EP0855350B1 - Récipient pressurisé à deux valves - Google Patents
Récipient pressurisé à deux valves Download PDFInfo
- Publication number
- EP0855350B1 EP0855350B1 EP97403066A EP97403066A EP0855350B1 EP 0855350 B1 EP0855350 B1 EP 0855350B1 EP 97403066 A EP97403066 A EP 97403066A EP 97403066 A EP97403066 A EP 97403066A EP 0855350 B1 EP0855350 B1 EP 0855350B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- valve
- product
- reservoir
- valve stem
- stem
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/42—Filling or charging means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
Definitions
- the invention relates to a new pressurized container, having, with a reduced number of parts, two valves: a first valve for the distribution of product, and a second valve for filling the container, refilling this when its content has been exhausted, or adding an additional asset to the product initially contained in the container.
- the invention is particularly suitable for the distribution of cosmetic or dermo-cosmetic products, under liquid, foam, gel, or cream form.
- such a small device can be used advantageously for a precise dosage of product for each use, especially in the field of pharmacy and dermo-cosmetics.
- a concept has still not seen the light of day, mainly for cost reasons.
- a pressurized container even a small one, requires, in order to function, a certain number of essential elements, which are the container body, i.e. a tin or aluminum can, on the walls of which a varnish is deposited and on the neck of which is crimped a valve, via a valve holder cup, as well as a distribution means connected to the valve.
- the technique of manufacturing pressurized cans does not allow manufacturing cans small enough to match the volume of a test dose, or 3.5 ml to 8 ml approximately.
- the work of crimping metal crimping the valve holder cup, on the container body, on the one hand, and around the valve, on the other hand
- This manufacturing constraint therefore conditions the size of the valve holder cup and therefore the volume of the container, which is necessarily greater than a dose of use.
- rechargeable devices always consist of a container, a first valve for the distribution of the product, a system of filling, which is in fact, no more and no less than a second valve.
- German patent DE 1,166,225 describing such a container fitted with two valves, each valve comprising a valve body and a separate spring, for, in the absence of an actuation command, maintain the valves in the closed position.
- Patent FR 1 228 733 describes a refillable aerosol can, in which the filling or recharging, is carried out by means of an auxiliary container, by the same valve as that used for dispensing the product.
- patent FR 2 378 572 describes a process making it possible to aspirate and store a predetermined dose of a product, inside a removable head.
- the two operations occur simultaneously by the compression of a spring during the screwing of the head on a tank, and the compression of the dose stored at adequate pressure by loosening the head and releasing the same spring, so that, after the separation of the head and the tank, the head, made independent, can be used as an aerosol can.
- Spraying takes place by opening a separate valve held in the closed position by a separate spring.
- Another problem is to offer the consumer products cosmetics, for example, products combining two active ingredients in one only formula.
- products two in one "available on the market, such as treating shampoos, styling-nourishing, make-up removers and moisturizers, etc.
- Such packaging is not possible as long as the two assets are compatible with each other and compatible with the support.
- Some formulas are impossible to formulate in the current state of the art, because the two active agents are incompatible with each other.
- the difficulty with such products is that since the assets are not stable when mixed, they should be used quickly after mixing and by therefore, must be either single-dose or of sufficiently small volume to be used in a shorter period of time than the time during which the mixture is active enough to be used with good efficacy.
- Patent applications EP-A-063 759 and EP-A-217 582 describe systems for the extemporaneous mixing of two products by means of devices pressurized, mixing takes place in a device with two valves: a valve intake and distribution valve. Each of the valves has a cup, valve body, valve stem, seal and spring. Such a design has the disadvantage of being of a high cost price, due to the number of parts used. Furthermore, it does not authorize manufacturing single-dose, or multi-dose devices of low volume. A similar system is described in patent FR 1 431 181.
- a device comprising a pressurized product tank, on which a first valve is mounted and a second valve, said second valve being oriented opposite the first valve, and substantially in alignment with the first valve, means for distribution being associated with at least one of said first or second valves, each of the valves comprising means for, in response to a command, selectively allow the opening / closing of said valves, means of elastic reminder for, in the absence of an order, to request resources opening / closing in closed position, characterized in that said first and second valves are mounted inside the same body in communication with the reservoir, and are biased in the closed position by the same means of elastic recall.
- a device with two actuated valves is produced independent, and this, with a limited number of pieces.
- the means for opening / closing the first and / or the second valve may consist of an emerging valve stem, of the side-tilt type, or depressing.
- a lateral tilting rod being a rod mounted so as to ability to tilt out of its axis, so as to connect a passage or orifice in the vicinity of its lower end, with the body valve on which it is mounted, thus allowing the product under pressure, contained in the valve body, to go back up inside the valve stem view of its distribution.
- a push-in valve stem setting communication of the passage or orifice, is ensured by pushing in the rod in the valve body, along the axis of the stem.
- the means for opening / closing the first and / or the second valve consist of a female member capable of receiving so removable, a control rod.
- This control rod can be part part of an actuation and distribution device, button type pusher, or consist of the valve stem emerging from an auxiliary container used to recharge the device. This characteristic, especially for the valve intended for refilling the container, is a possible solution to the problem accidental actuation of the filling valve.
- the device may include a push button mounted on the first valve, in view of valve actuation and product distribution, the second valve being intended for filling or refilling the tank.
- the push button includes a diffusion means, of the grid, porous dome, or nozzle.
- the device comprises a body and a bottom, the body forming a valve holder cup for the first valve, the bottom forming a valve cup for the second valve, the body of the device cooperating with the bottom to form, on the one hand, the reservoir of pressurized product, and on the other hand the valve body for said first and second valves.
- This configuration is particularly advantageous in that it helps to limit even more importantly the size of the device and the number of parts put used in such a device, thereby also reducing its cost of manufacturing. Furthermore, the mounting of such a device is very simple.
- the first valve may include a first valve stem including a first end opens into the valve body, a second end opening out of the valve body, the second valve comprising a second valve stem, a first end of which opens inside the body valve, substantially opposite the first end of the first rod valve, a second end opening to the outside of the valve body, the elastic return means consisting of a spring bearing between said first ends of said first and second valve stems.
- the first end of the second valve stem advantageously has a substantially flat portion, one face of which is situated opposite the bottom of the valve body, the second valve being held in the closed position by a support elastic between a sealing ring formed on said face and a seal crossed by the second valve stem and disposed in the bottom of the valve body, said seal being in tight contact, on the one hand with the internal walls from the second central chimney, and on the other hand with the second valve stem.
- the body of the device can be tightly mounted on the bottom by welding, snap-fastening, screwing or gluing.
- the body may consist of a transverse wall, forming a valve holder cup for the first valve, a first side skirt defining an external contour for the tank, and a first central chimney of given internal diameter, and defining an internal contour for the reservoir, the bottom having a wall transverse, forming valve holder cup for the second valve, a second side skirt cooperating with the first for attaching the bottom to the body, and a second central chimney forming a valve body, said second chimney central with an external diameter, slightly smaller than the internal diameter of the first central chimney, means being provided to allow the communication between the tank and the valve body.
- the transverse wall of the body has, according to a preferred embodiment, at outside the device, an annular groove between the first side skirt and the first central chimney so as to receive a free edge of said means of distribution.
- the first and second central chimneys are preferably of height substantially identical, said first central chimney having an edge free welded to the transverse wall of the bottom.
- the means allowing communication between the reservoir and the valve body are arranged to allow either upside down operation or head at the top of the device, whatever the position of the device.
- the choice of this or that configuration depends on the application of the device and its Terms of use.
- the bottom has a step in which the second valve stem emerges, said recess having a height according to the axis of the device greater than the height of the emerging part of the second valve stem.
- such an offset is used in a way advantageous, in the case of a female type opening / closing member, for stacking several such devices.
- Such a drop can present on its lateral walls external to the device, a profile forming a key, said profile having a profile complementary to that of an adapter intended for be mounted on an auxiliary container for recharging the device.
- This characteristic makes it possible to prevent, or in any case, to limit so the risks of filling the container with a product other than that recommended by the device manufacturer, which could constitute a danger to the person performing such filling. This also allows limit the risk of seeing a container, initially marketed for a product of a given trademark, recharged later by a product competitor.
- the bottom can be between the second side skirt and the second chimney central, a rounded annular profile, the concavity of which faces inwards of the tank. This characteristic contributes to substantially improve the degree of emptying of the tank.
- the first end of the first valve stem forms an axial stop so as to limit the movement of the second rod of valve when the second valve is opened for filling or tank refill.
- the end of the second valve stem opening to the outside of the device, is preferably of a shape adapted to cooperate with a free end of a valve stem of a pressurized auxiliary container for recharging the device.
- said end of the second valve stem has a frustoconical profile.
- the product can be pressurized by means of a liquefiable gas mixed with the product for "aerosolizable" formulas.
- pressurization is made by means of a closed cell cellular material organ, at the by means of a non-liquefiable gas above the free surface of the product, or at by means of a gas under pressure separated from the product by a flexible or rigid element, type, piston, pocket, etc.
- the assembly also includes an adapter for mounting means for distributing the second device on the means for admitting the first device, for the transfer of product B into the first device.
- the means for pressurizing the mixture A + B can comprise a liquefiable propellant, or an isolated non-liquefiable propellant optionally mixing by a flexible bag or a plunger.
- the means for pressurizing the mixture A + B comprise a block of closed cell foam.
- Product B can be kept under pressure in the second tank device by a liquefiable propellant, a block of cellular foam closed cells, a non-liquefiable propellant, possibly isolated from the mixing by a plunger or a flexible bag.
- a method is also carried out for the preparation of an extemporaneous mixture of at least two products A and B, intended for be distributed under pressure, characterized in that it is implemented by means of an assembly according to the invention.
- Product A can be placed in the first device when mounting this one, or after mounting it, by transfer from another device pressurized.
- Product A can be in the form of a powder (Vitamin, Enzymes, etc.) of a liquid or cream (silicone for styling and fixing sprays, etc.).
- the mixture A + B is chosen by way of example from the following mixtures: keratolitic enzymes / moisturizing lotion, vitamins / nourishing cream, sprays fixants / shiny sprays, styling mousse / detangling mousse, etc.
- the pressurized container of FIG. 1, of generally cylindrical shape, of axis X, is composed of a body 2 having a transverse wall 3 forming a cup valve holder for a distribution valve 4.
- the body has a side skirt 5 delimiting the external contour of the reservoir 6 containing a pressurized product P, and forms a chimney or axial skirt 7 delimiting the internal contour of the tank 6.
- the body has an annular recess 47 so as to receive by snapping for example, a removable cover (not shown).
- the recipient also includes a bottom 8 consisting of a transverse wall 9, and a skirt lateral 100 comprising an external profile capable of cooperating with the internal profile of the lower part of the skirt 5, in order to ensure a tight mounting of the body 2 on the bottom 8.
- the assembly can be carried out by any suitable technique.
- the body can be welded (ultrasound, mirror, rotational welding), screwed, or slammed on the bottom.
- the bottom 8 forms a valve holder cup for the valve 13.
- the bottom has a concavity 46 facing the interior of the tank. This concavity allows better emptying of the tank and provides greater resistance pressure to the entire device.
- the bottom 8 forms a chimney or axial skirt 10, of slightly outer diameter smaller than the internal diameter of the axial chimney 7, so that it can be mounted inside the axial chimney 7 and form a valve body 11, which will be discussed in more detail later.
- the body valve 11 is delimited by the axial chimney 10, the transverse wall 3 of the body, and a part 12 of the bottom 8, forming an axial offset 14 relative to at the bottom 8.
- the step is slightly higher than the height of the emerging part of the valve stem 15, so as to prevent any accidental actuation of the intake valve 13.
- the heights of the two axial skirts 7 and 10 are substantially identical to so that the free edge of the skirt 7 is substantially in contact with the internal wall the bottom.
- the free edge of the skirt 7 is welded to the bottom. Apart from waterproofing, this welding gives greater resistance to the entire container, in especially better resistance to gas pressure.
- This weld can be carried out by any means known to those skilled in the art, such as, for example, ultrasonic, mirror, rotational welding, bonding.
- a chamfer 16 On the internal periphery of the skirt 7 is disposed a chamfer 16.
- An orifice 17 is formed in the lower part of the skirt 7 and opens onto a groove or groove 18 formed for example over the entire height of the internal surface of the axial skirt 7.
- the groove 17 opens at the top of the container onto an orifice 19 crossing the axial skirt 10.
- This arrangement allows the communication of the reservoir 6 with the interior of the valve body 11.
- Such a container is used head at the top, and is particularly suitable for dispensing hairspray, lotion capillary, or perfume, etc.
- the orifice 17 in the axial skirt 7 is placed at the same level as the orifice 19 in the axial skirt 10, so that no groove is required between the walls of the two axial skirts 7 and 10. This configuration allows head-down operation of the device.
- the device according to the invention comprises inside the same valve body 11, two valves 4 and 13.
- the first valve is a product distribution. It includes a valve stem 20, centered on the X axis, and comprising an emerging part 28 outside the container, through an orifice formed in the transverse wall 3.
- On the emerging part 28 of the rod valve 20 is mounted an actuation and distribution device 21, of the type pushbutton.
- the transverse wall defines a groove annular 22 between the side skirt 5 and the axial skirt 7, so as to receive the free annular edge 23 of the push button. The depth of the groove 22 is chosen so as to allow the push button sufficient axial travel for actuating the valve stem 20.
- the valve assembly 4 is sealed by means of a seal seal 23, of external diameter substantially equal to the internal diameter of the axial skirt 7, and held in abutment against the transverse wall 3 by the edge upper annular of the axial skirt 10.
- the valve stem is provided with at least an orifice or radial passage 24, opening onto an internal axial channel 25.
- the end 26 of the valve stem 20 opening out inside the valve body 11 has a shoulder, one face of which bears on the seal, preferably, via a sealing ring 40.
- the other face forms a bearing surface for a first end 33 of a helical spring 27, the restoring force keeps the shoulder in abutment against the seal 23. In this position, the orifice 24 is opposite the seal, which ensures a sealed closure of said orifice.
- the seal 23 is an attached seal.
- the seal forms a single piece with the body of the device, and is obtained by bi-injection of an elastomeric material during the manufacture of the body 2.
- a second valve 13 comprising a valve stem 15, facing away from the valve stem 20, and located in the axis X of the container 1.
- the valve stem 15 is of structural similar to the valve stem 20.
- This valve stem 15 has one end 29 opening out of the container, in the recess 14, through a opening made in part 12 of the bottom.
- the other end 30 leads to the inside of the valve body 11 and forms a shoulder of which one face is in support on a seal 31, via a seal ring 32.
- the other face of the shoulder serves as a support for the end 34 of the spring 27, opposite to the end 33.
- the spring maintains on the one hand the sealing ring 40 of the first valve 4 against the seal 23, and on the other hand the rod 32 of the valve 13 resting on the seal 31.
- a radial passage 35 of the valve stem faces the seal 31.
- the seal 31 is mounted tight in the bottom 36 of the valve body.
- the rod valve is also mounted tight in the central hole of the seal 31.
- the seal 31, tightened on the valve stem resumes its initial position at the bottom of the valve body, the sealing being completed by the presence of the sealing ring resting on the gasket 31.
- the part 26 of the rod valve 20, located inside the valve body 11 is extended by an axial part 37 forming a stop for the part 30 of the valve stem 15, so as to prevent the valve stem 15, when the latter is pressed axially, to enter completely inside the valve body 11, which would make the device completely inoperative, and would cause the untimely exit of product P.
- valves 4 and 15 contained in the same valve body 11, and biased in the closed position by the same means elastic 27.
- Means other than a spring could be used. Both valves are independently operated.
- the distribution of the product is ensured by action on the push button 21, which causes the valve stem 20 to sink in, and the communication of the orifice 24 with the valve body.
- the actuation and distribution means are of different structure and advantageously include diffusion means (not shown), type, nozzle, grid, or porous dome. Releasing the pressure exerted on the push button 21, the return force of the spring 27, urges the part 26 resting on the seal 23, and the orifice 24 opposite the seal 23, interrupting thus the distribution of product P.
- valve 42 When the content of the reservoir 6 is exhausted, the user recharges the latter at by means of a pressurized container 41, at the top of which is crimped a valve 42.
- This valve comprises an emerging valve stem 43 having an internal channel 44 of diameter slightly greater than the diameter of the end of the rod emerging 15 from the intake valve.
- the end of the rod 15 has a frustoconical profile, so as to promote tight cooperation between the two valve stems 15 and 43.
- a axial depression of the valve stem 15 which causes setting communication of the passage 35 with the interior of the valve body 11.
- the portion 30 abuts against portion 37 of valve stem 20.
- the movement is transmitted to the valve stem 43 of the auxiliary device 41, which causes the rod 43 to sink, and the opening of valve 42.
- the product under pressure contained in device 41 rises in the channel 44 and is transferred to the internal channel 45 of the valve stem 15, then is conveyed into the tank 6, via the passage 35, the valve body 11, the orifice 19, the groove 18, the chamfer 16 and the lower orifice 17.
- the transfer is continues until the pressure balance is reached between the device 41 and the device 1.
- the device 1 thus recharged can be used again, in the conditions described above.
- the container according to the invention is made of material thermoplastic, using the same material or two different materials, chemically compatible, so that they can be welded together.
- materials which can be used in the present invention there may be mentioned, for example, the family of polyolefins, such as polypropylene, polyethylene and copolymers of ethylene and propylene, the family of polyacetals, such as polyoxyethylene. It is also possible to use polyethylene tetphthalate, polymethyl methacrylate.
- polybutylene terephthalate for reasons waterproofing and keeping the formula.
- the polymer used for the device according to the invention can comprise also fillers such as silica, glass fibers, or carbon.
- the product is pressurized at using liquefiable gas.
- liquefiable gas any suitable gas that can be used to pressurize the product, in particular for formulas not "aerosolizable" such as liquid to pasty, self-foaming formulas, etc. these products, pressurization is ensured either by a non-liquefiable gas, pressing directly on the free surface of the product, either by means of a gas compressed, isolated from the product by a flexible bag or a plunger.
- a piston is used fitted at its periphery with sealing means of the type sealing lips allowing a tight positioning of the piston relative to the side skirt 5 and relative to the axial skirt 7.
- the piston may have a profile adapted to the profile of the bottom, or of the upper transverse wall 3 of the device 1, so as to allow complete emptying of the tank.
- a deformable pocket is used attached to a cylindrical coil.
- the pressurization of the product in the tank is ensured by means of a block of foam foam closed cells, in the form of a ring arranged, before mounting the bottom on the body, around the axial skirt 7.
- the ring of foam When filling with product, the ring of foam, preferably split over its entire height, compresses in a multi-directional manner, which ensures the pressurization of the product in the tank.
- a plastazote polyolefin foam and gas consisting nitrogen
- the gas can be any compressible gas or liquefiable at working pressures or can simply be air. All these pressurization means which can be used according to the invention are described from in detail in French application FR-96/05918, filed on behalf of the Applicant on May 13, 1996.
- FIGS. 3A and 3B differs from that in FIGS. 1 and 2A-2B, in that it includes a security key which has two specific functions: protect the emerging rod of the auxiliary device 41 on the one hand, and on the other hand, prevent the filling of device 1 with a product other than that provided for in the device manufacturer.
- a security key consists of an adapter 50, comprising means 51 to allow it to be mounted by breakdown, for example, on the top of the auxiliary device 41.
- the adapter comprises an axial chimney 52, which is forcibly mounted on the valve stem 43 of the valve 42.
- the axial chimney 52 has an external diameter slightly smaller than the internal diameter of the step 14.
- the axial chimney 52 has a height slightly greater than the height of the valve stem 43, so that one cannot trigger the unexpected opening of the valve 42 by simple pressing of any object on the top of the rod 43.
- the external walls 54 of the recess 14 have a profile of notch type 53, able to cooperate with a complementary profile of the wall outside of the axial chimney 52.
- FIG. 4 illustrates another use advantageous device according to the invention.
- the device is used as a mixer of two active ingredients A and B, which can only be mixed just before use.
- a and B active ingredients
- the dosage form of this active does not matter: we can consider a powder, such as vitamin or enzymes, or a liquid or cream, such as silicone in the case of styling and fixing sprays. In the case of "aerosolizable" products, we weld then the background on the body.
- non “aerosolizable” products advantageously has a cell foam ring above the product closed M, before mounting the bottom on the body.
- the foam ring M occupies all the space above the product A and is preferably in slight compression.
- the product B is pressurized in the auxiliary device 41, either by a propellant liquefiable, either by a block of closed-cell foam, or by any other propellant means isolated from product B by a flexible bag or a piston.
- the mixture is immediate and can be used at once.
- the foam closed cell thermoplastic M will contract when filling with product B, and allowing the latter to reach the first A, possibly playing the role of agitator to help mix the two active ingredients.
- the foam ring can be split over its entire height, thus forming an open ring, so that it can contract in all directions (laterally and longitudinally).
- the open ring can thus contract to such an extent that it only partially surrounds the chimney 7, and this on only part of its height, thus authorizing the product B to mix with product A.
- the open foam ring returns to its original shape while around the chimney 7.
- kits comprising several mini-devices 1 partially filled with active ingredient A, a larger pressurized container containing the active ingredient B, the largest container with sufficient capacity and pressure to fill at least all the mini-devices in the kit.
- the kit may include a transfer adapter between the large container and the mini-devices.
- the mini-devices are delivered empty, and are sold with two auxiliary pressurized containers, one containing product A, the other containing product B. The user first transfers a given quantity of product A from the manner previously described with reference to the previous figure, then, from the same way, add to the device partially filled with product A, a quantity of product B so as to complete the reservoir and form a mixture A + B.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Closures For Containers (AREA)
- Multiple-Way Valves (AREA)
- Supply Devices, Intensifiers, Converters, And Telemotors (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9700635 | 1997-01-22 | ||
FR9700635A FR2758537B1 (fr) | 1997-01-22 | 1997-01-22 | Dispositif pressurise a deux valves |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0855350A1 EP0855350A1 (fr) | 1998-07-29 |
EP0855350B1 true EP0855350B1 (fr) | 2002-04-10 |
Family
ID=9502857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97403066A Expired - Lifetime EP0855350B1 (fr) | 1997-01-22 | 1997-12-17 | Récipient pressurisé à deux valves |
Country Status (9)
Country | Link |
---|---|
US (1) | US5894958A (ja) |
EP (1) | EP0855350B1 (ja) |
JP (1) | JP2933579B2 (ja) |
AR (1) | AR011426A1 (ja) |
CA (1) | CA2224502C (ja) |
DE (1) | DE69711839T2 (ja) |
ES (1) | ES2175310T3 (ja) |
FR (1) | FR2758537B1 (ja) |
MX (1) | MXPA98000479A (ja) |
Families Citing this family (8)
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JP4666716B2 (ja) * | 2000-05-26 | 2011-04-06 | 株式会社ダイゾー | エアゾール製品 |
US20040084479A1 (en) * | 2002-11-04 | 2004-05-06 | Domoy Brett C. | Valve |
GB0328564D0 (en) * | 2003-12-10 | 2004-01-14 | Dunne Stephen T | Variable flow discharge metered dose valve |
FR2868050B1 (fr) | 2004-03-24 | 2006-06-02 | Oreal | Ensemble de conditionnement et de distribution d'un produit |
CA2580666C (en) * | 2004-09-16 | 2014-01-28 | Clayton Corporation | Improved aerosol dispenser valve |
FR2904613B1 (fr) * | 2006-08-03 | 2010-12-31 | M Plascopar Sa | Dispositif de recharge pour flacon rechargeable |
NL1039786C2 (en) * | 2012-09-03 | 2014-03-04 | Markus Franciscus Brouwer | Foam dispenser. |
DE102018101238A1 (de) * | 2018-01-19 | 2019-07-25 | Carl Hoernecke Chem. Fabrik Gmbh & Co. Kg | Wirkstoffpatrone sowie Selbstverteidigungsgerät |
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GB975287A (en) * | 1961-06-08 | 1964-11-11 | Seary Ltd | Improvements in metering valve assemblies for use with pressurized containers |
US3181737A (en) * | 1963-09-30 | 1965-05-04 | R H Macy & Co Inc | Method of storing, combining and applying two-part polymer mixtures |
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US3447722A (en) * | 1968-02-09 | 1969-06-03 | Rexall Drug Chemical | Plural source valved pressurized fluid dispenser |
US3637114A (en) * | 1970-09-03 | 1972-01-25 | Philip Meshberg | Device for codispensing two materials |
FR2378572A1 (fr) * | 1977-01-28 | 1978-08-25 | Normos Norbert | Tete de pulverisation de type nouveau |
DE3116282A1 (de) * | 1981-04-24 | 1982-11-11 | Henkel KGaA, 4000 Düsseldorf | "aerosol-verpackung" |
GB8522813D0 (en) * | 1985-09-16 | 1985-10-23 | Unilever Plc | Package |
-
1997
- 1997-01-22 FR FR9700635A patent/FR2758537B1/fr not_active Expired - Fee Related
- 1997-12-17 EP EP97403066A patent/EP0855350B1/fr not_active Expired - Lifetime
- 1997-12-17 DE DE69711839T patent/DE69711839T2/de not_active Expired - Fee Related
- 1997-12-17 ES ES97403066T patent/ES2175310T3/es not_active Expired - Lifetime
-
1998
- 1998-01-15 MX MXPA98000479A patent/MXPA98000479A/es not_active IP Right Cessation
- 1998-01-20 AR ARP980100228A patent/AR011426A1/es unknown
- 1998-01-21 CA CA002224502A patent/CA2224502C/fr not_active Expired - Fee Related
- 1998-01-21 JP JP10009915A patent/JP2933579B2/ja not_active Expired - Fee Related
- 1998-01-22 US US09/012,178 patent/US5894958A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2224502A1 (fr) | 1998-07-22 |
MXPA98000479A (es) | 2005-03-31 |
DE69711839D1 (de) | 2002-05-16 |
DE69711839T2 (de) | 2002-08-29 |
FR2758537A1 (fr) | 1998-07-24 |
JPH10211949A (ja) | 1998-08-11 |
AR011426A1 (es) | 2000-08-16 |
ES2175310T3 (es) | 2002-11-16 |
US5894958A (en) | 1999-04-20 |
FR2758537B1 (fr) | 1999-02-26 |
CA2224502C (fr) | 2003-07-22 |
EP0855350A1 (fr) | 1998-07-29 |
JP2933579B2 (ja) | 1999-08-16 |
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