EP0927330B1 - Explosionsfeste, explosionsrichtung steuernde verpackung - Google Patents

Explosionsfeste, explosionsrichtung steuernde verpackung Download PDF

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Publication number
EP0927330B1
EP0927330B1 EP97922297A EP97922297A EP0927330B1 EP 0927330 B1 EP0927330 B1 EP 0927330B1 EP 97922297 A EP97922297 A EP 97922297A EP 97922297 A EP97922297 A EP 97922297A EP 0927330 B1 EP0927330 B1 EP 0927330B1
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EP
European Patent Office
Prior art keywords
band
container
bands
poly
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP97922297A
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English (en)
French (fr)
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EP0927330A1 (de
Inventor
Igor Palley
Gary Allan Harpell
Max Wilhelm Gerlach
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Honeywell International Inc
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Honeywell International Inc
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Publication of EP0927330A1 publication Critical patent/EP0927330A1/de
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D90/00—Component parts, details or accessories for large containers
    • B65D90/22—Safety features
    • B65D90/32—Arrangements for preventing, or minimising the effect of, excessive or insufficient pressure
    • B65D90/325—Arrangements for preventing, or minimising the effect of, excessive or insufficient pressure due to explosion, e.g. inside the container
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42—AMMUNITION; BLASTING
    • F42D—BLASTING
    • F42D5/00—Safety arrangements
    • F42D5/04—Rendering explosive charges harmless, e.g. destroying ammunition; Rendering detonation of explosive charges harmless
    • F42D5/045—Detonation-wave absorbing or damping means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42—AMMUNITION; BLASTING
    • F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B39/00—Packaging or storage of ammunition or explosive charges; Safety features thereof; Cartridge belts or bags
    • F42B39/14—Explosion or fire protection arrangements on packages or ammunition

Definitions

  • the present invention relates to container assemblies. More particularly, this invention relates to various blast resistant and blast directing container assemblies for receiving explosive articles and preventing or minimizing damage in the event of an explosion.
  • container assemblies have utility as containment and transport devices for hazardous materials such as gunpowder and explosives, e.g., bombs and grenades, particularly in aircraft where weight is an important consideration, and more particularly in the cargo holds and passenger cabins of the aircraft. They are also particularly useful to bomb squad personnel in combating terrorist and other threats.
  • a hardened luggage container is wrapped in a blanket woven from low density materials such as SPECTRA® fibers, commercially available from AlliedSignal Inc., and lined with a rigid polyurethane foam and perforated aluminum alloy sheet. A sandwich of this material covers four sides of the container in a seamless shell.
  • low density materials such as SPECTRA® fibers, commercially available from AlliedSignal Inc.
  • Doors provide a significant weak point for the container during an explosion since a blast from within the container forces a typical door outward. If the door is connected through a hinge and metal pin arrangement, the pins become dangerous projectiles. If the door slides in grooves or channels, the grooves or channels may bend or distort to cause failure of the container. It would thus be desirable to have a container design that eliminates the aforesaid problems with doors for access to the container's interior.
  • U.S.P. 5,312,182 discloses hardened cargo containers wherein the door engages by sliding in grooves/tracks with an interlock that ostensibly responds to such an explosive blast by gripping tighter to resist rupture of the device.
  • Other blast resistant and/or blast directing containers are described in European Patent Publication 0 572 965 A1 and in U.S.P. Nos. 5,376,426; 5,249,534; and 5,170,690.
  • Containers for storing and/or transporting explosives such as bombs, or suspected explosives are also known. See, for example, U.S.P. Nos. 5,225,622; 4,889,258; 4,432,285; 4,055,247; 4,027,601; and 3.786,956.
  • These containers are typically made of a high strength outer housing having a fixed shape and containing a structure for supporting the explosive out of contact with the housing.
  • High strength materials taught for forming the outer housing include metal, such as stainless steel or steel plate, and ballistic fiberglass.
  • Supporting structures taught include vermiculite in a binder, foamed plastic (such as styrofoam), foam rubber, and cardboard.
  • the containers generally are heavy and have a bulky, fixed shape or construction.
  • WO-A-9712195 constitutes prior art under Article 54(3) EPC. It describes blast resistant containers comprising at least three nested bands of material wherein the bands are oriented relative to one another to enclose a volume, and to form a container wall having a thickness substantially equivalent to the sum of the thicknesses of at least two of the bands.
  • US-A-4543872 describes a blast attenuator device comprising a collapsible/inflatable cylinder containing a foam therein.
  • EP-A-0204863 describes a method of blast suppression comprising forming an expanded foam barrier which is held in position by an inflatable barrier element. A variety of designs of barrier elements is described.
  • EP-A-0276918 forms the basis of the preamble of claim 1.
  • This document describes a bomb blast inhibitor comprising a series of vertically stacked chambers interconnected by holes, each chamber containing a liquid, such as water.
  • the bomb blast inhibitor may be deflated for storage.
  • the environment in which a container is to be used may have weight and space constraints, for example, the passenger cabin or cargo hold of an aircraft. Such constraints make desirable a collapsible container that folds into a compact shape for storage when not in use.
  • the present invention which was developed to overcome the deficiencies of the prior art, provides blast resistant and blast directing container assemblies, some of which are collapsible.
  • This invention is a blast resistant container assembly for receiving an explosive.
  • the container assembly is defined in claim 1.
  • the blast resistant container assembly comprises at least three collapsible, seamless bands of a blast resistant material and an aqueous foam.
  • the blast resistant material comprises high strength fibers having a tenacity of at least about 10 g/d and a tensile modulus of at least about 200 g/d.
  • the bands are nested one within the other when assembled with their longitudinal axes at right angles to one another to substantially enclose a volume and to form a container wall having a thickness substantially equivalent to the sum of the thicknesses of at least two of the bands.
  • the bands are collapsible for storage when disassembled.
  • the inner band preferably includes a foldable flap forming a lip on each side thereof and is stabilized to prevent twisting.
  • the inner band can be stabilized by consolidation if it comprises a composite material or by affixing rigid plates or other support structure thereto if not susceptible to consolidation.
  • the aqueous foam located within the inner band preferably has a density in the range of from about 0.01 to about 0.10 g/cm 3 , more preferably in the range of from about 0.03 to about 0.08 g/cm 3 . This embodiment is particularly useful as an aircraft in-cabin emergency containment system.
  • the three band box design of the preferred container assembly of this invention has several advantages over containers of the prior art. It eliminates the need for an entry door since access can be achieved through an open side or sides of the innermost band. This eliminates one of the weak points of the prior art containers: door and panel hinges with steel rods are no longer necessary and neither are door-channel interlock systems. Other modifications permit easy access to the container's interior for loading and unloading in spite of limited exterior space constraints.
  • the box is not impervious to explosive's gas and allows controlled release of the gas through the comers which contributes to the design function.
  • the box production is technology inexpensive and simple.
  • the bands of the box can be made rigid or flexible as desired. If the bands of the box are made with flexible edges and rigid faces , then they can be collapsed for more efficient storage and transported as a set of three or more essentially flat parts (bands) for subsequent assembly and use with the blast mitigating material.
  • Blast mitigating materials can absorb heat energy from the blast by an increase in temperature, phase transition, e.g., vaporization of water). They may collapse and absorb energy by crushing and/or visco-elastic effects. Condensable gases (in foams) may condense under elevated pressure, thereby liberating heat of condensation to the aqueous phase. Condensable gases will cause a decrease in shock wave velocity and through condensation transmit heat energy. Kinetic energy can be imparted to all of these materials.
  • aqueous foam with condensable gas as a foaming agent significantly lengthens the time of venting and reduces the hazard. As such, it is a preferred blast mitigating materials.
  • the numeral 10 indicates a blast resistant container assembly.
  • the construction of container assembly 10 is critical to the advantages of this invention.
  • the container comprises a set of at least three nested and mutually reinforcing four-sided continuous bands of material 11, 12, and 13 assembled into a cube. See FIGURES 1A, 1B, and 1C.
  • band is meant a thin, flat, volume-encircling strip.
  • the cross-section of the encircled volume may vary , although polygonal is preferred to circular, with rectangular being more preferred and square being most preferred, as depicted.
  • a first inner band 11 is filled with blast mitigating material 14 (depicted as an aqueous foam) and then nested within a slightly larger second band 12 which is nested within a slightly larger third band 13, all bands with their respective longitudinal axes perpendicular to one another.
  • each of the six panels forming the faces of the cubic container will have a thickness substantially equivalent to the sum of the thicknesses of at least two of the bands 11, 12 and 13, where they overlap, and every edge 15 of the container is covered by at least one band of material, 11, 12, or 13.
  • blast mitigating material 14 is placed or dispersed around the load within the first band 11.
  • the second structurally similar band 12 of slightly larger dimensions is placed over the first so that its longitudinal axis is perpendicular to that of first band 11 (see FIGURE 1D).
  • the third, similar yet larger, band 13 is slid over the second band 12, so that its longitudinal axis is perpendicular to the axes of both bands 11 and 12 (see FIGURE 1E).
  • the third band 13 completes the preferred blast resistant container assembly 10.
  • the fit between bands 11, 12 and 13 is not intended to be a gastight seal, but is a close fit to permit gas to vent gradually, in the event of an explosion, from the comers 16 of the cubic container.
  • the bands slide on one another, and therefore the frictional characteristics of their surfaces may need to be modified, as will be discussed in more detail later.
  • FIGURE 1G depicts a weight/load bearing frame 17 which may optionally be nested within container assembly 10 in the event that container assembly 10 is insufficiently rigid for bearing the items to be loaded therein.
  • Inner band 11 is slipped over the frame initially, and then assembly proceeds as earlier discussed.
  • Frame 17 may be made from metal or structural composite rods designed in a way to optimize the load bearing capacity of the structure and to minimize container weight.
  • second band 12 is replaced by band 12', which is a five-sided, discontinuous strip (see FIGURE 2A), i.e., band 12' comprises five substantially rectangular, preferably square as depicted, surfaces in series, which is one more than the four sides forming the rectangular cross-section thereof
  • Bands 11 and 13 and blast mitigating material 14 are the same as in the basic design.
  • band 12' is wrapped around filled inner band 11 with its first and fifth sides overlapping at one of the open sides of first band 11 to create flaps X and Y.
  • Third band 13 completes the blast resistant container assembly 10'. Access to one side of cubic container assembly 10' is achieved by removal of band 13 and opening flaps X and Y.
  • band 12' preferably is a nested band to prevent flaps X and Y being blown open during an explosion.
  • Container assembly 10' does not have a separate entry door and thus avoids all of the limitations presented by the same in the prior art.
  • inner band 11 is replaced by inner band 11'' which has lips 18 formed on both sides thereof prior to being filled with blast mitigating material 14 and subsequent assembly with the other bands 12 and 13.
  • Band 11'' can be made wider than needed, cut at each corner 16, and folded to create lips 18 on each side (see FIGURES 3A and 3B).
  • Lip 18 is a projecting edge or small flap which is substantially perpendicular to the plane of band 11'' in use - the next outermost band (in this instance band 12) will hold flap 18 in this relationship to band 11''.
  • lips 18 during an explosion of the container serves to limit the rate at which hot gases escape from the container after an explosion; this serves to prevent damage to nearby people and property, as well as to decrease the danger of the container catching fire.
  • Any inside band can be formed with lips; however, best results are obtained with the lips 18 on the innermost band 11''.
  • FIGURE 5C container assembly 10'''' formed by a first inner band 11'''' (see FIGURE 5A), substantially hexagonal in cross-section, filled with blast mitigating material 14 and nested in four-sided band 12'''' (FIGURE 5B), which is nested in four-sided band 13'''', which is nested in four-sided band 14''''.
  • the preference for the bands to have a polygonal cross-section is derived from the tendency for the container to deform to increase the internal volume during an explosion.
  • second band 12'''''' is split by design into two identical parallel and coaxial parts M and N in which inner band 11''''' is nested (or, which are placed over inner band 11''''').
  • the assembly of band 11''''' is with smaller parts (bands) M and N nested in outer band 13'''''.
  • Such a container assembly 10''''' would be much easier to load and unload than a comparable container assembly 10 of standard aircraft size, i.e., 1.82x1.82x1.82 m ((6x6x6 ft).
  • loading takes place when the first band 11'''''' is placed on a beam by a conventional lifting fork. Subsequently first band 11''''' is see-sawed up for band M to be placed around it. Band 11''''' is then stabilized for items 19 to be loaded onto first band 11'''''. After loading, band 11''''' is then filled with blast mitigating material 14 and then see-sawed in the other direction to permit band N to be placed therearound.
  • band 13'''''' is placed over the assembled bands as shown in FIGURES 6B and 6C.
  • the procedure is reversed for unloading container 10'''''.
  • Intermediate parts (bands) M and N do not have to be removed entirely for unloading, and can be slid in whatever direction is preferred, i.e., in opposition to one another, as depicted, or in the same direction. They can also be arranged to telescopically slide in the same direction.
  • Outer band 13''''' could similarly be made out of two or more sections as desired.
  • coaxial bands can be used in parallel, preferably abutting one another, to substitute for any one band in the basic three-band container concept of the invention.
  • all of the coaxial bands can have lips (e.g., see FIGURE 3B) or overlapping flaps (e.g., see FIGURE 2B).
  • all of the coaxial bands can have flaps but only those adjacent the edge can have a lip on the side adjacent to the edge. It is preferred that the outermost band comprises a single continuous band.
  • coaxial bands can also be coaxially nested one within the other to substitute for any one band in the basic three band container concept of the invention; the number of bands utilized as an equivalent may depend upon the desired rigidity of the equivalent. It is possible to have several flexible bands which, when nested coaxially, become rigid.
  • FIGURES 7A and 7B depict a blast resistant container assembly 20 that addresses the issue of an effective closure.
  • Container assembly 20 is a container with two bands of the three-band concept already discussed and having an access opening on one or more sides thereof.
  • FIGURE 7B depicts container assembly 20 in the open position for loading or unloading. Flap door 21 provides access to the interior from one side; there can be a similar access on one or more of the other side faces.
  • the explosive (not shown) and blast mitigating material 14 have already been loaded. It is preferred that both the door and the container be formed of a rigid material, which will be detailed later.
  • a band 22, preferably square in cross-section, is slipped onto container 20 to encircle its side faces and thereby secure closure of container 20 (see FIGURE 7A).
  • Band 22 may cover all or only a small fraction of flap door 21 when closed. At least about 20, preferably at least about 40, more preferably at least about 60, percent of the surface area of door 21 should be covered by band 22.
  • Band 22 slides to one side of flap door 21, as depicted in FIGURE 7B, or completely off of the container to permit access through door 21.
  • the shape of band 22's inner cross-section should conform to the portion of the container that it encircles.
  • a polygonal cross-section is preferred with rectangular being more preferred and square (as depicted) being most preferred.
  • band 22 holds door 21 in place. In the event that there was no door 21 covering the access opening, then at least about 50, preferably at least about 80, and more preferably substantially all, of the surface area of the access opening is covered by band 22.
  • FIGURES 8A-8F depict yet another blast resistant container assembly 30 which has loading and unloading capabilities when in a restricted space.
  • This design is very similar to the three-band concept already discussed, which is very blast-containment effective. Modification to the three-band concept is necessary to provide convenient access to the interior of the container within the space constraints of an aircraft cargo hold.
  • FIGURE 8A is depicted a honeycomb core panel 31 which provides structural rigidity to the fully assembled container assembly 30.
  • Panel 31 is a essentially a cube with a truncated edge 32 and an opening 33 on one face that will provide the basis for access to the interior of container when assembled.
  • a first inner band 34 is placed around panel 31 so that it covers opening 33.
  • the material forming band 34 is flexible and can be cut to create an upper 35 and a lower 36 access flap in band 34 at opening 33.
  • the intermediate band 37 is a continuous strip/band under which floor panel 39 is attached (see FIGURE 8C).
  • the outer band is a two-piece vertically sliding band consisting of sections 40 and 41 that can slide and telescope one 40 within the other 41 to open the container. Although it is preferred that sections 40 and 41 together completely cover flaps 35 and 36 when the container is closed, they may cover somewhat less than all of this area and still be effective.
  • the interior of section 41 is sized slightly larger than the exterior of section 40 (see FIGURE 8D) so that it can slide up over it to completely open access 33 as shown in FIGURE 8F.
  • Stops 38 are provided on the side of the container.
  • the rim on the bottom of stop 38 secures section 41 from falling down to the floor while the top of stop 38 secures section 40 from falling down inside of section 41.
  • FIGURE 8E depicts the closed completely assembled container assembly.
  • the telescoping feature of this design reduces the required extra space for loading or unloading to one-half that of the standard cubic box container. It would reduce the required extra space to one-third in the case of three telescoping sections, etc. Although more than three sections could theoretically be utilized, it would probably be impractical.
  • the telescoping feature of this design could also be used in the closure embodiment depicted in FIGURES 7A and 7B utilizing containers of the prior art.
  • inner band 11 is replaced by inner band 50 which has lips 18' formed on both sides thereof prior to assembly.
  • Band 52 can be made wider than needed and folded at its edges 15 to create lips 18' on each side.
  • Lip 18' is a projecting edge or small flap which is substantially perpendicular to the plane of band 52 in use - the next outermost band will hold lip/flap 18' in this relationship to band 52.
  • FIGURE 9A shows the use of reinforcing inserts for the inner band, i.e., a hardened square picture frame insert 51 for each of the four faces of the band, and the use of reinforcing inserts for the flaps on each side of the band, i.e., two hardened rectangular inserts 52 and two trapezoidal inserts 53.
  • These inserts 51, 52, and 53 are spaced from one another to permit folding the flaps to form lips 18'.
  • the flaps with trapezoidal inserts 53 oppose one another and are folded inward 90 degrees to form sides of a cube without having to cut the fabric along the edges between flaps.
  • the flaps with rectangular inserts 52 which also oppose one another, are then folded inward 90 degrees and attached to the other flaps, e.g., by mating VELCRO® brand hook and loop type fasteners 54.
  • the benefit of leaving the flaps/lip 18' uncut and connected is that they will be restrained from being flipped outward by the force of an explosion in the container assembly.
  • FIGURES 10A through 10I depict an aircraft in cabin emergency container assembly, in its disassembled kit form 60 (FIGURE 10A) through assembly (FIGURES B through F) to an emergency container assembly 70 (FIGURE 10G).
  • kit 60 comprises collapsed (folded) bands 62, 63 and 64; a canister 66 of blast mitigating material, preferably an aqueous foam; optional telescoping pole 67; and belts 68 for holding kit 60 together while stored.
  • FIGURE 10B shows the unfolding of inner band 63 at its edges 15 until fully erect at FIGURE 10C.
  • FIGURE 10D shows placement of suspect luggage 61 in the inner band 62 with closable flaps 65.
  • blast mitigating material 14 depicted as an aqueous foam, is dispersed into inner band 62 around suspect luggage 61 via canister 66. Flaps 65 are closed to form a lip, and inner band 62 is nested within band 63 with their longitudinal axes perpendicular to one another.
  • the third, similar yet larger, band 64 is slid over the second band 63 (see FIGURE 10F), so that its longitudinal axis is perpendicular to the axes of both bands 62 and 63.
  • the in cabin container assembly 70 is shown in FIGURE 10G.
  • FIGURE 10H shows the use of optional net 69 for holding the suspect luggage 61' out of contact with the sides of bands 62 and 63.
  • FIGURE 10I shows optional handles 71 through which telescoping pole 67 is placed for carrying the assembly 70. Handles 71 are taped (72) in place after assembly of container assembly 70.
  • a band is inflexible across the face or faces thereof.
  • Each band comprises a plurality of faces and edges, and may be substantially inflexible across the faces but retain its flexibility at the edges and still be considered “rigid.”
  • Such a band is also considered “collapsible” since its flexible edges act as pin-less hinges connecting the substantially inflexible faces, and the band can be essentially flattened by folding at least two of its edges.
  • flexibility is determined as follows. A length of the material is clamped horizontally along one side on a flat support surface with an unsupported overhang portion of length "L”. The vertical distance "D" that the unclamped side of the overhang portion drops below the flat support surface is measured.
  • the ratio D/L gives a measure of drapability. When the ratio approaches 1, the structure/face is highly flexible, and when the ratio approaches 0, it is very rigid or inflexible. Structures are considered rigid when D/L is less than about 0.2, more preferably less than about 0.1.
  • the structural designs of the present invention enhance the blast containment capability of the container. Blast containment capability is also enhanced with increased areal density of the container.
  • the "areal density" is the weight of a structure per unit area of the structure in kg/m 2 , as discussed in more detail in conjunction with the examples which follow below.
  • the preferred blast resistant materials utilized in forming the containers and bands of the present invention are oriented films, fibrous layers, and/or a combination thereof.
  • a resin matrix may optionally be used with the fibrous layers, and a film (oriented or not) may comprise the resin matrix.
  • Uniaxially or biaxially oriented films acceptable for use as the blast resistant material can be single layer, bilayer, or multilayer films selected from the group consisting of homopolymers and copolymers of thermoplastic polyolefins, thermoplastic elastomers, crosslinked thermoplastics, crosslinked elastomers, polyesters, polyamides, fluorocarbons, urethanes, epoxies, polyvinylidene chloride, polyvinyl chloride, and blends thereof Films of choice are high density polyethylene, polypropylene, and polyethylene/elastomeric blends. Film thickness preferably ranges from about 5-10 16 ⁇ m (0.2 to 40 mils), more preferably from about 12.7-50 8 ⁇ m (0.5 to 20 mils), most preferably from about 25.4-38 1 ⁇ m (1 to 15 mils.)
  • a fibrous layer comprises at least one network of fibers either alone or with a matrix.
  • Fiber denotes an elongated body, the length dimension of which is much greater than the transverse dimensions of width and thickness. Accordingly, the term fiber includes monofilament, multifilament, ribbon, strip, staple and other forms of chopped, cut or discontinuous fiber and the like having regular or irregular cross-sections.
  • the term fiber includes a plurality of any one or combination of the above.
  • the cross-sections of filaments for use in this invention may vary widely. They may be circular, flat or oblong in cross-section. They also may be of irregular or regular multi-lobal cross-section having one or more regular or irregular lobes projecting from the linear or longitudinal axis of the fibers. It is particularly preferred that the filaments be of substantially circular, flat or oblong cross-section, most preferably the former.
  • network is meant a plurality of fibers arranged into a predetermined configuration or a plurality of fibers grouped together to form a twisted or untwisted yarn, which yarns are arranged into a predetermined configuration.
  • the fibers or yarn may be formed as a felt or other nonwoven, knitted or woven (plain, basket, satin and crow feet weaves, etc.) into a network, or formed into a network by any conventional techniques.
  • the fibers are unidirectionally aligned so that they are substantially parallel to each other along a common fiber direction. Continuous length fibers are most preferred although fibers that are oriented and have a length of from about 7.6 to about 30.4 centimeters (3 to 12 inches) are also acceptable and are deemed “substantially continuous" for purposes of this invention.
  • At least about 10 weight percent of the fibers be substantially continuous lengths of fiber that encircle the volume enclosed by the container.
  • encircle the volume is meant in the band or hoop direction, i.e., substantially parallel to or in the direction of the band, as band has been previously defined and shown.
  • substantially parallel to or in the direction of the band is meant within ⁇ 10°.
  • the bands of the present invention be substantially seamless.
  • substantially seamless is meant that the band is seamless across each edge joining adjacent faces for more than at least one full wrap of the fibrous layer and also that at any given point on the band there is at least one wrap /layer that is seamless.
  • each face of a band is connected to another face at at least one common edge with a fibrous material that functions as a hinge therebetween; the preferred fibrous material comprises substantially continuous, parallel lengths of fiber perpendicular to the edge.
  • the continuous bands can be fabricated using a number of procedures.
  • the bands especially those without resin matrix, are formed by winding fabric around a mandrel and securing the shape by suitable securing means, e.g., heat and/or pressure bonding, heat shrinking, adhesives, staples, sewing and other securing means known to those of skill in the art.
  • Sewing can be either spot sewing, line sewing or sewing with intersecting sets of parallel lines. Stitches are typically utilized in sewing, but no specific stitching type or method constitutes a preferred securing means for use in this invention. Fiber used to form stitches can also vary widely.
  • Useful fiber may have a relatively low modulus or a relatively high modulus, and may have a relatively low tenacity or a relatively high tenacity.
  • Fiber for use in the stitches preferably has a tenacity equal to or greater than about 2 g/d and a modulus equal to or greater than about 20 g/d. All tensile properties are evaluated by pulling a 25.4 cm (10 in) fiber length clamped between barrel clamps at 25.4 cm/min (10 in/min) on an Instron Tensile Tester. In cases where it is desirable to make the band somewhat more rigid, pockets can be sewn in the fabric into which rigid plates may be inserted, or the plates themselves can be sewn into the band between wraps of material.
  • An advantage to the collapsible embodiments of the present invention is that the apparatus can be transported flat and set up immediately prior to use.
  • Another way to make wraps of fabric selectively rigid within a band is by way of stitch patterns, e.g., parallel rows of stitches can be used across the face portions of the band to make them rigid while leaving the joints/edges unsewn to create another "collapsible" rigid band.
  • the type of fibers used in the blast resistant material may vary widely and can be inorganic or organic fibers.
  • Preferred fibers for use in the practice of this invention, especially for the substantially continuous lengths are those having a tenacity equal to or greater than about 10 grams/denier (g/d) and a tensile modulus equal to or greater than about 200 g/d (as measured by an Instron Tensile Testing machine).
  • Particularly preferred fibers are those having a tenacity equal to or greater than about 20 g/d and a tensile modulus equal to or greater than about 500 g/d.
  • the tenacity of the fibers is equal to or greater than about 25 g/d and the tensile modulus is equal to or greater than about 1000 g/d.
  • the fibers of choice have a tenacity equal to or greater than about 30 g/d and a tensile modulus equal to or greater than about 1200 g/d.
  • High performance fibers can be incorporated into bands together and/or in conjunction with other fibers which may be inorganic, organic or metallic.
  • the high performance fiber is the continuous (warp) fiber and the other fiber is the fill fiber.
  • the other fiber can be incorporated in both warp and fill.
  • Such fabrics are designated hybrid fabrics.
  • Hybrid fabrics can be used to construct one or more bands of the container.
  • hybrid fabrics would be used to construct part or all of the outer band.
  • Bands can also be created by simultaneously or serially wrapping one or more fabrics made with conventional fibers with one or more fabrics made from high performance fibers.
  • the denier of the fiber may vary widely. In general, fiber denier is equal to or less than about 8,000. In the preferred embodiments of the invention, fiber denier is from about 10 to about 4000, and in the more preferred embodiments of the invention, fiber denier is from about 10 to about 2000. In the most preferred embodiments of the invention, fiber denier is from about 10 to about 1500. Fabrics made with coarser (higher) denier fibers will allow more venting of gases, which may be desirable in some cases.
  • Useful inorganic fibers include S-glass fibers, E-glass fibers, carbon fibers, boron fibers, alumina fibers, zirconia-silica fibers, alumina-silica fibers and the like.
  • glass fibers such as fibers formed from quartz, magnesia alumuninosilicate, non-alkaline aluminoborosilicate, soda borosilicate, soda silicate, soda lime-aluminosilicate, lead silicate, non-alkaline lead boroalumina, non-alkaline barium boroalumina, non-alkaline zinc boroalumina, non-alkaline iron aluminosilicate, cadmium borate, alumina fibers which include "saffil” fiber in eta, delta, and theta phase form, asbestos, boron, silicone carbide, graphite and carbon such as those derived from the carbonization of saran, polyaramide (Nomex), nylon, polybenzimidazole, polyoxadiazole, polyphenylene, PPR, petroleum and coal pitches (isotropic), mesophase pitch, cellulose and polyacrylonitrile, ceramic fibers, metal fibers, metal fibers, metal fibers, metal fibers, metal fibers
  • useful organic filaments are those composed of polyesters, polyolefins, polyetheramides, fluoropolymers, polyethers, celluloses, phenolics, polyesteramides, polyurethanes, epoxies, aminoplastics, silicones, polysulfones, polyetherketones, polyetheretherketones, polyesterimides, polyphenylene sulfides, polyether acryl ketones, poly(amideimides), and polyimides.
  • aramids aromatic polyamides
  • liquid crystalline polymers such as lyotropic liquid crystalline polymers which include polypeptides such as poly- ⁇ -benzyl L-glutamate and the like; aromatic polyamides such as poly(1,4-benzamide), poly(chloro-1-4-phenylene terephthalamide), poly(1,4-phenylene fumaramide), poly(chloro-1,4-phenylene fumaramide), poly(4,4'-benzanilide trans, trans-muconamide), poly(1,4-phenylene mesaconamide), poly(1,4-phenylene) (trans-1,4-cyclohexylene amide), poly(chloro-1,4-phenylene) (trans-1,4-cyclohexylene amide), poly(1,4-phenylene 1,4-dimethyl-trans-1,4-cyclohexylene amide), poly(1,4-phenylene 2,5-pyridine amide), poly(chloro-1,4-phenylene
  • the most useful high strength fibers include extended chain polyolefin fibers, particularly extended chain polyethylene (ECPE) fibers, aramid fibers, polyvinyl alcohol fibers, polyacrylonitrile fibers, liquid crystal copolyester fibers, polyamide fibers, glass fibers, carbon fibers and/or mixtures thereof. Particularly preferred are the polyolefin and aramid fibers. If a mixture of fibers is used, it is preferred that the fibers be a mixture of at least two of polyethylene fibers, aramid fibers, polyamide fibers, carbon fibers, and glass fibers.
  • U.S.P. 4,457,985 generally discusses such extended chain polyethylene and polypropylene fibers.
  • suitable fibers are those of weight average molecular weight of at least 150,000, preferably at least one million and more preferably between two million and five million.
  • Such extended chain polyethylene fibers may be grown in solution as described in U.S.P. 4,137,394 or U.S.P. 4,356,138, or may be spun from a solution to form a gel structure, as described in German Off. 3,004,699 and GB 2051667, and especially as described in U.S.P. 4,413,110, 4,551,296.
  • polyethylene shall mean a predominantly linear polyethylene material that may contain minor amounts of chain branching or comonomers not exceeding 5 modifying units per 100 main chain carbon atoms, and that may also contain admixed therewith not more than about 50 weight percent of one or more polymeric additives such as alkene-1-polymers, in particular low density polyethylene, polypropylene or polybutylene, copolymers containing mono-olefins as primary monomers, oxidized polyolefins, graft polyolefin copolymers and polyoxymethylenes, or low molecular weight additives such as antioxidants, lubricants, ultraviolet screening agents, colorants and the like which are commonly incorporated by reference.
  • polymeric additives such as alkene-1-polymers, in particular low density polyethylene, polypropylene or polybutylene, copolymers containing mono-olefins as primary monomers, oxidized polyolefins, graft polyolefin copolymers and poly
  • the tenacity of the filaments is at least about 15 g/d, preferably at least 20 g/d, more preferably at least 25 g/d and most preferably at least 30 g/d.
  • the tensile modulus of the filaments is at least about 200 g/d, preferably at least 500 g/d, more preferably at least 1,000 g/d, and most preferably at least 1,200 g/d.
  • the filaments have melting points higher than the melting point of the polymer from which they were formed.
  • high molecular weight polyethylene of 150,000, one million and two million generally have melting points in the bulk of 138°C.
  • the highly oriented polyethylene filaments made of these materials have melting points of from about 7° to about 13 °C higher.
  • a slight increase in melting point reflects the crystalline perfection and higher crystalline orientation of the filaments as compared to the bulk polymer.
  • highly oriented extended chain polypropylene fibers of weight average molecular weight at least 200,000, preferably at least one million and more preferably at least two million, may be used.
  • extended chain polypropylene may be formed into reasonably well oriented filaments by techniques described in the various references referred to above, and especially by the technique of U.S.P.'s 4,413,110, 4,551,296, 4,663,101, and 4 784 820. Since polypropylene is a much less crystalline material than polyethylene and contains pendant methyl groups, tenacity values achievable with polypropylene are generally substantially lower than the corresponding values for polyethylene.
  • a suitable tenacity is at least about 8 g/d, with a preferred tenacity being at least about 11 g/d.
  • the tensile modulus for polypropylene is at least about 160 g/d, preferably at least about 200 g/d.
  • the melting point of the polypropylene is generally raised several degrees by the orientation process, such that the polypropylene filament preferably has a main melting point of at least 168°C., more preferably at least 170°C.
  • the particularly preferred ranges for the above-described parameters can be advantageously provide improved performance in the final article.
  • Employing fibers having a weight average molecular weight of at least about 200,000 coupled with the preferred ranges for the above-described parameters (modulus and tenacity) can provide advantageously improved performance in the final article.
  • High molecular weight polyvinyl alcohol fibers having high tensile modulus are described in U.S.P. 4,440,711.
  • High molecular weight PV-OH fibers should have a weight average molecular weight of at least about 200,000.
  • Particularly useful PV-OH fibers should have a modulus of at least about 300 g/d, a tenacity of at least about 7 g/d (preferably at least about 10 g/d, more preferably about 14 g/d, and most preferably at least about 17 g/d), and an energy-to-break of at least about 8 joules/g.
  • PV-OH fibers having a weight average molecular weight of at least about 200,000, a tenacity of at least about 10 g/d, a modulus of at least about 300 g/d, and an energy to break of about 8 joules/g are likely to be more useful in producing articles of the present invention.
  • PV-OH fibers having such properties can be produced, for example, by the process disclosed in U.S.P. 4,599,267, hereby incorporated by reference.
  • PAN fibers for use in the present invention are of molecular weight of at least about 400,000.
  • Particularly useful PAN fiber should have a tenacity of at least about 10 g/d and an energy-to-break of at least about 8 joules/g.
  • PAN fibers having a molecular weight of at least about 400,000, a tenacity of at least about 15 to about 20 g/d and an energy-to-break of at least about 8 joules/g are most useful; such fibers are disclosed, for example, in U.S.P. 4,535,027, hereby incorporated by reference.
  • aramid fibers suitable aramid fibers formed principally from aromatic polyamide are described in U.S.P. 3,671,542.
  • Preferred aramid fiber will have a tenacity of at least about 20 g/d, a tensile modulus of at least about 400 g/d and an energy-to-break at least about 8 joules/g
  • particularly preferred aramid fiber will have a tenacity of at least about 20 g/d, a modulus of at least about 480 g/d and an energy-to-break of at least about 20 joules/g.
  • aramid fibers will have a tenacity of at least about 20 g/d, a modulus of at least about 900 g/d and an energy-to-break of at least about 30 joules/g.
  • poly(phenylenediamine terephthalamide) filaments produced commercially by Dupont Corporation under the trade name of KEVLAR® 29, 49, 129 and 149 and having moderately high moduli and tenacity values are particularly useful in forming articles of the present invention.
  • KEVLAR 29 has 500 g/d and 22 g/d and KEVLAR 49 has 1000 g/d and 22 g/d as values of modulus and tenacity, respectively.
  • poly(metaphenylene isophthalamide) fibers produced commercially by Dupont under the trade name NOMEX®.
  • suitable fibers are disclosed, for example, in U.S.P. No.'s 3,975,487; 4,118,372; and 4,161,470.
  • Tenacity's of about 15 to about 30 g/d and preferably about 20 to about 25 g/d, and tensile modulus of about 500 to 1500 g/d and preferably about 1000 to about 1200 g/d are particularly desirable.
  • a matrix material may comprise one or more thermosetting resins, or one or more thermoplastic resins, or a blend of such resins.
  • the choice of a matrix material will depend on how the bands are to be formed and used. The desired rigidity of the band and/or ultimate container will greatly influence choice of matrix material.
  • thermoplastic resins are resins which can be heated and softened, cooled and hardened a number of times without undergoing a basic alteration
  • thermosetting resins are resins which cannot be resoftened and reworked after molding, extruding or casting and which attain new, irreversible properties when once set at a temperature which is critical to each resin.
  • the tensile modulus of the matrix material in the band(s) may be low (flexible) or high (rigid), depending upon how the band is to be used.
  • the key requirement of the matrix material is that it be flexible enough to process at whatever stage of the band-forming method it is added.
  • thermosetting resins which are fully uncured or have been B-staged but not fully cured would probably process acceptably, as would fully cured thermosetting resins which can be plied together with compatible adhesives. Heat added to the process would permit processing of higher modulus thermoplastic materials which are too rigid to process otherwise; the temperature "seen" by the material and duration of exposure must be such that the material softens for processing without adversely affecting the impregnated fibers, if any.
  • thermosetting resins useful in the practice of this invention may include, by way of illustration, bismaleimides, alkyds, acrylics, amino resins, urethanes, unsaturated polyesters, silicones, epoxies, vinylesters and mixtures thereof Greater detail on useful thermosetting resins may be found in U.S.P. 5,330,820. Particularly preferred thermosetting resins are the epoxies, polyesters and vinylesters, with an epoxy being the thermosetting resin of choice.
  • Thermoplastic resins for use in the practice of this invention may also vary widely.
  • Illustrative of useful thermoplastic resins are polylactones, polyurethanes, polycarbonates, polysulfones, polyether ether ketones, polyamides, polyesters, poly(arylene oxides), poly(arylene sulfides), vinyl polymers, polyacrylics, polyacrylates, polyolefins, ionomers, polyepichlorohydrins, polyetherimides, liquid crystal resins, and elastomers and copolymers and mixtures thereof. Greater detail on useful thermoplastic resins may be found in U.S.P. 5,330,820, hereby incorporated by reference.
  • thermoplastic (elastomeric) resins are described in U.S.P. 4,820,568, especially those produced commercially by the Shell Chemical Co. which are described in the bulletin "KRATON Thermoplastic Rubber", SC-68-81.
  • Particularly preferred thermoplastic resins are the high density, low density, and linear low density polyethylenes, alone or as blends, as described in U. S.P. 4,820,458.
  • a broad range of elastomers may be used, including natural rubber, styrene-butadiene copolymers, polyisoprene, polychloroprene-butadiene-acrylonitrile copolymers, ER rubbers, EPDM rubbers, and polybutylenes.
  • the matrix comprises a low modulus polymeric matrix selected from the group consisting of a low density polyethylene; a polyurethane; a flexible epoxy; a filled elastomer vulcanizate; a thermoplastic elastomer; and a modified nylon-6.
  • the proportion of matrix to filament in the bands is not critical and may vary widely.
  • the matrix material forms from about 10 to about 90% by volume of the fibers, preferably about 10 to 80%, and most preferably about 10 to 30%.
  • a matrix resin it may be applied in a variety of ways to the fiber, e.g., encapsulation, impregnation, lamination, extrusion coating, solution coating, solvent coating. Effective techniques for forming coated fibrous layers suitable for use in the present invention are detailed in referenced U.S.P.'s 4,820,568 and 4,916,000.
  • the blast resistant bands can be made according to the following method steps:
  • Another method of making bands for assembly into a blast resistant container comprises the steps of:
  • the flexible sheet material is formed as follows. Yarn bundles of from about 30 to about 2000 individual filaments of less than about 12 denier, and more preferably of about 100 individual filaments of less than about 7 denier, are supplied from a creel, and are led through guides and a spreader bar into a collimating comb just prior to coating. The collimating comb aligns the filaments coplanarly and in a substantially parallel, and unidirectional fashion. The filaments are then sandwiched between release papers, one of which is coated with a wet matrix resin. This system is then passed under a series of pressure rolls to complete the impregnation of the filaments.
  • top release paper is pulled off and rolled up on a take-up reel while the impregnated network of filaments proceeds through a heated tunnel oven to remove solvent and then be taken up.
  • a single release paper coated with the wet matrix resin can be used to create the impregnated network of filaments.
  • One such impregnated network is referred to as unidirectional prepreg, tape or sheet material and is one of the preferred feed materials for making some of the bands in the examples below.
  • two such impregnated networks are continuously cross plied, preferably by cutting one of the networks into lengths that can be placed successively across the width of the other network in a 0°/90° orientation.
  • This forms a continuous flexible sheet of high strength fiber material. See U.S.P. 5,173,138.
  • This flexible sheet (fibrous layer), optionally with film as discussed below, can then be used to form one or more bands in accordance with the methods of the present invention.
  • This fibrous layer is sufficiently flexible to wrap in accordance with the methods of the present invention; it can then be made substantially rigid (per the drapability test), if desired, either by the sheer number of wraps or by the manner in which it is secured.
  • the weight percent of fiber in the hoop direction of the band can be varied by varying the number and the orientation of the networks.
  • One way to achieve varying weight percents of fiber in the hoop direction is to make a composite sheet from the cross plied material and one or more layers of unidirectional tape/material (see the examples which follow).
  • two unidirectional sheets with one cross-plied sheet forms an imbalanced fabric having about 75 weight percent fiber in the hoop direction.
  • one or more uncured thermosetting resin-impregnated networks of high strength filaments are similarly formed into a flexible sheet for winding around a mandrel into a band or bands in accordance with the present invention followed by curing (or spot curing) of the resin.
  • Film may optionally be used as one or more layers of the band(s), preferably as an outer layer.
  • the film, or films can be added as the matrix material (lamination), with the matrix material or after the matrix material, as the case may be.
  • the film is added as the matrix material, it is preferably simultaneously wound with the fiber or fabric (network) onto a mandrel and subsequently consolidated; the mandrel may optionally become part of the structure.
  • the film thickness minimally is about 2.5 ⁇ m (0.1 mil) and may be as large as desired so long as the length is still sufficiently flexible to permit band formation.
  • the preferred film thickness ranges from 2.5 ⁇ m-1270 ⁇ m (0.1 to 50 mil) with 8.9 ⁇ m-254 ⁇ m (0.35 to 10 mil) being most preferred.
  • Films can also be used on the surfaces of the bands for a variety of reasons, e.g., to vary frictional properties, to increase flame retardance, to increase chemical resistance, to increase resistance to radiation degradation, and/or to prevent diffusion of material into the matrix.
  • the film may or may not adhere to the band depending on the choice of film, resin and filament. Heat and/or pressure may cause the desired adherence, or it may be necessary to use an adhesive which is heat or pressure sensitive between the film and the band to cause the desired adherence.
  • acceptable adhesives include polystyrene-polyisoprene-polystyrene block copolymer, thermoplastic elastomers, thermoplastic and thermosetting polyurethanes, thermoplastic and thermosetting polysulfides, and typical hot melt adhesives.
  • Films which may be used as matrix materials in the present invention include thermoplastic polyolefinic films, thermoplastic elastomeric films, crosslinked thermoplastic films, crosslinked elastomeric films, polyester films, polyamide films, fluorocarbon films, urethane films, polyvinylidene chloride films, polyvinyl chloride films and multilayer films. Homopolymers or copolymers of these films can be used, and the films may be unoriented, uniaxially oriented or biaxially oriented.
  • the films may include pigments or plasticizers.
  • thermoplastic polyolefinic films include those of low density polyethylene, high density polyethylene, linear low density polyethylene, polybutylene, and copolymers of ethylene and propylene which are crystalline.
  • Polyester films which may be used include those of polyethylene terephthalate and polybutylene terephthalate.
  • Pressure can be applied by an interleaf material made from a plastic film wrap which shrinks when the band is exposed to heat; acceptable materials for this application, by way of example, are polyethylene, polyvinyl chloride and ethylenevinylacetate copolymers.
  • temperatures and/or pressures to which the bands of the present invention are exposed to cure the thermosetting resin or to cause adherence of the networks to each other and optionally, to at least one sheet of film vary depending upon the particular system used.
  • temperatures range from about 20°C. to about 150°C., preferably from about 50°C. to about 145°C., more preferably from about 80°C. to about 120°C, depending on the type of matrix material selected.
  • the pressures may range from about 69 kPa (10 psi) to about 69,000 kPa (10,000 psi).
  • the upper limitation of the temperature range would be about 10 to about 20°C. higher than for ECPE filament.
  • the temperature range would be about 149 to 205°C. (about 300 to 400°F.).
  • Pressure may be applied to the bands on the mandrel in a variety of ways. Shrink wrapping with plastic film wrap is mentioned above. Autoclaving is another way of applying pressure, in this case simultaneous with the application of heat.
  • the exterior of each band may be wrapped with a shrink wrappable material and then exposed to temperatures which will shrink wrap the material and thus apply pressure to the band.
  • the band can be shrink wrapped on the mandrel in its hoop direction which will consolidate the entire band, or the band can be shrink wrapped across its faces with material placed around the band wrapped mandrel perpendicular to the hoop direction of the band; in the latter case, the edges of the band can remain unconsolidated while the faces are consolidated.
  • bands formed with fibrous layers utilizing elastomeric resin systems, thermosetting resin systems, or resin systems wherein a thermoplastic resin is combined with an elastomeric or thermosetting resin can be treated with pressure alone to consolidate the band. This is the preferred way of consolidating the band.
  • many of the bands formed with continuous lengths/plies utilizing thermoplastic resin systems can be treated with heat, alone or combined with pressure, to consolidate the band.
  • each fibrous layer has an areal density of from about 0.1 to about 0.15 kg/m 2 .
  • the areal density per band ranges from about 1 to about 40 kg/m 2 , preferably from about 2 to 20 kg/m 2 , and more preferably from about 4 to about 10 kg/m 2 .
  • these areal densities correspond to a number of fibrous layers per band ranging from about 10 to about 400, preferably from about 20 to about 200, more preferably from about 40 to about 100.
  • each face of the cube comprises two bands of blast resistant material, which effectively doubles the aforesaid ranges for each face of the cube.
  • fibers other than high strength extended chain polyethylene, like SPECTRA® polyethylene fibers are utilized the number of layers may need to be increased to achieve the high strength and modulus characteristics provided by the preferred embodiments.
  • blast mitigating material is meant any material that functionally improves the resistance of the container to blast.
  • the preferred blast mitigating material utilized in forming the container assemblies of the present invention are polymeric foams; particulates, such as vermiculite; condensable gases, preferably non-flammable; heat sink materials; foamed glass; microballoons; balloons; bladders; hollow spheres, preferably elastomeric such as basketballs and tennis balls; wicking fibers; and combinations thereof. These materials are used to surround the explosive or explosive-carrying luggage within the blast resistant container, and mitigate the shock wave transmitted by an explosion.
  • Chemical explosions are characterized by a rapid self-propagating decomposition which liberates considerable heat and develops a sudden pressure effect through the action of heat on the produced or adjacent gases.
  • the heat of vaporization of water is similar to the heat liberated by the explosive. Provided that rapid heat transfer can be accomplished, water has the potential of greatly decreasing the blast overpressure.
  • One technique to achieve the desired effect is to surround the explosive with heat sink materials.
  • Effective heat sink materials include aqueous foams; aqueous solutions having antifreeze therein such as glycerin, ethylene glycol; hydrated inorganic salts; aqueous gels, preferably reinforced; aqueous mists; wet sponges, preferably elastomeric; wet profiled fibers; wet fabrics; wet felts; and combinations thereof.
  • Aqueous foams are most preferred, especially aqueous foams having a density in the range of from about 0.01 to about 0.10 g/cm 3 , more preferably in the range of from about 0.03 to about 0.08 g/cm 3 .
  • aqueous foams In general, aqueous foams, through a number of mechanisms, transform energy of the explosion to heat energy within the aqueous phase. After an explosion venting of gases occurs in most containers, and when the pressure drops below some critical value the collapsed foam expands again causing additional slow release of gases. The presence of these foams decreases the rate at which energy is transmitted from the container to the surroundings, and thereby decreases the hazard.
  • Aqueous foams for use with this invention are preferably prepared with gases (foaming agents) which do not support combustion and that are condensable.
  • condensable is meant that under pressure the gas will change phase from gas to liquid, simultaneously evolving their heat of condensation which heats the aqueous solution with which the gas has intimate contact.
  • gases include the hydrocarbons such as propane, butane (both isomers), and pentane(all isomers); carbon dioxide; inorganic gases such as ammonia, sulfur dioxide; fluorocarbons, particularly the hydrochlorofluorocarbons and the hydrofluorocarbons, such as, for example, the GENETRON® series of refrigerants commercially available from AlliedSignal Inc.
  • hydrocarbons such as propane, butane (both isomers), and pentane(all isomers); carbon dioxide; inorganic gases such as ammonia, sulfur dioxide; fluorocarbons, particularly the hydrochlorofluorocarbons and the hydrofluorocarbons, such as, for example, the GENETRON® series of refrigerants commercially available from AlliedSignal Inc.
  • a preferred gas is isobutane, which can be condensed at modest pressures, about 0.2 MPa (30 psi) at room temperature.
  • Mixtures of condensable and non-condensable gases can be used.
  • a mixture of isobutane and tetrafluoromethane can be used for a room temperature application. The blast overpressure would cause the isobutane to condense but the tetrafluoromethane would remain gaseous.
  • Preferred gases have low sonic velocities.
  • a gas that does not condense in the pressurized canister in combination with a condensed gas.
  • Carbon dioxide, nitrogen, nitrous oxide or carbon tetrafluoride could serve as such as gas.
  • Gases which vaporize to provide propellant action cool the canister during dispensing and the rate of discharge slows.
  • the explosive used was TRENCHRITE 5, a product of Explosives Technologies International and a class A explosive having a shock wave velocity of 5,900 m/sec (6,700 ft/sec).
  • the explosive used was C4, which is 90 percent RDX (cyclo-1,3,5-trimethylene-2,4,6-trinitroamine) and 10 percent of a plasticizer (polyisobutylene), a product of Hitech Inc., and a class A explosive having a shock wave velocity of 8200 m/sec (26,900 ft/sec).
  • the video camera utilized to record the explosive events was a vhs video, Sylvania Model VCC 159 AV01. The camera was remotely operated and was located so that the subject box or tube filled approximately 30% of the viewing area.
  • Three cubic boxes were constructed for testing, two utilizing SPECTRA SHIELD® composite panels for their faces and one utilizing KEVLAR® composite panels for its faces.
  • the box made from SPECTRA SHIELD composite was constructed 78.7 cm (31 inches) on a side utilizing six flat SPECTRA SHIELD® composite panels as its faces, each 174 cm 2 (27 inches) square, hinged together with two sets of hinges and two pins per edge (total of 24 pins and hinges).
  • Fabric shapes were partially wrapped around the perimeter rods of an aluminum frame. The wrapping (bending) occurred along a dotted line having an overall length of 69 cm (27.25"). Three fabric layers (shapes) were wrapped on each of the four perimeter rods. These fabric shapes consisted of SPECTRA 1000 fabric, Style 904 (plain weave, 34 x 34 ends per 2.54 cm (inch.) 650 denier SPECTRA 1000 yarn weighing 204 gr/m 2 (6 oz/yd 2 )) The fabrics were impregnated with a sufficient amount of Dow XU71943.00L experimental vinyl ester resin (diallyl phthalate - 6 wt. %, methyl ethyl ketone - 31 wt.
  • the resin contained 1.0 wt. % Lupersol 256, a product or the Lucidol Division of Ato Chem Corporation [2,5-dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane].
  • the aluminum frame was also used to wrap the square composite panels. Two rolls and of unidirectional prepreg tape were positioned to adjacent sides of the frame for wrapping alternatively around the frame to achieve a 0°/90°/0°/90°/etc. laydown of prepreg. The process was repeated until the desired areal density was attained.
  • Each prepreg tape contained 7.6 ends per linear inch of 1500 denier SPECTRA 1000 yarn in Dow Resin XU71943.00L experimental vinyl ester resin, described above. The methyl ethyl ketone volatizes before the composite is cured.
  • the prepreg was 76 wt. % SPECTRA 1000 fiber and 24 wt. % resin.
  • the diagonal bar of the aluminum frame was removed, and the central area (61 x 61 cm (27 x 27 inches)) was molded at 120°C for 30 minutes under a force of 150 tons.
  • the perimeter aluminum rods 126 were then removed, which left perimeter loops.
  • the perimeter loops were then cut at intervals of 7.62 cm (3 inches.)
  • the cubic box container was assembled with one inch diameter cold rolled steel pins. One half of the perimeter loops were folded to be on the outside of the container and one half of the perimeter loops were folded to be on the inside of the container. There were 9 loops per edge, alternated inside and outside. Pins were placed in both the inside and outside loops, two per edge.
  • the box made from KEVLAR composite was constructed in a similar manner, except that KEVLAR 29 fabric (Style 423 - 2X2 basket weave of 1500 denier yarn, (476 gr/m 2 (14 oz/yd 2 )) was utilized, and only one layer of the fabric was wrapped around each perimeter rod.
  • the panel overall areal density was the same as the SPECTRA SHIELD panel, i.e., 54.6 Pa (1.14 lb/ft 2 ).
  • the first two boxes made from SPECTRA SHIELD composite panels were tested using 0.23 and 0.46 kg (8 and 16 ounces) of explosive charges, respectively, placed at their respective geometric centers.
  • the box was found to withstand the blast from the 0.23 kg (8 ounce) explosion; however, considerable rapid venting occurred at the edges and corners of the box.
  • the 0.46 kg (16 ounce) charge blew the container apart, and the steel hinge pins became dangerous projectiles.
  • the third box made from KEVLAR composite panels was tested using an 0.23 kg (8 ounce) explosive charge placed at its geometric center. The explosion caused massive rupture of the container, and the steel hinge pins became dangerous projectiles.
  • a SPECTRA SHIELD® PCR composite roll commercially available from AlliedSignal, Inc., was cut into four 381 cm (15 inch) wide strips, each approximately 838 cm (330 inches) in length.
  • the SPECTRA SHIELD® PCR composite contained 80 weight percent SPECTRA® 1000 extended chain polyethylene fiber (nominal tenacity of about 35 g/d, tensile modulus of about 1150 g/d, and elongation-to-break of about 3.4%, also available from AlliedSignal, Inc.) in a 20 weight percent resin matrix of polystyrene-polyisoprene-polystyrene block copolymer, available from Shell Co. under the trade name KRATON® D1107.
  • the SPECTRA fibers were arranged in the composite in a 0°/90° configuration. Each strip was wrapped in successive layers around a square cross-sectional mandrel having a side length of 38.1 cm (15 inches) to form a band having 22 wraps of SPECTRA SHIELD. The wrapping of each successive strip was started at the point where the prior strip ended, with the identical fiber configuration and under sufficient tension (about 0.18 kg/cm (1 lb per linear inch)) to minimize voids in successive wraps. An adhesive solution consisting of 5 g of KRATON D1107 per 95 g of toluene was painted onto the exterior of the strips during wrapping to provide adhesive material between successive wraps. A conventional rolling pin was used to consolidate the successive wraps during band formation to minimize voids in successive wraps.
  • a second set of four aluminum plates were affixed to the faces of the second band followed by construction of a third band in the same manner as the first and second bands.
  • the three bands were removed from the mandrel, and the toluene evaporated from the bands.
  • 50 weight percent of the fiber was continuous and oriented in the hoop direction of the band.
  • the three bands were nested together as shown in FIGURE 1F to create a Box 1 for evaluation against an explosive charge.
  • Each side of the box corresponds to 44 wraps of 0°/90° SPECTRA SHIELD PCR since there are faces of two bands covering each side of the box, and each band face comprises 22 wraps.
  • the areal density of Box 1 0.13
  • X 44 5.72 kg/m 2 (1.17 lb/ft 2 ).
  • the weight of the Box 1 was 5.8 kg (12.6 lb).
  • Box 2 was constructed in the same manner as Box 1 with the following modifications.
  • the first two strips of SPECTRA SHIELD composite used in constructing the first band were 61 cm (24 inches) wide. After removal of the band and evaporation of the toluene, the first band was cut into a distance of 11.4 cm (4.5 inches) from either side at each comer to allow for eight flaps (four on each side of the 38.1 cm (15 inch) wide band, two per face) of 11.4 cm (4.5 inch) width to be created.
  • the flaps were made by folding the cut portion of the strip along the band width line. The plane of each flap was perpendicular to the plane of the side of the band to which it was attached. These flaps were held in place by the second and third bands.
  • Weight of Box 2 was 6.08 kg (13.4 lb). The areal density of the faces was identical to Box 1, and the increase in weight was due to the flaps.
  • Boxes 3 and 4 were prepared in an identical manner to Box 2, and were essentially identical in weight and areal density.
  • Box 1 was tested using a 0.46 kg (16 ounce) explosive charge at its geometric center. During detonation, the edges of all three bands were completely or almost completely destroyed to result in a number of 38.1 cm (15 inch) square pieces, which were still intact and showed little damage.
  • Box 2 was tested using an 0.23 kg (8 ounce) charge in a manner identical to testing of Box 1. High speed video showed initial charge containment followed by distortion and breakage of band 3 at two opposite edges (broken band 3 consisted of two identical halves). Extensive gas venting occurred. Bands 1 and 2 remained essentially intact.
  • Box 3 was tested using a 57 gr (2 ounce) charge in a manner identical to testing of Box 1. High speed video showed minor gas venting during the detonation and bulging of the sides. However, the box remained intact. All three bands were undamaged.
  • a box was constructed in the same manner as Box 2 of Example 2 above, with the following changes.
  • the mandrel was modified so that the edges were round, having a radius of 46 cm (5/8 inch).
  • the areal density of the bands was one-half that of Box 2.
  • the flap width on Band 1 was increased to 15.24 (6 inches.) Band was reinforced to control deformation and the rate of escape of gases from the explosion. This reinforcement consisted of first wrapping the mandrel in two complete wraps of 38.4 cm (15 inch)wide S-2 glass cloth (Style 6781, areal density 0.309 kg/m 2 , manufactured by Clark Schwebel).
  • This glass cloth was impregnated with EPON 828 epoxy resin, commercially available from the Shell Co., by using 8 pph Millamine, a cycloaliphatic diamine, available from Milliken Chemical Co., as a room temperature curing agent. The glass/resin ratio was 48/52 by weight.
  • the SPECTRA SHIELD composite strips for Band 1 were then wound on top of the glass fabric, which became an integral part of Band 1.
  • a panel of glass/epoxy composite commercially available from 3M Corporation as Scotch Ply Type 1002 , was attached to each of the four inside surfaces of the glass fabric band (Band 1). Each panel measured about 34.31 x 36.8 cm (13.5 x 14.5 inches), weighed 340 g and was 0.14 cm (56 mil) thick. The panels were attached with a total of 200 g of a polysulfide adhesive PROSEAL 890-B1/2, manufactured by Courtaulds Aerospace Company.
  • the inside surfaces of the 8 flaps were also reinforced by attaching to each a 9.5 x 34.9 cm (3.75 x 13.75 inches) piece of the glass/epoxy panel using Scctch 410 Flat Stock linear double coated paper tape, available from 3M Corporation. The total weight of these 8 pieces of panel was 707 g.
  • the assembled box weighed 6.17 kg (13.6 lb), consisting of 3.04 kg (6.7 lb) SPECTRA SHIELD composite and 3.13 kg (6.9 lb) fiber glass composite and adhesives.
  • This box was tested using a 6 ounce charge of TRENCHRITE 5 in a manner identical to testing of Boxes in Example 2.
  • the container contained the charge with minimum distortion, no rapid venting and essentially no visible permanent damage to the structure.
  • a box was constructed like Box 2 of Example 2 with the following modifications.
  • Band 1 the first half of the composite strip length was 53 cm (21 inches) wide while the second half was 15 inches wide. This permitted eight flaps to be created, four per side of the band, each 7.62 (3 inches) by 38.1 cm (15 inches) and having an areal density 4.75 kg/m 2 .
  • Band 1 consisted of 70 SPECTRA SHIELD composite wraps and had an areal density of 9.5 kg/m 2 .
  • An 0.3 cm (0.125 inch) wide aluminum plate was placed around Band 1.
  • Band 2 was formed by wrapping strips that were 43 cm (17 inches) wide around the spacer.
  • a second spacer of 4.3 cm (0.125 inch) width was placed around Band 2 and Band 3 was formed by wrapping strips that were 45.7 cm (18 inches) wide.
  • the three bands were removed from the mandrel and from the spacers. In each band, about 50 weight percent of the fiber was continuous and oriented in the hoop direction.
  • the three bands were assembled with Band 1 nesting inside of Band 2 which nested inside of Band 3 , with two band faces per side.
  • the flaps of Band 1 were held in place by Bands 2 and 3.
  • the completed container had a side length of approximately 45.7 cm (18 inches and) weighed 24.06 kg (53 lb).
  • An M67 fragmentation hand grenade was modified so that it could be detonated electronically.
  • the M67 grenade weighed 0.4 kg (14 ounces) and incorporated 184 gr (6.5 ounces) of compound B explosive.
  • the grenade was placed in the geometrical center of the container and detonated.
  • the container maintained its shape and the integrity of the individual bands.
  • the container was disassembled and examined.
  • the number of perforations in the four inner fiberglass panels of Band 1 indicated that more than 1200 steel projectiles were generated by the exploding grenade. Examination of the outer faces of the container indicated that 21 penetrations occurred.
  • a 68.6 cm (27 inch) wide sheet of SPECTRA SHIELD® PCR composite material were wrapped in 18 successive layers around a square cross-sectional mandrel having a side length of 38.1 cm (15 inches).
  • a 5 weight % KRATON D1107 adhesive solution was applied with a paint roller to the exterior of the sheet as wrapping proceeded to provide adhesive material between successive wraps.
  • a second, 43 cm (17 inch) wide sheet of SPECTRA SHIELD PCR composite material was centered on the wrapped first sheet and wrapped in the same manner for 18 successive wraps. The resulting band was allowed to dry at ambient temperature 21°C (approximately 70°F) on the mandrel overnight and was then removed.
  • the 68.6 cm (27 inch) wide portion of the band was cut into at the corners a sufficient distance to produce a 43 cm (17 inch) wide band and eight 12.7 cm (5 inch) wide flaps (four on each side of the 43 cm (17 inch) wide band, two per face).
  • the flaps were made by folding the cut portions of the sheet along the band width line. The plane of each flap was perpendicular to the plane of the side of the band to which it was attached.
  • Neither of these bands had flaps or fiberglass plates. Both bands were collapsible.
  • the first band of box A was placed on its side on a table, i.e., with its open sides to the top and bottom.
  • a thin low density polyethylene plastic bag was placed completely across the bottom open side of the band.
  • 0.23 kg (Eight ounces) of C4 explosive charge were placed at the geometric center.
  • the balance of the inside cavity was filled with BARBASOL® brand shaving cream (density of foam about 0.053 g/c 3 , blowing agent isobutane), commercially available from Pfizer Inc.
  • the slightly larger second band was then slid onto the first band with two of its opposing faces covering the originally open sides of the first band.
  • the slightly larger third band was then slid over this assembly.
  • Box B was similarly tested against 10 ounces of C4 with its cavity filled with shaving cream. Minor container distortion occurred and venting took place over a few seconds. This container was emptied, dried, and retested against 170 gr (6 ounces) of C4, without any shaving cream in the cavity. On explosion of the C4, fire emanated from the edges of the container. The container remained intact, but began to burn and was subsequently destroyed by the fire.
  • the C 50 value for this container assembly (includes aqueous foam) was 312 gr (11 ounces.)
  • a cubic container of 38.1 cm (15 inch) internal side length was constructed from three bands of SPECTRA 1000, 215 denier, 55 x 55 ends per 2.54 cm plain weave fabric, areal density 0.112 kg/m 2 (3.30 oz/yd 2 ).
  • an aluminum picture frame was incorporated into each face and flaps in order to provide structural support; these were cut from 0.16 cm (1/16 inch) thick aluminum plate having an areal density of 4.16 kg/m 2 .
  • the bands were easily folded and the outer bands could also be rolled into a cylinder.
  • a set of four pieces were placed on each side of the band.
  • two plates on opposite sides of the mandrel were modified by cutting them into trapezoids with a 45 degree angle with the short side facing away from the picture frames. This allowed folding the flaps inward 90 degrees (once removed from the mandrel) to form sides of a cube without having to cut the fabric along the edges between flaps. See FIGURES 9A - 9E and accompanying discussion, supra .
  • two additional wraps of 68.6 cm (27 inch) wide fabric were wound around the picture frame. Twenty-one wraps of 38.1 cm (15 inch) wide fabric centered on the 68.6 cm (27 inch) wide portion, were wound onto the mandrel for a total of 25 plies.
  • the middle band was made by hand winding a 38.1 cm (15 inch) wide strip of fabric around the inner band set up in form of the cube described above. Twenty-five wraps of fabric were wound. The direction of winding was over two closed sides of the inner band and over the two open sides (where flaps are located). Again the band was temporarily taped together followed by hand stitching with sewing thread along one side and once across the width. The middle band could be easily rolled up in the direction in which it had been wrapped.
  • the outer band was made from 25 wraps of fabric like the middle band, but the fabric strip was 40.6 cm (16 inches) wide for complete coverage of the underlying bands. It was made by wrapping the fabric over the assembled inner and middle bands. The wrapping direction was over two closed and two open sides of the inner band but perpendicular to the middle band. Taping and stitching were done as for the middle band. The outer band could be easily rolled up in the direction in which it had been wrapped.
  • the assembled cubic container had a fiber areal density of twice that of the individual bands, excluding areal density contributed by the flaps.
  • the final weights of the bands were: inner - 3.75 kg; middle - 1.77 kg; and outer - 1.87 kg; for a total weight of 7.39 kg.
  • the aluminum sheet incorporated in the frame and flaps of the inner band formed about 1.33 kg of this total.
  • About 50 weight percent of the fibers were continuous length fibers in the hoop or band direction.
  • the inner band was filled with aqueous foam (BARBASOL brand shaving cream), as in Example 5, after 113.5 grams (4 ounces) of C4 had been located at the geometric center of the band.
  • Bands two and three were assembled over the inner band, as in Example 10, and Anderson Blastguages were place at 76 cm and 152 cm (2.5 and 5 feet) from the center of the container assembly and parallel to two faces to measure overpressures.
  • the Anderson Blastguage gauges consist of two flat aluminum plates pierced with ten round holes of various diameters and comes with four screws and wing nuts. Standard xerox (#20 lb) copy paper is inserted between the plates and held tightly by the screws and wing nuts to create a series of paper diaphragms often different diameters. Overpressure is estimated by the damage to paper in the various diaphragms. ⁇
  • the overpressure for the unconfined charge was greater that 44.8 kPa at 152 cm (6.5 psi at 5 ft) between 22 kPa and 38.6 kPa at 2.29 m (3.2 and 5.6 psi at 7.5 ft.) and between 13.8 kPa and 25.5 kPa at 3 m (2.0 and 3.7 psi at 10 ft).
  • the foam did not penetrate the fabric faces of the inner band.
  • the container was emptied, dried, and retested with 170 gr (6 ounces) of C4, with the cavity again filled with shaving cream.
  • the container assembly contained the explosion.
  • the container again was emptied, dried, and retested with 284 gr (10 ounces) of C4, with the cavity once again filled with shaving cream. Upon detonation, the container ripped apart.
  • the C 50 value for this container assembly (includes aqueous foam) was 227 gr (8 ounces) (note that charge increments are typically smaller than in this example).
  • Examples 7 - 11 comparative studies were carried out on containers and container assemblies using different materials of construction for the containers, but with the identical three band design, with and without blast mitigating material (an aqueous foam).
  • the areal density of each of the three bands was 2.8 kg/m 2
  • overall container weight was 7.4 kg (16.3 lb)
  • the inner cavity (volume) was a cube with a side length of 38.1 cm (15 inches.).
  • band 1 was placed on a table with flaps folded to provide rigidity and with the designated charge in place attached to the detonating wire (detonating wire also served to support the charge in the geometric center of the container).
  • One open side of band 1 was in contact with the table and a low density polyethylene (LDPE) plastic bag was placed in band 1 to cover the bottom opening.
  • LDPE low density polyethylene
  • BARBASOL brand shaving cream was discharged into the cavity, as in Example 5.
  • Bands 2 and 3 were placed in position, as in the previous examples. The cubic container was placed on sawhorses and the charge detonated.
  • a video record was obtained and in some cases overpressures at 76 cm and 152 cm (2.5 and 5.0 ft.) from the container were measured, as in Example 6. In cases where aqueous foam was not used assembly proceeded without using the LDPE bag and shaving cream.
  • the fabric utilized in this example was a fine denier SPECTRA 1000, 215 denier, 55 x 55 ends per 2.54 cm (inch) plain weave fabric, areal density 0.112 kg/m 2 (3.30 oz/yd 2 ).
  • a series of identical fine denier fabric containers was constructed in the following manner.
  • Test results and C 50 values are set forth in Tables 1 and 2, respectively.
  • Example 7 was repeated with the following changes.
  • the material used to form the bands was a coarser denier SPECTRA 900, 1200 denier, 21 x 21 ends per 2.54 cm (inch), areal density 0.228 kg/m 2 , plain weave fabric.
  • To create the inner shell for this example only one wrap of the 68.6 cm (27 inch) wide strip was made before the picture frame and flaps were attached. One more wrap of the 68.6 cm (27 inch) wide fabric was made and the picture frames and flaps were sewn between the two layers. Test results and C 50 values are set forth in Tables 1 and 2, respectively.
  • Example 7 was repeated with the following changes.
  • the material used-to form the bands was SPECTRA SHIELD composite, described in Example 2 above, and having an areal density of 0.134 kg/m 2 .
  • About 50 weight percent of the fibers were continuous length fibers in the hoop or band direction.
  • the containers were constructed in the following manner:
  • Test results and C 50 values are set forth in Tables 1 and 2, respectively.
  • Example 9 was repeated with the following changes.
  • the material used to form the bands was a SPECTRA prepreg sheet (unidirectional sheet commercially available from AlliedSignal Inc., areal density 0.067 kg/m2).
  • the containers were constructed in the same manner except that two wraps of SPECTRA SHIELD composite strip were used at the beginning and end of each band.
  • Band 1 contained 78 weight percent unidirectional tape and 22 weight percent SPECTRA SHIELD.
  • Bands 2 and 3 contained 81 weight percent unidirectional tape and 19 weight percent SPECTRA SHIELD.
  • About 90 weight percent of the fibers were continuous length fibers in the hoop or band direction. Test results and C 50 values are set forth in Tables 1 and 2, respectively.
  • Example 7 was repeated with the following changes.
  • the material used to form the inner shell and bands was a coarse (3000) denier KEVLAR® 129 aramid woven fabric, areal density 0.446 kg/m 2 , Style 745, 17 x 17 ends per 2.54 cm (inch.) Test results and C 50 values are set forth in Tables 1 and 2, respectively.
  • the cube was rotated at the rate of 2 to 3 rotations per minute and stopped intermittently as necessary to apply the adhesive.
  • the process was first repeated by rotating the cube around its y axis and finally by rotating the cube around its z axis.
  • a second set of three bands of 9 wraps was repeated with the identical sequence (x then y then z) of wrapping directions.
  • a 16 cm 2 (2.5 inch square) was cut from one face near one corner. The sides of the square hole were parallel to the sides of the face and 5 cm (2 inches) from two of the adjacent edges.
  • the wrapped container weighed 7.6 kg (16.7 lb), and the wrapping material had an areal density of 2.43 kg/m 2 .
  • an aluminum plate 7.62 cm x 12.7 cm x 0.64 cm (3 x 5 x 0.25 inch) in size, was inserted diagonally into the box through the hole.
  • a square plywood plate 6.1 cm x 6.1 cm x 0.64 cm (2.4 x 2.4 x 0.25 inch)
  • a paper clip loop was threaded through two holes, 0.16 cm (0.0625 inch) in diameter, drilled through the plywood and aluminum plates.
  • a 0.64 cm (0.25 inch) diameter nylon tube was inserted through the loop to fix the plate in position.
  • a small hole 0.16 cm (0.0625 inch) was drilled in the center of the adjacent side for placement of the detonation wire.
  • Two strips of SPECTRA SHIELD (762 cm (3 inches) wide and corresponding in length to 9 wraps) were wrapped around each cube over the aluminum plate held in register in the square hole. The two strips were parallel to the edges of the cube and their length directions formed a right angle over the square hole.
  • Duct tape was used at the beginning, middle and end of each strip to secure the resulting band. Thus, there were 2 mutually perpendicular bands placed around the container that both covered the access hole.
  • the fourth container was filled with GENETRON 134A, a condensable gas (1,1,1,2-tetrafluorethane) commercially available from AlliedSignal Inc., and tested against a C4 charge of 57 g (2 oz). The container remained intact.
  • GENETRON 134A a condensable gas (1,1,1,2-tetrafluorethane) commercially available from AlliedSignal Inc.
  • Example 2's Box 2 of side length 38.1 cm (15 inches) was able to contain almost as large an explosive charge as the control cubic container of Example 1 of side length 78.7 cm 31 inches and having almost an identical areal density (made utilizing SPECTRA SHIELD composite panels).
  • similar performance is obtained using a box significantly lighter and smaller than that of the control, i.e., 1/4 the weight of the control and containing 1/8 the volume.
  • the boxes designed in accordance with the present invention are much easier to open and close and do not have steel hinge pins which can act as long rod penetrators during an explosive event. It is interesting to note that the box of the comparative example utilizing SPECTRA SHIELD composite panels outperformed the box utilizing KEVLAR composite panels.
  • Example 2 Examination of the boxes of Example 2 after explosive testing, coupled with evaluation of high speed photography results, indicated that container failure did not occur by "shock holing" (rupture caused by the impulse of the shock wave against the container wall). Shock holing would have caused rupture of the containers at the center of the faces of the cube. In no case was this observed; failure occurred along the edges of the boxes.
  • the bands of theses boxes distorted and allowed venting of gases.
  • the flaps of the flapped boxes helped to control, but did not eliminate, the venting of hot gases.
  • the inner band was made more rigid in Example 3 by incorporating a rigid epoxy inner shell. This container easily contained 170 gr (6 ounces) of explosive, with minimum distortion, no rapid venting and essentially no visible permanent damage to the structure.
  • the blast mitigating material improved the efficiency of the blast resistant container significantly.
  • the temperature of the constrained foam was raised significantly above the ambient temperature of about 25°C.
  • foam temperature was 70°C when measured in a container assembly which had withstood the explosion of 170 g (6 ounces) of C4.
  • Example 6 shows that aqueous foam not only mitigates blast, but also prevents fire. At a charge level approximately one-half of the C 50 of the container plus foam assembly, there was significant container damage, followed by a fire which destroyed the container.
  • Examples 7 - 11 show that the aqueous foams play a critically important role in providing blast protection, providing protection against explosive charges weighing 2 to 4 times that of what can be contained without foam. These examples further show that coarse fabric constructed from higher denier SPECTRA 900 yarn gives similar blast protection to the considerably more expensive fine fabrics utilizeing lower denier SPECTRA 1000 yarn. All of these examples included containers that were collapsible when empty, i.e., without blast mitigating material therein. These are especially useful in space constrained environments.
  • Example 12 illustrates that blast resistance is improved when air is replaced with a low sonic velocity, condensable gas, in combination with a non-collapsible container having bands and a door for closure.
  • certain of these gases can also curtail the oxidation process and prevent fires.

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Claims (5)

  1. Explosionssicherer Behälteraufbau (10) zur Aufnahme eines Sprengstoffs, der Folgendes umfasst: '
    a. einen Behälter aus explosionsfestem Material, wobei der Behälter für Lagerungszwecke zusammenlegbar ist, wenn er leer ist; und
    b. ein explosionsabschwächendes Material (14) innerhalb des Behälters,
    wobei der Behälter aus mindestens drei Bändern (11, 12, 13) besteht, die im zusammengebauten Zustand in Bezug auf einander ausgerichtet sind, um im Wesentlichen ein Volumen zu umschließen und eine Behälterwand zu bilden, wobei die Bänder im zerlegten Zustand zur Lagerung faltbar sind und zumindest eines der Bänder aus einem explosionsfesten Material besteht, dadurch gekennzeichnet, dass die Bänder ein erstes Innenband (11) enthalten, das innerhalb eines zweiten Bandes (12) eingeschachtelt ist, welches innerhalb eines dritten Bandes (13) eingeschachtelt ist, wobei die Bänder übereinander verschiebbar sind und eine Behälterwand mit einer Dicke bilden, die im Wesentlichen mit der Summe der Dicken von mindestens zwei Bändern äquivalent ist, und dass jedes der Bänder eine Vielzahl von Flächen aufweist, wobei jede Fläche mit einer anderen Fläche an wenigstens einer gemeinsamen Kante durch ein Fasermaterial verbunden ist und das Fasermaterial zwischen den Flächen als Scharnier funktioniert, wobei die Flächen von wenigstens einem Band starr sind.
  2. Behälteraufbau nach Anspruch 1, bei dem das explosionsabschwächende Material aus einer Gruppe bestehend aus polymeren Schaumstoffen, Partikeln, verflüssigbaren Gasen, wärmeabführenden Materialien, Schaumglas, Mikrobällen, Bällen, Blasen, Hohlkugeln, Dochtfasern und Kombinationen derselben gewählt wird.
  3. Behälteraufbau nach Anspruch 1, bei dem das explosionsabschwächende Material wässrigen Schaumstoff umfasst.
  4. Behälteraufbau nach Anspruch 1, bei dem das explosionsfeste Material zumindest eine Faserschicht umfasst, diese Faserschicht aus mindestens einem Fasernetzwerk besteht, wobei wenigstens ungefähr 50 Gewichtsprozent der Fasern im Wesentlichen Endlosfaserlängen sind, die das eingeschlossene Volumen umschließen.
  5. Behälteraufbau nach Anspruch 4, bei dem das Fasernetzwerk in einer Harzmatrix eingebettet ist.
EP97922297A 1996-09-20 1997-04-11 Explosionsfeste, explosionsrichtung steuernde verpackung Expired - Lifetime EP0927330B1 (de)

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US717042 1985-04-01
US71704296A 1996-09-20 1996-09-20
PCT/US1997/006055 WO1998012496A1 (en) 1996-09-20 1997-04-11 Blast resistant and blast directing container assemblies

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EP0927330B1 true EP0927330B1 (de) 2004-03-31

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CN1238040A (zh) 1999-12-08
DE69728409T2 (de) 2005-03-31
CA2266312A1 (en) 1998-03-26
AU741018C (en) 2002-08-08
KR100476827B1 (ko) 2005-03-18
JP2001501896A (ja) 2001-02-13
AU2801097A (en) 1998-04-14
EP0927330A1 (de) 1999-07-07
IL129073A (en) 2007-05-15
IL129073A0 (en) 2000-02-17
DE69728409D1 (de) 2004-05-06
CN1110687C (zh) 2003-06-04
HK1025626A1 (en) 2000-11-17
TW344028B (en) 1998-11-01
KR20000048505A (ko) 2000-07-25
CA2266312C (en) 2006-10-17
JP4502409B2 (ja) 2010-07-14
MY118681A (en) 2005-01-31
WO1998012496A1 (en) 1998-03-26
AU741018B2 (en) 2001-11-22

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