to about pH6 to pH7 to precipitate principally ferric/ferrous hydroxide. If a different base was used instead of lime then an alternative iron salt may be formed. The iron product is recovered as a cake following dewatering of the sludge.
- the pH of the leachate is further adjusted to about pH8 to pH9 with more lime to precipitate principally ferric hydroxide, aluminium hydroxide, copper hydroxide and arsenic.
- ferric salts may be added to the leachate to co-precipitate iron with arsenic. If a different base was used instead of lime then an alternative precipitate may be formed.
- the pH of the leachate is further adjusted to about pHlO to pHll with more lime to precipitate principally zinc hydroxide.
- the zinc hydroxide may be recovered through dewatering of the sludge to produce a zinc hydroxide cake or alternatively the hydroxide can be combined with an acid to form a different salt such as zinc sulphate, zinc chloride or zinc bromide.
- the initial waste residue or size-reduced residue
- the at least some of the residue is added to the final (fourth) separation stage. From the fourth stage the residue is further refluxed upstream to the third separation stage and then refluxed to second separation stage and then on to the first separation stage.
- the precipitate residue from the separating means e.g. the underflow sludge of a HDS reactor
- the precipitate residue from the separating means is recirculated back to the treatment stage. It is most preferred if the precipitate residue is recirculated and the waste-solid residue is added to the separating means as this maximises the befits of the present invention.
- the actual number of refluxes and the precise nature and direction of a reflux will depend on the particular recovery process being adopted. Generally however the reflux operation provides a way of significantly reducing the amount of reagent needed in some separation stages and therefore significantly improves the efficiency and cost- effectiveness of the overall process. It is preferred if at least one of the separation stage ⁇ comprises a high density sludge (HDS) treatment and then the refluxed residue can be taken from the underflow sludge of the HDS process.
- HDS high density sludge
- the process is further advantageously enhanced by using the leaching technique of adding acid directly to the residue and subsequently diluting the product with water.
- This technique minimises the hydrolysis of silica in the residue and minimises the formation of aluminium silicate/ ' silicic acid compounds which may affect the subsequent leachate neutralisation and precipitation processes.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9615946 | 1996-07-30 | ||
GB9615946A GB9615946D0 (en) | 1996-07-30 | 1996-07-30 | Zinc recovery process |
PCT/GB1997/002023 WO1998004752A1 (fr) | 1996-07-30 | 1997-07-25 | Procede et dispositif de recuperation hydrometallurgique du zinc |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0946765A1 true EP0946765A1 (fr) | 1999-10-06 |
Family
ID=10797711
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97933768A Withdrawn EP0946765A1 (fr) | 1996-07-30 | 1997-07-25 | Procede et dispositif de recuperation hydrometallurgique du zinc |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0946765A1 (fr) |
AU (1) | AU3701197A (fr) |
GB (1) | GB9615946D0 (fr) |
WO (1) | WO1998004752A1 (fr) |
ZA (1) | ZA976788B (fr) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4610722A (en) * | 1985-01-31 | 1986-09-09 | Amax Inc. | Process for metal recovery from steel plant dust |
US4670051A (en) * | 1985-03-19 | 1987-06-02 | Hydrochem Developments Ltd. | Oxidation process for releasing metal values in which nitric acid is regenerated in situ |
GB8928368D0 (en) * | 1989-12-15 | 1990-02-21 | Sherritt Gordon Ltd | Recovery of metal values from zinc plant residues |
ZA928157B (en) * | 1991-10-25 | 1993-06-09 | Sasox Processing Pty Ltd | Extraction or recovery of metal values. |
DE4230223A1 (de) * | 1992-09-10 | 1994-03-17 | Hoechst Ag | Verfahren und Anlage zum Entfernen von Blei, Cadmium und Zink aus Stäuben |
FR2705102B1 (fr) * | 1993-05-12 | 1995-08-11 | Rhone Poulenc Chimie | Procede de traitement de compositions contenant des metaux precieux et autres elements de valeur en vue de leur recuperation. |
-
1996
- 1996-07-30 GB GB9615946A patent/GB9615946D0/en active Pending
-
1997
- 1997-07-25 EP EP97933768A patent/EP0946765A1/fr not_active Withdrawn
- 1997-07-25 AU AU37011/97A patent/AU3701197A/en not_active Abandoned
- 1997-07-25 WO PCT/GB1997/002023 patent/WO1998004752A1/fr not_active Application Discontinuation
- 1997-07-30 ZA ZA9706788A patent/ZA976788B/xx unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9804752A1 * |
Also Published As
Publication number | Publication date |
---|---|
AU3701197A (en) | 1998-02-20 |
GB9615946D0 (en) | 1996-09-11 |
ZA976788B (en) | 1998-02-11 |
WO1998004752A1 (fr) | 1998-02-05 |
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