EP0839608B1 - A polishing and smoothing machine for slabs, tiles and the like. - Google Patents

A polishing and smoothing machine for slabs, tiles and the like. Download PDF

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Publication number
EP0839608B1
EP0839608B1 EP97830510A EP97830510A EP0839608B1 EP 0839608 B1 EP0839608 B1 EP 0839608B1 EP 97830510 A EP97830510 A EP 97830510A EP 97830510 A EP97830510 A EP 97830510A EP 0839608 B1 EP0839608 B1 EP 0839608B1
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EP
European Patent Office
Prior art keywords
platform
rotation axis
frontal
machine
rotating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97830510A
Other languages
German (de)
French (fr)
Other versions
EP0839608A1 (en
Inventor
Paolo Cuoghi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Onix SRL
Original Assignee
Onix SRL
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Filing date
Publication date
Application filed by Onix SRL filed Critical Onix SRL
Publication of EP0839608A1 publication Critical patent/EP0839608A1/en
Application granted granted Critical
Publication of EP0839608B1 publication Critical patent/EP0839608B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B41/00Component parts such as frames, beds, carriages, headstocks
    • B24B41/04Headstocks; Working-spindles; Features relating thereto
    • B24B41/047Grinding heads for working on plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B29/00Machines or devices for polishing surfaces on work by means of tools made of soft or flexible material with or without the application of solid or liquid polishing agents
    • B24B29/005Machines or devices for polishing surfaces on work by means of tools made of soft or flexible material with or without the application of solid or liquid polishing agents using brushes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • B24B7/06Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor involving conveyor belts, a sequence of travelling work-tables or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B7/00Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor
    • B24B7/20Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground
    • B24B7/22Machines or devices designed for grinding plane surfaces on work, including polishing plane glass surfaces; Accessories therefor characterised by a special design with respect to properties of the material of non-metallic articles to be ground for grinding inorganic material, e.g. stone, ceramics, porcelain

Definitions

  • the invention relates to a polishing-smoothing machine for slabs, tiles and the like.
  • the invention is applicable in the smoothing of marble slabs and ceramic tiles made of the material known as porcelain stoneware.
  • WO-A-95/30515 discloses the nearest prior art and particularly describes a polishing-smoothing machine for slabs, tiles and the like, comprising
  • the prior art teaches polishing marble slabs and porcelain stoneware tiles using sanding machines having a plurality of grinders arranged in line which operate on the slab or tile first by smoothing the work-surface and then, with a series of passages under progressively-finer grinders, by progressively polishing same.
  • a characteristic of this working technique is the removal of a considerable breadth of material from the face of the slab or tile, i.e. a breadth which is sufficient to produce a perfectly flat surface which is necessary in order to obtain a fine shine.
  • this type of sanding has the drawback of opening up microporosities (which are not present in the piece as it exits from the kiln) which causes the polished surface to stain when in contact with dirt particles small enough to lodge in these porosities. Consequently it is usually necessary to apply a further proofing process, whereby the tiles are treated with a substance able to impregnate the microporosities and render them safe from dirt infiltration.
  • a further serious limitation of the prior art relating to sanding is that it is not at all able to produce a smooth finish or polish on irregular, i.e. not perfectly flat surfaces.
  • This in effect means that the kinds of tile known as structured, which are designed to have irregular rough surfaces (the prior art, indeed, presupposes that all surface irregularities have to be levelled before polishing can take place) cannot be polished.
  • the present invention provides a polishing and smoothing machine able to carry out a surface treatment which makes the tile or slab surface shinier and smoother without detracting from the original geometric conformation thereof.
  • a further aim of the present invention is to perform a smoothing operation which is characterised by the removal of a very small breadth of material.
  • a still further aim of the present invention is to realise various degrees of finish without leaving any sign of working whatsoever on the worked surface.
  • An advantage of the present invention consists in its constructional, functional and operative simplicity.
  • a further advantage of the present invention is its ability to work with consistent results on products having flat and regular surfaces but also on those having irregular surfaces and conformations.
  • a still further advantage of the present invention consists in the fact that it can be used for obtaining special products, such as antiquated marbles.
  • a yet further advantage is that the operation of the invention is very economical.
  • the frontal rotating brushes 4 are mounted idle on the platform 3, that is, with full rotating liberty about respective axes thereof, which axes are inclined at a predetermined angle with respect to a perpendicular of the plane 1.
  • the rotation axis of each brush 4 is contained within a plane which also contains the rotation axis x-x of the platform 3.
  • the angle at which the rotation axis of each brush 4 is inclined with respect to the perpendicular of the plane 1 is small - preferably about 1 sexagesimal degree.
  • the rotation axes of the brushes 4 are arranged in such a way that the active frontal surfaces of the brushes are turned towards the rotation axis x-x of the platform.
  • Each brush 4 is constituted by a disc 40.
  • Bristles 41 are arranged in a circular crown on the downwards-turned face of the disc 40, which bristles can be made of any of various materials.
  • they are made of a composite, the preference being for a plastic material functioning as a bond comprising abrasive particles of a predetermined granulometry.
  • the brushes 4 contact the upper surface of the slab or tile 2 with a predetermined pressure obtained with said known device (not illustrated) having the task of keeping the whole motor head 6 pressed downwards (i.e. against the surface of the slab or tile 2) at a predetermined and adjustable pressure.
  • Each brush 4 comes into contact with the upper surface of the slab or tile 2 only at one zone of the brush 4 frontal surface, due to the fact that the brush 4 rotation axis is slightly inclined with respect to the perpendicular of the upper surface of the slab or tile 2.
  • This geometric situation combining with the rotation about its own axis x-x of the platform 3, generates a tangential force on the brush, causing it to rotate.
  • the brushes 4 are in contact with the slab or tile 2 they are automatically drawn into rotation about their respective axes.
  • the original profile of the workpiece surface is not changed (in this case, the workpiece surface being the whole upper surface of the slab or tile 2); the operation is limited to smoothing the surface.
  • the device is particularly useful in smoothing-polishing operations on irregular and not perfectly flat surfaces, such as those of tiles made of porcelain stoneware, known as "structured" .
  • a further fundamental characteristic of the invention is that it polishes and smooths without leaving any marks, such as scoring, on the workpiece surface, independently of the degree of finishing required. This degree of finishing essentially depends on the granulometry of the abrasive contained in the bristles forming the single brushes.
  • the work surfaces are passed through a series of machine operations, rather like the one described above.
  • the machines are arranged in line, and each is equipped with brushes 4 having bristles 41 impregnated with abrasives of varying granulometry.
  • the work order is organised so that a gradually decreasing abrasive granulometry (as well as different kinds of abrasives) comes into contact with the work surface.
  • a further embodiment of the invention uses a platform 3' arranged with its rotation axis x'-x' inclined with respect to the vertical of the plane 1'.
  • the inclination is of small entity, preferably about 1 degree.
  • the platform 3' bears a plurality of brushes 4', structurally identical to the brushes 4 of the first embodiment, but having rotation axes parallel to the rotation axis x'-x' of the platform 3'. Thus the axes thereof are also inclined with respect to the perpendicular of the plane 1'.
  • This geometrical situation is the cause of the rotation of the brushes 4', which are in contact with the underlying slab or tile 2, due to the effect of the rotation of the platform 3'.
  • the overall result is similar to that obtained in the first embodiment.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
  • Grinding Of Cylindrical And Plane Surfaces (AREA)

Description

  • The invention relates to a polishing-smoothing machine for slabs, tiles and the like.
  • In particular, but not exclusively, the invention is applicable in the smoothing of marble slabs and ceramic tiles made of the material known as porcelain stoneware.
  • WO-A-95/30515 discloses the nearest prior art and particularly describes a polishing-smoothing machine for slabs, tiles and the like, comprising
  • a mobile rest plane for the slabs or tiles, whereon the slabs or tiles are conveyed in a predetermined direction;
  • a rotating plafform, commanded to rotate about an incident axis on said mobile rest plane and provided with at least one frontal rotating grinding wheel which rotates about an axis not coinciding with the rotation axis of the platform and which is predisposed to operate in contact with at least one slab or tile situated on said plane;
  • said rotation axis of said at least one frontal rotating brinding wheel being inclined, having a inclination which is predetermined with respect to a perpendicular of said mobile rest plane.
  • The prior art teaches polishing marble slabs and porcelain stoneware tiles using sanding machines having a plurality of grinders arranged in line which operate on the slab or tile first by smoothing the work-surface and then, with a series of passages under progressively-finer grinders, by progressively polishing same. A characteristic of this working technique is the removal of a considerable breadth of material from the face of the slab or tile, i.e. a breadth which is sufficient to produce a perfectly flat surface which is necessary in order to obtain a fine shine.
  • For porcelain stoneware tiles, in particular, this type of sanding has the drawback of opening up microporosities (which are not present in the piece as it exits from the kiln) which causes the polished surface to stain when in contact with dirt particles small enough to lodge in these porosities. Consequently it is usually necessary to apply a further proofing process, whereby the tiles are treated with a substance able to impregnate the microporosities and render them safe from dirt infiltration.
  • A further serious limitation of the prior art relating to sanding is that it is not at all able to produce a smooth finish or polish on irregular, i.e. not perfectly flat surfaces. This in effect means that the kinds of tile known as structured, which are designed to have irregular rough surfaces (the prior art, indeed, presupposes that all surface irregularities have to be levelled before polishing can take place) cannot be polished.
  • The present invention, as it is characterised in the claims that follow, provides a polishing and smoothing machine able to carry out a surface treatment which makes the tile or slab surface shinier and smoother without detracting from the original geometric conformation thereof.
  • A further aim of the present invention is to perform a smoothing operation which is characterised by the removal of a very small breadth of material.
  • A still further aim of the present invention is to realise various degrees of finish without leaving any sign of working whatsoever on the worked surface.
  • An advantage of the present invention consists in its constructional, functional and operative simplicity.
  • A further advantage of the present invention is its ability to work with consistent results on products having flat and regular surfaces but also on those having irregular surfaces and conformations.
  • A still further advantage of the present invention consists in the fact that it can be used for obtaining special products, such as antiquated marbles.
  • A yet further advantage is that the operation of the invention is very economical.
  • Further characteristics and advantages of the present invention will better emerge from the detailed description that follows of some preferred but non-exclusive embodiments of the invention, illustrated purely by way of nonlimiting examples in the accompanying figures of the drawings, in which:
  • figure 1 is a schematic vertical-elevation frontal view of a first embodiment of the invention;
  • figure 2 is a schematic lateral view from the left of figure 1;
  • figure 3 is a schematic view from above of figure 1 with some parts removed better to evidence others;
  • figure 4 is a schematic frontal view of a second embodiment of the invention. With reference to the figures, 1 denotes in its entirety a mobile rest plane for slabs or ceramic tiles 2 along which the tiles are translated in the direction indicated by the arrow 5. The plane 1 is constituted, for example, by the upper branches 10 of a normal pair of conveyor belts for ceramic tiles supported during motion by guides 11, horizontal guides in the present example. In the first embodiment shown, a rotating platform 3 is arranged above the plane 1. The platform 3 rotates about an axis x-x which is perpendicular to the plane 1 and arranged on the same longitudinal halfway-line. The platform 3 is mounted on a motor head 6 which in turn is vertically-slidably coupled on a vertical guide 7 fixed to a frame. A known-type device, not illustrated in the figures, presses the motor head 6 downwards against the tiles on the plane; the entity of the downwards pressure being adjustable and predetermined.
  • The rotating platform 3, in the embodiment shown in figures 1 and 2, inferiorly bears a plurality of rotating frontal brushes 4 which are arranged in such a way as to form a crown about axis x-x of the platform itself.
  • With reference to the presence of a plurality of frontal rotating brushes supported on the rotating platform, it should be noted that the essential characteristics and specific functionality of the invention are all perfectly expressed in an embodiment having at least one frontal rotating brush, obviously having all of the attributes of each of the frontal rotating brushes of said plurality of brushes.
  • The frontal rotating brushes 4 are mounted idle on the platform 3, that is, with full rotating liberty about respective axes thereof, which axes are inclined at a predetermined angle with respect to a perpendicular of the plane 1. In particular, the rotation axis of each brush 4 is contained within a plane which also contains the rotation axis x-x of the platform 3. The angle at which the rotation axis of each brush 4 is inclined with respect to the perpendicular of the plane 1 is small - preferably about 1 sexagesimal degree.
  • The rotation axes of the brushes 4 are arranged in such a way that the active frontal surfaces of the brushes are turned towards the rotation axis x-x of the platform.
  • Each brush 4 is constituted by a disc 40. Bristles 41 are arranged in a circular crown on the downwards-turned face of the disc 40, which bristles can be made of any of various materials. In the present example, concerned with porcelain stoneware, they are made of a composite, the preference being for a plastic material functioning as a bond comprising abrasive particles of a predetermined granulometry.
  • During normal functioning the slabs or tiles 2 are translated on the plane 1 in the direction indicated by the arrow 5. Two lateral containment edges 9, situated in the operative zone of the brushes 4, prevent lateral displacements of the tiles 2 during the smoothing operation.
  • The brushes 4 contact the upper surface of the slab or tile 2 with a predetermined pressure obtained with said known device (not illustrated) having the task of keeping the whole motor head 6 pressed downwards (i.e. against the surface of the slab or tile 2) at a predetermined and adjustable pressure.
  • Each brush 4 comes into contact with the upper surface of the slab or tile 2 only at one zone of the brush 4 frontal surface, due to the fact that the brush 4 rotation axis is slightly inclined with respect to the perpendicular of the upper surface of the slab or tile 2. This geometric situation, combining with the rotation about its own axis x-x of the platform 3, generates a tangential force on the brush, causing it to rotate. Thus, when the brushes 4 are in contact with the slab or tile 2 they are automatically drawn into rotation about their respective axes.
  • As a result of the combination of movements generated, the ends of the bristles 41 come into contact with the upper surface of the slab or tile 2, dragging thereupon over short tracts thereof, during which, thanks to the abrasives contained in the bristles themselves, a mechanical smoothing action is produced, characterised by the removal of very small quantities of material.
  • Overall, when working on homogeneous materials, the original profile of the workpiece surface is not changed (in this case, the workpiece surface being the whole upper surface of the slab or tile 2); the operation is limited to smoothing the surface.
  • For the above reason, the device is particularly useful in smoothing-polishing operations on irregular and not perfectly flat surfaces, such as those of tiles made of porcelain stoneware, known as "structured" .
  • A further fundamental characteristic of the invention is that it polishes and smooths without leaving any marks, such as scoring, on the workpiece surface, independently of the degree of finishing required. This degree of finishing essentially depends on the granulometry of the abrasive contained in the bristles forming the single brushes.
  • In order to obtain a predetermined degree of slab or tile surface finish, the work surfaces are passed through a series of machine operations, rather like the one described above. The machines are arranged in line, and each is equipped with brushes 4 having bristles 41 impregnated with abrasives of varying granulometry. The work order is organised so that a gradually decreasing abrasive granulometry (as well as different kinds of abrasives) comes into contact with the work surface.
  • A further embodiment of the invention uses a platform 3' arranged with its rotation axis x'-x' inclined with respect to the vertical of the plane 1'. In this case, too, the inclination is of small entity, preferably about 1 degree.
  • The platform 3' bears a plurality of brushes 4', structurally identical to the brushes 4 of the first embodiment, but having rotation axes parallel to the rotation axis x'-x' of the platform 3'. Thus the axes thereof are also inclined with respect to the perpendicular of the plane 1'. This geometrical situation is the cause of the rotation of the brushes 4', which are in contact with the underlying slab or tile 2, due to the effect of the rotation of the platform 3'. The overall result is similar to that obtained in the first embodiment.

Claims (11)

  1. A polishing-smoothing machine for slabs, tiles and the like, comprising:
    a mobile rest plane (1) for the slabs or tiles (2), whereon the slabs or tiles (2) are conveyed in a predetermined direction;
    a rotating platform (3, 3'), commanded to rotate about an incident axis on said mobile rest plane (1) and provided with at least one frontal rotating brush (4, 4') which rotates about an axis not coinciding with the rotation axis of the platform (3, 3') and which is predisposed to operate in contact with at least one slab or tile (2) situated on said plane (1);
    said rotation axis of said at least one frontal rotating brush (4, 4') being inclined, having a inclination which is predetermined with respect to a perpendicular of said mobile rest plane (1).
  2. The machine of claim 1, characterised in that the rotation axis of said platform (3, 3') is contained in a plane which is parallel to an advancement direction of the slabs or tiles (2) on said mobile plane (1) and which is perpendicular to said mobile plane (1).
  3. The machine of claim 2, characterised in that the at least one frontal rotating brush (4, 4') is mounted idle on said platform (3, 3'), having full freedom rotation about an axis thereof.
  4. The machine of claim 3, characterised in that the rotation axis of the platform (3, 3') and the rotation axis of the at least one frontal rotating brush (4, 4') are coplanar.
  5. The machine of claim 4, characterised in that the rotation axis of the platform (3) is perpendicular to the mobile rest plane (1).
  6. The machine of claim 5, characterised in that the rotation axis of the at least one frontal rotating brush (4) is inclined with respect to the perpendicular- of the mobile rest plane (1), said perpendicular axis being parallel to the rotation axis of said platform (3), with a small-entity inclination angle.
  7. The machine of claim 1, characterised in that the at least one frontal rotating brush (4, 4') is constituted by a disc (40) on a face of which bristles (41) are fixed and arranged in a circular crown pattern; said bristles (41) exhibiting a composite structure constituted by a plastic material functioning as a bond and containing particles of abrasive material.
  8. The machine of any one of the preceding claims, characterised in that said rotating platform (3) is provided with a plurality of said frontal rotating brushes (4) which are arranged in such a way as to form a crown configuration about the rotation axis of the platform (3).
  9. The machine of claim 8, characterised in that the frontal rotating brushes (4) of said plurality of brushes exhibit rotation axes which are equally inclined with respect to the rotation axis of the platform (3).
  10. The machine of any one of the preceding claims from 1 to 4 and claim 7,
    characterised in that the rotation axis of said rotating platform (3') is inclined, with a small entity of inclination, with respect to the perpendicular of said mobile rest plane (1); the rotation axis of said at least one frontal rotating brush (4') being parallel to the rotation axis of the platform (3').
  11. The machine of claim 10, characterised in that said rotating platform (3') is provided with a plurality of said frontal rotating brushes (4'), which are arranged in such a way as to form a crown about the rotation axis of the platform.
EP97830510A 1996-11-04 1997-10-10 A polishing and smoothing machine for slabs, tiles and the like. Expired - Lifetime EP0839608B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT96MO000144A IT1287499B1 (en) 1996-11-04 1996-11-04 POLISHING-SMOOTHING MACHINE FOR SLABS, TILES AND SIMILAR
ITMO960144 1996-11-04

Publications (2)

Publication Number Publication Date
EP0839608A1 EP0839608A1 (en) 1998-05-06
EP0839608B1 true EP0839608B1 (en) 2001-05-23

Family

ID=11386173

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97830510A Expired - Lifetime EP0839608B1 (en) 1996-11-04 1997-10-10 A polishing and smoothing machine for slabs, tiles and the like.

Country Status (5)

Country Link
EP (1) EP0839608B1 (en)
DE (1) DE69704918T2 (en)
ES (1) ES2157057T3 (en)
IT (1) IT1287499B1 (en)
PT (1) PT839608E (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6986703B2 (en) 2002-09-25 2006-01-17 Georg Weber Apparatus for processing substantially planar workpieces

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1305459B1 (en) * 1998-02-24 2001-05-09 Onix Srl SANDING-POLISHING MACHINE FOR SLABS, TILES AND SIMILAR
DE10035637A1 (en) * 2000-07-21 2002-02-07 Richard Scheuerlein Method and device for treating a surface of concrete components
DE10125448A1 (en) * 2001-05-25 2002-12-05 Paul Wasmer Grinding machine for finishing concrete or stone workpieces has rotary driven support disc and grinding tools inclined relative to workpiece support to allow air cooling when grinding parts are not in engagement
WO2008064637A1 (en) * 2006-12-01 2008-06-05 Fleissner Gmbh Method and device for producing web material having a fluffy surface, and web material produced accordingly
ITVI20110025A1 (en) * 2011-02-11 2012-08-12 Alba Paolo HEAD OF WHEELS TO BE MOUNTED ON SANDING MACHINES OF STONE MATERIALS, AS MARBLE, GRANITE AND SIMILAR
CN108284377B (en) * 2017-01-09 2023-12-19 广东科达洁能股份有限公司 Ceramic tile composite motion trail polishing method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4319434A (en) * 1980-05-08 1982-03-16 R/B Manufacturing, Inc. Surface processing machine
FR2584011B1 (en) * 1985-06-28 1989-02-24 Renault BRUSHING HEAD, ESPECIALLY FOR MACHINING CENTERS
IT1215384B (en) * 1987-03-13 1990-02-08 Pola E Massa S N C Di Pola C E DEVICE FOR THE TREATMENT OF PLATES FOR PRINTED CIRCUITS, IN PARTICULAR FOR PUMICE CLEANING AND DEBURRING.
DE8806552U1 (en) * 1988-05-19 1988-08-11 KADIA Maschinenbau Kopp GmbH & Co, 7440 Nürtingen Machine for deburring workpieces
EP0758287A1 (en) * 1994-05-06 1997-02-19 Sirt Societa' Industriale Ricerca Tecnologica S.R.L. A machine for smoothing/polishing flat slabs, in particular of ceramic material, natural stone, or other equivalent materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6986703B2 (en) 2002-09-25 2006-01-17 Georg Weber Apparatus for processing substantially planar workpieces

Also Published As

Publication number Publication date
DE69704918D1 (en) 2001-06-28
ES2157057T3 (en) 2001-08-01
ITMO960144A0 (en) 1996-11-04
DE69704918T2 (en) 2001-11-15
PT839608E (en) 2001-09-28
ITMO960144A1 (en) 1998-05-04
EP0839608A1 (en) 1998-05-06
IT1287499B1 (en) 1998-08-06

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