EP0843587A1 - Procede permettant de reduire la teneur en dioxine et en furane dans des gaz brules de fours et utilisation des poussieres de filtrage produites a cette occasion - Google Patents
Procede permettant de reduire la teneur en dioxine et en furane dans des gaz brules de fours et utilisation des poussieres de filtrage produites a cette occasionInfo
- Publication number
- EP0843587A1 EP0843587A1 EP96927659A EP96927659A EP0843587A1 EP 0843587 A1 EP0843587 A1 EP 0843587A1 EP 96927659 A EP96927659 A EP 96927659A EP 96927659 A EP96927659 A EP 96927659A EP 0843587 A1 EP0843587 A1 EP 0843587A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkali compound
- filter
- approx
- injected
- dioxin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
- B01D53/70—Organic halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/0084—Obtaining aluminium melting and handling molten aluminium
- C22B21/0092—Remelting scrap, skimmings or any secondary source aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S75/00—Specialized metallurgical processes, compositions for use therein, consolidated metal powder compositions, and loose metal particulate mixtures
- Y10S75/961—Treating flue dust to obtain metal other than by consolidation
Definitions
- the invention relates to a method for cleaning furnace exhaust gases from melting, remelting or combustion plants, and to the use of the filter dusts which are produced in the process.
- the invention is used in particular in the manufacture or processing of non-ferrous metals, the filter dusts being returned to the melting process.
- a disadvantage of the known processes is that the removal rate of the dioxins and furans often does not meet the requirements.
- the resulting filter dust is usually deposited.
- melting aids e.g. B. salt salts and energy supplied.
- Metal, slag, e.g. B. salt slag, and pollutant and dust-containing exhaust gases leave the production process.
- the quantities of slag obtained are either processed for landfill or deposited.
- the exhaust gases are primarily freed of dust, sulfur dioxide, HCl and HF. Methods are usually used for this, in which u. a. Quicklime or calcium hydroxide can be used. The resulting filter dust is deposited.
- furnace types are used for the production of cast aluminum alloys, which are heated electrically or with gas or oil.
- the rotary drum oven is widespread. It is particularly suitable for melting contaminated aluminum waste, shavings and other small-sized materials, but especially for starting materials with low yield.
- the melting of the aluminum-containing scrap (aluminum waste, aluminum chips, aluminum dross, etc.) in the rotary drum furnace usually takes place under a closed salt blanket.
- the purpose of the salt is to prevent oxidation of the aluminum, to bind the non-metallic impurities in the metal-containing insert and to facilitate the detachment of oxide layers from the base metal.
- the salt from which the salt layer is formed consists of approx. 70% NaCl, approx. 30% KC1 and approx. 5% flux.
- the process temperatures are between 600 ° C and 900 ° C depending on the alloy.
- Fossil fuels are used as energy sources.
- the exhaust gas stream also contains S0 2 , the composition of the exhaust gas constituents depending on the materials to be melted and the heating medium being able to vary.
- sublimed alkali metal chlorides and fluorides, aluminum oxide and small amounts of heavy metals, aluminum in metallic form and free and organically bound carbon, inter alia in the form of dibenzodioxins and furans (PCDD / F) are contained in the exhaust gas. Both the exhaust gas and the salt slag obtained must be freed from the pollutants.
- the salt slag can be processed by the dissolving process in such a way that the cleaned mixed salt is used again as the top salt in the rotary drum furnace.
- the insoluble sediments (alumina residue) remaining after the dissolving process are processed further.
- the exhaust gases which contain environmentally harmful components, are currently freed from undesired components in exhaust gas purification systems.
- the exhaust gases are usually treated in a dry process at approx. 100 to 350 ° C with Ca (OH) 2 as sorbent, with free chlorine, HCl. HF and S0 2 react to CaCl 2 , CaF 2 and CaS0 4 .
- the dioxins and furans are bound by adsorption.
- At least one alkali compound is introduced into the exhaust gas, if appropriate in the presence of activated carbon and / or stove coke, and the filter dust is returned to a melting or combustion process.
- Sodium carbonate, sodium hydrogen carbonate, sodium hydroxide, potassium carbonate, potassium hydroxide, potassium hydrogen carbonate are used alone or as a mixture as the alkali compound. If technical mixtures are used, impurities e.g. B. on alkaline earth compounds in the range of ⁇ 5% are accepted without the essence of the invention being impaired.
- the activated carbon and / or the hearth furnace coke can either be separated or introduced into the exhaust gas stream in a mixture with the alkali compound.
- sodium hydrogen carbonate which has an average particle size of 1 to 100 ⁇ m, preferably 5 to 40 ⁇ m, in particular 10 to 35 ⁇ m, is sprayed dry into a reactor or into the flue gas duct, preferably against the direction of flow, and mixed with the flue gases mixes.
- the residence time in the flue gas is at least 0.5 seconds, preferably more than 2 seconds. During this time, the reaction of the harmful substances takes place e.g. B. to NaCl, NaF and Na 2 S0 4 .
- technical grade sodium hydrogen carbonate was used, which has the following composition:
- the effect of the alkali compound can be improved by adding activated carbon and / or stove coke.
- the dioxins and furans are adsorbed.
- the concentration of HCl in the clean gas is usually chosen as a guideline for the amount of additive added.
- HCl is the main pollutant that is separated with sodium bicarbonate. Due to the fluctuations in the raw gas values that occur during operation, the amount of additive required cannot be clearly defined.
- the amount of additive actually used therefore depends on the amount of pollutant actually to be separated. For example, about 8 to 12 kg of additive are used per ton of aluminum.
- An optimized amount of additive is particularly important with regard to the return of the filter dust to the aluminum melt.
- Sodium hydrogen carbonate not reacted with pollutants decomposes to sodium carbonate. Too high a proportion of sodium carbonate in the salt can lead to aluminum losses in the melting process. For economic reasons, however, aluminum losses are to be kept as low as possible.
- the minimum reaction temperature for flue gas cleaning is approx. 70 to approx. 500 ° C, preferably between 90 and 280 ° C.
- the gas stream, the z. B. contains sodium chloride, sodium sulfate and sodium carbonate happens z. B. a fabric filter in which the solids are separated.
- the separated filter dust from the flue gas cleaning largely contains NaCl as well as small amounts of e.g. B. Sodium sulfate, sodium fluoride and additive components not reacted with pollutants.
- the dioxins and furans contained in the flue gas cleaning residues are destroyed on the one hand by carrying out the reaction in the melting furnace. Furthermore, the returned filter dust suppresses the formation and / or decomposition of already formed dioxins and furans.
- Another positive aspect is that the amount of additive required can be reduced in comparison with hydrated lime as an additive for flue gas cleaning. For example, only about 30 to 60% by weight of the usual amounts of additives are required.
- Another advantage of the method according to the invention is the possibility of using the alkali metal compounds formed in further processes, e.g. B. the use of sodium compounds as sodium carriers or as additives for a wide variety of processes. It is also within the meaning of the invention to exhaust gases from other production processes, e.g. B. incinerators, analogous to the process described above by dry injection of z. B. sodium bicarbonate, if necessary in the presence of activated carbon and / or hearth coke, and the solid sodium compounds formed as a table salt for non-ferrous metal processing, e.g. B. Use aluminum scrap processing.
- the melting process produces approx. 70,000 Nm 3 / h exhaust gas, which has the following pollutant contents:
- the temperature of the exhaust gas when it enters the flue gas cleaning system is approximately 230 ° C.
Abstract
L'invention concerne un procédé permettant de purifier des gaz brûlés de fours d'installations de fusion, de refusion ou de combustion, ainsi que l'utilisation des poussières de filtrage produites à cette occasion. Cette invention s'utilise notamment pendant la production ou la préparation de métaux non ferreux. Selon l'invention, on injecte à sec au moins un composé alcalin, notamment du NaHCO3, éventuellement en présence de charbon actif et/ou de coke de four Martin, dans les gaz brûlés qui se dégagent du processus de production. La poussière de filtrage produite à cette occasion est renvoyée dans le processus de fusion ou de combustion. Etonnamment, il a été démontré que la poussière de filtrage ainsi renvoyée permettait d'abaisser la teneur en dioxine et en furane dans le gaz brut. La composition de la poussière de filtrage permet également de l'utiliser comme sel de recouvrement pour la production d'aluminium secondaire.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19529649 | 1995-08-11 | ||
DE19529649 | 1995-08-11 | ||
DE19621492 | 1996-05-29 | ||
DE1996121492 DE19621492A1 (de) | 1995-08-11 | 1996-05-29 | Verfahren zur Verminderung des Dioxin- und Furangehaltes in Ofenabgasen und Nutzung der dabei anfallenden Filterstäube |
PCT/EP1996/003407 WO1997006876A1 (fr) | 1995-08-11 | 1996-08-02 | Procede permettant de reduire la teneur en dioxine et en furane dans des gaz brules de fours et utilisation des poussieres de filtrage produites a cette occasion |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0843587A1 true EP0843587A1 (fr) | 1998-05-27 |
Family
ID=26017633
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96927659A Ceased EP0843587A1 (fr) | 1995-08-11 | 1996-08-02 | Procede permettant de reduire la teneur en dioxine et en furane dans des gaz brules de fours et utilisation des poussieres de filtrage produites a cette occasion |
Country Status (5)
Country | Link |
---|---|
US (1) | US6077328A (fr) |
EP (1) | EP0843587A1 (fr) |
CA (1) | CA2225654A1 (fr) |
RO (1) | RO119693B1 (fr) |
WO (1) | WO1997006876A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG68092A1 (en) * | 1998-02-20 | 1999-10-19 | Meidensha Electric Mfg Co Ltd | Process and system for treating material containing noxious components |
JP2001215007A (ja) * | 1999-11-25 | 2001-08-10 | Zeolite Kagaku Sangyo Kk | ダイオキシン類を殆ど発生しないごみの焼却方法及びダイオキシン類発生抑制剤並びにその製造方法 |
ES2321550T3 (es) * | 2006-12-18 | 2009-06-08 | Befesa Aluminio Bilbao, S.L. | Proceso de reciclado de polvos de filtro. |
US11874173B1 (en) | 2015-11-24 | 2024-01-16 | Exergen Corporation | Devices and methods for detecting inflammation |
EP3960279A1 (fr) * | 2020-09-01 | 2022-03-02 | Primetals Technologies Austria GmbH | Recirculation des matières valorisables de la purification de gaz d'échappement |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE294187C (fr) * | ||||
DE2056096B2 (de) * | 1970-11-14 | 1978-09-28 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Abtrennung von Fluorwasserstoff aus Gasen |
US4065271A (en) * | 1973-09-15 | 1977-12-27 | Metallgesellschaft Aktiengesellschaft | Process of separating hydrogen fluoride from gases |
IT1126403B (it) * | 1979-11-27 | 1986-05-21 | Tonolli & C Spa A | Procedimento e impianto per il lavaggio dei fumi e il recupero dei sali in un processo di produzione di alluminio secondario |
SU899101A1 (ru) * | 1980-06-12 | 1982-01-23 | Донецкий Ордена Трудового Красного Знамени Политехнический Институт | Способ очистки отход щих газов алюминиевого производства |
DE3941894C2 (de) * | 1989-12-19 | 1996-03-07 | Steinmueller Gmbh L & C | Verfahren zum Abscheiden organischer Schadstoffe aus einem Abgas |
DE4109991C1 (fr) * | 1991-03-27 | 1992-06-25 | Metallwarenfabrik Stockach Gmbh, 7768 Stockach, De | |
US5364443A (en) * | 1993-12-01 | 1994-11-15 | Alcan International Limited | Process for combined decoating and melting of aluminum scrap contaminated with organics |
AT400007B (de) * | 1994-04-06 | 1995-09-25 | Austria Metall | Verfahren zur reinigung von ofenabgasen und zur nutzung des dabei anfallenden filterstaubes |
-
1996
- 1996-08-02 RO RO98-00186A patent/RO119693B1/ro unknown
- 1996-08-02 CA CA 2225654 patent/CA2225654A1/fr not_active Abandoned
- 1996-08-02 WO PCT/EP1996/003407 patent/WO1997006876A1/fr not_active Application Discontinuation
- 1996-08-02 EP EP96927659A patent/EP0843587A1/fr not_active Ceased
- 1996-08-02 US US09/011,534 patent/US6077328A/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO9706876A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2225654A1 (fr) | 1997-02-27 |
RO119693B1 (ro) | 2005-02-28 |
WO1997006876A1 (fr) | 1997-02-27 |
US6077328A (en) | 2000-06-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE2834950C2 (de) | Verfahren zur Rückgewinnung der Aluminium-, Alkalimetall- und Fluorbestandteile aus den bei der elektrolytischen Reduktion von Aluminiumoxyd erzeugten Abfällen und Rückständen | |
US5024822A (en) | Stabilization of fluorides of spent potlining by chemical dispersion | |
EP0359003B1 (fr) | Procédé pour vitrifier des déchets solides substantiellement anhydres et appareillage pour le réaliser | |
EP2375153B1 (fr) | Traitement de cendres volantes | |
US4956158A (en) | Stabilization of fluorides of spent potlining by chemical dispersion | |
US4722774A (en) | Recovery or arsenic and antimony from spent antimony catalyst | |
CH683676A5 (de) | Verfahren zur Aufbereitung von Kehrichtverbrennungsrückständen zu einem umweltverträglichen und für Bauzwecke verwendbaren Produkt. | |
DE3615027A1 (de) | Verfahren zur zerstoerung organischer halogenverbindungen insbesondere von chlorierten biphenylen, polychlorierten dioxinen und polychlorierten furanen | |
DE69909992T2 (de) | Nasschemisches verfahren zur aufarbeitung von stahlwerkstäuben | |
EP0340644B1 (fr) | Procédé pour l'élimination et le recyclage de déchets | |
DE2908570A1 (de) | Verfahren zur rueckgewinnung der wertmetalle aus katalysatoren | |
EP0843587A1 (fr) | Procede permettant de reduire la teneur en dioxine et en furane dans des gaz brules de fours et utilisation des poussieres de filtrage produites a cette occasion | |
AT502396B1 (de) | Verfahren zum abtrennen von verunreinigungen aus einsatzstoffen | |
DE3200347C2 (fr) | ||
CN106964628A (zh) | 一种垃圾焚烧飞灰无害化处置方法 | |
DE2700121A1 (de) | Verfahren zur halogenierung von erz | |
DE19621492A1 (de) | Verfahren zur Verminderung des Dioxin- und Furangehaltes in Ofenabgasen und Nutzung der dabei anfallenden Filterstäube | |
CN115921501A (zh) | 一种湿法干法联合脱氮除盐固氟的二次铝灰处理方法 | |
KR100418129B1 (ko) | 비산회처리방법 | |
SK132497A3 (en) | Process for the separation of copper and heavy metals from incinerated garbage residue and slag | |
DE69827331T2 (de) | Verfahren zur Reinigung von Müllverbrennungsabgasen und zur Herstellung einer wässrigen Salzlösung | |
DE2815446A1 (de) | Verfahren zum nassabscheiden von verunreinigungen aus gasen hoeherer temperatur | |
DE2107844B2 (de) | Verfahren zur großtechnischen Herstellung von Magnesiumoxyd hoher Reinheit | |
DE2818113C3 (de) | Verfahren zur Verwertung der bei der Phosphorherstellung anfallenden Abfallprodukte | |
EP0470066A2 (fr) | Procédé pour la fusion d'acier à partir de ferrailles et/ou des immondices métallifères |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19980311 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
17Q | First examination report despatched |
Effective date: 19990716 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: SOLVAY SODA DEUTSCHLAND GMBH |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
18R | Application refused |
Effective date: 20000316 |