EP0809617A1 - Vehicle occupant restraint systems powered by gas generating compositions - Google Patents

Vehicle occupant restraint systems powered by gas generating compositions

Info

Publication number
EP0809617A1
EP0809617A1 EP96902368A EP96902368A EP0809617A1 EP 0809617 A1 EP0809617 A1 EP 0809617A1 EP 96902368 A EP96902368 A EP 96902368A EP 96902368 A EP96902368 A EP 96902368A EP 0809617 A1 EP0809617 A1 EP 0809617A1
Authority
EP
European Patent Office
Prior art keywords
vehicle occupant
occupant restraint
gas generating
restraint system
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96902368A
Other languages
German (de)
English (en)
French (fr)
Inventor
David Gerald Davies
John Robertson
Mark Inigo Phillips
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BAE Systems Global Combat Systems Munitions Ltd
Original Assignee
Royal Ordnance PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Royal Ordnance PLC filed Critical Royal Ordnance PLC
Publication of EP0809617A1 publication Critical patent/EP0809617A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06DMEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
    • C06D5/00Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
    • C06D5/06Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/16Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
    • B60R21/26Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow
    • B60R21/264Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow using instantaneous generation of gas, e.g. pyrotechnic
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B25/00Compositions containing a nitrated organic compound
    • C06B25/34Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine

Definitions

  • This invention relates to vehicle occupant restraint systems which arc
  • composition is required to inflate the bag, and in the case of a scat belt
  • pre-tensioner it provides the motive force to operate the pre-tensioning
  • compositions arc generally of a pyrotechnic nature and arc
  • sodium azide-bascd compositions single or
  • propcllants in stability and to sodium azidc in toxicity are propcllants in stability and to sodium azidc in toxicity.
  • the percentage conversion to gas is approximately 60 - 70% by weight, of which most is nitrogen and very little is carbon monoxide, although up to 10% is carbon
  • compositions generate a smaller weight of solid particulatc products
  • aminotctrazolcs is, however, relatively high and their advantages arc not
  • composition of low toxicity having combustion products also of low toxicity
  • a stable gas generating composition comprising
  • the present invention provides a vehicle occupant restraint system which
  • compositions of the invention is aluminium, or a silicate.
  • nitroguanidinc component (i) of the compositions of the invention is
  • invention is also preferably of low toxicity and has combustion products of low
  • Suitable oxidising agents include, for example, nitrates, and particularly
  • nitrates of metals more particularly alkali and alkaline earth metals, especially
  • oxidising agents such as potassium pcrchlorate may also be used, cither
  • Oxidising agents comprising bismuth, barium, vanadium and chromium
  • salts arc not preferred because of the toxicity of the compounds themselves, or of
  • Component (iii) of the composition comprises an oxide of silicon or
  • aluminium aluminium, a mixed oxide of silicon and aluminium, or a silicate.
  • silica silica, alumina, silicoaluminatcs. diatomaccous solids and
  • the third component is preferably present in a
  • compositions of the present invention preferably comprise from 50 to
  • compositions according to the invention arc relatively
  • temperatures for example up to 200°C.
  • the vehicle occupant restraint system according to the invention can be an
  • a solid gas generating composition according to the invention is prepared
  • composition I sodium nitrate, and 4% by weight of silica in a blender.
  • composition is found to be stable at 105°C for a period of 6 months.
  • Figure 1 shows, in side elevation, an embodiment of a vehicle occupant
  • restraint system in the form of a scat belt pretensioner
  • Figure 2 shows the pretensioner of Figure 1 in top elevation
  • Figure 3 shows the pretensioner of Figures 1 and 2 in side elevation in
  • FIG 4 shows the pretensioner of Figures 1 to 3 in end elevation again
  • Figure 5 shows a scrap view in section of the gas-gencrating
  • Figure 6 shows another embodiment of a vehicle occupant restraint
  • the pressure tube 2 is mounted eccentrically of the axis of
  • the drive wheel 3 and has a diameter of curvature slightly greater than the wheel.
  • the tube 2 has a closed end, at which there is situated a cap enclosing a gas- generating mechanism 5, and an open end which is cut back, as illustrated by
  • curved pressure tube 2 describes approximately ⁇ V ⁇ turns about the drive wheel 3.
  • the pretensioner is enclosed in a collection chamber 9, which may comprise the
  • the balls 1 1 have a diameter slightly less than the internal diameter of the
  • the drive wheel 3 is provided with a
  • Figure 4 which also shows the drive shaft 4 which is attached to the take-up reel of a scat belt retractor (not shown).
  • Figure 5 shows a detail of the gas-generating mechanism 5.
  • Example Composition I is packed into a pressure -resistant plug 14 firmly
  • the pyrotechnic composition 13 is ignited by an electronic igniter (not shown) which is activated by a deceleration
  • a felt plug 16 is positioned at the end 15 of the pressure tube
  • the plug 16 prevents the foam from reacting the
  • the ball retaining means may alternatively comprise, for example, a
  • frangible plug or a spring means, which is compressed as the balls arc ejected
  • the deceleration sensor activates
  • composition 13 The volume of gas generated by the composition 13 is sufficient
  • the path of the balls is tangential to the circumference of the drive
  • pretensioner is preferably enclosed within the housing of the scat belt retractor
  • pretensioner has been activated. After use. they can be recovered and reused
  • retractor lock is released and the scat belt can again be used normally.
  • Figure 6 shows an inflator assembly for an
  • the inflator assembly illustrated generally at 21, comprises a generally
  • the flange 23 has
  • the air bag is
  • cap member 29 mounted on the housing 22. is a cap member 29 provided with an annular
  • control unit (not shown) which, when a rapid deceleration is detected, electrically
  • the igniter and booster 25 ignites the pellets
  • This invention extends to any novel one, or any novel combination, of the

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Mechanical Engineering (AREA)
  • Air Bags (AREA)
  • Automotive Seat Belt Assembly (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
EP96902368A 1995-02-16 1996-02-15 Vehicle occupant restraint systems powered by gas generating compositions Withdrawn EP0809617A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9503066 1995-02-16
GBGB9503066.4A GB9503066D0 (en) 1995-02-16 1995-02-16 Gas generating composition
PCT/GB1996/000328 WO1996025375A1 (en) 1995-02-16 1996-02-15 Vehicle occupant restraint systems powered by gas generating compositions

Publications (1)

Publication Number Publication Date
EP0809617A1 true EP0809617A1 (en) 1997-12-03

Family

ID=10769729

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96902368A Withdrawn EP0809617A1 (en) 1995-02-16 1996-02-15 Vehicle occupant restraint systems powered by gas generating compositions

Country Status (5)

Country Link
EP (1) EP0809617A1 (ja)
JP (1) JPH11503398A (ja)
KR (1) KR19980702167A (ja)
GB (1) GB9503066D0 (ja)
WO (1) WO1996025375A1 (ja)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3247929B2 (ja) * 1995-11-14 2002-01-21 ダイセル化学工業株式会社 ガス発生剤組成物
US6527886B1 (en) 1996-07-22 2003-03-04 Daicel Chemical Industries, Ltd. Gas generant for air bag
US6306232B1 (en) * 1996-07-29 2001-10-23 Automotive Systems Laboratory, Inc. Thermally stable nonazide automotive airbag propellants
US6071364A (en) * 1997-02-19 2000-06-06 Breed Automotive Technology, Inc. Gas generating compositions containing mica
JP3641343B2 (ja) * 1997-03-21 2005-04-20 ダイセル化学工業株式会社 低残渣エアバッグ用ガス発生剤組成物
US6024889A (en) 1998-01-29 2000-02-15 Primex Technologies, Inc. Chemically active fire suppression composition
DE19812372C2 (de) * 1998-03-20 2001-10-04 Nigu Chemie Gmbh Gasgeneratortreibstoffe
JP2001002488A (ja) 1999-06-17 2001-01-09 Daicel Chem Ind Ltd プリテンショナー用ガス発生剤組成物
DE10064285C1 (de) * 2000-12-22 2002-10-17 Nigu Chemie Gmbh Gasgeneratortreibstoff-Zusammensetzung und deren Verwendung
CN111675589B (zh) * 2020-05-15 2021-08-06 湖北航鹏化学动力科技有限责任公司 一种气体发生剂组合物、制备方法及其应用
CN111548242B (zh) * 2020-05-15 2021-09-03 湖北航鹏化学动力科技有限责任公司 气体发生器

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE884170C (de) * 1946-11-08 1953-07-23 Ici Ltd Gaserzeugende Ladung
US5125684A (en) * 1991-10-15 1992-06-30 Hercules Incorporated Extrudable gas generating propellants, method and apparatus
CA2115557C (en) * 1992-07-13 2000-07-25 Tadao Yoshida Air bag gas generating composition
DE4412871C2 (de) * 1993-04-15 1997-08-14 Nof Corp Zusammensetzungen für Gasgeneratoren
HUT76867A (en) * 1993-10-06 1997-12-29 Nigu Chemie Gmbh Gas developing agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9625375A1 *

Also Published As

Publication number Publication date
WO1996025375A1 (en) 1996-08-22
MX9706474A (es) 1998-06-28
JPH11503398A (ja) 1999-03-26
GB9503066D0 (en) 1995-04-05
KR19980702167A (ko) 1998-07-15

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